Startseite Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
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Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2

  • Mohammed A. Elmakki ORCID logo EMAIL logo , Orbett T. Alexander ORCID logo , Johan A. Venter und Andreas Roodt
Veröffentlicht/Copyright: 25. Oktober 2024
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 239 Heft 6

Abstract

C68H56As3NO5Rh2, triclinic, P 1 ‾ (no. 2), a = 14.048(4) Å, b = 14.569(4) Å, c = 17.942(5) Å, α = 92.273(9)°, β = 112.728(9)°, γ = 115.910(9)°, V = 2948.7(13) Å3, Z = 2, R gt(F) = 0.0378, wR ref(F 2) = 0.0990, T = 100 K.

CCDC no.: 2389961

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Yellow cuboid
Size: 0.37 × 0.27 × 0.07 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 2.28 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω
θ max, completeness: 28.3°, >99 %
N(hkl)measured, N(hkl)unique, R int: 51,426, 14,547, 0.069
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 11,878
N(param)refined: 714
Programs: SHELX 1 , Bruker 2 , Olex2 3 , Diamond 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
Rh1 0.79134 (2) 0.29834 (2) 0.22951 (2) 0.01971 (6)
Rh2 0.42314 (2) 0.12525 (2) 0.27869 (2) 0.01904 (6)
As1 0.71298 (2) 0.39805 (2) 0.15301 (2) 0.02027 (7)
As2 0.49169 (2) 0.28291 (2) 0.37905 (2) 0.01931 (7)
As3 0.33916 (2) −0.04416 (2) 0.18659 (2) 0.01924 (7)
O1 0.9990 (2) 0.3980 (2) 0.19712 (18) 0.0471 (7)
O2 0.65112 (17) 0.23173 (16) 0.26069 (12) 0.0232 (4)
O3 0.58455 (16) 0.12646 (16) 0.33612 (12) 0.0223 (4)
O4 0.1902 (2) 0.1131 (2) 0.21100 (17) 0.0518 (8)
N1 0.84275 (19) 0.21163 (19) 0.30648 (14) 0.0205 (5)
C1 0.6632 (2) 0.1763 (2) 0.31286 (17) 0.0212 (6)
C2 0.7725 (2) 0.1708 (2) 0.34603 (18) 0.0218 (6)
C3 0.8194 (3) 0.1290 (2) 0.40890 (19) 0.0253 (6)
H3 0.787137 0.097484 0.444932 0.030*
C4 0.9248 (2) 0.1427 (2) 0.40863 (18) 0.0240 (6)
C5 1.0115 (3) 0.1171 (2) 0.45641 (19) 0.0287 (7)
H5 1.006320 0.085424 0.500967 0.034*
C6 1.1040 (3) 0.1388 (3) 0.4375 (2) 0.0306 (7)
H6 1.163540 0.122383 0.469543 0.037*
C7 1.1110 (3) 0.1851 (2) 0.3713 (2) 0.0303 (7)
H7 1.174292 0.197075 0.358341 0.036*
C8 1.0293 (2) 0.2137 (2) 0.32442 (19) 0.0253 (6)
H8 1.036318 0.246394 0.280616 0.030*
C9 0.9357 (2) 0.1930 (2) 0.34368 (17) 0.0213 (6)
C10 0.2808 (3) 0.1173 (2) 0.2359 (2) 0.0308 (7)
C11 0.9166 (3) 0.3578 (3) 0.2086 (2) 0.0290 (7)
C12 0.7400 (3) 0.5181 (2) 0.22645 (18) 0.0241 (6)
C13 0.8495 (3) 0.5752 (3) 0.2960 (2) 0.0365 (8)
H13 0.908498 0.555022 0.306694 0.044*
C14 0.8726 (4) 0.6618 (3) 0.3498 (2) 0.0449 (9)
H14 0.947925 0.701613 0.396792 0.054*
C15 0.7865 (4) 0.6901 (3) 0.3353 (2) 0.0476 (10)
H15 0.802236 0.748914 0.372369 0.057*
C16 0.6776 (4) 0.6328 (3) 0.2667 (2) 0.0419 (9)
H16 0.618339 0.652333 0.256550 0.050*
C17 0.6542 (3) 0.5469 (3) 0.2126 (2) 0.0308 (7)
H17 0.578721 0.507497 0.165719 0.037*
C18 0.7784 (2) 0.4639 (2) 0.07975 (18) 0.0231 (6)
C19 0.8257 (3) 0.5703 (2) 0.0857 (2) 0.0274 (7)
H19 0.825069 0.614220 0.125797 0.033*
C20 0.8747 (3) 0.6138 (3) 0.0329 (2) 0.0340 (8)
H20 0.907139 0.687378 0.037254 0.041*
C21 0.8765 (3) 0.5513 (3) −0.0252 (2) 0.0390 (8)
H21 0.909904 0.581354 −0.061088 0.047*
C22 0.8295 (4) 0.4446 (3) −0.0312 (2) 0.0484 (10)
H22 0.831107 0.401158 −0.071177 0.058*
C23 0.7799 (3) 0.4000 (3) 0.0207 (2) 0.0398 (8)
H23 0.747019 0.326360 0.016063 0.048*
C24 0.5437 (2) 0.3325 (2) 0.08146 (17) 0.0218 (6)
C25 0.4995 (3) 0.3683 (3) 0.01218 (19) 0.0304 (7)
H25 0.551845 0.422708 −0.002825 0.036*
C26 0.3771 (3) 0.3232 (3) −0.0348 (2) 0.0362 (8)
H26 0.346314 0.346630 −0.082478 0.043*
C27 0.3007 (3) 0.2455 (3) −0.01308 (19) 0.0323 (7)
