Startseite Naturwissenschaften Responses of feldspathic sandstone and sand-reconstituted soil C and N to freeze–thaw cycles
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Responses of feldspathic sandstone and sand-reconstituted soil C and N to freeze–thaw cycles

  • Haiou Zhang EMAIL logo , Chenxi Yang , Xueying Wu , Zhen Guo und Yingguo Wang
Veröffentlicht/Copyright: 26. Januar 2023

Abstract

The Mu Us Desert in China is significantly affected by seasonal freeze–thaw processes. In order to evaluate the adaptation potential of reconstituted soil with different proportions of feldspathic sandstone and sand to extreme environment, the laboratory simulation freeze-thaw experiments was conducted to study the characteristics of soil C and N under freeze–thaw conditions. The results showed that the content of soil organic matter reached the peak after two cycles of freezing and thawing in T1, T2 and T3, compared to before freeze–thaw cycle, the soil organic matter content increased by 70, 55 and 59%. After ten cycles of freezing and thawing, the content of soil organic matter increased significantly in T2 and T3. After one cycle of freezing and thawing, soil nitrogen content reached the peak. After ten cycles of freeze–thaw cycle, compared to before freeze–thaw cycle, the contents of ammonium nitrogen increased by 10, 49 and 11%, and the contents of nitrate nitrogen increased by 14, 39 and 34% in T1, T2 and T3. In conclusion, short-term freeze–thaw cycles in the Mu Us Desert significantly increased the accumulation of soil carbon and nitrogen reconstructed by different ratios of feldspathic sandstone and sand, and T2 and T3 treatments had better retention performance on soil organic matter and nitrogen, which has a good adaptability to the extreme environment.

1 Introduction

Soil freezing and thawing is an important factor affecting the release and availability of soil nutrients [1,2]. However, soil organic matter and nitrogen are important components of soils, and their content and dynamic balance not only directly affect soil quality and land productivity [3,4], but also have important implications for the carbon and nitrogen cycles in ecosystems [5,6]. At present, soil organic matter and nitrogen have become one of the core research types on global change problems [7]. Soil freezing and thawing is mainly by destroying soil aggregates and organic matter structure, killing certain microorganisms in the soil, increasing the death and decomposition of fine plant roots, and accelerating the fragmentation of plant residues to release nutrients needed for plant growth [8,9]. At the same time, the thawing process following soil freezing often leads to enhanced microbial respiration [10] and increased concentrations of C, N and P nutrients in the soil [11], potentially affecting ecosystem nutrient cycling processes and ecosystem productivity [12]. After freezing–thawing cycle, soil coarse mineral particles are fragmented mechanically and fine particles are aggregated, and soil particle size tends to be homogeneous [13]. Therefore, the seasonal freezing–thawing alternating action can pulverize large blocks of feldspathic sandstone, which is more conducive to the full mixing of feldspathic sandstone and sand to form reconstituted soil in the Mu Us Desert [14].

The Mu Us Desert annually lasts a freeze period of 4–5 months, and the temperature goes below 0°C in November and gradually returns to above 0°C in March of the following year, with the soil in a frozen and thawed state in the late autumn and early spring seasons. Soils are affected by the temperate cool climate and the seasonal freeze layer, and the resulting freeze–thaw alternation has a significant impact on regional soils [15]. In the Mu Us Desert, feldspathic sandstone and sand are two relatively independent natural substances, and they are the main factors causing soil erosion and land desertification. Han et al. [16,17] found that the rich clay minerals in feldspathic sandstone can improve the erosion resistance and water and fertility retention of sandy soils, and after reconstituting feldspathic sandstone and sandy soils into “soil” according to scientific ratios, they found that the optimal mixing ratio of feldspathic sandstone and sand was 1:1–1:5, and its water and fertility retention performance was the strongest [18,19]. It has been used in large-scale demonstrations. The effects of freeze–thaw on soil structure and mechanical characteristics have been studied extensively at home and abroad [8,11,13,20,21]; however, studies on the effects of soil freeze–thaw processes on organic carbon and nitrogen mineralization in feldspathic sandstone and sand-reconstructed soils in the Mu Us Desert, China, have not been reported. In this study, we investigated the effects of soil freeze–thaw processes on the carbon and nitrogen contents of different proportions of feldspathic sandstone and sand-reconstituted soils in the Mu Us Desert after land remediation, so as to determine the adaptation potential of different proportions of reconstituted soils to extreme environments and to help understand the soil nitrogen cycling processes in the Mu Us Desert. This study has important practical significance for guiding vegetation management and soil fertility improvement in early spring in seasonal frozen soil region.

