Abstract
C28H78Si10, monoclinic, Pn (no. 7), a = 21.413(4) Å, b = 9.8568(17) Å, c = 22.074(4) Å, β = 93.426(4)°, V = 4650.6(14) Å3, Z = 4, Rgt(F) = 0.0613, wRref(F2) = 0.1750, T = 296(2) K.
The molecular structure (asymmetric unit) is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.
Data collection and handling.
Crystal: | Colourless prism |
Size: | 0.25 × 0.20 × 0.20 mm |
Wavelength: | Mo Kα radiation (0.71073 Å) |
μ: | 0.30 mm−1 |
Diffractometer, scan mode: | Bruker APEX-II, ω |
θmax, completeness: | 27.5°, 99% |
N(hkl)measured, N(hkl)unique, Rint: | 29235, 15502, 0.056 |
Criterion for Iobs, N(hkl)gt: | Iobs > 2 σ(Iobs), 9548 |
N(param)refined: | 737 |
Programs: | Bruker [1], SHELX [2], [3], [4] |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).
Atom | x | y | z | Uiso*/Ueq |
---|---|---|---|---|
Si1 | 0.99894(11) | 1.0164(3) | 0.01981(10) | 0.0554(6) |
Si2 | 0.90737(9) | 1.0505(2) | 0.07317(8) | 0.0394(4) |
Si3 | 0.89817(9) | 0.9222(2) | 0.16375(8) | 0.0416(5) |
Si4 | 0.97431(9) | 0.9587(2) | 0.24484(9) | 0.0429(5) |
Si5 | 0.95029(9) | 0.8876(2) | 0.34393(8) | 0.0394(4) |
Si6 | 0.89429(13) | 1.0388(3) | 0.40548(13) | 0.0702(7) |
Si7 | 0.81432(11) | 1.0116(3) | 0.01157(11) | 0.0634(7) |
Si8 | 0.90308(11) | 1.2883(2) | 0.09181(10) | 0.0538(6) |
Si9 | 0.91322(10) | 0.6616(2) | 0.34537(10) | 0.0523(5) |
Si10 | 1.05020(11) | 0.8755(3) | 0.39857(11) | 0.0637(7) |
Si11 | 0.71885(10) | 0.4928(2) | 0.63324(11) | 0.0569(6) |
Si12 | 0.79200(8) | 0.6052(2) | 0.70117(9) | 0.0399(4) |
Si13 | 0.90057(8) | 0.58940(19) | 0.68316(8) | 0.0375(4) |
Si14 | 0.94275(8) | 0.3685(2) | 0.68237(9) | 0.0406(4) |
Si15 | 1.05274(8) | 0.3474(2) | 0.70306(9) | 0.0376(4) |
Si16 | 1.12214(9) | 0.4557(2) | 0.63823(10) | 0.0532(6) |
Si17 | 0.77355(11) | 0.8412(2) | 0.70840(11) | 0.0564(6) |
Si18 | 0.76834(12) | 0.5221(3) | 0.79878(12) | 0.0694(7) |
Si19 | 1.08630(10) | 0.4308(3) | 0.80123(10) | 0.0548(6) |
Si20 | 1.06689(10) | 0.1082(2) | 0.71137(10) | 0.0509(5) |
C1 | 1.0073(5) | 0.8506(10) | −0.0239(4) | 0.073(2) |
C2 | 1.0039(5) | 1.1575(11) | −0.0357(4) | 0.082(3) |
H2A | 1.0415 | 1.1483 | −0.0569 | 0.122* |
H2B | 1.0044 | 1.2427 | −0.0146 | 0.122* |
H2C | 0.9683 | 1.1543 | −0.0642 | 0.122* |
C3 | 1.0680(4) | 1.0351(12) | 0.0750(5) | 0.087(3) |
H3A | 1.0624 | 1.1134 | 0.1000 | 0.130* |
H3B | 1.1052 | 1.0457 | 0.0533 | 0.130* |
H3C | 1.0718 | 0.9557 | 0.1001 | 0.130* |
C4 | 0.9030(5) | 0.7336(9) | 0.1464(4) | 0.077(3) |
H4A | 0.8824 | 0.7156 | 0.1074 | 0.115* |
H4B | 0.8830 | 0.6831 | 0.1770 | 0.115* |
H4C | 0.9461 | 0.7069 | 0.1461 | 0.115* |
C5 | 0.8163(4) | 0.9459(11) | 0.1868(4) | 0.070(3) |
H5A | 0.8149 | 0.9306 | 0.2297 | 0.105* |
H5B | 0.7891 | 0.8826 | 0.1652 | 0.105* |
H5C | 0.8028 | 1.0368 | 0.1774 | 0.105* |
C6 | 1.0448(4) | 0.8560(10) | 0.2253(4) | 0.069(2) |
H6A | 1.0765 | 0.8626 | 0.2577 | 0.104* |
H6B | 1.0607 | 0.8904 | 0.1885 | 0.104* |
H6C | 1.0328 | 0.7628 | 0.2196 | 0.104* |
C7 | 1.0000(5) | 1.1409(10) | 0.2482(5) | 0.076(3) |
H7A | 1.0239 | 1.1609 | 0.2139 | 0.114* |
H7B | 1.0254 | 1.1562 | 0.2849 | 0.114* |
H7C | 0.9639 | 1.1988 | 0.2476 | 0.114* |
C8 | 0.8766(7) | 0.9493(13) | 0.4813(5) | 0.105(4) |
H8A | 0.8548 | 0.8657 | 0.4725 | 0.157* |
H8B | 0.8511 | 1.0074 | 0.5044 | 0.157* |
H8C | 0.9152 | 0.9306 | 0.5041 | 0.157* |
C9 | 0.9468(6) | 1.1888(12) | 0.4241(5) | 0.095(4) |
H9A | 0.9233 | 1.2583 | 0.4430 | 0.143* |
H9B | 0.9627 | 1.2235 | 0.3874 | 0.143* |
H9C | 0.9810 | 1.1607 | 0.4513 | 0.143* |
C10 | 0.9986(7) | 0.7291(11) | 0.0171(6) | 0.116(5) |
H10A | 1.0274 | 0.7351 | 0.0520 | 0.174* |
H10B | 1.0063 | 0.6471 | −0.0048 | 0.174* |
H10C | 0.9565 | 0.7282 | 0.0299 | 0.174* |
C11 | 1.0723(5) | 0.8471(13) | −0.0484(5) | 0.099(4) |
H11A | 1.0884 | 0.7563 | −0.0457 | 0.148* |
H11B | 1.0995 | 0.9069 | −0.0249 | 0.148* |
