Crystal structure of triaqua-(1,10-phenanthroline)-(dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoato) cobalt(II)dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoate, C72H82Co2N16O42
Abstract
C72H82Co2N16O42, triclinic, P1̅, a = 15.7653(19) Å, b = 16.955(2) Å, c = 18.838(2) Å, α = 70.35(2)°, β = 87.78(2)°, γ = 63.73(2)°, V = 4216.5(8) Å3, Z = 2, Rgt(F) = 0.0735, wRref(F2) = 0.1405, T = 296(2) K.

The crystal structure is shown in the figure, Tables 1–3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.
Data collection and handling.
| Crystal: | Red, Block, size 0.10×0.20×0.20 mm |
| Wavelength: | Mo Kα radiation (0.71073 Å) |
| μ: | 5.02 cm−1 |
| Diffractometer, scan mode: | CCD area detector, φ and ω scans |
| 2θmax: | 50.1° |
| N(hkl)measured, N(hkl)unique: | 22224, 1472 |
| Criterion for Iobs, N(hkl)gt: | Iobs > 2 σ(Iobs), 7580 |
| N(param)refined: | 1202 |
| Programs: | Bruker data collection and reduction software [7–9], SHELX [10] |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).
| Atom | Site | x | y | z | Uiso |
|---|---|---|---|---|---|
| H(1) | 2i | 0.9032 | −0.0372 | 0.1503 | 0.051 |
| H(2) | 2i | 0.9997 | 0.0368 | 0.1219 | 0.058 |
| H(3) | 2i | 0.9827 | 0.1392 | 0.0022 | 0.057 |
| H(5) | 2i | 0.8960 | 0.2214 | −0.1356 | 0.062 |
| H(6) | 2i | 0.7822 | 0.2452 | −0.2202 | 0.073 |
| H(8) | 2i | 0.6444 | 0.2155 | −0.2492 | 0.092 |
| H(9A) | 2i | 0.5500 | 0.1430 | −0.2045 | 0.091 |
| H(10) | 2i | 0.5685 | 0.0569 | −0.0772 | 0.072 |
| H(14A) | 2i | 0.5390 | 0.1828 | 0.1887 | 0.050 |
| H(14B) | 2i | 0.4402 | 0.1845 | 0.1759 | 0.050 |
| H(15A) | 2i | 0.5210 | 0.2725 | 0.0574 | 0.061 |
| H(15B) | 2i | 0.4210 | 0.2764 | 0.0466 | 0.061 |
| H(17A) | 2i | 0.4732 | 0.5157 | 0.2154 | 0.091 |
| H(17B) | 2i | 0.5609 | 0.4537 | 0.1833 | 0.091 |
| H(18A) | 2i | 0.4292 | 0.6377 | 0.0982 | 0.087 |
| H(18B) | 2i | 0.5215 | 0.5757 | 0.0700 | 0.087 |
| H(21A) | 2i | 0.1571 | 0.4672 | 0.1588 | 0.097 |
| H(21B) | 2i | 0.1767 | 0.5315 | 0.1936 | 0.097 |
| H(26A) | 2i | 0.8415 | 0.1942 | 0.2263 | 0.070 |
| H(26B) | 2i | 0.7434 | 0.2814 | 0.2185 | 0.070 |
| H(27A) | 2i | 0.8280 | 0.2419 | 0.0920 | 0.055 |
| H(27B) | 2i | 0.7343 | 0.3327 | 0.0872 | 0.055 |
| H(29A) | 2i | 1.1302 | 0.3007 | 0.1911 | 0.059 |
| H(29B) | 2i | 1.1149 | 0.2102 | 0.2187 | 0.059 |
| H(30A) | 2i | 1.1530 | 0.2899 | 0.0725 | 0.064 |
| H(30B) | 2i | 1.1316 | 0.2032 | 0.0964 | 0.064 |
| H(33A) | 2i | 0.7617 | 0.6045 | 0.0631 | 0.060 |
| H(33B) | 2i | 0.8635 | 0.5985 | 0.0707 | 0.060 |
| H(34A) | 2i | 0.7608 | 0.5630 | 0.1949 | 0.063 |
| H(34B) | 2i | 0.8661 | 0.5470 | 0.2062 | 0.063 |
| H(38A) | 2i | 0.5847 | −0.0807 | 0.4354 | 0.051 |
| H(38B) | 2i | 0.5555 | −0.1453 | 0.4097 | 0.051 |
| H(39A) | 2i | 0.5152 | 0.0411 | 0.3188 | 0.049 |
| H(39B) | 2i | 0.4915 | −0.0235 | 0.2887 | 0.049 |
| H(41A) | 2i | 0.2855 | 0.2283 | 0.4365 | 0.046 |
| H(41B) | 2i | 0.1851 | 0.2302 | 0.4385 | 0.046 |
| H(42A) | 2i | 0.2498 | 0.3143 | 0.3058 | 0.048 |
| H(42B) | 2i | 0.1512 | 0.3124 | 0.3049 | 0.048 |
| H(45A) | 2i | 0.1551 | −0.0186 | 0.4157 | 0.050 |
| H(45B) | 2i | 0.2470 | −0.1037 | 0.4090 | 0.050 |
| H(46A) | 2i | 0.1058 | 0.0412 | 0.2883 | 0.053 |
| H(46B) | 2i | 0.2063 | −0.0234 | 0.2714 | 0.053 |
| H(49) | 2i | 0.3401 | 0.5863 | 0.3079 | 0.075 |
| H(50) | 2i | 0.5047 | 0.5283 | 0.3285 | 0.097 |
| H(51) | 2i | 0.5892 | 0.4131 | 0.4419 | 0.097 |
| H(53) | 2i | 0.5871 | 0.3065 | 0.5738 | 0.101 |
| H(54) | 2i | 0.5016 | 0.2674 | 0.6657 | 0.102 |
| H(56) | 2i | 0.3371 | 0.2908 | 0.7103 | 0.097 |
| H(57) | 2i | 0.1760 | 0.3626 | 0.6789 | 0.099 |
| H(58) | 2i | 0.1091 | 0.4692 | 0.5581 | 0.075 |
| H(62A) | 2i | 0.8355 | 0.3018 | 0.3370 | 0.064 |
| H(62B) | 2i | 0.9359 | 0.2312 | 0.3251 | 0.064 |
| H(63A) | 2i | 0.9683 | 0.1370 | 0.4502 | 0.057 |
| H(63B) | 2i | 0.8786 | 0.2121 | 0.4705 | 0.057 |
| H(65A) | 2i | 0.5730 | 0.1328 | 0.4461 | 0.074 |
| H(65B) | 2i | 0.5825 | 0.2123 | 0.4646 | 0.074 |
| H(66A) | 2i | 0.5466 | 0.2155 | 0.3188 | 0.094 |
| H(66B) | 2i | 0.5723 | 0.2902 | 0.3316 | 0.094 |
| H(3A) | 2i | 0.7526 | −0.1124 | 0.2175 | 0.209 |
| H(2A) | 2i | 0.6633 | −0.0815 | 0.0958 | 0.209 |
| H(1A) | 2i | 0.8546 | −0.1824 | 0.0410 | 0.209 |
| H(24A) | 2i | −0.0062 | 0.6306 | 0.4063 | 0.209 |
| H(22A) | 2i | 0.0910 | 0.6506 | 0.2641 | 0.209 |
| H(23A) | 2i | 0.2001 | 0.6509 | 0.4596 | 0.209 |
| H(22B) | 2i | 0.1417 | 0.6417 | 0.2484 | 0.209 |
| H(69A) | 2i | 0.8567 | −0.1250 | 0.4390 | 0.057 |
| H(69B) | 2i | 0.9513 | −0.1158 | 0.4256 | 0.057 |
| H(70A) | 2i | 0.8052 | −0.0562 | 0.3087 | 0.046 |
| H(70B) | 2i | 0.8943 | −0.0374 | 0.2931 | 0.046 |
| H(1B) | 2i | 0.7690 | −0.1304 | −0.0107 | 0.074 |
| H(2B) | 2i | 0.6355 | −0.1233 | 0.0932 | 0.065 |
| H(3B) | 2i | 0.7990 | −0.1703 | 0.1798 | 0.058 |
| H(7) | 2i | 0.5909 | 0.7092 | 0.1188 | 0.110 |
| H(9) | 2i | −0.0459 | 0.6434 | 0.1775 | 0.108 |
| H(13) | 2i | 0.6931 | 0.1380 | 0.1343 | 0.083 |
| H(17) | 2i | 1.3674 | 0.1151 | 0.1033 | 0.098 |
| H(23B) | 2i | 0.0944 | 0.6840 | 0.4529 | 0.080 |
| H(24B) | 2i | 0.0253 | 0.5423 | 0.3943 | 0.079 |
| H(28) | 2i | 0.0532 | −0.1135 | 0.2635 | 0.085 |
| H(31) | 2i | 0.7886 | −0.2084 | 0.3882 | 0.070 |
| H(35) | 2i | 0.3794 | 0.3131 | 0.2764 | 0.272 |
| H(38) | 2i | 0.9918 | 0.3931 | 0.3295 | 0.087 |
Atomic displacement parameters (Å2).
