Home Crystal Structure of tris(tetrakis{1-vinyl-1H-imidazole-κN}copper(II)) bis[tri-μ2-bromido-tetrabromido-bis(1-vinyl-1H-imidazole-κN)tetracopper(I)], C80H96N32Cu11Br14
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Crystal Structure of tris(tetrakis{1-vinyl-1H-imidazole-κN}copper(II)) bis[tri-μ2-bromido-tetrabromido-bis(1-vinyl-1H-imidazole-κN)tetracopper(I)], C80H96N32Cu11Br14

  • Fu-Jie Liu EMAIL logo and Guo-Xi Wang
Published/Copyright: September 25, 2019
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 234 Issue 6

Abstract

C80H96N32Cu11Br14, triclinic, P1̄ (no. 2), a = 11.370(2) Å, b = 14.287(3) Å, c = 17.621(3) Å, α = 85.929(2)°, β = 88.392(2)°, γ = 74.464(2)°, V = 2750.9(8) Å3, Z = 1, Rgt(F) = 0.0432, wRref(F2) = 0.0859, T = 296(2) K.

CCDC no.: 1920741

The crystal structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Yellow block
Size:0.18 × 0.17 × 0.16 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:7.22 mm−1
Diffractometer, scan mode:Bruker SMART, φ and ω-scans
θmax, completeness:25°, >99%
N(hkl)measured, N(hkl)unique, Rint:41708, 9671, 0.083
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 5665
N(param)refined:629
Programs:Bruker programs [1], SHELX [2], [3], OLEX2 [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Br10.69435(6)0.33237(5)0.14653(4)0.0563(2)
Br20.73557(8)0.54387(6)0.28770(4)0.0710(2)
Br31.02242(6)0.39541(5)0.16195(4)0.04680(19)
Br41.06701(6)0.11054(5)0.16952(4)0.0587(2)
Br51.33063(6)0.13219(5)0.32275(4)0.04979(19)
Br61.40609(6)−0.07729(5)0.16794(4)0.0526(2)
Br71.16922(7)−0.16903(7)0.31610(5)0.0850(3)
Cu10.52157(7)0.24233(5)0.24128(4)0.0411(2)
Cu20.80650(8)0.42127(6)0.20410(5)0.0552(2)
Cu3a1.0033(8)0.2556(4)0.2380(2)0.0593(8)
Cu3Ab0.963(5)0.2623(15)0.228(2)0.057(6)
Cu41.00000.50000.00000.0361(3)
Cu51.26290(8)0.05462(6)0.22447(5)0.0585(3)
Cu61.35474(8)−0.12991(7)0.29517(5)0.0685(3)
N10.3915(5)0.3709(4)0.2412(3)0.0414(14)
N20.2281(5)0.4756(4)0.2814(3)0.0464(14)
N30.8180(4)0.5491(3)0.0094(3)0.0347(12)
N40.6311(4)0.6099(4)0.0525(3)0.0399(13)
N50.4691(4)0.2061(3)0.1430(3)0.0349(12)
N60.3621(4)0.1742(3)0.0507(3)0.0356(12)
N70.9764(4)0.3811(4)−0.0451(3)0.0355(12)
N80.9183(4)0.2471(4)−0.0497(3)0.0455(14)
N90.5732(4)0.2693(4)0.3436(3)0.0412(13)
N100.6227(4)0.3411(4)0.4394(3)0.0435(14)
N110.9759(5)0.2322(4)0.3456(3)0.0532(15)
N121.0208(6)0.1570(6)0.4580(4)0.0656(18)
N130.6493(4)0.1151(4)0.2503(3)0.0394(13)
N140.7352(5)−0.0413(4)0.2562(3)0.0421(14)
N151.4873(5)−0.1576(4)0.3703(3)0.0507(15)
N161.6396(5)−0.2385(5)0.4419(4)0.0612(17)
C10.4036(6)0.4629(5)0.2245(4)0.0468(18)
H10.47000.47810.19950.056*
C20.3034(7)0.5283(5)0.2500(4)0.0510(19)
H20.28880.59560.24680.061*
C30.2838(6)0.3830(5)0.2745(4)0.0460(18)
H30.25090.33210.29120.055*
C40.1078(8)0.5075(6)0.3176(4)0.069(2)
