Home Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re
Article Open Access

Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re

  • Amanda-Lee Manicum EMAIL logo , Marietjie Schutte-Smith , Hendrik G. Visser , Carla Pretorius and Andreas Roodt
Published/Copyright: February 11, 2016
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 231 Issue 1

Abstract

C16H21O8N2F6Re, triclinic, P1̅, a = 9.161(5) Å, b = 10.283(5) Å, c = 12.974(5) Å, α = 87.739(5)°, β = 78.339(5)°, γ = 75.047(5)°, V = 1156.3(10) Å3, Z = 2, Rgt(F) = 0.037, wRref(F2) = 0.1012, T = 100(2) K.

CCDC no.:: 1447936

The crystal structure is shown in the figure. Tables 1–3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Source of material

fac-[NEt4]2[Re(CO)3Br3] (500 mg; 0.649 mmol) was dissolved in water (10 ml) at pH 2.2 and AgNO3 (331 mg; 1.947 mmol) was added. The solution was stirred overnight for 16 hours at room temperature and the precipitated AgBr was filtered off and weighed (367 mg; 1.955 mmol). Hexafluoroacetylacetone (0.135 g; 0.649 mmol) was added to the solution and stirred for 24 hours at room temperature. The orange precipitate, fac-[NEt4]2[Re(Hfaa)(CO)3NO3], was filtered off, washed, dried and weighed. (Yield: 274 mg; 86%). Crystals of the title complex was obtained from crystallization of the precipitate in MeOH. Yield = 148 mg; 40%. IR (KBr, cm−1): νCO (2023, 1880).

Experimental details

In the structure all the H atoms were positioned geometrically and refined discernible using a riding model, with C—Hmethine = 0.98 Å; C—Hmethyl = 0.96 Å; C—Haromatic = 0.93 Å. The H atom isotropic displacement parameters were fixed; Uiso(H) = 1.2Ueq(C) for aromatic and methine and Uiso(H) = 1.5Ueq(C) for methyl protons, allowing them to ride on the parent atom. The CF3 substituents on the beta-diketone backbone are both structurally disordered, as manifested by the fluoro-atoms on both carbons (C4 and C8), occupying six positions on each carbon with occupancies of 0.181(16) (for F4A, F5A and F6A) and 0.819(16) (for F4B, F5B and F6B) on C4, and 0.724(13) (for F1A, F2A and F3A) and 0.276(13) (for F1B, F2B and F3B) on C8 [1]. In one case, F1A, F2A and F3A displays the dominant occupancy, and in the other case, F4B, F5B and F6B.

Table 1

Data collection and handling.

Crystal:Orange, plate, size 0.14×0.27×0.69 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:53.46 cm−1
Diffractometer, scan mode:Bruker APEX-II CCD, φ and ω scans
2θmax:56°
N(hkl)measured, N(hkl)unique:21687, 5560
N(param)refined:330
Programs:Bruker data collection and reduction software [17], SHELX [18], Diamond [19]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomSitexyzUiso
H(01A)2i0.45370.94460.72450.084
H(01B)2i0.47030.78930.70270.084
H(02A)2i0.32580.92210.59210.156
H(02B)2i0.20390.99840.69110.156
H(02C)2i0.22020.84270.66950.156
H(03A)2i0.52350.90290.88760.072
H(03B)2i0.43480.82610.97830.072
H(04A)2i0.67840.69160.91260.114
H(04B)2i0.64230.69930.79650.114
H(04C)2i0.55240.62180.88680.114
H(05A)2i0.12750.99470.86660.079
H(05B)2i0.19340.96890.97240.079
H(6)2i1.19950.33370.58070.071
H(06A)2i0.19091.18490.91330.137
H(06B)2i0.29971.12610.80390.137
H(06C)2i0.36501.10070.91040.137
H(07A)2i0.16820.77030.82810.074
H(07B)2i0.33070.66370.82220.074
H(08A)2i0.15730.63060.97100.114
H(08B)2i0.13660.78061.01120.114
H(08C)2i0.29850.67161.00440.114
Table 3

Atomic displacement parameters (Å2).

