Startseite The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
Artikel Open Access

The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16

  • Guang Huang ORCID logo EMAIL logo , Jianhui Liu und Xinyu Chen
Veröffentlicht/Copyright: 25. Oktober 2024
Artikel downloaden (PDF)
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 239 Heft 6

Abstract

C46H32I2N8Nd2O16, triclinic, P 1 ‾ (no. 2), a = 8.6591(17) Å, b = 11.655(2) Å, c = 12.711(3) Å, α = 81.55(3)°, β = 86.62(3)°, γ = 68.50(3)°, V = 1180.5(5) Å3, Z = 1, R gt(F) = 0.0298, wRref (F 2) = 0.1211, T = 293(2) K.

CCDC no.: 2389958

A part of the molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Pink block
Size: 0.26 × 0.18 × 0.12 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 3.57 mm−1
Diffractometer, scan mode: Bruker P4, φ and ω scans
θ max, completeness: 27.5°, >99 %
N(hkl)measured, N(hkl)unique, R int: 11663, 5383, 0.032
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 4,758
N(param)refined: 335
Programs: Bruker, 1 Olex2, 2 SHELX 3 , 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.1522 (6) 0.7273 (6) 0.2679 (5) 0.0385 (12)
H1 0.060136 0.723509 0.307787 0.046*
C2 0.1351 (7) 0.8124 (6) 0.1785 (5) 0.0476 (15)
H2 0.030477 0.868820 0.157430 0.057*
C3 0.2746 (8) 0.8140 (6) 0.1196 (5) 0.0469 (15)
H3 0.264559 0.868815 0.057101 0.056*
C4 0.4293 (6) 0.7321 (5) 0.1557 (4) 0.0299 (10)
C5 0.5865 (6) 0.7332 (5) 0.0990 (4) 0.0284 (10)
C6 0.5780 (8) 0.8238 (6) 0.0114 (4) 0.0430 (14)
H6 0.476427 0.880807 −0.014507 0.052*
C7 0.7252 (8) 0.8254 (6) −0.0351 (5) 0.0472 (15)
H7 0.724171 0.885840 −0.091904 0.057*
C8 0.8733 (8) 0.7378 (6) 0.0025 (4) 0.0401 (13)
H8 0.973108 0.737889 −0.028813 0.048*
C9 0.8716 (6) 0.6491 (5) 0.0880 (4) 0.0294 (10)
C10 1.0269 (6) 0.5517 (5) 0.1296 (4) 0.0277 (10)
C11 1.1796 (6) 0.5348 (6) 0.0769 (4) 0.0347 (11)
H11 1.182709 0.583081 0.012293 0.042*
C12 1.3241 (6) 0.4477 (6) 0.1202 (4) 0.0370 (12)
H12 1.425451 0.436234 0.085806 0.044*
C13 1.3148 (6) 0.3782 (5) 0.2153 (4) 0.0345 (11)
H13 1.410887 0.319449 0.246977 0.041*
C14 1.1648 (6) 0.3951 (5) 0.2635 (4) 0.0334 (11)
H14 1.160694 0.345685 0.327299 0.040*
C15 0.7237 (5) 0.7556 (4) 0.4158 (4) 0.0217 (9)
C16 0.5406 (5) 0.8311 (4) 0.4110 (3) 0.0221 (9)
C17 0.4268 (6) 0.7864 (4) 0.4696 (3) 0.0246 (9)
C18 0.2612 (6) 0.8599 (5) 0.4703 (4) 0.0357 (11)
H18 0.186641 0.831046 0.510993 0.043*
C19 0.2049 (7) 0.9768 (5) 0.4107 (5) 0.0440 (14)
H19 0.092439 1.025317 0.410664 0.053*
C20 0.3124 (7) 1.0210 (5) 0.3526 (5) 0.0400 (13)
H20 0.273548 1.098887 0.311750 0.048*
C21 0.4814 (6) 0.9491 (5) 0.3541 (4) 0.0297 (10)
C22 0.3124 (6) 0.6464 (5) 0.2972 (4) 0.0303 (10)
H22 0.324820 0.587831 0.357412 0.036*
C23 0.4847 (6) 0.6558 (4) 0.5262 (4) 0.0247 (9)
I1 0.64666 (5) 1.02360 (3) 0.26854 (3) 0.04201 (13)
N1 0.4490 (5) 0.6485 (4) 0.2433 (3) 0.0271 (8)
N2 0.7291 (5) 0.6468 (4) 0.1349 (3) 0.0245 (8)
N3 1.0221 (5) 0.4809 (4) 0.2222 (3) 0.0286 (9)
N4 0.8356 (6) 0.2750 (5) 0.2096 (4) 0.0405 (11)
Nd1 0.73807 (3) 0.50312 (2) 0.32045 (2) 0.01917 (10)
O1 0.6093 (4) 0.5762 (3) 0.4882 (2) 0.0251 (7)
O2 0.7864 (4) 0.6866 (3) 0.3442 (3) 0.0267 (7)
O3 0.8025 (5) 0.7685 (3) 0.4886 (3) 0.0341 (8)
O4 0.4060 (4) 0.6319 (3) 0.6074 (3) 0.0293 (7)
O5 0.7275 (5) 0.3800 (4) 0.1732 (3) 0.0415 (9)
O6 0.9097 (5) 0.2703 (4) 0.2926 (4) 0.0448 (10)
O7 0.8633 (8) 0.1839 (5) 0.1639 (5) 0.0746 (18)
O1W 0.9263 (5) 0.4108(4) 0.4721(3) 0.0368 (8)
H1WA 0.961452 0.330874 0.477517 0.055*
H1WB 0.872213 0.427544 0.530396 0.055*

