Home Crystal structure of bis[triaqua-(μ2-1,2-di(4-pyridyl)ethylene-κ2N:N′)-(4-sulfonatobenzoato-κ2O,O′)zinc(II)], C13H15NO8SZn
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Crystal structure of bis[triaqua-(μ2-1,2-di(4-pyridyl)ethylene-κ2N:N′)-(4-sulfonatobenzoato-κ2O,O′)zinc(II)], C13H15NO8SZn

  • Xiao-Ling Li ORCID logo EMAIL logo , Ling-Yun Xin , Yue-Yi Yu , Qing-Qing Yang and Meng-Ke Liu
Published/Copyright: October 11, 2019
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 235 Issue 1

Abstract

C13H15NO8SZn, monoclinic, C2/c (no. 15), a = 12.3456(3) Å, b = 13.7680(4) Å, c = 19.9125(5) Å, β = 107.051(2)°, V = 3235.85(14) Å3, Z = 8, Rgt(F) = 0.0325, wRref(F2) = 0.0819, T = 293(2) K.

CCDC no.: 1955111

The asymmetric unit of the dinuclear title structure is shown using ellipsoids in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Source of material

All chemicals were used as obtained without further purification. The mixtures of potassium 4-carboxybenzenesulfonate (4-khsb) (0.1 mmol, 24.03 mg), 1,2-di(4-pyridyl)ethylene (bpe) (0.05 mmol, 9.18 mg), Zn(Ac)2 ⋅ 2 H2O (0.1 mmol, 21.9 mg), ethanol (3.0 mL), and H2O (3.0 mL) were sealed in a 23 mL Teflon-lined autoclave, heated to 393 K for 4 days, then cooled at 5 °C h−1 to room temperature. Colorless block crystals were obtained.

Table 1:

Data collection and handling.

Crystal:Colourless block
Size:0.38 × 0.34 × 0.31 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:1.69 mm−1
Diffractometer, scan mode:SuperNova, ω
θmax, completeness:28.4°, >99%
N(hkl)measured, N(hkl)unique, Rint:11762, 3481, 0.027
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3031
N(param)refined:217
Programs:CrysAlisPRO [1], SHELX [2], Olex2 [3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Zn10.54265(2)0.67311(2)0.45790(2)0.02716(10)
S10.83898(5)0.50448(5)0.88844(3)0.02908(14)
O10.71180(15)0.65672(13)0.55134(9)0.0383(4)
O1W0.53705(16)0.81464(13)0.49183(10)0.0445(5)
H1WA0.57360.81850.53520.067*
H1WB0.49800.86610.48900.067*
O20.54207(14)0.62057(13)0.55678(8)0.0369(4)
O2W0.57738(15)0.53409(13)0.42577(10)0.0411(4)
H2WA0.62960.49260.42900.062*
H2WB0.52510.49490.42760.062*
O30.81569(15)0.40008(13)0.88624(9)0.0394(4)
O3W0.62555(14)0.71734(13)0.38827(8)0.0345(4)
H3WA0.66330.66880.38110.052*
H3WB0.67170.76300.40560.052*
O40.77728(16)0.55695(15)0.92854(9)0.0438(5)
O50.95914(14)0.52554(14)0.90855(9)0.0393(4)
N10.37271(16)0.67166(14)0.40144(10)0.0287(4)
C10.6484(2)0.62631(17)0.58547(12)0.0303(5)
C20.69611(19)0.59643(17)0.66059(11)0.0272(5)
C30.6251(2)0.5854(2)0.70241(13)0.0383(6)
H30.54770.59600.68360.046*
C40.6686(2)0.5585(2)0.77216(12)0.0390(6)
H40.62070.55080.80020.047*
C50.78323(18)0.54346(17)0.79971(11)0.0258(5)
C60.8548(2)0.55506(19)0.75893(12)0.0340(6)
H60.93230.54550.77820.041*
C70.8113(2)0.58107(19)0.68903(12)0.0347(6)
H70.85950.58820.66120.042*
C80.2911(2)0.6638(2)0.43257(13)0.0382(6)
H80.31200.65700.48110.046*
C90.1773(2)0.6653(2)0.39625(13)0.0402(6)
H90.12340.65940.42030.048*
C100.14351(19)0.67578(17)0.32361(12)0.0310(5)
C110.2290(2)0.68347(19)0.29133(13)0.0348(6)
H110.21070.69010.24280.042*
C120.3403(2)0.68119(19)0.33127(13)0.0347(6)
H120.39610.68650.30860.042*
C130.0216(2)0.67632(18)0.28455(13)0.0349(6)
H13−0.02930.67670.31090.042*

Experimental details

The structure was solved and refined using the SHELX and OLEX2-system [1], [2]. Hydrogen atoms bonded to the carbon atoms were placed in calculated positions and refined with a riding mode. The water hydrogen atoms were initially located in the difference Fourier maps.