2 Materials and methods

2.1 Overview of the study area

The study area is located at the southern edge of the Mu Us Desert, in the middle reaches of the Wuding River (109°28′58″-109°30′10″E, 38°27′53″-38°28′23″N), at an altitude of 1,206–1,215 m. The climate is mainly temperate arid and semi-arid types, with annual rainfall ranging from 200 to 600, sunshine for 2,500–3,000 h throughout the year, with a sunshine percentage as high as 70–80%. The annual average temperature in the sandy area is 6.0–8.5°C, the average temperature in January is −9.5 to 12°C, the average temperature in July is 22–24°C, and the annual average frost-free period is 120–300 days. Feldspathic sandstone and sand in the Mu Us Desert are distributed interspersedly, and the soil type is mainly aeolian soils, with a total nitrogen content of 0.075%, a total phosphorus content of 0.63 g kg−1, a total potassium content of 26.51 g kg−1 and an organic matter content of 0.03%.

2.2 Research methodology

The experimental soil samples were collected from the field scientific observation test plots of feldspathic sandstone amended wind-sand soil in Xiao Jihan Township, Yuyang District, Yulin City, Shaanxi Province, with each plot being 12 m long × 5 m wide. The original sandy soil was covered with a layer of 30-cm-thick reconstituted soil in each test plot according to the needs of the study, with volumetric ratios of 1:1 (T1), 1:2 (T2) and 1:5 (T3) of feldspathic sandstone to sandy soil, respectively. Below 30 cm was the original local aeolian soils 0:1 (T0). Soils were collected from the 0 to 30 cm surface layer and immediately placed in a 0–4°C freezer and taken back to the laboratory for freeze–thaw incubation tests. Local irrigation water was also collected, and the test samples were moisture corrected. The main physicochemical properties of the reconstituted soil and the original aeolian soil for the different treatments are detailed in Table 1.

Table 1

Main physical and chemical properties of soils reconstructed by feldspathic sandstone and sand

Feldspathic sandstone (F): Sand (S) Soil depth (cm) Soil mechanical composition (%) Texture Bulk density (g cm−3) Total nitrogen (g kg−1) Organic matter (g kg−1)
Sand Silt Clay
T1 0–30 53.82 38.12 8.06 Loam 1.37 0.44 2.26
T2 0–30 68.86 26.01 5.13 Sandy loam 1.52 0.54 2.61
T3 0–30 79.03 17.35 3.62 Sandy loam 1.56 0.65 2.97
T0 0–30 95.00 4.15 0.85 Sandy soil 1.61 0.75 3.32

The collected soil samples treated with T0, T1, T2 and T3 were removed from grassroots and other debris, air-dried, and then passed through a 2 mm sieve for freeze–thaw culture experiments. The five samples of 500 g each were prepared for each treatment and placed in 20 round aluminium boxes. In order to keep the freeze–thaw conditions in the chamber closer to the natural state, i.e. temperature fluctuations start as close as possible to the top layer of soil, the aluminium boxes were covered with asbestos mesh to achieve better insulation. The soil was completely frozen at −15 to −5°C for a 24-h period and then placed at 15°C for 24 h, and this constituted one freeze–thaw cycle. Five samples from each treatment, replicated three times, were used to determine the organic matter, nitrate and ammonium nitrogen content of the soil of before freeze–thaw, one cycle, two cycles, five cycles and ten cycles, respectively. The T1 freeze–thaw-treated soil samples were recorded as M0, M1, M2, M5 and M10; the T2 soil samples were recorded as A0, A1, A2, A5 and A10; the T3 soil samples were recorded as S0, S1, S2, S5 and S10; and the T0 soil samples were recorded as H0, H1, H2, H5 and H10. M0, A0, S0 and H0 were control samples and were not subjected to freeze–thaw treatment. In order to simulate the actual soil freeze–thaw conditions, the moisture content of the soil samples needed to be moisture corrected by adjusting the soil moisture content to 60% of the maximum field holding capacity, and then, during the experiment, the lost water was continuously replenished by weighing method to maintain the corresponding moisture condition of the test soil samples. Soil samples were extracted with 2 mol L−1 KCl solution (5:1 water to soil ratio) before the test and the nitrate, and ammonium nitrogen content was determined using a fully automated intermittent chemical analyser (Cleverchem 200, Germany), while the soil moisture was measured by gravimetric method. Soil organic matter content was determined using the potassium dichromate volumetric method – external heating method [22].

2.3 Data processing

SPSS 13.0 statistical analysis software was used for T-test to analyse the differences of soil organic matter, ammonia nitrogen and nitrate nitrogen in T1, T2 and T3 treatments after different freeze–thaw cycles. There were significant differences (P < 0.05) and no significant differences (P > 0.05). The experimental data were collated and plotted using Excel 2010 and SigmaPlot 12, respectively.