H40.06130.46310.32540.083*
C50.0663(8)0.5887(7)0.3378(5)0.091(3)
H5A0.11110.63440.33060.109*
H5B−0.01060.60580.36060.109*
C60.7340(6)0.5394(5)−0.0432(4)0.0481(18)
H60.75360.5109−0.08940.058*
C70.6209(6)0.5772(5)−0.0175(4)0.0459(17)
H70.54870.5807−0.04250.055*
C80.7511(6)0.5911(4)0.0661(4)0.0403(16)
H80.78310.60600.11030.048*
C90.5379(7)0.6546(5)0.1031(4)0.058(2)
H90.56140.67160.14920.069*
C100.4219(7)0.6737(5)0.0899(5)0.073(2)
H10A0.39510.65770.04440.087*
H10B0.36550.70340.12600.087*
C110.5470(6)0.1602(4)0.0880(4)0.0437(17)
H110.63170.14500.09000.052*
C120.4835(6)0.1404(4)0.0312(3)0.0441(17)
H120.51520.1099−0.01270.053*
C130.3586(5)0.2133(4)0.1181(3)0.0344(15)
H130.28700.24190.14400.041*
C140.2607(6)0.1683(5)0.0097(4)0.0529(19)
H140.18390.19400.03080.063*
C150.2653(7)0.1306(5)−0.0542(4)0.072(2)
H15A0.34040.1041−0.07720.086*
H15B0.19360.1295−0.07780.086*
C160.9755(6)0.3587(5)−0.1195(4)0.0478(18)
H160.99650.3949−0.16120.057*
C170.9398(6)0.2764(5)−0.1231(4)0.0533(19)
H170.93150.2457−0.16670.064*
C180.9403(5)0.3115(5)−0.0056(4)0.0426(17)
H180.93140.30820.04710.051*
C190.8814(7)0.1617(6)−0.0201(5)0.075(3)
H190.87620.15060.03240.090*
C200.8570(7)0.1043(6)−0.0602(6)0.102(3)
H20A0.86150.1137−0.11290.122*
H20B0.83380.0507−0.03840.122*
C210.6000(6)0.2045(5)0.4066(4)0.0513(19)
H210.59700.14000.40800.062*
C220.6307(6)0.2467(5)0.4650(4)0.0506(18)
H220.65310.21800.51330.061*
C230.5885(5)0.3509(5)0.3666(4)0.0445(17)
H230.57700.40830.33590.053*
C240.6427(6)0.4183(5)0.4799(4)0.059(2)
H240.63810.47740.45280.071*
C250.6670(6)0.4117(6)0.5524(4)0.081(3)
H25A0.67230.35360.58120.098*
H25B0.67910.46510.57520.098*
C260.9248(6)0.2930(6)0.3998(5)0.067(2)
H260.87720.35650.39020.081*
C270.9522(7)0.2487(7)0.4699(5)0.079(3)
H270.92900.27530.51650.095*
C281.0335(6)0.1500(6)0.3820(5)0.061(2)
H281.07710.09460.35860.073*
C291.0756(9)0.0891(8)0.5186(6)0.099(3)
H291.04780.10270.56780.118*
C301.1548(9)0.0161(7)0.5107(6)0.110(4)
H30A1.18480.00020.46230.132*
H30B1.1863−0.02490.55290.132*
C310.7736(6)0.0991(5)0.2558(4)0.052(2)
H310.81470.14730.25620.063*
C320.8257(6)0.0042(5)0.2604(4)0.057(2)
H320.9087−0.02580.26560.069*
C330.6313(6)0.0290(5)0.2506(3)0.0425(17)
H330.55470.01790.24740.051*
C340.7427(6)−0.1427(5)0.2585(4)0.0546(19)
H340.6725−0.16080.24800.065*
C350.8367(7)−0.2084(6)0.2737(4)0.078(3)
H35A0.9086−0.19290.28450.093*
H35B0.8354−0.27330.27420.093*
C361.5169(7)−0.0959(5)0.4179(4)0.0559(19)
H361.4783−0.02990.41920.067*
C371.6101(7)−0.1452(6)0.4628(4)0.063(2)
H371.6468−0.12050.50040.076*
C381.5636(7)−0.2422(6)0.3872(4)0.061(2)
H381.5646−0.29860.36360.073*
C391.7327(8)−0.3250(8)0.4672(6)0.099(3)
H391.7478−0.37880.43810.119*
C401.7908(10)−0.3307(9)0.5233(6)0.142(5)
H40A1.7774−0.27780.55330.170*
H40B1.8497−0.38800.53700.170*