Comment

The design and construction of diverse metal complexes has attracted great attention in recent years because of the enormous variety of intriguing structure as well as their potential applications in many fields [4], [5], [6]. To the best of our knowledge, 4-khsb is a good candidate for the construction of complexes that display rich structural diversity, due to their extension ability both in covalent bonding and in supramolecular interactions (H-bonding and aromatic stacking) [7], [8], [9], [10]. Furthermore, N-donor ancillary ligand can modify the structures and properties of the resulting materials. So far very interesting and promising results are constructed by mixed likers. With these considerations in mind, we report herein a dinuclear Zn(II) complex.

The asymmetric unit of the title complex contains one crystallographically independent Zn(II) center, one 4-sb2− anion, a half bpe ligand and three coordination water molecules (see the figure). The Zn1 atom resides in a distorted octahedral environment [ZnO5N] with the basal plane defined by O1 and O2 atoms from the carboxyl group of one 4-sb2− anion and O3W from one coordination water molecule as well as N3 from one bpe molecule. Two O atoms (O1W and O2W) from two coordination water molecules are positioned at the axial positions. All the Zn—O bond lengths are in the range of 2.0429(16)–2.3653(17) Å and the Zn—N bond is 2.0695(19) Å. The sulfonate group remains uncoordinated. The adjacent Zn⋯Zn atoms are separated by one bpe connector 13.528 Å.

There are hydrogen bonds between coordinated water oxygen atoms and coordinated oxygen atoms of carboxylate (O2W—H2WB⋯O24 with the donor-acceptor distance of 2.670(2) Å and a bond angle of 158.6° as well as O3W—H3WB⋯O15 with the donor-acceptor distance of 2.659(2) Å and a bond angle of 169.8°). Several kinds of hydrogen bonding between coordinated water oxygen atoms and uncoordinated oxygen atoms of the sulfonate group are observed [(1) O1W—H1WA⋯O31 with the donor-acceptor distance of 2.828(2) Å and a bond angle of 146.5°; (2) O1W—H1WB⋯O52 with the donor-acceptor distance of 2.753(3) Å and a bond angle of 129.0°; (3) O2W—H2WA⋯O43 with the donor-acceptor distance of 2.754(3) Å and bond angle of 157.7°; (4) O3W—H3WA⋯O33 with the bond distance of 2.860(2) Å and a bond angle of 151.8°]. (symmetric code: 13/2 − x, 1/2 + y, 3/2 − z; 2−1/2 + x, 3/2 − y, −1/2 − z; 3 + x, 1 − y, −1/2 + z; 41 − x, 1 − y, 1 − z; 53/2 − x, 3/2 − y, 1 − z) The weaker face to face π-π stacking interactions occur between bpe (the ring of N1/C8—C12) and 4-sb2− (the ring of C2—C7) with a centroid-centroid distance is 3.8344(1) Å.

References

1. Agilent, CrysalisPRO software system, Oxford, UK (2015).Search in Google Scholar

2. Sheldrick, G. M.: SHELXT-integrated space-group and crystal-structure determination. Acta Crystallogr. A71 (2015) 3–8.10.1107/S2053273314026370Search in Google Scholar PubMed PubMed Central

3. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H.: OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 42 (2009) 339–341.10.1107/S0021889808042726Search in Google Scholar

4. Li, G. L.; Liu, G. Z.; Ma, L. F.; Xin, L. Y.; Li, X. L.; Wang, L. Y.: Crystallographic determination of solid-state structural transformations in a dynamic metal-organic framework. Chem. Commun. 50 (2014) 2615–2617.10.1039/C3CC49106DSearch in Google Scholar

5. Xin, L. Y.; Li, Y. P.; Ju, F. Y.; Li, X. L.; Liu, G. Z.: A supramolecular microporous network of zinc(II) coordination polymer for highly selective fluorescent detection of Pb2+. Indian J. Chem. 56A (2017) 826–831.Search in Google Scholar

