Startseite The crystal structure of diphenyl bis(2-((diphenoxyphosphoryl)amino)ethyl)phosphoramidate monohydrate C40H42N3O10P3
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The crystal structure of diphenyl bis(2-((diphenoxyphosphoryl)amino)ethyl)phosphoramidate monohydrate C40H42N3O10P3

  • Chao-Jun Du ORCID logo EMAIL logo , Bin Cai und Dan-Xia Li
Veröffentlicht/Copyright: 9. Dezember 2024
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 240 Heft 1

Abstract

C40H42N3O10P3, monoclinic, P21 (no. 4), a = 9.1649(2) Å, b = 17.1144(3) Å, c = 13.3495(3) Å, β = 109.548(2)°, V = 1973.20(7) Å3, Z = 2, R gt (F) = 0.0559, wR ref (F 2) = 0.1505, T = 99.99(10) K.

CCDC no.: 2405574

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Metallic dark colourless block
Size: 0.24 × 0.15 × 0.11 mm
Wavelength: Cu Kα radiation (1.54184 Å)
μ: 1.91 mm−1
Diffractometer, scan mode: XtaLAB Synergy R, DW system, HyPix, ω
θ max, completeness: 70.1°, 99 %
N(hkl)measured , N(hkl)unique, R int: 18,380, 6,782, 0.066
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 6,103
N(param)refined: 508
Programs: CrysAlisPRO, 1 Olex2, 2 SHELX 3 , 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.6563 (6) 0.6484 (3) 0.8625 (4) 0.0252 (11)
C2 0.7107 (7) 0.7243 (3) 0.8777 (5) 0.0280 (11)
H2 0.654635 0.765523 0.833890 0.034*
C3 0.8502 (7) 0.7388 (4) 0.9590 (5) 0.0311 (12)
H3 0.890096 0.790507 0.970451 0.037*
C4 0.9315 (7) 0.6787 (4) 1.0234 (5) 0.0342 (13)
H4 1.026213 0.689262 1.078662 0.041*
C5 0.8741 (7) 0.6036 (4) 1.0068 (5) 0.0342 (12)
H5 0.929332 0.562410 1.051163 0.041*
C6 0.7359 (6) 0.5877 (4) 0.9256 (5) 0.0286 (11)
H6 0.696850 0.535864 0.913695 0.034*
C7 0.1734 (6) 0.6514 (4) 0.6505 (4) 0.0268 (11)
C8 0.1392 (7) 0.6250 (4) 0.7378 (5) 0.0323 (12)
H8 0.198740 0.584639 0.781470 0.039*
C9 0.0161 (7) 0.6586 (4) 0.7603 (5) 0.0353 (13)
H9 −0.010502 0.640725 0.819338 0.042*
C10 −0.0679 (7) 0.7180 (4) 0.6970 (5) 0.0336 (13)
H10 −0.150911 0.741549 0.713644 0.040*
C11 −0.0324 (7) 0.7435 (4) 0.6100 (5) 0.0334 (12)
H11 −0.092168 0.783799 0.566376 0.040*
C12 0.0907 (6) 0.7104 (4) 0.5857 (5) 0.0294 (12)
H12 0.116823 0.727914 0.526316 0.035*
C13 0.6018 (7) 0.3044 (4) 0.9513 (5) 0.0321 (12)
H13 0.519386 0.284917 0.892301 0.038*
C14 0.6193 (8) 0.2809 (4) 1.0551 (5) 0.0370 (13)
H14 0.549157 0.244127 1.066949 0.044*
C15 0.7375 (8) 0.3107 (4) 1.1403 (5) 0.0384 (13)
H15 0.746624 0.295375 1.210509 0.046*
C16 0.8432 (8) 0.3630 (4) 1.1238 (5) 0.0378 (13)
H16 0.925345 0.382714 1.182633 0.045*
C17 0.8288 (7) 0.3863 (4) 1.0213 (5) 0.0318 (12)
H17 0.900672 0.421981 1.009362 0.038*
C18 0.7086 (7) 0.3570 (3) 0.9372 (4) 0.0277 (11)
C19 1.0475 (6) 0.3400 (4) 0.7683 (4) 0.0297 (11)
C20 1.0607 (7) 0.2683 (4) 0.7261 (5) 0.0344 (13)
H20 0.993689 0.226517 0.728639 0.041*