AtomSitexyzU11U22U33U12U13U23
C(1)2i0.5582(6)0.3619(5)0.8038(5)0.043(3)0.048(3)0.063(4)−0.017(2)−0.009(2)0.000(2)
C(01)2i0.3963(8)0.8743(7)0.7315(5)0.074(4)0.073(4)0.056(4)−0.019(3)0.007(3)0.000(3)
C(02)2i0.276(1)0.913(1)0.6653(6)0.109(6)0.142(8)0.057(5)−0.021(6)−0.026(4)0.010(5)
C(2)2i0.5836(6)0.2237(6)0.6348(5)0.038(2)0.057(3)0.054(3)−0.012(2)−0.011(2)−0.010(2)
C(3)2i0.6244(7)0.4713(6)0.6171(5)0.060(3)0.056(3)0.062(4)−0.021(3)−0.010(3)−0.013(3)
C(03)2i0.4746(7)0.8269(7)0.9015(6)0.048(3)0.071(4)0.067(4)−0.026(3)−0.008(3)−0.007(3)
C(04)2i0.5976(7)0.6988(8)0.8718(6)0.055(3)0.085(5)0.083(5)−0.008(3)−0.015(3)0.003(4)
C(4)2i1.1449(6)0.1871(6)0.4436(5)0.052(3)0.097(5)0.049(4)−0.022(3)0.003(3)−0.005(3)
C(5)2i1.0367(6)0.2566(6)0.5414(5)0.043(3)0.060(3)0.051(3)−0.014(2)−0.008(2)0.004(2)
C(05)2i0.2219(6)0.9826(6)0.8958(6)0.045(3)0.070(4)0.078(4)−0.013(3)−0.002(3)−0.017(3)
C(6)2i1.0955(6)0.3294(6)0.6025(5)0.042(3)0.068(4)0.073(4)−0.026(3)−0.003(3)−0.001(3)
C(06)2i0.2739(8)1.1095(7)0.8794(8)0.071(4)0.056(4)0.137(7)−0.014(3)0.005(4)−0.017(4)
C(07)2i0.2597(7)0.7437(6)0.8612(5)0.061(3)0.070(4)0.064(4)−0.035(3)−0.011(3)−0.004(3)
C(7)2i1.0102(6)0.3960(5)0.6936(5)0.040(2)0.044(3)0.074(4)−0.020(2)−0.020(2)0.004(2)
C(8)2i1.0844(6)0.4718(5)0.7556(5)0.053(3)0.066(4)0.090(5)−0.028(3)−0.028(3)−0.002(3)
C(08)2i0.2087(8)0.7032(7)0.9714(6)0.077(4)0.090(5)0.071(4)−0.048(4)−0.007(3)0.008(4)
O(1)2i0.4603(5)0.3911(4)0.8766(3)0.052(2)0.076(3)0.058(3)−0.009(2)0.002(2)−0.010(2)
O(2)2i0.4997(5)0.1721(4)0.6065(4)0.054(2)0.076(3)0.081(3)−0.030(2)−0.023(2)−0.011(2)
O(3)2i0.5665(6)0.5684(5)0.5790(5)0.103(4)0.055(3)0.098(4)−0.021(3)−0.043(3)0.012(2)
O(4)2i0.9038(4)0.2418(4)0.5546(3)0.044(2)0.065(2)0.053(2)−0.026(2)0.003(2)−0.011(2)
O(5)2i0.8730(4)0.4011(4)0.7371(3)0.047(2)0.057(2)0.063(2)−0.021(2)−0.017(2)−0.010(2)
O(6)2i0.8553(4)0.1418(4)0.7514(3)0.036(2)0.059(2)0.066(3)−0.019(2)−0.009(2)−0.002(2)
O(7)2i0.8915(5)−0.0401(4)0.8417(4)0.061(2)0.074(3)0.071(3)−0.008(2)−0.023(2)0.010(2)
O(8)2i0.6642(5)0.0597(5)0.8210(5)0.045(2)0.087(3)0.143(5)−0.031(2)−0.016(3)0.048(3)
Re(1)2i0.71603(2)0.31160(2)0.68294(2)0.0353(1)0.0490(1)0.0498(2)−0.01844(9)−0.00744(9)−0.00651(9)
N(1)2i0.8010(5)0.0508(5)0.8057(4)0.046(2)0.054(3)0.051(3)−0.015(2)−0.009(2)−0.004(2)
N(2)2i0.3380(5)0.8555(4)0.8471(4)0.042(2)0.047(2)0.051(3)−0.015(2)−0.002(2)−0.006(2)
F(4A)2i1.214(2)0.066(1)0.462(2)0.12(2)0.09(2)0.11(2)−0.05(1)0.06(2)−0.02(1)
F(5A)2i1.250(2)0.248(2)0.407(2)0.12(2)0.09(2)0.11(2)−0.05(1)0.06(2)−0.02(1)
F(6A)2i1.072(2)0.185(2)0.371(1)0.09(2)0.07(2)0.04(1)−0.02(1)0.01(1)−0.01(1)
F(4B)2i1.2884(6)0.1452(8)0.4508(6)0.064(3)0.140(7)0.104(5)0.004(3)0.004(3)−0.030(5)
F(5B)2i1.145(1)0.267(1)0.3644(6)0.21(1)0.22(1)0.067(5)0.069(9)0.040(6)0.059(6)
F(6B)2i1.1100(9)0.083(1)0.4175(8)0.135(8)0.25(1)0.21(1)−0.134(8)0.104(7)−0.18(1)
F(1A)2i1.0885(8)0.4265(9)0.8521(6)0.089(4)0.177(7)0.130(5)−0.075(4)−0.032(3)−0.039(4)
F(2A)2i1.2252(7)0.4748(9)0.7140(6)0.089(4)0.177(7)0.130(5)−0.075(4)−0.032(3)−0.039(4)
F(3A)2i1.0077(7)0.5976(5)0.7744(7)0.090(5)0.042(3)0.21(1)−0.006(3)−0.091(6)−0.026(4)
F(1B)2i1.120(1)0.570(1)0.701(1)0.12(1)0.097(9)0.23(2)−0.016(8)−0.13(1)−0.016(9)
F(3B)2i0.986(1)0.522(1)0.8428(9)0.12(1)0.097(9)0.23(2)−0.016(8)−0.13(1)−0.016(9)
F(2B)2i1.206(1)0.401(2)0.7858(9)0.12(1)0.097(9)0.23(2)−0.016(8)−0.13(1)−0.016(9)

Discussion

Researchers are continually showing interest in the fac-[M(CO)3]+ [M = Re, Tc] synthon, particularly the fac-[Re(CO)3(OH2)3]+ moiety, primarily because of its potential use in the design of new diagnostic and therapeutic radiopharmaceuticals [2–4]. A considerable amount of work, involving the rhenium tricarbonyl core has already been published from our group, and this study forms part of on-going research, aimed at studying the chelation behaviour and structure and reactivity of the rhenium(I) metal centre and other middle and late transition metal complexes' behaviour when coordinated to β-diketone types of ligands [5–15].

The title compound, fac-[NEt4][Re(CO)3(Hfaa)(NO3)], consists of three facial coordinated carbonyl ligands, a fluorinated β-diketone ligand (hexafluoroacetylacetonate-Hfaa) in the axial position, a nitrate ligand in the equatorial plane, as well as a counterion, tetraethylammonium (NEt4), in the asymetric unit (see the figure, upper part). The coordination at Re(I) is a distorted octahedron, as seen in the C3—Re1—O6 (170.30(19)°) angle which deviates from 180°. The O4—Re1—O5 bite angle of 84.14(15)° correlates well with a similar hexafluoroacetylacetonate coordinated Re(I) complex, 84.56(8)° [6]. The bond distances in the coordination polyhedron, are within normal range when compared to a similar structure, ranging from 1.892(6) to 2.157(4) Å [16]. The molecules within the unit cell are packed in horizontal layers, in a head-to-head manner, when viewed along the c-axis. These layers are stabilised by intermolecular C—H⋯O bonds (see the figure, lower part).

Corresponding author: Amanda-Lee Manicum, Department of Chemistry, University of the Free State, P.O. Box 339, Bloemfontein, 9300, South Africa, e-mail:

Acknowledgements:

Financial assistance from the University of the Free State is gratefully acknowledged. We also express our gratitude towards NTeMBI, PETLabs Pharmaceuticals, SASOL and the South African National Research Foundation (SA-NRF/THRIP). This work is based on the research supported in part by the National Research Foundations of South-Africa and the Thuthuka programme (Grant specific unique reference numbers (UID) 84913 and 94142). The Grant holders acknowledge that opinions, findings and conclusions or recommendations expressed in any publication generated by the NRF supported research are that of the author(s) and that the NRF accepts no liability whatsoever in this regard.

