Startseite The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
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The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn

  • Miao Lin , Meng-Qin Wu , Wei-Kun Ou , Qin Wan und Wei-Wei Fu ORCID logo EMAIL logo
Veröffentlicht/Copyright: 4. September 2024
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 239 Heft 6

Abstract

C44H34Cl2N6O2Zn, triclinic, P 1 ‾ (no. 2), a = 10.875(9) Å, b = 11.755(9) Å, c = 16.471(13) Å, α = 105.924(14)°, β = 97.552(13)°, γ = 104.507(13)°, V = 1,914(3) Å3, Z = 2, R gt(F) = 0.0455, wR ref(F 2) = 0.1154, T = 296 K.

CCDC no.: 2366201

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Yellow block
Size: 0.27 × 0.23 × 0.19 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.83 mm−1
Diffractometer, scan mode: Bruker SMART APEX2, φ and ω
θ max, completeness: 25.0°, 98 %
N(hkl)measured, N(hkl)unique, R int: 10,500, 6,597, 0.034
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 4,139
N(param)refined: 498
Programs: Bruker 1 , SHELX 2 , 3 , Olex2 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
Zn1 0.79541(4) 0.32271(4) 0.29359(3) 0.04299(16)
Cl1 0.89579(10) 0.52398(10) 0.35097(7) 0.0619(3)
Cl2 0.91750(11) 0.20267(11) 0.24525(7) 0.0665(3)
O1 0.6831(3) 0.5574(3) −0.42977(18) 0.0739(10)
O2 0.8372(3) −0.0820(3) 0.95210(17) 0.0628(8)
N1 0.6693(3) 0.3011(3) 0.18164(18) 0.0426(8)
N2 0.3398(3) 0.3278(3) −0.04697(18) 0.0389(8)
N3 −0.1240(3) 0.3359(4) −0.0958(3) 0.0749(12)
N4 0.7115(3) 0.2641(3) 0.38399(19) 0.0442(8)
N5 0.4303(3) 0.1412(3) 0.58074(19) 0.0397(7)
N6 −0.0257(3) 0.1083(3) 0.6217(3) 0.0642(10)
C1 0.5410(3) 0.2845(4) 0.1672(2) 0.0475(10)
H1 0.496336 0.267950 0.209144 0.057*
C2 0.4723(3) 0.2910(3) 0.0929(2) 0.0429(10)
H2 0.382907 0.277492 0.085104 0.052*
C3 0.5361(3) 0.3174(3) 0.0300(2) 0.0344(8)
C4 0.6678(3) 0.3297(4) 0.0432(2) 0.0462(10)
H4 0.714029 0.343124 0.001304 0.055*
C5 0.7295(3) 0.3220(4) 0.1190(2) 0.0488(11)
H5 0.818321 0.331845 0.127225 0.059*
C6 0.4656(3) 0.3363(3) −0.0471(2) 0.0344(8)
C7 0.5266(3) 0.3655(3) −0.1103(2) 0.0364(9)
H7 0.612935 0.367429 −0.108476 0.044*
C8 0.4579(3) 0.3922(3) −0.1770(2) 0.0343(8)
C9 0.3274(3) 0.3818(3) −0.1773(2) 0.0368(9)
H9 0.277140 0.396649 −0.221169 0.044*
C10 0.2719(3) 0.3496(3) −0.1127(2) 0.0365(9)
C11 0.1336(3) 0.3425(3) −0.1085(2) 0.0405(9)
C12 0.0867(4) 0.3277(5) −0.0376(3) 0.0739(15)
H12 0.139852 0.319265 0.008073 0.089*
C13 −0.0398(4) 0.3254(6) −0.0345(3) 0.095(2)
H13 −0.068499 0.315802 0.014628 0.114*
C14 −0.0783(4) 0.3466(4) −0.1644(3) 0.0650(13)
H14 −0.134522 0.352352 −0.209781 0.078*
C15 0.0470(4) 0.3499(4) −0.1743(3) 0.0536(11)
H15 0.072316 0.357105 −0.224902 0.064*
C16 0.5206(3) 0.4328(3) −0.2433(2) 0.0356(9)