C21 1.1742 (7) 0.2581 (4) 0.6796 (5) 0.0401 (14)
H21 1.184132 0.208959 0.649457 0.048*
C22 1.2730 (8) 0.3186 (5) 0.6766 (5) 0.0446 (15)
H22 1.350217 0.311129 0.644605 0.053*
C23 1.2583 (8) 0.3892 (5) 0.7203 (6) 0.0503 (16)
H23 1.326308 0.430739 0.718834 0.060*
C24 1.1450 (8) 0.4011 (5) 0.7670 (6) 0.0431 (14)
H24 1.135031 0.450235 0.797296 0.052*
C25 0.2536 (7) 0.5354 (4) 0.1509 (5) 0.0299 (12)
C26 0.3269 (7) 0.5932 (4) 0.1149 (5) 0.0368 (13)
H26 0.322693 0.645968 0.135779 0.044*
C27 0.4075 (8) 0.5727 (4) 0.0471 (6) 0.0447 (15)
H27 0.459898 0.611901 0.021819 0.054*
C28 0.4122 (8) 0.4958 (4) 0.0163 (6) 0.0409 (14)
H28 0.466742 0.482279 −0.030516 0.049*
C29 0.3365 (8) 0.4383 (4) 0.0541 (5) 0.0383 (13)
H29 0.339823 0.385473 0.033128 0.046*
C30 0.2565 (7) 0.4578 (4) 0.1220 (5) 0.0333 (13)
H30 0.204689 0.418799 0.148141 0.040*
C31 −0.0210 (7) 0.5287 (4) 0.3718 (5) 0.0338 (13)
C32 0.0042 (8) 0.4773 (4) 0.4550 (6) 0.0397 (14)
H32 0.100362 0.476861 0.511657 0.048*
C33 −0.1127 (9) 0.4263 (4) 0.4547 (6) 0.0466 (15)
H33 −0.097308 0.390791 0.511944 0.056*
C34 −0.2495 (9) 0.4266 (4) 0.3730 (7) 0.0479 (15)
H34 −0.327884 0.390154 0.372577 0.057*
C35 −0.2758 (8) 0.4795 (5) 0.2908 (7) 0.0483 (16)
H35 −0.373103 0.480312 0.235363 0.058*
C36 −0.1597 (7) 0.5318 (4) 0.2889 (5) 0.0387 (14)
H36 −0.175688 0.568127 0.232439 0.046*
C37 0.5676 (6) 0.5159 (3) 0.6275 (5) 0.0256 (11)
H37A 0.495124 0.493097 0.561430 0.031*
H37B 0.527947 0.503461 0.686120 0.031*
C38 0.7255 (6) 0.4784 (3) 0.6507 (5) 0.0265 (11)
H38A 0.770888 0.494265 0.596190 0.032*
H38B 0.795809 0.495757 0.721030 0.032*
C39 0.6212 (6) 0.6320 (3) 0.5289 (4) 0.0256 (11)
H39A 0.732957 0.620713 0.546470 0.031*
H39B 0.608631 0.689485 0.526319 0.031*
C40 0.5357 (6) 0.5992 (4) 0.4199 (4) 0.0275 (11)
H40A 0.582467 0.620351 0.368596 0.033*
H40B 0.548377 0.541760 0.421766 0.033*
N1 0.7081 (5) 0.3930 (3) 0.6500 (4) 0.0276 (10)
H1 0.669108 0.369276 0.588270 0.033*
N2 0.5700 (5) 0.6011 (3) 0.6154 (4) 0.0240 (10)
N3 0.3698 (5) 0.6180 (3) 0.3827 (4) 0.0303 (11)
H3A 0.340373 0.666913 0.383018 0.036*
O1 0.9361 (4) 0.3549 (2) 0.8176 (3) 0.0275 (9)
O2 0.6875 (4) 0.3852 (2) 0.8345 (3) 0.0276 (9)
O3 0.7129 (5) 0.2584 (2) 0.7383 (3) 0.0300 (9)
O4 0.5121 (4) 0.6296 (2) 0.7874 (3) 0.0261 (8)
O5 0.2967 (4) 0.6159 (2) 0.6247 (3) 0.0262 (8)
O6 0.4690 (4) 0.7382 (2) 0.6478 (3) 0.0283 (9)
O7 0.0987 (5) 0.5813 (2) 0.3726 (3) 0.0309 (9)
O8 0.1639 (4) 0.5559 (3) 0.2151 (3) 0.0288 (9)
O9 0.2948 (5) 0.4719 (3) 0.3774 (3) 0.0336 (9)
P1 0.75639 (15) 0.34067 (8) 0.75578 (11) 0.0238 (3)
P2 0.46376 (15) 0.65409 (8) 0.66534 (11) 0.0234 (3)
P3 0.23987 (16) 0.55039 (8) 0.34105 (11) 0.0267 (3)
O10 0.4465 (5) 0.3407 (3) 0.4801 (3) 0.0318 (9)
H10A 0.460388 0.313930 0.428628 0.048*
H10B 0.397117 0.382368 0.449432 0.048*

