Startseite Naturwissenschaften Crystal structure of a low-temperature (100 K) polymorph of catena-poly[(μ2-4,4′-bipyridine-κ2N,N′)-bis(O,O′-diethyldithiophosphato-κ1S)zinc(II)], C18H28N2O4P2S4Zn
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Crystal structure of a low-temperature (100 K) polymorph of catena-poly[(μ2-4,4′-bipyridine-κ2N,N′)-bis(O,O′-diethyldithiophosphato-κ1S)zinc(II)], C18H28N2O4P2S4Zn

  • Yee Seng Tan und Edward R.T. Tiekink ORCID logo EMAIL logo
Veröffentlicht/Copyright: 18. Oktober 2019
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 235 Heft 1

Abstract

C18H28N2O4P2S4Zn, triclinic, P1̄ (no. 2), a = 15.2379(1) Å, b = 17.3322(2) Å, c = 21.8829(1) Å, α = 75.919(1)°, β = 78.050(1)°, γ = 68.170(1)°, V = 5159.97(8) Å3, Z = 8, Rgt(F) = 0.0246, wRref(F2) = 0.0681, T = 100 K.

CCDC no.: 1957379

A part of the molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Colourless prism
Size:0.28 × 0.17 × 0.12 mm
Wavelength:Cu Kα radiation (1.54184 Å)
μ:5.76 mm−1
Diffractometer, scan mode:XtaLAB Synergy, ω
θmax, completeness:67.1°, >99%
N(hkl)measured, N(hkl)unique, Rint:123255, 18426, 0.031
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 17365
N(param)refined:1143
Programs:CrysAlisPRO [1], SHELX [2], [3], WinGX/ORTEP [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Zn11.27642(2)0.07163(2)0.07760(2)0.01050(5)
Zn20.72088(2)0.43395(2)0.42150(2)0.01085(5)
Zn30.26991(2)0.02044(2)0.59357(2)0.01154(5)
Zn4−0.25437(2)0.46831(2)0.89893(2)0.01162(5)
S11.23935(3)0.01375(2)0.00699(2)0.01662(8)
S21.16429(3)0.22510(3)−0.04588(2)0.01933(9)
S31.38694(3)−0.03354(2)0.14090(2)0.01434(8)
S41.33166(3)−0.21187(3)0.16243(2)0.02243(9)
S50.76166(3)0.49006(2)0.49145(2)0.01568(8)
S60.82759(3)0.28049(2)0.55427(2)0.01811(9)
S70.61060(3)0.54206(2)0.35999(2)0.01528(8)
S80.67151(3)0.71469(3)0.35391(2)0.02640(10)
S90.19049(3)−0.00534(2)0.52636(2)0.01404(8)
S100.13376(3)0.20121(3)0.45112(2)0.02146(9)
S110.37827(3)−0.09027(3)0.65260(2)0.01767(9)
S120.18010(3)−0.14169(3)0.67108(2)0.02008(9)
S13−0.20078(3)0.51391(2)0.96891(2)0.01571(8)
S14−0.13417(3)0.30750(2)1.03947(2)0.01695(8)
S15−0.35606(3)0.56966(2)0.83013(2)0.01652(8)
S16−0.16391(3)0.62632(3)0.82114(2)0.02018(9)
P11.18693(3)0.11368(3)−0.06241(2)0.01342(8)
P21.31363(3)−0.10984(2)0.19258(2)0.01358(8)
P30.81163(3)0.39373(2)0.56375(2)0.01319(8)
P40.68508(3)0.62071(3)0.31560(2)0.01441(8)
P50.19564(3)0.08202(2)0.44657(2)0.01285(8)
P60.28871(3)−0.14872(3)0.70786(2)0.01378(8)
P7−0.20182(3)0.42504(2)1.04798(2)0.01246(8)
P8−0.28551(3)0.65366(3)0.79243(2)0.01390(8)
O11.25043(8)0.09469(8)−0.12815(5)0.0181(2)
O21.09596(8)0.10366(7)−0.08057(5)0.0155(2)
O31.20573(8)−0.04811(7)0.19927(6)0.0189(2)
O41.33449(9)−0.12861(7)0.26423(5)0.0203(3)
O50.90597(8)0.40195(7)0.57791(5)0.0165(2)
O60.74914(8)0.41947(7)0.62839(5)0.0167(2)
O70.65535(9)0.65838(8)0.24594(6)0.0262(3)
O80.79198(8)0.55684(7)0.30699(6)0.0199(2)
O90.14869(8)0.06414(7)0.39520(5)0.0189(2)
O100.30703(8)0.05658(7)0.42120(5)0.0172(2)
O110.26206(8)−0.11112(7)0.77138(5)0.0191(2)
O120.35364(8)−0.24311(7)0.73409(5)0.0192(2)
O13−0.31136(8)0.44580(7)1.07637(5)0.0169(2)
O15−0.35500(8)0.74447(7)0.80511(5)0.0176(2)
O16−0.28275(9)0.66834(7)0.71725(5)0.0207(3)
N11.35491(9)0.15071(8)0.04131(6)0.0118(3)
N21.65809(9)0.39541(8)−0.06228(6)0.0130(3)
N31.17131(9)0.13826(8)0.13849(6)0.0118(3)
N40.82489(9)0.36448(8)0.36108(6)0.0124(3)
N50.64200(9)0.35469(8)0.45698(6)0.0123(3)
N60.35574(10)0.09386(8)0.55467(6)0.0140(3)
N70.16944(9)0.09730(8)0.65171(6)0.0135(3)
N8−0.15272(9)0.38416(8)0.84627(6)0.0140(3)
C11.35002(12)0.08948(13)−0.13911(8)0.0231(4)
H1A1.38840.0382−0.11220.028*
H1B1.35580.1396−0.12850.028*
C21.38477(12)0.08592(13)−0.20826(8)0.0249(4)
H2A1.45240.0804−0.21690.037*
H2B1.34790.1379−0.23440.037*
H2C1.37670.0372−0.21850.037*
C31.00827(12)0.11942(11)−0.03694(8)0.0198(4)
H3A0.98870.1763−0.02620.024*
H3B1.01770.07690.00280.024*
C40.93287(13)0.11388(12)−0.06863(9)0.0241(4)
H4A0.87460.1188−0.03850.036*
H4B0.95540.0594−0.08270.036*
H4C0.91940.1598−0.10540.036*
C51.13063(13)−0.08271(11)0.23007(9)0.0233(4)
H5A1.1402−0.10910.27480.028*
H5B1.1311−0.12630.20780.028*
C61.03745(13)−0.01054(12)0.22719(11)0.0312(4)
H6A0.9851−0.03150.24800.047*
H6B1.02840.01450.18270.047*
H6C1.03810.03240.24890.047*
C71.41502(13)−0.20013(12)0.28741(8)0.0254(4)
H7A1.4754−0.18900.26990.030*
H7B1.4180−0.25190.27420.030*
C81.40080(14)−0.21147(13)0.35842(9)0.0293(4)
H8A1.4538−0.25960.37550.044*
H8B1.3407−0.22220.37520.044*
H8C1.3985−0.16010.37100.044*
C91.32977(11)0.22655(10)0.05775(7)0.0146(3)
H91.27080.24650.08370.018*
C101.38646(11)0.27678(10)0.03832(7)0.0147(3)
H101.36610.33040.05060.018*
C111.47346(11)0.24839(10)0.00074(7)0.0121(3)
C121.49854(11)0.17030(10)−0.01740(7)0.0144(3)
H121.55680.1491−0.04370.017*
C131.43775(11)0.12459(10)0.00336(7)0.0151(3)
H131.45510.0719−0.00970.018*
C141.69316(11)0.31061(10)−0.04750(7)0.0138(3)
H141.76040.2835−0.05190.017*
C151.63609(11)0.26108(10)−0.02619(7)0.0138(3)
H151.66400.2013−0.01610.017*
C161.53709(11)0.29933(10)−0.01947(7)0.0122(3)
C171.50051(11)0.38762(10)−0.03381(7)0.0142(3)
H171.43360.4164−0.02910.017*
C181.56257(11)0.43241(10)−0.05486(7)0.0149(3)
H181.53670.4923−0.06460.018*
C191.19221(11)0.13689(10)0.19559(7)0.0152(3)