References

1. Viljoen, J. A.; Visser, H. G.; Roodt, A.; Steyn, M.: Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexafluoroacetylacetonato-κ2O,O′)-hafnium(IV)] acetone solvate. Acta Crystallogr. E65 (2009) m1367–m1368.10.1107/S1600536809041658Search in Google Scholar PubMed PubMed Central

2. Papagiannopoulou, D.; Triantis, C.; Vassileiadis, V.; Raptopoulou, C. P.; Psycharis, V.; Terzis, A.; Pirmettis, I.; Papadopoulous, M. S.: Synthesis, structural characterisation and radiochemistry of di- and tricarbonyl Re(I) and 99mTc(I) complexes with 8-hydroxy quinolone or 8-mercaptoquinoline and triphenylphosphine. Polyhedron. 68 (2014) 46–52.10.1016/j.poly.2013.09.039Search in Google Scholar

3. Vassileiadis, V.; Triantis, C.; Raptopoulou, C. P.; Psycharis, V.; Pirmettis, I.; Papadopoulous, M. S.; Papagiannopoulou, D.: Synthesis, structural characterisation and radiochemistry of “2+1” fac-[99mTc/Re(CO)3(L)(2-mercaptopyridine)] complexes, where L is phosphine or isocyanide. Polyhedron. 81 (2014) 511–516.10.1016/j.poly.2014.07.008Search in Google Scholar

4. Triantis, C.; Tsotakos, T.; Tsoukalas, C.; Sagnou, M.; Raptopoulou, C.; Terzis, A.; Psycharis, V.; Pelecanou, M.; Pirmettis, I.; Papadopoulos, M.: Synthesis and characterization of fac-[M(CO)3(P)(OO)] and cis-trans-[M(CO)2(P)(OO)] complexes (M = Re, 99mTc) with acetylacetone and curcumin as OO donor bidentate ligands. Inorg. Chem. 52 (2013) 12995–13003.10.1021/ic401503bSearch in Google Scholar

5. Visser, H. G.; Roodt, A.; Volmink, A.; Kemp, G.: fac-Tricarbonyl-(pyridine-κN)(1,1,1-trifluoroacetylacetone-κ2O,O′)rhenium(I). Acta Crystallogr. E67 (2011) m1631–m1631.10.1107/S160053681104476XSearch in Google Scholar PubMed PubMed Central

6. Manicum, A.; Schutte-Smith, M.; Kemp, G.; Visser, H. G.: Illustration of the electronic influence of coordinated β-diketone type ligands: A kinetic and structural study. Polyhedron. 85 (2015) 190–195.10.1016/j.poly.2014.08.005Search in Google Scholar

7. Manicum, A.; Visser, H. G.; Engelbrecht, I.; Roodt, A: Crystal structure of fac-(acetylacetonato-κ2O,O′)\ tricarbonyl(cyclohexyldiphenylphosphine-κP) rhenium(I), C26H28O5PRe. Zeits. Z. Kristallogr. NCS. 230 (2015) 150–152.10.1515/ncrs-2014-9013Search in Google Scholar

8. Schutte, M.; Roodt, A.; Visser, H. G.: Coordinated aqua vs methanol substitution kinetics in fac-Re(I) tricarbonyl tropolonato complexes. Inorg. Chem. 51 (2012) 11996–12006.10.1021/ic301891uSearch in Google Scholar

9. Schutte, M.; Kemp, G.; Visser, H. G.; Roodt, A.: Tuning the reactivity in classic low-spin d6 rhenium(I) tricarbonyl radiopharmaceutical synthon by selective bidentate ligand variation (L,L′-Bid; L,L′ = N,N′, N,O and O,O′ donor atom sets) in fac-[Re(CO)3(L,L′-Bid)(MeOH)]n complexes. Inorg. Chem. 50 (2011) 12486–12498.10.1021/ic2013792Search in Google Scholar

10. Brink, A.; Roodt, A.; Steyl, G.; Visser, H. G.: Steric vs electronic anomaly observed from iodomethane oxidative addition to tertiary phosphine modified rhodium (I) acetylacetonato complexes following progressive phenyl replacement by cyclohexyl [PR(3) = PPh(3), PPh(2)Cy, PPhCy(2) and PCy(3)]. Dalt. Trans. 39 (2010) 5572–5578.10.1039/b922083fSearch in Google Scholar

11. Roodt, A.; Basson S. S.; Leipoldt, J. G.: Studies on the substitution reactions of dioxotetracyanometalate systems with bidentate ligands: kinetics of the reaction between aquaoxotetracyanotungstate(IV) and 2-pyridinecarboxylate ions. Polyhedron. 13 (1994) 599–607.10.1016/S0277-5387(00)84737-3Search in Google Scholar

12. Van Aswegen, K. G.; Leipoldt, J. G.; Potgieter, I. M.; Lamprecht,G. J.; Roodt, A.; van Zyl, G. J.: The crystal structure of the acetone adduct of trans-methyliodo-8 hydroxyquinolinatocarbonyltriphenylphosphinerhodium( III). Transit. Met. Chem. 16 (1991) 369–371.10.1007/BF01024085Search in Google Scholar

13. Kemp, G.; Roodt, A.; Purcell, W.; Koch, K. R.: Unprecedented N,S,O co-ordination of the doubly deprotonated anion of N-benzoyl-N′-phenylthiourea (H2L2) bridging two rhodium(I) centres: crystal structure of the acetone solvate of [(PPh3)2(CO)Rh(μ-L2-κN′:κO,S)Rh(PPh3)(CO)]. J. Chem. Soc. Dalton Trans. 23 (1997) 4481–4484.10.1039/a705887jSearch in Google Scholar

14. Sacht, C.; Datt, M. S.; Otto,S.; Roodt, A.: Synthesis, characterisation and coordination chemistry of novel chiral N,N-dialkyl-N′-menthyloxycarbonylthioureas. Crystal and molecular structures of N,N-diethyl-N′-(-)-(3R)-menthyloxycarbonylthiourea and cis-(S,S)-[Pt(L)Cl(DMSO)] [where HL = N-(+)-(3R)-menthyloxycarbonyl-N′-morpholinothiourea or N-benzoyl-N′, N′-diethylthiourea]. J. Chem. Soc. Dalton Trans. (2000) 4579–4586.10.1039/b007589mSearch in Google Scholar

15. Erasmus, J. J. C.; Lamprecht, G. J.; Swarts, J. C.; Roodt, A.; Oskarsson, A.: (E)-1,3-Diferrocenyl-2-buten-1-one-water (4–1). Acta Crystallogr. 52 (1996) 3000–3002.10.1107/S0108270196004258Search in Google Scholar

16. Brink, A.; Visser, H. G.; Roodt, A.: Tetraethylammonium (acetylacetonenato)bromidotricarbonylrhenate(I). Acta Crystallogr. E67 (2011) m34–m35.10.1107/S1600536810050105Search in Google Scholar PubMed PubMed Central

17. Bruker SAINT-Plus (Version 7.12) and SADABS (Version 2004/1). Bruker AXS Inc., Madison, Wisconsin, USA 2004.Search in Google Scholar

18. Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed

19. Brandenburg, K.; Putz, H. DIAMOND. Visual crystal structure information system. Version 3.2i. Crystal Impact, Bonn, Germany 2012.Search in Google Scholar

Received: 2015-6-3
Accepted: 2016-1-18
Published Online: 2016-2-11
Published in Print: 2016-3-1