C17 0.4471(3) 0.4314(3) −0.3195(2) 0.0407(9)
H17 0.356870 0.401959 −0.329698 0.049*
C18 0.5038(3) 0.4721(4) −0.3798(2) 0.0445(10)
H18 0.452002 0.468449 −0.430711 0.053*
C19 0.6377(4) 0.5188(4) −0.3656(2) 0.0487(11)
C20 0.7130(4) 0.5229(4) −0.2903(2) 0.0612(13)
H20 0.803090 0.554334 −0.279718 0.073*
C21 0.6540(3) 0.4800(4) −0.2303(2) 0.0534(11)
H21 0.705846 0.483036 −0.179717 0.064*
C22 0.8188(4) 0.5960(6) −0.4242(3) 0.104(2)
H22A 0.835559 0.612227 −0.476390 0.156*
H22B 0.854603 0.531886 −0.416643 0.156*
H22C 0.858409 0.670234 −0.375822 0.156*
C23 0.7809(4) 0.2293(5) 0.4396(3) 0.0725(15)
H23 0.865123 0.230599 0.433975 0.087*
C24 0.7364(4) 0.1914(4) 0.5050(3) 0.0646(14)
H24 0.790440 0.168712 0.542217 0.077*
C25 0.6117(3) 0.1870(3) 0.5157(2) 0.0377(9)
C26 0.5402(4) 0.2242(4) 0.4587(2) 0.0475(10)
H26 0.455754 0.223988 0.463075 0.057*
C27 0.5918(4) 0.2618(4) 0.3955(2) 0.0501(11)
H27 0.540543 0.287110 0.358438 0.060*
C28 0.5550(3) 0.1440(3) 0.5832(2) 0.0367(9)
C29 0.6243(3) 0.1082(3) 0.6439(2) 0.0402(9)
H29 0.710192 0.110242 0.643140 0.048*
C30 0.5655(3) 0.0696(3) 0.7054(2) 0.0388(9)
C31 0.4365(3) 0.0696(3) 0.7034(2) 0.0402(9)
H31 0.393718 0.045933 0.744158 0.048*
C32 0.3723(3) 0.1052(3) 0.6402(2) 0.0384(9)
C33 0.2347(3) 0.1056(3) 0.6348(2) 0.0424(10)
C34 0.1590(4) 0.0659(4) 0.6878(3) 0.0676(14)
H34 0.193089 0.036077 0.729632 0.081*
C35 0.0324(4) 0.0700(5) 0.6796(3) 0.0769(15)
H35 −0.015125 0.043852 0.717611 0.092*
C36 0.0483(4) 0.1473(4) 0.5711(3) 0.0665(13)
H36 0.011444 0.176680 0.529991 0.080*
C37 0.1757(4) 0.1478(4) 0.5748(3) 0.0571(12)
H37 0.221677 0.176454 0.536982 0.069*
C38 0.6346(3) 0.0281(3) 0.7705(2) 0.0404(9)
C39 0.7213(3) −0.0379(4) 0.7511(3) 0.0493(10)
H39 0.736318 −0.058278 0.695373 0.059*
C40 0.7865(4) −0.0745(4) 0.8124(2) 0.0526(11)
H40 0.842837 −0.120791 0.797483 0.063*
C41 0.7678(4) −0.0421(4) 0.8956(3) 0.0472(10)
C42 0.6818(4) 0.0241(4) 0.9173(3) 0.0537(11)
H42 0.668181 0.045208 0.973355 0.064*
C43 0.6159(4) 0.0587(4) 0.8548(2) 0.0511(11)
H43 0.558054 0.103331 0.869526 0.061*
C44 0.8401(5) −0.0316(5) 1.0421(3) 0.0764(15)
H44A 0.755147 −0.061289 1.052811 0.115*
H44B 0.865848 0.057328 1.058664 0.115*
H44C 0.901249 −0.056885 1.075231 0.115*

1 Source of materials

The reagents were purchased from standard commercial sources and used without further purification. A mixture of ZnCl2 (0.014 g, 0.10 mmol), meophtpy (0.034 g, 0.10 mmol) was dispersed in C2H5OH (7 mL) solution and ammonia (25 %) was added dropwise until a clear colorless solution was obtained. The resultant solution was allowed slowly to evaporate under room temperature for two weeks to give light yellow crystals which were isolated by filtration and washed by deionized water and dried in air.

