Home Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
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Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S

  • Zheng-Jun Liu ORCID logo EMAIL logo , Xiao-Miao Chen ORCID logo , Qiang Wu , Wu-Chao Zhou , Xu-Min Jiao and Juan Tan
Published/Copyright: October 23, 2024
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 239 Issue 6

Abstract

C32H30ClCoN5O8S, monoclinic, P21/c (no. 14), a = 14.5008(9) Å, b = 13.6648(9) Å, c = 17.9741(12) Å, β = 113.086(2)°, V = 3276.4(4) Å3, Z = 4, R gt (F) = 0.0620, wR ref (F 2) = 0.1696, T = 293(2) K.

CCDC no.: 1846941

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Green block
Size: 0.27 × 0.15 × 0.14 mm
Wavelength:

μ:		 Mo Kα radiation (0.71073 Å)

0.73 mm−1
Diffractometer, scan mode:

θ max, completeness:		 Bruker APEX-II, φ and ω

27.5°, 99 %
N(hkl)measured, N(hkl)unique, R int: 51,167, 7520, 0.057
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 5061
N(param) refined: 452
Programs: Bruker, 1 Olex2, 2 SHELX 3 , 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.3588 (3) 0.2079 (3) 0.4876 (2) 0.0530 (10)
H1 0.347188 0.273553 0.473215 0.064*
C2 0.4032 (4) 0.1843 (4) 0.5698 (3) 0.0656 (12)
H2 0.421054 0.232823 0.609226 0.079*
C3 0.4193 (4) 0.0881 (4) 0.5902 (3) 0.0697 (12)
H3 0.447468 0.070681 0.644581 0.084*
C4 0.3501 (3) 0.0468 (3) 0.4509 (2) 0.0447 (8)
C5 0.3949 (3) 0.0163 (3) 0.5324 (3) 0.0557 (10)
C6 0.4122 (4) −0.0868 (4) 0.5484 (4) 0.0767 (16)
H6 0.440360 −0.108344 0.601663 0.092*
C7 0.3887 (4) −0.1526 (4) 0.4883 (4) 0.0828 (18)
H7 0.401893 −0.218381 0.501209 0.099*
C8 0.3244 (3) −0.0242 (3) 0.3873 (2) 0.0484 (9)
C9 0.3441 (3) −0.1247 (3) 0.4053 (3) 0.0628 (13)
C10 0.3201 (4) −0.1894 (3) 0.3400 (4) 0.0759 (16)
H10 0.333129 −0.255861 0.349340 0.091*
C11 0.2778 (4) −0.1552 (3) 0.2631 (4) 0.0759 (15)
H11 0.261148 −0.197875 0.219481 0.091*
C12 0.2597 (3) −0.0558 (3) 0.2506 (3) 0.0608 (11)
H12 0.230649 −0.033218 0.197573 0.073*
C13 0.0867 (3) 0.1718 (3) 0.3572 (2) 0.0466 (9)
H13 0.134923 0.180679 0.409218 0.056*
C14 −0.0128 (3) 0.1661 (3) 0.3473 (3) 0.0528 (10)
H14 −0.030089 0.171396 0.391822 0.063*
C15 −0.0846 (3) 0.1526 (3) 0.2727 (3) 0.0521 (10)
H15 −0.151519 0.147618 0.265511 0.063*
C16 −0.0576 (3) 0.1462 (2) 0.2058 (2) 0.0435 (8)
C17 −0.1279 (3) 0.1344 (3) 0.1246 (3) 0.0571 (11)
H17 −0.195831 0.129700 0.114107 0.068*
C18 −0.0978 (3) 0.1300 (3) 0.0629 (3) 0.0615 (12)