H11C | 1.0698 | 0.8759 | −0.0900 | 0.148* |
C12 | 0.9606(6) | 0.8463(13) | −0.0783(5) | 0.103(4) |
H12A | 0.9193 | 0.8634 | −0.0653 | 0.154* |
H12B | 0.9616 | 0.7584 | −0.0970 | 0.154* |
H12C | 0.9712 | 0.9142 | −0.1071 | 0.154* |
C16 | 0.7979(5) | 0.8257(11) | 0.0021(6) | 0.098(4) |
H16A | 0.8346 | 0.7806 | −0.0106 | 0.147* |
H16B | 0.7641 | 0.8129 | −0.0279 | 0.147* |
H16C | 0.7865 | 0.7884 | 0.0401 | 0.147* |
C17 | 0.8208(6) | 1.0858(13) | −0.0665(5) | 0.099(4) |
H17A | 0.8435 | 1.1698 | −0.0634 | 0.149* |
H17B | 0.7797 | 1.1020 | −0.0848 | 0.149* |
H17C | 0.8426 | 1.0233 | −0.0911 | 0.149* |
C18 | 0.7457(5) | 1.0950(14) | 0.0443(6) | 0.100(4) |
H18A | 0.7082 | 1.0708 | 0.0208 | 0.150* |
H18B | 0.7511 | 1.1917 | 0.0436 | 0.150* |
H18C | 0.7426 | 1.0654 | 0.0855 | 0.150* |
C19 | 0.8711(6) | 1.3829(10) | 0.0233(5) | 0.089(3) |
H19A | 0.8793 | 1.4780 | 0.0286 | 0.133* |
H19B | 0.8267 | 1.3684 | 0.0182 | 0.133* |
H19C | 0.8907 | 1.3507 | −0.0119 | 0.133* |
C20 | 0.9812(4) | 1.3677(9) | 0.1116(5) | 0.072(3) |
H20A | 0.9780 | 1.4643 | 0.1067 | 0.109* |
H20B | 1.0114 | 1.3328 | 0.0852 | 0.109* |
H20C | 0.9941 | 1.3467 | 0.1529 | 0.109* |
C21 | 0.8524(5) | 1.3236(10) | 0.1564(4) | 0.076(3) |
H21A | 0.8131 | 1.2774 | 0.1496 | 0.113* |
H21B | 0.8451 | 1.4195 | 0.1592 | 0.113* |
H21C | 0.8730 | 1.2921 | 0.1936 | 0.113* |
C22 | 0.9177(5) | 0.5964(10) | 0.4258(4) | 0.077(3) |
H22A | 0.9174 | 0.4990 | 0.4255 | 0.115* |
H22B | 0.8824 | 0.6291 | 0.4464 | 0.115* |
H22C | 0.9557 | 0.6279 | 0.4466 | 0.115* |
C23 | 0.9621(6) | 0.5469(11) | 0.2990(5) | 0.089(3) |
H23A | 0.9646 | 0.5841 | 0.2591 | 0.134* |
H23B | 0.9431 | 0.4587 | 0.2962 | 0.134* |
H23C | 1.0034 | 0.5395 | 0.3182 | 0.134* |
C24 | 0.8297(5) | 0.6435(10) | 0.3149(6) | 0.094(4) |
H24A | 0.8029 | 0.6927 | 0.3404 | 0.141* |
H24B | 0.8183 | 0.5493 | 0.3144 | 0.141* |
H24C | 0.8255 | 0.6792 | 0.2745 | 0.141* |
C25 | 1.0441(5) | 0.8778(14) | 0.4827(4) | 0.093(4) |
H25A | 1.0245 | 0.9607 | 0.4944 | 0.140* |
H25B | 1.0851 | 0.8719 | 0.5025 | 0.140* |
H25C | 1.0194 | 0.8020 | 0.4946 | 0.140* |
C26 | 1.0934(4) | 0.7159(13) | 0.3817(5) | 0.090(4) |
H26A | 1.0672 | 0.6389 | 0.3885 | 0.136* |
H26B | 1.1308 | 0.7103 | 0.4077 | 0.136* |
H26C | 1.1042 | 0.7167 | 0.3401 | 0.136* |
C27 | 1.1031(5) | 1.0205(14) | 0.3796(6) | 0.106(5) |
H27A | 1.1391 | 1.0214 | 0.4078 | 0.158* |
H27B | 1.0809 | 1.1046 | 0.3823 | 0.158* |
H27C | 1.1164 | 1.0092 | 0.3392 | 0.158* |
C28 | 0.7116(4) | 0.5566(10) | 0.5513(4) | 0.066(2) |
C29 | 1.1185(4) | 0.4022(10) | 0.5556(4) | 0.071(3) |
C30 | 0.7373(5) | 0.3034(10) | 0.6292(7) | 0.105(4) |
H30A | 0.7039 | 0.2577 | 0.6066 | 0.157* |
H30B | 0.7416 | 0.2667 | 0.6695 | 0.157* |
H30C | 0.7756 | 0.2907 | 0.6095 | 0.157* |
C31 | 0.6398(4) | 0.5079(14) | 0.6647(6) | 0.103(4) |
H31A | 0.6080 | 0.4932 | 0.6328 | 0.154* |
H31B | 0.6351 | 0.5969 | 0.6814 | 0.154* |
H31C | 0.6358 | 0.4412 | 0.6959 | 0.154* |
C32 | 0.9439(4) | 0.6985(8) | 0.7415(4) | 0.059(2) |
H32A | 0.9286 | 0.7899 | 0.7383 | 0.089* |
H32B | 0.9878 | 0.6975 | 0.7347 | 0.089* |
H32C | 0.9376 | 0.6639 | 0.7813 | 0.089* |
C33 | 0.9170(4) | 0.6646(9) | 0.6081(4) | 0.061(2) |
H33A | 0.9614 | 0.6652 | 0.6036 | 0.091* |
H33B | 0.9014 | 0.7559 | 0.6059 | 0.091* |
H33C | 0.8968 | 0.6114 | 0.5762 | 0.091* |
C34 | 0.9042(4) | 0.2581(9) | 0.7394(5) | 0.070(2) |
H34A | 0.9137 | 0.1646 | 0.7320 | 0.104* |
H34B | 0.8597 | 0.2712 | 0.7355 | 0.104* |
H34C | 0.9196 | 0.2825 | 0.7797 | 0.104* |
C35 | 0.9191(4) | 0.2930(10) | 0.6051(4) | 0.073(3) |
H35A | 0.8778 | 0.2555 | 0.6058 | 0.110* |
H35B | 0.9481 | 0.2227 | 0.5959 | 0.110* |
H35C | 0.9196 | 0.3627 | 0.5748 | 0.110* |
C36 | 1.1094(5) | 0.6460(9) | 0.6376(5) | 0.076(3) |
H36A | 1.0703 | 0.6665 | 0.6161 | 0.113* |
H36B | 1.1428 | 0.6894 | 0.6179 | 0.113* |
H36C | 1.1086 | 0.6784 | 0.6786 | 0.113* |