H191.25520.10570.20540.018*
C201.12601(11)0.17894(10)0.24059(7)0.0150(3)
H201.14390.17690.28020.018*
C211.03300(11)0.22428(9)0.22757(7)0.0115(3)
C221.01116(11)0.22379(10)0.16881(7)0.0150(3)
H220.94800.25240.15850.018*
C231.08134(11)0.18166(10)0.12582(7)0.0146(3)
H231.06560.18330.08560.018*
C240.90555(11)0.30354(10)0.37904(8)0.0161(3)
H240.91600.29230.42210.019*
C250.97360(12)0.25674(11)0.33757(8)0.0168(3)
H251.02900.21360.35240.020*
C260.96097(11)0.27286(10)0.27370(7)0.0120(3)
C270.87777(11)0.33656(10)0.25522(7)0.0136(3)
H270.86630.35000.21220.016*
C280.81219(11)0.37998(10)0.29962(7)0.0140(3)
H280.75560.42270.28620.017*
C290.99217(12)0.37729(12)0.53321(8)0.0223(4)
H29A0.98350.41600.49170.027*
H29B1.00580.31920.52670.027*
C301.07310(13)0.38117(12)0.55961(10)0.0285(4)
H30A1.13090.36770.52890.043*
H30B1.08370.34020.59940.043*
H30C1.05770.43820.56780.043*
C310.64853(12)0.42862(12)0.63842(8)0.0209(4)
H31A0.64010.38110.62560.025*
H31B0.61200.48210.61260.025*
C320.61331(13)0.42894(13)0.70800(8)0.0251(4)
H32A0.54490.43780.71560.038*
H32B0.62460.47460.72060.038*
H32C0.64750.37460.73300.038*
C330.66389(15)0.60428(13)0.20259(9)0.0302(4)
H33A0.61990.57170.21920.036*
H33B0.72980.56390.19770.036*
C340.63928(16)0.65927(15)0.13969(9)0.0365(5)
H34A0.64840.62370.10870.055*
H34B0.68080.69360.12480.055*
H34C0.57260.69640.14450.055*
C350.87014(13)0.58892(12)0.28151(10)0.0253(4)
H35A0.86520.63410.30370.030*
H35B0.86820.61280.23570.030*
C360.96164(14)0.51656(14)0.29137(13)0.0410(5)
H36A1.01570.53680.27530.061*
H36B0.96650.47280.26840.061*
H36C0.96240.49280.33680.061*
C370.68047(11)0.27094(10)0.45769(7)0.0154(3)
H370.74730.24720.44600.018*
C380.62713(12)0.21808(10)0.47464(7)0.0156(3)
H380.65680.15950.47350.019*
C390.52927(11)0.25119(10)0.49348(7)0.0120(3)
C400.48985(12)0.33749(10)0.49479(8)0.0163(3)
H400.42390.36240.50870.020*
C410.54790(12)0.38616(10)0.47569(8)0.0164(3)
H410.51990.44510.47580.020*
C420.31778(12)0.17713(11)0.53288(8)0.0177(3)
H420.25080.20110.53230.021*
C430.37162(12)0.22940(10)0.51135(8)0.0171(3)
H430.34180.28790.49590.021*
C440.46981(11)0.19633(10)0.51232(7)0.0121(3)
C450.50950(11)0.10943(10)0.53377(8)0.0155(3)
H450.57640.08360.53420.019*
C460.45090(12)0.06141(10)0.55424(8)0.0164(3)
H460.47910.00240.56880.020*
C470.16451(13)−0.01967(11)0.38450(9)0.0231(4)
H47A0.2152−0.06200.40900.028*
H47B0.1857−0.02210.33890.028*
C480.07433(15)−0.03968(13)0.40481(10)0.0307(4)
H48A0.0843−0.09500.39530.046*
H48B0.02360.00370.38180.046*
H48C0.0559−0.04090.45060.046*
C490.33982(13)0.10112(12)0.36037(8)0.0223(4)
H49A0.38840.12310.36610.027*
H49B0.28570.14960.34370.027*
C500.38220(15)0.04084(14)0.31406(9)0.0313(4)
H50A0.40050.07130.27230.047*
H50B0.33500.01680.31050.047*
H50C0.4387−0.00470.32930.047*
C510.19425(13)−0.13683(11)0.82225(8)0.0223(4)
H51A0.2178−0.19890.83640.027*
H51B0.1318−0.12040.80700.027*
C520.18396(18)−0.09344(15)0.87613(10)0.0398(5)
H52A0.1377−0.10870.91080.060*
H52B0.1616−0.03210.86140.060*
H52C0.2458−0.11120.89150.060*
C530.38761(14)−0.30803(12)0.69567(9)0.0293(4)
H53A0.3541−0.28760.65760.035*
H53B0.3731−0.35890.72030.035*
C540.49179(16)−0.33073(14)0.67573(10)0.0380(5)
H54A0.5133−0.37570.65060.057*
H54B0.5250−0.35050.71340.057*
H54C0.5059−0.28100.64990.057*
C550.18965(12)0.09915(11)0.70812(8)0.0204(4)
H550.24880.06150.72150.025*
C560.12845(12)0.15330(11)0.74754(8)0.0209(4)
H560.14550.15220.78720.025*
C570.04136(11)0.20968(10)0.72896(7)0.0126(3)
C580.01973(12)0.20584(10)0.67108(7)0.0152(3)
H58−0.03950.24190.65700.018*
C590.08450(11)0.14955(10)0.63419(7)0.0149(3)
H590.06830.14780.59500.018*
C60−0.17993(12)0.36935(11)0.79679(8)0.0212(4)
H60−0.24380.39860.78810.025*
C61−0.11993(12)0.31394(11)0.75812(8)0.0205(4)
H61−0.14270.30520.72400.025*
C62−0.02559(11)0.27071(10)0.76937(7)0.0126(3)
C630.00256(11)0.28630(10)0.82059(7)0.0131(3)
H630.06620.25850.83000.016*
C64−0.06221(11)0.34229(10)0.85774(7)0.0134(3)
H64−0.04180.35140.89270.016*
C65−0.34049(13)0.39258(12)1.13352(8)0.0214(4)
H65A−0.39090.42841.16130.026*
H65B−0.28540.36001.15730.026*
C66−0.37756(13)0.33272(12)1.11585(9)0.0258(4)
H66A−0.39680.29701.15450.039*
H66B−0.32740.29701.08870.039*
H66C−0.43270.36511.09290.039*
O14a−0.16418(8)0.45149(8)1.10007(5)0.0177(2)
C67a−0.06684(12)0.45251(12)1.08937(8)0.0222(4)
H67Aa−0.04650.46691.04330.027*
H67Ba−0.02270.39621.10620.027*
C68a−0.0654(4)0.5181(3)1.1234(3)0.0296(11)
H68Aa−0.10760.57391.10530.044*
H68Ba−0.00030.51881.11810.044*
H68Ca−0.08760.50411.16870.044*
O14′a−0.16418(8)0.45149(8)1.10007(5)0.0177(2)
C67′a−0.06684(12)0.45251(12)1.08937(8)0.0222(4)
H67Ca−0.03470.43621.04790.027*
H67Da−0.03050.41151.12310.027*
C68′a−0.0699(4)0.5382(4)1.0899(3)0.0354(12)
H68Da−0.10150.57781.05430.053*
H68Ea−0.00480.53861.08580.053*
H68Fa−0.10540.55541.12990.053*
C69−0.45037(12)0.77971(11)0.78591(8)0.0196(3)
H69A−0.47680.73400.79070.023*
H69B−0.44750.80800.74080.023*
C70−0.51284(13)0.84238(12)0.82716(8)0.0240(4)
H70A−0.57450.87220.81110.036*
H70B−0.48200.88320.82650.036*
H70C−0.52280.81260.87080.036*
C71−0.21623(15)0.60301(13)0.68298(9)0.0331(5)
H71A−0.22020.54700.70490.040*
H71B−0.15020.60150.68140.040*
C72−0.24125(17)0.62239(13)0.61747(9)0.0331(5)
H72A−0.19440.58100.59290.050*
H72B−0.24100.67930.59700.050*
H72C−0.30480.61960.61930.050*