H27 0.217579 0.216243 −0.045165 0.039*
C28 0.3443 (3) 0.2098 (3) 0.05510 (19) 0.0294 (7)
H28 0.291298 0.155352 0.069613 0.035*
C29 0.4663 (3) 0.2535 (3) 0.10298 (18) 0.0269 (7)
H29 0.496262 0.229094 0.150302 0.032*
C30 0.4131 (2) 0.3624 (2) 0.33181 (18) 0.0215 (6)
C31 0.4105 (3) 0.3836 (3) 0.2565 (2) 0.0318 (7)
H31 0.451373 0.364171 0.233229 0.038*
C32 0.3484 (3) 0.4333 (3) 0.2150 (2) 0.0389 (8)
H32 0.347747 0.448319 0.163832 0.047*
C33 0.2882 (3) 0.4606 (3) 0.2477 (2) 0.0379 (8)
H33 0.245143 0.493853 0.218876 0.045*
C34 0.2899 (3) 0.4400 (3) 0.3223 (2) 0.0345 (8)
H34 0.248039 0.458948 0.344819 0.041*
C35 0.3533 (3) 0.3910 (2) 0.36498 (19) 0.0269 (6)
H35 0.355167 0.377429 0.416752 0.032*
C36 0.6570 (2) 0.3884 (2) 0.44000 (17) 0.0210 (6)
C37 0.6932 (3) 0.4952 (2) 0.45390 (19) 0.0269 (6)
H37 0.636812 0.518203 0.430565 0.032*
C38 0.8130 (3) 0.5690 (3) 0.5024 (2) 0.0336 (7)
H38 0.837583 0.642204 0.512250 0.040*
C39 0.8954 (3) 0.5363 (3) 0.5358 (2) 0.0352 (8)
H39 0.976539 0.586442 0.569097 0.042*
C40 0.8589 (3) 0.4299 (3) 0.52046 (19) 0.0332 (7)
H40 0.915910 0.407193 0.542400 0.040*
C41 0.7400 (3) 0.3553 (3) 0.47335 (18) 0.0262 (6)
H41 0.715788 0.282225 0.464066 0.031*
C42 0.4533 (2) 0.2430 (2) 0.46968 (18) 0.0244 (6)
C43 0.4834 (3) 0.3162 (3) 0.5377 (2) 0.0357 (8)
H43 0.520937 0.389220 0.539648 0.043*
C44 0.4592 (3) 0.2839 (4) 0.6030 (2) 0.0527 (11)
H44 0.477753 0.334305 0.648871 0.063*
C45 0.4073 (3) 0.1768 (4) 0.6009 (2) 0.0563 (13)
H45 0.391054 0.154000 0.645587 0.068*
C46 0.3800 (3) 0.1049 (4) 0.5344 (3) 0.0503 (11)
H46 0.345797 0.032169 0.533497 0.060*
C47 0.4017 (3) 0.1369 (3) 0.4684 (2) 0.0348 (8)
H47 0.381238 0.086077 0.422034 0.042*
C48 0.2750 (2) −0.1581 (2) 0.23482 (18) 0.0233 (6)
C49 0.3366 (3) −0.1442 (3) 0.3205 (2) 0.0316 (7)
H49 0.405663 −0.078875 0.353550 0.038*
C50 0.2974 (3) −0.2251 (3) 0.3572 (2) 0.0406 (9)
H50 0.339251 −0.215627 0.415511 0.049*
C51 0.1964 (3) −0.3208 (3) 0.3085 (2) 0.0419 (9)
H51 0.169781 −0.376892 0.333527 0.050*
C52 0.1349 (3) −0.3343 (3) 0.2241 (2) 0.0393 (8)
H52 0.065383 −0.399428 0.191193 0.047*
C53 0.1741 (3) −0.2530 (3) 0.1869 (2) 0.0289 (7)
H53 0.131633 −0.262605 0.128648 0.035*
C54 0.2119 (2) −0.0858 (2) 0.07508 (17) 0.0217 (6)
C55 0.2249 (3) −0.1097 (3) 0.00531 (19) 0.0300 (7)
H55 0.296509 −0.107404 0.012130 0.036*
C56 0.1344 (3) −0.1370 (3) −0.0746 (2) 0.0383 (8)
H56 0.144368 −0.152713 −0.122074 0.046*
C57 0.0300 (3) −0.1411 (3) −0.0847 (2) 0.0385 (8)
H57 −0.032126 −0.159820 −0.139078 0.046*
C58 0.0163 (3) −0.1181 (3) −0.0156 (2) 0.0329 (7)
H58 −0.055649 −0.120977 −0.022696 0.039*
C59 0.1063 (3) −0.0907 (2) 0.06419 (19) 0.0271 (7)
H59 0.095627 −0.075365 0.111416 0.033*
C60 0.4499 (2) −0.0702 (3) 0.16362 (18) 0.0271 (7)
C61 0.5205 (3) 0.0054 (3) 0.1352 (2) 0.0371 (8)
H61 0.516667 0.068638 0.131129 0.044*
C62 0.5962 (3) −0.0118 (4) 0.1130 (2) 0.0477 (10)
H62 0.645535 0.039820 0.094383 0.057*
C63 0.5995 (4) −0.1046 (4) 0.1182 (2) 0.0615 (14)
H63 0.650718 −0.116966 0.102064 0.074*
C64 0.5303 (4) −0.1793 (4) 0.1461 (3) 0.0625 (13)
H64 0.533749 −0.242781 0.149316 0.075*
C65 0.4547 (3) −0.1620 (3) 0.1699 (2) 0.0404 (9)
H65 0.407298 −0.212844 0.190210 0.048*
O00O 0.9584 (3) 0.8245 (2) 0.18113 (17) 0.0591 (8)
C66 1.0860 (3) 0.9061 (3) 0.3235 (2) 0.0496 (10)
H66A 1.126773 0.869169 0.315783 0.074*
H66B 1.062660 0.885824 0.367744 0.074*
H66C 1.139373 0.982386 0.339211 0.074*
C67 0.9784 (3) 0.8770 (3) 0.2440 (2) 0.0374 (8)
C68 0.8977 (3) 0.9164 (3) 0.2465 (3) 0.0570 (12)
H68A 0.933528 0.991875 0.248864 0.085*
H68B 0.884681 0.905010 0.295976 0.085*
H68C 0.821671 0.878145 0.196151 0.085*