C37 | 1.2043(4) | 0.4182(12) | 0.6710(5) | 0.078(3) |
H37A | 1.2338 | 0.4723 | 0.6506 | 0.116* |
H37B | 1.2135 | 0.3238 | 0.6655 | 0.116* |
H37C | 1.2071 | 0.4395 | 0.7135 | 0.116* |
C39 | 0.6608(7) | 0.4737(18) | 0.5166(6) | 0.139(6) |
H39A | 0.6548 | 0.5079 | 0.4759 | 0.208* |
H39B | 0.6224 | 0.4809 | 0.5366 | 0.208* |
H39C | 0.6734 | 0.3803 | 0.5154 | 0.208* |
C40 | 0.6913(10) | 0.7009(15) | 0.5486(6) | 0.160(8) |
H40A | 0.6690 | 0.7181 | 0.5104 | 0.240* |
H40B | 0.7273 | 0.7588 | 0.5528 | 0.240* |
H40C | 0.6644 | 0.7188 | 0.5810 | 0.240* |
C41 | 0.7714(6) | 0.5375(18) | 0.5200(6) | 0.124(5) |
H41A | 0.8045 | 0.5867 | 0.5415 | 0.186* |
H41B | 0.7661 | 0.5710 | 0.4792 | 0.186* |
H41C | 0.7818 | 0.4428 | 0.5193 | 0.186* |
C42 | 1.1259(7) | 0.2459(10) | 0.5520(5) | 0.100(4) |
H42A | 1.1214 | 0.2175 | 0.5104 | 0.149* |
H42B | 1.0943 | 0.2032 | 0.5745 | 0.149* |
H42C | 1.1666 | 0.2204 | 0.5689 | 0.149* |
C43 | 1.0566(5) | 0.4452(17) | 0.5236(5) | 0.117(5) |
H43A | 1.0540 | 0.4101 | 0.4829 | 0.175* |
H43B | 1.0542 | 0.5424 | 0.5224 | 0.175* |
H43C | 1.0226 | 0.4101 | 0.5453 | 0.175* |
C44 | 1.1727(6) | 0.4715(16) | 0.5232(5) | 0.109(4) |
H44A | 1.1720 | 0.5675 | 0.5306 | 0.164* |
H44B | 1.1676 | 0.4550 | 0.4803 | 0.164* |
H44C | 1.2121 | 0.4349 | 0.5387 | 0.164* |
C45 | 0.6879(5) | 0.8852(12) | 0.7054(5) | 0.089(3) |
H45A | 0.6703 | 0.8735 | 0.6647 | 0.134* |
H45B | 0.6830 | 0.9779 | 0.7176 | 0.134* |
H45C | 0.6668 | 0.8268 | 0.7323 | 0.134* |
C46 | 0.8068(6) | 0.9078(11) | 0.7826(5) | 0.091(3) |
H46A | 0.7898 | 0.9962 | 0.7896 | 0.137* |
H46B | 0.8515 | 0.9138 | 0.7818 | 0.137* |
H46C | 0.7961 | 0.8476 | 0.8146 | 0.137* |
C47 | 0.8095(6) | 0.9387(11) | 0.6480(5) | 0.093(3) |
H47A | 0.8542 | 0.9349 | 0.6541 | 0.139* |
H47B | 0.7960 | 1.0314 | 0.6493 | 0.139* |
H47C | 0.7970 | 0.9003 | 0.6092 | 0.139* |
C48 | 0.7468(5) | 0.3410(13) | 0.8004(6) | 0.101(4) |
H48A | 0.7349 | 0.3174 | 0.8403 | 0.152* |
H48B | 0.7819 | 0.2868 | 0.7903 | 0.152* |
H48C | 0.7123 | 0.3246 | 0.7715 | 0.152* |
C49 | 0.7003(6) | 0.6205(13) | 0.8271(5) | 0.105(4) |
H49A | 0.6918 | 0.5898 | 0.8670 | 0.158* |
H49B | 0.6639 | 0.6062 | 0.8001 | 0.158* |
H49C | 0.7104 | 0.7153 | 0.8284 | 0.158* |
C50 | 0.8355(6) | 0.5466(15) | 0.8569(5) | 0.106(4) |
H50A | 0.8673 | 0.4805 | 0.8506 | 0.158* |
H50B | 0.8208 | 0.5357 | 0.8969 | 0.158* |
H50C | 0.8525 | 0.6360 | 0.8529 | 0.158* |
C51 | 1.0191(5) | 0.0100(9) | 0.6510(4) | 0.069(2) |
H51A | 1.0241 | −0.0856 | 0.6582 | 0.104* |
H51B | 1.0332 | 0.0319 | 0.6117 | 0.104* |
H51C | 0.9757 | 0.0338 | 0.6525 | 0.104* |
C52 | 1.0408(5) | 0.0439(10) | 0.7870(4) | 0.079(3) |
H52A | 1.0485 | 0.1123 | 0.8175 | 0.119* |
H52B | 1.0637 | −0.0368 | 0.7983 | 0.119* |
H52C | 0.9968 | 0.0236 | 0.7833 | 0.119* |
C53 | 1.1509(4) | 0.0567(12) | 0.7075(5) | 0.088(3) |
H53A | 1.1625 | 0.0614 | 0.6662 | 0.131* |
H53B | 1.1562 | −0.0345 | 0.7221 | 0.131* |
H53C | 1.1770 | 0.1168 | 0.7321 | 0.131* |
C54 | 1.1519(5) | 0.3233(13) | 0.8347(5) | 0.096(4) |
H54A | 1.1679 | 0.3624 | 0.8723 | 0.143* |
H54B | 1.1847 | 0.3189 | 0.8069 | 0.143* |
H54C | 1.1367 | 0.2335 | 0.8419 | 0.143* |
C55 | 1.0209(5) | 0.4287(11) | 0.8544(4) | 0.077(3) |
H55A | 0.9877 | 0.4865 | 0.8388 | 0.116* |
H55B | 1.0362 | 0.4607 | 0.8936 | 0.116* |
H55C | 1.0055 | 0.3377 | 0.8580 | 0.116* |
C56 | 1.1166(5) | 0.6065(12) | 0.8021(5) | 0.087(3) |
H56A | 1.1534 | 0.6107 | 0.7794 | 0.130* |
H56B | 1.1269 | 0.6338 | 0.8432 | 0.130* |
H56C | 1.0853 | 0.6662 | 0.7842 | 0.130* |
C57 | 0.8177(6) | 1.1094(13) | 0.3750(5) | 0.093(3) |
C58 | 0.8328(6) | 1.1927(13) | 0.3156(5) | 0.098(4) |
H58A | 0.7955 | 1.2375 | 0.2997 | 0.147* |
H58B | 0.8474 | 1.1317 | 0.2857 | 0.147* |
H58C | 0.8645 | 1.2591 | 0.3258 | 0.147* |
C60 | 0.7707(5) | 0.9910(15) | 0.3597(7) | 0.112(4) |
H60A | 0.7318 | 1.0277 | 0.3431 | 0.168* |