  1. Occupancies: a = 0.86(3), b = 0.14(3).

Source of material

1-Vinyl-1H-imidazole (1 mmol), copper(I) bromide (1 mmol), and methanol (2 mL) were added to deionized water (0.2 mL) in the heat-resistant glass tube. The mixtures were carefully stirred, and then frozen the tube, finally sealed with a gas burner. The tube was placed in the oven at 60 °C under the hydro-thermal reaction conditions for 3 days to get good quality yellow block crystal appeared in the tube wall.

Experimental details

Hydrogen atoms were added using geometric restraints.

Discussion

Imidazole is of considerable interest as a versatile organic ligand in metal-organic systems in which it offers potential coordinate sites to synthesis coordination polymers [5], [6], [7], [8]. The rational design of crystal structures based on the imidazole derivatives is an exciting research topic in mental-organic chemistry [9], [10], [11]. The transition metal (Cu) together with organic ligands, leads to synthesis of a functional complex. Which have the potential applications, such as catalytic organic reaction [12]. Here, we report the 1-vinyl-1H-imidazole react with copper(I) bromide to obtain the title complex.

Single crystal X-ray diffraction reveals that the copper atoms have four different coordination environments in its crystal structure, presenting a mixed-valence Cu (I/II) complex. The Cu1(II) and Cu4(II) atoms are in twisted tetrahedron coordination environments, respectively, resulting from four coordination of the N atoms of four ligands. The Cu2(I) and Cu5(I) atoms are in distorted trigonal planar geometry, which is defined by a terminal Br atom and two μ-bridging Br atoms. The center of Cu6(I) coordinates a N atom of the ligand, a terminal Br atom and a μ2-Br atom, and completes its coordination environment to a twisted triangle geometry. The central Cu3(I) coordinated with a N atom of the ligand and two μ2-Br atoms to form a distorted triangle geometry. Weak secondary interactions may be present, which gives Cu1(II)—Br1 and Cu4(II)—Br3 bond lengths with 3.0276(11) Å and 3.1102(8) Å. The Cu—Br bond lengths range from 2.3220(11) Å and 2.4196(12) Å in the complex, respectively⋅ The Cu—N bonds lengths range from 1.993(5) Å and 2.2026(5) Å, which are all within a reasonable range [13].

Acknowledgements

This work was supported by Fund of Zhenjiang key laboratory of functional chemistry 2037100003.

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Received: 2019-04-19
Accepted: 2019-06-04
Published Online: 2019-09-25
Published in Print: 2019-11-26