3 Results

3.1 Effects of freezing–thawing cycles on reconstructed soil organic matter content

The freeze–thaw cycle had a significant effect (P < 0.005) on the organic matter content of the feldspathic sandstone and sand reconstituted soils (Figure 1). The organic matter content of the three reconstituted soils before freeze–thaw was T2 > T3 > T1, and as the freeze–thaw cycle increased, the organic matter content of the soils in the three treatments showed an overall trend of increasing and then decreasing. The organic matter content of the soils increased significantly at the beginning of the freeze–thaw cycle, and the organic matter content of the soils of the three treatments reached a peak at the second cycle of the freeze–thaw cycle, in the order of T1 > T2 > T3. Before freeze–thaw cycle, the organic matter content of the soils of the T1, T2 and T3 reconstructions increased by 70, 55 and 59%, respectively. After two cycles, the soil organic matter content began to decrease; after ten cycles, the organic matter content of T1, T2 and T3 reconstituted soils was 0.89, 0.74 and 0.77%, respectively, with an overall levelling off, but the organic matter content still increased overall compared to before freeze–thaw cycle, with no significant difference between T2 and T3 (P > 0.005).

Figure 1 
                  Changes of organic matter content in reconstructed soils with different freezing–thawing cycles. Letters above the bars indicate the significance of the differences (at 0.05 level) between treatments; the small bar shows standard deviation. Bars in different treatments but with the same letters are not significantly different at P > 0.05.
Figure 1

Changes of organic matter content in reconstructed soils with different freezing–thawing cycles. Letters above the bars indicate the significance of the differences (at 0.05 level) between treatments; the small bar shows standard deviation. Bars in different treatments but with the same letters are not significantly different at P > 0.05.

3.2 Effects of freezing–thawing cycles on nitrate nitrogen content in reconstructed soils

As can be seen from Figure 2, with the increase in the freeze–thaw cycle, the nitrate–nitrogen content of the soils of the three treatments showed a trend of first increasing, then decreasing and then steadily increasing. Before freeze–thaw and at the beginning of the freeze–thaw cycle, the nitrate–nitrogen content of the soils in all three treatments was T2 > T1 > T3. The nitrate–nitrogen content of the reconstituted soil increased significantly with increasing freeze–thaw cycles at the beginning of the freeze–thaw cycle, with the most pronounced increase reaching a peak at one cycle of freeze–thaw. Compared to the pre-freeze–thaw treatment, soil nitrate-N content increased by 1.30, 1.52 and 1.49 times in the T1, T2 and T3 treatments, respectively. After two cycles of freeze–thaw, the nitrate–nitrogen content of the soils in the three treatments decreased significantly and reached a minimum value. After five cycles of freeze–thaw, the overall trend of the samples with all treatments increased. Compared to the period before freeze–thaw, after ten cycles of freeze–thaw, the nitrate–nitrogen content of the soils in the T1, T2 and T3 treatments increased by 14, 39 and 34%, respectively, with the content showing: T2 > T3 > T1, with the rate of increase in the nitrate–nitrogen content of the soils in the T2 and T3 treatments being more significant.

Figure 2 
                  Changes of nitrate nitrogen content in reconstructed soil with different freezing–thawing cycles.
Figure 2

Changes of nitrate nitrogen content in reconstructed soil with different freezing–thawing cycles.

3.3 Effects of freezing–thawing cycles on the ammonium nitrogen content in reconstructed soils

With the increase of freeze–thaw cycle, the distribution of ammonium nitrogen content of reconstituted soils in the three treatments changed, and the ammonium nitrogen content of reconstituted soils in different proportions showed a trend of first increasing, then decreasing and then increasing steadily. During freeze–thaw cycles 0–1, the soil ammonium nitrogen content of the three treatments was T3 > T2 > T1. During freeze–thaw cycle 1, the soil ammonium nitrogen content of the T1, T2 and T3 treatments increased significantly and reached the peak, which was 1.41, 1.64 and 1.44 times higher than that before the freeze–thaw treatment, respectively. Then, the ammonium nitrogen content of the soils in the three treatments then began to decline, reaching a minimum value after two cycles of freeze–thaw, after which the content showed a steady increase. Compared with freeze–thaw cycle 0, after ten cycles of freeze–thaw, soil ammonium nitrogen content increased by 10, 49 and 11% in the T1, T2 and T3 treatments, respectively, with T2 > T3 > T1, with T2 and T3 treatments having significantly higher soil ammonium nitrogen content than T1 (Figure 3).

Figure 3 
                  Changes of ammonium nitrogen content in reconstituted soil with different freezing–thawing cycles.
Figure 3

Changes of ammonium nitrogen content in reconstituted soil with different freezing–thawing cycles.