1 Source of materials

An amount of 0.25 mol of diethylenetriamine and 0.80 mol of triethylamine was added to 150 mL of dry chloroform in a 500 mL three-necked round bottom flask equipped with a constant dropping stirring, and spherical condensation reflux tube in a nitrogen atmosphere in an ice water bath. After 10 min, 0.75 mol of diphenyl chlorophosphate dissolved in 150 mL of dry chloroform was added dropwise using the constant pressure dropping funnel in 2 h. About 4 h later, the ice water bath was removed and the reaction stayed overnight at room temperature. The solvent was concentrated under reduced pressure and a white precipitate was obtained. The residue was washed with cold distilled water to remove unreacted diphenyl chlorophosphate, then was recrystallized in THF to obtain colorless block crystals with a yield of 94.8 % (based on diethylenetriamine).

2 Experimental details

The structure was solved by Direct Methods with the SHELXS-2018 program. All H-atoms from C were positioned with idealized geometry and refined isotropically (U iso(H) = 1.2 U eq(C)) using a riding model with C–H = 0.950 and 0.951 (benzene ring), 0.989 and 0.990 Å(methylene), and N–H = 0.880 Å, respectively. The H-atoms from O atoms were positioned with idealized geometry and refined isotropically with U iso(H) = 1.5 U eq(O) and O–H = 0.870 Å.

3 Comment

It is well known that many crystal structures of diphenyl phosphoryl based monophosphoramidate, 5 , 6 , 7 some diphosphoramidate 8 , 9 , 10 , 11 , 12 and one tetraphosphoramidate 13 have been reported. Only, one tin(IV) complex 14 containing this type of diphosphoramidate was reported. To date, there is not any single crystal structure of triphosphoramidate published anywhere.

As shown in the figure, the asymmetrical unit is made of three diphenyl phosphoryl groups, one diethylenetriamine moiety losing three protons from different amine groups and one crystal water molecule. All nitrogen atoms are in a planar configuration. All atoms on all six phenyl groups are nearly co-planar.

The two kinds of hydrogen bonds N1–H1⃛O10, N3–H3⃛O3, O10–H10A⃛O9, O10–H10B⃛O6, are linked to generate an one-dimensional double-chain structure. A three dimensional supramolecular structure was obtained by linking the 1D double-chains through the C–H⃛π, van der Waals and other weak intermolecular force. All bond lengths and angles are consistent with the reported results. 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14

Corresponding author: Chao-Jun Du, Academy for Mechanical Discipline Studies, Nanyang Institute of Technology, Nanyang 473000, Henan, P.R. China, E-mail:

  1. Conflict of interest: The authors declare no conflicts of interest regarding this article.

  2. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

References

1. CrysAlisPRO 1.171.43.92a. Rigaku OD, Oxfordshire, England, 2023.10.3917/forum.171.0092aSuche in Google Scholar

2. Bourhis, L. J.; Dolomanov, O. V.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. The Anatomy of a Comprehensive Constrained, Restrained Refinement Program for the Modern Computing Environment-Olex2 Dissected. Acta Cryst. 2015, A71, 59–75; https://doi.org/10.1107/s2053273314022207.Suche in Google Scholar

3. Sheldrick, G. M. Crystal Structure Refinement with SHELXL. Acta Cryst. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Suche in Google Scholar

4. Sheldrick, G. Using Phases to Determine the Space Group. Acta Cryst. 2018, A74, A353; https://doi.org/10.1107/s0108767318096472.Suche in Google Scholar

5. Hasija, A.; Som, S.; Chopra, D. Investigation of Crystal Structures, Energetics and Isostructurality in Halogen-Substituted Phosphoramidates. Acta Crystallogr. 2022, B78, 179–194; https://doi.org/10.1107/s2052520622000889.Suche in Google Scholar PubMed