1 Source of materials

All raw materials are analytical grade, purchased without further purification, and used directly. The titled neodymium(III) complex was hydrothermally synthesized as follows: 0.0433 g neodymium nitrate hexahydrate (0.1 mmol), 0.0292 g (0.1 mmol) 3-iodobenzene-1,2-dicarboxylic acid, 0.0233 g 2,2′:6′,2″-terpyridine (0.1 mmol), and 0.008 g NaOH (0.2 mmol) were mixed with 5 mL H2O, then added to a 20 mL Teflon-lined stainless steel autoclave at 393 K for 72 h. The pink block crystals were harvested with a yield 56.4 % (based on 3-iodobenzene-1,2-dicarboxylic acid).

2 Experimental details

The structure was solved by direct methods with the SHELXS-2018 program. All H-atoms from C and O atoms were positioned with idealized geometry and refined isotropically (U iso(H) = 1.2U eq(C) and U iso(H) = 1.5U eq(O)) using a riding model with C–H = 0.930 Å and O–H = 0.861 Å.

3 Comment

The crystal structures of four-components of lanthanide complexes base on lanthanide(III), benzenecarboxylic acid or its direvatives, 2,2′:6′,2″-terpyridine, and nitrate have been reported elsewhere, including mono-nuclear Ln(III), 5 , 6 di-nuclear Ln(III) 7 , 8 , 9 , 10 , 11 and 1D chain. 12 Besides, the crystal structure of 3-iodophthalic acid 13 and its mono-nuclear 1D chainlike structure 12 have been reported, the crystal structure of di-nuclear Ln(III) complex based on the four-components mentioned above has not been published anywhere. Thus, we reported one crystal structure of this type of neodymium(III) complex. The asymmetric unit consists of one neodymium(III) cation, one full-deprotonated 3-iodobenzene-1,2-dicarboxylate anion, one neutral 2,2′:6′2″-tripyridine, one nitrate, and one coordinated water molucule. The neodymium(III) is nine-coordinated with three nitrogen atoms from one 2,2′:6′2″-tripyridine, three oxygen atoms from three carboxyl groups of two 3-iodobenzene-1,2-dicarboxylate anions, two oxygen atoms from one nitrate, and one oxygen atom from one coordinated water molecule. 3-Iodobenzene-1,2-dicarboxylates were bridged by two carboxylates to generate one di-nuclear neodymium(III) complex. A three dimensional supramolecular structure is obtained by two kind of hydrogen bonds C–H⋯O (C1–H1⋯O2, C8–H8⋯O7, C11–H11⋯O5, C12–H12⋯O5, and C14–H14⋯O3) and O–H⋯O (O1–H1WA⋯O3), and π⋯π weak interactions.

