Abstract
C40H40N4O12Ni, triclinic, P1̅, a = 7.6612(6) Å, b = 8.0725(7) Å, c = 16.3021(10) Å, α = 89.394(6)°, β = 77.966(6)°, γ = 69.868(8)°, V = 923.75(12) Å3, Z = 1, Rgt(F) = 0.0492, wRref(F2) = 0.1309, T = 293(2) K.

The crystal structure is shown in the figure. Tables 1–3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.
Data collection and handling.
| Crystal: | Colourless, block, size 0.28×0.38×0.41 mm |
| Wavelength: | Mo Kα radiation (0.71073 Å) |
| μ: | 5.98 cm−1 |
| Diffractometer, scan mode: | CCD area detector, φ and ω scans |
| 2θmax: | 50.98° |
| N(hkl)measured, N(hkl)unique: | 7301, 3429 |
| Criterion for Iobs, N(hkl)gt: | Iobs > 2 σ(Iobs), 2864 |
| N(param)refined: | 262 |
| Programs: | SHELX [7] |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).
| Atom | Site | x | y | z | Uiso |
|---|---|---|---|---|---|
| H(1W) | 2i | 0.9911 | 0.4555 | 0.1553 | 0.058 |
| H(2W) | 2i | 0.8549 | 0.4290 | 0.1971 | 0.058 |
| H(3W) | 2i | 1.0596 | 1.2716 | −0.0027 | 0.049 |
| H(4W) | 2i | 1.0636 | 1.2446 | 0.0869 | 0.049 |
| H(5) | 2i | 0.9108 | 0.5763 | 0.4480 | 0.084 |
| H(3) | 2i | 1.0393 | 0.6568 | 0.2614 | 0.038 |
| H(8A) | 2i | 1.7085 | 0.4441 | 0.3420 | 0.076 |
| H(8B) | 2i | 1.5682 | 0.3503 | 0.3852 | 0.076 |
| H(8C) | 2i | 1.5328 | 0.5462 | 0.4137 | 0.076 |
| H(9A) | 2i | 1.6865 | 0.6570 | 0.0902 | 0.070 |
| H(9B) | 2i | 1.5216 | 0.6735 | 0.0441 | 0.070 |
| H(9C) | 2i | 1.6638 | 0.4864 | 0.0561 | 0.070 |
| H(10) | 2i | 0.5702 | 1.0903 | 0.0518 | 0.045 |
| H(11) | 2i | 0.3382 | 1.0889 | 0.1629 | 0.049 |
| H(13) | 2i | 0.7110 | 1.0194 | 0.3101 | 0.042 |
| H(14) | 2i | 0.9305 | 1.0331 | 0.1949 | 0.039 |
| H(16) | 2i | 0.1183 | 1.1860 | 0.2848 | 0.054 |
| H(17) | 2i | −0.1044 | 1.1607 | 0.3971 | 0.055 |
| H(19) | 2i | 0.3073 | 0.8639 | 0.5047 | 0.061 |
| H(20) | 2i | 0.5305 | 0.8876 | 0.3922 | 0.060 |
Atomic displacement parameters (Å2).
| Atom | Site | x | y | z | U11 | U22 | U33 | U12 | U13 | U23 |
|---|---|---|---|---|---|---|---|---|---|---|
| Ni(1) | 2a | 1.0 | 1.0 | 0.0 | 0.0213(3) | 0.0339(3) | 0.0223(3) | −0.0088(2) | −0.0027(2) | 0.0070(2) |
| O(1) | 2i | 0.9635(3) | 0.3747(3) | 0.1830(1) | 0.036(1) | 0.039(1) | 0.039(1) | −0.011(1) | −0.006(1) | 0.009(1) |
| O(2) | 2i | 1.0938(3) | 1.1959(3) | 0.0310(1) | 0.034(1) | 0.038(1) | 0.028(1) | −0.014(1) | −0.008(1) | 0.0082(9) |
| O(3) | 2i | 1.1902(3) | 0.8363(3) | 0.0662(1) | 0.026(1) | 0.040(1) | 0.029(1) | −0.0110(9) | −0.0047(9) | 0.013(1) |
| O(4) | 2i | 1.0513(4) | 0.6355(3) | 0.0961(2) | 0.046(2) | 0.050(1) | 0.038(1) | −0.027(1) | −0.018(1) | 0.018(1) |
| O(5) | 2i | 0.9643(4) | 0.6075(4) | 0.4049(2) | 0.033(2) | 0.096(2) | 0.035(2) | −0.019(1) | −0.004(1) | 0.025(1) |
| O(6) | 2i | 1.2197(4) | 0.4753(4) | 0.4569(2) | 0.043(2) | 0.101(2) | 0.032(2) | −0.027(2) | −0.011(1) | 0.032(2) |
| N(1) | 2i | 0.7781(4) | 1.0544(3) | 0.1104(2) | 0.024(1) | 0.038(2) | 0.029(1) | −0.010(1) | −0.002(1) | 0.007(1) |
| N(2) | 2i | 1.5581(4) | 0.5387(4) | 0.2259(2) | 0.028(2) | 0.046(2) | 0.030(2) | −0.009(1) | −0.006(1) | 0.010(1) |
| C(1) | 2i | 1.4694(4) | 0.5986(4) | 0.1629(2) | 0.025(2) | 0.038(2) | 0.026(2) | −0.009(1) | −0.002(1) | 0.007(1) |
| C(2) | 2i | 1.2713(4) | 0.6462(4) | 0.1743(2) | 0.027(2) | 0.032(2) | 0.024(2) | −0.009(1) | −0.005(1) | 0.006(1) |
| C(3) | 2i | 1.1705(5) | 0.6283(4) | 0.2524(2) | 0.027(2) | 0.037(2) | 0.028(2) | −0.010(1) | −0.003(1) | 0.006(1) |