H18 −0.145469 0.123127 0.010372 0.074*
C19 0.0055 (3) 0.1358 (3) 0.0762 (2) 0.0499 (9)
C20 0.0776 (3) 0.1473 (2) 0.1556 (2) 0.0366 (7)
C21 0.0448 (2) 0.1526 (2) 0.2215 (2) 0.0346 (7)
C22 0.0426 (4) 0.1304 (4) 0.0150 (3) 0.0660 (12)
H22 −0.001519 0.122160 −0.038534 0.079*
C23 0.1419 (4) 0.1371 (4) 0.0335 (3) 0.0679 (13)
H23 0.166230 0.133373 −0.007216 0.082*
C24 0.2083 (3) 0.1498 (3) 0.1140 (2) 0.0535 (10)
H24 0.276507 0.155173 0.125850 0.064*
C25 −0.0442 (3) 0.3980 (3) 0.0829 (2) 0.0487 (9)
C26 −0.0548 (3) 0.3946 (3) 0.1556 (3) 0.0504 (10)
H26 −0.118299 0.391451 0.156755 0.060*
C27 0.0293 (3) 0.3961 (3) 0.2268 (2) 0.0443 (9)
H27 0.022621 0.393241 0.276169 0.053*
C28 0.1331 (3) 0.4070 (3) 0.1518 (2) 0.0441 (9)
H28 0.196465 0.411718 0.150636 0.053*
C29 0.0493 (3) 0.4053 (3) 0.0803 (2) 0.0509 (10)
H29 0.055847 0.409052 0.030915 0.061*
C30 0.1236 (2) 0.4017 (2) 0.2248 (2) 0.0353 (7)
C31 0.4471 (3) 0.2491 (3) 0.2928 (2) 0.0446 (9)
C32 0.3967 (3) 0.3382 (3) 0.3093 (4) 0.0691 (14)
H32A 0.438877 0.365609 0.361362 0.083*
H32B 0.388943 0.387339 0.268271 0.083*
Cl1 −0.14930 (8) 0.39317 (10) −0.00707 (8) 0.0761 (4)
Co1 0.26804 (3) 0.16814 (3) 0.30081 (3) 0.03432 (15)
N1 0.2816 (2) 0.0092 (2) 0.3101 (2) 0.0474 (8)
N2 0.3327 (2) 0.1422 (2) 0.42965 (18) 0.0448 (7)
N3 0.1173 (2) 0.1655 (2) 0.29682 (16) 0.0361 (6)
N4 0.1766 (2) 0.1544 (2) 0.17391 (17) 0.0399 (7)
N5 0.2996 (2) 0.3148 (2) 0.30930 (17) 0.0371 (6)
O1 0.28102 (19) 0.49502 (18) 0.31874 (16) 0.0514 (7)
O2 0.1963 (2) 0.3847 (2) 0.37872 (15) 0.0559 (7)
O3 0.40152 (19) 0.16917 (19) 0.28193 (17) 0.0481 (6)
O4 0.5322 (2) 0.2591 (2) 0.2929 (2) 0.0702 (9)
O5 0.3105 (3) 0.6232 (3) 0.1980 (3) 0.0983 (12)
H5A 0.347048 0.666098 0.188612 0.147*
H5B 0.258118 0.613758 0.155492 0.147*
O6 0.3351 (4) 0.8969 (3) 0.0997 (3) 0.1259 (17)
H6A 0.376116 0.937335 0.131724 0.189*
H6B 0.357366 0.877645 0.064874 0.189*
O7Aa 0.4063 (6) 0.5759 (5) 0.4692 (5) 0.108 (3)
H7AAa 0.371085 0.584915 0.496824 0.163*
H7ABa 0.454505 0.537395 0.494454 0.163*
O7Bb 0.4614 (12) 0.5853 (10) 0.4370 (9) 0.146 (6)
H7BAb 0.507441 0.607708 0.423668 0.219*
H7BBb 0.425621 0.632318 0.441668 0.219*
O8Aa 0.5302 (6) 0.5306 (7) 0.2911 (6) 0.118 (3)
H8AAa 0.579273 0.567926 0.316685 0.176*
H8ABa 0.477073 0.564506 0.270094 0.176*
O8Bb 0.5483 (10) 0.5755 (10) 0.3449 (10) 0.128 (5)
H8BAb 0.523108 0.617531 0.366272 0.192*
H8BBb 0.565908 0.525171 0.375012 0.192*
S2 0.23263 (7) 0.40128 (6) 0.31590 (5) 0.0367 (2)