H60B | 0.7636 | 0.9411 | 0.3960 | 0.168* |
H60C | 0.7879 | 0.9315 | 0.3305 | 0.168* |
C59 | 0.7895(7) | 1.1985(17) | 0.4256(7) | 0.146(6) |
H59A | 0.7894 | 1.1475 | 0.4627 | 0.218* |
H59B | 0.7474 | 1.2238 | 0.4130 | 0.218* |
H59C | 0.8144 | 1.2788 | 0.4321 | 0.218* |
Source of material
In a representative experiment, the mixture of 2,2,5,5-tetrakis(trimethylsilyl)-1,1,1,3,3,4,4,6,6,6-decamethylhexasilane [5] (18.30 g, 30 mmol) and t-BuOK (7.00 g, 63 mmol) was stirred in 100 mL THF at 60 °C for 10 hours. After removing the solvent, 40 mL toluene was added and then 20 mL toluene solution of tert-butyldimethyl chlorosilane was added dropwise at −20 °C. The mixture was slowly warmed to room temperature and stirred for 2 hours. After aqueous workup and recrystallization from ethanol, the title compound were obtained in the yield of 92%. Crystals were obtained by slow evaporating the hexane solution at 5 °C in 2 days. 1H NMR (CDCl3, 400 MHz): δ [ppm] 0.95 (s, 18H, t-Bu), 0.45 (s, 12H, SiMe2), 0.27 (s, 36H, SiMe3), 0.19 (s, 12H, SiMe2(t-Bu)); 13C NMR (CDCl3, 100 MHz): δ [ppm] 28.44 (t-Bu), 19.02 (t-Bu), 4.42 (SiMe2), 2.47 (SiMe2(t-Bu)), −0.07 (SiMe3); 29Si NMR (CDCl3, 80 MHz): δ [ppm] 5.15 (SiMe2(t-Bu)), −9.04(SiMe3), −27.44(SiMe2), −127.43(Si(SiMe3)4).
Experimental details
A suitable crystal was selected and was mounted onto the tip of glass fibres. An empirical (multi-scan) absorption correction was applied with the program SADABS [3]. The structures were solved with the ShelXS structure solution program using Direct Methods and subsequently refined on F2 (ShelXL) [4]. The figure of the solid-state molecular structure was generated using XP as implemented in Shelxtl program [1].
Comment
The chemistry of carbenes and their heavier analogues (tetrylenes) has attracted more and more attention because of the occurrence of orthogonal donor and acceptor orbitals within a small energetic separation, which made them good candidates to mimic transition-metal behavior, for example, in oxidative addition or reductive elimination reactions [6], [7], [8]. Many examples of these tetrylenes are stabilized by the presence of nitrogen directly adjacent to the divalent centres, if electronegative groups are replaced by alkyl groups, the energy difference between singlet and triplet states (ΔEst) will be reduced. The even more electropositive silyl or oligosilyl substituents are of particular interest as for these tetrylenes even smaller ΔEst values are expected [9]. During the synthesis of silyl-substituted tetrylenes, [10], [11] we prepared the 2,2,5,5-tetrakis(tert-butyldimethylsilyl)-1,1,1,3,3,4,4,6,6,6-decamethylhexasilane as the pre-ligands. However, the yield is quite low [12]. Another route for its syntheses was adopted, during which the title compound was prepared.
In the asymmetric unit of the title compound, two crystallographically independent molecules are shown. The silicon atoms in the main chain are of zig-zag type. The two tert-butyldimethylsilyl groups are arranged in an anti-fashion. The dihedral angle of Si2-Si3-Si4-Si5 is 161.5°. The 28 Si-Si-Si bond angles average 110.4°. The average Si-Si distance of these 18 Si-Si bonds is 2.379 Å, which is larger than that of 2.340 Å found in hexamethyldisilane. The average bond length of these 44 Si-C bonds is 1.882 Å. But all geometric parameters are in the expected ranges [12].
Funding source: China Postdoctoral Science Foundation
Award Identifier / Grant number: 2018M630663
Funding statement: We gratefully acknowledge financial support by the China Postdoctoral Science Foundation (Grant No. 2018M630663).
References
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©2019 Xu-Qiong Xiao et al., published by De Gruyter, Berlin/Boston
This work is licensed under the Creative Commons Attribution 4.0 Public License.