6. Ju, F. Y.; Li, Y. P.; Li, G. L.; Liu, G. Z.; Xin, L. Y.; Li, X. L.: Zinc(II) and cadmium(II) coordination polymers with various polynuclears spaced by semirigid 4-carboxybenzeneacetate and nitrogen-rich co-ligangds: synthese, structures and properties. Chin. J. Inorg. Chem. 32 (2016) 1876–1884.Search in Google Scholar

7. Garcia, H. C.; Diniz, R.; de Oliveira, L. F. C.: Supramolecular architectures of metal complexes containing 4-sulfobenzoate dianion and 1,2-bis(4-pyridyl)ethane. Polyhedron 53 (2013) 40–47.10.1016/j.poly.2013.01.011Search in Google Scholar

8. Wang, H.; Huo, L. H.; Deng, Z. P.; Zhao, H.; Gao, S.: Syntheses, crystal structures and luminescent properties of Zn(II)/Cd(II) supramolecular complexes incorporating 4-sulfifinobenzoate and its in situoxidized ligand. CrystEngComm 14 (2012) 3501–3508.10.1039/c2ce06584cSearch in Google Scholar

9. Wagner, C.; Merzweiler, K.: Synthesis, crystal structures and thermal properties of 4-carboxylbenzenesulfonates of iron, cobalt and zinc. Z. Anorg. Allg. Chem. 636 (2010) 557–561.10.1002/zaac.200900375Search in Google Scholar

10. Zhang, J.; Zhu, L. G.: Syntheses, structures, and supra-molecular assembles of zinc 4-sulfobenzoate complexes with chelating and/or bridging ligands. J. Mol. Struct. 931 (2009) 87–93.10.1016/j.molstruc.2009.05.032Search in Google Scholar

Received: 2019-08-03
Accepted: 2019-09-22
Published Online: 2019-10-11
Published in Print: 2019-12-18