| Atom | Site | x | y | z | U11 | U22 | U33 | U12 | U13 | U23 |
|---|---|---|---|---|---|---|---|---|---|---|
| Co(1) | 2i | 0.72001(5) | −0.02489(5) | 0.06879(4) | 0.0311(4) | 0.0329(5) | 0.0414(5) | −0.0160(4) | 0.0063(4) | −0.0176(4) |
| Co(2) | 2i | 0.17706(6) | 0.55117(5) | 0.40345(5) | 0.0387(5) | 0.0298(5) | 0.0429(5) | −0.0168(4) | 0.0057(4) | −0.0147(4) |
| C(1) | 2i | 0.8933(4) | 0.0070(4) | 0.1019(4) | 0.038(4) | 0.043(4) | 0.056(4) | −0.021(3) | 0.010(3) | −0.025(3) |
| C(2) | 2i | 0.9532(5) | 0.0501(5) | 0.0848(4) | 0.050(4) | 0.058(4) | 0.053(5) | −0.030(4) | 0.006(3) | −0.030(4) |
| C(3) | 2i | 0.9426(4) | 0.1109(5) | 0.0141(4) | 0.037(4) | 0.063(5) | 0.066(5) | −0.032(4) | 0.019(3) | −0.040(4) |
| C(4) | 2i | 0.8714(4) | 0.1322(4) | −0.0420(4) | 0.039(4) | 0.031(3) | 0.058(4) | −0.018(3) | 0.014(3) | −0.021(3) |
| C(5) | 2i | 0.8571(5) | 0.1922(4) | −0.1197(4) | 0.054(4) | 0.035(4) | 0.069(5) | −0.025(3) | 0.015(4) | −0.016(4) |
| C(6) | 2i | 0.7885(5) | 0.2072(5) | −0.1698(4) | 0.068(5) | 0.043(4) | 0.055(5) | −0.023(4) | 0.006(4) | 0.000(4) |
| C(7) | 2i | 0.7251(5) | 0.1664(4) | −0.1478(4) | 0.052(4) | 0.043(4) | 0.041(4) | −0.017(4) | 0.001(3) | −0.002(3) |
| C(8) | 2i | 0.6533(6) | 0.1787(6) | −0.1981(4) | 0.078(6) | 0.080(6) | 0.051(5) | −0.033(5) | −0.015(4) | −0.002(4) |
| C(9) | 2i | 0.5970(6) | 0.1364(6) | −0.1714(5) | 0.075(6) | 0.084(6) | 0.056(5) | −0.038(5) | −0.023(4) | −0.005(5) |
| C(10) | 2i | 0.6094(5) | 0.0832(5) | −0.0948(4) | 0.050(4) | 0.062(5) | 0.066(5) | −0.029(4) | −0.014(4) | −0.015(4) |
| C(11) | 2i | 0.7352(4) | 0.1089(4) | −0.0726(4) | 0.033(3) | 0.033(4) | 0.045(4) | −0.008(3) | 0.001(3) | −0.014(3) |
| C(12) | 2i | 0.8120(4) | 0.0888(4) | −0.0187(3) | 0.028(3) | 0.029(3) | 0.043(4) | −0.008(3) | 0.004(3) | −0.015(3) |
| C(13) | 2i | 0.5443(4) | 0.1009(4) | 0.1275(4) | 0.028(3) | 0.033(4) | 0.057(4) | −0.010(3) | 0.003(3) | −0.019(3) |
| C(14) | 2i | 0.4956(4) | 0.1851(4) | 0.1521(3) | 0.036(4) | 0.038(4) | 0.058(4) | −0.017(3) | 0.005(3) | −0.025(3) |
| C(15) | 2i | 0.4654(5) | 0.2744(4) | 0.0822(4) | 0.047(4) | 0.041(4) | 0.066(5) | −0.012(3) | 0.012(3) | −0.032(4) |
| C(16) | 2i | 0.4784(5) | 0.3947(5) | 0.1172(5) | 0.038(4) | 0.043(4) | 0.110(7) | −0.018(4) | 0.011(4) | −0.036(4) |
| C(17) | 2i | 0.4958(5) | 0.5036(5) | 0.1697(5) | 0.068(5) | 0.071(6) | 0.111(7) | −0.045(5) | 0.004(5) | −0.039(5) |
| C(18) | 2i | 0.4944(5) | 0.5886(5) | 0.1143(5) | 0.067(5) | 0.065(5) | 0.104(7) | −0.041(5) | 0.007(5) | −0.035(5) |
| C(19) | 2i | 0.5518(5) | 0.6212(6) | 0.1497(5) | 0.065(5) | 0.064(5) | 0.080(6) | −0.044(5) | 0.015(5) | −0.035(5) |
| C(20) | 2i | 0.3407(6) | 0.5096(6) | 0.1494(7) | 0.048(5) | 0.071(6) | 0.24(1) | −0.020(5) | 0.031(6) | −0.107(8) |
| C(21) | 2i | 0.1815(6) | 0.5127(6) | 0.1497(5) | 0.095(7) | 0.102(7) | 0.084(7) | −0.070(6) | 0.018(5) | −0.044(6) |
| C(22) | 2i | 0.1341(6) | 0.5910(6) | 0.0823(5) | 0.073(6) | 0.078(6) | 0.082(6) | −0.035(5) | −0.025(5) | 0.012(5) |
| C(23) | 2i | 0.0261(6) | 0.6457(6) | 0.1030(6) | 0.053(5) | 0.069(6) | 0.094(7) | −0.032(5) | 0.011(5) | −0.050(6) |
| C(24) | 2i | 0.3238(5) | 0.3963(5) | 0.1069(5) | 0.040(4) | 0.047(4) | 0.119(7) | −0.015(4) | 0.005(4) | −0.050(5) |
| C(25) | 2i | 0.7293(4) | 0.1776(4) | 0.1976(4) | 0.031(4) | 0.040(4) | 0.054(5) | −0.012(3) | 0.003(3) | −0.019(4) |
| C(26) | 2i | 0.7799(5) | 0.2353(5) | 0.1954(4) | 0.052(4) | 0.065(5) | 0.082(6) | −0.037(4) | 0.007(4) | −0.041(4) |
| C(27) | 2i | 0.7955(4) | 0.2865(4) | 0.1173(4) | 0.035(4) | 0.042(4) | 0.078(5) | −0.026(3) | 0.008(3) | −0.030(4) |
| C(28) | 2i | 0.9496(4) | 0.2784(5) | 0.1446(4) | 0.041(4) | 0.039(4) | 0.059(5) | −0.018(3) | 0.012(3) | −0.024(3) |
| C(29) | 2i | 1.1056(4) | 0.2652(5) | 0.1750(4) | 0.039(4) | 0.056(4) | 0.065(5) | −0.024(3) | 0.007(3) | −0.032(4) |
| C(30) | 2i | 1.1593(4) | 0.2348(5) | 0.1148(4) | 0.030(4) | 0.073(5) | 0.062(5) | −0.018(3) | 0.006(3) | −0.037(4) |
| C(31) | 2i | 1.2630(4) | 0.1699(4) | 0.1424(4) | 0.036(4) | 0.045(4) | 0.055(5) | −0.018(3) | 0.007(3) | −0.025(4) |
| C(32) | 2i | 0.9650(4) | 0.4201(4) | 0.1263(4) | 0.037(4) | 0.044(4) | 0.077(5) | −0.020(3) | 0.009(3) | −0.036(4) |
| C(33) | 2i | 0.8222(5) | 0.5718(4) | 0.0955(4) | 0.053(4) | 0.027(3) | 0.071(5) | −0.016(3) | 0.002(4) | −0.021(3) |
| C(34) | 2i | 0.8065(5) | 0.5846(4) | 0.1722(4) | 0.058(4) | 0.034(4) | 0.066(5) | −0.020(3) | 0.005(4) | −0.018(3) |
| C(35) | 2i | 0.7696(5) | 0.6876(5) | 0.1623(4) | 0.062(5) | 0.037(4) | 0.052(5) | −0.023(4) | 0.011(4) | −0.016(3) |
| C(36) | 2i | 0.8078(5) | 0.4299(5) | 0.1060(4) | 0.039(4) | 0.048(4) | 0.081(5) | −0.024(4) | 0.007(4) | −0.037(4) |
| C(37) | 2i | 0.6659(4) | −0.1293(4) | 0.3583(4) | 0.032(4) | 0.043(4) | 0.053(4) | −0.018(3) | 0.005(3) | −0.024(3) |
| C(38) | 2i | 0.5748(4) | −0.0957(4) | 0.3920(3) | 0.038(4) | 0.044(4) | 0.050(4) | −0.022(3) | 0.008(3) | −0.018(3) |
| C(39) | 2i | 0.4971(4) | −0.0094(4) | 0.3335(3) | 0.028(3) | 0.041(4) | 0.054(4) | −0.013(3) | 0.011(3) | −0.022(3) |
| C(40) | 2i | 0.3703(4) | 0.1043(4) | 0.3773(4) | 0.034(4) | 0.036(4) | 0.058(4) | −0.015(3) | 0.004(3) | −0.022(3) |
| C(41) | 2i | 0.2362(4) | 0.2279(4) | 0.4076(3) | 0.039(4) | 0.028(3) | 0.055(4) | −0.016(3) | 0.008(3) | −0.023(3) |
| C(42) | 2i | 0.1980(4) | 0.3144(4) | 0.3353(3) | 0.039(4) | 0.030(3) | 0.053(4) | −0.013(3) | 0.004(3) | −0.022(3) |
| C(43) | 2i | 0.1524(5) | 0.4040(4) | 0.3531(3) | 0.047(4) | 0.033(4) | 0.047(4) | −0.021(3) | 0.004(3) | −0.013(3) |