©2019 Fu-Jie Liu et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

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  42. Crystal structure of bis(acridin-10-ium) 2,5-dihydroxyterephthalate — 2,5-dihydroxyterephthalic acid (1/1), C21H15NO6
  43. The crystal structure of 1,12-diazaperylene, C18H10N2
  44. Crystal structure of 1-(5-(4-chlorophenyl)-3-(2-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)ethan-1-one, C17H14N2OFCl
  45. Crystal structure of (4aR,6aR,6bR,10S,12aR)-10-acetoxy-1,2,3,4, 4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a, 12b,13,14b-icosahydro-2,2,4a,6b,9,9,12a-heptamethylpicene-6a-carboxylic acid, C32H50O4
  46. The crystal structure of tetrachlorido-bis{1,3-bis(2,6-diisopropylphenyl)-1H-3λ4-imidazol-2-yl}-(μ2-pyrimidine-κ2N:N′)dipalladium(IV) — dichloromethane (1/2), C60H80Cl8N6Pd2
  47. The crystal structure of (E)-4-(7-methoxy-2-oxo-2H-chromen-8-yl)-2-methylbut-2-en-1-yl 4-nitrobenzoate, C22H19NO7
  48. Crystal structure of 3-methyl-N-(pyrimidin-5-ylmethyl)pyridin-2-amine, C11H12N4
  49. The crystal structure of 2,5-dichloroterephthalic acid dihydrate, C8H8Cl2O6
  50. The crystal structure of 2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine — dimethylformamide (1/1), C33H28N10O
  51. Crystal structure of N-(adamantan-1-yl)-5-(dimethylamino)naphthalene-1-sulfonamide, C22H28N2O2S
  52. Crystal structure of poly[diaqua-(μ4-4-(3,5-dicarboxy-κ1O-phenoxy)phthalato-κ3O:O′:O′)cadmium(II)], C16H12CdO11
  53. Crystal structure of poly[diaqua-bis(μ2-3-((1H-imidazol-1-yl)methyl)benzoato-κ2N:O)manganese(II)], C22H22MnN4O6
  54. Crystal structure of 9-(3-phenoxyphenyl)-3,4,6,7,9,10-hexahydroacridine-1,8(2H,5H)-dione, C25H23NO3
  55. The crystal structure of poly[(μ3-2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine-k3N:N′:N′′)-(nitrato-k2O,O)-(nitrato-k1O)zinc(II)] - N,N-dimethylacetamide (1/2), C38H39N13O8Zn
  56. Crystal structure of poly[(μ7-4-(3,5-dicarboxylatophenoxy)phthalato)-(1,10-phenanthroline-κ2N,N′)dizinc(II)], C28H14N2O9Zn2
  57. The crystal structure of methyl 2-(benzylamino)-5-(benzyloxy)benzoate, C22H21NO3
  58. Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanoplatinate(II), C14H24N8PdPt
  59. Crystal structure of (pyridine-2-carboxylato-κ2N,O)-[2-(2-pyridyl)phenyl-κ2N,C1]palladium(II), C17H12N2O2Pd
  60. Crystal structure of (cyclohexane-1,4-diammonium) 4-[(4-carboxylatophenyl)disulfanyl]benzoate dimethylsulphoxide hydrate (1/1/1/1), [C6H16N2]2+[C14H8O4S2]2−⋅C2H6OS⋅H2O
  61. Crystal structure of the 2:1 co-crystal 2-[(2-carboxyphenyl)disulfanyl]benzoic acid – 3-bromobenzoic acid, 2(C14H10O4S2)⋅C7H5BrO2
  62. Crystal structure of chlorido-dimethyl-(phenylpiperazine-1-carbodithioato-κ2S,S′)tin(IV), C13H19ClN2S2Sn
  63. Crystal structure of (N-n-butyl, N-methyl-dithiocarbamato-κ2 S,S′)-chlorido-dimethyl-tin(IV), C8H18ClNS2Sn
  64. Crystal structure of (2,2′-bipyridyl)bis(4-bromobenzyl)dibromidotin(IV), C24H20Br4N2Sn
  65. Crystal structure of (2,2′-bipyridyl)bis(4-chlorobenzyl)dichloridotin(IV), C24H20Cl4N2Sn
  66. Crystal structure of N-methyl-N-phenyl(methylsulfanyl)carbothioamide, C9H11NS2
  67. Crystal structure of 4-phenylpiperazin-1-ium (4-phenylpiperazin-1-yl)carbothioylsulfanide, [C10H15N2][C11H13N2S2]
  68. Crystal structure of catena-{di-aqua-sodium [n-butyl(methyl)carbamothioyl]sulfanide}n, [C6H16NNaO2S2]n
  69. Crystal structure of (2-([1,1-bis(hydroxymethyl)-2-oxyethyl]iminomethyl)-5-(n-decyl)phenolato)-dimethyl-tin(IV), C23H39NO5Sn
  70. Crystal structure of 4-chloro-N′-[(1E)-(3-ethoxy-2-hydroxyphenyl)methylidene]benzohydrazide – a Z′ = 3 structure, C16H15ClN2O3
https://doi.org/10.1515/ncrs-2019-0283
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Articles in the same Issue