Artikel in diesem Heft
- Frontmatter
- Crystal structure of [aqua[2,2′-(1,2-phenylene)bis(1H-imidazole-4-carboxylato-5-carboxy)-κ4N3,N3′,O4,O4′] zinc(II)] monohydrate, C16H10N4O9Zn⋅H2O
- Crystal structure of ethyl 3-(4-methoxyphenyl)-5-methylcarbamoyl-1H-pyrazole-4-carboxylate, C15H17N3O4
- 7-(4-Fluorobenzylidene)-3-(4-fluorophenyl)-N-phenyl-3,3a,4,5,6,7-hexahydro-2H-indazole-2-carbothioamide–dimethylformamide (2/1), C27H23F2N3S, 0.5(C3H7NO)
- Crystal structure of 4,4′-(hydrazonomethylene)diphenol dihydrate, C13H16N2O4
- Crystal structure of 4-methoxyphenyl-3-phenylpropiolate, C16H12O3
- Crystal Structure of tris(tetrakis{1-vinyl-1H-imidazole-κN}copper(II)) bis[tri-μ2-bromido-tetrabromido-bis(1-vinyl-1H-imidazole-κN)tetracopper(I)], C80H96N32Cu11Br14
- Crystal structure of (E)-2-(3,6-bis(diethylamino)-9H-xanthen-9-yl)-N′-(quinoxalin-2-ylmethylene)benzohydrazide, C37H36N6O2
- Crystal structure of 4-(1-phenylimidazo[1,5-a]pyridin-3-yl)benzoic acid (C20H14N2O2)
- Crystal structure of 3-fluoro-3-methyl-1-((2-nitrophenyl)sulfonyl)-5,5-diphenylpiperidine, C24H23FN2O4S
- Crystal structure of dimethyl 3,12-dibenzyl-6,10-diphenyl-3,12-diazapentacyclo [6.3.1.02.7.04.11.05.9]-dodecane-7,11-dicarboxylate — acetone (2/1), C40H38N2O2 ⋅ 0.5C3H6O
- Crystal structure of poly[(μ2-2-(1H-1,2,4-triazol-1-yl)benzoato-κ4O:O′:N:N′)silver(I)] monohydrate, C9H8AgO3N3
- Crystal structure of poly[(μ2-9H-carbazole-3,6-dicarboxylate-κ4O1,O2:O3,O4)(μ2-1,3-di(pyridin-4-yl)propane-κ2N:N′)cadmium(II)]monohydrate, C27H23N3O5Cd
- The synthesis and crystal structure of bis(2-(benzo[d]thiazol-2-yl)-5-methylbenzen-1-ido-κ2C,N)-(N,N′-diethyldithiocarbamato-κ2S,S′)iridium(III), C33H30N3S4Ir
- The crystal structure of 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfonyl)-1H-pyrazole-3-carboxamide, C12H6N4Cl2F6O3S
- Synthesis and crystal structure of poly[(μ2-nitrato-κ4O,O′:O′,O′′)-nitrato-κO-(μ2-1,4-bis((1H-imidazol-1-yl)methyl)benzene-κ2N:N′)cadmium(II)], C14H14N6O6Cd
- Crystal structure of ethyl (Z)-(4-oxo-4-phenylbut-2-en-2-yl)glycinate, C14H17NO3
- Halogen bonds in the crystal structure of 5-bromo-3,4′-bipyridine – 1,4-diiodotetrafluorobenzene (2/1), C26H14Br2F4I2N4
- Crystal structure of bis(2,2′-bipyridine-κ2N,N′)-tetrakis(μ2-3-(phenylsulfonamido)propanoato-κ2O:O′)-bis(3-(phenylsulfonamido)propanoato-κ2O,O′)digadolinium(III) – 2,2′-bipyridine (1/1), C84H84Gd2N12O24S6
- Crystal structure of poly[aqua(μ2-2-amino-1,4-benzenedisulfonato-κ2O:O′)bis(μ2-pyrazin-κ2N:N′)silver(I)], C14H16Ag2N5O8S2
- The crystal structure of 1,6-di-tert-butyl-1,1,3,3,4,4,6,6-octamethyl-2,2,5,5-tetrakis (trimethylsilyl)hexasilane, C28H78Si10
- Crystal structure of discandium triruthenium tetrasilicide, Sc2Ru3Si4
- Crystal structure of poly[(μ2-4-amino-1,5-naphthalenedisulfonato-κ4O,N:O′, N′)bis(μ2-hexamethylenetetramino-κ2N;N′)silver(I)], {C22H30Ag2N9O6S2}n
- Crystal structure of diaqua[5,5′-dicarboxy-2,2′-(propane-1,3-diyl)bis(1H-imidazole-4-carboxylato-κ4O,O′,N,N′)]zinc(II) dihydrate, C13H18N4O12Zn
- The crystal structure of poly [(μ3-N1,N4-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide-κ3-O:N:N′)-(p-toluenesulfonato-κ2O,O′)silver(I)], C25H27Ag1N4O5S
- The crystal structure of 1,2-bis(3-bromophenoxy) ethane, C14H12Br2O2
- The crystal structure of 4-(pyren-1-yl)butyl-3-nitrobenzoate, C27H21NO4
- Crystal structure of bis[(2-(4-chlorophenyl)-5-methyl-1,3-dioxane-5-carboxylato-κ1O) (5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)]nickel(II), C40H60Cl2N4NiO8
- The crystal structure of 1,5-dinitro-2,3,4-trichlorobenzene, C6H1Cl3N2O4
- The crystal structure of the solid solution of 3,5-dinitropyrazole and 4-chlorine-3,5-dinitropyrazole, C3H1.24Cl0.76N4O4
- The cocrystal structure of 4-nitropyrazole — acetic acid (1/1), C5H7N3O4
- The crystal structure of propan-2-one O-(2,4,6-trinitrophenyl) oxime, C9H8N4O7
- The crystal structure of ethyl 2-(3-(2-ethoxy-2-oxoethyl)benzo[d] thiazol-2(3H)-ylidene)acetate, C15H17NO4S
- Crystal structure of (acetic acid-κ1O)-bis(μ2-2-chlorobenzoato-κ2O:O′)-(2-chlorobenzoato-κ1O)-(μ2-hydroxy-κ2O:O)-bis(1,10-phenanthroline-κ2N,N′)dimanganese(II) — methanol (1/1), C48H37Cl3Mn2N4O10
- Crystal structure of 3-methyl-2-phenyl-1,8-naphthyridine, C15H12N2