| C(44) | 2i | 0.2175(4) | 0.0997(4) | 0.3906(3) | 0.034(4) | 0.030(3) | 0.048(4) | −0.017(3) | 0.001(3) | −0.014(3) |
| C(45) | 2i | 0.2050(4) | −0.0370(4) | 0.3842(3) | 0.050(4) | 0.030(3) | 0.053(4) | −0.025(3) | 0.004(3) | −0.013(3) |
| C(46) | 2i | 0.1603(4) | −0.0207(4) | 0.3074(4) | 0.040(4) | 0.033(4) | 0.062(5) | −0.021(3) | 0.001(3) | −0.013(3) |
| C(47) | 2i | 0.1290(4) | −0.0946(5) | 0.3152(4) | 0.040(4) | 0.043(4) | 0.055(5) | −0.024(3) | 0.001(3) | −0.019(4) |
| C(48) | 2i | 0.3502(4) | −0.0222(4) | 0.3590(3) | 0.031(3) | 0.029(3) | 0.048(4) | −0.014(3) | 0.003(3) | −0.014(3) |
| C(49) | 2i | 0.3732(6) | 0.5416(5) | 0.3549(4) | 0.080(6) | 0.066(5) | 0.063(5) | −0.048(5) | 0.018(4) | −0.031(4) |
| C(50) | 2i | 0.4732(6) | 0.5058(7) | 0.3667(6) | 0.071(6) | 0.102(7) | 0.128(9) | −0.065(6) | 0.043(6) | −0.079(7) |
| C(51) | 2i | 0.5231(6) | 0.4385(6) | 0.4340(6) | 0.044(5) | 0.087(7) | 0.141(9) | −0.025(5) | 0.016(6) | −0.084(7) |
| C(52) | 2i | 0.4735(5) | 0.4077(5) | 0.4920(5) | 0.046(5) | 0.060(5) | 0.094(6) | −0.018(4) | 0.002(5) | −0.055(5) |
| C(53) | 2i | 0.5209(6) | 0.3365(6) | 0.5643(6) | 0.065(6) | 0.066(6) | 0.115(9) | −0.006(5) | −0.028(6) | −0.053(6) |
| C(54) | 2i | 0.4695(7) | 0.3129(5) | 0.6187(6) | 0.095(8) | 0.042(5) | 0.089(7) | −0.011(5) | −0.046(6) | −0.013(5) |
| C(55) | 2i | 0.3683(6) | 0.3548(5) | 0.6073(4) | 0.079(6) | 0.048(5) | 0.057(5) | −0.024(4) | −0.021(5) | −0.019(4) |
| C(56) | 2i | 0.3096(8) | 0.3340(6) | 0.6615(5) | 0.129(8) | 0.064(6) | 0.044(5) | −0.050(6) | 0.001(6) | −0.003(4) |
| C(57) | 2i | 0.2147(7) | 0.3760(6) | 0.6432(5) | 0.114(8) | 0.090(7) | 0.055(6) | −0.067(6) | 0.009(5) | −0.010(5) |
| C(58) | 2i | 0.1751(6) | 0.4401(5) | 0.5700(4) | 0.078(5) | 0.072(5) | 0.053(5) | −0.050(5) | 0.019(4) | −0.020(4) |
| C(59) | 2i | 0.3203(5) | 0.4212(4) | 0.5347(4) | 0.063(5) | 0.035(4) | 0.047(4) | −0.023(4) | −0.005(4) | −0.017(3) |
| C(60) | 2i | 0.3750(5) | 0.4484(4) | 0.4769(4) | 0.048(4) | 0.035(4) | 0.063(5) | −0.017(3) | −0.005(4) | −0.027(4) |
| C(61) | 2i | 0.9453(4) | 0.3154(4) | 0.3786(4) | 0.041(4) | 0.041(4) | 0.066(5) | −0.021(3) | 0.012(4) | −0.023(4) |
| C(62) | 2i | 0.9009(5) | 0.2597(5) | 0.3606(4) | 0.052(4) | 0.058(5) | 0.064(5) | −0.036(4) | 0.005(4) | −0.024(4) |
| C(63) | 2i | 0.9027(4) | 0.1847(4) | 0.4319(4) | 0.043(4) | 0.048(4) | 0.065(5) | −0.027(3) | 0.000(3) | −0.026(4) |
| C(64) | 2i | 0.7497(5) | 0.1824(5) | 0.4268(4) | 0.043(4) | 0.051(4) | 0.069(5) | −0.028(4) | 0.013(3) | −0.036(4) |
| C(65) | 2i | 0.5958(4) | 0.1798(5) | 0.4288(5) | 0.036(4) | 0.077(5) | 0.110(7) | −0.036(4) | 0.041(4) | −0.066(5) |
| C(66) | 2i | 0.5448(5) | 0.2476(5) | 0.3533(5) | 0.035(4) | 0.059(5) | 0.141(8) | −0.020(4) | 0.003(5) | −0.037(6) |
| C(67) | 2i | 0.4360(9) | 0.3040(8) | 0.370(1) | 0.07(1) | 0.055(7) | 0.37(3) | −0.044(7) | −0.08(1) | −0.01(1) |
| C(68) | 2i | 0.7409(4) | 0.0444(4) | 0.4216(3) | 0.048(4) | 0.042(4) | 0.046(4) | −0.026(3) | 0.008(3) | −0.021(3) |
| C(69) | 2i | 0.8839(5) | −0.0861(4) | 0.4072(3) | 0.056(4) | 0.032(4) | 0.058(5) | −0.020(3) | 0.000(3) | −0.018(3) |
| C(70) | 2i | 0.8722(4) | −0.0805(4) | 0.3258(3) | 0.038(4) | 0.029(3) | 0.042(4) | −0.011(3) | 0.000(3) | −0.012(3) |
| C(71) | 2i | 0.9281(4) | −0.1764(4) | 0.3193(4) | 0.038(4) | 0.028(3) | 0.049(4) | −0.011(3) | −0.005(3) | −0.018(3) |
| C(72) | 2i | 0.8922(5) | 0.0534(4) | 0.4106(3) | 0.040(4) | 0.045(4) | 0.045(4) | −0.022(3) | 0.006(3) | −0.022(3) |
| N(1) | 2i | 0.8228(3) | 0.0264(3) | 0.0523(3) | 0.026(3) | 0.036(3) | 0.043(3) | −0.014(2) | 0.002(2) | −0.018(3) |
| N(2) | 2i | 0.6777(3) | 0.0686(3) | −0.0458(3) | 0.033(3) | 0.041(3) | 0.047(3) | −0.017(3) | 0.000(2) | −0.016(3) |
| N(3) | 2i | 0.4203(4) | 0.3604(3) | 0.1007(3) | 0.031(3) | 0.036(3) | 0.104(5) | −0.011(3) | 0.008(3) | −0.038(3) |
| N(4) | 2i | 0.4344(4) | 0.4716(4) | 0.1394(4) | 0.046(4) | 0.057(4) | 0.159(7) | −0.026(3) | 0.014(4) | −0.067(4) |
| N(5) | 2i | 0.2872(4) | 0.4731(5) | 0.1296(5) | 0.035(4) | 0.081(5) | 0.25(1) | −0.024(4) | 0.024(5) | −0.114(6) |
| N(6) | 2i | 0.8528(3) | 0.3340(3) | 0.1220(3) | 0.032(3) | 0.034(3) | 0.084(4) | −0.015(3) | 0.005(3) | −0.034(3) |
| N(7) | 2i | 1.0022(3) | 0.3243(3) | 0.1474(3) | 0.031(3) | 0.040(3) | 0.071(4) | −0.017(3) | 0.008(3) | −0.031(3) |
| N(8) | 2i | 0.8665(3) | 0.4701(3) | 0.1072(3) | 0.034(3) | 0.033(3) | 0.075(4) | −0.016(2) | 0.010(3) | −0.031(3) |
| N(9) | 2i | 0.2593(3) | 0.0154(3) | 0.3785(3) | 0.033(3) | 0.033(3) | 0.053(3) | −0.021(2) | 0.007(2) | −0.023(3) |
| N(10) | 2i | 0.2758(3) | 0.1401(3) | 0.3914(3) | 0.035(3) | 0.027(3) | 0.046(3) | −0.015(2) | 0.005(2) | −0.017(2) |
| N(11) | 2i | 0.4035(3) | 0.0228(3) | 0.3618(3) | 0.027(3) | 0.031(3) | 0.052(3) | −0.014(2) | 0.006(2) | −0.017(2) |
| N(12) | 2i | 0.3249(4) | 0.5143(3) | 0.4079(3) | 0.052(3) | 0.039(3) | 0.048(3) | −0.027(3) | 0.016(3) | −0.023(3) |
| N(13) | 2i | 0.2259(4) | 0.4620(3) | 0.5161(3) | 0.047(3) | 0.040(3) | 0.050(4) | −0.023(3) | 0.008(3) | −0.016(3) |
| N(14) | 2i | 0.8453(3) | 0.1393(3) | 0.4207(3) | 0.038(3) | 0.040(3) | 0.060(4) | −0.022(3) | 0.004(3) | −0.026(3) |
| N(15) | 2i | 0.6997(3) | 0.1330(3) | 0.4269(3) | 0.039(3) | 0.047(3) | 0.062(4) | −0.027(3) | 0.015(3) | −0.034(3) |
| N(16) | 2i | 0.8370(3) | 0.0077(3) | 0.4138(3) | 0.042(3) | 0.033(3) | 0.050(3) | −0.020(3) | 0.004(2) | −0.019(3) |
| O(1) | 2i | 0.8035(3) | −0.1310(3) | 0.0212(2) | 0.047(3) | 0.049(3) | 0.059(3) | −0.017(2) | 0.006(2) | −0.033(2) |