  1. Frontmatter
  2. Crystal structure of [aqua[2,2′-(1,2-phenylene)bis(1H-imidazole-4-carboxylato-5-carboxy)-κ4N3,N3′,O4,O4′] zinc(II)] monohydrate, C16H10N4O9Zn⋅H2O
  3. Crystal structure of ethyl 3-(4-methoxyphenyl)-5-methylcarbamoyl-1H-pyrazole-4-carboxylate, C15H17N3O4
  4. 7-(4-Fluorobenzylidene)-3-(4-fluorophenyl)-N-phenyl-3,3a,4,5,6,7-hexahydro-2H-indazole-2-carbothioamide–dimethylformamide (2/1), C27H23F2N3S, 0.5(C3H7NO)
  5. Crystal structure of 4,4′-(hydrazonomethylene)diphenol dihydrate, C13H16N2O4
  6. Crystal structure of 4-methoxyphenyl-3-phenylpropiolate, C16H12O3
  7. Crystal Structure of tris(tetrakis{1-vinyl-1H-imidazole-κN}copper(II)) bis[tri-μ2-bromido-tetrabromido-bis(1-vinyl-1H-imidazole-κN)tetracopper(I)], C80H96N32Cu11Br14
  8. Crystal structure of (E)-2-(3,6-bis(diethylamino)-9H-xanthen-9-yl)-N′-(quinoxalin-2-ylmethylene)benzohydrazide, C37H36N6O2
  9. Crystal structure of 4-(1-phenylimidazo[1,5-a]pyridin-3-yl)benzoic acid (C20H14N2O2)
  10. Crystal structure of 3-fluoro-3-methyl-1-((2-nitrophenyl)sulfonyl)-5,5-diphenylpiperidine, C24H23FN2O4S
  11. Crystal structure of dimethyl 3,12-dibenzyl-6,10-diphenyl-3,12-diazapentacyclo [6.3.1.02.7.04.11.05.9]-dodecane-7,11-dicarboxylate — acetone (2/1), C40H38N2O2 ⋅ 0.5C3H6O
  12. Crystal structure of poly[(μ2-2-(1H-1,2,4-triazol-1-yl)benzoato-κ4O:O′:N:N′)silver(I)] monohydrate, C9H8AgO3N3
  13. Crystal structure of poly[(μ2-9H-carbazole-3,6-dicarboxylate-κ4O1,O2:O3,O4)(μ2-1,3-di(pyridin-4-yl)propane-κ2N:N′)cadmium(II)]monohydrate, C27H23N3O5Cd
  14. The synthesis and crystal structure of bis(2-(benzo[d]thiazol-2-yl)-5-methylbenzen-1-ido-κ2C,N)-(N,N′-diethyldithiocarbamato-κ2S,S′)iridium(III), C33H30N3S4Ir
  15. The crystal structure of 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfonyl)-1H-pyrazole-3-carboxamide, C12H6N4Cl2F6O3S
  16. Synthesis and crystal structure of poly[(μ2-nitrato-κ4O,O′:O′,O′′)-nitrato-κO-(μ2-1,4-bis((1H-imidazol-1-yl)methyl)benzene-κ2N:N′)cadmium(II)], C14H14N6O6Cd
  17. Crystal structure of ethyl (Z)-(4-oxo-4-phenylbut-2-en-2-yl)glycinate, C14H17NO3
  18. Halogen bonds in the crystal structure of 5-bromo-3,4′-bipyridine – 1,4-diiodotetrafluorobenzene (2/1), C26H14Br2F4I2N4
  19. Crystal structure of bis(2,2′-bipyridine-κ2N,N′)-tetrakis(μ2-3-(phenylsulfonamido)propanoato-κ2O:O′)-bis(3-(phenylsulfonamido)propanoato-κ2O,O′)digadolinium(III) – 2,2′-bipyridine (1/1), C84H84Gd2N12O24S6
  20. Crystal structure of poly[aqua(μ2-2-amino-1,4-benzenedisulfonato-κ2O:O′)bis(μ2-pyrazin-κ2N:N′)silver(I)], C14H16Ag2N5O8S2
  21. The crystal structure of 1,6-di-tert-butyl-1,1,3,3,4,4,6,6-octamethyl-2,2,5,5-tetrakis (trimethylsilyl)hexasilane, C28H78Si10
  22. Crystal structure of discandium triruthenium tetrasilicide, Sc2Ru3Si4
  23. Crystal structure of poly[(μ2-4-amino-1,5-naphthalenedisulfonato-κ4O,N:O′, N′)bis(μ2-hexamethylenetetramino-κ2N;N′)silver(I)], {C22H30Ag2N9O6S2}n