| C(4) | 2i | 1.2619(5) | 0.5684(4) | 0.3177(2) | 0.031(2) | 0.039(2) | 0.025(2) | −0.011(1) | −0.005(1) | 0.008(1) |
| C(5) | 2i | 1.4595(5) | 0.5253(4) | 0.3025(2) | 0.033(2) | 0.042(2) | 0.027(2) | −0.009(1) | −0.008(1) | 0.007(1) |
| C(6) | 2i | 1.1487(5) | 0.5461(5) | 0.3994(2) | 0.035(2) | 0.054(2) | 0.025(2) | −0.016(2) | −0.005(2) | 0.009(2) |
| C(7) | 2i | 1.1640(4) | 0.7097(4) | 0.1059(2) | 0.023(2) | 0.034(2) | 0.022(2) | −0.003(1) | −0.000(1) | 0.006(1) |
| C(8) | 2i | 1.5779(5) | 0.4607(6) | 0.3666(2) | 0.032(2) | 0.080(3) | 0.035(2) | −0.010(2) | −0.012(2) | 0.017(2) |
| C(9) | 2i | 1.5966(5) | 0.6044(6) | 0.0810(2) | 0.030(2) | 0.073(3) | 0.033(2) | −0.015(2) | −0.003(2) | 0.016(2) |
| C(10) | 2i | 0.5997(5) | 1.0746(5) | 0.1045(2) | 0.030(2) | 0.054(2) | 0.027(2) | −0.014(2) | −0.006(1) | 0.011(2) |
| C(11) | 2i | 0.4592(5) | 1.0736(5) | 0.1711(2) | 0.023(2) | 0.063(2) | 0.032(2) | −0.013(2) | −0.003(1) | 0.011(2) |
| C(12) | 2i | 0.4955(5) | 1.0498(4) | 0.2510(2) | 0.028(2) | 0.034(2) | 0.030(2) | −0.010(1) | −0.001(1) | 0.004(1) |
| C(13) | 2i | 0.6784(5) | 1.0340(4) | 0.2580(2) | 0.029(2) | 0.047(2) | 0.025(2) | −0.012(1) | −0.001(1) | 0.002(1) |
| C(14) | 2i | 0.8109(5) | 1.0397(4) | 0.1879(2) | 0.025(2) | 0.044(2) | 0.028(2) | −0.013(1) | −0.002(1) | 0.001(1) |
| C(15) | 2i | 0.3506(5) | 1.0380(4) | 0.3247(2) | 0.027(2) | 0.037(2) | 0.027(2) | −0.009(1) | 0.000(1) | 0.004(1) |
| C(16) | 2i | 0.1585(5) | 1.1195(5) | 0.3287(2) | 0.029(2) | 0.066(2) | 0.034(2) | −0.011(2) | −0.002(2) | 0.021(2) |
| C(17) | 2i | 0.0240(5) | 1.1042(5) | 0.3968(2) | 0.021(2) | 0.069(2) | 0.039(2) | −0.007(2) | −0.003(2) | 0.022(2) |
| C(18) | 2i | 0.0729(4) | 1.0088(4) | 0.4638(2) | 0.026(2) | 0.039(2) | 0.026(2) | −0.008(1) | 0.002(1) | 0.004(1) |
| C(19) | 2i | 0.2673(5) | 0.9286(6) | 0.4603(2) | 0.028(2) | 0.076(3) | 0.037(2) | −0.008(2) | −0.001(2) | 0.031(2) |
| C(20) | 2i | 0.4020(5) | 0.9431(6) | 0.3924(2) | 0.022(2) | 0.073(3) | 0.043(2) | −0.005(2) | −0.000(2) | 0.024(2) |
Source of material
A mixture of Ni(OAc)2·4H2O (0.1 mmol, 0.0248 g), 4,4′-bis(pyrid-4-yl)biphenyl (0.1 mmol, 0.0308 g), 2,6-dimethyl-pyridine-3,5-dicarboxylic acid (0.1 mmol, 0.0195 g) was dissolved in 10 mL H2O. Then the solution was heated in a 25 mL Teflon-lined autoclave under autogenous pressure at 403 K for four days. After cooling to room temperature, the green block crystals that formed were collected.
Discussion
In recent years, research on coordination complexes has made considerable progress in the fields of supramolecular chemistry and crystal engineering, owing to their intriguing architectures and applications, such as gas storage [1], catalysis [2], magnetism [3] and luminescence [4]. Studies in this field have been focused on the rational design and synthesis of novel frameworks and the relationships between their structures and properties. The observation of coordination complexes constructed from organic ligands and metal ions through a self-assembly route has been explored intensively, and many efforts have been devoted to use of N- and O-donor organic ligands as co-ligands to bridge metal ions to form infinite network structures [5]. However, it is still a great challenge in crystal engineering to obtain designed and predictable frameworks with potential properties assembled by coordination bonds and/or weak supramolecular interactions such as hydrogen bonds, π–π stacking, and host–guest ionic interactions, etc. [6].