  1. aOccupancy: 0.5.

Source of material

The Zn[S2P(OEt)2]2 precursor was prepared in high yield from the in situ reaction of Zn(NO3)2 ⋅ 6 H2O (Alfa Aesar; 14.87 g, 0.05 mol), EtOH (Merck; 12.25 mL, 0.21 mol), P2S5 (Sigma-Aldrich; 11.11 g, 0.05 mol) and 50% w/w NaOH solution (Merck; 8.80 mL, 0.11 mol). The title compound was obtained by mixing a suspension of this precursor (0.50 g, 1.15 mmol) and 4,4′-bipyridine (Merck; 0.18 g, 1.15 mmol) in dimethylformamide (Merck; 5 mL), followed by stirring for 30 min at 373 K. The solution was filtered and the filtrate was collected in a sample vial containing acetonitrile (Merck; 1 mL). Colourless blocks formed after one day. Yield: 0.46 g, (67.6%, based on Zn[S2P(OEt)2]2). M.pt (Stuart SMP 30 Melting point apparatus): 420.2–421.9 K. IR (Bruker Vertex 70 V equipped with Platinum ATR from 400 to 80 cm−1): 1057(w) ν(C—O); 940(s) ν(P—O); 667(s) ν(P—S)asym; 521(m) ν(P—S)sym; 294(m) ν(Zn—S); 380(w) ν(Zn—N).

Experimental details

The C-bound H atoms were geometrically placed (C—H = 0.95–0.99 Å) and refined as riding with Uiso(H) = 1.2–1.5Ueq(C). The methyl-C68 atom was found, from refinement, to be statistically disordered over two positions with 50:50% site occupancy. Each position was modelled with independent anisotropic displacement parameters. Owing to poor agreement, one reflection, i.e. (7 0 2), was omitted from the final cycles of refinement. Translational pseudosymmetry is observed (<90%) but after careful analysis the refinement was carried out using the given unit cell.

Comment

The neutral, usually bidentate bridging ligand, 4,4′-bipyridine (4,4′-bipy), has proven to be a mainstay in coordination chemistry for the construction of coordination polymers, up to and including three-dimensional metal-organic framework architectures. An early aspiration of complexing zinc-triad 1,1-dithiolates, such as dithiophosphates [−S2P(OR)2], with 4,4′-bipy was the expectation that the aggregated precursor structures, through the agency of M⋯S bridging [5], would be assembled into higher-dimensional architectures via links provided by the 4,4′-bipy molecules. While complexation by 4,4′-bipy did occur, this was at the expense of M⋯S bridging so that, usually, only one-dimensional coordination polymers eventuated [6]. In the case of zinc dithiophosphates, {Zn[S2P(OR)2]2(4,4′-bipy)}n, one-dimensional, zig-zag polymers are formed when R = [7], Et [8] and iPr [9]. However, when the R group is bulky, such as when R = cyclohexyl (Cy), only zero-dimensional, binuclear molecules could be isolated, i.e. {Zn[S2P(OCy)2]2}2(4,4′-bipy) [10]. Such steric control over supramolecular association in the zinc-triad dithiophosphate adducts of bipyridyl-type molecules is well established [6], [10], [11], [12]. In continuation of studies in this area, a low temperature (100 K) form of {Zn[S2P(OEt)2]2(4,4′bipy)}n, (I), was characterised crystallographically and compared with the previously reported room-temperature form [8].