1 Source of materials

The complex was synthesized starting with the reduction of hydrated RhCl3 in DMF which was refluxed for approximately 20 min to give a yellow solution of di-μ-chloro-tetra-carbonyldirhodium(I), [RhCl(CO)2]2. 5 , 6 , 7 The addition of an equivalent amount of indol-2-carboxylic acid (indol(H2)) to the aforementioned yellow solution followed by addition of ice water yielded the dicarbonylrhodium(I) complex, [RhI(indol)(CO)2] by precipitation. The anion formed by double deprotonation of the indole-2-carboxylic acid (indol(H2)) ligand displays an unprecedented and unexpected mode of coordination with Rh(I) by forming bridging ligand to two rhodium centers; the ketonic oxygen atom coordinating (κO) to the Rh2 atom, while the N,O atoms bind to a second rhodium atom Rh1 atom in the more familiar bidentate (κN,O) fashion. The dinuclear title complex simplifies as [Rh(indol)(CO)(AsPh3)Rh(CO)(AsPh3)2]. 8 [Rh(indol)(CO)(AsPh3)Rh(CO)(AsPh3)2] was synthesized by dissolving [Rh(indol)(CO)2] (0.0412 g, 0.1291 mmol) in 5 cm3 of acetone. Triphenylarsine (AsPh3) (0.0396 g, 0.1291 mmol) was added to the solution with stirring, resulting in the immediate evolution of CO gas. After a few minutes the reaction was completed as determined by IR spectroscopy. Ice water was added drop-wise to the solution. A yellow precipitate was filtered off and dried. Yellow cuboid crystals were obtained from recrystallization in acetone and a few drops of water.