4 Discussion

4.1 Reconstructing soil organic content changes

Freeze–thaw alternation can affect soil organic matter content, but the results vary depending on the soil type and the research method [23,24]. In this research, it was found that with the increase in the freeze–thaw cycle, the soil organic matter content of T1, T2 and T3 treatments showed a trend of increasing and then decreasing, and the rate of change of organic matter content in different treatments was different. This is similar to the findings of Hao et al. [25], who found that soil organic matter content increased after 1–3 cycles of freeze–thawing and began to decrease after 6 cycles. Therefore, the short-term effect of freeze–thaw cycling on soil organic matter content is obvious, with significant effects of freeze–thaw frequency. This is due to the fact that changes in soil organic matter under the freeze–thaw cycle mainly originate from changes in soil microorganisms [25,26]. The increase of organic matter content in the early stage of freeze–thaw cycle is due to the death of some microorganisms in the soil due to the severe freezing temperature. These killed microorganisms release some small molecular organic matter in the decomposition process, which increases the content of organic matter in the soil. On the other hand, the stability of soil aggregates is an important factor to determine the content of soil organic matter. Freezing–thawing breaks the stability of soil aggregates and causes the organic matter wrapped and adsorbed by the soil to disaggregate ahead of time, and soil organic matter content increased [26]. After several freeze–thaw cycles, the content of organic matter in the reconstructed soil gradually decreased. On the one hand, the absolute death amount of microorganisms gradually decreased because they had adapted to the temperature change of the outside environment; accordingly, the amount of organic matter released by microorganisms is also decreasing. Second, with the development of freeze–thaw cycle experiment, the microorganisms living in the soil gradually decompose and utilize the original organic matter, resulting in the reduction of the content of organic matter in the soil [27].

4.2 Reconstructing soil nitrogen changes

There is no universal conclusion as to whether nitrate and ammonium nitrogen content in soils increases or decreases under the freeze–thaw cycle, depending on the parent soil forming material, the study area and the mode of analysis. In this study, a significant decrease in nitrate and ammonium nitrogen was found in the soils of the T1, T2 and T3 treatments after two cycles of freeze–thaw. There are mainly several reasons: (1) The nitrate and ammonium nitrogen in the soil was used by the small amount of plant roots remaining during the indoor simulated freeze–thaw test. (2) Nitrogen is sequestered by surviving or nascent microorganisms in the soil, especially under the effect of mild freeze–thaw alternations, to which the microorganisms are highly resistant. (3) Loss of inorganic nitrogen from reconstituted soil infiltrates during indoor simulations. (4) Loss of gaseous nitrogen in reconstituted soils may also lead to a decrease in the ammonium nitrogen content of the soil.

Starting from cycle 5 of the freeze–thaw cycle, the nitrate and ammonium nitrogen contents in the soils of the T1, T2 and T3 treatments all began to show a steady increase, indicating that the effect of multiple freeze–thaw cycles can increase the nitrate and ammonium nitrogen contents in the soil. This is due to the fact that some microorganisms are adapted to survive at low temperatures, and when the frozen soil thaws at elevated temperatures, the residual microorganisms use the sufficient substrate provided by the dead microorganisms, which stimulates microbial activity and facilitates the process of reconstituting the mineralization of soil organic nitrogen, thus promoting the increase of soil nitrate and ammonium nitrogen contents during the freeze–thaw cycle [28,29]. Freppaz et al. [30] and Chen et al. [31] showed that the freeze–thaw cycling process may lead to the release of NH 4 + –N from previously unavailable organic and inorganic colloids in the soil. Wang et al. [32] found that the disruption of soil aggregates during the freeze–thaw cycle resulted in an increase in extractable organic matter and mineral N in the soil.

5 Conclusions

The diurnal freeze–thaw cycle in the late autumn and early spring seasons of the Mu Us Desert enhances soil microbial activity, and the mineralization of carbon and nitrogen in the soil is still ongoing. It was found that the short-term freeze–thaw cycle could promote the increase of soil organic matter, nitrate nitrogen and ammonium nitrogen, and the adaptation potential of T2 and T3 treatments to extreme environment was higher than that of T1 treatments. After freezing and thawing cycles, the soil organic matter content, nitrate nitrogen content and ammonium nitrogen content increased significantly in T2 and T3 treatments, and the soil nutrient retention performance is better. The freeze–thaw cycle increases the mass fraction of organic matter and inorganic nitrogen in the soil, which is conducive to providing a large amount of nutrients for the growth of plants in early spring, and plays an important role in improving the fertility of the soil. This study has important scientific value for guiding the improvement of soil fertility and sustainable agricultural development in frozen soil area.

  1. Funding information: This study was financially supported by the Key Research and Development Program of Shaanxi Province (2022NY-082), Shaanxi Provincial Natural Science Basic Research Program (2021JZ-57), funded by Technology Innovation Center for Land Engineering and Human Settlements, Shaanxi Land Engineering Construction Group Co., Ltd and Xi’an Jiaotong University (2021WHZ0087) and Shaanxi Provincial Land Engineering Construction Group internal research project (DJNY2022-17).

  2. Author contributions: H.Z. – conceptualization; X.W. – methodology, C.Y. and Z.G. – software; Y.W. – Formal Analysis; Y.W. – investigation; H.Z. and C.Y. – resources; X.W. – data curation; H.Z. – writing original draft preparation; H.Z. – writing review and editing; Z.G. – project administration; H.Z. – funding acquisition. All authors have read and agreed to the published version of the manuscript.