  24. Crystal structure of diaqua[5,5′-dicarboxy-2,2′-(propane-1,3-diyl)bis(1H-imidazole-4-carboxylato-κ4O,O′,N,N′)]zinc(II) dihydrate, C13H18N4O12Zn
  25. The crystal structure of poly [(μ3-N1,N4-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide-κ3-O:N:N′)-(p-toluenesulfonato-κ2O,O′)silver(I)], C25H27Ag1N4O5S
  26. The crystal structure of 1,2-bis(3-bromophenoxy) ethane, C14H12Br2O2
  27. The crystal structure of 4-(pyren-1-yl)butyl-3-nitrobenzoate, C27H21NO4
  28. Crystal structure of bis[(2-(4-chlorophenyl)-5-methyl-1,3-dioxane-5-carboxylato-κ1O) (5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)]nickel(II), C40H60Cl2N4NiO8
  29. The crystal structure of 1,5-dinitro-2,3,4-trichlorobenzene, C6H1Cl3N2O4
  30. The crystal structure of the solid solution of 3,5-dinitropyrazole and 4-chlorine-3,5-dinitropyrazole, C3H1.24Cl0.76N4O4
  31. The cocrystal structure of 4-nitropyrazole — acetic acid (1/1), C5H7N3O4
  32. The crystal structure of propan-2-one O-(2,4,6-trinitrophenyl) oxime, C9H8N4O7
  33. The crystal structure of ethyl 2-(3-(2-ethoxy-2-oxoethyl)benzo[d] thiazol-2(3H)-ylidene)acetate, C15H17NO4S
  34. Crystal structure of (acetic acid-κ1O)-bis(μ2-2-chlorobenzoato-κ2O:O′)-(2-chlorobenzoato-κ1O)-(μ2-hydroxy-κ2O:O)-bis(1,10-phenanthroline-κ2N,N′)dimanganese(II) — methanol (1/1), C48H37Cl3Mn2N4O10
  35. Crystal structure of 3-methyl-2-phenyl-1,8-naphthyridine, C15H12N2
  36. Crystal structure of chlorido-(5-acetyl-2-(5-methylpyridin-2-yl)benzen-1-ido-κ2C,N)-pyridine-κN-palladium(II), C19H17ClN2OPd
  37. Crystal structure of (4-methyl-benzoato-κ2O,O′)-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, C24H45ClN4NiO7
  38. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6) 1,2,3,4,5-pentamethyl-cyclopenta-2,4-dien-1-yl(potassium, rubidium) — ammonia (1/2), [K0.3Rb0.7(18-crown-6)]Cp*⋅2 NH3, C22H45K0.3N2O6Rb0.7
  39. Crystal structure of (3E,5E)-1-((4-fluorophenyl)sulfonyl)-3,5-bis(3-nitrobenzylidene)piperidin-4-one — dichloromethane (2/1), C51H38Cl2F2N6O14S2
  40. Crystal structure of (E)-N′-((1,6-dihydropyren-1-yl)methylene)isonicotinohydrazide — methanol (1/1), C24H19N3O2
  41. Crystal structure of poly[aqua(μ2-2-amino-1,4-benzenedisulfonato-κ3N,O:O′)-(μ4-hexamethylenetetramino-κ4N:N′:N′′:N′′′)disilver(I)] monohydrate, C12H21Ag2N5O8S2
  42. Crystal structure of bis(acridin-10-ium) 2,5-dihydroxyterephthalate — 2,5-dihydroxyterephthalic acid (1/1), C21H15NO6
  43. The crystal structure of 1,12-diazaperylene, C18H10N2
  44. Crystal structure of 1-(5-(4-chlorophenyl)-3-(2-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)ethan-1-one, C17H14N2OFCl
  45. Crystal structure of (4aR,6aR,6bR,10S,12aR)-10-acetoxy-1,2,3,4, 4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a, 12b,13,14b-icosahydro-2,2,4a,6b,9,9,12a-heptamethylpicene-6a-carboxylic acid, C32H50O4
  46. The crystal structure of tetrachlorido-bis{1,3-bis(2,6-diisopropylphenyl)-1H-3λ4-imidazol-2-yl}-(μ2-pyrimidine-κ2N:N′)dipalladium(IV) — dichloromethane (1/2), C60H80Cl8N6Pd2