  1. aOccupancy: 0.597 (10), bOccupancy: 0.403 (10).

1 Source of material

In a 250 ml round-bottom flask, a solution was prepared by dissolving glycine (7.51 g, 100 mmol), sodium hydroxide (8.00 g, 200 mmol), and 100 ml of deionized water with thorough stirring to ensure complete solubilization. Subsequently, 4-chlorobenzenesulfonyl chloride (21.11 g, 100 mmol) was introduced into the mixture, which was then stirred continuously at ambient temperature for a duration of 10 h to facilitate the sulfonylation reaction. Upon completion of the reaction, the pH of the reaction mixture was carefully adjusted to 1 using a 6 mol/L hydrochloric acid solution, prompting the precipitation of a white solid. The precipitate was isolated via filtration, rinsed with deionized water to remove any residual impurities, and then dried to yield the desired product, ((4-chlorophenyl)sulfonyl)glycine.

A mixture of ((4-chlorophenyl)sulfonyl)glycine (124.8 mg, 0.5 mmol), Co(CH3COO)2⋅4H2O (124.5 mg, 0.5 mmol), and 1,10-phenanthroline (180.2 mg, 1.0 mmol) was dissolved in a 50 ml volume of a 50 % methanolic solution at ambient temperature. The pH of the resulting solution was meticulously adjusted to neutral (pH 7) using a 2 mol/L sodium hydroxide solution. Subsequently, the reaction mixture was subjected to thermal processing at 80 °C for 12 h within a Teflon-lined autoclave and then filtered. The filtrate was then allowed to undergo slow evaporation at room temperature, leading to the crystallization of colorless, block crystals of the title compound over a period of two weeks.

2 Experimental details

Hydrogen atoms were added using riding models. Their U iso values were set to 1.2U eq of the parent atoms. The structure was solved with the ShelXT 3 structure solution program and refined with the ShelXL. 4

3 Comment

The acquisition of single crystals for peptide metal complexes often presents a formidable challenge, prompting the exploration of ligands with structural analogies to peptides to elucidate the intricate interactions between these biomolecules and metal ions. 5 , 6 , 7 Sulfonamide moieties are renowned for their diverse biological activities. 8 , 9 , 10 When amino acids are shielded by sulfonamide groups, they exhibit the versatility to function as monodentate ligands through the oxygen of the carboxyl group, or as bidentate ligands by engaging both the carboxyl oxygen and the amino nitrogen. Intriguingly, the –SO2- group has been observed to partake in coordination as well. 11 , 12 , 13 Our research group has successfully synthesized a range of ((4-chlorophenyl)sulfonyl)-glycine complexes, 14 , 15 , 16 , 17 and this study contributes to our ongoing investigation.

In this paper, the synthesis and crystal structure of a new cobalt(II) complex with ((4-chlorophenyl)sulfonyl)-glycine and 1,10-phenanthroline were reported. Single crystal X-ray structure analysis reveals that the title complex crystallizes in the monoclinic system with space group P21/c. The asymmetric unit is composed of an independent Co(II) ion, one ((4-chlorophenyl)sulfonyl)glycine ligand, two 1,10-phenanthroline ligands, and four lattice water molecules. The crystallographically unique Co(II) ion of the title complex is six-coordinated by four N atoms (N1, N2, N3, N4) from two 1,10-phenanthroline groups, one O atom (O3) and one N atom (N5) from ((4-chlorophenyl)sulfonyl)glycine group, giving rise to a octahedron geometry. Co–N bond lengths fall in the range 2.0443(18)–2.185(2) Å, and Co–O bond length is 2.0872(16) Å. The bond lengths observed fall within the expected range and align closely with those documented for analogous complexes in prior studies. 16 , 17 The extended 3D supramolecular network is formed through hydrogen bonds of lattice water molecules.

Corresponding author: Zheng-Jun Liu, Key Laboratory of Agricultural Resources and Environment in High Education Institute of Guizhou Province Anshun University, Anshun 561000, P.R. China, E-mail:

Funding source: Doctoral Fund of Anshun University

Award Identifier / Grant number: asxybsjj202314

Funding source: Key Laboratory of Agricultural Resources and Environment in High Education Institute of Guizhou Province

Award Identifier / Grant number: Qianjiaoji[2023]025

Funding source: Porous Materials and Green Catalysis Innovation Team in High Education Institute of Guizhou Province

Award Identifier / Grant number: Qianjiaoji[2023]086

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Competing interests: The authors declare no conflicts of interest regarding this article.

  3. Research funding: Doctoral Fund of Anshun University (asxybsjj202314), Key Laboratory of Agricultural Resources and Environment in High Education Institute of Guizhou Province (Qianjiaoji[2023]025), and Porous Materials and Green Catalysis Innovation Team in High Education Institute of Guizhou Province (Qianjiaoji[2023]086).

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Received: 2024-08-09
Accepted: 2024-10-10
Published Online: 2024-10-23
Published in Print: 2024-12-17