  3. Conflict of interest: The authors state no conflict of interest.

  4. Ethical approval: The conducted research is not related to either human or animal use.

  5. Data availability statement: The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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Received: 2022-06-14
Revised: 2022-12-18
Accepted: 2023-01-04
Published Online: 2023-01-26

© 2023 the author(s), published by De Gruyter

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  27. Changes in oxidative stress markers in pediatric burn injury over a 1-week period
  28. Integrated geophysical techniques applied for petroleum basins structural characterization in the central part of the Western Desert, Egypt
  29. The impact of chemical modifications on gamma-ray attenuation properties of some WO3-reinforced tellurite glasses
  30. Microwave and Cs+-assisted chemo selective reaction protocol for synthesizing 2-styryl quinoline biorelevant molecules
  31. Structural, physical, and radiation absorption properties of a significant nuclear power plant component: A comparison between REX-734 and 316L SS austenitic stainless steels
  32. Effect of Moringa oleifera on serum YKL-40 level: In vivo rat periodontitis model
  33. Investigating the impact of CO2 emissions on the COVID-19 pandemic by generalized linear mixed model approach with inverse Gaussian and gamma distributions
  34. Influence of WO3 content on gamma rays attenuation characteristics of phosphate glasses at low energy range
  35. Study on CO2 absorption performance of ternary DES formed based on DEA as promoting factor
  36. Performance analyses of detonation engine cogeneration cycles
  37. Sterols from Centaurea pumilio L. with cell proliferative activity: In vitro and in silico studies
  38. Untargeted metabolomics revealing changes in aroma substances in flue-cured tobacco
  39. Effect of pumpkin enriched with calcium lactate on iron status in an animal model of postmenopausal osteoporosis
  40. Energy consumption, mechanical and metallographic properties of cryogenically treated tool steels
  41. Optimization of ultra-high pressure-assisted extraction of total phenols from Eucommia ulmoides leaves by response surface methodology
  42. Harpin enhances antioxidant nutrient accumulation and decreases enzymatic browning in stored soybean sprouts
  43. Physicochemical and biological properties of carvacrol
  44. Radix puerariae in the treatment of diabetic nephropathy: A network pharmacology analysis and experimental validation
  45. Anti-Alzheimer, antioxidants, glucose-6-phosphate dehydrogenase effects of Taverniera glabra mediated ZnO and Fe2O3 nanoparticles in alloxan-induced diabetic rats
  46. Experimental study on photocatalytic CO2 reduction performance of ZnS/CdS-TiO2 nanotube array thin films
  47. Epoxy-reinforced heavy metal oxides for gamma ray shielding purposes
  48. Black mulberry (Morus nigra L.) fruits: As a medicinal plant rich in human health-promoting compounds
  49. Promising antioxidant and antimicrobial effects of essential oils extracted from fruits of Juniperus thurifera: In vitro and in silico investigations
  50. Chloramine-T-induced oxidation of Rizatriptan Benzoate: An integral chemical and spectroscopic study of products, mechanisms and kinetics
  51. Study on antioxidant and antimicrobial potential of chemically profiled essential oils extracted from Juniperus phoenicea (L.) by use of in vitro and in silico approaches
  52. Screening and characterization of fungal taxol-producing endophytic fungi for evaluation of antimicrobial and anticancer activities
  53. Mineral composition, principal polyphenolic components, and evaluation of the anti-inflammatory, analgesic, and antioxidant properties of Cytisus villosus Pourr leaf extracts
  54. In vitro antiproliferative efficacy of Annona muricata seed and fruit extracts on several cancer cell lines
  55. An experimental study for chemical characterization of artificial anterior cruciate ligament with coated chitosan as biomaterial
  56. Prevalence of residual risks of the transfusion-transmitted infections in Riyadh hospitals: A two-year retrospective study
  57. Computational and experimental investigation of antibacterial and antifungal properties of Nicotiana tabacum extracts
  58. Reinforcement of cementitious mortars with hemp fibers and shives
  59. X-ray shielding properties of bismuth-borate glass doped with rare earth ions
  60. Green supported silver nanoparticles over modified reduced graphene oxide: Investigation of its antioxidant and anti-ovarian cancer effects
  61. Orthogonal synthesis of a versatile building block for dual functionalization of targeting vectors
  62. Thymbra spicata leaf extract driven biogenic synthesis of Au/Fe3O4 nanocomposite and its bio-application in the treatment of different types of leukemia
  63. The role of Ag2O incorporation in nuclear radiation shielding behaviors of the Li2O–Pb3O4–SiO2 glass system: A multi-step characterization study
  64. A stimuli-responsive in situ spray hydrogel co-loaded with naringenin and gentamicin for chronic wounds
  65. Assessment of the impact of γ-irradiation on the piperine content and microbial quality of black pepper