The asymmetric unit of the title structure contains one half of a Ni(II) ion, one half of a 4,4′-bis(pyrid-4-yl)biphenyl and one 2,6-dimethyl-pyridine-3,5-dicarboxylate anion as well as one coordinated and one uncoordinated water molecule. The dipyridyl ligand connects nickel atoms to a chain structure (see the figure). The nickel atom is six-coordinated by two oxygen atoms from two 2,6-dimethyl-pyridine-3,5-dicarboxylate ligands, by two nitrogen atom from 4,4′-bis(pyrid-4-yl)biphenyl ligands and two water ligands. The Ni—O bond lengths range from 2.055(2)–2.081(2) Å, the Ni—N bond lengths is 2.132(3) Å. The bond angles of O—Ni—O are in the range of 86.06(8)° to 180°. There are intern molecular hydrogen bonds between coordinated and uncoordinated water molecules (d(O(2)—H(4W)⋯O(1)#4) = 2.696(3) Å). Water molecules are connected with adjacent 4,4′-bis(pyrid-4-yl)biphenyl ligands and 2,6-dimethyl-pyridine-3,5-dicarboxylate anions by further hydrogen bonds (d(O(1)—H(1W)⋯O(4)) = 2.721(3) Å, d(O(1)—H(2W)⋯N(2)#3) = 2.859(4) Å, d(O(2)—H(3W)⋯O(4)#1) = 2.691(3) Å), d(O(5)—H(5)⋯O(6)#5) = 2.608(4) Å). Symmetry codes: #1 −x+2, −y+2, −z; #3 x−1, y, z; #4 x, y+1, z; #5 −x+2, −y+1, −z+1.
References
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©2016 Shi-Hui Li et al., published by De Gruyter.
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.
Artikel in diesem Heft
- Cover and Frontmatter
- Crystal structure of rac-4,4,4-trifluoro-3-hydroxy-3-methylbutanoic acid, C5H7O2F3
- Crystal structure of 5-methyl-2-phenyl-1,3-dioxane-5-carboxylic acid, C12H14O4
- Crystal structure of ethyl 2-(2-(2-(4-chlorophenyl)-3-methylbutanamido)thiazol-4-yl)acetate, C18H21ClN2O3S
- The crystal structure of (4E,11E,31E,38E)-1,4,12,15,18,26,31,39-Octaaza-7,21,24-trihydroxy-penta-cyclo[13·13·13·16,10·120,24·133,37]tetratetraconta-4,6(44),7,9,11,18,20(43),21,23,25,31,33(42),34,36,38-pentadecaene, C36H42N8O3
- Crystal structure of poly[diaqua-μ5-4-(3,5-dicarboxylato-κ3O1:O2:O3-phenoxy)phthalato-κ3O5,O7:O8)(μ2-4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)dicobalt(II)] C24H16N3O11Co2
- Crystal structure of catena-poly[(μ2-acetamido-benzoato-κ2O:O′)triphenyltin(IV)], C27H23NO3Sn
- Crystal structure of chlorido(2,2′-((1E,1′E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanylylidene))bis(methylylidene))diphenolato-κ4N,N′,O,O′)iron(III), C20H20ClFeN2O2
- Crystal structure of (E)-3-(4-tert-butyl)phenyl)-1-(3-chlorophenyl)prop-2-en-1-one, C18H17CIO
- Crystal structure of trans-1,2-bis(pyridinium-4-yl)ethylene–2-carboxy-4-methylbenzoate (1/2), C30H26N2O8
- Crystal structure of poly[aqua-ethylenediamine-tetraacetatolead(II)zinc(II)]
- Crystal structure of (E)-2-((2-(2,4-dinitrophenyl)hydrazono)methyl)-4-nitrophenol — triethylamine (2/1), C32H33N11O14
- Crystal structure of catena-poly[diaqua-bis-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)cadmium(II)] dihydrate, C26H24N2O12Cd
- Crystal structure of 2-(ethoxycarbonyl)-2-(2-nitro-1-phenylethyl)-3-oxopyrrolidinium chloride, C15H19N2O5Cl
- Crystal structure of 4-((pyridin-4-ylmethyl)sulfinyl)pyridine, C11H10N2OS
- Crystal structure of 2,5-diethoxy-1,4-bis[2-(quinoline)ethenyl]benzene, C32H28N2O2
- Crystal structure of diaqua(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)tetrakis(3-carboxy-5-ethylpyridine-2-carboxylato-κ2N,O)dizinc(II), C54H50N8O18Zn2
- Crystal structure of a poly[bis(3,4,5,6-tetrachlorophthalato)neodym(III)potassium(I)] — 4,4′-bipyridine — water (1/1/5.5)
- The second polymorph of triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide, C9H18N4S3
- Crystal structure of 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid dihydrate, C14H16N2O6
- Crystal structure of the catena-poly[bis(1H-imidazole-κN)-(μ2-furan-2,5-dicarboxylato-κ2O1:O4)manganese(II)]monohydrate, C12H12MnN4O6
- Crystal structure of (acetylacetonato-κ2O:O′)bis-((1-(2-hydroxyphenyl)-3-(pyridin-2-yl)prop-2-en-1-one)-κ2C,N)iridium(III), C33H27IrN2O6
- Crystal structure of 1-benzyl-3-(4-methylpyridin-2-yl)-1H-imidazol-3-ium hexafluorophosphate, C16H16F6N3P
- Crystal structure of tetraethylammonium 3,5-dinitrosalicylate, C15H23N3O7