| O(2) | 2i | 0.6153(3) | −0.0679(3) | 0.0658(3) | 0.035(2) | 0.034(2) | 0.065(3) | −0.016(2) | 0.001(2) | −0.022(2) |
| O(3) | 2i | 0.7808(3) | −0.1160(3) | 0.1776(2) | 0.041(2) | 0.030(2) | 0.042(3) | −0.013(2) | 0.006(2) | −0.015(2) |
| O(4) | 2i | 0.6297(3) | 0.0772(3) | 0.1147(2) | 0.032(2) | 0.036(2) | 0.066(3) | −0.017(2) | 0.011(2) | −0.032(2) |
| O(5) | 2i | 0.4982(3) | 0.0601(3) | 0.1184(3) | 0.026(2) | 0.049(3) | 0.112(4) | −0.019(2) | 0.014(2) | −0.049(3) |
| O(6) | 2i | 0.5792(4) | 0.5930(4) | 0.2155(3) | 0.127(5) | 0.118(5) | 0.076(4) | −0.097(4) | 0.012(4) | −0.030(4) |
| O(7) | 2i | 0.5637(4) | 0.6897(4) | 0.0980(3) | 0.082(4) | 0.070(4) | 0.089(4) | −0.046(3) | 0.003(3) | −0.034(3) |
| O(8) | 2i | −0.0320(4) | 0.7000(4) | 0.0516(4) | 0.059(4) | 0.099(5) | 0.091(5) | −0.015(3) | 0.015(3) | −0.033(4) |
| O(9) | 2i | 0.0110(3) | 0.6274(4) | 0.1749(3) | 0.040(3) | 0.056(3) | 0.107(5) | −0.004(3) | −0.020(3) | −0.037(3) |
| O(10) | 2i | 0.5621(3) | 0.3597(3) | 0.1136(3) | 0.033(3) | 0.065(3) | 0.157(6) | −0.020(3) | 0.010(3) | −0.044(4) |
| O(11) | 2i | 0.3057(4) | 0.5732(4) | 0.1762(5) | 0.071(4) | 0.101(5) | 0.257(9) | −0.027(4) | 0.019(5) | −0.129(6) |
| O(12) | 2i | 0.2758(3) | 0.3628(3) | 0.0938(3) | 0.044(3) | 0.067(3) | 0.163(6) | −0.026(3) | 0.010(3) | −0.073(4) |
| O(13) | 2i | 0.7236(3) | 0.1672(3) | 0.1320(3) | 0.051(3) | 0.065(3) | 0.082(4) | −0.039(3) | 0.025(2) | −0.047(3) |
| O(14) | 2i | 0.7006(4) | 0.1446(4) | 0.2531(3) | 0.080(4) | 0.079(4) | 0.060(4) | −0.050(3) | 0.012(3) | −0.020(3) |
| O(15) | 2i | 0.9859(3) | 0.1940(3) | 0.1612(3) | 0.042(3) | 0.042(3) | 0.121(5) | −0.017(2) | 0.007(3) | −0.039(3) |
| O(16) | 2i | 1.2982(3) | 0.1422(4) | 0.2069(3) | 0.043(3) | 0.089(4) | 0.064(4) | −0.014(3) | −0.005(3) | −0.017(3) |
| O(17) | 2i | 1.3107(3) | 0.1490(4) | 0.0869(3) | 0.037(3) | 0.085(4) | 0.083(4) | −0.017(3) | 0.011(2) | −0.056(3) |
| O(18) | 2i | 1.0130(3) | 0.4588(3) | 0.1269(3) | 0.046(3) | 0.058(3) | 0.146(5) | −0.032(3) | 0.014(3) | −0.058(3) |
| O(19) | 2i | 0.6827(3) | 0.7420(3) | 0.1392(3) | 0.051(3) | 0.034(3) | 0.087(4) | −0.018(2) | 0.004(3) | −0.025(3) |
| O(20) | 2i | 0.8287(3) | 0.7126(3) | 0.1781(3) | 0.048(3) | 0.039(3) | 0.075(3) | −0.018(2) | 0.008(2) | −0.028(2) |
| O(21) | 2i | 0.7219(3) | 0.4760(3) | 0.0909(3) | 0.032(3) | 0.049(3) | 0.164(6) | −0.013(2) | −0.005(3) | −0.048(3) |
| O(22) | 2i | 0.1354(3) | 0.6450(3) | 0.2917(2) | 0.083(3) | 0.041(3) | 0.039(3) | −0.016(3) | 0.008(2) | −0.016(2) |
| O(23) | 2i | 0.1456(3) | 0.6688(3) | 0.4360(3) | 0.068(3) | 0.046(3) | 0.059(3) | −0.030(3) | 0.017(3) | −0.030(2) |
| O(24) | 2i | 0.0363(3) | 0.5751(3) | 0.4123(3) | 0.045(3) | 0.041(3) | 0.082(4) | −0.023(2) | 0.011(2) | −0.029(2) |
| O(25) | 2i | 0.2070(3) | 0.4351(3) | 0.3675(2) | 0.038(2) | 0.043(3) | 0.070(3) | −0.021(2) | 0.009(2) | −0.033(2) |
| O(26) | 2i | 0.0639(3) | 0.4444(3) | 0.3522(3) | 0.038(3) | 0.044(3) | 0.105(4) | −0.019(2) | 0.010(3) | −0.041(3) |
| O(27) | 2i | 0.1341(3) | 0.1348(3) | 0.4010(3) | 0.034(3) | 0.049(3) | 0.085(4) | −0.020(2) | 0.014(2) | −0.033(3) |
| O(28) | 2i | 0.0648(3) | −0.0696(3) | 0.2589(3) | 0.066(3) | 0.055(3) | 0.062(3) | −0.040(3) | −0.003(3) | −0.018(3) |
| O(29) | 2i | 0.1610(4) | −0.1694(3) | 0.3651(3) | 0.098(4) | 0.040(3) | 0.085(4) | −0.044(3) | −0.038(3) | 0.008(3) |
| O(30) | 2i | 0.3814(3) | −0.0926(3) | 0.3427(3) | 0.042(3) | 0.041(3) | 0.092(4) | −0.014(2) | 0.007(2) | −0.040(3) |
| O(31) | 2i | 0.7401(3) | −0.1956(3) | 0.4090(2) | 0.030(2) | 0.045(3) | 0.059(3) | −0.012(2) | 0.007(2) | −0.018(2) |
| O(32) | 2i | 0.6695(3) | −0.0986(3) | 0.2911(3) | 0.043(3) | 0.082(4) | 0.044(3) | −0.014(3) | 0.011(2) | −0.022(3) |
| O(33) | 2i | 0.4182(3) | 0.1419(3) | 0.3789(3) | 0.049(3) | 0.064(3) | 0.147(5) | −0.040(3) | 0.027(3) | −0.061(3) |
| O(34) | 2i | 0.4003(7) | 0.310(1) | 0.404(1) | 0.095(7) | 0.29(2) | 0.60(3) | −0.140(8) | 0.19(1) | −0.39(2) |
| O(35) | 2i | 0.3967(6) | 0.3471(7) | 0.2873(7) | 0.075(6) | 0.115(7) | 0.32(1) | −0.052(5) | 0.053(8) | −0.031(9) |
| O(36) | 2i | 0.7116(3) | 0.2593(3) | 0.4324(3) | 0.052(3) | 0.055(3) | 0.126(5) | −0.028(3) | 0.023(3) | −0.058(3) |
| O(37) | 2i | 0.9572(4) | 0.3166(4) | 0.4414(3) | 0.096(4) | 0.089(4) | 0.069(4) | −0.069(3) | 0.032(3) | −0.049(3) |
| O(38) | 2i | 0.9682(3) | 0.3640(3) | 0.3177(3) | 0.063(3) | 0.056(3) | 0.070(3) | −0.038(3) | 0.004(3) | −0.023(3) |
| O(39) | 2i | 0.9752(3) | 0.0195(3) | 0.4028(3) | 0.038(3) | 0.063(3) | 0.105(4) | −0.025(3) | 0.015(3) | −0.048(3) |
| O(40) | 2i | 0.9981(3) | −0.1891(3) | 0.2821(2) | 0.036(2) | 0.039(2) | 0.060(3) | −0.019(2) | 0.007(2) | −0.024(2) |
| O(41) | 2i | 0.9033(3) | −0.2387(3) | 0.3519(2) | 0.032(2) | 0.032(2) | 0.071(3) | −0.013(2) | 0.008(2) | −0.022(2) |
| O(42) | 2i | 0.6957(3) | 0.0020(3) | 0.4239(3) | 0.060(3) | 0.058(3) | 0.084(4) | −0.042(3) | 0.019(3) | −0.035(3) |
Source of material
A mixture of Co(NO3)2 · 6H2O (0.030 g, 0.1 mmol) 3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoic acid (TTA) (0.036 g 0.1 mmol), 1,10-phenanthroline (phen) (0.020 g, 0.1 mmol), NaOH (0.2 M, 1.5 mL) and H2O (10 mL) was stirred for about 30 min. The resulting solution was sealed in a Teflon-lined stainless autoclave and heated to 373 K for 3 days. The bottle was cooled to ambient temperature spontaneously. Red single crystals (about 66%, based on Co input) were recovered by vacuum filtration, drying in air.