©2016 Amanda-Lee Manicum et al., published by De Gruyter.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of rac-4,4,4-trifluoro-3-hydroxy-3-methylbutanoic acid, C5H7O2F3
  3. Crystal structure of 5-methyl-2-phenyl-1,3-dioxane-5-carboxylic acid, C12H14O4
  4. Crystal structure of ethyl 2-(2-(2-(4-chlorophenyl)-3-methylbutanamido)thiazol-4-yl)acetate, C18H21ClN2O3S
  5. The crystal structure of (4E,11E,31E,38E)-1,4,12,15,18,26,31,39-Octaaza-7,21,24-trihydroxy-penta-cyclo[13·13·13·16,10·120,24·133,37]tetratetraconta-4,6(44),7,9,11,18,20(43),21,23,25,31,33(42),34,36,38-pentadecaene, C36H42N8O3
  6. Crystal structure of poly[diaqua-μ5-4-(3,5-dicarboxylato-κ3O1:O2:O3-phenoxy)phthalato-κ3O5,O7:O8)(μ2-4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)dicobalt(II)] C24H16N3O11Co2
  7. Crystal structure of catena-poly[(μ2-acetamido-benzoato-κ2O:O′)triphenyltin(IV)], C27H23NO3Sn
  8. Crystal structure of chlorido(2,2′-((1E,1′E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanylylidene))bis(methylylidene))diphenolato-κ4N,N′,O,O′)iron(III), C20H20ClFeN2O2
  9. Crystal structure of (E)-3-(4-tert-butyl)phenyl)-1-(3-chlorophenyl)prop-2-en-1-one, C18H17CIO
  10. Crystal structure of trans-1,2-bis(pyridinium-4-yl)ethylene–2-carboxy-4-methylbenzoate (1/2), C30H26N2O8
  11. Crystal structure of poly[aqua-ethylenediamine-tetraacetatolead(II)zinc(II)]
  12. Crystal structure of (E)-2-((2-(2,4-dinitrophenyl)hydrazono)methyl)-4-nitrophenol — triethylamine (2/1), C32H33N11O14
  13. Crystal structure of catena-poly[diaqua-bis-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)cadmium(II)] dihydrate, C26H24N2O12Cd
  14. Crystal structure of 2-(ethoxycarbonyl)-2-(2-nitro-1-phenylethyl)-3-oxopyrrolidinium chloride, C15H19N2O5Cl
  15. Crystal structure of 4-((pyridin-4-ylmethyl)sulfinyl)pyridine, C11H10N2OS
  16. Crystal structure of 2,5-diethoxy-1,4-bis[2-(quinoline)ethenyl]benzene, C32H28N2O2
  17. Crystal structure of diaqua(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)tetrakis(3-carboxy-5-ethylpyridine-2-carboxylato-κ2N,O)dizinc(II), C54H50N8O18Zn2
  18. Crystal structure of a poly[bis(3,4,5,6-tetrachlorophthalato)neodym(III)potassium(I)] — 4,4′-bipyridine — water (1/1/5.5)
  19. The second polymorph of triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide, C9H18N4S3
  20. Crystal structure of 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid dihydrate, C14H16N2O6
  21. Crystal structure of the catena-poly[bis(1H-imidazole-κN)-(μ2-furan-2,5-dicarboxylato-κ2O1:O4)manganese(II)]monohydrate, C12H12MnN4O6
  22. Crystal structure of (acetylacetonato-κ2O:O′)bis-((1-(2-hydroxyphenyl)-3-(pyridin-2-yl)prop-2-en-1-one)-κ2C,N)iridium(III), C33H27IrN2O6
  23. Crystal structure of 1-benzyl-3-(4-methylpyridin-2-yl)-1H-imidazol-3-ium hexafluorophosphate, C16H16F6N3P
  24. Crystal structure of tetraethylammonium 3,5-dinitrosalicylate, C15H23N3O7
  25. Crystal structure of 4-[5-(4-fluorophenyl)-3-(4-hydroxyphenyl)-4,5-dihydropyrazol-1-yl] benzenesulfonamide, C21H18FN3O3S
  26. Crystal structure of 2,4-dichlorobenzene anhydride, C14H6Cl4O3
  27. Crystal structure of bis(2-hydroxy-2-phenylacetato-κ2O,O′)bis(pyridine-κN)nickel(II), C26H24N2NiO6
  28. Crystal structure of (E)-4-nitro-2-(((3-(tetrahydro-8λ4-[1,3,2]oxazaborolo[2,3-b][1,3,2]oxaborol-8-yl)phenyl)imino)methyl)phenol – water (1/2), C17H18BN3O5·2H2O
  29. Crystal structure of 5-(4-carboxyphenoxy)-nicotinic acid, C13H9NO5
  30. Crystal structure of catena-poly[hexaaquabis(μ2-3-nitrophthalate-κ2O:O′)-(μ2-1,4-bis(4-pyridylmethyl)piperazine-κ2N:N′)dimanganese(II)] dihydrate, C32H42Mn2N6O20
  31. Crystal structure of diaquabis(bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate-κ4O, O′:/O′′,O′′′)bis-(2,2′-bipyridine-κ2N, N′)dicadmium(II) hydrate
  32. Crystal structure of (R)-1-(1-(6-fluorobenzo[d]thiazol-2-yl)ethyl)-3-phenylthiourea
  33. Crystal structure of poly[(μ2-1,4-bis((1H-imidiazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-(1,2-phenylenebis(oxy)dibenzoato-κ4O,O′:O′′,O′′′)nickel(II)], C34H26O6N4Ni
  34. Crystal structure of 3′,4′,5-trihydroxy-3,7-dimethoxyflavone, C17H14O7