- Crystal structure of 4-[5-(4-fluorophenyl)-3-(4-hydroxyphenyl)-4,5-dihydropyrazol-1-yl] benzenesulfonamide, C21H18FN3O3S
- Crystal structure of 2,4-dichlorobenzene anhydride, C14H6Cl4O3
- Crystal structure of bis(2-hydroxy-2-phenylacetato-κ2O,O′)bis(pyridine-κN)nickel(II), C26H24N2NiO6
- Crystal structure of (E)-4-nitro-2-(((3-(tetrahydro-8λ4-[1,3,2]oxazaborolo[2,3-b][1,3,2]oxaborol-8-yl)phenyl)imino)methyl)phenol – water (1/2), C17H18BN3O5·2H2O
- Crystal structure of 5-(4-carboxyphenoxy)-nicotinic acid, C13H9NO5
- Crystal structure of catena-poly[hexaaquabis(μ2-3-nitrophthalate-κ2O:O′)-(μ2-1,4-bis(4-pyridylmethyl)piperazine-κ2N:N′)dimanganese(II)] dihydrate, C32H42Mn2N6O20
- Crystal structure of diaquabis(bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate-κ4O, O′:/O′′,O′′′)bis-(2,2′-bipyridine-κ2N, N′)dicadmium(II) hydrate
- Crystal structure of (R)-1-(1-(6-fluorobenzo[d]thiazol-2-yl)ethyl)-3-phenylthiourea
- Crystal structure of poly[(μ2-1,4-bis((1H-imidiazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-(1,2-phenylenebis(oxy)dibenzoato-κ4O,O′:O′′,O′′′)nickel(II)], C34H26O6N4Ni
- Crystal structure of 3′,4′,5-trihydroxy-3,7-dimethoxyflavone, C17H14O7
- Crystal structure of n-butyl-chlorido-bis[N-sec-butyl,N-n-propyl-carbamodithioato κ2S,S′]-tin(IV), C20H41ClN2S4Sn
- Crystal structure of poly[bis(μ4-4,4′-(1,2-phenylenebis(oxy))dibenzoato-κ4O:O′:O′′:O′′′)bis(μ3-4,4′-(1,2-phenylenebis(oxy))dibenzoato–κ3O:O′:O′′)(μ2-1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazole-κ2N:N′)tetracobalt(II)], C94H62O24N4Co4
- Crystal structure of catenapoly[diaqua-(μ24,4′-bipyridine)-κ2N:N′)-bis(2,6-difluorobenzoate)-κO)nickel(II)] ethanol monosolvate, C28H30F4N2O8Ni
- Crystal structure of 2-(9H-fluoren-9-ylidene)hydrazine-1-carbothioamide, C14H11N3S
- Crystal structure of 2-(4-methoxyphenyl)-2,3-dihydro-1H-perimidine, C18H16N2O
- Crystal structure of catena-poly[diaquabis(μ2-3-carboxybenzene-1,2-dicarboxylato-1:2κ2O:O′)-(μ2-1,4-bis(2-ethylbenzimidazol-1-ylmethyl)-benzene-1:1′κ2N:N′)dizinc(II)], [Zn2(C26H26N4)(C9H4O6)2(H2O)2]
- Crystal structure of diaquabis(phenoxyacetato-κ2O,O′)-zinc(II), C16H18O8Zn
- Crystal structure of 4-(1H-imidazol-1-yl)-6-pyrimidinylferrocene, C17H14FeN4
- Crystal structure of [2-(4-methoxyphenyl)pyrazine-κ2C,N) chlorido[N,N′-bis-(2,6-diisopropyl-phenyl)imidazol-2-ylidene-κC)] palladium(II), C38H45ClN4OPd
- Crystal structure of 2-(4-acetyl-2,6-dimethyl-phenyl)-5,6-dichloro-isoindole-1,3-dione, C18H13Cl2NO3
- Crystal structure of 4,4′-bipyridin-1-ium 3,3′,5′-tricarboxy-[1,1′-biphenyl]-2-carboxylate, (C26H18N2O8)
- Crystal structure of catena-poly[diaqua-μ2-4,4′-biphenyl-4,4′-diyldipyridine-κ2N:N′-bis(5-carboxy-2,6-dimethylpyridine-3-carboxylato-κO)nickel(II)] dihydrate, C40H40N4O12Ni
- Crystal structure of poly-[μ2-4,4′-bipyridine-κ2N:N′−μ3-thiophene-2,3-di-carboxylato-κ4O,O′, O′′:O′′′ -cadmium(II)]
- Crystal structure of hexaaquamanganese(II) bis(3-carboxythiophene-2-carboxylate) C12H18MnO14S2
- Crystal structure of 4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoic acid, C14H10N4O2
- Crystal structure of (E)-2-(benzo[d]thiazol-2-yl)-3-(pyridin-3-yl)acrylonitrile)
- Crystal structure of catena-poly[2,2′-bipyridinyl-6,6′-dicarboxylato-κ4N,N′,O,O′)-(μ2-2,2′-bipyridinyl-6′-carboxyl-6-carboxylato-κ5N,N′,O,O′:O′′)samarium(III)] monohydrate, C24H13N4O8Sm · H2O
- Crystal structure of catena-poly[bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato)-κ2N:O)copper(II)] dihydrate, C28H22N8O6Cu
- Crystal structure of catena-poly[tetraaqua-(μ2-4,4′-bipyridine-k2N:N′)-zinc(II)] fumarate tetrahydrate, C14H26N2O12Zn
- Crystal structure of triaqua-(1,10-phenanthroline)-(dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoato) cobalt(II)dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoate, C72H82Co2N16O42
- Crystal structure of poly[dibromido-(μ2–4,4′-bis-(pyrid-4-yl)biphenyl-κ2N:N′)lead(II)], C22H16N2PbBr2
- Crystal structure of catena-poly[diaqua-bis(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)-cobalt(II)]dihydrate, C26H24N2O12Co
- Crystal structure of 5-(4-pyridyl)pyrimidine–4,4′-bipyridine–1,3,5-benzenetriol–water (1:1:1:1), C25H23N5O4
- Crystal structure of 5-hydroxy-4-((4-hydroxyphenyl)imino)naphthalen-1(4H)-one monohydrate, C16H11NO3 · 0.5H2O