Experimental details
The C-bound H atoms were geometrically placed (C—H = 0.93, 0.97 Å) and refined as riding with Uiso(H) = 1.2Ueq(C).
The O-bound H atoms were geometrically placed (O—H = 0.82 Å) and refined as riding with Uiso(H) = 1.5Ueq(O).
Results and discussion
In recent years, extensive efforts have been focused on the rational design and controlled synthesis of coordination polymers, owing to their intriguing topological structures and potential applications [1–3]. Aromatic multicarboxylates, especially benzene multi-carboxylates, including 1,3-benzenedicarboxylate, 1,3,5-benzenetricarboxylate and 1,2,4,5- benzenetetracarboxylate have been widely utilized to create novel CPs [1–3]. Compared to these rigid ligands, 3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoic acid (TTA) is semi-flexible and longer ligand, and may be good candidates for construction of CPs. In particular, coordination polymers with flexible ligands exhibit more complex and unusual structures, as functional groups on the ligands offer variable configurations. Some studies of metal-organic networks based on TTA ligands were reported. The results show that the ligand exhibits a special ability to formulate the compounds, and can adopt different coordination modes in different chemical environments [4–6]. Most of these compounds have a 2D or 3D structure. In this paper, we select TTA as spacer to obtain a cobalt complex.
There are two crystallographically independent cobalt(II) ions in the structure. Both the Col and Co2 ions are six- coordinated by three oxygen atoms from three aqua ligands, two nitrogen atoms from bidentate chelating phen ligand, and one oxygen atom from one TTA ligand. Their coordination geometry can be described as a distorted octahedron. The Co—N and Co—O bond distances are comparable to those reported for other cobalt complexes. There are four unique TTA anions in the asymmetric unit. Two carboxyl groups of BTB ligand are protonated, so each TTA ligand carries a charge of −1, satisfying the charge balance. Two BTB anions do not participate in the coordination of the Co(II) atoms. In comparable structures, TTA can adopt a μ5-mode to bind metal centers [4, 5], and all carboxyl oxygen atoms are involved in metal coordination. In the title compound, the complex cations and dihydrogen TTA ligands align in neat alternating mode, which is made possible by the well matched ionic size, and interact with each other O—H⋯O hydrogen bonds between the carboxyl groups and coordinated water molecules resulting in the formation of infinite chains. Adjacent chains are linked by O—H⋯O hydrogen bonds formed between the carboxyl groups and coordinated water molecules to create three dimensional networks.
Acknowledgements:
This work was financially supported by the National Natural Science Foundation (No. 21371148 and 81401470), the financial support from Key Scientific and Technological Project of Henan Province (No. 122102310196) and the financial support from Education Project of Henan Province (No. 12 A150019).
References
1. Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D. W.: Hydrogen storage in metal-organic frameworks. Chem. Rev. 112 (2012) 782–835.10.1021/cr200274sSearch in Google Scholar
2. Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; VanDuyne, R. P.; Hupp, J. T.: Metal-organic framework materials as chemical sensors. Chem. Rev. 112 (2012) 1105–1125.10.1021/cr200324tSearch in Google Scholar
3. O'Keeffe, M.; Yaghi, O. M.: Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 112 (2012) 675–702.10.1021/cr200205jSearch in Google Scholar
4. Han, Z. B.; Zhang, G. X.: Solvothermal synthesis of two unique metal-organic frameworks: a 3-fold interpenetrating (3,4,5)-connected network and a 2-fold interpenetrating (4,5)-connected network. CrystEngComm 12 (2010) 348–351.10.1039/B912158GSearch in Google Scholar
5. Han, Z. B.; Zhang, G. X.; Zeng M. H.; Ge, C. H.; Zou, X. H.; Han, G. X.: Synthesis, crystal structure and magnetic properties of two 3-D gadolinium complexes. CrystEngComm 11 (2009) 2629–2633.10.1039/b905663gSearch in Google Scholar
6. Li, H. J.; Xu, Z. Q.; Zhao, B.; Jia, Y. Y.; Hou, H. W.; Fan, Y. T.: Nuclearity control of manganese polymers dependent on structural differences in the coligands and magnetic properties studies. CrystEngComm 16 (2014) 2470–2479.10.1039/c3ce41553hSearch in Google Scholar
7. Bruker (2007) SADABS. Brucker AXS Inc., Madison, Wisconsin, USA.Search in Google Scholar
8. Bruker (2007) SMART and SAINT. Brucker AXS Inc., Madison, Wisconsin, USA.Search in Google Scholar
9. Bruker AXS (2003) SHELXTL Version 6.14. Brucker AXS Inc., Madison, Wisconsin, USA.Search in Google Scholar
10. Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Cryst. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central
©2016 Guang-Jie He et al., published by De Gruyter.
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.
Articles in the same Issue
- Cover and Frontmatter
- Crystal structure of rac-4,4,4-trifluoro-3-hydroxy-3-methylbutanoic acid, C5H7O2F3
- Crystal structure of 5-methyl-2-phenyl-1,3-dioxane-5-carboxylic acid, C12H14O4
- Crystal structure of ethyl 2-(2-(2-(4-chlorophenyl)-3-methylbutanamido)thiazol-4-yl)acetate, C18H21ClN2O3S
- The crystal structure of (4E,11E,31E,38E)-1,4,12,15,18,26,31,39-Octaaza-7,21,24-trihydroxy-penta-cyclo[13·13·13·16,10·120,24·133,37]tetratetraconta-4,6(44),7,9,11,18,20(43),21,23,25,31,33(42),34,36,38-pentadecaene, C36H42N8O3
- Crystal structure of poly[diaqua-μ5-4-(3,5-dicarboxylato-κ3O1:O2:O3-phenoxy)phthalato-κ3O5,O7:O8)(μ2-4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)dicobalt(II)] C24H16N3O11Co2
- Crystal structure of catena-poly[(μ2-acetamido-benzoato-κ2O:O′)triphenyltin(IV)], C27H23NO3Sn
- Crystal structure of chlorido(2,2′-((1E,1′E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanylylidene))bis(methylylidene))diphenolato-κ4N,N′,O,O′)iron(III), C20H20ClFeN2O2
- Crystal structure of (E)-3-(4-tert-butyl)phenyl)-1-(3-chlorophenyl)prop-2-en-1-one, C18H17CIO
- Crystal structure of trans-1,2-bis(pyridinium-4-yl)ethylene–2-carboxy-4-methylbenzoate (1/2), C30H26N2O8
- Crystal structure of poly[aqua-ethylenediamine-tetraacetatolead(II)zinc(II)]
- Crystal structure of (E)-2-((2-(2,4-dinitrophenyl)hydrazono)methyl)-4-nitrophenol — triethylamine (2/1), C32H33N11O14
- Crystal structure of catena-poly[diaqua-bis-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)cadmium(II)] dihydrate, C26H24N2O12Cd
- Crystal structure of 2-(ethoxycarbonyl)-2-(2-nitro-1-phenylethyl)-3-oxopyrrolidinium chloride, C15H19N2O5Cl
- Crystal structure of 4-((pyridin-4-ylmethyl)sulfinyl)pyridine, C11H10N2OS
- Crystal structure of 2,5-diethoxy-1,4-bis[2-(quinoline)ethenyl]benzene, C32H28N2O2
- Crystal structure of diaqua(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)tetrakis(3-carboxy-5-ethylpyridine-2-carboxylato-κ2N,O)dizinc(II), C54H50N8O18Zn2
- Crystal structure of a poly[bis(3,4,5,6-tetrachlorophthalato)neodym(III)potassium(I)] — 4,4′-bipyridine — water (1/1/5.5)
- The second polymorph of triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide, C9H18N4S3
