Abstract
C26H40AuFNOPS, triclinic, P1 (no. 1), a = 9.62498(7) Å, b = 11.78239(10) Å, c = 12.74349(13) Å, α = 78.7411(8)°, β = 73.5635(8)°, γ = 76.6096(1)°, V = 1335.34(2) Å3, Z = 2, Rgt(F) = 0.0224, wRref(F2) = 0.0557, T = 100 K.
The molecular structures are shown in the Figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Data collection and handling.
Crystal: | Colourless block |
Size: | 0.14 × 0.08 × 0.06 mm |
Wavelength: | Cu Kα radiation (1.54184 Å) |
μ: | 11.8 mm−1 |
Diffractometer, scan mode: | XtaLAB Synergy, ω |
θmax, completeness: | 75.3°, >99% |
N(hkl)meas., N(hkl)unique, Rint: | 66,451, 10,653, 0.030 |
Criterion for Iobs, N(hkl)gt: | Iobs > 2 σ(Iobs), 10,567 |
N(param)ref.: | 638 |
Programs: | CrysAlisPRO [1], SHELX [2], [3], WinGX/ORTEP [4] |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).
Atom | x | y | z | Uiso*/Ueq |
---|---|---|---|---|
Au1 | 0.66877 (2) | 0.94917 (2) | 0.86592 (2) | 0.02693 (7) |
S1 | 0.50132 (16) | 0.88755 (13) | 1.02309 (13) | 0.0296 (3) |
P1 | 0.83683 (16) | 1.00086 (14) | 0.70931 (13) | 0.0283 (3) |
O1 | 0.3991 (5) | 1.1114 (4) | 0.9725 (4) | 0.0328 (9) |
N1 | 0.2734 (6) | 1.0304 (5) | 1.1402 (5) | 0.0337 (11) |
C1 | 0.3771 (6) | 1.0189 (5) | 1.0521 (5) | 0.0267 (11) |
C2a | 0.2638 (7) | 0.9264 (5) | 1.2191 (5) | 0.0309 (13) |
C3a | 0.3376 (8) | 0.9039 (6) | 1.3020 (6) | 0.0366 (14) |
H3a | 0.390074 | 0.959564 | 1.309723 | 0.044* |
C4a | 0.3340 (7) | 0.8001 (6) | 1.3726 (6) | 0.0355 (13) |
F1a | 0.4082 (7) | 0.7793 (5) | 1.4510 (5) | 0.0464 (18) |
C5a | 0.2601 (7) | 0.7160 (6) | 1.3664 (6) | 0.0357 (13) |
H5a | 0.262979 | 0.643259 | 1.414265 | 0.043* |
C6a | 0.1804 (8) | 0.7435 (6) | 1.2856 (6) | 0.0380 (14) |
H6a | 0.124105 | 0.689208 | 1.280712 | 0.046* |
C7a | 0.1806 (7) | 0.8466 (6) | 1.2131 (6) | 0.0357 (14) |
H7a | 0.124676 | 0.863203 | 1.159500 | 0.043* |
C2′b | 0.2638 (7) | 0.9264 (5) | 1.2191 (5) | 0.0309 (13) |
C3′b | 0.3376 (8) | 0.9039 (6) | 1.3020 (6) | 0.0366 (14) |
H3′b | 0.390074 | 0.959564 | 1.309723 | 0.044* |
C4′b | 0.3340 (7) | 0.8001 (6) | 1.3726 (6) | 0.0355 (13) |
H4′b | 0.385450 | 0.785588 | 1.428875 | 0.043* |
C5′b | 0.2601 (7) | 0.7160 (6) | 1.3664 (6) | 0.0357 (13) |
H5′b | 0.262979 | 0.643259 | 1.414265 | 0.043* |
C6′b | 0.1804 (8) | 0.7435 (6) | 1.2856 (6) | 0.0380 (14) |
F1′b | 0.090 (2) | 0.6796 (17) | 1.288 (2) | 0.061 (7) |
C7′b | 0.1806 (7) | 0.8466 (6) | 1.2131 (6) | 0.0357 (14) |
H7′b | 0.124676 | 0.863203 | 1.159500 | 0.043* |
C8 | 0.2945 (8) | 1.2199 (6) | 0.9894 (7) | 0.0449 (17) |
H8A | 0.286604 | 1.239819 | 1.062243 | 0.067* |
H8B | 0.197896 | 1.210239 | 0.985174 | 0.067* |
H8C | 0.328077 | 1.283297 | 0.932088 | 0.067* |
C11 | 0.8548 (7) | 0.9020 (6) | 0.6092 (5) | 0.0334 (13) |
H11 | 0.942359 | 0.914068 | 0.546327 | 0.040* |
C12 | 0.8797 (8) | 0.7734 (6) | 0.6632 (6) | 0.0366 (15) |
H12A | 0.971851 | 0.756233 | 0.688163 | 0.044* |
H12B | 0.797494 | 0.762801 | 0.729406 | 0.044* |
C13 | 0.8902 (9) | 0.6854 (8) | 0.5877 (7) | 0.053 (2) |
H13A | 0.899100 | 0.604906 | 0.629242 | 0.064* |
H13B | 0.979437 | 0.688279 | 0.525817 | 0.064* |
C14 | 0.7545 (10) | 0.7131 (9) | 0.5423 (7) | 0.060 (2) |
H14A | 0.766255 | 0.658701 | 0.488901 | 0.072* |
H14B | 0.666770 | 0.701091 | 0.603405 | 0.072* |
C15 | 0.7316 (12) | 0.8383 (10) | 0.4859 (8) | 0.067 (3) |
H15A | 0.641013 | 0.854794 | 0.459018 | 0.081* |
H15B | 0.815773 | 0.848129 | 0.421007 | 0.081* |
C16 | 0.7179 (8) | 0.9266 (7) | 0.5631 (7) | 0.0465 (18) |
H16A | 0.629053 | 0.921570 | 0.624933 | 0.056* |
H16B | 0.706104 | 1.007456 | 0.522255 | 0.056* |
C21 | 1.0218 (8) | 0.9802 (10) | 0.7340 (7) | 0.059 (2) |
H21 | 1.040992 | 0.892354 | 0.751361 | 0.070* |
C22 | 1.0266 (9) | 1.0070 (14) | 0.8374 (7) | 0.085 (4) |
H22A | 0.959596 | 0.963389 | 0.896914 | 0.102* |
H22B | 0.986571 | 1.092101 | 0.839788 | 0.102* |