- Crystal structure of 2-amino-N-(4-methoxyphenyl)benzamide, C14H14N2O2
- Crystal structure of (2,5-dihydroxyphenyl)-(4-hydroxy-3,5-dimethoxyphenyl)methanone, C15H14O6
- Crystal structure of dichlorido[bis(2-hydroxyethyl)5′-([2,2′:6′,2′′-terpyridin]-4′-yl)-[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato]zinc(II), C39H31Cl2N3O6Zn
- Crystal structure of bis[4-(3-carboxy-6-fluoro-1-(4-fluorophenyl)-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium] benzene-1,4-dicarboxylate (C20H18F2N3O3)2(C8H4O4), C48H40F4N6O10
- Crystal structure of (2,5-dihydroxyphenyl)-(4-methoxyphenyl)methanone, C14H12O4
- Crystal structure of photochromic 1-(2-methyl-5-phenyl-3-thienyl-2-[2-methyl-5-(4-ethoxylphenyl)-3-thienyl] 3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H22F6OS2
- Crystal structure of poly[diaquabis(μ2-biphenyl-2,4′-dicarboxylato-κ2O:O′)tris(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)dicobalt(II)] monohydrat, C82H64N12O11Co2
- Crystal structure of 2-amino-4-(3,4-difluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12N2O2F2
- Crystal structure of poly[(di-μ2-aqua-κ2O:O)bis(μ5-oxalato-1:2κ2O1; 1κ1O2; 3:4:5κ3O3; 3κ1O4)(μ4-oxalato-1:2κ2O1; 2:3κ2O2; 3:4κ2O3; 4:1κ2O4)dizinc(II)disodium(I)]
- Crystal structure of tetraethylammonium hexachloridotantalate(V), C8H20Cl6NTa
- Crystal structure of (E)-2,4-dibromo-6-(((2-nitrophenyl)imino)methyl)phenol, C13H8Br2N2O3
- The crystal structure of 6-chloro-2,4-diphenylquinoline
- Crystal structure of (E)-2-(((1,10-phenanthrolin-5-yl)imino)methyl)-5-methylphenol monohydrate, C20H15N3O·H2O
- Crystal structure of tris(3-(2-pyridyl)pyrazole)zinc(II)tetrachlorido zincate(II), C24H21Cl4N9Zn2
- Crystal structure of 4-chloro-N,N-diethyl-6-(piperidin-1-yl)-1,3,5-triazin-2-amine, C12H20ClN5
- The crystal structure of 4-allyl-5-benzyl-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H13N3O
- Crystal structure of diethyl 2-(((2-(pyridin-3-ylthio)phenyl)amino)methylene)malonate, C19H20N2O4S
- Crystal structure of fac-tricarbonyl(2-(isopropylimino)methyl-5-methylphenolatido-κ2N,O)(pyridine-κN)rhenium(I), C19H19N2O4Re
- Crystal structure of 1,3,6,8-tetrakis(p-tolylthio)pyrene, C44H34S4
- Crystal structure of catena-poly-(diaqua-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)-(4-methylphthalato-κ2O,O′)-cobalt(II)trihydrate, C21H26CoN2O9
- Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re
- Crystal structure of 3-(thiophen-2-yl)-5-(p-tolyl)-4,5-dihydro-1H-pyrazole-1-carboxamide
- Crystal structure of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate(II), [C6H11N2]2[CdBr4]
- Crystal structure of N′-(adamantan-2-ylidene)-isonicotinohydrazide, C16H19N3O
- Crystal structure of trans-tetraaquabis(4-(pyridin-4-ylsulfonyl)pyridine-κN)cobalt(II) diperchlorate dihydrate, C20H28Cl2CoN4O18S2
- Crystal structure of (Z)-4-(furan-2-yl(p-tolylamino)methylene)-3-methyl-1-p-tolyl-1H-pyrazol-5(4H)-one, C23H21N3O2
- Crystal structure of 2-[(4-fluorobenzyl)sulfanyl]-4-(2-methylpropyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C16H16FN3OS
- Crystal structure of poly[octaaqua-tris(benzene-1,2,4,5-tetracarboxylato)tetralanthanum(III)] hexahydrate, C30H34La4O38
- Crystal structure of trans-tetraaqua-bis(4,4′-sulfonyldipyridine-κN)zinc(II) diperchlorate dihydrate, C20H28Cl2ZnN4O18S2
- Crystal structure of 4-nitro-thiophene-2-carboxylic acid, a structure with a Z′ = 4, C5H3NO4S
- Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se4
- Crystal structure of 5-(adamantan-1-yl)-3-[(4-chloroanilino)methyl]-2,3-dihydro-1,3,4-oxadiazole-2-thione, C19H22ClN3OS
- Crystal structure of hexaaquamagnesium(II) 5,5′-bitetrazole-1,1′-diolate, C2H12N8O8Mg
- The crystal structure of catena-poly[(μ2-1,1′-benzene-1,4-diylbis(1H-benzimidazole-κ2N:N′)silver(I)] nitrate, C20H14N5AgO3
- The crystal structure of 1-(2-(4-chlorophenoxy)-4-chlorophenyl)ethanone, C14H10Cl2O2
- The crystal structure of 3,5-dinitro-1,3,5-oxadiazinane, C3H6N4O5
- Crystal structure of methyl 5-methoxy 1H-indole-2-carboxylate, C11H11NO3
- Crystal structure of (Z)-1-(((3-acetyl-2-hydroxyphenyl)amino)methylene)naphthalen-2(1H)-one, C19H15NO3