- Crystal structure of 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid dihydrate, C14H16N2O6
- Crystal structure of the catena-poly[bis(1H-imidazole-κN)-(μ2-furan-2,5-dicarboxylato-κ2O1:O4)manganese(II)]monohydrate, C12H12MnN4O6
- Crystal structure of (acetylacetonato-κ2O:O′)bis-((1-(2-hydroxyphenyl)-3-(pyridin-2-yl)prop-2-en-1-one)-κ2C,N)iridium(III), C33H27IrN2O6
- Crystal structure of 1-benzyl-3-(4-methylpyridin-2-yl)-1H-imidazol-3-ium hexafluorophosphate, C16H16F6N3P
- Crystal structure of tetraethylammonium 3,5-dinitrosalicylate, C15H23N3O7
- Crystal structure of 4-[5-(4-fluorophenyl)-3-(4-hydroxyphenyl)-4,5-dihydropyrazol-1-yl] benzenesulfonamide, C21H18FN3O3S
- Crystal structure of 2,4-dichlorobenzene anhydride, C14H6Cl4O3
- Crystal structure of bis(2-hydroxy-2-phenylacetato-κ2O,O′)bis(pyridine-κN)nickel(II), C26H24N2NiO6
- Crystal structure of (E)-4-nitro-2-(((3-(tetrahydro-8λ4-[1,3,2]oxazaborolo[2,3-b][1,3,2]oxaborol-8-yl)phenyl)imino)methyl)phenol – water (1/2), C17H18BN3O5·2H2O
- Crystal structure of 5-(4-carboxyphenoxy)-nicotinic acid, C13H9NO5
- Crystal structure of catena-poly[hexaaquabis(μ2-3-nitrophthalate-κ2O:O′)-(μ2-1,4-bis(4-pyridylmethyl)piperazine-κ2N:N′)dimanganese(II)] dihydrate, C32H42Mn2N6O20
- Crystal structure of diaquabis(bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate-κ4O, O′:/O′′,O′′′)bis-(2,2′-bipyridine-κ2N, N′)dicadmium(II) hydrate
- Crystal structure of (R)-1-(1-(6-fluorobenzo[d]thiazol-2-yl)ethyl)-3-phenylthiourea
- Crystal structure of poly[(μ2-1,4-bis((1H-imidiazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-(1,2-phenylenebis(oxy)dibenzoato-κ4O,O′:O′′,O′′′)nickel(II)], C34H26O6N4Ni
- Crystal structure of 3′,4′,5-trihydroxy-3,7-dimethoxyflavone, C17H14O7
- Crystal structure of n-butyl-chlorido-bis[N-sec-butyl,N-n-propyl-carbamodithioato κ2S,S′]-tin(IV), C20H41ClN2S4Sn
- Crystal structure of poly[bis(μ4-4,4′-(1,2-phenylenebis(oxy))dibenzoato-κ4O:O′:O′′:O′′′)bis(μ3-4,4′-(1,2-phenylenebis(oxy))dibenzoato–κ3O:O′:O′′)(μ2-1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazole-κ2N:N′)tetracobalt(II)], C94H62O24N4Co4
- Crystal structure of catenapoly[diaqua-(μ24,4′-bipyridine)-κ2N:N′)-bis(2,6-difluorobenzoate)-κO)nickel(II)] ethanol monosolvate, C28H30F4N2O8Ni
- Crystal structure of 2-(9H-fluoren-9-ylidene)hydrazine-1-carbothioamide, C14H11N3S
- Crystal structure of 2-(4-methoxyphenyl)-2,3-dihydro-1H-perimidine, C18H16N2O
- Crystal structure of catena-poly[diaquabis(μ2-3-carboxybenzene-1,2-dicarboxylato-1:2κ2O:O′)-(μ2-1,4-bis(2-ethylbenzimidazol-1-ylmethyl)-benzene-1:1′κ2N:N′)dizinc(II)], [Zn2(C26H26N4)(C9H4O6)2(H2O)2]
- Crystal structure of diaquabis(phenoxyacetato-κ2O,O′)-zinc(II), C16H18O8Zn
- Crystal structure of 4-(1H-imidazol-1-yl)-6-pyrimidinylferrocene, C17H14FeN4
- Crystal structure of [2-(4-methoxyphenyl)pyrazine-κ2C,N) chlorido[N,N′-bis-(2,6-diisopropyl-phenyl)imidazol-2-ylidene-κC)] palladium(II), C38H45ClN4OPd
- Crystal structure of 2-(4-acetyl-2,6-dimethyl-phenyl)-5,6-dichloro-isoindole-1,3-dione, C18H13Cl2NO3
- Crystal structure of 4,4′-bipyridin-1-ium 3,3′,5′-tricarboxy-[1,1′-biphenyl]-2-carboxylate, (C26H18N2O8)
- Crystal structure of catena-poly[diaqua-μ2-4,4′-biphenyl-4,4′-diyldipyridine-κ2N:N′-bis(5-carboxy-2,6-dimethylpyridine-3-carboxylato-κO)nickel(II)] dihydrate, C40H40N4O12Ni
- Crystal structure of poly-[μ2-4,4′-bipyridine-κ2N:N′−μ3-thiophene-2,3-di-carboxylato-κ4O,O′, O′′:O′′′ -cadmium(II)]
- Crystal structure of hexaaquamanganese(II) bis(3-carboxythiophene-2-carboxylate) C12H18MnO14S2
- Crystal structure of 4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoic acid, C14H10N4O2
- Crystal structure of (E)-2-(benzo[d]thiazol-2-yl)-3-(pyridin-3-yl)acrylonitrile)
- Crystal structure of catena-poly[2,2′-bipyridinyl-6,6′-dicarboxylato-κ4N,N′,O,O′)-(μ2-2,2′-bipyridinyl-6′-carboxyl-6-carboxylato-κ5N,N′,O,O′:O′′)samarium(III)] monohydrate, C24H13N4O8Sm · H2O
- Crystal structure of catena-poly[bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato)-κ2N:O)copper(II)] dihydrate, C28H22N8O6Cu
- Crystal structure of catena-poly[tetraaqua-(μ2-4,4′-bipyridine-k2N:N′)-zinc(II)] fumarate tetrahydrate, C14H26N2O12Zn
- Crystal structure of triaqua-(1,10-phenanthroline)-(dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoato) cobalt(II)dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoate, C72H82Co2N16O42
- Crystal structure of poly[dibromido-(μ2–4,4′-bis-(pyrid-4-yl)biphenyl-κ2N:N′)lead(II)], C22H16N2PbBr2
- Crystal structure of catena-poly[diaqua-bis(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)-cobalt(II)]dihydrate, C26H24N2O12Co
- Crystal structure of 5-(4-pyridyl)pyrimidine–4,4′-bipyridine–1,3,5-benzenetriol–water (1:1:1:1), C25H23N5O4
- Crystal structure of 5-hydroxy-4-((4-hydroxyphenyl)imino)naphthalen-1(4H)-one monohydrate, C16H11NO3 · 0.5H2O
- Crystal structure of 2-amino-N-(4-methoxyphenyl)benzamide, C14H14N2O2
- Crystal structure of (2,5-dihydroxyphenyl)-(4-hydroxy-3,5-dimethoxyphenyl)methanone, C15H14O6
- Crystal structure of dichlorido[bis(2-hydroxyethyl)5′-([2,2′:6′,2′′-terpyridin]-4′-yl)-[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato]zinc(II), C39H31Cl2N3O6Zn
- Crystal structure of bis[4-(3-carboxy-6-fluoro-1-(4-fluorophenyl)-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium] benzene-1,4-dicarboxylate (C20H18F2N3O3)2(C8H4O4), C48H40F4N6O10
- Crystal structure of (2,5-dihydroxyphenyl)-(4-methoxyphenyl)methanone, C14H12O4
- Crystal structure of photochromic 1-(2-methyl-5-phenyl-3-thienyl-2-[2-methyl-5-(4-ethoxylphenyl)-3-thienyl] 3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H22F6OS2
- Crystal structure of poly[diaquabis(μ2-biphenyl-2,4′-dicarboxylato-κ2O:O′)tris(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)dicobalt(II)] monohydrat, C82H64N12O11Co2
- Crystal structure of 2-amino-4-(3,4-difluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12N2O2F2
- Crystal structure of poly[(di-μ2-aqua-κ2O:O)bis(μ5-oxalato-1:2κ2O1; 1κ1O2; 3:4:5κ3O3; 3κ1O4)(μ4-oxalato-1:2κ2O1; 2:3κ2O2; 3:4κ2O3; 4:1κ2O4)dizinc(II)disodium(I)]
- Crystal structure of tetraethylammonium hexachloridotantalate(V), C8H20Cl6NTa
- Crystal structure of (E)-2,4-dibromo-6-(((2-nitrophenyl)imino)methyl)phenol, C13H8Br2N2O3
- The crystal structure of 6-chloro-2,4-diphenylquinoline
- Crystal structure of (E)-2-(((1,10-phenanthrolin-5-yl)imino)methyl)-5-methylphenol monohydrate, C20H15N3O·H2O
- Crystal structure of tris(3-(2-pyridyl)pyrazole)zinc(II)tetrachlorido zincate(II), C24H21Cl4N9Zn2
- Crystal structure of 4-chloro-N,N-diethyl-6-(piperidin-1-yl)-1,3,5-triazin-2-amine, C12H20ClN5
- The crystal structure of 4-allyl-5-benzyl-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H13N3O
- Crystal structure of diethyl 2-(((2-(pyridin-3-ylthio)phenyl)amino)methylene)malonate, C19H20N2O4S
- Crystal structure of fac-tricarbonyl(2-(isopropylimino)methyl-5-methylphenolatido-κ2N,O)(pyridine-κN)rhenium(I), C19H19N2O4Re
- Crystal structure of 1,3,6,8-tetrakis(p-tolylthio)pyrene, C44H34S4
- Crystal structure of catena-poly-(diaqua-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)-(4-methylphthalato-κ2O,O′)-cobalt(II)trihydrate, C21H26CoN2O9
- Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re