C23 | 1.1723 (7) | 0.9804 (6) | 0.8632 (6) | 0.0368 (14) |
H23A | 1.187765 | 0.898385 | 0.900961 | 0.044* |
H23B | 1.169731 | 1.032711 | 0.916089 | 0.044* |
C24 | 1.3027 (9) | 0.9936 (14) | 0.7669 (8) | 0.090 (4) |
H24A | 1.319512 | 1.075207 | 0.756898 | 0.108* |
H24B | 1.390416 | 0.940374 | 0.786406 | 0.108* |
C25 | 1.2948 (8) | 0.9704 (11) | 0.6641 (8) | 0.069 (3) |
H25A | 1.339600 | 0.886446 | 0.658863 | 0.083* |
H25B | 1.358903 | 1.017404 | 0.605670 | 0.083* |
C26 | 1.1483 (7) | 0.9924 (6) | 0.6354 (6) | 0.0346 (13) |
H26A | 1.130782 | 1.072824 | 0.594644 | 0.042* |
H26B | 1.152629 | 0.936003 | 0.585681 | 0.042* |
C31c | 0.7819 (12) | 1.1511 (6) | 0.6493 (6) | 0.078 (4) |
H31c | 0.692503 | 1.140334 | 0.630071 | 0.094* |
C32c | 0.7069 (16) | 1.2391 (9) | 0.7256 (8) | 0.045 (3) |
H32Ac | 0.781506 | 1.264643 | 0.751039 | 0.054* |
H32Bc | 0.640521 | 1.202330 | 0.791258 | 0.054* |
C33c | 0.6154 (9) | 1.3490 (6) | 0.6691 (7) | 0.059 (2) |
H33Ac | 0.536737 | 1.325656 | 0.646679 | 0.071* |
H33Bc | 0.568956 | 1.407820 | 0.720702 | 0.071* |
C34c | 0.7247 (18) | 1.4019 (9) | 0.5659 (10) | 0.051 (4) |
H34Ac | 0.674005 | 1.476726 | 0.531240 | 0.061* |
H34Bc | 0.808261 | 1.418194 | 0.587625 | 0.061* |
C35c | 0.7809 (17) | 1.3114 (9) | 0.4840 (8) | 0.039 (3) |
H35Ac | 0.696466 | 1.295650 | 0.462970 | 0.047* |
H35Bc | 0.847987 | 1.344051 | 0.416272 | 0.047* |
C36c | 0.8626 (6) | 1.1965 (5) | 0.5351 (5) | 0.0377 (14) |
H36Ac | 0.880769 | 1.135758 | 0.486552 | 0.045* |
H36Bc | 0.959726 | 1.208810 | 0.538022 | 0.045* |
C31′c | 0.7819 (12) | 1.1511 (6) | 0.6493 (6) | 0.078 (4) |
H31Cc | 0.834931 | 1.186112 | 0.688446 | 0.094* |
C32′c | 0.6357 (13) | 1.2144 (9) | 0.6981 (11) | 0.042 (3) |
H32Cc | 0.615248 | 1.194065 | 0.779438 | 0.050* |
H32Dc | 0.561946 | 1.187030 | 0.673391 | 0.050* |
C33′c | 0.6154 (9) | 1.3490 (6) | 0.6691 (7) | 0.059 (2) |
H33Cc | 0.674378 | 1.379919 | 0.705459 | 0.071* |
H33Dc | 0.510376 | 1.385177 | 0.695488 | 0.071* |
C34′c | 0.6667 (15) | 1.3806 (12) | 0.5415 (11) | 0.056 (5) |
H34Cc | 0.610642 | 1.346940 | 0.504906 | 0.067* |
H34Dc | 0.648877 | 1.467209 | 0.520648 | 0.067* |
C35′c | 0.8315 (14) | 1.3299 (10) | 0.5047 (13) | 0.051 (5) |
H35Cc | 0.866195 | 1.350320 | 0.423670 | 0.062* |
H35Dc | 0.886851 | 1.365542 | 0.540234 | 0.062* |
C36′c | 0.8626 (6) | 1.1965 (5) | 0.5351 (5) | 0.0377 (14) |
H36Cc | 0.836234 | 1.160547 | 0.481142 | 0.045* |
H36Dc | 0.969863 | 1.169917 | 0.528034 | 0.045* |
Au2 | 0.93580 (2) | 0.39019 (2) | 0.87113 (2) | 0.02961 (7) |
S1A | 1.0989 (2) | 0.32835 (14) | 0.71298 (14) | 0.0380 (4) |
P1A | 0.75511 (17) | 0.42992 (14) | 1.02503 (13) | 0.0305 (3) |
O1A | 1.1869 (5) | 0.5211 (4) | 0.7141 (4) | 0.0331 (9) |
N1A | 1.2592 (7) | 0.4590 (5) | 0.5450 (5) | 0.0341 (12) |
C1A | 1.1908 (7) | 0.4434 (5) | 0.6470 (5) | 0.0282 (12) |
C2Ad | 1.2616 (7) | 0.3788 (6) | 0.4748 (6) | 0.0334 (13) |
C3Ad | 1.1758 (8) | 0.4133 (6) | 0.3987 (6) | 0.0364 (14) |
H3Ad | 1.111909 | 0.487951 | 0.396442 | 0.044* |
C4Ad | 1.1854 (8) | 0.3370 (6) | 0.3265 (6) | 0.0377 (14) |
F1Ad | 1.1005 (7) | 0.3731 (5) | 0.2528 (5) | 0.0481 (19) |
C5Ad | 1.2738 (9) | 0.2282 (6) | 0.3252 (6) | 0.0414 (16) |
H5Ad | 1.276318 | 0.177440 | 0.274924 | 0.050* |
C6Ad | 1.3606 (9) | 0.1950 (7) | 0.4018 (6) | 0.0450 (17) |
H6Ad | 1.424345 | 0.120176 | 0.403097 | 0.054* |
C7Ad | 1.3555 (8) | 0.2692 (6) | 0.4758 (6) | 0.0406 (15) |
H7Ad | 1.415624 | 0.245297 | 0.526810 | 0.049* |
C2A′e | 1.2616 (7) | 0.3788 (6) | 0.4748 (6) | 0.0334 (13) |
C3A′e | 1.1758 (8) | 0.4133 (6) | 0.3987 (6) | 0.0364 (14) |
H3A′e | 1.111909 | 0.487951 | 0.396442 | 0.044* |
C4A′e | 1.1854 (8) | 0.3370 (6) | 0.3265 (6) | 0.0377 (14) |
H4A′e | 1.126932 | 0.361656 | 0.274451 | 0.045* |
C5A′e | 1.2738 (9) | 0.2282 (6) | 0.3252 (6) | 0.0414 (16) |