Corresponding author: Guang Huang, Sino-Portugal Belt and Road Joint Laboratory on Science of Cultural Heritage Conservation, City University of Macau, Taipa, Macau; HERCULES Laboratory, Universidade de Évora, 7000-809, Evora, Portugal; and Sino-Portugal Belt and Road Joint Laboratory on Science of Cultural Heritage Conservation, Soochow University, Suzhou, Jiangsu, P.R. China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest: The authors declare no conflicts of interest regarding this article.

References

1. Bruker XSCANS, Bruker SHEXLTL; Bruker AXS Inc: Madison, Wisconsin, USA, 2012.Suche in Google Scholar

2. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX2: A Complete Structure Solution, Refinement and Analysis Program. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Suche in Google Scholar

3. Sheldrick, G. M. Crystal Structure Refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8, https://doi.org/10.1107/s2053229614024218.Suche in Google Scholar

4. Sheldrick, G. Using Phases to Determine the Space Group. Acta Crystallogr. 2018, A74, A353; https://doi.org/10.1107/s0108767318096472.Suche in Google Scholar

5. Li, Y.; You, Y.; Zhao, P.; Ding, B.; Zhang, N.; Liu, Z.-Y.; Yang, E.-C.; Zhao, X.-J. Fine Tuning the Relaxation Dynamics of Mononuclear Dy(III) Complexes by Auxiliary Ligand. Inorg. Chem. Commun. 2022, 140, 109461; https://doi.org/10.1016/j.inoche.2022.109461.Suche in Google Scholar

6. Geng, S.; Ren, N.; He, S.-M.; Zhang, J.-J. Synthesis and Structural Characterization of Lanthanide Metal Complexes by 2-Fluorobenzoic Acid with 2,2′:6′,2″-Terpyridine, and Their Fluorescence Properties. J. Mol. Struct. 2021, 1252, 132165; https://doi.org/10.1016/j.molstruc.2021.132165.Suche in Google Scholar

7. Messimeri, A.; Papadimitriou, C.; Raptopoulou, C. P.; Escuer, A.; Perlepes, S. P.; Boudalis, A. K. The Benzoate/Nitrate/2,2′:6′,2″-terpyridine ‘Blend’ in Lanthanide(III) Chemistry: Relevance to the Separation of Lanthanides and Actinides by Solvent Extraction. Inorg. Chem. Commun. 2007, 10, 800–804; https://doi.org/10.1016/j.inoche.2007.03.030.Suche in Google Scholar

8. Xie, H.; Lu, G. Crystal Structures and Fluorescence Properties of Lanthanide Complexes Prepared with 2,2′-Biphenyldicarboxylic Acid and 2,2′:6′,2″-Terpyridine. J. Rare Earths 2013, 31, 639–644; https://doi.org/10.1016/s1002-0721(12)60334-2.Suche in Google Scholar

9. Herder, J. A.; Walusiak, B. W.; Cahill, C. L. RE-Halobenzoic Acid-Terpyridine Complexes, Part V: Synthesis and Supramolecular Assembly of Rare-Earth-3,5-Dihalobenzoic Acid-Terpyridine Naterials and Subsequent Comparison of Non-covalent Interactions. J. Chem. Cryst. 2021, 51, 317–336; https://doi.org/10.1007/s10870-020-00858-x.Suche in Google Scholar

10. Wang, S.-L.; Xu, C.-L.; Liu, Z.-J.; Ren, N.; Zhang, J.-J. Synthesis, Structure, Fluorescence and Thermochemical Properties of the Lanthanide Complexes of 2-Chloro-6-Fluorobenzoic Acid and 2,2′:6′2″-Tripyridine Ligands. J. Solid State Chem. 2022, 315, 123454; https://doi.org/10.1016/j.jssc.2022.123454.Suche in Google Scholar