  47. The crystal structure of (E)-4-(7-methoxy-2-oxo-2H-chromen-8-yl)-2-methylbut-2-en-1-yl 4-nitrobenzoate, C22H19NO7
  48. Crystal structure of 3-methyl-N-(pyrimidin-5-ylmethyl)pyridin-2-amine, C11H12N4
  49. The crystal structure of 2,5-dichloroterephthalic acid dihydrate, C8H8Cl2O6
  50. The crystal structure of 2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine — dimethylformamide (1/1), C33H28N10O
  51. Crystal structure of N-(adamantan-1-yl)-5-(dimethylamino)naphthalene-1-sulfonamide, C22H28N2O2S
  52. Crystal structure of poly[diaqua-(μ4-4-(3,5-dicarboxy-κ1O-phenoxy)phthalato-κ3O:O′:O′)cadmium(II)], C16H12CdO11
  53. Crystal structure of poly[diaqua-bis(μ2-3-((1H-imidazol-1-yl)methyl)benzoato-κ2N:O)manganese(II)], C22H22MnN4O6
  54. Crystal structure of 9-(3-phenoxyphenyl)-3,4,6,7,9,10-hexahydroacridine-1,8(2H,5H)-dione, C25H23NO3
  55. The crystal structure of poly[(μ3-2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine-k3N:N′:N′′)-(nitrato-k2O,O)-(nitrato-k1O)zinc(II)] - N,N-dimethylacetamide (1/2), C38H39N13O8Zn
  56. Crystal structure of poly[(μ7-4-(3,5-dicarboxylatophenoxy)phthalato)-(1,10-phenanthroline-κ2N,N′)dizinc(II)], C28H14N2O9Zn2
  57. The crystal structure of methyl 2-(benzylamino)-5-(benzyloxy)benzoate, C22H21NO3
  58. Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanoplatinate(II), C14H24N8PdPt
  59. Crystal structure of (pyridine-2-carboxylato-κ2N,O)-[2-(2-pyridyl)phenyl-κ2N,C1]palladium(II), C17H12N2O2Pd
  60. Crystal structure of (cyclohexane-1,4-diammonium) 4-[(4-carboxylatophenyl)disulfanyl]benzoate dimethylsulphoxide hydrate (1/1/1/1), [C6H16N2]2+[C14H8O4S2]2−⋅C2H6OS⋅H2O
  61. Crystal structure of the 2:1 co-crystal 2-[(2-carboxyphenyl)disulfanyl]benzoic acid – 3-bromobenzoic acid, 2(C14H10O4S2)⋅C7H5BrO2
  62. Crystal structure of chlorido-dimethyl-(phenylpiperazine-1-carbodithioato-κ2S,S′)tin(IV), C13H19ClN2S2Sn
  63. Crystal structure of (N-n-butyl, N-methyl-dithiocarbamato-κ2 S,S′)-chlorido-dimethyl-tin(IV), C8H18ClNS2Sn
  64. Crystal structure of (2,2′-bipyridyl)bis(4-bromobenzyl)dibromidotin(IV), C24H20Br4N2Sn
  65. Crystal structure of (2,2′-bipyridyl)bis(4-chlorobenzyl)dichloridotin(IV), C24H20Cl4N2Sn
  66. Crystal structure of N-methyl-N-phenyl(methylsulfanyl)carbothioamide, C9H11NS2
  67. Crystal structure of 4-phenylpiperazin-1-ium (4-phenylpiperazin-1-yl)carbothioylsulfanide, [C10H15N2][C11H13N2S2]
  68. Crystal structure of catena-{di-aqua-sodium [n-butyl(methyl)carbamothioyl]sulfanide}n, [C6H16NNaO2S2]n
  69. Crystal structure of (2-([1,1-bis(hydroxymethyl)-2-oxyethyl]iminomethyl)-5-(n-decyl)phenolato)-dimethyl-tin(IV), C23H39NO5Sn
  70. Crystal structure of 4-chloro-N′-[(1E)-(3-ethoxy-2-hydroxyphenyl)methylidene]benzohydrazide – a Z′ = 3 structure, C16H15ClN2O3
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