2 Experimental details

The structure was solved by Direct Methods with the SHELXT-2018 program. All H-atoms from C atoms were positioned with idealized geometry and refined isotropically (U iso(H) = 1.2U eq(C)) using a riding model with C–H = 0.93 and 0.97 Å.

3 Comment

In the past few years, metal-organic frameworks (MOFs) have been extensively studied for their diversity of structures, topologies, properties and potential application in different fields like gas sorption, fluorescence sensing, magnetism and photodegradation, etc. 5 , 6 , 7 , 8 The successful synthesis of MOFs mainly relies on the careful selection of metal ions and organic links. In this text, Zn(II) ion is accepted for its success in the assembly of fluorescence complexes 9 , 10 and 4,2′:6′,4″-terpyridine ligand is accepted as it contains two terminal pyridine N atoms which would behave as bridges among metal ions. 11 , 12 A Zn(II) complex was obtained with 4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine (meophtpy) as ligand and its structure has been determined. Just as it still possesses unsaturated coordination groups, the title complex may also behave as metalloligand, which are better alternative to direct the assembly of large molecular arrays and 1D, 2D, 3D coordination polymers and networks. 13 , 14

As shown in the figure, the asymmetric unit contains one Zn(II) ion, two meophtpy ligands, and two Cl− anions. Each Zn(II) ion is coordinated by two pyridyl N atoms from two meophtpy ligands, Zn1–N1 = 2.036(3) Å, Zn1–N4 = 2.062(3) Å and two chlorides, Zn1–Cl1 = 2.2340(18) Å, Zn1–Cl2 = 2.211(2) Å to furnish a distorted tetrahedral geometry. In this complex, the Cl–Zn–Cl bond angle is 116.55(7)°, the N–Zn–N bond angle is 115.56(14)° and the N–Zn–Cl bond angles range from 102.32(12)° to 108.65(11)°. All these bond lengths and angles are similar with other complexes with ZnN2Cl2 coordination environment. 12 , 13 , 14 , 15 , 16 , 17

In the crystal structure, five C atoms, C4, C15, C18, C22 and C24 act as hydrogen donors, contributing hydrogen atoms H4, H15, H18, H22C and H12 to N3, Cl1, O1, Cl2, and N6 to form non-classic hydrogen bonds between molecules. In addition, there are two kinds of offset face to face π–π stacking interactions with center to center distances of 3.641(4) Å and 3.896(4) Å, between pyridine rings. The discrete complexes were further extended into 3D network mainly by the hydrogen bonding interaction and the π–π stacking interactions.

Corresponding author: Wei-Wei Fu, Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Organometallic New Materials, Department of Hunan Province, Hunan Provincial Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, College of Chemistry and Materials Science, Nanyue College, Hengyang Normal University, Hengyang, Hunan 421008, P.R. China, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

  3. Research funding: This work was supported by the 2023 Innovation and Entrepreneurship Training Program for Nanyue College of Hengyang Normal University Students (No. NYD202319), Hunan Provincial Training Program of Innovation and Entrepreneurship for Undergraduates (No. S202412659002) and the Scientific Research Project of Hengyang Normal University (2023HSKFJJ013).

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Received: 2024-06-27
Accepted: 2024-08-23
Published Online: 2024-09-04
Published in Print: 2024-12-17