11. Zhao, J.-Y.; Ren, N.; Zhang, J.-J. Lanthanide Complexes with 2,6-dimethylbenzoic Acid and 2,2′:6′,2″-Terpyridine: Crystal Structures, Thermochemical Property and Luminescent Behavior. Thermochim. Acta 2021, 699, 178915; https://doi.org/10.1016/j.tca.2021.178915.Suche in Google Scholar

12. Cai, B.; Meng, Y. The Crystal Structure of catena-[nitrato-κ2O, O′-(μ3-3-iodobenzene-1,2-dicarboxylato- κ4O: O′: O″, O‴)-(2,2′:6′,2″-Terpyridine-κ3N, N′, N″)lanthanum(III)], C23H14IN4O7La. Z. Kristallogr. N. Cryst. Struct. 2023, 238, 465–466; https://doi.org/10.1515/ncrs-2023-0036.Suche in Google Scholar

13. Du, C.-J.; Wang, Z.-D.; Zhu, D.-F.; Zhu, Y.-L.; Zeng, Y. Crystal Structure of 3-Iodophthalic Acid, C8H5IO4. Z. Kristallogr. N. Cryst. Struct. 2020, 235, 243–244; https://doi.org/10.1515/ncrs-2019-0598.Suche in Google Scholar
Received: 2024-07-31
Accepted: 2024-10-10
Published Online: 2024-10-25
Published in Print: 2024-12-17