©2019 Xiao-Ling Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

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  76. The pseudosymmetric low temperature polymorph of catena-poly[(μ2-4,4′-bipyridyl-κN,N′)-bis(O,O′-diethyldithiophosphato-κS)-cadmium(II)], {C18H28CdN2O4P2S4}n
  77. Crystal structure of 3-iodophthalic acid, C8H5IO4
  78. The crystal structure of tert-butyl (tert-butoxy(oxo)methyl)(5-bromo-2-fluorophenyl)carbamate, C16H21BrFNO4
  79. The crystal structure of bis(μ2-5,7-dichloroquinolin-8-olato-κ3N,O:O)-tetrakis(5,7-dichloroquinolin-8-olato-κ2N,O)bis(methanol-κ1O)dieuropium(III) — toluene (1/1), C63H39Cl12Eu2N6O8
  80. Crystal structure of dichlorido-(N′-(1-(3-ethylpyrazin-2-yl)ethylidene)-4-methoxybenzohydrazide-κ3N,N′,O)cadmium(II), C16H18N4O2Cl2Cd
  81. A redetermination of the crystal structure of catena-poly[(bis(O,O′-isopropyl dithiophosphato-κ2S,S′)-(μ2-1,2-bis(3-pyridylmethylene)hydrazine-κ2N,N′)cadmium(II)], {C24H38CdN4O4P2S4}n
https://doi.org/10.1515/ncrs-2019-0558
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  1. 10.1515/ncrs-2020-frontmatter1
  2. The crystal structure of 3,5-dicarboxybenzenaminium perchlorate monohydrate, C8H8ClNO9
  3. The crystal structure of poly[(m4-4-bromoisophthalato-κ4O: O′:O′′:O′′′)zinc(II)], C8H3BrO4Zn
  4. Crystal structure of (E)-2-(2-chloro-6-hydroxybenzylidene)hydrazine-1-carbothioamide, C8H8ClN3O4S
  5. Crystal structure of 1,1′-methylenebis(3-ethyl-1H-imidazol-3-ium) bis(hexafluorophosphate(V)), C11H18F12N4P2
  6. The crystal structure of hexakis(1-isopropyl-1H-imidazole-κ1N)copper(II) dichloride, C36H58Cl2CuN12
  7. Crystal structure of catena-poly[μ2-4,4′-bipyridine-κ2N:N′)-tetrakis(μ2-2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-κ2O:O′)dicobalt(II)], C19H10Cl6CoN3O6
  8. Crystal structure of (E)-1-(4-(((E)-2-bromo-6-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H15BrN2O2
  9. Crystal structure of ethyl 2-methyl-4-(5-methylthiophen-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C18H21NO3S
  10. The crystal structure of 5-bromo-2-(1-methyl-1H-tetrazol-5-yl)pyridine, C7H6BrN5
  11. Crystal structure of Bis(acetato-κ2O,O′)-bis[4-(dimethylamino)pyridine-κN]nickel(II), C18H26N4NiO4
  12. Crystal structure of (E)-3-chloro-2-(((4-chlorophenyl)imino)methyl)phenol, C13H9Cl2NO
  13. The co-crystal structure of (17b)-estra-1,3,5(10)-triene-3,17diol – acetamide (1/1), a Z′ = 4 structure, C20H29NO3
  14. Crystal structure of 3-(3-(pyridin-3-yl)ureido)benzoic acid, C13H11N3O3
  15. The crystal structure of 1,1′-(9-ethyl-9H-carbazole-3,6-diyl)bis(3-ethyl-1H-imidazol-3-ium) bis(hexafluorophosphate(IV)), C24H27N5F12P2
  16. The crystal structure of 2-bromoisophthalic acid, C8H5BrO4
  17. The crystal structure of 13-ethoxycarbonyl-9-methyl-4-chlor-11-thioxo-8-oxa-10,12-diazatricyclo[7.3.1.02,7]trideca-2,4,6-triene, C14H15ClN2O3S
  18. The crystal structure of (E)-4-((4-(diethylamino)benzylidene)amino)-N,N-diphenylaniline, C29H29N3
  19. Crystal structure of 2-(3-(2-(4-phenylpiperazin-1-yl)ethyl)benzyl)isoindoline-1,3-dione, C27H27N3O2
  20. Crystal structure of 2-ethoxy-6-((E)-((3-(((E)-3-ethoxy-2-hydroxybenzylidene)amino)-2-hydroxypropyl)iminio)methyl)phenolate, C21H26N2O5
  21. The crystal structure of catena-poly(μ2-4,4′-bipyridine-κ2N:N′)-tetrakis(μ2-2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-κ2O:O′)dinickel(II)], C19H10Cl6N3NiO6
  22. Crystal structure of hexakis(μ2-azido-κ2N:N)-diazido-κ1N-tetrakis(phenanthroline-κ2N,N′)tetrazinc(II), C48H32N32Zn4
  23. Synthesis and crystal structure of bis{2-bromo-6-(((4-(1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O}cobalt(II)–dichloromethane(1/1), C34H32Br2Cl4CoN4O4