- Crystal structure of chlorido-(5-acetyl-2-(5-methylpyridin-2-yl)benzen-1-ido-κ2C,N)-pyridine-κN-palladium(II), C19H17ClN2OPd
- Crystal structure of (4-methyl-benzoato-κ2O,O′)-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, C24H45ClN4NiO7
- Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6) 1,2,3,4,5-pentamethyl-cyclopenta-2,4-dien-1-yl(potassium, rubidium) — ammonia (1/2), [K0.3Rb0.7(18-crown-6)]Cp*⋅2 NH3, C22H45K0.3N2O6Rb0.7
- Crystal structure of (3E,5E)-1-((4-fluorophenyl)sulfonyl)-3,5-bis(3-nitrobenzylidene)piperidin-4-one — dichloromethane (2/1), C51H38Cl2F2N6O14S2
- Crystal structure of (E)-N′-((1,6-dihydropyren-1-yl)methylene)isonicotinohydrazide — methanol (1/1), C24H19N3O2
- Crystal structure of poly[aqua(μ2-2-amino-1,4-benzenedisulfonato-κ3N,O:O′)-(μ4-hexamethylenetetramino-κ4N:N′:N′′:N′′′)disilver(I)] monohydrate, C12H21Ag2N5O8S2
- Crystal structure of bis(acridin-10-ium) 2,5-dihydroxyterephthalate — 2,5-dihydroxyterephthalic acid (1/1), C21H15NO6
- The crystal structure of 1,12-diazaperylene, C18H10N2
- Crystal structure of 1-(5-(4-chlorophenyl)-3-(2-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)ethan-1-one, C17H14N2OFCl
- Crystal structure of (4aR,6aR,6bR,10S,12aR)-10-acetoxy-1,2,3,4, 4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a, 12b,13,14b-icosahydro-2,2,4a,6b,9,9,12a-heptamethylpicene-6a-carboxylic acid, C32H50O4
- The crystal structure of tetrachlorido-bis{1,3-bis(2,6-diisopropylphenyl)-1H-3λ4-imidazol-2-yl}-(μ2-pyrimidine-κ2N:N′)dipalladium(IV) — dichloromethane (1/2), C60H80Cl8N6Pd2
- The crystal structure of (E)-4-(7-methoxy-2-oxo-2H-chromen-8-yl)-2-methylbut-2-en-1-yl 4-nitrobenzoate, C22H19NO7
- Crystal structure of 3-methyl-N-(pyrimidin-5-ylmethyl)pyridin-2-amine, C11H12N4
- The crystal structure of 2,5-dichloroterephthalic acid dihydrate, C8H8Cl2O6
- The crystal structure of 2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine — dimethylformamide (1/1), C33H28N10O
- Crystal structure of N-(adamantan-1-yl)-5-(dimethylamino)naphthalene-1-sulfonamide, C22H28N2O2S
- Crystal structure of poly[diaqua-(μ4-4-(3,5-dicarboxy-κ1O-phenoxy)phthalato-κ3O:O′:O′)cadmium(II)], C16H12CdO11
- Crystal structure of poly[diaqua-bis(μ2-3-((1H-imidazol-1-yl)methyl)benzoato-κ2N:O)manganese(II)], C22H22MnN4O6
- Crystal structure of 9-(3-phenoxyphenyl)-3,4,6,7,9,10-hexahydroacridine-1,8(2H,5H)-dione, C25H23NO3
- The crystal structure of poly[(μ3-2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine-k3N:N′:N′′)-(nitrato-k2O,O)-(nitrato-k1O)zinc(II)] - N,N-dimethylacetamide (1/2), C38H39N13O8Zn
- Crystal structure of poly[(μ7-4-(3,5-dicarboxylatophenoxy)phthalato)-(1,10-phenanthroline-κ2N,N′)dizinc(II)], C28H14N2O9Zn2
- The crystal structure of methyl 2-(benzylamino)-5-(benzyloxy)benzoate, C22H21NO3
- Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanoplatinate(II), C14H24N8PdPt
- Crystal structure of (pyridine-2-carboxylato-κ2N,O)-[2-(2-pyridyl)phenyl-κ2N,C1]palladium(II), C17H12N2O2Pd
- Crystal structure of (cyclohexane-1,4-diammonium) 4-[(4-carboxylatophenyl)disulfanyl]benzoate dimethylsulphoxide hydrate (1/1/1/1), [C6H16N2]2+[C14H8O4S2]2−⋅C2H6OS⋅H2O
- Crystal structure of the 2:1 co-crystal 2-[(2-carboxyphenyl)disulfanyl]benzoic acid – 3-bromobenzoic acid, 2(C14H10O4S2)⋅C7H5BrO2
- Crystal structure of chlorido-dimethyl-(phenylpiperazine-1-carbodithioato-κ2S,S′)tin(IV), C13H19ClN2S2Sn
- Crystal structure of (N-n-butyl, N-methyl-dithiocarbamato-κ2 S,S′)-chlorido-dimethyl-tin(IV), C8H18ClNS2Sn
- Crystal structure of (2,2′-bipyridyl)bis(4-bromobenzyl)dibromidotin(IV), C24H20Br4N2Sn
- Crystal structure of (2,2′-bipyridyl)bis(4-chlorobenzyl)dichloridotin(IV), C24H20Cl4N2Sn
- Crystal structure of N-methyl-N-phenyl(methylsulfanyl)carbothioamide, C9H11NS2
- Crystal structure of 4-phenylpiperazin-1-ium (4-phenylpiperazin-1-yl)carbothioylsulfanide, [C10H15N2][C11H13N2S2]
- Crystal structure of catena-{di-aqua-sodium [n-butyl(methyl)carbamothioyl]sulfanide}n, [C6H16NNaO2S2]n
- Crystal structure of (2-([1,1-bis(hydroxymethyl)-2-oxyethyl]iminomethyl)-5-(n-decyl)phenolato)-dimethyl-tin(IV), C23H39NO5Sn
- Crystal structure of 4-chloro-N′-[(1E)-(3-ethoxy-2-hydroxyphenyl)methylidene]benzohydrazide – a Z′ = 3 structure, C16H15ClN2O3