H5A′e | 1.276318 | 0.177440 | 0.274924 | 0.050* |
C6A′e | 1.3606 (9) | 0.1950 (7) | 0.4018 (6) | 0.0450 (17) |
F1A′e | 1.461 (2) | 0.1001 (15) | 0.4013 (17) | 0.060 (7) |
C7A′e | 1.3555 (8) | 0.2692 (6) | 0.4758 (6) | 0.0406 (15) |
H7A′e | 1.415624 | 0.245297 | 0.526810 | 0.049* |
C8A | 1.2601 (8) | 0.6179 (6) | 0.6603 (6) | 0.0393 (15) |
H8A1 | 1.215334 | 0.661523 | 0.600553 | 0.059* |
H8A2 | 1.364811 | 0.587750 | 0.629733 | 0.059* |
H8A3 | 1.250011 | 0.670397 | 0.714010 | 0.059* |
C11A | 0.5766 (8) | 0.4848 (6) | 0.9849 (7) | 0.0453 (17) |
H11A | 0.567661 | 0.421607 | 0.946347 | 0.054* |
C12A | 0.4395 (8) | 0.4957 (7) | 1.0788 (6) | 0.0453 (16) |
H12C | 0.442299 | 0.554223 | 1.123947 | 0.054* |
H12D | 0.435915 | 0.418881 | 1.126793 | 0.054* |
C13A | 0.3006 (9) | 0.5343 (9) | 1.0338 (9) | 0.068 (3) |
H13C | 0.289714 | 0.469254 | 0.999749 | 0.082* |
H13D | 0.213018 | 0.549094 | 1.096210 | 0.082* |
C14A | 0.3044 (9) | 0.6415 (8) | 0.9511 (7) | 0.0522 (19) |
H14C | 0.297913 | 0.709964 | 0.987772 | 0.063* |
H14D | 0.217902 | 0.656553 | 0.919450 | 0.063* |
C15A | 0.4447 (10) | 0.6291 (9) | 0.8587 (8) | 0.064 (3) |
H15C | 0.441149 | 0.571272 | 0.813044 | 0.077* |
H15D | 0.449357 | 0.705807 | 0.810788 | 0.077* |
C16A | 0.5809 (10) | 0.5901 (10) | 0.9000 (9) | 0.080 (4) |
H16C | 0.666547 | 0.572761 | 0.836849 | 0.096* |
H16D | 0.595746 | 0.655553 | 0.931458 | 0.096* |
C21A | 0.7316 (6) | 0.2951 (5) | 1.1207 (5) | 0.0284 (12) |
H21A | 0.645801 | 0.314476 | 1.184413 | 0.034* |
C22A | 0.8688 (8) | 0.2430 (6) | 1.1654 (7) | 0.0413 (16) |
H22C | 0.956326 | 0.230279 | 1.102558 | 0.050* |
H22D | 0.884072 | 0.300141 | 1.206707 | 0.050* |
C23A | 0.8550 (10) | 0.1269 (7) | 1.2410 (7) | 0.053 (2) |
H23C | 0.947197 | 0.094883 | 1.265164 | 0.064* |
H23D | 0.773277 | 0.140555 | 1.307471 | 0.064* |
C24A | 0.8256 (11) | 0.0383 (7) | 1.1820 (7) | 0.050 (2) |
H24C | 0.910783 | 0.019875 | 1.118833 | 0.060* |
H24D | 0.813699 | −0.035615 | 1.233328 | 0.060* |
C25A | 0.6870 (9) | 0.0867 (6) | 1.1406 (7) | 0.0483 (18) |
H25C | 0.600772 | 0.098952 | 1.204388 | 0.058* |
H25D | 0.671606 | 0.028480 | 1.100441 | 0.058* |
C26A | 0.6981 (7) | 0.2029 (5) | 1.0640 (6) | 0.0353 (14) |
H26C | 0.604065 | 0.234222 | 1.042171 | 0.042* |
H26D | 0.777257 | 0.188824 | 0.996139 | 0.042* |
C31A | 0.7938 (12) | 0.5279 (7) | 1.1046 (6) | 0.063 (3) |
H31B | 0.881580 | 0.478027 | 1.128721 | 0.076* |
C32A | 0.8562 (14) | 0.6321 (9) | 1.0397 (6) | 0.082 (4) |
H32E | 0.782067 | 0.683847 | 1.002715 | 0.099* |
H32F | 0.943530 | 0.604551 | 0.981237 | 0.099* |
C33Af | 0.9011 (8) | 0.7037 (6) | 1.1054 (6) | 0.0467 (17) |
H33Ef | 0.920249 | 0.779115 | 1.059125 | 0.056* |
H33Ff | 0.994234 | 0.660795 | 1.123999 | 0.056* |
C34Af | 0.7850 (13) | 0.7301 (9) | 1.2121 (7) | 0.051 (4) |
H34Ef | 0.829267 | 0.762620 | 1.258268 | 0.061* |
H34Ff | 0.702497 | 0.791205 | 1.193418 | 0.061* |
C35Af | 0.7253 (13) | 0.6248 (9) | 1.2776 (6) | 0.084 (4) |
H35Ef | 0.635432 | 0.652171 | 1.334077 | 0.100* |
H35Ff | 0.798813 | 0.576742 | 1.317128 | 0.100* |
C33Bg | 0.9011 (8) | 0.7037 (6) | 1.1054 (6) | 0.0467 (17) |
H33Gg | 1.009564 | 0.696566 | 1.080979 | 0.056* |
H33Hg | 0.857389 | 0.787460 | 1.086494 | 0.056* |
C34Bg | 0.860 (2) | 0.674 (2) | 1.2274 (9) | 0.023 (8) |
H34Gg | 0.943101 | 0.616247 | 1.249470 | 0.027* |
H34Hg | 0.849355 | 0.745937 | 1.259913 | 0.027* |
C35Bg | 0.7253 (13) | 0.6248 (9) | 1.2776 (6) | 0.084 (4) |
H35Gg | 0.641442 | 0.691474 | 1.291669 | 0.100* |
H35Hg | 0.733944 | 0.579368 | 1.350204 | 0.100* |
C36A | 0.6875 (8) | 0.5468 (6) | 1.2138 (5) | 0.0443 (16) |
H36E | 0.681220 | 0.469174 | 1.259814 | 0.053* |
H36F | 0.588582 | 0.581487 | 1.201151 | 0.053* |
aOccupancy: 0.763(14).
bOccupancy: 0.237(14).
cOccupancy: 0.5.
dOccupancy: 0.741(14).
eOccupancy: 0.259(14).
fOccupancy: 0.77 (3).
gOccupancy: 0.23(3).