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

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  2. New Crystal Structures
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  5. Crystal structure of poly[bis(μ3-3-fluoro-4-(1H-1,2,4-triazol-1-yl)benzoato-κ3 O:O′:N)cadmium(II)] – dimethylformamide (1/1), C21H17CdF2N7O5
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  9. Crystal structure of [1-(4-carboxyphenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylic acid]-(methylsulfinyl)methane, C15H16N2O6S
  10. The crystal structure of 2-ethyl-1,1-dimethyl-1H-benzo[e]indole, C16H17N
  11. The crystal structure of (Z)-5-amino-N ′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
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  15. The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
  16. The crystal structure of 1-(2-carboxyethyl)-1H-imidazole 3-oxide
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  18. Crystal structure of a (E)-4-bromo-N-(4-(diethylamino)-2-hydroxybenzylidene) benzenaminium acetate ─ 4-bromoaniline (1/1)
  19. Crystal structure of 2,2′-(iminobis(methylene))bis(benzimidazolium) bis(p-toluenesulfonate), C30H31N5O6S2
  20. The crystal structure of alogliptinium meta-chlorobenzoate
  21. Crystal structure of 4-bromobenzyl 2-(6-methoxy-naphthalen-2-yl)propanoate, C21H19BrO3
  22. The hydrated double salt structure of (E)-4-(2-benzylidenehydrazine-1-carbonyl)pyridin-1-ium cation with 2-hydroxybenzoate and benzoate anions
  23. Crystal structure of (R)(R)-5-chloro-3-((S,1E,3E)-3,5-dimethyl-hepta-1,3-dien-1-yl)-7-methyl-6,8-dioxo-2,6,7,8-tetrahydroisoquinolin-7-yl acetate, C21H24ClNO4
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  27. The crystal structure of N-benzylquinoline-2-carbothioamide, C17H14N2S
  28. Crystal structure of bis(3-isopropylphenyl)-4,4′-bipyridinium dichloride dihydrate, C28H30N2⋅2Cl⋅2H2O
  29. The crystal structure of ethyl 2-amino-4-(cyanophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C19H18N2O4
  30. Crystal structure of (4R,10S)-6-hydroxy-7-isopropyl-4,10-dimethyl-1,2,3,5-hexahydro-6,10-epoxyazulen-9-one, C15H22O3
  31. The crystal structure of (E)-(2-(2-hydroxy-3-methoxybenzylidene)aminophenyl)arsonic acid, C14H14AsNO5
  32. The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U
  33. The crystal structure of the co-crystal isonicotinamide · terephthalic acid, C8H6O4·2(C6H6N2O)
  34. The crystal structure of (E)-1-phenyl-3-(p-tolylthio)but-2-en-1-one, C17H16OS
  35. The crystal structure of 4,5-bis((Z)-chloro(hydroxyimino)methyl)-1H-imidazol-3-ium chloride monohydrate
  36. The crystal structure of 1,2-bis(4-(dimethylamino)phenyl)ethane-1,2-dione. C18H20N2O2
  37. Crystal structure of 2-chloro-4-fluorobenzyl 2-acetoxybenzoate, C16H12ClFO4
  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
https://doi.org/10.1515/ncrs-2024-0272
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 3-nitrophenol-2,1,3-benzoselenadiazole (1/1), C12H9N3O3Se
  4. Crystal structure of diaqua-(hydroxido)-{μ-[2-(hydroxy)-5-[(4-nitrophenyl)diazenyl]benzoato]}-{2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzoato}-(1,10-phenanthroline)-diterbium hydrate, C38H27.4N8O12.2Tb
  5. Crystal structure of poly[bis(μ3-3-fluoro-4-(1H-1,2,4-triazol-1-yl)benzoato-κ3 O:O′:N)cadmium(II)] – dimethylformamide (1/1), C21H17CdF2N7O5
  6. The crystal structure of 2-amino-N-(pyridin-2-yl)benzamide, C12H11N3O
  7. The crystal structure of 2,3-di(pyridin-2-yl)-2,3-dihydroquinazolin-4(1H)-one, C18H14N4O