2 Experimental details

All H-atoms were positioned on geometrically idealized positions and refined using the riding model with fixed C–H distances for aromatic C–H of 0.93 Å (C–H) [U iso(H) = 1.2U eq], for methine C–H of 0.98 Å (C–H) [U iso(H) = 1.5U eq]. The graphics were obtained using the DIAMOND 4 program with 50 % probability ellipsoids. The highest peak is located 0.87 Å from As3 and the deepest hole is situated 0.70 Å from Rh2 respectively.

3 Comment

The rhodium(I) complexes and their oxidative additive (RhIII-alkyl) and migratory insertion (RhIII-acyl) products have been extensively studied in the past decade. The precursor [Rh I (I)2(CO)2]− in the Monsanto process is relatively unstable and by manipulating the precursor by introducing different bidentate ligands forming [Rh(BID)(CO)2] complexes (where BID denote different monocharged bidentate ligands such as 2-oxopyridine N-oxide, 8-hydroxyquinoline, indoline-2-carboxylic acid, etc.) One of the carbonyl ligands in this precursor may be replaced by monophosphine or arsine or stibine ligands to form [Rh(L,L’-BID)(CO)(AX3)] complexes (where A = P, As, Sb and X3 = Ph3, Ph2Cy, PhCy2, Cy3, etc.) Generally, this substitution with asymmetrical bidentate ligands might form two isomers, with complexes where AX3 is trans with respect to the strongest donor atom of the bidentate ligand as the preferred isomer. 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 The title complex is isomorphous and isostructural with the corresponding triphenylphospnine complex. 8 The individual indol2− ligand is coordinated to both rhodium atoms in a distorted square planar geometry, as seen in (a) the small 79.61(16)° bite angle of the five membered ring as well the angles C11–Rh1–As: 90.27(18)°, O2–Rh1–As1: 91.36(15)°, C11–Rh1–N1: 98.58(17)°, around Rh1, as well as (b) the angles C10–Rh2–As3: 90.16(17)°, As3–Rh2–O3: 89.40(13)°, O3–Rh2–As2: 92.94(16)°, and As2–Rh2–C19: 86.86(14)° around Rh2, respectively.

Corresponding author: Mohammed A. Elmakki, Department of Chemistry, University of the Free State, 9301, Bloemfontein, South Africa; and Department of Chemistry, Omdurman Islamic University, 14415, Omdurman, Sudan, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors acknowledge funding under the Swiss–South Africa joint research program (SSAJRP) from the SANRF (A. Roodt: UID: 107802) as well as from the Competitive Program for Rated Researchers of the SANRF (A. Roodt: UID: 111698), from the South African Department of Science Innovation (DSI) and the Department of Science and Technology (DST) respectively, “Department of Science and Innovation, Republic of South Africa” and “Department of Science and Technology, Republic of South Africa”.

  3. Conflict of interest: The authors declare no conflicts of interest regarding this article.

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Received: 2024-09-04
Accepted: 2024-10-10
Published Online: 2024-10-25
Published in Print: 2024-12-17