Source of material
NaOH (Merck; 0.020 g, 0.50 mmol) in water (5 mL) was added to a suspension of (cyclohexyl)3PAuCl (0.256 g, 0.50 mmol) in acetonitrile (20 mL), followed by the addition of MeOC(=S)N(H)C6H4F-3 [5] (0.093 g, 0.50 mmol) in acetonitrile (20 mL) and stirred for 3 h. The resulting mixture was left for slow evaporation at room temperature, yielding crystals after 2 weeks. Yield: 0.261 g (79%). M. pt.: (Biobase automatic melting point apparatus MP450): 425–426 K. Elemental Analysis for C26H40AuFNOPS (Leco TruSpec Micro CHN Elemental Analyser): C, 47.20; H, 6.09; N, 2.12%. Found: C, 47.04; H, 6.19; N, 1.82%. IR (Bruker Vertex 70v FTIR Spectrophotometer; cm−1): 1575 (s) ν(C=N), 1155 (s) ν(C–O), 1124 (s) ν(C–S). 1H NMR (Bruker Ascend 400 MHz NMR spectrometer with chemical shifts relative to Me4Si in
Experimental details
The C-bound H atoms were geometrically placed (C–H = 0.95–1.00 Å) and refined as riding with Uiso(H) = 1.2–1.5Ueq(C). Disorder was modelled in four regions of the structure. Each 3-fluorophenyl ring was disordered over two co-planar orientations so the C atoms were exactly coincident but, two positions were apparent for the F atoms; the latter were refined independently. At the conclusion of the refinement, the major component of the C2- and C2a-rings had site occupancy factors of 0.763(14) and 0.741(14), respectively. The cyclohexyl‐C31 ring exhibited two, partially overlapping chair conformations. Thus, while the C31, C33 and C36 atoms were coincident, the remaining atoms were statistically disordered (from refinement) and refined independently. The cyclohexyl–C31a ring exhibited two conformations, i.e. chair and boat, depending on the relative orientation of the C34a atom. From independent refinement, the chair conformation was most pronounced with a site occupancy factor of 0.77(3). For the different orientations of the two disordered cyclohexyl rings, soft distance constraints were introduced with 1,1‐C–C and 1,2‐C⋯C separations being 1.53 ± 0.01 and 2.52 ± 0.01 Å, respectively. Finally, the crystal was refined as an inversion twin with the minor component contributing 0.109(8) to the measured crystal.
Comment
The specific interest leading to the synthesis and characterization of the title compound, Cy3Au[SC(OMe)=NC6H4F-3], (I), revolves around the noted biological activity of related species, such as anti-cancer [6] and anti-bacterial [7] potential; Cy = cyclo‐C6H11. The inclusion of a fluoride atom in the molecular structure was motivated by suggestions in the literature that such chemical substitution enhances biological activity [8]. Herein, the synthesis, spectroscopic characterization and X-ray crystal structure determination of (I) are described.
The crystallographic asymmetric unit of (I) comprises two formula units and their molecular structures are shown in the figure (50% displacement ellipsoids; minor disorder components are omitted). Each of the gold(I) atoms in (I) is coordinated by phosphane–P [Au1–P1 = 2.2638(15) Å; Au2–P1a = 2.2674(15) Å] and thiolate‐S [Au1–S1 = 2.2987(15) Å; Au2–S1a = 2.3043(15) Å] atoms with the equivalent bonds being experimentally indistinguishable. The P- and S-donor atoms define an almost linear geometry with the P1–Au1–S1 angle of 177.25(6)° being significantly greater than the P1a–Au2–S1a angle of 170.98(6)°. In each case, the thiolato ligand is orientated so the O atom is directed towards the Au atom with the Au1⋯O1 and Au2⋯O1a separations being 2.993(5) and 3.164(5) Å, respectively. These separations indicate there is no direct correlation between the magnitude of the Au⋯O interaction and the deviation from the ideal linear angle. In some related structures an alternate conformation of the thiolate ligand is observed where the O atom is directed away from the Au atom, an orientation which allows for the formation of an intramolecular Au⋯π(phenyl) contact instead. Calculations (DFT) indicate that Au⋯π interactions are approximately 6 kcal/mol more stable than Au⋯O contacts [9], [10] but, the former are susceptible to steric effects [11]. In this regard, it is noteworthy that none of the known Cy3PAu[SC(OR)=NAr] structures feature intramolecular Au⋯π interactions, an observation that is ascribed to the bulky nature of the cyclohexyl substituents [11]. The major conformational difference in the molecules is apparent in the relative disposition of the fluorophenyl groups with respect to the central CNOS plane, as seen in the dihedral angles formed between the plane through the C1, N1, O1 and S1 atoms and that through the fluorophenyl ring of 87.9(2)° for the Au1-molecule, which is clearly closer to orthogonal compared to the equivalent angle of 75.1(2)° for the Au2-molecule.
In the molecular packing for (I), layers of molecules assemble in the ab-plane with the cyclohexyl and fluorophenyl rings projecting to either side. These stack along the c-axis so the latter rings occupy channels. Yet, there are no close interactions between the rings. A more detailed analysis of the packing is not warranted owing to the disorder in several of the residues.
Funding source: Ministry of Education, Malaysia
Award Identifier / Grant number: TR002-2014A
Funding source: Sunway University
Award Identifier / Grant number: STR-RCTR-RCCM-001-201
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: This research was supported by the Trans‐disciplinary Research Grant Scheme (TR002‐2014A) provided by the Ministry of Education, Malaysia. Sunway University Sdn Bhd is thanked for financial support of this work through Grant No. STR‐RCTR‐RCCM‐001‐2019.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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© 2020 Chien Ing Yeo et al., published by De Gruyter, Berlin/Boston
This work is licensed under the Creative Commons Attribution 4.0 International License.