  35. Crystal structure of n-butyl-chlorido-bis[N-sec-butyl,N-n-propyl-carbamodithioato κ2S,S′]-tin(IV), C20H41ClN2S4Sn
  36. Crystal structure of poly[bis(μ4-4,4′-(1,2-phenylenebis(oxy))dibenzoato-κ4O:O′:O′′:O′′′)bis(μ3-4,4′-(1,2-phenylenebis(oxy))dibenzoato–κ3O:O′:O′′)(μ2-1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazole-κ2N:N′)tetracobalt(II)], C94H62O24N4Co4
  37. Crystal structure of catenapoly[diaqua-(μ24,4′-bipyridine)-κ2N:N′)-bis(2,6-difluorobenzoate)-κO)nickel(II)] ethanol monosolvate, C28H30F4N2O8Ni
  38. Crystal structure of 2-(9H-fluoren-9-ylidene)hydrazine-1-carbothioamide, C14H11N3S
  39. Crystal structure of 2-(4-methoxyphenyl)-2,3-dihydro-1H-perimidine, C18H16N2O
  40. Crystal structure of catena-poly[diaquabis(μ2-3-carboxybenzene-1,2-dicarboxylato-1:2κ2O:O′)-(μ2-1,4-bis(2-ethylbenzimidazol-1-ylmethyl)-benzene-1:1′κ2N:N′)dizinc(II)], [Zn2(C26H26N4)(C9H4O6)2(H2O)2]
  41. Crystal structure of diaquabis(phenoxyacetato-κ2O,O′)-zinc(II), C16H18O8Zn
  42. Crystal structure of 4-(1H-imidazol-1-yl)-6-pyrimidinylferrocene, C17H14FeN4
  43. Crystal structure of [2-(4-methoxyphenyl)pyrazine-κ2C,N) chlorido[N,N′-bis-(2,6-diisopropyl-phenyl)imidazol-2-ylidene-κC)] palladium(II), C38H45ClN4OPd
  44. Crystal structure of 2-(4-acetyl-2,6-dimethyl-phenyl)-5,6-dichloro-isoindole-1,3-dione, C18H13Cl2NO3
  45. Crystal structure of 4,4′-bipyridin-1-ium 3,3′,5′-tricarboxy-[1,1′-biphenyl]-2-carboxylate, (C26H18N2O8)
  46. Crystal structure of catena-poly[diaqua-μ2-4,4′-biphenyl-4,4′-diyldipyridine-κ2N:N′-bis(5-carboxy-2,6-dimethylpyridine-3-carboxylato-κO)nickel(II)] dihydrate, C40H40N4O12Ni
  47. Crystal structure of poly-[μ2-4,4′-bipyridine-κ2N:N′−μ3-thiophene-2,3-di-carboxylato-κ4O,O′, O′′:O′′′ -cadmium(II)]
  48. Crystal structure of hexaaquamanganese(II) bis(3-carboxythiophene-2-carboxylate) C12H18MnO14S2
  49. Crystal structure of 4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoic acid, C14H10N4O2
  50. Crystal structure of (E)-2-(benzo[d]thiazol-2-yl)-3-(pyridin-3-yl)acrylonitrile)
  51. Crystal structure of catena-poly[2,2′-bipyridinyl-6,6′-dicarboxylato-κ4N,N′,O,O′)-(μ2-2,2′-bipyridinyl-6′-carboxyl-6-carboxylato-κ5N,N′,O,O′:O′′)samarium(III)] monohydrate, C24H13N4O8Sm · H2O
  52. Crystal structure of catena-poly[bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato)-κ2N:O)copper(II)] dihydrate, C28H22N8O6Cu
  53. Crystal structure of catena-poly[tetraaqua-(μ2-4,4′-bipyridine-k2N:N′)-zinc(II)] fumarate tetrahydrate, C14H26N2O12Zn
  54. Crystal structure of triaqua-(1,10-phenanthroline)-(dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoato) cobalt(II)dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoate, C72H82Co2N16O42
  55. Crystal structure of poly[dibromido-(μ2–4,4′-bis-(pyrid-4-yl)biphenyl-κ2N:N′)lead(II)], C22H16N2PbBr2
  56. Crystal structure of catena-poly[diaqua-bis(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)-cobalt(II)]dihydrate, C26H24N2O12Co
  57. Crystal structure of 5-(4-pyridyl)pyrimidine–4,4′-bipyridine–1,3,5-benzenetriol–water (1:1:1:1), C25H23N5O4
  58. Crystal structure of 5-hydroxy-4-((4-hydroxyphenyl)imino)naphthalen-1(4H)-one monohydrate, C16H11NO3 · 0.5H2O
  59. Crystal structure of 2-amino-N-(4-methoxyphenyl)benzamide, C14H14N2O2
  60. Crystal structure of (2,5-dihydroxyphenyl)-(4-hydroxy-3,5-dimethoxyphenyl)methanone, C15H14O6
  61. Crystal structure of dichlorido[bis(2-hydroxyethyl)5′-([2,2′:6′,2′′-terpyridin]-4′-yl)-[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato]zinc(II), C39H31Cl2N3O6Zn
  62. Crystal structure of bis[4-(3-carboxy-6-fluoro-1-(4-fluorophenyl)-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium] benzene-1,4-dicarboxylate (C20H18F2N3O3)2(C8H4O4), C48H40F4N6O10
  63. Crystal structure of (2,5-dihydroxyphenyl)-(4-methoxyphenyl)methanone, C14H12O4
  64. Crystal structure of photochromic 1-(2-methyl-5-phenyl-3-thienyl-2-[2-methyl-5-(4-ethoxylphenyl)-3-thienyl] 3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H22F6OS2
  65. Crystal structure of poly[diaquabis(μ2-biphenyl-2,4′-dicarboxylato-κ2O:O′)tris(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)dicobalt(II)] monohydrat, C82H64N12O11Co2