- Crystal structure of 3-(thiophen-2-yl)-5-(p-tolyl)-4,5-dihydro-1H-pyrazole-1-carboxamide
- Crystal structure of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate(II), [C6H11N2]2[CdBr4]
- Crystal structure of N′-(adamantan-2-ylidene)-isonicotinohydrazide, C16H19N3O
- Crystal structure of trans-tetraaquabis(4-(pyridin-4-ylsulfonyl)pyridine-κN)cobalt(II) diperchlorate dihydrate, C20H28Cl2CoN4O18S2
- Crystal structure of (Z)-4-(furan-2-yl(p-tolylamino)methylene)-3-methyl-1-p-tolyl-1H-pyrazol-5(4H)-one, C23H21N3O2
- Crystal structure of 2-[(4-fluorobenzyl)sulfanyl]-4-(2-methylpropyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C16H16FN3OS
- Crystal structure of poly[octaaqua-tris(benzene-1,2,4,5-tetracarboxylato)tetralanthanum(III)] hexahydrate, C30H34La4O38
- Crystal structure of trans-tetraaqua-bis(4,4′-sulfonyldipyridine-κN)zinc(II) diperchlorate dihydrate, C20H28Cl2ZnN4O18S2
- Crystal structure of 4-nitro-thiophene-2-carboxylic acid, a structure with a Z′ = 4, C5H3NO4S
- Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se4
- Crystal structure of 5-(adamantan-1-yl)-3-[(4-chloroanilino)methyl]-2,3-dihydro-1,3,4-oxadiazole-2-thione, C19H22ClN3OS
- Crystal structure of hexaaquamagnesium(II) 5,5′-bitetrazole-1,1′-diolate, C2H12N8O8Mg
- The crystal structure of catena-poly[(μ2-1,1′-benzene-1,4-diylbis(1H-benzimidazole-κ2N:N′)silver(I)] nitrate, C20H14N5AgO3
- The crystal structure of 1-(2-(4-chlorophenoxy)-4-chlorophenyl)ethanone, C14H10Cl2O2
- The crystal structure of 3,5-dinitro-1,3,5-oxadiazinane, C3H6N4O5
- Crystal structure of methyl 5-methoxy 1H-indole-2-carboxylate, C11H11NO3
- Crystal structure of (Z)-1-(((3-acetyl-2-hydroxyphenyl)amino)methylene)naphthalen-2(1H)-one, C19H15NO3
- Crystal structure of (Z)-5-(4-chlorobenzylidene)-2-thioxothiazolidin-4-one —dimethylsulfoxide (1:1), C12H12ClNO2S3
- Crystal structure of 5,5′-((4-(trifluoromethyl)phenyl)methylene)bis(1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione) – diethylamine – dichloromethane (1/1/1) C25H32Cl2F3N5O6
- Crystal structure of 2-(dimethylsulfanylidene)-N-(4-methoxyphenyl)-3-oxo-3-phenylpropanamide
- Crystal structure of (1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)platinum(II), C14H8N4PtS2
- Crystal structure of di(μ2-chlorido)bis[2-(2-pyridyl)phenyl-κ2N,C1]dipalladium(II), C22H16Cl2N2Pd2
- Crystal structure of trans-dibromidodi(pyridine-κN)palladium(II), PdBr2(C5H5N)2
Articles in the same Issue
- Cover and Frontmatter
- Crystal structure of rac-4,4,4-trifluoro-3-hydroxy-3-methylbutanoic acid, C5H7O2F3
- Crystal structure of 5-methyl-2-phenyl-1,3-dioxane-5-carboxylic acid, C12H14O4
- Crystal structure of ethyl 2-(2-(2-(4-chlorophenyl)-3-methylbutanamido)thiazol-4-yl)acetate, C18H21ClN2O3S
- The crystal structure of (4E,11E,31E,38E)-1,4,12,15,18,26,31,39-Octaaza-7,21,24-trihydroxy-penta-cyclo[13·13·13·16,10·120,24·133,37]tetratetraconta-4,6(44),7,9,11,18,20(43),21,23,25,31,33(42),34,36,38-pentadecaene, C36H42N8O3
- Crystal structure of poly[diaqua-μ5-4-(3,5-dicarboxylato-κ3O1:O2:O3-phenoxy)phthalato-κ3O5,O7:O8)(μ2-4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)dicobalt(II)] C24H16N3O11Co2
- Crystal structure of catena-poly[(μ2-acetamido-benzoato-κ2O:O′)triphenyltin(IV)], C27H23NO3Sn
- Crystal structure of chlorido(2,2′-((1E,1′E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanylylidene))bis(methylylidene))diphenolato-κ4N,N′,O,O′)iron(III), C20H20ClFeN2O2
- Crystal structure of (E)-3-(4-tert-butyl)phenyl)-1-(3-chlorophenyl)prop-2-en-1-one, C18H17CIO
- Crystal structure of trans-1,2-bis(pyridinium-4-yl)ethylene–2-carboxy-4-methylbenzoate (1/2), C30H26N2O8
- Crystal structure of poly[aqua-ethylenediamine-tetraacetatolead(II)zinc(II)]
- Crystal structure of (E)-2-((2-(2,4-dinitrophenyl)hydrazono)methyl)-4-nitrophenol — triethylamine (2/1), C32H33N11O14
- Crystal structure of catena-poly[diaqua-bis-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)cadmium(II)] dihydrate, C26H24N2O12Cd
- Crystal structure of 2-(ethoxycarbonyl)-2-(2-nitro-1-phenylethyl)-3-oxopyrrolidinium chloride, C15H19N2O5Cl
- Crystal structure of 4-((pyridin-4-ylmethyl)sulfinyl)pyridine, C11H10N2OS
- Crystal structure of 2,5-diethoxy-1,4-bis[2-(quinoline)ethenyl]benzene, C32H28N2O2
- Crystal structure of diaqua(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)tetrakis(3-carboxy-5-ethylpyridine-2-carboxylato-κ2N,O)dizinc(II), C54H50N8O18Zn2
- Crystal structure of a poly[bis(3,4,5,6-tetrachlorophthalato)neodym(III)potassium(I)] — 4,4′-bipyridine — water (1/1/5.5)
- The second polymorph of triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide, C9H18N4S3
- Crystal structure of 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid dihydrate, C14H16N2O6
- Crystal structure of the catena-poly[bis(1H-imidazole-κN)-(μ2-furan-2,5-dicarboxylato-κ2O1:O4)manganese(II)]monohydrate, C12H12MnN4O6
- Crystal structure of (acetylacetonato-κ2O:O′)bis-((1-(2-hydroxyphenyl)-3-(pyridin-2-yl)prop-2-en-1-one)-κ2C,N)iridium(III), C33H27IrN2O6
- Crystal structure of 1-benzyl-3-(4-methylpyridin-2-yl)-1H-imidazol-3-ium hexafluorophosphate, C16H16F6N3P
- Crystal structure of tetraethylammonium 3,5-dinitrosalicylate, C15H23N3O7
- Crystal structure of 4-[5-(4-fluorophenyl)-3-(4-hydroxyphenyl)-4,5-dihydropyrazol-1-yl] benzenesulfonamide, C21H18FN3O3S
- Crystal structure of 2,4-dichlorobenzene anhydride, C14H6Cl4O3
- Crystal structure of bis(2-hydroxy-2-phenylacetato-κ2O,O′)bis(pyridine-κN)nickel(II), C26H24N2NiO6
- Crystal structure of (E)-4-nitro-2-(((3-(tetrahydro-8λ4-[1,3,2]oxazaborolo[2,3-b][1,3,2]oxaborol-8-yl)phenyl)imino)methyl)phenol – water (1/2), C17H18BN3O5·2H2O
- Crystal structure of 5-(4-carboxyphenoxy)-nicotinic acid, C13H9NO5
- Crystal structure of catena-poly[hexaaquabis(μ2-3-nitrophthalate-κ2O:O′)-(μ2-1,4-bis(4-pyridylmethyl)piperazine-κ2N:N′)dimanganese(II)] dihydrate, C32H42Mn2N6O20
- Crystal structure of diaquabis(bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate-κ4O, O′:/O′′,O′′′)bis-(2,2′-bipyridine-κ2N, N′)dicadmium(II) hydrate
- Crystal structure of (R)-1-(1-(6-fluorobenzo[d]thiazol-2-yl)ethyl)-3-phenylthiourea
- Crystal structure of poly[(μ2-1,4-bis((1H-imidiazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-(1,2-phenylenebis(oxy)dibenzoato-κ4O,O′:O′′,O′′′)nickel(II)], C34H26O6N4Ni
- Crystal structure of 3′,4′,5-trihydroxy-3,7-dimethoxyflavone, C17H14O7
- Crystal structure of n-butyl-chlorido-bis[N-sec-butyl,N-n-propyl-carbamodithioato κ2S,S′]-tin(IV), C20H41ClN2S4Sn
- Crystal structure of poly[bis(μ4-4,4′-(1,2-phenylenebis(oxy))dibenzoato-κ4O:O′:O′′:O′′′)bis(μ3-4,4′-(1,2-phenylenebis(oxy))dibenzoato–κ3O:O′:O′′)(μ2-1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazole-κ2N:N′)tetracobalt(II)], C94H62O24N4Co4
- Crystal structure of catenapoly[diaqua-(μ24,4′-bipyridine)-κ2N:N′)-bis(2,6-difluorobenzoate)-κO)nickel(II)] ethanol monosolvate, C28H30F4N2O8Ni
- Crystal structure of 2-(9H-fluoren-9-ylidene)hydrazine-1-carbothioamide, C14H11N3S
- Crystal structure of 2-(4-methoxyphenyl)-2,3-dihydro-1H-perimidine, C18H16N2O
- Crystal structure of catena-poly[diaquabis(μ2-3-carboxybenzene-1,2-dicarboxylato-1:2κ2O:O′)-(μ2-1,4-bis(2-ethylbenzimidazol-1-ylmethyl)-benzene-1:1′κ2N:N′)dizinc(II)], [Zn2(C26H26N4)(C9H4O6)2(H2O)2]