Artikel in diesem Heft
- Frontmatter
- New Crystal Structures
- The crystal structure of 3-oxo-urs-12-en-28-oic acid, C30H46O3·1/6H2O
- The crystal structure of (3S,12R,20R,24R)-3,12-diacetyl-20,24-epoxy-dammarane-3,12,25–triol–ethyl acetate (4/1), C34H56O6⋅ 0.25(C4H8O2)
- A new polymorph of tetrakis(dimethylammonium) catena-poly[tetrakis(μ2-sulfato-κ2O:O′)dizinc(II)], Zn2C8H32N4O16S4
- Crystal structure of 10-oxysophoridine, C15H22N2O2
- The crystal structure of (5R,8R,9R,10R,12R,13R,14R)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)tetradecahydro-3H-cyclopenta[a]phenanthrene-3,6(2H)-dione, C30H48O4
- Synthesis, crystal structure and optical property of 1,6-bis(p-tolylthio)pyrene, C30H22S2
- The crystal structure of hexakis(2-(pyridin-2-ylamino)pyridin-1-ium) decavanadate(V) dihydrate, C60H64N18O30V10
- Preparation and crystal structure of a cationic olefin polymerization precatalyst: (1,7-bis(2,6–dichlorophenyl)-1,7-di-aza-4-oxo-heptan-1,4,7-triyl)dimethyl zirconium(IV), C18H20Cl4N2OZr
- The crystal structure of fac-tricarbonyl(4,4-dimethyl-2,2-dipyridyl-κ2N,N′)- (pyrazole-κN)rhenium(I) nitrate, C18H16O3N4Re
- Synthesis and crystal structure of hexaaquacopper(II) 2,5-dicarboxyterephthalate, C10H16O14Cu
- The crystal structure of (8R,10R,12R,14R)- 12-hydroxy-16-(5-(2-hydroxypropan-2-yl)-2-methyltetrahydrofuran-2-yl)- 4,4,8,10,14-pentamethyltetradecahydro-3H- cyclopenta[a]phenanthrene-3,6(2H)-dione, C30H48O5
- Structure of the mixed crystal (S)-(6-(bromo/chloro)-2-methoxy-2,6-dihydroquinolin-3-yl)(phenyl)methanol, C17H14Br0.5Cl0.5NO2
- The crystal structure of trans-tetraaqua-bis(4-acetylphenoxyacetato-κ1O)manganese(II), C20H26O12Mn
- Crystal structure of (E)-2-(4-fluoro-3-(trifluoromethyl)benzylidene)-7-methoxy-3,4-dihydronaphthalen-1(2H)-one, C19H14F4O2
- Crystal structure of DL-α-(methylaminomethyl)benzyl alcohol, C9H13NO
- The crystal structure of dipentaerthritol hexanitrate, C10H16N6O19
- Crystal structure of N,N-diphenylformamide, C13H11NO
- Crystal structure of (E)-2-(3,5-bis(trifluoromethyl)benzylidene)-7-methoxy-3,4-dihydronaphthalen- 1(2H)-one, C20H14F6O2
- Crystal structure of ortho-methoxy benzaldehyde, C8H8O2 – a second polymorph and deposition of 3D coordinates
- Crystal structure of catena-poly[diaqua-bis(μ2-2-(4-(2,4,4-trimethylpentan-2-yl)phenoxy)propanoato-κ2O:O')-(2-(4-(2,4,4-trimethylpentan-2-yl)phenoxy)propanoato-κ2O,O')yttrium(III)], C51H79O11Y
- Crystal structure of benzylthiouronium chloride, C8H11ClN2S
- Synthesis and crystal structure of tert-butyl (2′R,3R,3′R,4a′R,9a′S)-1-acetyl-5-chloro-3″-methyl-2,5″,9′-trioxo-1″-phenyl-1″,4a′,5″,9a′-tetrahydro-1′H,3′H,9′H-dispiro[indoline-3,4′-xanthene-2′,4″-pyrazole]-3′-carboxylate, C36H32ClN3O7
- Crystal structure of 2-hydroxy-4-methoxy benzaldehyde, C8H8O3
- Crystal structure of poly[diaqua-(m3-3′,5′-dicarboxy-[1,1′-biphenyl]-3,4-dicarboxylato-K4O,O′:O″:O‴) cadmium(II)], C16H11O10Cd
- Crystal structure of {tetraaqua-bis(1-(4-hydroxy-2-oxotetrahydrofuran-3-yl)-2-((4aS,6R,8aS)-6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylenedecahydronaphthalen-1-yl)ethane-1-sulfonato-k2O,O') calcium(II)}-{triaqua-bis(1-(4-hydroxy-2-oxotetrahydrofuran-3-yl)-2-((4aS,6R,8aS)-6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylenedecahydronaphthalen-1-yl)ethane-1-sulfonato-k2O,O') calcium(II)} – water – acetone (1/1/8/2)
- Synthesis and crystal structure of bis{2-bromo-6-((E)-((4-((E)-1-(methoxy-imino)ethyl)phenyl)imino)methyl)phenolato- κ2N,O}zinc(II)-methanol(1/2), C65H60Br4N8O9Zn2
- Crystal structure of benzenesulphonic acid
- Crystal structure of N-benzyl-N-nicotinoyl-nicotine amide C19H15N3O2
- Crystal structure of poly[aqua(μ3-2,4-diamino-benzenesulfonato-κ4N:N′,O:O′)silver(I)], C12H18O8N4S2Ag2
- Crystal structure of 1,4-bis(methylpyridinium benzene) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S:S)nickel(II), C26H18N6NiS4
- Crystal structure of the Cu(II) complex chlorido-(6-oxo-2-phenyl-1,6-dihydropyrimidine-4-carboxylato-k2N,O)-(phenanthroline-k2N,N')copper(II), C23H15ClCuN4O3
- Crystal structure of phenarsazine chloride acetic acid solvate, C14H13AsClNO2
- Crystal structure of poly[aqua-(μ2-3,3′,4,5′-biphenyl tetracarboxylate- κ3O,O′:O′′) -(μ2-4,4′-bis(pyrid-4-yl)biphenyl-κ2N:N′)zinc(II)], C27H18NO9Zn
- Crystal structure of catena-poly[(μ2-3-amino-benzenedisulfonato-κ2N:O)-bis (3-methyl-isoquinoline-κN)silver(I)], C26H24N3O3SAg
- Crystal structure of 2-((4-Aminophenyl)thio)acetic acid, C8H9NO2S
- Crystal structure of phenarsazine chloride dimethylsulfoxide solvate, C14H15AsClNOS