The asymmetric unit of (I) is shown in the figure (70% probability displacement ellipsoids; only one position for the statistically disordered C68 atom is shown) and comprises four independent Zn[S2P(OEt)2]2(4,4′-bipy) repeat units linked to form part of a one-dimensional coordination polymer with a zig-zag topology. The coordination environment for each zinc centre is approximately the same whereby each is coordinated by two sulphur atoms derived from two monodentate dithiophosphate ligands and two pyridyl-nitrogen atoms. The Zn—S(coordinating) bond lengths lie in the experimentally distinct range 2.2854(4) Å, for Zn4—S13, to 2.3519(4) Å, for Zn1—S3. Similarly, the Zn—N bond lengths span a range of over 0.045 Å, i.e. 2.0405(13) Å, for Zn1—N3, to 2.0879(13) Å, for Zn4—N2i (symmetry operation (i): −2 + x, y, 1 + z). Evidence that the dithiophosphate ligands are coordinating in a monodentate mode is seen in the non-bonding separations. For each repeat unit, one dithiophosphate ligand is orientated to place a thione-sulphur atom in close proximity to the zinc centre, whereas the other directs one of the ethoxy-oxygen atoms towards the zinc atom. An interesting trend is noted in the non-bonding-Zn⋯S, O separations in that the zinc atom forming the shortest Zn⋯S separation, forms the longest Zn⋯O separation, i.e. Zn4⋯S16 = 3.4445(5) Å and Zn4—O13 = 3.7553(11) Å, and vice versa, i.e. Zn2⋯S6 = 3.6248(4) Å and Zn2—O8 3.1598(12) Å; the other zinc centres follow the same trend but, with intermediate separations Zn3⋯S12 = 3.4964(5) Å and Zn3⋯O10 = 3.6291(11) Å, and Zn1⋯S2 = 3.5116(4) Å and Zn1⋯O3 = 3.2159(12) Å. The P—S bond lengths also exhibit definitive trends with those involving the coordinating sulphur atom being systematically longer (range 2.0190(5) Å, for P7—S13, to 2.0417(6) Å, for P8—S15) than those formed by the formally thione-sulphur atoms [range 1.9331(6) Å, for P8—S16, to 1.9470(6) Å, for P7—S14]. Interestingly, the shortest and longest P—S(thione) bonds involve atoms forming weak Zn⋯S and no Zn⋯S interactions, respectively, indicating no trend in the nature of the sulphur atom and the magnitude of the P=S bond. The coordination geometries for the zinc atoms are based on P2S2 donor sets which define approximate tetrahedra. By contrast to the bond lengths, systematic trends are lacking in the bond angles about the zinc atom. Thus, the bonds subtended by the coordinating sulphur atoms span a range of ca 10°, i.e. S5—Zn2—S7 = 109.371(16)° to S9—Zn3—S11 = 120.758(17)°, and those by the pyridyl-nitrogen atoms, ca 5°, i.e. N8—Zn4—N2i = 97.50(5)° to N1—Zn1—N3 = 102.09(5)°. However, despite these variations, the range of tetrahedral angles about the individual zinc atoms is narrow, being about 21° for the Zn4 atom [S15—Zn4—N2i = 97.15(4)° to S13—Zn4—S15 = 117.883(16)°] and about 23° for the Zn1 atom [S3—Zn1—N1 = 97.80(4)° to S1—Zn1—N3 = 120.32(4)°]. The twists between the pyridyl rings of the 4,4′-bipy molecules also differentiate the four repeat units with the dihedral angles between the N1-/N2-pyridyl [35.06(7)°], N3-/N4-pyridyl [17.40(8)°], N5-/N6-pyridyl [22.25(8)°] and N7-/N8-pyridyl [13.00(8)°] rings varying by over 20°.

In the crystal, the zig-zag chains run parallel to [2 0 −1]. The connections between the chains to consolidate the three-dimensional architecture are of the type C—H⋯O, C—H⋯S and C—H⋯π. Of each of these, the shortest and most directional interactions are pyridyl-C—H⋯O(ethoxy), pyridyl-C—H⋯S(coordinating) and methyl-C—H⋯π(pyridyl) [C56—H56⋯O1ii: H56⋯O1ii = 2.47 Å, C56⋯O1ii = 3.351(2) Å with angle at H56 = 153°, C38—H38⋯S9iii: H38⋯S9iii = 2.82 Å, C38⋯S9iii = 3.7031(17) Å with angle at H38 = 156° and C6—H6a⋯Cg(N7, C55—C59)iv: H6a⋯Cg(N7, C55—C59)iv = 2.85 Å, C6⋯Cg(N7, C55—C59)iv = 3.776(2) Å with angle at H6a = 158° for symmetry operations (ii) −1 + x, y, 1 + z, (iii) 1 − x, −y, 1 − z and (iv) 1 − x, −y, 1 − z].

The crystal of the room temperature (296 K) polymorph of (I) is also triclinic P1̅, with two independent repeat units of Zn[S2P(OEt)2]2(4,4′-bipy) in the asymmetric unit [8]. Similar coordination modes for the dithiophosphate ligands about each zinc atom, as described above, are apparent in the room-temperature form. The pitch in the zig-zag chains in (I) range from 16.2 to 17.5 Å, and match those in the literature precedent, i.e. 16.4 to 17.5 Å [8].

Finally, in an accompanying report, a low temperature (100 K) polymorph for {Cd[S2P(OEt)2]2(4,4′bipy)}n was described [13]. This, as was the room temperature (293 K) form [14], is a linear coordination polymer with a trans-N2S4 coordination geometry for the cadmium(II) centre. The obvious difference between the room- and low-temperature forms is in the number of Cd[S2P(OEt)2]2(4,4′-bipy) repeating units. In the former, the repeat unit lies on a centre of inversion, whereas in the latter, there are four independent repeat units, two in general positions and two with the cadmium atom lying on a centre of inversion.

Acknowledgements

Sunway University Sdn Bhd is thanked for financial support of this work through Grant no. STR-RCTR-RCCM-001-2019.

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Received: 2019-08-16
Accepted: 2019-10-03
Published Online: 2019-10-18
Published in Print: 2019-12-18