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
https://doi.org/10.1515/ncrs-2024-0333
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 3-nitrophenol-2,1,3-benzoselenadiazole (1/1), C12H9N3O3Se
  4. Crystal structure of diaqua-(hydroxido)-{μ-[2-(hydroxy)-5-[(4-nitrophenyl)diazenyl]benzoato]}-{2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzoato}-(1,10-phenanthroline)-diterbium hydrate, C38H27.4N8O12.2Tb
  5. Crystal structure of poly[bis(μ3-3-fluoro-4-(1H-1,2,4-triazol-1-yl)benzoato-κ3 O:O′:N)cadmium(II)] – dimethylformamide (1/1), C21H17CdF2N7O5
  6. The crystal structure of 2-amino-N-(pyridin-2-yl)benzamide, C12H11N3O
  7. The crystal structure of 2,3-di(pyridin-2-yl)-2,3-dihydroquinazolin-4(1H)-one, C18H14N4O
  8. Crystal structure of 2-chloro-4-fluorobenzyl (R)-2-(6-methoxynaphthalen-2-yl)propanoate, C21H18ClFO3
  9. Crystal structure of [1-(4-carboxyphenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylic acid]-(methylsulfinyl)methane, C15H16N2O6S
  10. The crystal structure of 2-ethyl-1,1-dimethyl-1H-benzo[e]indole, C16H17N
  11. The crystal structure of (Z)-5-amino-N ′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  12. The crystal structure of 2,2,5-trimethyl-3-(4-(4-(5-phenyl-4,5-dihydroisoxazol-3-yl)thiazol-2-yl)phenyl)imidazolidin-4-one, C24H24N4O2S
  13. The crystal structure of tetrakis(μ2-acetato-κ2 O:O′)-bis[(4′-phenyl-4,2′:6′,4″-terpyridine-κ1 N)dicopper(II)], C25H21CuN3O4
  14. Crystal structure of poly(3-thiophenecarboxylato-κ 3 O,O′:O′)-(methanol-κO)cadmium(II), C11H10O5S2Cd
  15. The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
  16. The crystal structure of 1-(2-carboxyethyl)-1H-imidazole 3-oxide
  17. Crystal structure of 1,1′,1″-(nitrilotris(ethane-2,1-diyl))tris(3-(4-(((E)-pyridin-2-ylmethylene)amino)phenyl)urea), C45H47N13O4
  18. Crystal structure of a (E)-4-bromo-N-(4-(diethylamino)-2-hydroxybenzylidene) benzenaminium acetate ─ 4-bromoaniline (1/1)
  19. Crystal structure of 2,2′-(iminobis(methylene))bis(benzimidazolium) bis(p-toluenesulfonate), C30H31N5O6S2
  20. The crystal structure of alogliptinium meta-chlorobenzoate
  21. Crystal structure of 4-bromobenzyl 2-(6-methoxy-naphthalen-2-yl)propanoate, C21H19BrO3
  22. The hydrated double salt structure of (E)-4-(2-benzylidenehydrazine-1-carbonyl)pyridin-1-ium cation with 2-hydroxybenzoate and benzoate anions
  23. Crystal structure of (R)(R)-5-chloro-3-((S,1E,3E)-3,5-dimethyl-hepta-1,3-dien-1-yl)-7-methyl-6,8-dioxo-2,6,7,8-tetrahydroisoquinolin-7-yl acetate, C21H24ClNO4
  24. The crystal structure of bis(3-oxo-1,3-diphenylprop-1-en-1-olato-κ 2 O:O′)-bis(1,4-dioxane-κ 1 O)nickel(II), C38H38O8Ni
  25. Crystal structure of poly[aqua-(pyridine-3-carboxylato-κ1 N)(pyridine-3-carboxylato-κ2 O,O′) cadmium(II)] dihydrate, C12H14N2O7Cd
  26. The crystal structure of 4-(4-phenyl-5-(((1-(2,4,6-tribromophenyl)-1H-1,2,3-triazol-4-yl)methyl)thio)-4H-1,2,4-triazol-3-yl)pyridine, C22H14Br3N7S
  27. The crystal structure of N-benzylquinoline-2-carbothioamide, C17H14N2S
  28. Crystal structure of bis(3-isopropylphenyl)-4,4′-bipyridinium dichloride dihydrate, C28H30N2⋅2Cl⋅2H2O
  29. The crystal structure of ethyl 2-amino-4-(cyanophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C19H18N2O4
  30. Crystal structure of (4R,10S)-6-hydroxy-7-isopropyl-4,10-dimethyl-1,2,3,5-hexahydro-6,10-epoxyazulen-9-one, C15H22O3
  31. The crystal structure of (E)-(2-(2-hydroxy-3-methoxybenzylidene)aminophenyl)arsonic acid, C14H14AsNO5
  32. The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U
  33. The crystal structure of the co-crystal isonicotinamide · terephthalic acid, C8H6O4·2(C6H6N2O)
  34. The crystal structure of (E)-1-phenyl-3-(p-tolylthio)but-2-en-1-one, C17H16OS
  35. The crystal structure of 4,5-bis((Z)-chloro(hydroxyimino)methyl)-1H-imidazol-3-ium chloride monohydrate
  36. The crystal structure of 1,2-bis(4-(dimethylamino)phenyl)ethane-1,2-dione. C18H20N2O2
  37. Crystal structure of 2-chloro-4-fluorobenzyl 2-acetoxybenzoate, C16H12ClFO4
  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
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