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 3-nitrophenol-2,1,3-benzoselenadiazole (1/1), C12H9N3O3Se
  4. Crystal structure of diaqua-(hydroxido)-{μ-[2-(hydroxy)-5-[(4-nitrophenyl)diazenyl]benzoato]}-{2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzoato}-(1,10-phenanthroline)-diterbium hydrate, C38H27.4N8O12.2Tb
  5. Crystal structure of poly[bis(μ3-3-fluoro-4-(1H-1,2,4-triazol-1-yl)benzoato-κ3 O:O′:N)cadmium(II)] – dimethylformamide (1/1), C21H17CdF2N7O5
  6. The crystal structure of 2-amino-N-(pyridin-2-yl)benzamide, C12H11N3O
  7. The crystal structure of 2,3-di(pyridin-2-yl)-2,3-dihydroquinazolin-4(1H)-one, C18H14N4O
  8. Crystal structure of 2-chloro-4-fluorobenzyl (R)-2-(6-methoxynaphthalen-2-yl)propanoate, C21H18ClFO3
  9. Crystal structure of [1-(4-carboxyphenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylic acid]-(methylsulfinyl)methane, C15H16N2O6S
  10. The crystal structure of 2-ethyl-1,1-dimethyl-1H-benzo[e]indole, C16H17N
  11. The crystal structure of (Z)-5-amino-N ′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  12. The crystal structure of 2,2,5-trimethyl-3-(4-(4-(5-phenyl-4,5-dihydroisoxazol-3-yl)thiazol-2-yl)phenyl)imidazolidin-4-one, C24H24N4O2S
  13. The crystal structure of tetrakis(μ2-acetato-κ2 O:O′)-bis[(4′-phenyl-4,2′:6′,4″-terpyridine-κ1 N)dicopper(II)], C25H21CuN3O4
  14. Crystal structure of poly(3-thiophenecarboxylato-κ 3 O,O′:O′)-(methanol-κO)cadmium(II), C11H10O5S2Cd
  15. The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
  16. The crystal structure of 1-(2-carboxyethyl)-1H-imidazole 3-oxide
  17. Crystal structure of 1,1′,1″-(nitrilotris(ethane-2,1-diyl))tris(3-(4-(((E)-pyridin-2-ylmethylene)amino)phenyl)urea), C45H47N13O4
  18. Crystal structure of a (E)-4-bromo-N-(4-(diethylamino)-2-hydroxybenzylidene) benzenaminium acetate ─ 4-bromoaniline (1/1)
  19. Crystal structure of 2,2′-(iminobis(methylene))bis(benzimidazolium) bis(p-toluenesulfonate), C30H31N5O6S2
  20. The crystal structure of alogliptinium meta-chlorobenzoate
  21. Crystal structure of 4-bromobenzyl 2-(6-methoxy-naphthalen-2-yl)propanoate, C21H19BrO3
  22. The hydrated double salt structure of (E)-4-(2-benzylidenehydrazine-1-carbonyl)pyridin-1-ium cation with 2-hydroxybenzoate and benzoate anions
  23. Crystal structure of (R)(R)-5-chloro-3-((S,1E,3E)-3,5-dimethyl-hepta-1,3-dien-1-yl)-7-methyl-6,8-dioxo-2,6,7,8-tetrahydroisoquinolin-7-yl acetate, C21H24ClNO4
  24. The crystal structure of bis(3-oxo-1,3-diphenylprop-1-en-1-olato-κ 2 O:O′)-bis(1,4-dioxane-κ 1 O)nickel(II), C38H38O8Ni
  25. Crystal structure of poly[aqua-(pyridine-3-carboxylato-κ1 N)(pyridine-3-carboxylato-κ2 O,O′) cadmium(II)] dihydrate, C12H14N2O7Cd
  26. The crystal structure of 4-(4-phenyl-5-(((1-(2,4,6-tribromophenyl)-1H-1,2,3-triazol-4-yl)methyl)thio)-4H-1,2,4-triazol-3-yl)pyridine, C22H14Br3N7S
  27. The crystal structure of N-benzylquinoline-2-carbothioamide, C17H14N2S
  28. Crystal structure of bis(3-isopropylphenyl)-4,4′-bipyridinium dichloride dihydrate, C28H30N2⋅2Cl⋅2H2O
  29. The crystal structure of ethyl 2-amino-4-(cyanophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C19H18N2O4
  30. Crystal structure of (4R,10S)-6-hydroxy-7-isopropyl-4,10-dimethyl-1,2,3,5-hexahydro-6,10-epoxyazulen-9-one, C15H22O3
  31. The crystal structure of (E)-(2-(2-hydroxy-3-methoxybenzylidene)aminophenyl)arsonic acid, C14H14AsNO5
  32. The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U
  33. The crystal structure of the co-crystal isonicotinamide · terephthalic acid, C8H6O4·2(C6H6N2O)
  34. The crystal structure of (E)-1-phenyl-3-(p-tolylthio)but-2-en-1-one, C17H16OS
  35. The crystal structure of 4,5-bis((Z)-chloro(hydroxyimino)methyl)-1H-imidazol-3-ium chloride monohydrate
  36. The crystal structure of 1,2-bis(4-(dimethylamino)phenyl)ethane-1,2-dione. C18H20N2O2
  37. Crystal structure of 2-chloro-4-fluorobenzyl 2-acetoxybenzoate, C16H12ClFO4
  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
https://doi.org/10.1515/ncrs-2024-0326
Creative Commons
BY 4.0