©2019 Yee Seng Tan et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

Artikel in diesem Heft

  1. 10.1515/ncrs-2020-frontmatter1
  2. The crystal structure of 3,5-dicarboxybenzenaminium perchlorate monohydrate, C8H8ClNO9
  3. The crystal structure of poly[(m4-4-bromoisophthalato-κ4O: O′:O′′:O′′′)zinc(II)], C8H3BrO4Zn
  4. Crystal structure of (E)-2-(2-chloro-6-hydroxybenzylidene)hydrazine-1-carbothioamide, C8H8ClN3O4S
  5. Crystal structure of 1,1′-methylenebis(3-ethyl-1H-imidazol-3-ium) bis(hexafluorophosphate(V)), C11H18F12N4P2
  6. The crystal structure of hexakis(1-isopropyl-1H-imidazole-κ1N)copper(II) dichloride, C36H58Cl2CuN12
  7. Crystal structure of catena-poly[μ2-4,4′-bipyridine-κ2N:N′)-tetrakis(μ2-2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-κ2O:O′)dicobalt(II)], C19H10Cl6CoN3O6
  8. Crystal structure of (E)-1-(4-(((E)-2-bromo-6-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H15BrN2O2
  9. Crystal structure of ethyl 2-methyl-4-(5-methylthiophen-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C18H21NO3S
  10. The crystal structure of 5-bromo-2-(1-methyl-1H-tetrazol-5-yl)pyridine, C7H6BrN5
  11. Crystal structure of Bis(acetato-κ2O,O′)-bis[4-(dimethylamino)pyridine-κN]nickel(II), C18H26N4NiO4
  12. Crystal structure of (E)-3-chloro-2-(((4-chlorophenyl)imino)methyl)phenol, C13H9Cl2NO
  13. The co-crystal structure of (17b)-estra-1,3,5(10)-triene-3,17diol – acetamide (1/1), a Z′ = 4 structure, C20H29NO3
  14. Crystal structure of 3-(3-(pyridin-3-yl)ureido)benzoic acid, C13H11N3O3
  15. The crystal structure of 1,1′-(9-ethyl-9H-carbazole-3,6-diyl)bis(3-ethyl-1H-imidazol-3-ium) bis(hexafluorophosphate(IV)), C24H27N5F12P2
  16. The crystal structure of 2-bromoisophthalic acid, C8H5BrO4
  17. The crystal structure of 13-ethoxycarbonyl-9-methyl-4-chlor-11-thioxo-8-oxa-10,12-diazatricyclo[7.3.1.02,7]trideca-2,4,6-triene, C14H15ClN2O3S
  18. The crystal structure of (E)-4-((4-(diethylamino)benzylidene)amino)-N,N-diphenylaniline, C29H29N3
  19. Crystal structure of 2-(3-(2-(4-phenylpiperazin-1-yl)ethyl)benzyl)isoindoline-1,3-dione, C27H27N3O2
  20. Crystal structure of 2-ethoxy-6-((E)-((3-(((E)-3-ethoxy-2-hydroxybenzylidene)amino)-2-hydroxypropyl)iminio)methyl)phenolate, C21H26N2O5
  21. The crystal structure of catena-poly(μ2-4,4′-bipyridine-κ2N:N′)-tetrakis(μ2-2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-κ2O:O′)dinickel(II)], C19H10Cl6N3NiO6
  22. Crystal structure of hexakis(μ2-azido-κ2N:N)-diazido-κ1N-tetrakis(phenanthroline-κ2N,N′)tetrazinc(II), C48H32N32Zn4
  23. Synthesis and crystal structure of bis{2-bromo-6-(((4-(1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O}cobalt(II)–dichloromethane(1/1), C34H32Br2Cl4CoN4O4
  24. Crystal structure of (E)-3-chloro-2-(((4-nitrophenyl)imino)methyl)phenol, C13H9ClN2O3
  25. Crystal structure of aqua-bis(5-bromo-6-methyl-picolinato-κ2N,O)zinc(II) dihydrate, C14H16Br2N2O7Zn
  26. Crystal structure of biaqua(2,2′-bipyridine-4,4′-dicarboxylato-κ2N,N′)(pyridine-2,6-dicarboxylato-κ3O,N,O′)nickel(II) hydrate, C19H15N3NiO10
  27. Synthesis and crystal structure of bis(2-(((4-(1-(ethoxyimino)ethyl)phenyl)imino)methyl)-5-fluorophenolato-κ2N,O)zinc(II) - methanol (1/1), C33H32F2N4O4Zn
  28. Crystal structure of tetraaqua-bis(μ2-5-aminoisophthalato-κ3N:O,O′)-bis(4,4′-dipyridylsulfide-κ1N)dizinc(II), C36H34N6O12S2Ni2
  29. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)palladium(II) tetracyanonickelate(II), C14H24N8NiPd
  30. The crystal structure of 3-benzyl-1-((8-(benzyloxy)quinolin-2-yl)methyl)-1H-imidazol-3-ium hexafluorophosphate, C27H24N3OF6P
  31. Crystal structure of 1-(4-chloro-2-hydroxy-5-iodophenyl)ethan-1-one, C8H6ClIO2
  32. Crystal structure of hexaaquamagnesium(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MgN6O12S2
  33. Crystal structure of the coordination polymer catena-poly[(1,2-di(pyridin-4-yl)ethane-κN)-(μ2-2-nitroisophthalato-κ2O:O′)zinc(II)], C20H17N3O7Zn
  34. Crystal structure of catena-{[tri-aqua-di-sodium bis(2-{[n-butyl(methyl)carbamothioyl]sulfanyl}acetate)]}n, [C16H34N2Na2O7S4]n
  35. The crystal structure of diaqua-bis(μ2-3-((3-acetyl-5-carboxyphenyl)oxidophosphoryl)-5-carboxybenzoato-κ2O:O′)bis(5,5′-dimethyl-2,2′-bipyridine-k2N,N′)zinc(II), C56H46N4O22P2Zn2
  36. Crystal structure of N′,2-bis((E)-2-chloro-6-hydroxybenzylidene)hydrazine-1-carbothiohydrazide, C15H12Cl2N4O2S
  37. Crystal structure of 2-[(1E)-{[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]iminiumyl}methyl]-5-(dodecyloxy)benzen-1-olate, C23H39NO5
  38. Crystal structure of 12-(2-hydroxybenzoyl)benzo[f]pyrido[1,2-a]indole-6,11-dione, C23H13NO4
  39. Crystal structure of chlorido-(4-chloro-6-(p-tolyl)pyrimidine-κ2C,N)-(triphenylphosphane-κP)palladium(II), C29H23Cl2N2PPd
  40. Crystal structure of catena-poly[diaqua-bis(3,4,5,6-tetrabromo-carboxybenzoato-κ1O)-(μ2-4,4′-bipyridine-κ2N:N′)cobalt(II)], C26H14Br8CoN2O10
  41. Crystal structure of catena-poly[dibenzyl-dichlorido-(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′)tin(IV)], C24H22Cl2N2O2Sn