  8. Crystal structure of 2-chloro-4-fluorobenzyl (R)-2-(6-methoxynaphthalen-2-yl)propanoate, C21H18ClFO3
  9. Crystal structure of [1-(4-carboxyphenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylic acid]-(methylsulfinyl)methane, C15H16N2O6S
  10. The crystal structure of 2-ethyl-1,1-dimethyl-1H-benzo[e]indole, C16H17N
  11. The crystal structure of (Z)-5-amino-N ′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  12. The crystal structure of 2,2,5-trimethyl-3-(4-(4-(5-phenyl-4,5-dihydroisoxazol-3-yl)thiazol-2-yl)phenyl)imidazolidin-4-one, C24H24N4O2S
  13. The crystal structure of tetrakis(μ2-acetato-κ2 O:O′)-bis[(4′-phenyl-4,2′:6′,4″-terpyridine-κ1 N)dicopper(II)], C25H21CuN3O4
  14. Crystal structure of poly(3-thiophenecarboxylato-κ 3 O,O′:O′)-(methanol-κO)cadmium(II), C11H10O5S2Cd
  15. The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
  16. The crystal structure of 1-(2-carboxyethyl)-1H-imidazole 3-oxide
  17. Crystal structure of 1,1′,1″-(nitrilotris(ethane-2,1-diyl))tris(3-(4-(((E)-pyridin-2-ylmethylene)amino)phenyl)urea), C45H47N13O4
  18. Crystal structure of a (E)-4-bromo-N-(4-(diethylamino)-2-hydroxybenzylidene) benzenaminium acetate ─ 4-bromoaniline (1/1)
  19. Crystal structure of 2,2′-(iminobis(methylene))bis(benzimidazolium) bis(p-toluenesulfonate), C30H31N5O6S2
  20. The crystal structure of alogliptinium meta-chlorobenzoate
  21. Crystal structure of 4-bromobenzyl 2-(6-methoxy-naphthalen-2-yl)propanoate, C21H19BrO3
  22. The hydrated double salt structure of (E)-4-(2-benzylidenehydrazine-1-carbonyl)pyridin-1-ium cation with 2-hydroxybenzoate and benzoate anions
  23. Crystal structure of (R)(R)-5-chloro-3-((S,1E,3E)-3,5-dimethyl-hepta-1,3-dien-1-yl)-7-methyl-6,8-dioxo-2,6,7,8-tetrahydroisoquinolin-7-yl acetate, C21H24ClNO4
  24. The crystal structure of bis(3-oxo-1,3-diphenylprop-1-en-1-olato-κ 2 O:O′)-bis(1,4-dioxane-κ 1 O)nickel(II), C38H38O8Ni
  25. Crystal structure of poly[aqua-(pyridine-3-carboxylato-κ1 N)(pyridine-3-carboxylato-κ2 O,O′) cadmium(II)] dihydrate, C12H14N2O7Cd
  26. The crystal structure of 4-(4-phenyl-5-(((1-(2,4,6-tribromophenyl)-1H-1,2,3-triazol-4-yl)methyl)thio)-4H-1,2,4-triazol-3-yl)pyridine, C22H14Br3N7S
  27. The crystal structure of N-benzylquinoline-2-carbothioamide, C17H14N2S
  28. Crystal structure of bis(3-isopropylphenyl)-4,4′-bipyridinium dichloride dihydrate, C28H30N2⋅2Cl⋅2H2O
  29. The crystal structure of ethyl 2-amino-4-(cyanophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C19H18N2O4
  30. Crystal structure of (4R,10S)-6-hydroxy-7-isopropyl-4,10-dimethyl-1,2,3,5-hexahydro-6,10-epoxyazulen-9-one, C15H22O3
  31. The crystal structure of (E)-(2-(2-hydroxy-3-methoxybenzylidene)aminophenyl)arsonic acid, C14H14AsNO5
  32. The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U
  33. The crystal structure of the co-crystal isonicotinamide · terephthalic acid, C8H6O4·2(C6H6N2O)
  34. The crystal structure of (E)-1-phenyl-3-(p-tolylthio)but-2-en-1-one, C17H16OS
  35. The crystal structure of 4,5-bis((Z)-chloro(hydroxyimino)methyl)-1H-imidazol-3-ium chloride monohydrate
  36. The crystal structure of 1,2-bis(4-(dimethylamino)phenyl)ethane-1,2-dione. C18H20N2O2
  37. Crystal structure of 2-chloro-4-fluorobenzyl 2-acetoxybenzoate, C16H12ClFO4
  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
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Heruntergeladen am 6.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2024-0272/html
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