Artikel in diesem Heft
- Frontmatter
- Crystal structure of [aqua[2,2′-(1,2-phenylene)bis(1H-imidazole-4-carboxylato-5-carboxy)-κ4N3,N3′,O4,O4′] zinc(II)] monohydrate, C16H10N4O9Zn⋅H2O
- Crystal structure of ethyl 3-(4-methoxyphenyl)-5-methylcarbamoyl-1H-pyrazole-4-carboxylate, C15H17N3O4
- 7-(4-Fluorobenzylidene)-3-(4-fluorophenyl)-N-phenyl-3,3a,4,5,6,7-hexahydro-2H-indazole-2-carbothioamide–dimethylformamide (2/1), C27H23F2N3S, 0.5(C3H7NO)
- Crystal structure of 4,4′-(hydrazonomethylene)diphenol dihydrate, C13H16N2O4
- Crystal structure of 4-methoxyphenyl-3-phenylpropiolate, C16H12O3
- Crystal Structure of tris(tetrakis{1-vinyl-1H-imidazole-κN}copper(II)) bis[tri-μ2-bromido-tetrabromido-bis(1-vinyl-1H-imidazole-κN)tetracopper(I)], C80H96N32Cu11Br14
- Crystal structure of (E)-2-(3,6-bis(diethylamino)-9H-xanthen-9-yl)-N′-(quinoxalin-2-ylmethylene)benzohydrazide, C37H36N6O2
- Crystal structure of 4-(1-phenylimidazo[1,5-a]pyridin-3-yl)benzoic acid (C20H14N2O2)
- Crystal structure of 3-fluoro-3-methyl-1-((2-nitrophenyl)sulfonyl)-5,5-diphenylpiperidine, C24H23FN2O4S
- Crystal structure of dimethyl 3,12-dibenzyl-6,10-diphenyl-3,12-diazapentacyclo [6.3.1.02.7.04.11.05.9]-dodecane-7,11-dicarboxylate — acetone (2/1), C40H38N2O2 ⋅ 0.5C3H6O
- Crystal structure of poly[(μ2-2-(1H-1,2,4-triazol-1-yl)benzoato-κ4O:O′:N:N′)silver(I)] monohydrate, C9H8AgO3N3
- Crystal structure of poly[(μ2-9H-carbazole-3,6-dicarboxylate-κ4O1,O2:O3,O4)(μ2-1,3-di(pyridin-4-yl)propane-κ2N:N′)cadmium(II)]monohydrate, C27H23N3O5Cd
- The synthesis and crystal structure of bis(2-(benzo[d]thiazol-2-yl)-5-methylbenzen-1-ido-κ2C,N)-(N,N′-diethyldithiocarbamato-κ2S,S′)iridium(III), C33H30N3S4Ir
- The crystal structure of 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfonyl)-1H-pyrazole-3-carboxamide, C12H6N4Cl2F6O3S
- Synthesis and crystal structure of poly[(μ2-nitrato-κ4O,O′:O′,O′′)-nitrato-κO-(μ2-1,4-bis((1H-imidazol-1-yl)methyl)benzene-κ2N:N′)cadmium(II)], C14H14N6O6Cd
- Crystal structure of ethyl (Z)-(4-oxo-4-phenylbut-2-en-2-yl)glycinate, C14H17NO3
- Halogen bonds in the crystal structure of 5-bromo-3,4′-bipyridine – 1,4-diiodotetrafluorobenzene (2/1), C26H14Br2F4I2N4
- Crystal structure of bis(2,2′-bipyridine-κ2N,N′)-tetrakis(μ2-3-(phenylsulfonamido)propanoato-κ2O:O′)-bis(3-(phenylsulfonamido)propanoato-κ2O,O′)digadolinium(III) – 2,2′-bipyridine (1/1), C84H84Gd2N12O24S6
- Crystal structure of poly[aqua(μ2-2-amino-1,4-benzenedisulfonato-κ2O:O′)bis(μ2-pyrazin-κ2N:N′)silver(I)], C14H16Ag2N5O8S2
- The crystal structure of 1,6-di-tert-butyl-1,1,3,3,4,4,6,6-octamethyl-2,2,5,5-tetrakis (trimethylsilyl)hexasilane, C28H78Si10
- Crystal structure of discandium triruthenium tetrasilicide, Sc2Ru3Si4
- Crystal structure of poly[(μ2-4-amino-1,5-naphthalenedisulfonato-κ4O,N:O′, N′)bis(μ2-hexamethylenetetramino-κ2N;N′)silver(I)], {C22H30Ag2N9O6S2}n
- Crystal structure of diaqua[5,5′-dicarboxy-2,2′-(propane-1,3-diyl)bis(1H-imidazole-4-carboxylato-κ4O,O′,N,N′)]zinc(II) dihydrate, C13H18N4O12Zn
- The crystal structure of poly [(μ3-N1,N4-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide-κ3-O:N:N′)-(p-toluenesulfonato-κ2O,O′)silver(I)], C25H27Ag1N4O5S
- The crystal structure of 1,2-bis(3-bromophenoxy) ethane, C14H12Br2O2
- The crystal structure of 4-(pyren-1-yl)butyl-3-nitrobenzoate, C27H21NO4
- Crystal structure of bis[(2-(4-chlorophenyl)-5-methyl-1,3-dioxane-5-carboxylato-κ1O) (5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)]nickel(II), C40H60Cl2N4NiO8
- The crystal structure of 1,5-dinitro-2,3,4-trichlorobenzene, C6H1Cl3N2O4
- The crystal structure of the solid solution of 3,5-dinitropyrazole and 4-chlorine-3,5-dinitropyrazole, C3H1.24Cl0.76N4O4
- The cocrystal structure of 4-nitropyrazole — acetic acid (1/1), C5H7N3O4
- The crystal structure of propan-2-one O-(2,4,6-trinitrophenyl) oxime, C9H8N4O7
- The crystal structure of ethyl 2-(3-(2-ethoxy-2-oxoethyl)benzo[d] thiazol-2(3H)-ylidene)acetate, C15H17NO4S
- Crystal structure of (acetic acid-κ1O)-bis(μ2-2-chlorobenzoato-κ2O:O′)-(2-chlorobenzoato-κ1O)-(μ2-hydroxy-κ2O:O)-bis(1,10-phenanthroline-κ2N,N′)dimanganese(II) — methanol (1/1), C48H37Cl3Mn2N4O10
- Crystal structure of 3-methyl-2-phenyl-1,8-naphthyridine, C15H12N2