6. Das, D.; Rao, C. V. S. B.; Sivaraman, N.; Sivaramakrishna, A.; Vijayakrishna, K. Synthesis and Extraction Behavior of Alkyl and Cyclic Aminophosphonates Towards Actinides. Inorg. Chim. Acta 2018, 482, 597–604.10.1016/j.ica.2018.07.002Suche in Google Scholar

7. Sabbaghi, F.; Pourayoubi, M.; Necas, M.; Bartos, P. Diphenyl (Methylamido)Phosphate. Acta Crystallogr. 2012, E68, o2934; https://doi.org/10.1107/s160053681203869x.Suche in Google Scholar PubMed PubMed Central

8. Gholivand, K.; Valmoozi, A. A. E.; Mahzouni, H. R. Structural and Electronic Aspects of Hydrogen Bonding in Two Polymorphs of Butylene-N,N′-bis(O,O′-Diarylphosphoramidate). Acta Crystallogr. 2013, B69, 55–61; https://doi.org/10.1107/s0108768112048331.Suche in Google Scholar

9. Zhang, N.; Cheng, C.-M.; Wang, R.-J. Synthesis and Crystal Structure Analysis of 2-Amino-4,6-Bis(Diphenoxyl Phosphoramide)-1,3,5-Triazine. Chin. J. Struct. Chem. 2012, 31, 1042–1046.Suche in Google Scholar

10. Pourayoubi, M.; Zargaran, P. Tetraphenyl Piperazine-1,4-Diyldiphosphonate. Acta Crystallogr. 2010, E66, o3273–o3274; https://doi.org/10.1107/s1600536810047860.Suche in Google Scholar

11. Smolobochkin, A. V.; Turmanov, R. A.; Abdullaeva, D. S.; Gazizov, A. S.; Voronina, J. K.; Appazov, N. O.; Buzyurova, D. N.; Burilov, A. R.; Pudovik, M. A. 2-(Het)aryl-N-phosphorylpyrrolidines via Cyclization of Phosphorus Acid Amides: A Regioselective Approach. Chem. Sel. 2020, 5, 12045–12050; https://doi.org/10.1002/slct.202003353.Suche in Google Scholar

12. Alviri, B. V.; Pourayoubi, M.; Farhadipour, A.; Necas, M.; Bertolasi, V. A Combined X-Ray Crystallography and Theoretical Study of N–H⃛OX (X is = P and –C) Hydrogen Bonds in Two New Structures with a (C–O)2(N)P(=Y) (Y is O and S) Skeleton. Acta Crystallogr. 2018, C74, 1610–1621.10.1107/S2053229618014006Suche in Google Scholar PubMed

13. Feng, C.; Cao, M. A.; Zhao, Q. Synthesis and Structural Analysis of Two Cyclam Derivatives. J. Mol. Struct. 2021, 1224, 128842.10.1016/j.molstruc.2020.128842Suche in Google Scholar

14. Gholivand, K.; Gholami, A.; Ebrahimi, A. A. V.; Abolghasemi, S. T.; Esrafili, M. D.; Fadaei, F. T.; Schenk, K. J. Triphenyltin(iv) Adducts of Diphosphoryl Ligands: Structural, Electronic and Energy Aspects from X-ray Crystallography and Theoretical Calculations. RSC Adv. 2015, 5, 17482–17492; https://doi.org/10.1039/c4ra12925c.Suche in Google Scholar
Received: 2024-10-06
Accepted: 2024-11-26
Published Online: 2024-12-09
Published in Print: 2025-02-25