- Crystal structure of (Z)-5-(4-chlorobenzylidene)-2-thioxothiazolidin-4-one —dimethylsulfoxide (1:1), C12H12ClNO2S3
- Crystal structure of 5,5′-((4-(trifluoromethyl)phenyl)methylene)bis(1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione) – diethylamine – dichloromethane (1/1/1) C25H32Cl2F3N5O6
- Crystal structure of 2-(dimethylsulfanylidene)-N-(4-methoxyphenyl)-3-oxo-3-phenylpropanamide
- Crystal structure of (1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)platinum(II), C14H8N4PtS2
- Crystal structure of di(μ2-chlorido)bis[2-(2-pyridyl)phenyl-κ2N,C1]dipalladium(II), C22H16Cl2N2Pd2
- Crystal structure of trans-dibromidodi(pyridine-κN)palladium(II), PdBr2(C5H5N)2
Artikel in diesem Heft
- Cover and Frontmatter
- Crystal structure of rac-4,4,4-trifluoro-3-hydroxy-3-methylbutanoic acid, C5H7O2F3
- Crystal structure of 5-methyl-2-phenyl-1,3-dioxane-5-carboxylic acid, C12H14O4
- Crystal structure of ethyl 2-(2-(2-(4-chlorophenyl)-3-methylbutanamido)thiazol-4-yl)acetate, C18H21ClN2O3S
- The crystal structure of (4E,11E,31E,38E)-1,4,12,15,18,26,31,39-Octaaza-7,21,24-trihydroxy-penta-cyclo[13·13·13·16,10·120,24·133,37]tetratetraconta-4,6(44),7,9,11,18,20(43),21,23,25,31,33(42),34,36,38-pentadecaene, C36H42N8O3
- Crystal structure of poly[diaqua-μ5-4-(3,5-dicarboxylato-κ3O1:O2:O3-phenoxy)phthalato-κ3O5,O7:O8)(μ2-4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)dicobalt(II)] C24H16N3O11Co2
- Crystal structure of catena-poly[(μ2-acetamido-benzoato-κ2O:O′)triphenyltin(IV)], C27H23NO3Sn
- Crystal structure of chlorido(2,2′-((1E,1′E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanylylidene))bis(methylylidene))diphenolato-κ4N,N′,O,O′)iron(III), C20H20ClFeN2O2
- Crystal structure of (E)-3-(4-tert-butyl)phenyl)-1-(3-chlorophenyl)prop-2-en-1-one, C18H17CIO
- Crystal structure of trans-1,2-bis(pyridinium-4-yl)ethylene–2-carboxy-4-methylbenzoate (1/2), C30H26N2O8
- Crystal structure of poly[aqua-ethylenediamine-tetraacetatolead(II)zinc(II)]
- Crystal structure of (E)-2-((2-(2,4-dinitrophenyl)hydrazono)methyl)-4-nitrophenol — triethylamine (2/1), C32H33N11O14
- Crystal structure of catena-poly[diaqua-bis-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)cadmium(II)] dihydrate, C26H24N2O12Cd
- Crystal structure of 2-(ethoxycarbonyl)-2-(2-nitro-1-phenylethyl)-3-oxopyrrolidinium chloride, C15H19N2O5Cl
- Crystal structure of 4-((pyridin-4-ylmethyl)sulfinyl)pyridine, C11H10N2OS
- Crystal structure of 2,5-diethoxy-1,4-bis[2-(quinoline)ethenyl]benzene, C32H28N2O2
- Crystal structure of diaqua(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)tetrakis(3-carboxy-5-ethylpyridine-2-carboxylato-κ2N,O)dizinc(II), C54H50N8O18Zn2
- Crystal structure of a poly[bis(3,4,5,6-tetrachlorophthalato)neodym(III)potassium(I)] — 4,4′-bipyridine — water (1/1/5.5)
- The second polymorph of triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide, C9H18N4S3
- Crystal structure of 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid dihydrate, C14H16N2O6
- Crystal structure of the catena-poly[bis(1H-imidazole-κN)-(μ2-furan-2,5-dicarboxylato-κ2O1:O4)manganese(II)]monohydrate, C12H12MnN4O6
- Crystal structure of (acetylacetonato-κ2O:O′)bis-((1-(2-hydroxyphenyl)-3-(pyridin-2-yl)prop-2-en-1-one)-κ2C,N)iridium(III), C33H27IrN2O6
- Crystal structure of 1-benzyl-3-(4-methylpyridin-2-yl)-1H-imidazol-3-ium hexafluorophosphate, C16H16F6N3P
- Crystal structure of tetraethylammonium 3,5-dinitrosalicylate, C15H23N3O7
- Crystal structure of 4-[5-(4-fluorophenyl)-3-(4-hydroxyphenyl)-4,5-dihydropyrazol-1-yl] benzenesulfonamide, C21H18FN3O3S
- Crystal structure of 2,4-dichlorobenzene anhydride, C14H6Cl4O3
- Crystal structure of bis(2-hydroxy-2-phenylacetato-κ2O,O′)bis(pyridine-κN)nickel(II), C26H24N2NiO6
- Crystal structure of (E)-4-nitro-2-(((3-(tetrahydro-8λ4-[1,3,2]oxazaborolo[2,3-b][1,3,2]oxaborol-8-yl)phenyl)imino)methyl)phenol – water (1/2), C17H18BN3O5·2H2O
- Crystal structure of 5-(4-carboxyphenoxy)-nicotinic acid, C13H9NO5
- Crystal structure of catena-poly[hexaaquabis(μ2-3-nitrophthalate-κ2O:O′)-(μ2-1,4-bis(4-pyridylmethyl)piperazine-κ2N:N′)dimanganese(II)] dihydrate, C32H42Mn2N6O20