  42. Crystal structure of benzyl-chlorido-(4-chloro-N-[(2-oxidophenyl)methylidene]benzenecarbohydrazonato)-methanol-tin(IV), C22H20Cl2N2O3Sn
  43. Crystal structure of catena-poly[triaqua-(1,3-di(1H-imidazol-1-yl)benzene-κ2N:N′)-(3-nitrophthalato-κ1O)cobalt(II)] — water (2/3), C20H22N5O10.5Co
  44. Crystal structure of (3R,5R,8R,9R,10R,12R,13R,14R)-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)hexadecahydro-1H-cyclopenta[a]phenanthrene-3,12-diol, C30H52O3
  45. Crystal structure of 3-(3-(4-carboxyphenyl)ureido)pyridin-1-ium perchlorate, C26H24Cl2N6O14
  46. Crystal structure of 8-hydroxy-2-methylquinolin-1-ium chloride dihydrate, C10H14ClNO3
  47. Crystal structure of (dibenzyl sulphoxide-κO)dibromido-bis(4-bromobenzyl-κC)tin(IV), C28H26Br4OSSn
  48. Crystal structure of bromido-tri(4-chlorophenyl-κ1C)-(ethanol-κ1O)tin(IV) — 4,4′-dimethyl-2,2′-bipyridine (2/1), C52H48Br2Cl6N2O2Sn2
  49. Crystal structure of 2-butyl-6-(ethylamino)-1H-benzo[de]isoquinoline-1,3(2H)-dione, C18H20N2O2
  50. Crystal structure of (4-chloro-N-[(2-oxido-5-chlorophenyl)methylidene] benzene-carbohydrazonato-κ3N,O,O′)bis(2-fluorobenzyl)tin(IV), C28H20Cl2F2N2O2Sn
  51. Crystal structure of aqua-chlorido-(4-fluorobenzyl-κC)-(N′-(4-methoxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ3N,O,O′)tin(IV), C26H22ClFN2O5Sn
  52. Crystal structure of catena-poly[tri(4-chlorophenyl)-(μ2-hydroxido)tin(IV)] – 2-propanol (1/1), C21H21Cl3O2Sn
  53. Crystal structure of bromido-dimethyl-4-tolyl-(triphenylphosphine oxide)tin(IV), C27H28BrOPSn
  54. Crystal structure of 2-(bis(2-hydroxyethyl)ammonio)ethane-1-sulfonate, C6H15NO5S
  55. Crystal structure of bis[triaqua-(μ2-1,2-di(4-pyridyl)ethylene-κ2N:N′)-(4-sulfonatobenzoato-κ2O,O′)zinc(II)], C13H15NO8SZn
  56. Crystal structure of 2-((2-(3-hydroxy-7-methylene-2,3-dihydro-7H-furo[3,2-g]chromen-2-yl)propan-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol – a marmesin derivative, C20H24O10
  57. Crystal structure of octa(4-chlorobenzyl)-dichlorido-bis(μ2-methanolato)-bis(μ3-oxo)-tetratin(IV), C58H54Cl10O4Sn4
  58. Crystal structure of iodido-triphenyl-(triphenylphosphine oxide)tin(IV), C36H30IOPSn
  59. Crystal structure of dichlorido-bis(4-methylphenyl-κC)-bis(triphenylarsine oxide-κO)tin(IV), C50H44As2Cl2O2Sn
  60. Crystal structure of 4-benzyl-1-oxo-N-phenethyl-1H-[1,4]oxazino [4,3-b]indazole-3-carboxamide, C26H21N3O3
  61. Crystal structure of bis{(N-[(5-chloro-2-oxidophenyl)methylidene]-2-hydroxybenzenecarbohydrazonato)-dioxo-molybdenum(VI)}(μ2-4,4′-bipyridine), C38H26Cl2Mo2N6O10
  62. Crystal structure of dichlorido-octamethyl-bis(μ3-oxido)-bis(μ2-2-(phenylamino)ethanolato-κ2O:O)tetratin(IV), C24H44Cl2N2O4Sn4
  63. The crystal structure of 1-(2-(2-(imidazo[1,5-a]pyridine-4-ium)ethoxy)ethyl)-imidazo[1,5-a]pyridine-4-ium bis(hexafluorophosphate) — acetonitrile (1/1), C18H20ON4F12P2
  64. Crystal structure of cyclo[tetra(μ2-cyanido)-tetracyanido-bis(1,4,7,10-tetraazacyclododecane-κ4N,N′,N′′,N′′′)dinickel(II)dipalladium(II)] hexahydrate, C24H52N16Ni2O6Pd2
  65. Crystal structure of (dimethyl sulfoxide)-dioxido-[2-hydroxy-N′-(4-oxo-4-phenylbutan-2-ylidene)benzohydrazidato κ3N,O,O′]molybdenum(VI), C19H20MoN2O6S
  66. Crystal structure of bis(acetylacetonato-κ2O,O′)-(ethanolamine-κ2N,O)copper(II), C14H25CuNO5
  67. Crystal structure of chlorido-diphenyl-(isopropyl(propyl)carbamodithioato-κ2S,S′)tin(IV), C19H24ClNS2Sn
  68. The crystal structure of bis(imidazole-1-yl)methane monohydrate, C7H10N4O
  69. The crystal structure of bis(4-nitroimidazole-1-1yl)methane, C7H6N6O4
  70. Crystal structure of di(naphthalen-2-yl)sulfane, C20H14S
  71. Crystal structure of 3-acetyl-6-bromo-4-hydroxy-2H-chromen-2-one, C11H7BrO4
  72. Crystal structure of N′2,N′6-bis((E)-1-(pyrazin-2-yl)ethylidene)pyridine-2,6-dicarbohydrazide — methanol (1/2), C21H25N9O4
  73. The crystal structure of 3-nitro-4-(p-tolylamino)-2H-chromen-2-one, C16H12N2O4
  74. The crystal structure of 1,2-bis((4-methoxyphenyl)ethynyl)benzene, C24H18O2
  75. Crystal structure of a low-temperature (100 K) polymorph of catena-poly[(μ2-4,4′-bipyridine-κ2N,N′)-bis(O,O′-diethyldithiophosphato-κ1S)zinc(II)], C18H28N2O4P2S4Zn
  76. The pseudosymmetric low temperature polymorph of catena-poly[(μ2-4,4′-bipyridyl-κN,N′)-bis(O,O′-diethyldithiophosphato-κS)-cadmium(II)], {C18H28CdN2O4P2S4}n
  77. Crystal structure of 3-iodophthalic acid, C8H5IO4
  78. The crystal structure of tert-butyl (tert-butoxy(oxo)methyl)(5-bromo-2-fluorophenyl)carbamate, C16H21BrFNO4
  79. The crystal structure of bis(μ2-5,7-dichloroquinolin-8-olato-κ3N,O:O)-tetrakis(5,7-dichloroquinolin-8-olato-κ2N,O)bis(methanol-κ1O)dieuropium(III) — toluene (1/1), C63H39Cl12Eu2N6O8
  80. Crystal structure of dichlorido-(N′-(1-(3-ethylpyrazin-2-yl)ethylidene)-4-methoxybenzohydrazide-κ3N,N′,O)cadmium(II), C16H18N4O2Cl2Cd
  81. A redetermination of the crystal structure of catena-poly[(bis(O,O′-isopropyl dithiophosphato-κ2S,S′)-(μ2-1,2-bis(3-pyridylmethylene)hydrazine-κ2N,N′)cadmium(II)], {C24H38CdN4O4P2S4}n
https://doi.org/10.1515/ncrs-2019-0594
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Artikel in diesem Heft