  66. Antioxidant, sensory, and functional properties of low-alcoholic IPA beer with Pinus sylvestris L. shoots addition fermented using unconventional yeast
  67. Screening and optimization of extracellular pectinase produced by Bacillus thuringiensis SH7
  68. Determination of polyphenols in Chinese jujube using ultra-performance liquid chromatography–mass spectrometry
  69. Synergistic effects of harpin and NaCl in determining soybean sprout quality under non-sterile conditions
  70. Field evaluation of different eco-friendly alternative control methods against Panonychus citri [Acari: Tetranychidae] spider mite and its predators in citrus orchards
  71. Exploring the antimicrobial potential of biologically synthesized zero valent iron nanoparticles
  72. NaCl regulates goldfish growth and survival at three food supply levels under hypoxia
  73. An exploration of the physical, optical, mechanical, and radiation shielding properties of PbO–MgO–ZnO–B2O3 glasses
  74. A novel statistical modeling of air pollution and the COVID-19 pandemic mortality data by Poisson, geometric, and negative binomial regression models with fixed and random effects
  75. Treatment activity of the injectable hydrogels loaded with dexamethasone In(iii) complex on glioma by inhibiting the VEGF signaling pathway
  76. An alternative approach for the excess lifetime cancer risk and prediction of radiological parameters
  77. Panax ginseng leaf aqueous extract mediated green synthesis of AgNPs under ultrasound condition and investigation of its anti-lung adenocarcinoma effects
  78. Study of hydrolysis and production of instant ginger (Zingiber officinale) tea
  79. Novel green synthesis of zinc oxide nanoparticles using Salvia rosmarinus extract for treatment of human lung cancer
  80. Evaluation of second trimester plasma lipoxin A4, VEGFR-1, IL-6, and TNF-α levels in pregnant women with gestational diabetes mellitus
  81. Antidiabetic, antioxidant and cytotoxicity activities of ortho- and para-substituted Schiff bases derived from metformin hydrochloride: Validation by molecular docking and in silico ADME studies
  82. Antioxidant, antidiabetic, antiglaucoma, and anticholinergic effects of Tayfi grape (Vitis vinifera): A phytochemical screening by LC-MS/MS analysis
  83. Identification of genetic polymorphisms in the stearoyl CoA desaturase gene and its association with milk quality traits in Najdi sheep
  84. Cold-acclimation effect on cadmium absorption and biosynthesis of polyphenolics, and free proline and photosynthetic pigments in Spirogyra aequinoctialis
  85. Analysis of secondary metabolites in Xinjiang Morus nigra leaves using different extraction methods with UPLC-Q/TOF-MS/MS technology
  86. Nanoarchitectonics and performance evaluation of a Fe3O4-stabilized Pickering emulsion-type differential pressure plugging agent
  87. Investigating pyrolysis characteristics of Shengdong coal through Py-GC/MS
  88. Extraction, phytochemical characterization, and antifungal activity of Salvia rosmarinus extract
  89. Introducing a novel and natural antibiotic for the treatment of oral pathogens: Abelmoschus esculentus green-formulated silver nanoparticles
  90. Optimization of gallic acid-enriched ultrasonic-assisted extraction from mango peels
  91. Effect of gamma rays irradiation in the structure, optical, and electrical properties of samarium doped bismuth titanate ceramics
  92. Combinatory in silico investigation for potential inhibitors from Curcuma sahuynhensis Škorničk. & N.S. Lý volatile phytoconstituents against influenza A hemagglutinin, SARS-CoV-2 main protease, and Omicron-variant spike protein
  93. Physical, mechanical, and gamma ray shielding properties of the Bi2O3–BaO–B2O3–ZnO–As2O3–MgO–Na2O glass system
  94. Twofold interpenetrated 3D Cd(ii) complex: Crystal structure and luminescent property
  95. Study on the microstructure and soil quality variation of composite soil with soft rock and sand
  96. Ancient spring waters still emerging and accessible in the Roman Forum area: Chemical–physical and microbiological characterization
  97. Extraction and characterization of type I collagen from scales of Mexican Biajaiba fish
  98. Finding small molecular compounds to decrease trimethylamine oxide levels in atherosclerosis by virtual screening
  99. Prefatory in silico studies and in vitro insecticidal effect of Nigella sativa (L.) essential oil and its active compound (carvacrol) against the Callosobruchus maculatus adults (Fab), a major pest of chickpea
  100. Polymerized methyl imidazole silver bromide (CH3C6H5AgBr)6: Synthesis, crystal structures, and catalytic activity
  101. Using calcined waste fish bones as a green solid catalyst for biodiesel production from date seed oil
  102. Influence of the addition of WO3 on TeO2–Na2O glass systems in view of the feature of mechanical, optical, and photon attenuation
  103. Naringin ameliorates 5-fluorouracil elicited neurotoxicity by curtailing oxidative stress and iNOS/NF-ĸB/caspase-3 pathway
  104. GC-MS profile of extracts of an endophytic fungus Alternaria and evaluation of its anticancer and antibacterial potentialities