- Crystal structure of diaquabis(bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate-κ4O, O′:/O′′,O′′′)bis-(2,2′-bipyridine-κ2N, N′)dicadmium(II) hydrate
- Crystal structure of (R)-1-(1-(6-fluorobenzo[d]thiazol-2-yl)ethyl)-3-phenylthiourea
- Crystal structure of poly[(μ2-1,4-bis((1H-imidiazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-(1,2-phenylenebis(oxy)dibenzoato-κ4O,O′:O′′,O′′′)nickel(II)], C34H26O6N4Ni
- Crystal structure of 3′,4′,5-trihydroxy-3,7-dimethoxyflavone, C17H14O7
- Crystal structure of n-butyl-chlorido-bis[N-sec-butyl,N-n-propyl-carbamodithioato κ2S,S′]-tin(IV), C20H41ClN2S4Sn
- Crystal structure of poly[bis(μ4-4,4′-(1,2-phenylenebis(oxy))dibenzoato-κ4O:O′:O′′:O′′′)bis(μ3-4,4′-(1,2-phenylenebis(oxy))dibenzoato–κ3O:O′:O′′)(μ2-1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazole-κ2N:N′)tetracobalt(II)], C94H62O24N4Co4
- Crystal structure of catenapoly[diaqua-(μ24,4′-bipyridine)-κ2N:N′)-bis(2,6-difluorobenzoate)-κO)nickel(II)] ethanol monosolvate, C28H30F4N2O8Ni
- Crystal structure of 2-(9H-fluoren-9-ylidene)hydrazine-1-carbothioamide, C14H11N3S
- Crystal structure of 2-(4-methoxyphenyl)-2,3-dihydro-1H-perimidine, C18H16N2O
- Crystal structure of catena-poly[diaquabis(μ2-3-carboxybenzene-1,2-dicarboxylato-1:2κ2O:O′)-(μ2-1,4-bis(2-ethylbenzimidazol-1-ylmethyl)-benzene-1:1′κ2N:N′)dizinc(II)], [Zn2(C26H26N4)(C9H4O6)2(H2O)2]
- Crystal structure of diaquabis(phenoxyacetato-κ2O,O′)-zinc(II), C16H18O8Zn
- Crystal structure of 4-(1H-imidazol-1-yl)-6-pyrimidinylferrocene, C17H14FeN4
- Crystal structure of [2-(4-methoxyphenyl)pyrazine-κ2C,N) chlorido[N,N′-bis-(2,6-diisopropyl-phenyl)imidazol-2-ylidene-κC)] palladium(II), C38H45ClN4OPd
- Crystal structure of 2-(4-acetyl-2,6-dimethyl-phenyl)-5,6-dichloro-isoindole-1,3-dione, C18H13Cl2NO3
- Crystal structure of 4,4′-bipyridin-1-ium 3,3′,5′-tricarboxy-[1,1′-biphenyl]-2-carboxylate, (C26H18N2O8)
- Crystal structure of catena-poly[diaqua-μ2-4,4′-biphenyl-4,4′-diyldipyridine-κ2N:N′-bis(5-carboxy-2,6-dimethylpyridine-3-carboxylato-κO)nickel(II)] dihydrate, C40H40N4O12Ni
- Crystal structure of poly-[μ2-4,4′-bipyridine-κ2N:N′−μ3-thiophene-2,3-di-carboxylato-κ4O,O′, O′′:O′′′ -cadmium(II)]
- Crystal structure of hexaaquamanganese(II) bis(3-carboxythiophene-2-carboxylate) C12H18MnO14S2
- Crystal structure of 4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoic acid, C14H10N4O2
- Crystal structure of (E)-2-(benzo[d]thiazol-2-yl)-3-(pyridin-3-yl)acrylonitrile)
- Crystal structure of catena-poly[2,2′-bipyridinyl-6,6′-dicarboxylato-κ4N,N′,O,O′)-(μ2-2,2′-bipyridinyl-6′-carboxyl-6-carboxylato-κ5N,N′,O,O′:O′′)samarium(III)] monohydrate, C24H13N4O8Sm · H2O
- Crystal structure of catena-poly[bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato)-κ2N:O)copper(II)] dihydrate, C28H22N8O6Cu
- Crystal structure of catena-poly[tetraaqua-(μ2-4,4′-bipyridine-k2N:N′)-zinc(II)] fumarate tetrahydrate, C14H26N2O12Zn
- Crystal structure of triaqua-(1,10-phenanthroline)-(dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoato) cobalt(II)dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoate, C72H82Co2N16O42
- Crystal structure of poly[dibromido-(μ2–4,4′-bis-(pyrid-4-yl)biphenyl-κ2N:N′)lead(II)], C22H16N2PbBr2
- Crystal structure of catena-poly[diaqua-bis(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)-cobalt(II)]dihydrate, C26H24N2O12Co
- Crystal structure of 5-(4-pyridyl)pyrimidine–4,4′-bipyridine–1,3,5-benzenetriol–water (1:1:1:1), C25H23N5O4
- Crystal structure of 5-hydroxy-4-((4-hydroxyphenyl)imino)naphthalen-1(4H)-one monohydrate, C16H11NO3 · 0.5H2O
- Crystal structure of 2-amino-N-(4-methoxyphenyl)benzamide, C14H14N2O2
- Crystal structure of (2,5-dihydroxyphenyl)-(4-hydroxy-3,5-dimethoxyphenyl)methanone, C15H14O6
- Crystal structure of dichlorido[bis(2-hydroxyethyl)5′-([2,2′:6′,2′′-terpyridin]-4′-yl)-[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato]zinc(II), C39H31Cl2N3O6Zn
- Crystal structure of bis[4-(3-carboxy-6-fluoro-1-(4-fluorophenyl)-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium] benzene-1,4-dicarboxylate (C20H18F2N3O3)2(C8H4O4), C48H40F4N6O10
- Crystal structure of (2,5-dihydroxyphenyl)-(4-methoxyphenyl)methanone, C14H12O4