- Synthesis and crystal structure of 2-azido-N-phenylacetamide, C8H8N4O
- Crystal structure of chlorido{hydridotris[3-phenyl-5-methylpyrazol-1-yl-κN3]borato}copper(II), C30H28BClCuN6
- Crystal structure of benzanthrone – a redetermination for correct molecular geometry and localization of hydrogen atoms
- Crystal structure of 4-bromobenzaldehyde – complete redetermination at 200 K, C7H5BrO
- Crystal structure and spectroscopic properties of chlorido{hydridotris[3-,5-dimethylpyrazol-1-yl-κN3]borato}(3-,5-dimethylpyrazol-1-yl-κN)copper(II), C20H30BClCuN8
- The crystal structure of 4-((2-hydroxynaphthalen-1-yl)(pyrrolidin-1-yl)methyl)benzonitrile, C22H20N2O
- Crystal structure of 4-ethyl-3-phenylisoquinolin-1(2H)-one, C17H15NO
- Crystal structure of (tricyclohexylphosphane-κP)-[(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-k1S]gold(I), C26H40AuFNOPS
- Crystal structure of (3S,8R,10R,12R,14R)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl) hexadecahydro-1H-cyclopenta[a]phenanthren-3-yl acetate, C32H54O4
- The crystal structure of 2-[(S)-1-(naphthalen-1-yl)ethyl]-2,3,7,7a- tetrahydro-3a,6-epoxyisoindol-1(6H)-one, C19H20NO2
- Crystal structure of {hydridotris[3-(t-butyl)-5-isopropylpyrazol-1-yl-κN3]borato}thallium(I), C30H52BN6Tl
- Synthesis and crystal structure of 1-octyl-3-phenylquinoxalin-2(1H)-one, C22H26N2O
- The crystal structure of 2,6-difluorophenol, C6H4F2O
- 4-(9H-Fluoren-9-yl)-4-methylmorpholin-4-ium bromide, C18H20BrNO
- The crystal structure of 2,4-dimethylimidazole monohydrate, C5H10N2O
- The crystal structure of 1,2-dimethylimidazole, C5H8N2
- The crystal structure of 3-ammonio-4-aminobenzoate, C7H8N2O2 – a second polymorph
- The crystal structure of 4-hydroxy-2,5-bis(1-methyl-1H-imidazol-3-ium-2-ylthio)-3,6-dioxocyclohexa-1,4-dienolate chloride monohydrate, C14H15N4O5S2Cl
- The crystal structure of butyrylferrocene, C14H16FeO
- The crystal structure of bi-1,1′-cyclopentane-1,1′-diol, C10H18O2
- The crystal structure of 2-iso-propylimidazole, C6H10N2
- The crystal structure of aqua-tris (1,3-diphenylpropane-1,3-dionato-κ2O,O′)-lanthanum(III), C45H35LaO7
- Crystal structure of (3E,5E)-3,5-bis-4-methoxy-3-(trifluoromethyl)benzylidene)-1-methylpiperidin-4-one, C24H21F6NO3
- The crystal structure of 3,5-dichloro-6-diazo-2,4-dinitrocyclohexa-2,4-dien-1-one, C6Cl2N4O5
- Crystal structure of carbonyl(2-methylquinolin-8-olato-κ2N,O)(triphenylarsine-κAs)rhodium(I), C29H23AsNO2Rh
- Crystal structure of (1aS,1a1S,2S)-4a-butoxy-1a,1a1,2,4a,5,6-hexahydro-1H-cyclobuta[de]naphthalen-2-yl-4-nitrobenzoate, C22H25NO5
- Crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-k2O,O′)(triphenylarsine-κAs)rhodium(I), C24H19AsNO3Rh
- Crystal structure of catena-poly[triqua-bis(μ2-4-carboxy-2-(1H-tetrazol-1-yl)-1H-imidazole-5-carboxylato-k3N,O:O′)barium(II)] tetrahydrate, C14H14BaN12O15
- Crystal structure of (E)-3′,6′-bis(ethylamino)-2-((quinoxalin-2-ylmethylene)amino)spiro[isoindoline-1,9′-xanthen]-3-one, C35H32N6O2
- Crystal structure of diaqua-bis(μ2-5-chloro-salicylato-κ3O,O′:O′)-bis(5-chloro-salicylato-κ2O,O′)-bis(1,10-phenanthroline-κ2N,N′) dilead(II) – water (1/2), C52H36C14N4O14Pb2·2(H2O)
- Crystal structure of (E)-2-(4-ethoxycarbonyl-3,5-dimethyl-2-(pyrrole-2-ylmethyleneamino)-3′,6′-dihydroxylspiro[isoindoline-1,9′-xanthen]-3-one-methanol (1/1), C31H29N3O7
- The crystal structure of 5H-dibenzo[b,e]azepine-6,11-dione, C14H9NO2
- Crystal structure of (E)-2-(4-fluoro-2-(trifluoromethyl)benzylidene)-7-methoxy-3,4-dihydronaphthalen-1(2H)-one, C19H14F4O2
- The crystal structure of N-(2-methoxy-4,5-bis[phenylselanyl]phenyl)picolinamide, C25H20N2O2Se2
- The crystal structure of (E)-2-(5-bromo-2-hydroxybenzylidene)-N-phenylhydrazine-1- carboxamide monohydrate, C14H14BrN3O3
- Crystal structure of fac-tricarbonyl-(nitrato-k1O)-bis(pyridine-κN)-rhenium, C13H10O6N3Re
- Crystal structure of (E)-2-(((1H-pyrrol-2-yl)methylene)amino)-3′,6′-dihydroxyspiro[isoindoline-1,9′-xanthen]-3-one — methanol (1/2), C27H25N3O6
- The crystal structure of 4-amino-N′-(4-aminobenzoyl)benzohydrazide monohydrate, C14H16N4O3
- Crystal structure of bis(amino(carbamothioylamino)methaniminium) 5-hydroxyisophthalate monohydrate, C12H20N8O6S2
- The crystal structure of 2-(chloromethyl)pyridine, C6H6ClN
- The crystal structure of 1-bromo-4-iodo-benzene, C6H4BrI
- The crystal structure of 2,6-dimethyl-4-nitro-phenol, C8H9NO3
- The crystal structure of 3-chloropropionic acid, C3H5ClO2
- The crystal structure of 2-(2-methoxyphenyl)acetic acid, C9H10O3