  105. Green synthesis, chemical characterization, and antioxidant and anti-colorectal cancer effects of vanadium nanoparticles
  106. Determination of caffeine content in coffee drinks prepared in some coffee shops in the local market in Jeddah City, Saudi Arabia
  107. A new 3D supramolecular Cu(ii) framework: Crystal structure and photocatalytic characteristics
  108. Bordeaux mixture accelerates ripening, delays senescence, and promotes metabolite accumulation in jujube fruit
  109. Important application value of injectable hydrogels loaded with omeprazole Schiff base complex in the treatment of pancreatitis
  110. Color tunable benzothiadiazole-based small molecules for lightening applications
  111. Investigation of structural, dielectric, impedance, and mechanical properties of hydroxyapatite-modified barium titanate composites for biomedical applications
  112. Metal gel particles loaded with epidermal cell growth factor promote skin wound repair mechanism by regulating miRNA
  113. In vitro exploration of Hypsizygus ulmarius (Bull.) mushroom fruiting bodies: Potential antidiabetic and anti-inflammatory agent
  114. Alteration in the molecular structure of the adenine base exposed to gamma irradiation: An ESR study
  115. Comprehensive study of optical, thermal, and gamma-ray shielding properties of Bi2O3–ZnO–PbO–B2O3 glasses
  116. Lewis acids as co-catalysts in Pd-based catalyzed systems of the octene-1 hydroethoxycarbonylation reaction
  117. Synthesis, Hirshfeld surface analysis, thermal, and selective α-glucosidase inhibitory studies of Schiff base transition metal complexes
  118. Protective properties of AgNPs green-synthesized by Abelmoschus esculentus on retinal damage on the virtue of its anti-inflammatory and antioxidant effects in diabetic rat
  119. Effects of green decorated AgNPs on lignin-modified magnetic nanoparticles mediated by Cydonia on cecal ligation and puncture-induced sepsis
  120. Treatment of gastric cancer by green mediated silver nanoparticles using Pistacia atlantica bark aqueous extract
  121. Preparation of newly developed porcelain ceramics containing WO3 nanoparticles for radiation shielding applications
  122. Utilization of computational methods for the identification of new natural inhibitors of human neutrophil elastase in inflammation therapy
  123. Some anticancer agents as effective glutathione S-transferase (GST) inhibitors
  124. Clay-based bricks’ rich illite mineral for gamma-ray shielding applications: An experimental evaluation of the effect of pressure rates on gamma-ray attenuation parameters
  125. Stability kinetics of orevactaene pigments produced by Epicoccum nigrum in solid-state fermentation
  126. Treatment of denture stomatitis using iron nanoparticles green-synthesized by Silybum marianum extract
  127. Characterization and antioxidant potential of white mustard (Brassica hirta) leaf extract and stabilization of sunflower oil
  128. Characteristics of Langmuir monomolecular monolayers formed by the novel oil blends
  129. Strategies for optimizing the single GdSrFeO4 phase synthesis
  130. Oleic acid and linoleic acid nanosomes boost immunity and provoke cell death via the upregulation of beta-defensin-4 at genetic and epigenetic levels
  131. Unraveling the therapeutic potential of Bombax ceiba roots: A comprehensive study of chemical composition, heavy metal content, antibacterial activity, and in silico analysis
  132. Green synthesis of AgNPs using plant extract and investigation of its anti-human colorectal cancer application
  133. The adsorption of naproxen on adsorbents obtained from pepper stalk extract by green synthesis
  134. Treatment of gastric cancer by silver nanoparticles encapsulated by chitosan polymers mediated by Pistacia atlantica extract under ultrasound condition
  135. In vitro protective and anti-inflammatory effects of Capparis spinosa and its flavonoids profile
  136. Wear and corrosion behavior of TiC and WC coatings deposited on high-speed steels by electro-spark deposition
  137. Therapeutic effects of green-formulated gold nanoparticles by Origanum majorana on spinal cord injury in rats
  138. Melanin antibacterial activity of two new strains, SN1 and SN2, of Exophiala phaeomuriformis against five human pathogens
  139. Evaluation of the analgesic and anesthetic properties of silver nanoparticles supported over biodegradable acacia gum-modified magnetic nanoparticles
  140. Review Articles
  141. Role and mechanism of fruit waste polyphenols in diabetes management
  142. A comprehensive review of non-alkaloidal metabolites from the subfamily Amaryllidoideae (Amaryllidaceae)
  143. Discovery of the chemical constituents, structural characteristics, and pharmacological functions of Chinese caterpillar fungus
  144. Eco-friendly green approach of nickel oxide nanoparticles for biomedical applications
  145. Advances in the pharmaceutical research of curcumin for oral administration
  146. Rapid Communication
  147. Determination of the contents of bioactive compounds in St. John’s wort (Hypericum perforatum): Comparison of commercial and wild samples
  148. Retraction
  149. Retraction of “Two mixed-ligand coordination polymers based on 2,5-thiophenedicarboxylic acid and flexible N-donor ligands: The protective effect on periodontitis via reducing the release of IL-1β and TNF-α”