  24. Crystal structure of (E)-3-chloro-2-(((4-nitrophenyl)imino)methyl)phenol, C13H9ClN2O3
  25. Crystal structure of aqua-bis(5-bromo-6-methyl-picolinato-κ2N,O)zinc(II) dihydrate, C14H16Br2N2O7Zn
  26. Crystal structure of biaqua(2,2′-bipyridine-4,4′-dicarboxylato-κ2N,N′)(pyridine-2,6-dicarboxylato-κ3O,N,O′)nickel(II) hydrate, C19H15N3NiO10
  27. Synthesis and crystal structure of bis(2-(((4-(1-(ethoxyimino)ethyl)phenyl)imino)methyl)-5-fluorophenolato-κ2N,O)zinc(II) - methanol (1/1), C33H32F2N4O4Zn
  28. Crystal structure of tetraaqua-bis(μ2-5-aminoisophthalato-κ3N:O,O′)-bis(4,4′-dipyridylsulfide-κ1N)dizinc(II), C36H34N6O12S2Ni2
  29. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)palladium(II) tetracyanonickelate(II), C14H24N8NiPd
  30. The crystal structure of 3-benzyl-1-((8-(benzyloxy)quinolin-2-yl)methyl)-1H-imidazol-3-ium hexafluorophosphate, C27H24N3OF6P
  31. Crystal structure of 1-(4-chloro-2-hydroxy-5-iodophenyl)ethan-1-one, C8H6ClIO2
  32. Crystal structure of hexaaquamagnesium(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MgN6O12S2
  33. Crystal structure of the coordination polymer catena-poly[(1,2-di(pyridin-4-yl)ethane-κN)-(μ2-2-nitroisophthalato-κ2O:O′)zinc(II)], C20H17N3O7Zn
  34. Crystal structure of catena-{[tri-aqua-di-sodium bis(2-{[n-butyl(methyl)carbamothioyl]sulfanyl}acetate)]}n, [C16H34N2Na2O7S4]n
  35. The crystal structure of diaqua-bis(μ2-3-((3-acetyl-5-carboxyphenyl)oxidophosphoryl)-5-carboxybenzoato-κ2O:O′)bis(5,5′-dimethyl-2,2′-bipyridine-k2N,N′)zinc(II), C56H46N4O22P2Zn2
  36. Crystal structure of N′,2-bis((E)-2-chloro-6-hydroxybenzylidene)hydrazine-1-carbothiohydrazide, C15H12Cl2N4O2S
  37. Crystal structure of 2-[(1E)-{[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]iminiumyl}methyl]-5-(dodecyloxy)benzen-1-olate, C23H39NO5
  38. Crystal structure of 12-(2-hydroxybenzoyl)benzo[f]pyrido[1,2-a]indole-6,11-dione, C23H13NO4
  39. Crystal structure of chlorido-(4-chloro-6-(p-tolyl)pyrimidine-κ2C,N)-(triphenylphosphane-κP)palladium(II), C29H23Cl2N2PPd
  40. Crystal structure of catena-poly[diaqua-bis(3,4,5,6-tetrabromo-carboxybenzoato-κ1O)-(μ2-4,4′-bipyridine-κ2N:N′)cobalt(II)], C26H14Br8CoN2O10
  41. Crystal structure of catena-poly[dibenzyl-dichlorido-(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′)tin(IV)], C24H22Cl2N2O2Sn
  42. Crystal structure of benzyl-chlorido-(4-chloro-N-[(2-oxidophenyl)methylidene]benzenecarbohydrazonato)-methanol-tin(IV), C22H20Cl2N2O3Sn
  43. Crystal structure of catena-poly[triaqua-(1,3-di(1H-imidazol-1-yl)benzene-κ2N:N′)-(3-nitrophthalato-κ1O)cobalt(II)] — water (2/3), C20H22N5O10.5Co
  44. Crystal structure of (3R,5R,8R,9R,10R,12R,13R,14R)-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)hexadecahydro-1H-cyclopenta[a]phenanthrene-3,12-diol, C30H52O3
  45. Crystal structure of 3-(3-(4-carboxyphenyl)ureido)pyridin-1-ium perchlorate, C26H24Cl2N6O14
  46. Crystal structure of 8-hydroxy-2-methylquinolin-1-ium chloride dihydrate, C10H14ClNO3
  47. Crystal structure of (dibenzyl sulphoxide-κO)dibromido-bis(4-bromobenzyl-κC)tin(IV), C28H26Br4OSSn
  48. Crystal structure of bromido-tri(4-chlorophenyl-κ1C)-(ethanol-κ1O)tin(IV) — 4,4′-dimethyl-2,2′-bipyridine (2/1), C52H48Br2Cl6N2O2Sn2
  49. Crystal structure of 2-butyl-6-(ethylamino)-1H-benzo[de]isoquinoline-1,3(2H)-dione, C18H20N2O2
  50. Crystal structure of (4-chloro-N-[(2-oxido-5-chlorophenyl)methylidene] benzene-carbohydrazonato-κ3N,O,O′)bis(2-fluorobenzyl)tin(IV), C28H20Cl2F2N2O2Sn
  51. Crystal structure of aqua-chlorido-(4-fluorobenzyl-κC)-(N′-(4-methoxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ3N,O,O′)tin(IV), C26H22ClFN2O5Sn
  52. Crystal structure of catena-poly[tri(4-chlorophenyl)-(μ2-hydroxido)tin(IV)] – 2-propanol (1/1), C21H21Cl3O2Sn