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  49. Crystal structure of (E)-2,2′,3,3′-tetrahydro-[1,1′-biindenylidene]-4,4′-diol, C18H16O2
  50. Crystal structure of di-glycylglycinium squarate dihydrate, C12H22N4O12, at 105 K
  51. Crystal structure of {[(4-fluorophenyl)methyl]triphenylphosphonium}dibromocopper(I), [C25H21FP]+[CuBr2]−
  52. Crystal structure of poly[diaqua-bis(μ2-5-((pyridin-4-yl-methyl)amino)benzene-1,3-dicarboxylato-κ 2 N:O)cadmium(II)], C28H26CdN4O10
https://doi.org/10.1515/ncrs-2024-0395
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of the co-crystal 2,4,6-triamino-1,3,5-triazine-1,3-dioxide — acetic acid (1/2) C7H14N6O6
  4. Crystal structure of the dinuclear mercury(II) complex bis(μ2-bromido)-dibromido-bis{1-[(benzotriazol-1-yl)methyl]-1-H-1,3-(2-ethyl-5-methyl-imidazol)-κ1 N} dimercury(II), C26H30N10Hg2Br4
  5. Crystal structure of poly[hexaqua-pentakis(μ4-2,2′-bipyridine-4,4′-dicarboxylato-κ4 O:O′:O″:O‴)-(μ2-2,2′-bipyridine-4,4′-dicarboxylato-κ2 O:O)tetraytterbium(III)] hydrate, C36H26N6O16Yb2
  6. Hydrothermal synthesis and crystal structure of catena-poly[(1,10-phenanthroline-κ 2 N,N′)-bis(μ 2-nitroisophthalato-κ 3 O,O′:O″)nickel(II)], C20H13NiN3O7
  7. Crystal structure of 72,73,75,76-tetrafluoro-25,44-dimethyl-31,33,36,38-tetraoxo-31,32,33,36,37,38-hexahydro-3(2,7)-benzo[lmn][3,8]phenanthrolina-1,5(4,1)-dipyridin-1-iuma-2,4(1,2),7(1,4)-tribenzenacyclooctaphane-11,51-diium hexafluoridophosphate, [C46H28F4N4O4][PF6]2, a dicationic cyclophane
  8. Crystal structure of (E)-2-(4-(1H-imidazol-1-yl)benzylidene)-7-fluoro-3,4-dihydronaphthalen-1(2H)-one, C20H15FN2O
  9. The salt crystal structure of etoricoxib hydrochloride, C18H16Cl2N2O2S
  10. The structure of t-butyl 7-[2-(4-fluorophenyl)-3-phenyl-4-(phenylcarbamoyl)-5-(propan-2-yl)-1H-pyrrol-1-yl]-3,5-dihydroxyheptanoate, C37H43FN2O5
  11. The crystal structure of (μ4-oxo)-tri(μ4-2,2′-bipyridine-6,6′-bis(olato)-κ5 O,O′:N:N′:O″)tetrazinc(II) – methylformamide (1/1), C33H25N7O8Zn4
  12. The co-crystal structure of 4-chlorobenzophenone–salicylhydrazide(1/1), C20H17ClN2O3
  13. Crystal structure of 9-fluoro-4-(6-methoxypyridin-2-yl)-5,6-dihydrobenzo[h]quinazolin-2-amine, C18H15FN4O
  14. The crystal structure of the co-crystal composed of benzhydrazide and 5-aminoisophthalic acid, C8H7NO4⋅C7H8N2O
  15. The cocrystal structure of praziquantel-hesperetin (1/1), C35H38N2O8
  16. Crystal structure of new barium manganese fluorides dihydrates, Ba10Mn2F25·2H2O
  17. The crystal structure of bis[μ2-(3-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)propanoate-κ2O:N)-bis(2,2′-bipyridine-κ2 N, N′)dicopper(II)]dinitrate, C42H36Cu2N12O10
  18. Crystal structure of (3,6-di(2-pyridyl)-4-phenylaminopyridazine-κ2N,N′)-bis(2-(p-toluene)pyridinyl-κ2C,N)-iridium(III) hexafluorophosphate –dichloromethane (1/1), C45H37Cl2F6IrN7P
  19. The crystal structure of 2-(2′-carboxybenzyl)benzoic acid, C15H12O5
  20. The crystal structure of dichlorido-[(E)-N′,N″-bis((2E,3E)-3-(hydroxyimino)butan-2-ylidene)-2-((E)-3-(hydroxyimino)butan-2-ylidene)hydrazine-1-carbohydrazonhydrazide-κ 4 N 4]cobalt(II), C13H22N9O3Cl2Co
  21. Crystal structure of (−)-flavesine H, C15H22N2O2
  22. Crystal structure of 3-methoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C22H22O4
  23. Crystal structure of dicarbonyl(2-oxopyridin-1(2H)-olato-κ 2 O,O)iridium(I), C7H4IrNO4