  150. Topical Issue on Phytochemicals, biological and toxicological analysis of aromatic medicinal plants
  151. Anti-plasmodial potential of selected medicinal plants and a compound Atropine isolated from Eucalyptus obliqua
  152. Anthocyanin extract from black rice attenuates chronic inflammation in DSS-induced colitis mouse model by modulating the gut microbiota
  153. Evaluation of antibiofilm and cytotoxicity effect of Rumex vesicarius methanol extract
  154. Chemical compositions of Litsea umbellata and inhibition activities
  155. Green synthesis, characterization of silver nanoparticles using Rhynchosia capitata leaf extract and their biological activities
  156. GC-MS analysis and antibacterial activities of some plants belonging to the genus Euphorbia on selected bacterial isolates
  157. The abrogative effect of propolis on acrylamide-induced toxicity in male albino rats: Histological study
  158. A phytoconstituent 6-aminoflavone ameliorates lipopolysaccharide-induced oxidative stress mediated synapse and memory dysfunction via p-Akt/NF-kB pathway in albino mice
  159. Anti-diabetic potentials of Sorbaria tomentosa Lindl. Rehder: Phytochemistry (GC-MS analysis), α-amylase, α-glucosidase inhibitory, in vivo hypoglycemic, and biochemical analysis
  160. Assessment of cytotoxic and apoptotic activities of the Cassia angustifolia aqueous extract against SW480 colon cancer
  161. Biochemical analysis, antioxidant, and antibacterial efficacy of the bee propolis extract (Hymenoptera: Apis mellifera) against Staphylococcus aureus-induced infection in BALB/c mice: In vitro and in vivo study
  162. Assessment of essential elements and heavy metals in Saudi Arabian rice samples underwent various processing methods
  163. Two new compounds from leaves of Capparis dongvanensis (Sy, B. H. Quang & D. V. Hai) and inhibition activities
  164. Hydroxyquinoline sulfanilamide ameliorates STZ-induced hyperglycemia-mediated amyleoid beta burden and memory impairment in adult mice
  165. An automated reading of semi-quantitative hemagglutination results in microplates: Micro-assay for plant lectins
  166. Inductively coupled plasma mass spectrometry assessment of essential and toxic trace elements in traditional spices consumed by the population of the Middle Eastern region in their recipes
  167. Phytochemical analysis and anticancer activity of the Pithecellobium dulce seed extract in colorectal cancer cells
  168. Impact of climatic disturbances on the chemical compositions and metabolites of Salvia officinalis
  169. Physicochemical characterization, antioxidant and antifungal activities of essential oils of Urginea maritima and Allium sativum
  170. Phytochemical analysis and antifungal efficiency of Origanum majorana extracts against some phytopathogenic fungi causing tomato damping-off diseases
  171. Special Issue on 4th IC3PE
  172. Graphene quantum dots: A comprehensive overview
  173. Studies on the intercalation of calcium–aluminium layered double hydroxide-MCPA and its controlled release mechanism as a potential green herbicide
  174. Synergetic effect of adsorption and photocatalysis by zinc ferrite-anchored graphitic carbon nitride nanosheet for the removal of ciprofloxacin under visible light irradiation
  175. Exploring anticancer activity of the Indonesian guava leaf (Psidium guajava L.) fraction on various human cancer cell lines in an in vitro cell-based approach
  176. The comparison of gold extraction methods from the rock using thiourea and thiosulfate
  177. Special Issue on Marine environmental sciences and significance of the multidisciplinary approaches
  178. Sorption of alkylphenols and estrogens on microplastics in marine conditions
  179. Cytotoxic ketosteroids from the Red Sea soft coral Dendronephthya sp.
  180. Antibacterial and biofilm prevention metabolites from Acanthophora spicifera
  181. Characteristics, source, and health risk assessment of aerosol polyaromatic hydrocarbons in the rural and urban regions of western Saudi Arabia
  182. Special Issue on Advanced Nanomaterials for Energy, Environmental and Biological Applications - Part II
  183. Green synthesis, characterization, and evaluation of antibacterial activities of cobalt nanoparticles produced by marine fungal species Periconia prolifica
  184. Combustion-mediated sol–gel preparation of cobalt-doped ZnO nanohybrids for the degradation of acid red and antibacterial performance
  185. Perinatal supplementation with selenium nanoparticles modified with ascorbic acid improves hepatotoxicity in rat gestational diabetes
  186. Evaluation and chemical characterization of bioactive secondary metabolites from endophytic fungi associated with the ethnomedicinal plant Bergenia ciliata
  187. Enhancing photovoltaic efficiency with SQI-Br and SQI-I sensitizers: A comparative analysis
  188. Nanostructured p-PbS/p-CuO sulfide/oxide bilayer heterojunction as a promising photoelectrode for hydrogen gas generation
Heruntergeladen am 23.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/chem-2022-0277/html
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