  1. 10.1515/ncrs-2020-frontmatter1
  2. The crystal structure of 3,5-dicarboxybenzenaminium perchlorate monohydrate, C8H8ClNO9
  3. The crystal structure of poly[(m4-4-bromoisophthalato-κ4O: O′:O′′:O′′′)zinc(II)], C8H3BrO4Zn
  4. Crystal structure of (E)-2-(2-chloro-6-hydroxybenzylidene)hydrazine-1-carbothioamide, C8H8ClN3O4S
  5. Crystal structure of 1,1′-methylenebis(3-ethyl-1H-imidazol-3-ium) bis(hexafluorophosphate(V)), C11H18F12N4P2
  6. The crystal structure of hexakis(1-isopropyl-1H-imidazole-κ1N)copper(II) dichloride, C36H58Cl2CuN12
  7. Crystal structure of catena-poly[μ2-4,4′-bipyridine-κ2N:N′)-tetrakis(μ2-2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-κ2O:O′)dicobalt(II)], C19H10Cl6CoN3O6
  8. Crystal structure of (E)-1-(4-(((E)-2-bromo-6-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H15BrN2O2
  9. Crystal structure of ethyl 2-methyl-4-(5-methylthiophen-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C18H21NO3S
  10. The crystal structure of 5-bromo-2-(1-methyl-1H-tetrazol-5-yl)pyridine, C7H6BrN5
  11. Crystal structure of Bis(acetato-κ2O,O′)-bis[4-(dimethylamino)pyridine-κN]nickel(II), C18H26N4NiO4
  12. Crystal structure of (E)-3-chloro-2-(((4-chlorophenyl)imino)methyl)phenol, C13H9Cl2NO
  13. The co-crystal structure of (17b)-estra-1,3,5(10)-triene-3,17diol – acetamide (1/1), a Z′ = 4 structure, C20H29NO3
  14. Crystal structure of 3-(3-(pyridin-3-yl)ureido)benzoic acid, C13H11N3O3
  15. The crystal structure of 1,1′-(9-ethyl-9H-carbazole-3,6-diyl)bis(3-ethyl-1H-imidazol-3-ium) bis(hexafluorophosphate(IV)), C24H27N5F12P2
  16. The crystal structure of 2-bromoisophthalic acid, C8H5BrO4
  17. The crystal structure of 13-ethoxycarbonyl-9-methyl-4-chlor-11-thioxo-8-oxa-10,12-diazatricyclo[7.3.1.02,7]trideca-2,4,6-triene, C14H15ClN2O3S
  18. The crystal structure of (E)-4-((4-(diethylamino)benzylidene)amino)-N,N-diphenylaniline, C29H29N3
  19. Crystal structure of 2-(3-(2-(4-phenylpiperazin-1-yl)ethyl)benzyl)isoindoline-1,3-dione, C27H27N3O2
  20. Crystal structure of 2-ethoxy-6-((E)-((3-(((E)-3-ethoxy-2-hydroxybenzylidene)amino)-2-hydroxypropyl)iminio)methyl)phenolate, C21H26N2O5
  21. The crystal structure of catena-poly(μ2-4,4′-bipyridine-κ2N:N′)-tetrakis(μ2-2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-κ2O:O′)dinickel(II)], C19H10Cl6N3NiO6
  22. Crystal structure of hexakis(μ2-azido-κ2N:N)-diazido-κ1N-tetrakis(phenanthroline-κ2N,N′)tetrazinc(II), C48H32N32Zn4
  23. Synthesis and crystal structure of bis{2-bromo-6-(((4-(1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O}cobalt(II)–dichloromethane(1/1), C34H32Br2Cl4CoN4O4
  24. Crystal structure of (E)-3-chloro-2-(((4-nitrophenyl)imino)methyl)phenol, C13H9ClN2O3
  25. Crystal structure of aqua-bis(5-bromo-6-methyl-picolinato-κ2N,O)zinc(II) dihydrate, C14H16Br2N2O7Zn
  26. Crystal structure of biaqua(2,2′-bipyridine-4,4′-dicarboxylato-κ2N,N′)(pyridine-2,6-dicarboxylato-κ3O,N,O′)nickel(II) hydrate, C19H15N3NiO10
  27. Synthesis and crystal structure of bis(2-(((4-(1-(ethoxyimino)ethyl)phenyl)imino)methyl)-5-fluorophenolato-κ2N,O)zinc(II) - methanol (1/1), C33H32F2N4O4Zn
  28. Crystal structure of tetraaqua-bis(μ2-5-aminoisophthalato-κ3N:O,O′)-bis(4,4′-dipyridylsulfide-κ1N)dizinc(II), C36H34N6O12S2Ni2
  29. Crystal structure of (1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)palladium(II) tetracyanonickelate(II), C14H24N8NiPd
  30. The crystal structure of 3-benzyl-1-((8-(benzyloxy)quinolin-2-yl)methyl)-1H-imidazol-3-ium hexafluorophosphate, C27H24N3OF6P
  31. Crystal structure of 1-(4-chloro-2-hydroxy-5-iodophenyl)ethan-1-one, C8H6ClIO2
  32. Crystal structure of hexaaquamagnesium(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MgN6O12S2
  33. Crystal structure of the coordination polymer catena-poly[(1,2-di(pyridin-4-yl)ethane-κN)-(μ2-2-nitroisophthalato-κ2O:O′)zinc(II)], C20H17N3O7Zn
  34. Crystal structure of catena-{[tri-aqua-di-sodium bis(2-{[n-butyl(methyl)carbamothioyl]sulfanyl}acetate)]}n, [C16H34N2Na2O7S4]n
  35. The crystal structure of diaqua-bis(μ2-3-((3-acetyl-5-carboxyphenyl)oxidophosphoryl)-5-carboxybenzoato-κ2O:O′)bis(5,5′-dimethyl-2,2′-bipyridine-k2N,N′)zinc(II), C56H46N4O22P2Zn2
  36. Crystal structure of N′,2-bis((E)-2-chloro-6-hydroxybenzylidene)hydrazine-1-carbothiohydrazide, C15H12Cl2N4O2S
  37. Crystal structure of 2-[(1E)-{[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]iminiumyl}methyl]-5-(dodecyloxy)benzen-1-olate, C23H39NO5
  38. Crystal structure of 12-(2-hydroxybenzoyl)benzo[f]pyrido[1,2-a]indole-6,11-dione, C23H13NO4
  39. Crystal structure of chlorido-(4-chloro-6-(p-tolyl)pyrimidine-κ2C,N)-(triphenylphosphane-κP)palladium(II), C29H23Cl2N2PPd
  40. Crystal structure of catena-poly[diaqua-bis(3,4,5,6-tetrabromo-carboxybenzoato-κ1O)-(μ2-4,4′-bipyridine-κ2N:N′)cobalt(II)], C26H14Br8CoN2O10
  41. Crystal structure of catena-poly[dibenzyl-dichlorido-(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′)tin(IV)], C24H22Cl2N2O2Sn
  42. Crystal structure of benzyl-chlorido-(4-chloro-N-[(2-oxidophenyl)methylidene]benzenecarbohydrazonato)-methanol-tin(IV), C22H20Cl2N2O3Sn