Artikel in diesem Heft
- Frontmatter
- New Crystal Structures
- The crystal structure of 3-oxo-urs-12-en-28-oic acid, C30H46O3·1/6H2O
- The crystal structure of (3S,12R,20R,24R)-3,12-diacetyl-20,24-epoxy-dammarane-3,12,25–triol–ethyl acetate (4/1), C34H56O6⋅ 0.25(C4H8O2)
- A new polymorph of tetrakis(dimethylammonium) catena-poly[tetrakis(μ2-sulfato-κ2O:O′)dizinc(II)], Zn2C8H32N4O16S4
- Crystal structure of 10-oxysophoridine, C15H22N2O2
- The crystal structure of (5R,8R,9R,10R,12R,13R,14R)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)tetradecahydro-3H-cyclopenta[a]phenanthrene-3,6(2H)-dione, C30H48O4
- Synthesis, crystal structure and optical property of 1,6-bis(p-tolylthio)pyrene, C30H22S2
- The crystal structure of hexakis(2-(pyridin-2-ylamino)pyridin-1-ium) decavanadate(V) dihydrate, C60H64N18O30V10
- Preparation and crystal structure of a cationic olefin polymerization precatalyst: (1,7-bis(2,6–dichlorophenyl)-1,7-di-aza-4-oxo-heptan-1,4,7-triyl)dimethyl zirconium(IV), C18H20Cl4N2OZr
- The crystal structure of fac-tricarbonyl(4,4-dimethyl-2,2-dipyridyl-κ2N,N′)- (pyrazole-κN)rhenium(I) nitrate, C18H16O3N4Re
- Synthesis and crystal structure of hexaaquacopper(II) 2,5-dicarboxyterephthalate, C10H16O14Cu
- The crystal structure of (8R,10R,12R,14R)- 12-hydroxy-16-(5-(2-hydroxypropan-2-yl)-2-methyltetrahydrofuran-2-yl)- 4,4,8,10,14-pentamethyltetradecahydro-3H- cyclopenta[a]phenanthrene-3,6(2H)-dione, C30H48O5
- Structure of the mixed crystal (S)-(6-(bromo/chloro)-2-methoxy-2,6-dihydroquinolin-3-yl)(phenyl)methanol, C17H14Br0.5Cl0.5NO2
- The crystal structure of trans-tetraaqua-bis(4-acetylphenoxyacetato-κ1O)manganese(II), C20H26O12Mn
- Crystal structure of (E)-2-(4-fluoro-3-(trifluoromethyl)benzylidene)-7-methoxy-3,4-dihydronaphthalen-1(2H)-one, C19H14F4O2
- Crystal structure of DL-α-(methylaminomethyl)benzyl alcohol, C9H13NO
- The crystal structure of dipentaerthritol hexanitrate, C10H16N6O19
- Crystal structure of N,N-diphenylformamide, C13H11NO
- Crystal structure of (E)-2-(3,5-bis(trifluoromethyl)benzylidene)-7-methoxy-3,4-dihydronaphthalen- 1(2H)-one, C20H14F6O2
- Crystal structure of ortho-methoxy benzaldehyde, C8H8O2 – a second polymorph and deposition of 3D coordinates
- Crystal structure of catena-poly[diaqua-bis(μ2-2-(4-(2,4,4-trimethylpentan-2-yl)phenoxy)propanoato-κ2O:O')-(2-(4-(2,4,4-trimethylpentan-2-yl)phenoxy)propanoato-κ2O,O')yttrium(III)], C51H79O11Y
- Crystal structure of benzylthiouronium chloride, C8H11ClN2S
- Synthesis and crystal structure of tert-butyl (2′R,3R,3′R,4a′R,9a′S)-1-acetyl-5-chloro-3″-methyl-2,5″,9′-trioxo-1″-phenyl-1″,4a′,5″,9a′-tetrahydro-1′H,3′H,9′H-dispiro[indoline-3,4′-xanthene-2′,4″-pyrazole]-3′-carboxylate, C36H32ClN3O7
- Crystal structure of 2-hydroxy-4-methoxy benzaldehyde, C8H8O3
- Crystal structure of poly[diaqua-(m3-3′,5′-dicarboxy-[1,1′-biphenyl]-3,4-dicarboxylato-K4O,O′:O″:O‴) cadmium(II)], C16H11O10Cd
- Crystal structure of {tetraaqua-bis(1-(4-hydroxy-2-oxotetrahydrofuran-3-yl)-2-((4aS,6R,8aS)-6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylenedecahydronaphthalen-1-yl)ethane-1-sulfonato-k2O,O') calcium(II)}-{triaqua-bis(1-(4-hydroxy-2-oxotetrahydrofuran-3-yl)-2-((4aS,6R,8aS)-6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylenedecahydronaphthalen-1-yl)ethane-1-sulfonato-k2O,O') calcium(II)} – water – acetone (1/1/8/2)
- Synthesis and crystal structure of bis{2-bromo-6-((E)-((4-((E)-1-(methoxy-imino)ethyl)phenyl)imino)methyl)phenolato- κ2N,O}zinc(II)-methanol(1/2), C65H60Br4N8O9Zn2
- Crystal structure of benzenesulphonic acid
- Crystal structure of N-benzyl-N-nicotinoyl-nicotine amide C19H15N3O2
- Crystal structure of poly[aqua(μ3-2,4-diamino-benzenesulfonato-κ4N:N′,O:O′)silver(I)], C12H18O8N4S2Ag2
- Crystal structure of 1,4-bis(methylpyridinium benzene) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S:S)nickel(II), C26H18N6NiS4
- Crystal structure of the Cu(II) complex chlorido-(6-oxo-2-phenyl-1,6-dihydropyrimidine-4-carboxylato-k2N,O)-(phenanthroline-k2N,N')copper(II), C23H15ClCuN4O3
- Crystal structure of phenarsazine chloride acetic acid solvate, C14H13AsClNO2
- Crystal structure of poly[aqua-(μ2-3,3′,4,5′-biphenyl tetracarboxylate- κ3O,O′:O′′) -(μ2-4,4′-bis(pyrid-4-yl)biphenyl-κ2N:N′)zinc(II)], C27H18NO9Zn
- Crystal structure of catena-poly[(μ2-3-amino-benzenedisulfonato-κ2N:O)-bis (3-methyl-isoquinoline-κN)silver(I)], C26H24N3O3SAg
- Crystal structure of 2-((4-Aminophenyl)thio)acetic acid, C8H9NO2S
- Crystal structure of phenarsazine chloride dimethylsulfoxide solvate, C14H15AsClNOS