  66. Crystal structure of 2-amino-4-(3,4-difluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12N2O2F2
  67. Crystal structure of poly[(di-μ2-aqua-κ2O:O)bis(μ5-oxalato-1:2κ2O1; 1κ1O2; 3:4:5κ3O3; 3κ1O4)(μ4-oxalato-1:2κ2O1; 2:3κ2O2; 3:4κ2O3; 4:1κ2O4)dizinc(II)disodium(I)]
  68. Crystal structure of tetraethylammonium hexachloridotantalate(V), C8H20Cl6NTa
  69. Crystal structure of (E)-2,4-dibromo-6-(((2-nitrophenyl)imino)methyl)phenol, C13H8Br2N2O3
  70. The crystal structure of 6-chloro-2,4-diphenylquinoline
  71. Crystal structure of (E)-2-(((1,10-phenanthrolin-5-yl)imino)methyl)-5-methylphenol monohydrate, C20H15N3O·H2O
  72. Crystal structure of tris(3-(2-pyridyl)pyrazole)zinc(II)tetrachlorido zincate(II), C24H21Cl4N9Zn2
  73. Crystal structure of 4-chloro-N,N-diethyl-6-(piperidin-1-yl)-1,3,5-triazin-2-amine, C12H20ClN5
  74. The crystal structure of 4-allyl-5-benzyl-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H13N3O
  75. Crystal structure of diethyl 2-(((2-(pyridin-3-ylthio)phenyl)amino)methylene)malonate, C19H20N2O4S
  76. Crystal structure of fac-tricarbonyl(2-(isopropylimino)methyl-5-methylphenolatido-κ2N,O)(pyridine-κN)rhenium(I), C19H19N2O4Re
  77. Crystal structure of 1,3,6,8-tetrakis(p-tolylthio)pyrene, C44H34S4
  78. Crystal structure of catena-poly-(diaqua-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)-(4-methylphthalato-κ2O,O′)-cobalt(II)trihydrate, C21H26CoN2O9
  79. Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re
  80. Crystal structure of 3-(thiophen-2-yl)-5-(p-tolyl)-4,5-dihydro-1H-pyrazole-1-carboxamide
  81. Crystal structure of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate(II), [C6H11N2]2[CdBr4]
  82. Crystal structure of N′-(adamantan-2-ylidene)-isonicotinohydrazide, C16H19N3O
  83. Crystal structure of trans-tetraaquabis(4-(pyridin-4-ylsulfonyl)pyridine-κN)cobalt(II) diperchlorate dihydrate, C20H28Cl2CoN4O18S2
  84. Crystal structure of (Z)-4-(furan-2-yl(p-tolylamino)methylene)-3-methyl-1-p-tolyl-1H-pyrazol-5(4H)-one, C23H21N3O2
  85. Crystal structure of 2-[(4-fluorobenzyl)sulfanyl]-4-(2-methylpropyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C16H16FN3OS
  86. Crystal structure of poly[octaaqua-tris(benzene-1,2,4,5-tetracarboxylato)tetralanthanum(III)] hexahydrate, C30H34La4O38
  87. Crystal structure of trans-tetraaqua-bis(4,4′-sulfonyldipyridine-κN)zinc(II) diperchlorate dihydrate, C20H28Cl2ZnN4O18S2
  88. Crystal structure of 4-nitro-thiophene-2-carboxylic acid, a structure with a Z′ = 4, C5H3NO4S
  89. Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se4
  90. Crystal structure of 5-(adamantan-1-yl)-3-[(4-chloroanilino)methyl]-2,3-dihydro-1,3,4-oxadiazole-2-thione, C19H22ClN3OS
  91. Crystal structure of hexaaquamagnesium(II) 5,5′-bitetrazole-1,1′-diolate, C2H12N8O8Mg
  92. The crystal structure of catena-poly[(μ2-1,1′-benzene-1,4-diylbis(1H-benzimidazole-κ2N:N′)silver(I)] nitrate, C20H14N5AgO3
  93. The crystal structure of 1-(2-(4-chlorophenoxy)-4-chlorophenyl)ethanone, C14H10Cl2O2
  94. The crystal structure of 3,5-dinitro-1,3,5-oxadiazinane, C3H6N4O5
  95. Crystal structure of methyl 5-methoxy 1H-indole-2-carboxylate, C11H11NO3
  96. Crystal structure of (Z)-1-(((3-acetyl-2-hydroxyphenyl)amino)methylene)naphthalen-2(1H)-one, C19H15NO3
  97. Crystal structure of (Z)-5-(4-chlorobenzylidene)-2-thioxothiazolidin-4-one —dimethylsulfoxide (1:1), C12H12ClNO2S3
  98. Crystal structure of 5,5′-((4-(trifluoromethyl)phenyl)methylene)bis(1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione) – diethylamine – dichloromethane (1/1/1) C25H32Cl2F3N5O6
  99. Crystal structure of 2-(dimethylsulfanylidene)-N-(4-methoxyphenyl)-3-oxo-3-phenylpropanamide
  100. Crystal structure of (1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)platinum(II), C14H8N4PtS2
  101. Crystal structure of di(μ2-chlorido)bis[2-(2-pyridyl)phenyl-κ2N,C1]dipalladium(II), C22H16Cl2N2Pd2
  102. Crystal structure of trans-dibromidodi(pyridine-κN)palladium(II), PdBr2(C5H5N)2
https://doi.org/10.1515/ncrs-2015-0115
Creative Commons
BY-NC-ND 3.0