  53. Crystal structure of bromido-dimethyl-4-tolyl-(triphenylphosphine oxide)tin(IV), C27H28BrOPSn
  54. Crystal structure of 2-(bis(2-hydroxyethyl)ammonio)ethane-1-sulfonate, C6H15NO5S
  55. Crystal structure of bis[triaqua-(μ2-1,2-di(4-pyridyl)ethylene-κ2N:N′)-(4-sulfonatobenzoato-κ2O,O′)zinc(II)], C13H15NO8SZn
  56. Crystal structure of 2-((2-(3-hydroxy-7-methylene-2,3-dihydro-7H-furo[3,2-g]chromen-2-yl)propan-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol – a marmesin derivative, C20H24O10
  57. Crystal structure of octa(4-chlorobenzyl)-dichlorido-bis(μ2-methanolato)-bis(μ3-oxo)-tetratin(IV), C58H54Cl10O4Sn4
  58. Crystal structure of iodido-triphenyl-(triphenylphosphine oxide)tin(IV), C36H30IOPSn
  59. Crystal structure of dichlorido-bis(4-methylphenyl-κC)-bis(triphenylarsine oxide-κO)tin(IV), C50H44As2Cl2O2Sn
  60. Crystal structure of 4-benzyl-1-oxo-N-phenethyl-1H-[1,4]oxazino [4,3-b]indazole-3-carboxamide, C26H21N3O3
  61. Crystal structure of bis{(N-[(5-chloro-2-oxidophenyl)methylidene]-2-hydroxybenzenecarbohydrazonato)-dioxo-molybdenum(VI)}(μ2-4,4′-bipyridine), C38H26Cl2Mo2N6O10
  62. Crystal structure of dichlorido-octamethyl-bis(μ3-oxido)-bis(μ2-2-(phenylamino)ethanolato-κ2O:O)tetratin(IV), C24H44Cl2N2O4Sn4
  63. The crystal structure of 1-(2-(2-(imidazo[1,5-a]pyridine-4-ium)ethoxy)ethyl)-imidazo[1,5-a]pyridine-4-ium bis(hexafluorophosphate) — acetonitrile (1/1), C18H20ON4F12P2
  64. Crystal structure of cyclo[tetra(μ2-cyanido)-tetracyanido-bis(1,4,7,10-tetraazacyclododecane-κ4N,N′,N′′,N′′′)dinickel(II)dipalladium(II)] hexahydrate, C24H52N16Ni2O6Pd2
  65. Crystal structure of (dimethyl sulfoxide)-dioxido-[2-hydroxy-N′-(4-oxo-4-phenylbutan-2-ylidene)benzohydrazidato κ3N,O,O′]molybdenum(VI), C19H20MoN2O6S
  66. Crystal structure of bis(acetylacetonato-κ2O,O′)-(ethanolamine-κ2N,O)copper(II), C14H25CuNO5
  67. Crystal structure of chlorido-diphenyl-(isopropyl(propyl)carbamodithioato-κ2S,S′)tin(IV), C19H24ClNS2Sn
  68. The crystal structure of bis(imidazole-1-yl)methane monohydrate, C7H10N4O
  69. The crystal structure of bis(4-nitroimidazole-1-1yl)methane, C7H6N6O4
  70. Crystal structure of di(naphthalen-2-yl)sulfane, C20H14S
  71. Crystal structure of 3-acetyl-6-bromo-4-hydroxy-2H-chromen-2-one, C11H7BrO4
  72. Crystal structure of N′2,N′6-bis((E)-1-(pyrazin-2-yl)ethylidene)pyridine-2,6-dicarbohydrazide — methanol (1/2), C21H25N9O4
  73. The crystal structure of 3-nitro-4-(p-tolylamino)-2H-chromen-2-one, C16H12N2O4
  74. The crystal structure of 1,2-bis((4-methoxyphenyl)ethynyl)benzene, C24H18O2
  75. Crystal structure of a low-temperature (100 K) polymorph of catena-poly[(μ2-4,4′-bipyridine-κ2N,N′)-bis(O,O′-diethyldithiophosphato-κ1S)zinc(II)], C18H28N2O4P2S4Zn
  76. The pseudosymmetric low temperature polymorph of catena-poly[(μ2-4,4′-bipyridyl-κN,N′)-bis(O,O′-diethyldithiophosphato-κS)-cadmium(II)], {C18H28CdN2O4P2S4}n
  77. Crystal structure of 3-iodophthalic acid, C8H5IO4
  78. The crystal structure of tert-butyl (tert-butoxy(oxo)methyl)(5-bromo-2-fluorophenyl)carbamate, C16H21BrFNO4
  79. The crystal structure of bis(μ2-5,7-dichloroquinolin-8-olato-κ3N,O:O)-tetrakis(5,7-dichloroquinolin-8-olato-κ2N,O)bis(methanol-κ1O)dieuropium(III) — toluene (1/1), C63H39Cl12Eu2N6O8
  80. Crystal structure of dichlorido-(N′-(1-(3-ethylpyrazin-2-yl)ethylidene)-4-methoxybenzohydrazide-κ3N,N′,O)cadmium(II), C16H18N4O2Cl2Cd
  81. A redetermination of the crystal structure of catena-poly[(bis(O,O′-isopropyl dithiophosphato-κ2S,S′)-(μ2-1,2-bis(3-pyridylmethylene)hydrazine-κ2N,N′)cadmium(II)], {C24H38CdN4O4P2S4}n
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