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

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  4. Crystal structure of diaqua-(hydroxido)-{μ-[2-(hydroxy)-5-[(4-nitrophenyl)diazenyl]benzoato]}-{2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzoato}-(1,10-phenanthroline)-diterbium hydrate, C38H27.4N8O12.2Tb
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  6. The crystal structure of 2-amino-N-(pyridin-2-yl)benzamide, C12H11N3O
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  10. The crystal structure of 2-ethyl-1,1-dimethyl-1H-benzo[e]indole, C16H17N
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  13. The crystal structure of tetrakis(μ2-acetato-κ2 O:O′)-bis[(4′-phenyl-4,2′:6′,4″-terpyridine-κ1 N)dicopper(II)], C25H21CuN3O4
  14. Crystal structure of poly(3-thiophenecarboxylato-κ 3 O,O′:O′)-(methanol-κO)cadmium(II), C11H10O5S2Cd
  15. The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
  16. The crystal structure of 1-(2-carboxyethyl)-1H-imidazole 3-oxide
  17. Crystal structure of 1,1′,1″-(nitrilotris(ethane-2,1-diyl))tris(3-(4-(((E)-pyridin-2-ylmethylene)amino)phenyl)urea), C45H47N13O4
  18. Crystal structure of a (E)-4-bromo-N-(4-(diethylamino)-2-hydroxybenzylidene) benzenaminium acetate ─ 4-bromoaniline (1/1)
  19. Crystal structure of 2,2′-(iminobis(methylene))bis(benzimidazolium) bis(p-toluenesulfonate), C30H31N5O6S2
  20. The crystal structure of alogliptinium meta-chlorobenzoate
  21. Crystal structure of 4-bromobenzyl 2-(6-methoxy-naphthalen-2-yl)propanoate, C21H19BrO3
  22. The hydrated double salt structure of (E)-4-(2-benzylidenehydrazine-1-carbonyl)pyridin-1-ium cation with 2-hydroxybenzoate and benzoate anions
  23. Crystal structure of (R)(R)-5-chloro-3-((S,1E,3E)-3,5-dimethyl-hepta-1,3-dien-1-yl)-7-methyl-6,8-dioxo-2,6,7,8-tetrahydroisoquinolin-7-yl acetate, C21H24ClNO4
  24. The crystal structure of bis(3-oxo-1,3-diphenylprop-1-en-1-olato-κ 2 O:O′)-bis(1,4-dioxane-κ 1 O)nickel(II), C38H38O8Ni
  25. Crystal structure of poly[aqua-(pyridine-3-carboxylato-κ1 N)(pyridine-3-carboxylato-κ2 O,O′) cadmium(II)] dihydrate, C12H14N2O7Cd
  26. The crystal structure of 4-(4-phenyl-5-(((1-(2,4,6-tribromophenyl)-1H-1,2,3-triazol-4-yl)methyl)thio)-4H-1,2,4-triazol-3-yl)pyridine, C22H14Br3N7S
  27. The crystal structure of N-benzylquinoline-2-carbothioamide, C17H14N2S
  28. Crystal structure of bis(3-isopropylphenyl)-4,4′-bipyridinium dichloride dihydrate, C28H30N2⋅2Cl⋅2H2O
  29. The crystal structure of ethyl 2-amino-4-(cyanophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C19H18N2O4
  30. Crystal structure of (4R,10S)-6-hydroxy-7-isopropyl-4,10-dimethyl-1,2,3,5-hexahydro-6,10-epoxyazulen-9-one, C15H22O3
  31. The crystal structure of (E)-(2-(2-hydroxy-3-methoxybenzylidene)aminophenyl)arsonic acid, C14H14AsNO5
  32. The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U
  33. The crystal structure of the co-crystal isonicotinamide · terephthalic acid, C8H6O4·2(C6H6N2O)
  34. The crystal structure of (E)-1-phenyl-3-(p-tolylthio)but-2-en-1-one, C17H16OS
  35. The crystal structure of 4,5-bis((Z)-chloro(hydroxyimino)methyl)-1H-imidazol-3-ium chloride monohydrate
  36. The crystal structure of 1,2-bis(4-(dimethylamino)phenyl)ethane-1,2-dione. C18H20N2O2
  37. Crystal structure of 2-chloro-4-fluorobenzyl 2-acetoxybenzoate, C16H12ClFO4
  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
https://doi.org/10.1515/ncrs-2024-0357
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 3-nitrophenol-2,1,3-benzoselenadiazole (1/1), C12H9N3O3Se
  4. Crystal structure of diaqua-(hydroxido)-{μ-[2-(hydroxy)-5-[(4-nitrophenyl)diazenyl]benzoato]}-{2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzoato}-(1,10-phenanthroline)-diterbium hydrate, C38H27.4N8O12.2Tb