- Crystal structure of chlorido-(5-acetyl-2-(5-methylpyridin-2-yl)benzen-1-ido-κ2C,N)-pyridine-κN-palladium(II), C19H17ClN2OPd
- Crystal structure of (4-methyl-benzoato-κ2O,O′)-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, C24H45ClN4NiO7
- Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6) 1,2,3,4,5-pentamethyl-cyclopenta-2,4-dien-1-yl(potassium, rubidium) — ammonia (1/2), [K0.3Rb0.7(18-crown-6)]Cp*⋅2 NH3, C22H45K0.3N2O6Rb0.7
- Crystal structure of (3E,5E)-1-((4-fluorophenyl)sulfonyl)-3,5-bis(3-nitrobenzylidene)piperidin-4-one — dichloromethane (2/1), C51H38Cl2F2N6O14S2
- Crystal structure of (E)-N′-((1,6-dihydropyren-1-yl)methylene)isonicotinohydrazide — methanol (1/1), C24H19N3O2
- Crystal structure of poly[aqua(μ2-2-amino-1,4-benzenedisulfonato-κ3N,O:O′)-(μ4-hexamethylenetetramino-κ4N:N′:N′′:N′′′)disilver(I)] monohydrate, C12H21Ag2N5O8S2
- Crystal structure of bis(acridin-10-ium) 2,5-dihydroxyterephthalate — 2,5-dihydroxyterephthalic acid (1/1), C21H15NO6
- The crystal structure of 1,12-diazaperylene, C18H10N2
- Crystal structure of 1-(5-(4-chlorophenyl)-3-(2-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)ethan-1-one, C17H14N2OFCl
- Crystal structure of (4aR,6aR,6bR,10S,12aR)-10-acetoxy-1,2,3,4, 4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a, 12b,13,14b-icosahydro-2,2,4a,6b,9,9,12a-heptamethylpicene-6a-carboxylic acid, C32H50O4
- The crystal structure of tetrachlorido-bis{1,3-bis(2,6-diisopropylphenyl)-1H-3λ4-imidazol-2-yl}-(μ2-pyrimidine-κ2N:N′)dipalladium(IV) — dichloromethane (1/2), C60H80Cl8N6Pd2
- The crystal structure of (E)-4-(7-methoxy-2-oxo-2H-chromen-8-yl)-2-methylbut-2-en-1-yl 4-nitrobenzoate, C22H19NO7
- Crystal structure of 3-methyl-N-(pyrimidin-5-ylmethyl)pyridin-2-amine, C11H12N4
- The crystal structure of 2,5-dichloroterephthalic acid dihydrate, C8H8Cl2O6
- The crystal structure of 2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine — dimethylformamide (1/1), C33H28N10O
- Crystal structure of N-(adamantan-1-yl)-5-(dimethylamino)naphthalene-1-sulfonamide, C22H28N2O2S
- Crystal structure of poly[diaqua-(μ4-4-(3,5-dicarboxy-κ1O-phenoxy)phthalato-κ3O:O′:O′)cadmium(II)], C16H12CdO11
- Crystal structure of poly[diaqua-bis(μ2-3-((1H-imidazol-1-yl)methyl)benzoato-κ2N:O)manganese(II)], C22H22MnN4O6
- Crystal structure of 9-(3-phenoxyphenyl)-3,4,6,7,9,10-hexahydroacridine-1,8(2H,5H)-dione, C25H23NO3
- The crystal structure of poly[(μ3-2,4,6-tris[4-(1H-imidazol-1-yl)phenyl]-1,3,5-triazine-k3N:N′:N′′)-(nitrato-k2O,O)-(nitrato-k1O)zinc(II)] - N,N-dimethylacetamide (1/2), C38H39N13O8Zn
- Crystal structure of poly[(μ7-4-(3,5-dicarboxylatophenoxy)phthalato)-(1,10-phenanthroline-κ2N,N′)dizinc(II)], C28H14N2O9Zn2
- The crystal structure of methyl 2-(benzylamino)-5-(benzyloxy)benzoate, C22H21NO3
- Crystal structure of (1,4,8,11-tetraazacyclotetradecane)palladium(II) tetracyanoplatinate(II), C14H24N8PdPt
- Crystal structure of (pyridine-2-carboxylato-κ2N,O)-[2-(2-pyridyl)phenyl-κ2N,C1]palladium(II), C17H12N2O2Pd
- Crystal structure of (cyclohexane-1,4-diammonium) 4-[(4-carboxylatophenyl)disulfanyl]benzoate dimethylsulphoxide hydrate (1/1/1/1), [C6H16N2]2+[C14H8O4S2]2−⋅C2H6OS⋅H2O
- Crystal structure of the 2:1 co-crystal 2-[(2-carboxyphenyl)disulfanyl]benzoic acid – 3-bromobenzoic acid, 2(C14H10O4S2)⋅C7H5BrO2
- Crystal structure of chlorido-dimethyl-(phenylpiperazine-1-carbodithioato-κ2S,S′)tin(IV), C13H19ClN2S2Sn
- Crystal structure of (N-n-butyl, N-methyl-dithiocarbamato-κ2 S,S′)-chlorido-dimethyl-tin(IV), C8H18ClNS2Sn
- Crystal structure of (2,2′-bipyridyl)bis(4-bromobenzyl)dibromidotin(IV), C24H20Br4N2Sn
- Crystal structure of (2,2′-bipyridyl)bis(4-chlorobenzyl)dichloridotin(IV), C24H20Cl4N2Sn
- Crystal structure of N-methyl-N-phenyl(methylsulfanyl)carbothioamide, C9H11NS2
- Crystal structure of 4-phenylpiperazin-1-ium (4-phenylpiperazin-1-yl)carbothioylsulfanide, [C10H15N2][C11H13N2S2]
- Crystal structure of catena-{di-aqua-sodium [n-butyl(methyl)carbamothioyl]sulfanide}n, [C6H16NNaO2S2]n
- Crystal structure of (2-([1,1-bis(hydroxymethyl)-2-oxyethyl]iminomethyl)-5-(n-decyl)phenolato)-dimethyl-tin(IV), C23H39NO5Sn
- Crystal structure of 4-chloro-N′-[(1E)-(3-ethoxy-2-hydroxyphenyl)methylidene]benzohydrazide – a Z′ = 3 structure, C16H15ClN2O3