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 3-nitrophenol-2,1,3-benzoselenadiazole (1/1), C12H9N3O3Se
  4. Crystal structure of diaqua-(hydroxido)-{μ-[2-(hydroxy)-5-[(4-nitrophenyl)diazenyl]benzoato]}-{2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzoato}-(1,10-phenanthroline)-diterbium hydrate, C38H27.4N8O12.2Tb
  5. Crystal structure of poly[bis(μ3-3-fluoro-4-(1H-1,2,4-triazol-1-yl)benzoato-κ3 O:O′:N)cadmium(II)] – dimethylformamide (1/1), C21H17CdF2N7O5
  6. The crystal structure of 2-amino-N-(pyridin-2-yl)benzamide, C12H11N3O
  7. The crystal structure of 2,3-di(pyridin-2-yl)-2,3-dihydroquinazolin-4(1H)-one, C18H14N4O
  8. Crystal structure of 2-chloro-4-fluorobenzyl (R)-2-(6-methoxynaphthalen-2-yl)propanoate, C21H18ClFO3
  9. Crystal structure of [1-(4-carboxyphenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylic acid]-(methylsulfinyl)methane, C15H16N2O6S
  10. The crystal structure of 2-ethyl-1,1-dimethyl-1H-benzo[e]indole, C16H17N
  11. The crystal structure of (Z)-5-amino-N ′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  12. The crystal structure of 2,2,5-trimethyl-3-(4-(4-(5-phenyl-4,5-dihydroisoxazol-3-yl)thiazol-2-yl)phenyl)imidazolidin-4-one, C24H24N4O2S
  13. The crystal structure of tetrakis(μ2-acetato-κ2 O:O′)-bis[(4′-phenyl-4,2′:6′,4″-terpyridine-κ1 N)dicopper(II)], C25H21CuN3O4
  14. Crystal structure of poly(3-thiophenecarboxylato-κ 3 O,O′:O′)-(methanol-κO)cadmium(II), C11H10O5S2Cd
  15. The crystal structure of dichloridobis[4′-(p-methoxylphenyl)-4,2′:6′,4″-terpyridine-κN] zinc(II), C44H34Cl2N6O2Zn
  16. The crystal structure of 1-(2-carboxyethyl)-1H-imidazole 3-oxide
  17. Crystal structure of 1,1′,1″-(nitrilotris(ethane-2,1-diyl))tris(3-(4-(((E)-pyridin-2-ylmethylene)amino)phenyl)urea), C45H47N13O4
  18. Crystal structure of a (E)-4-bromo-N-(4-(diethylamino)-2-hydroxybenzylidene) benzenaminium acetate ─ 4-bromoaniline (1/1)
  19. Crystal structure of 2,2′-(iminobis(methylene))bis(benzimidazolium) bis(p-toluenesulfonate), C30H31N5O6S2
  20. The crystal structure of alogliptinium meta-chlorobenzoate
  21. Crystal structure of 4-bromobenzyl 2-(6-methoxy-naphthalen-2-yl)propanoate, C21H19BrO3
  22. The hydrated double salt structure of (E)-4-(2-benzylidenehydrazine-1-carbonyl)pyridin-1-ium cation with 2-hydroxybenzoate and benzoate anions
  23. Crystal structure of (R)(R)-5-chloro-3-((S,1E,3E)-3,5-dimethyl-hepta-1,3-dien-1-yl)-7-methyl-6,8-dioxo-2,6,7,8-tetrahydroisoquinolin-7-yl acetate, C21H24ClNO4
  24. The crystal structure of bis(3-oxo-1,3-diphenylprop-1-en-1-olato-κ 2 O:O′)-bis(1,4-dioxane-κ 1 O)nickel(II), C38H38O8Ni
  25. Crystal structure of poly[aqua-(pyridine-3-carboxylato-κ1 N)(pyridine-3-carboxylato-κ2 O,O′) cadmium(II)] dihydrate, C12H14N2O7Cd
  26. The crystal structure of 4-(4-phenyl-5-(((1-(2,4,6-tribromophenyl)-1H-1,2,3-triazol-4-yl)methyl)thio)-4H-1,2,4-triazol-3-yl)pyridine, C22H14Br3N7S
  27. The crystal structure of N-benzylquinoline-2-carbothioamide, C17H14N2S
  28. Crystal structure of bis(3-isopropylphenyl)-4,4′-bipyridinium dichloride dihydrate, C28H30N2⋅2Cl⋅2H2O
  29. The crystal structure of ethyl 2-amino-4-(cyanophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C19H18N2O4
  30. Crystal structure of (4R,10S)-6-hydroxy-7-isopropyl-4,10-dimethyl-1,2,3,5-hexahydro-6,10-epoxyazulen-9-one, C15H22O3