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of rac-4,4,4-trifluoro-3-hydroxy-3-methylbutanoic acid, C5H7O2F3
  3. Crystal structure of 5-methyl-2-phenyl-1,3-dioxane-5-carboxylic acid, C12H14O4
  4. Crystal structure of ethyl 2-(2-(2-(4-chlorophenyl)-3-methylbutanamido)thiazol-4-yl)acetate, C18H21ClN2O3S
  5. The crystal structure of (4E,11E,31E,38E)-1,4,12,15,18,26,31,39-Octaaza-7,21,24-trihydroxy-penta-cyclo[13·13·13·16,10·120,24·133,37]tetratetraconta-4,6(44),7,9,11,18,20(43),21,23,25,31,33(42),34,36,38-pentadecaene, C36H42N8O3
  6. Crystal structure of poly[diaqua-μ5-4-(3,5-dicarboxylato-κ3O1:O2:O3-phenoxy)phthalato-κ3O5,O7:O8)(μ2-4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)dicobalt(II)] C24H16N3O11Co2
  7. Crystal structure of catena-poly[(μ2-acetamido-benzoato-κ2O:O′)triphenyltin(IV)], C27H23NO3Sn
  8. Crystal structure of chlorido(2,2′-((1E,1′E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanylylidene))bis(methylylidene))diphenolato-κ4N,N′,O,O′)iron(III), C20H20ClFeN2O2
  9. Crystal structure of (E)-3-(4-tert-butyl)phenyl)-1-(3-chlorophenyl)prop-2-en-1-one, C18H17CIO
  10. Crystal structure of trans-1,2-bis(pyridinium-4-yl)ethylene–2-carboxy-4-methylbenzoate (1/2), C30H26N2O8
  11. Crystal structure of poly[aqua-ethylenediamine-tetraacetatolead(II)zinc(II)]
  12. Crystal structure of (E)-2-((2-(2,4-dinitrophenyl)hydrazono)methyl)-4-nitrophenol — triethylamine (2/1), C32H33N11O14
  13. Crystal structure of catena-poly[diaqua-bis-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)cadmium(II)] dihydrate, C26H24N2O12Cd
  14. Crystal structure of 2-(ethoxycarbonyl)-2-(2-nitro-1-phenylethyl)-3-oxopyrrolidinium chloride, C15H19N2O5Cl
  15. Crystal structure of 4-((pyridin-4-ylmethyl)sulfinyl)pyridine, C11H10N2OS
  16. Crystal structure of 2,5-diethoxy-1,4-bis[2-(quinoline)ethenyl]benzene, C32H28N2O2
  17. Crystal structure of diaqua(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)tetrakis(3-carboxy-5-ethylpyridine-2-carboxylato-κ2N,O)dizinc(II), C54H50N8O18Zn2
  18. Crystal structure of a poly[bis(3,4,5,6-tetrachlorophthalato)neodym(III)potassium(I)] — 4,4′-bipyridine — water (1/1/5.5)
  19. The second polymorph of triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide, C9H18N4S3
  20. Crystal structure of 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid dihydrate, C14H16N2O6
  21. Crystal structure of the catena-poly[bis(1H-imidazole-κN)-(μ2-furan-2,5-dicarboxylato-κ2O1:O4)manganese(II)]monohydrate, C12H12MnN4O6
  22. Crystal structure of (acetylacetonato-κ2O:O′)bis-((1-(2-hydroxyphenyl)-3-(pyridin-2-yl)prop-2-en-1-one)-κ2C,N)iridium(III), C33H27IrN2O6
  23. Crystal structure of 1-benzyl-3-(4-methylpyridin-2-yl)-1H-imidazol-3-ium hexafluorophosphate, C16H16F6N3P
  24. Crystal structure of tetraethylammonium 3,5-dinitrosalicylate, C15H23N3O7
  25. Crystal structure of 4-[5-(4-fluorophenyl)-3-(4-hydroxyphenyl)-4,5-dihydropyrazol-1-yl] benzenesulfonamide, C21H18FN3O3S
  26. Crystal structure of 2,4-dichlorobenzene anhydride, C14H6Cl4O3
  27. Crystal structure of bis(2-hydroxy-2-phenylacetato-κ2O,O′)bis(pyridine-κN)nickel(II), C26H24N2NiO6
  28. Crystal structure of (E)-4-nitro-2-(((3-(tetrahydro-8λ4-[1,3,2]oxazaborolo[2,3-b][1,3,2]oxaborol-8-yl)phenyl)imino)methyl)phenol – water (1/2), C17H18BN3O5·2H2O
  29. Crystal structure of 5-(4-carboxyphenoxy)-nicotinic acid, C13H9NO5
  30. Crystal structure of catena-poly[hexaaquabis(μ2-3-nitrophthalate-κ2O:O′)-(μ2-1,4-bis(4-pyridylmethyl)piperazine-κ2N:N′)dimanganese(II)] dihydrate, C32H42Mn2N6O20
  31. Crystal structure of diaquabis(bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate-κ4O, O′:/O′′,O′′′)bis-(2,2′-bipyridine-κ2N, N′)dicadmium(II) hydrate
  32. Crystal structure of (R)-1-(1-(6-fluorobenzo[d]thiazol-2-yl)ethyl)-3-phenylthiourea
  33. Crystal structure of poly[(μ2-1,4-bis((1H-imidiazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-(1,2-phenylenebis(oxy)dibenzoato-κ4O,O′:O′′,O′′′)nickel(II)], C34H26O6N4Ni
  34. Crystal structure of 3′,4′,5-trihydroxy-3,7-dimethoxyflavone, C17H14O7
  35. Crystal structure of n-butyl-chlorido-bis[N-sec-butyl,N-n-propyl-carbamodithioato κ2S,S′]-tin(IV), C20H41ClN2S4Sn
  36. Crystal structure of poly[bis(μ4-4,4′-(1,2-phenylenebis(oxy))dibenzoato-κ4O:O′:O′′:O′′′)bis(μ3-4,4′-(1,2-phenylenebis(oxy))dibenzoato–κ3O:O′:O′′)(μ2-1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazole-κ2N:N′)tetracobalt(II)], C94H62O24N4Co4
  37. Crystal structure of catenapoly[diaqua-(μ24,4′-bipyridine)-κ2N:N′)-bis(2,6-difluorobenzoate)-κO)nickel(II)] ethanol monosolvate, C28H30F4N2O8Ni
  38. Crystal structure of 2-(9H-fluoren-9-ylidene)hydrazine-1-carbothioamide, C14H11N3S
  39. Crystal structure of 2-(4-methoxyphenyl)-2,3-dihydro-1H-perimidine, C18H16N2O
  40. Crystal structure of catena-poly[diaquabis(μ2-3-carboxybenzene-1,2-dicarboxylato-1:2κ2O:O′)-(μ2-1,4-bis(2-ethylbenzimidazol-1-ylmethyl)-benzene-1:1′κ2N:N′)dizinc(II)], [Zn2(C26H26N4)(C9H4O6)2(H2O)2]
  41. Crystal structure of diaquabis(phenoxyacetato-κ2O,O′)-zinc(II), C16H18O8Zn
  42. Crystal structure of 4-(1H-imidazol-1-yl)-6-pyrimidinylferrocene, C17H14FeN4
  43. Crystal structure of [2-(4-methoxyphenyl)pyrazine-κ2C,N) chlorido[N,N′-bis-(2,6-diisopropyl-phenyl)imidazol-2-ylidene-κC)] palladium(II), C38H45ClN4OPd
  44. Crystal structure of 2-(4-acetyl-2,6-dimethyl-phenyl)-5,6-dichloro-isoindole-1,3-dione, C18H13Cl2NO3
  45. Crystal structure of 4,4′-bipyridin-1-ium 3,3′,5′-tricarboxy-[1,1′-biphenyl]-2-carboxylate, (C26H18N2O8)
  46. Crystal structure of catena-poly[diaqua-μ2-4,4′-biphenyl-4,4′-diyldipyridine-κ2N:N′-bis(5-carboxy-2,6-dimethylpyridine-3-carboxylato-κO)nickel(II)] dihydrate, C40H40N4O12Ni
  47. Crystal structure of poly-[μ2-4,4′-bipyridine-κ2N:N′−μ3-thiophene-2,3-di-carboxylato-κ4O,O′, O′′:O′′′ -cadmium(II)]
  48. Crystal structure of hexaaquamanganese(II) bis(3-carboxythiophene-2-carboxylate) C12H18MnO14S2
  49. Crystal structure of 4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoic acid, C14H10N4O2
  50. Crystal structure of (E)-2-(benzo[d]thiazol-2-yl)-3-(pyridin-3-yl)acrylonitrile)