- Synthesis and crystal structure of 2-azido-N-phenylacetamide, C8H8N4O
- Crystal structure of chlorido{hydridotris[3-phenyl-5-methylpyrazol-1-yl-κN3]borato}copper(II), C30H28BClCuN6
- Crystal structure of benzanthrone – a redetermination for correct molecular geometry and localization of hydrogen atoms
- Crystal structure of 4-bromobenzaldehyde – complete redetermination at 200 K, C7H5BrO
- Crystal structure and spectroscopic properties of chlorido{hydridotris[3-,5-dimethylpyrazol-1-yl-κN3]borato}(3-,5-dimethylpyrazol-1-yl-κN)copper(II), C20H30BClCuN8
- The crystal structure of 4-((2-hydroxynaphthalen-1-yl)(pyrrolidin-1-yl)methyl)benzonitrile, C22H20N2O
- Crystal structure of 4-ethyl-3-phenylisoquinolin-1(2H)-one, C17H15NO
- Crystal structure of (tricyclohexylphosphane-κP)-[(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-k1S]gold(I), C26H40AuFNOPS
- Crystal structure of (3S,8R,10R,12R,14R)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl) hexadecahydro-1H-cyclopenta[a]phenanthren-3-yl acetate, C32H54O4
- The crystal structure of 2-[(S)-1-(naphthalen-1-yl)ethyl]-2,3,7,7a- tetrahydro-3a,6-epoxyisoindol-1(6H)-one, C19H20NO2
- Crystal structure of {hydridotris[3-(t-butyl)-5-isopropylpyrazol-1-yl-κN3]borato}thallium(I), C30H52BN6Tl
- Synthesis and crystal structure of 1-octyl-3-phenylquinoxalin-2(1H)-one, C22H26N2O
- The crystal structure of 2,6-difluorophenol, C6H4F2O
- 4-(9H-Fluoren-9-yl)-4-methylmorpholin-4-ium bromide, C18H20BrNO
- The crystal structure of 2,4-dimethylimidazole monohydrate, C5H10N2O
- The crystal structure of 1,2-dimethylimidazole, C5H8N2
- The crystal structure of 3-ammonio-4-aminobenzoate, C7H8N2O2 – a second polymorph
- The crystal structure of 4-hydroxy-2,5-bis(1-methyl-1H-imidazol-3-ium-2-ylthio)-3,6-dioxocyclohexa-1,4-dienolate chloride monohydrate, C14H15N4O5S2Cl
- The crystal structure of butyrylferrocene, C14H16FeO
- The crystal structure of bi-1,1′-cyclopentane-1,1′-diol, C10H18O2
- The crystal structure of 2-iso-propylimidazole, C6H10N2
- The crystal structure of aqua-tris (1,3-diphenylpropane-1,3-dionato-κ2O,O′)-lanthanum(III), C45H35LaO7
- Crystal structure of (3E,5E)-3,5-bis-4-methoxy-3-(trifluoromethyl)benzylidene)-1-methylpiperidin-4-one, C24H21F6NO3
- The crystal structure of 3,5-dichloro-6-diazo-2,4-dinitrocyclohexa-2,4-dien-1-one, C6Cl2N4O5
- Crystal structure of carbonyl(2-methylquinolin-8-olato-κ2N,O)(triphenylarsine-κAs)rhodium(I), C29H23AsNO2Rh
- Crystal structure of (1aS,1a1S,2S)-4a-butoxy-1a,1a1,2,4a,5,6-hexahydro-1H-cyclobuta[de]naphthalen-2-yl-4-nitrobenzoate, C22H25NO5
- Crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-k2O,O′)(triphenylarsine-κAs)rhodium(I), C24H19AsNO3Rh
- Crystal structure of catena-poly[triqua-bis(μ2-4-carboxy-2-(1H-tetrazol-1-yl)-1H-imidazole-5-carboxylato-k3N,O:O′)barium(II)] tetrahydrate, C14H14BaN12O15
- Crystal structure of (E)-3′,6′-bis(ethylamino)-2-((quinoxalin-2-ylmethylene)amino)spiro[isoindoline-1,9′-xanthen]-3-one, C35H32N6O2
- Crystal structure of diaqua-bis(μ2-5-chloro-salicylato-κ3O,O′:O′)-bis(5-chloro-salicylato-κ2O,O′)-bis(1,10-phenanthroline-κ2N,N′) dilead(II) – water (1/2), C52H36C14N4O14Pb2·2(H2O)
- Crystal structure of (E)-2-(4-ethoxycarbonyl-3,5-dimethyl-2-(pyrrole-2-ylmethyleneamino)-3′,6′-dihydroxylspiro[isoindoline-1,9′-xanthen]-3-one-methanol (1/1), C31H29N3O7
- The crystal structure of 5H-dibenzo[b,e]azepine-6,11-dione, C14H9NO2
- Crystal structure of (E)-2-(4-fluoro-2-(trifluoromethyl)benzylidene)-7-methoxy-3,4-dihydronaphthalen-1(2H)-one, C19H14F4O2
- The crystal structure of N-(2-methoxy-4,5-bis[phenylselanyl]phenyl)picolinamide, C25H20N2O2Se2
- The crystal structure of (E)-2-(5-bromo-2-hydroxybenzylidene)-N-phenylhydrazine-1- carboxamide monohydrate, C14H14BrN3O3
- Crystal structure of fac-tricarbonyl-(nitrato-k1O)-bis(pyridine-κN)-rhenium, C13H10O6N3Re
- Crystal structure of (E)-2-(((1H-pyrrol-2-yl)methylene)amino)-3′,6′-dihydroxyspiro[isoindoline-1,9′-xanthen]-3-one — methanol (1/2), C27H25N3O6
- The crystal structure of 4-amino-N′-(4-aminobenzoyl)benzohydrazide monohydrate, C14H16N4O3
- Crystal structure of bis(amino(carbamothioylamino)methaniminium) 5-hydroxyisophthalate monohydrate, C12H20N8O6S2
- The crystal structure of 2-(chloromethyl)pyridine, C6H6ClN
- The crystal structure of 1-bromo-4-iodo-benzene, C6H4BrI
- The crystal structure of 2,6-dimethyl-4-nitro-phenol, C8H9NO3
- The crystal structure of 3-chloropropionic acid, C3H5ClO2
- The crystal structure of 2-(2-methoxyphenyl)acetic acid, C9H10O3