  5. Crystal structure of poly[bis(μ3-3-fluoro-4-(1H-1,2,4-triazol-1-yl)benzoato-κ3 O:O′:N)cadmium(II)] – dimethylformamide (1/1), C21H17CdF2N7O5
  6. The crystal structure of 2-amino-N-(pyridin-2-yl)benzamide, C12H11N3O
  7. The crystal structure of 2,3-di(pyridin-2-yl)-2,3-dihydroquinazolin-4(1H)-one, C18H14N4O
  8. Crystal structure of 2-chloro-4-fluorobenzyl (R)-2-(6-methoxynaphthalen-2-yl)propanoate, C21H18ClFO3
  9. Crystal structure of [1-(4-carboxyphenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylic acid]-(methylsulfinyl)methane, C15H16N2O6S
  10. The crystal structure of 2-ethyl-1,1-dimethyl-1H-benzo[e]indole, C16H17N
  11. The crystal structure of (Z)-5-amino-N ′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  12. The crystal structure of 2,2,5-trimethyl-3-(4-(4-(5-phenyl-4,5-dihydroisoxazol-3-yl)thiazol-2-yl)phenyl)imidazolidin-4-one, C24H24N4O2S
  13. The crystal structure of tetrakis(μ2-acetato-κ2 O:O′)-bis[(4′-phenyl-4,2′:6′,4″-terpyridine-κ1 N)dicopper(II)], C25H21CuN3O4
  14. Crystal structure of poly(3-thiophenecarboxylato-κ 3 O,O′:O′)-(methanol-κO)cadmium(II), C11H10O5S2Cd
  15. The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
  16. The crystal structure of 1-(2-carboxyethyl)-1H-imidazole 3-oxide
  17. Crystal structure of 1,1′,1″-(nitrilotris(ethane-2,1-diyl))tris(3-(4-(((E)-pyridin-2-ylmethylene)amino)phenyl)urea), C45H47N13O4
  18. Crystal structure of a (E)-4-bromo-N-(4-(diethylamino)-2-hydroxybenzylidene) benzenaminium acetate ─ 4-bromoaniline (1/1)
  19. Crystal structure of 2,2′-(iminobis(methylene))bis(benzimidazolium) bis(p-toluenesulfonate), C30H31N5O6S2
  20. The crystal structure of alogliptinium meta-chlorobenzoate
  21. Crystal structure of 4-bromobenzyl 2-(6-methoxy-naphthalen-2-yl)propanoate, C21H19BrO3
  22. The hydrated double salt structure of (E)-4-(2-benzylidenehydrazine-1-carbonyl)pyridin-1-ium cation with 2-hydroxybenzoate and benzoate anions
  23. Crystal structure of (R)(R)-5-chloro-3-((S,1E,3E)-3,5-dimethyl-hepta-1,3-dien-1-yl)-7-methyl-6,8-dioxo-2,6,7,8-tetrahydroisoquinolin-7-yl acetate, C21H24ClNO4
  24. The crystal structure of bis(3-oxo-1,3-diphenylprop-1-en-1-olato-κ 2 O:O′)-bis(1,4-dioxane-κ 1 O)nickel(II), C38H38O8Ni
  25. Crystal structure of poly[aqua-(pyridine-3-carboxylato-κ1 N)(pyridine-3-carboxylato-κ2 O,O′) cadmium(II)] dihydrate, C12H14N2O7Cd
  26. The crystal structure of 4-(4-phenyl-5-(((1-(2,4,6-tribromophenyl)-1H-1,2,3-triazol-4-yl)methyl)thio)-4H-1,2,4-triazol-3-yl)pyridine, C22H14Br3N7S
  27. The crystal structure of N-benzylquinoline-2-carbothioamide, C17H14N2S
  28. Crystal structure of bis(3-isopropylphenyl)-4,4′-bipyridinium dichloride dihydrate, C28H30N2⋅2Cl⋅2H2O
  29. The crystal structure of ethyl 2-amino-4-(cyanophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C19H18N2O4
  30. Crystal structure of (4R,10S)-6-hydroxy-7-isopropyl-4,10-dimethyl-1,2,3,5-hexahydro-6,10-epoxyazulen-9-one, C15H22O3
  31. The crystal structure of (E)-(2-(2-hydroxy-3-methoxybenzylidene)aminophenyl)arsonic acid, C14H14AsNO5
  32. The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U
  33. The crystal structure of the co-crystal isonicotinamide · terephthalic acid, C8H6O4·2(C6H6N2O)
  34. The crystal structure of (E)-1-phenyl-3-(p-tolylthio)but-2-en-1-one, C17H16OS
  35. The crystal structure of 4,5-bis((Z)-chloro(hydroxyimino)methyl)-1H-imidazol-3-ium chloride monohydrate
  36. The crystal structure of 1,2-bis(4-(dimethylamino)phenyl)ethane-1,2-dione. C18H20N2O2
  37. Crystal structure of 2-chloro-4-fluorobenzyl 2-acetoxybenzoate, C16H12ClFO4
  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
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Heruntergeladen am 6.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2024-0357/html
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