  51. Crystal structure of catena-poly[2,2′-bipyridinyl-6,6′-dicarboxylato-κ4N,N′,O,O′)-(μ2-2,2′-bipyridinyl-6′-carboxyl-6-carboxylato-κ5N,N′,O,O′:O′′)samarium(III)] monohydrate, C24H13N4O8Sm · H2O
  52. Crystal structure of catena-poly[bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato)-κ2N:O)copper(II)] dihydrate, C28H22N8O6Cu
  53. Crystal structure of catena-poly[tetraaqua-(μ2-4,4′-bipyridine-k2N:N′)-zinc(II)] fumarate tetrahydrate, C14H26N2O12Zn
  54. Crystal structure of triaqua-(1,10-phenanthroline)-(dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoato) cobalt(II)dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoate, C72H82Co2N16O42
  55. Crystal structure of poly[dibromido-(μ2–4,4′-bis-(pyrid-4-yl)biphenyl-κ2N:N′)lead(II)], C22H16N2PbBr2
  56. Crystal structure of catena-poly[diaqua-bis(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)-cobalt(II)]dihydrate, C26H24N2O12Co
  57. Crystal structure of 5-(4-pyridyl)pyrimidine–4,4′-bipyridine–1,3,5-benzenetriol–water (1:1:1:1), C25H23N5O4
  58. Crystal structure of 5-hydroxy-4-((4-hydroxyphenyl)imino)naphthalen-1(4H)-one monohydrate, C16H11NO3 · 0.5H2O
  59. Crystal structure of 2-amino-N-(4-methoxyphenyl)benzamide, C14H14N2O2
  60. Crystal structure of (2,5-dihydroxyphenyl)-(4-hydroxy-3,5-dimethoxyphenyl)methanone, C15H14O6
  61. Crystal structure of dichlorido[bis(2-hydroxyethyl)5′-([2,2′:6′,2′′-terpyridin]-4′-yl)-[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato]zinc(II), C39H31Cl2N3O6Zn
  62. Crystal structure of bis[4-(3-carboxy-6-fluoro-1-(4-fluorophenyl)-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium] benzene-1,4-dicarboxylate (C20H18F2N3O3)2(C8H4O4), C48H40F4N6O10
  63. Crystal structure of (2,5-dihydroxyphenyl)-(4-methoxyphenyl)methanone, C14H12O4
  64. Crystal structure of photochromic 1-(2-methyl-5-phenyl-3-thienyl-2-[2-methyl-5-(4-ethoxylphenyl)-3-thienyl] 3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H22F6OS2
  65. Crystal structure of poly[diaquabis(μ2-biphenyl-2,4′-dicarboxylato-κ2O:O′)tris(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)dicobalt(II)] monohydrat, C82H64N12O11Co2
  66. Crystal structure of 2-amino-4-(3,4-difluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12N2O2F2
  67. Crystal structure of poly[(di-μ2-aqua-κ2O:O)bis(μ5-oxalato-1:2κ2O1; 1κ1O2; 3:4:5κ3O3; 3κ1O4)(μ4-oxalato-1:2κ2O1; 2:3κ2O2; 3:4κ2O3; 4:1κ2O4)dizinc(II)disodium(I)]
  68. Crystal structure of tetraethylammonium hexachloridotantalate(V), C8H20Cl6NTa
  69. Crystal structure of (E)-2,4-dibromo-6-(((2-nitrophenyl)imino)methyl)phenol, C13H8Br2N2O3
  70. The crystal structure of 6-chloro-2,4-diphenylquinoline
  71. Crystal structure of (E)-2-(((1,10-phenanthrolin-5-yl)imino)methyl)-5-methylphenol monohydrate, C20H15N3O·H2O
  72. Crystal structure of tris(3-(2-pyridyl)pyrazole)zinc(II)tetrachlorido zincate(II), C24H21Cl4N9Zn2
  73. Crystal structure of 4-chloro-N,N-diethyl-6-(piperidin-1-yl)-1,3,5-triazin-2-amine, C12H20ClN5
  74. The crystal structure of 4-allyl-5-benzyl-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H13N3O
  75. Crystal structure of diethyl 2-(((2-(pyridin-3-ylthio)phenyl)amino)methylene)malonate, C19H20N2O4S
  76. Crystal structure of fac-tricarbonyl(2-(isopropylimino)methyl-5-methylphenolatido-κ2N,O)(pyridine-κN)rhenium(I), C19H19N2O4Re
  77. Crystal structure of 1,3,6,8-tetrakis(p-tolylthio)pyrene, C44H34S4
  78. Crystal structure of catena-poly-(diaqua-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)-(4-methylphthalato-κ2O,O′)-cobalt(II)trihydrate, C21H26CoN2O9
  79. Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re
  80. Crystal structure of 3-(thiophen-2-yl)-5-(p-tolyl)-4,5-dihydro-1H-pyrazole-1-carboxamide
  81. Crystal structure of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate(II), [C6H11N2]2[CdBr4]
  82. Crystal structure of N′-(adamantan-2-ylidene)-isonicotinohydrazide, C16H19N3O
  83. Crystal structure of trans-tetraaquabis(4-(pyridin-4-ylsulfonyl)pyridine-κN)cobalt(II) diperchlorate dihydrate, C20H28Cl2CoN4O18S2
  84. Crystal structure of (Z)-4-(furan-2-yl(p-tolylamino)methylene)-3-methyl-1-p-tolyl-1H-pyrazol-5(4H)-one, C23H21N3O2
  85. Crystal structure of 2-[(4-fluorobenzyl)sulfanyl]-4-(2-methylpropyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C16H16FN3OS
  86. Crystal structure of poly[octaaqua-tris(benzene-1,2,4,5-tetracarboxylato)tetralanthanum(III)] hexahydrate, C30H34La4O38
  87. Crystal structure of trans-tetraaqua-bis(4,4′-sulfonyldipyridine-κN)zinc(II) diperchlorate dihydrate, C20H28Cl2ZnN4O18S2
  88. Crystal structure of 4-nitro-thiophene-2-carboxylic acid, a structure with a Z′ = 4, C5H3NO4S
  89. Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se4
  90. Crystal structure of 5-(adamantan-1-yl)-3-[(4-chloroanilino)methyl]-2,3-dihydro-1,3,4-oxadiazole-2-thione, C19H22ClN3OS
  91. Crystal structure of hexaaquamagnesium(II) 5,5′-bitetrazole-1,1′-diolate, C2H12N8O8Mg
  92. The crystal structure of catena-poly[(μ2-1,1′-benzene-1,4-diylbis(1H-benzimidazole-κ2N:N′)silver(I)] nitrate, C20H14N5AgO3
  93. The crystal structure of 1-(2-(4-chlorophenoxy)-4-chlorophenyl)ethanone, C14H10Cl2O2
  94. The crystal structure of 3,5-dinitro-1,3,5-oxadiazinane, C3H6N4O5
  95. Crystal structure of methyl 5-methoxy 1H-indole-2-carboxylate, C11H11NO3
  96. Crystal structure of (Z)-1-(((3-acetyl-2-hydroxyphenyl)amino)methylene)naphthalen-2(1H)-one, C19H15NO3
  97. Crystal structure of (Z)-5-(4-chlorobenzylidene)-2-thioxothiazolidin-4-one —dimethylsulfoxide (1:1), C12H12ClNO2S3
  98. Crystal structure of 5,5′-((4-(trifluoromethyl)phenyl)methylene)bis(1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione) – diethylamine – dichloromethane (1/1/1) C25H32Cl2F3N5O6
  99. Crystal structure of 2-(dimethylsulfanylidene)-N-(4-methoxyphenyl)-3-oxo-3-phenylpropanamide
  100. Crystal structure of (1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)platinum(II), C14H8N4PtS2
  101. Crystal structure of di(μ2-chlorido)bis[2-(2-pyridyl)phenyl-κ2N,C1]dipalladium(II), C22H16Cl2N2Pd2
  102. Crystal structure of trans-dibromidodi(pyridine-κN)palladium(II), PdBr2(C5H5N)2
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 10.11.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2015-0115/html
Scroll to top button