  24. The crystal structure of 4-(3-(triphenylphosphonio)propyl)piperazin-1-ium dibromide trihydrate, C25H37Br2N2O3P
  25. The crystal structure of ethyl 5,6-dihydroxybenzofuran-3-carboxylate, C11H10O5
  26. Crystal structure of 14-(R)-(2′-cyano-phenoxy)-3,19-diacetyl andrographolide, C31H37NO7
  27. The twinned crystal structure of 10-(4-methyl benzoate)-2,8-diethyl-5,5-difluoro-1,3,7,9-tetramethyl-5H-di-pyrrolo[1,2-c:2′,1′-f] [1,3,2]diazaborinin-4-ium-5-uide, C25H29BF2N2O2
  28. The crystal structure of (9H-thioxanthen-9- ylidene)hydrazine monohydrate, C13H11N2SO0.5
  29. The crystal structure of pyridinium diaqua-{1,2-phenylenebis((carboxylatocarbonyl)amido-κ4 N,N′,O,O′)manganese(III), C15H14MnN3O8
  30. Crystal structure of the hydrogen storage active high entropy phase Tb0.82Sm0.18Ni0.83Co0.17Mg
  31. Crystal structure of diaqua-bis[5-methyl-1-(1H-pyrazol-3-yl)-1H-1,2,3-triazole-4-carboxylato-κ 2 N,O)]manganese(II), C14H16MnN10O6
  32. Crystal structures of diiodido-3-((pyridin-2-ylmethylene)amino)-2-(pyridin-3-yl)-2,3-dihydroquinazolin-4(1H)-one-cadmium(II)
  33. Synthesis and crystal structure of methyl 4-(2-ethoxy-2-oxoethoxy)-3,5-dimethoxybenzoate, C14H18O7
  34. Crystal structure of isoxazolo[4,5-b]pyridin-3-amine, C6H5N3O
  35. Crystal structure of 4-chloro-1-isobutyl-1H-imidazo, C14H14ClN3
  36. The crystal structure of 1,1,1,2,2,2-hexakis(2-methyl-2-phenylpropyl)distannane,C60H78Sn2
  37. The crystal structure of (2,7-dimethoxynaphthalene-1,8-diyl)bis((3-nitrophenyl)methanone), C26H18N2O8
  38. Crystal structure of diaqua-tetra((E)-(RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol-κ 1 N)zinc(II) dinitrate dihydrate, C60H76Cl8N14O14Zn
  39. The crystal structure of diphenyl bis(2-((diphenoxyphosphoryl)amino)ethyl)phosphoramidate monohydrate C40H42N3O10P3
  40. Crystal structure of 4,4′-bis(dibromomethyl)-1,1′-biphenyl, C14H10Br4
  41. Crystal structure of CaPtZn
  42. Crystal structure of 3-chloro-5-(trifluoromethyl)pyridine-2-carboxylic acid, C7H3ClF3NO2
  43. The crystal structure of (3′-(2-bromophenyl)-2-phenyl-[2,2′-bioxiran]-3-yl)(phenyl)methanone, C92H68O12Br4
  44. Crystal structure of ethyl 4-(4-benzylpiperazin-1-yl)benzoate, C20H24N2O2
  45. The crystal structure of bis(selenocyanato-κ1 N)-bis(methanol)-bis((1E,2E)-1,2-bis (1-(pyridin-4-yl)ethylidene)-hydrazine)iron(II) methanol solvate, C34H44FeN10O4Se2
  46. Crystal structure of (E)-1-(5-bromo-2-hydroxyphenyl)-3-(5-(4-methoxyphenoxy)-3-methyl-1-phenyl-1H-pyrazol-4-yl)prop-2-en-1-one, C26H21BrN2O4
  47. The crystal structure of methyl 4-(4-(methylsulfonyl)phenyl)-2-methyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C19H21NO5S
  48. Crystal structure of 1′,3′-dihydro-2,2′-spirobi[indene]-1,3-dione, C17H12O2
  49. Crystal structure of (E)-2,2′,3,3′-tetrahydro-[1,1′-biindenylidene]-4,4′-diol, C18H16O2
  50. Crystal structure of di-glycylglycinium squarate dihydrate, C12H22N4O12, at 105 K
  51. Crystal structure of {[(4-fluorophenyl)methyl]triphenylphosphonium}dibromocopper(I), [C25H21FP]+[CuBr2]−
  52. Crystal structure of poly[diaqua-bis(μ2-5-((pyridin-4-yl-methyl)amino)benzene-1,3-dicarboxylato-κ 2 N:O)cadmium(II)], C28H26CdN4O10
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Heruntergeladen am 8.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2024-0395/html
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