  43. Crystal structure of catena-poly[triaqua-(1,3-di(1H-imidazol-1-yl)benzene-κ2N:N′)-(3-nitrophthalato-κ1O)cobalt(II)] — water (2/3), C20H22N5O10.5Co
  44. Crystal structure of (3R,5R,8R,9R,10R,12R,13R,14R)-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)hexadecahydro-1H-cyclopenta[a]phenanthrene-3,12-diol, C30H52O3
  45. Crystal structure of 3-(3-(4-carboxyphenyl)ureido)pyridin-1-ium perchlorate, C26H24Cl2N6O14
  46. Crystal structure of 8-hydroxy-2-methylquinolin-1-ium chloride dihydrate, C10H14ClNO3
  47. Crystal structure of (dibenzyl sulphoxide-κO)dibromido-bis(4-bromobenzyl-κC)tin(IV), C28H26Br4OSSn
  48. Crystal structure of bromido-tri(4-chlorophenyl-κ1C)-(ethanol-κ1O)tin(IV) — 4,4′-dimethyl-2,2′-bipyridine (2/1), C52H48Br2Cl6N2O2Sn2
  49. Crystal structure of 2-butyl-6-(ethylamino)-1H-benzo[de]isoquinoline-1,3(2H)-dione, C18H20N2O2
  50. Crystal structure of (4-chloro-N-[(2-oxido-5-chlorophenyl)methylidene] benzene-carbohydrazonato-κ3N,O,O′)bis(2-fluorobenzyl)tin(IV), C28H20Cl2F2N2O2Sn
  51. Crystal structure of aqua-chlorido-(4-fluorobenzyl-κC)-(N′-(4-methoxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ3N,O,O′)tin(IV), C26H22ClFN2O5Sn
  52. Crystal structure of catena-poly[tri(4-chlorophenyl)-(μ2-hydroxido)tin(IV)] – 2-propanol (1/1), C21H21Cl3O2Sn
  53. Crystal structure of bromido-dimethyl-4-tolyl-(triphenylphosphine oxide)tin(IV), C27H28BrOPSn
  54. Crystal structure of 2-(bis(2-hydroxyethyl)ammonio)ethane-1-sulfonate, C6H15NO5S
  55. Crystal structure of bis[triaqua-(μ2-1,2-di(4-pyridyl)ethylene-κ2N:N′)-(4-sulfonatobenzoato-κ2O,O′)zinc(II)], C13H15NO8SZn
  56. Crystal structure of 2-((2-(3-hydroxy-7-methylene-2,3-dihydro-7H-furo[3,2-g]chromen-2-yl)propan-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol – a marmesin derivative, C20H24O10
  57. Crystal structure of octa(4-chlorobenzyl)-dichlorido-bis(μ2-methanolato)-bis(μ3-oxo)-tetratin(IV), C58H54Cl10O4Sn4
  58. Crystal structure of iodido-triphenyl-(triphenylphosphine oxide)tin(IV), C36H30IOPSn
  59. Crystal structure of dichlorido-bis(4-methylphenyl-κC)-bis(triphenylarsine oxide-κO)tin(IV), C50H44As2Cl2O2Sn
  60. Crystal structure of 4-benzyl-1-oxo-N-phenethyl-1H-[1,4]oxazino [4,3-b]indazole-3-carboxamide, C26H21N3O3
  61. Crystal structure of bis{(N-[(5-chloro-2-oxidophenyl)methylidene]-2-hydroxybenzenecarbohydrazonato)-dioxo-molybdenum(VI)}(μ2-4,4′-bipyridine), C38H26Cl2Mo2N6O10
  62. Crystal structure of dichlorido-octamethyl-bis(μ3-oxido)-bis(μ2-2-(phenylamino)ethanolato-κ2O:O)tetratin(IV), C24H44Cl2N2O4Sn4
  63. The crystal structure of 1-(2-(2-(imidazo[1,5-a]pyridine-4-ium)ethoxy)ethyl)-imidazo[1,5-a]pyridine-4-ium bis(hexafluorophosphate) — acetonitrile (1/1), C18H20ON4F12P2
  64. Crystal structure of cyclo[tetra(μ2-cyanido)-tetracyanido-bis(1,4,7,10-tetraazacyclododecane-κ4N,N′,N′′,N′′′)dinickel(II)dipalladium(II)] hexahydrate, C24H52N16Ni2O6Pd2
  65. Crystal structure of (dimethyl sulfoxide)-dioxido-[2-hydroxy-N′-(4-oxo-4-phenylbutan-2-ylidene)benzohydrazidato κ3N,O,O′]molybdenum(VI), C19H20MoN2O6S
  66. Crystal structure of bis(acetylacetonato-κ2O,O′)-(ethanolamine-κ2N,O)copper(II), C14H25CuNO5
  67. Crystal structure of chlorido-diphenyl-(isopropyl(propyl)carbamodithioato-κ2S,S′)tin(IV), C19H24ClNS2Sn
  68. The crystal structure of bis(imidazole-1-yl)methane monohydrate, C7H10N4O
  69. The crystal structure of bis(4-nitroimidazole-1-1yl)methane, C7H6N6O4
  70. Crystal structure of di(naphthalen-2-yl)sulfane, C20H14S
  71. Crystal structure of 3-acetyl-6-bromo-4-hydroxy-2H-chromen-2-one, C11H7BrO4
  72. Crystal structure of N′2,N′6-bis((E)-1-(pyrazin-2-yl)ethylidene)pyridine-2,6-dicarbohydrazide — methanol (1/2), C21H25N9O4
  73. The crystal structure of 3-nitro-4-(p-tolylamino)-2H-chromen-2-one, C16H12N2O4
  74. The crystal structure of 1,2-bis((4-methoxyphenyl)ethynyl)benzene, C24H18O2
  75. Crystal structure of a low-temperature (100 K) polymorph of catena-poly[(μ2-4,4′-bipyridine-κ2N,N′)-bis(O,O′-diethyldithiophosphato-κ1S)zinc(II)], C18H28N2O4P2S4Zn
  76. The pseudosymmetric low temperature polymorph of catena-poly[(μ2-4,4′-bipyridyl-κN,N′)-bis(O,O′-diethyldithiophosphato-κS)-cadmium(II)], {C18H28CdN2O4P2S4}n
  77. Crystal structure of 3-iodophthalic acid, C8H5IO4
  78. The crystal structure of tert-butyl (tert-butoxy(oxo)methyl)(5-bromo-2-fluorophenyl)carbamate, C16H21BrFNO4
  79. The crystal structure of bis(μ2-5,7-dichloroquinolin-8-olato-κ3N,O:O)-tetrakis(5,7-dichloroquinolin-8-olato-κ2N,O)bis(methanol-κ1O)dieuropium(III) — toluene (1/1), C63H39Cl12Eu2N6O8
  80. Crystal structure of dichlorido-(N′-(1-(3-ethylpyrazin-2-yl)ethylidene)-4-methoxybenzohydrazide-κ3N,N′,O)cadmium(II), C16H18N4O2Cl2Cd
  81. A redetermination of the crystal structure of catena-poly[(bis(O,O′-isopropyl dithiophosphato-κ2S,S′)-(μ2-1,2-bis(3-pyridylmethylene)hydrazine-κ2N,N′)cadmium(II)], {C24H38CdN4O4P2S4}n
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Heruntergeladen am 9.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2019-0594/html
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