- Crystal structure of photochromic 1-(2-methyl-5-phenyl-3-thienyl-2-[2-methyl-5-(4-ethoxylphenyl)-3-thienyl] 3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H22F6OS2
- Crystal structure of poly[diaquabis(μ2-biphenyl-2,4′-dicarboxylato-κ2O:O′)tris(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)dicobalt(II)] monohydrat, C82H64N12O11Co2
- Crystal structure of 2-amino-4-(3,4-difluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12N2O2F2
- Crystal structure of poly[(di-μ2-aqua-κ2O:O)bis(μ5-oxalato-1:2κ2O1; 1κ1O2; 3:4:5κ3O3; 3κ1O4)(μ4-oxalato-1:2κ2O1; 2:3κ2O2; 3:4κ2O3; 4:1κ2O4)dizinc(II)disodium(I)]
- Crystal structure of tetraethylammonium hexachloridotantalate(V), C8H20Cl6NTa
- Crystal structure of (E)-2,4-dibromo-6-(((2-nitrophenyl)imino)methyl)phenol, C13H8Br2N2O3
- The crystal structure of 6-chloro-2,4-diphenylquinoline
- Crystal structure of (E)-2-(((1,10-phenanthrolin-5-yl)imino)methyl)-5-methylphenol monohydrate, C20H15N3O·H2O
- Crystal structure of tris(3-(2-pyridyl)pyrazole)zinc(II)tetrachlorido zincate(II), C24H21Cl4N9Zn2
- Crystal structure of 4-chloro-N,N-diethyl-6-(piperidin-1-yl)-1,3,5-triazin-2-amine, C12H20ClN5
- The crystal structure of 4-allyl-5-benzyl-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H13N3O
- Crystal structure of diethyl 2-(((2-(pyridin-3-ylthio)phenyl)amino)methylene)malonate, C19H20N2O4S
- Crystal structure of fac-tricarbonyl(2-(isopropylimino)methyl-5-methylphenolatido-κ2N,O)(pyridine-κN)rhenium(I), C19H19N2O4Re
- Crystal structure of 1,3,6,8-tetrakis(p-tolylthio)pyrene, C44H34S4
- Crystal structure of catena-poly-(diaqua-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)-(4-methylphthalato-κ2O,O′)-cobalt(II)trihydrate, C21H26CoN2O9
- Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re
- Crystal structure of 3-(thiophen-2-yl)-5-(p-tolyl)-4,5-dihydro-1H-pyrazole-1-carboxamide
- Crystal structure of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate(II), [C6H11N2]2[CdBr4]
- Crystal structure of N′-(adamantan-2-ylidene)-isonicotinohydrazide, C16H19N3O
- Crystal structure of trans-tetraaquabis(4-(pyridin-4-ylsulfonyl)pyridine-κN)cobalt(II) diperchlorate dihydrate, C20H28Cl2CoN4O18S2
- Crystal structure of (Z)-4-(furan-2-yl(p-tolylamino)methylene)-3-methyl-1-p-tolyl-1H-pyrazol-5(4H)-one, C23H21N3O2
- Crystal structure of 2-[(4-fluorobenzyl)sulfanyl]-4-(2-methylpropyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C16H16FN3OS
- Crystal structure of poly[octaaqua-tris(benzene-1,2,4,5-tetracarboxylato)tetralanthanum(III)] hexahydrate, C30H34La4O38
- Crystal structure of trans-tetraaqua-bis(4,4′-sulfonyldipyridine-κN)zinc(II) diperchlorate dihydrate, C20H28Cl2ZnN4O18S2
- Crystal structure of 4-nitro-thiophene-2-carboxylic acid, a structure with a Z′ = 4, C5H3NO4S
- Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se4
- Crystal structure of 5-(adamantan-1-yl)-3-[(4-chloroanilino)methyl]-2,3-dihydro-1,3,4-oxadiazole-2-thione, C19H22ClN3OS
- Crystal structure of hexaaquamagnesium(II) 5,5′-bitetrazole-1,1′-diolate, C2H12N8O8Mg
- The crystal structure of catena-poly[(μ2-1,1′-benzene-1,4-diylbis(1H-benzimidazole-κ2N:N′)silver(I)] nitrate, C20H14N5AgO3
- The crystal structure of 1-(2-(4-chlorophenoxy)-4-chlorophenyl)ethanone, C14H10Cl2O2
- The crystal structure of 3,5-dinitro-1,3,5-oxadiazinane, C3H6N4O5
- Crystal structure of methyl 5-methoxy 1H-indole-2-carboxylate, C11H11NO3
- Crystal structure of (Z)-1-(((3-acetyl-2-hydroxyphenyl)amino)methylene)naphthalen-2(1H)-one, C19H15NO3
- Crystal structure of (Z)-5-(4-chlorobenzylidene)-2-thioxothiazolidin-4-one —dimethylsulfoxide (1:1), C12H12ClNO2S3
- Crystal structure of 5,5′-((4-(trifluoromethyl)phenyl)methylene)bis(1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione) – diethylamine – dichloromethane (1/1/1) C25H32Cl2F3N5O6
- Crystal structure of 2-(dimethylsulfanylidene)-N-(4-methoxyphenyl)-3-oxo-3-phenylpropanamide
- Crystal structure of (1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)platinum(II), C14H8N4PtS2
- Crystal structure of di(μ2-chlorido)bis[2-(2-pyridyl)phenyl-κ2N,C1]dipalladium(II), C22H16Cl2N2Pd2
- Crystal structure of trans-dibromidodi(pyridine-κN)palladium(II), PdBr2(C5H5N)2