- Crystal structure of diaquabis(phenoxyacetato-κ2O,O′)-zinc(II), C16H18O8Zn
- Crystal structure of 4-(1H-imidazol-1-yl)-6-pyrimidinylferrocene, C17H14FeN4
- Crystal structure of [2-(4-methoxyphenyl)pyrazine-κ2C,N) chlorido[N,N′-bis-(2,6-diisopropyl-phenyl)imidazol-2-ylidene-κC)] palladium(II), C38H45ClN4OPd
- Crystal structure of 2-(4-acetyl-2,6-dimethyl-phenyl)-5,6-dichloro-isoindole-1,3-dione, C18H13Cl2NO3
- Crystal structure of 4,4′-bipyridin-1-ium 3,3′,5′-tricarboxy-[1,1′-biphenyl]-2-carboxylate, (C26H18N2O8)
- Crystal structure of catena-poly[diaqua-μ2-4,4′-biphenyl-4,4′-diyldipyridine-κ2N:N′-bis(5-carboxy-2,6-dimethylpyridine-3-carboxylato-κO)nickel(II)] dihydrate, C40H40N4O12Ni
- Crystal structure of poly-[μ2-4,4′-bipyridine-κ2N:N′−μ3-thiophene-2,3-di-carboxylato-κ4O,O′, O′′:O′′′ -cadmium(II)]
- Crystal structure of hexaaquamanganese(II) bis(3-carboxythiophene-2-carboxylate) C12H18MnO14S2
- Crystal structure of 4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoic acid, C14H10N4O2
- Crystal structure of (E)-2-(benzo[d]thiazol-2-yl)-3-(pyridin-3-yl)acrylonitrile)
- Crystal structure of catena-poly[2,2′-bipyridinyl-6,6′-dicarboxylato-κ4N,N′,O,O′)-(μ2-2,2′-bipyridinyl-6′-carboxyl-6-carboxylato-κ5N,N′,O,O′:O′′)samarium(III)] monohydrate, C24H13N4O8Sm · H2O
- Crystal structure of catena-poly[bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato)-κ2N:O)copper(II)] dihydrate, C28H22N8O6Cu
- Crystal structure of catena-poly[tetraaqua-(μ2-4,4′-bipyridine-k2N:N′)-zinc(II)] fumarate tetrahydrate, C14H26N2O12Zn
- Crystal structure of triaqua-(1,10-phenanthroline)-(dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoato) cobalt(II)dihydrogen-3,3′,3′′-(2,4,6-trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanoate, C72H82Co2N16O42
- Crystal structure of poly[dibromido-(μ2–4,4′-bis-(pyrid-4-yl)biphenyl-κ2N:N′)lead(II)], C22H16N2PbBr2
- Crystal structure of catena-poly[diaqua-bis(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:N)-cobalt(II)]dihydrate, C26H24N2O12Co
- Crystal structure of 5-(4-pyridyl)pyrimidine–4,4′-bipyridine–1,3,5-benzenetriol–water (1:1:1:1), C25H23N5O4
- Crystal structure of 5-hydroxy-4-((4-hydroxyphenyl)imino)naphthalen-1(4H)-one monohydrate, C16H11NO3 · 0.5H2O
- Crystal structure of 2-amino-N-(4-methoxyphenyl)benzamide, C14H14N2O2
- Crystal structure of (2,5-dihydroxyphenyl)-(4-hydroxy-3,5-dimethoxyphenyl)methanone, C15H14O6
- Crystal structure of dichlorido[bis(2-hydroxyethyl)5′-([2,2′:6′,2′′-terpyridin]-4′-yl)-[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato]zinc(II), C39H31Cl2N3O6Zn
- Crystal structure of bis[4-(3-carboxy-6-fluoro-1-(4-fluorophenyl)-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium] benzene-1,4-dicarboxylate (C20H18F2N3O3)2(C8H4O4), C48H40F4N6O10
- Crystal structure of (2,5-dihydroxyphenyl)-(4-methoxyphenyl)methanone, C14H12O4
- Crystal structure of photochromic 1-(2-methyl-5-phenyl-3-thienyl-2-[2-methyl-5-(4-ethoxylphenyl)-3-thienyl] 3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H22F6OS2
- Crystal structure of poly[diaquabis(μ2-biphenyl-2,4′-dicarboxylato-κ2O:O′)tris(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2N:N′)dicobalt(II)] monohydrat, C82H64N12O11Co2
- Crystal structure of 2-amino-4-(3,4-difluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12N2O2F2
- Crystal structure of poly[(di-μ2-aqua-κ2O:O)bis(μ5-oxalato-1:2κ2O1; 1κ1O2; 3:4:5κ3O3; 3κ1O4)(μ4-oxalato-1:2κ2O1; 2:3κ2O2; 3:4κ2O3; 4:1κ2O4)dizinc(II)disodium(I)]
- Crystal structure of tetraethylammonium hexachloridotantalate(V), C8H20Cl6NTa
- Crystal structure of (E)-2,4-dibromo-6-(((2-nitrophenyl)imino)methyl)phenol, C13H8Br2N2O3
- The crystal structure of 6-chloro-2,4-diphenylquinoline
- Crystal structure of (E)-2-(((1,10-phenanthrolin-5-yl)imino)methyl)-5-methylphenol monohydrate, C20H15N3O·H2O
- Crystal structure of tris(3-(2-pyridyl)pyrazole)zinc(II)tetrachlorido zincate(II), C24H21Cl4N9Zn2
- Crystal structure of 4-chloro-N,N-diethyl-6-(piperidin-1-yl)-1,3,5-triazin-2-amine, C12H20ClN5
- The crystal structure of 4-allyl-5-benzyl-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H13N3O
- Crystal structure of diethyl 2-(((2-(pyridin-3-ylthio)phenyl)amino)methylene)malonate, C19H20N2O4S
- Crystal structure of fac-tricarbonyl(2-(isopropylimino)methyl-5-methylphenolatido-κ2N,O)(pyridine-κN)rhenium(I), C19H19N2O4Re
- Crystal structure of 1,3,6,8-tetrakis(p-tolylthio)pyrene, C44H34S4
- Crystal structure of catena-poly-(diaqua-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)-(4-methylphthalato-κ2O,O′)-cobalt(II)trihydrate, C21H26CoN2O9
- Crystal structure of tetraethylammonium fac-tricarbonyl(hexafluoroacetylacetonato-κ2O,O′)-(nitrato-κO)rhenium(I), C16H21O8N2F6Re
- Crystal structure of 3-(thiophen-2-yl)-5-(p-tolyl)-4,5-dihydro-1H-pyrazole-1-carboxamide
- Crystal structure of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate(II), [C6H11N2]2[CdBr4]
- Crystal structure of N′-(adamantan-2-ylidene)-isonicotinohydrazide, C16H19N3O
- Crystal structure of trans-tetraaquabis(4-(pyridin-4-ylsulfonyl)pyridine-κN)cobalt(II) diperchlorate dihydrate, C20H28Cl2CoN4O18S2
- Crystal structure of (Z)-4-(furan-2-yl(p-tolylamino)methylene)-3-methyl-1-p-tolyl-1H-pyrazol-5(4H)-one, C23H21N3O2
- Crystal structure of 2-[(4-fluorobenzyl)sulfanyl]-4-(2-methylpropyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C16H16FN3OS
- Crystal structure of poly[octaaqua-tris(benzene-1,2,4,5-tetracarboxylato)tetralanthanum(III)] hexahydrate, C30H34La4O38
- Crystal structure of trans-tetraaqua-bis(4,4′-sulfonyldipyridine-κN)zinc(II) diperchlorate dihydrate, C20H28Cl2ZnN4O18S2
- Crystal structure of 4-nitro-thiophene-2-carboxylic acid, a structure with a Z′ = 4, C5H3NO4S
- Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se4
- Crystal structure of 5-(adamantan-1-yl)-3-[(4-chloroanilino)methyl]-2,3-dihydro-1,3,4-oxadiazole-2-thione, C19H22ClN3OS
- Crystal structure of hexaaquamagnesium(II) 5,5′-bitetrazole-1,1′-diolate, C2H12N8O8Mg
- The crystal structure of catena-poly[(μ2-1,1′-benzene-1,4-diylbis(1H-benzimidazole-κ2N:N′)silver(I)] nitrate, C20H14N5AgO3
- The crystal structure of 1-(2-(4-chlorophenoxy)-4-chlorophenyl)ethanone, C14H10Cl2O2
- The crystal structure of 3,5-dinitro-1,3,5-oxadiazinane, C3H6N4O5
- Crystal structure of methyl 5-methoxy 1H-indole-2-carboxylate, C11H11NO3
- Crystal structure of (Z)-1-(((3-acetyl-2-hydroxyphenyl)amino)methylene)naphthalen-2(1H)-one, C19H15NO3
- Crystal structure of (Z)-5-(4-chlorobenzylidene)-2-thioxothiazolidin-4-one —dimethylsulfoxide (1:1), C12H12ClNO2S3
- Crystal structure of 5,5′-((4-(trifluoromethyl)phenyl)methylene)bis(1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione) – diethylamine – dichloromethane (1/1/1) C25H32Cl2F3N5O6
- Crystal structure of 2-(dimethylsulfanylidene)-N-(4-methoxyphenyl)-3-oxo-3-phenylpropanamide
- Crystal structure of (1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)platinum(II), C14H8N4PtS2
- Crystal structure of di(μ2-chlorido)bis[2-(2-pyridyl)phenyl-κ2N,C1]dipalladium(II), C22H16Cl2N2Pd2
- Crystal structure of trans-dibromidodi(pyridine-κN)palladium(II), PdBr2(C5H5N)2