  31. The crystal structure of (E)-(2-(2-hydroxy-3-methoxybenzylidene)aminophenyl)arsonic acid, C14H14AsNO5
  32. The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U
  33. The crystal structure of the co-crystal isonicotinamide · terephthalic acid, C8H6O4·2(C6H6N2O)
  34. The crystal structure of (E)-1-phenyl-3-(p-tolylthio)but-2-en-1-one, C17H16OS
  35. The crystal structure of 4,5-bis((Z)-chloro(hydroxyimino)methyl)-1H-imidazol-3-ium chloride monohydrate
  36. The crystal structure of 1,2-bis(4-(dimethylamino)phenyl)ethane-1,2-dione. C18H20N2O2
  37. Crystal structure of 2-chloro-4-fluorobenzyl 2-acetoxybenzoate, C16H12ClFO4
  38. Crystal structure of methyl 1-phenyl-9H-pyrido[3,4-b]indole-3-carboxylate, C19H14N2O2
  39. Crystal structure of (3-(dimethoxymethyl)-5-methoxy-1H-indol-1-yl)(5-fluoro-2-iodophenyl)methanone, C19H17FINO4
  40. Crystal structure of tetrachlorido-bis(1-[(1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2 N:N′)dicopper, C36H32Cu2N24Cl4
  41. Crystal structure of 2-(2,3-bis(4-methoxyphenyl)-1H-pyrrolo[2,3-b]quinoxalin-1-yl)anilin, C30H24N4O2
  42. Crystal structure of 5,7-dihydroxy-2-phenyl-4H-chromen-4-one–N,N-dimethylformamide(1/1), C18H17NO5
  43. The crystal structure of bis(μ 2-biphenyl-2,2′-dicarboxylato)-diaqua-bis(nitrato)-bis(2,2′:6′,2′′-terpyridine)dineodymium(III), C46H32I2N8Nd2O16
  44. Crystal structure of (Z)-4-amino-N ′-((4-chlorophenyl)(phenyl)methylene)benzohydrazide, C20H16ClN3O
  45. Crystal structure of (E)-6,8-dimethoxy-4-(4-morpholinobenzylidene)-3,4-dihydro-1-benzoxepin-5(2H)-one, C23H25NO5
  46. Crystal structure of (R)-2-((3-(3-aminopiperidin-1-yl)-6-methyl-5-oxo-1,2,4-triazin-4(5H)-yl) methyl)-4-fluorobenzonitrile benzoate monohydrate, C24H27FN6O4
  47. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylato-κ 3 N,O,O)copper(II)]monohydrate, C12H15NO9Cu
  48. Crystal structure of (((4-chlorophenyl)sulfonyl)glycinato-κ 2 N,O)bis(1,10-phenanthroline-κ 2 N,N′)cobalt(II) tetrahydrate, C32H30ClCoN5O8S
  49. Crystal structure of (((3-nitrophenyl)sulfonyl)-β-alaninato-κO)bis(2,2′-bipyridine-κ 2 N, N′)copper(II) 3-nitrobenzenesulfonate, C35H29CuN7O11S2
  50. Crystal structure of 3-phenoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C27H24O4
  51. 6-(2′,3′-Dihydroxy-3′-methylbutyl)-7-methoxy-8-(3″-methylbut-2″-en-1″-yl)-2H-chromen-2-one, C20H26O5
  52. Crystal structure of bromido-(2,2′:6′,2″-terpyridine-4′-onato-κ3N)palladium(II) methanol solvate
  53. The crystal structure of ethyl 2-amino-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H22N2O6
  54. Crystal structure of (1E,3E,5E)-1,6-bis(4-(pentyloxy)phenyl)hexa-1,3,5-triene, C28H36O2
  55. The crystal structure of tris(2-bromo-4-methylphenyl)amine, C21H18Br3N
  56. The crystal structure of 3-(2,5-dimethylanilino)-1-(2,5-dimethylphenyl)-4-methyl-1H-pyrrole-2,5-dione, C21H22N2O2
  57. Crystal structure of dicarbonyl (μ2-indole-2-carboxylato κ2 O:O′)tris(triphenylarsine-κAs)dirhodium(I) acetone solvate, C68H56As3NO5Rh2
  58. The crystal structure of 4-chloro-2-formylphenyl 4-methylbenzenesulfonate, C14H11ClO4S
  59. Crystal structure of 4-iodobenzyl 2-(6-methoxynaphthalen-2-yl) propanoate, C21H19IO3
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 6.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2024-0326/html
Button zum nach oben scrollen