Home Physical Sciences Crystal structure of bis(μ2-ferrocenecarboxylato-κ2O:O′)-bis(1,10-phenanthroline-κ2N,N′)-(μ2-methanolato-κ2O,O)dicopper(II) tetrafluoroborate – acetonitrile (1/1), C49H40BCu2F4Fe2N5O5
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Crystal structure of bis(μ2-ferrocenecarboxylato-κ2O:O′)-bis(1,10-phenanthroline-κ2N,N′)-(μ2-methanolato-κ2O,O)dicopper(II) tetrafluoroborate – acetonitrile (1/1), C49H40BCu2F4Fe2N5O5

  • Kuanguan Liu EMAIL logo , Qi-De Shan , Jing Nie and Xiaowei Yan
Published/Copyright: August 1, 2017
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 232 Issue 5

Abstract

C49H40BCu2F4Fe2N5O5, triclinic, P1̄ (no. 2), a = 11.526(2) Å, b = 12.902(2) Å, c = 15.469(3) Å, α = 95.632(2)°, β =107.789(2)°, γ = 96.251(2)°, V = 2156.3(7) Å3, Z = 2, Rgt(F) = 0.0443, wRref(F2) = 0.1198, T = 100(2) K.

CCDC no.:: 1560834

Parts of the title crystal structure are shown using a ball-and-stick scheme in the figure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Table 1

Data collection and handling.

Crystal:Blue-green block
Size:0.21 × 0.20 × 0.19 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:17.1 cm−1
Diffractometer, scan mode:Bruker CCD, φ and ω
2θmax, completeness:50°, >99%
N(hkl)measured, N(hkl)unique, Rint:15093, 7571, 0.037
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 5704
N(param)refined:637
Programs:SHELX [1], DIAMOND [2], Bruker programs [3]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
B10.6060(6)0.4603(4)0.6830(4)0.0358(14)
Cu1−0.02525(4)0.17999(4)0.39136(3)0.01835(14)
Cu2−0.02780(4)0.09554(4)0.19203(3)0.01927(14)
Fe2−0.36557(5)−0.15626(4)0.26782(4)0.01788(15)
Fe1−0.35154(5)0.36527(5)0.08624(4)0.01868(16)
O1−0.1984(3)0.1446(2)0.18177(19)0.0276(7)
O2−0.1781(3)0.2560(2)0.30717(18)0.0234(7)
O3−0.0881(3)0.0299(2)0.37014(18)0.0220(7)
O4−0.0700(3)−0.0375(2)0.23497(18)0.0215(6)
O50.0727(3)0.1671(2)0.31094(17)0.0214(6)
N1−0.1151(3)0.0307(3)0.0588(2)0.0221(8)
N20.0438(3)0.2055(3)0.1291(2)0.0223(8)
N30.0791(3)0.3172(3)0.4637(2)0.0200(8)
N4−0.1007(3)0.1950(3)0.4935(2)0.0205(8)
N5a−0.5445(8)0.0991(7)0.4620(6)0.087(3)
N5Ab−0.6635(17)0.1209(15)0.3943(13)0.082(7)
C1−0.1991(4)−0.0546(3)0.0271(3)0.0276(10)
H1A−0.2137−0.09990.06870.033*
C2−0.2674(4)−0.0796(4)−0.0671(3)0.0306(11)
H2A−0.3271−0.1411−0.08800.037*
C3−0.2476(4)−0.0155(4)−0.1281(3)0.0296(11)
H3A−0.2934−0.0321−0.19140.035*
C4−0.1593(4)0.0745(3)−0.0964(3)0.0249(10)
C5−0.1286(4)0.1470(4)−0.1536(3)0.0284(11)
H5A−0.16890.1335−0.21800.034*
C6−0.0440(4)0.2338(4)−0.1182(3)0.0301(11)
H6A−0.02540.2795−0.15820.036*
C70.0183(4)0.2585(4)−0.0215(3)0.0282(11)
C80.1031(4)0.3494(4)0.0205(3)0.0310(11)
H8A0.12300.3998−0.01550.037*
C90.1574(4)0.3651(4)0.1142(3)0.0305(11)
H9A0.21590.42590.14320.037*
C100.1255(4)0.2907(3)0.1667(3)0.0268(10)
H10A0.16390.30200.23130.032*
C11−0.0090(4)0.1881(3)0.0360(3)0.0196(9)
C12−0.0955(4)0.0953(3)−0.0015(3)0.0202(9)
C130.1709(4)0.3753(3)0.4490(3)0.0236(10)
H13A0.19900.35040.40020.028*
C140.2290(4)0.4720(3)0.5021(3)0.0269(10)
H14A0.29680.51000.49060.032*
C150.1876(4)0.5112(4)0.5704(3)0.0309(11)
H15A0.22380.57810.60530.037*
C160.0901(4)0.4508(3)0.5885(3)0.0241(10)
C170.0380(4)0.4842(4)0.6581(3)0.0295(11)
H17A0.06830.55150.69380.035*
C18−0.0535(4)0.4217(3)0.6736(3)0.0296(11)
H18A−0.08450.44500.72130.036*
C19−0.1044(4)0.3213(3)0.6201(3)0.0241(10)
C20−0.1996(4)0.2519(4)0.6309(3)0.0296(11)
H20A−0.23540.27080.67690.035*
C21−0.2416(4)0.1572(4)0.5758(3)0.0313(11)
H21A−0.30510.10950.58390.038*
C22−0.1891(4)0.1312(3)0.5067(3)0.0260(10)
H22A−0.21860.06540.46830.031*
C23−0.0569(4)0.2882(3)0.5498(3)0.0198(9)
C240.0395(4)0.3532(3)0.5341(3)0.0215(9)
C25−0.4173(4)0.2109(3)0.0797(3)0.0245(10)
H25A−0.39900.15040.04280.029*
C26−0.5161(4)0.2691(3)0.0489(3)0.0289(11)
H26A−0.57960.2567−0.01330.035*
C27−0.5093(4)0.3479(4)0.1224(3)0.0273(10)
H27A−0.56650.40120.12060.033*
C28−0.4049(4)0.3385(3)0.1984(3)0.0236(10)
H28A−0.37610.38410.25920.028*
C29−0.3473(4)0.2541(3)0.1716(3)0.0202(9)
C30−0.2314(4)0.2168(3)0.2259(3)0.0175(9)
C31−0.1732(4)0.4161(3)0.0966(3)0.0242(10)
H31A−0.09880.39030.13590.029*
C32−0.2423(4)0.3737(4)0.0042(3)0.0264(10)
H32A−0.22500.3128−0.03270.032*
C33−0.3400(4)0.4328(3)−0.0259(3)0.0251(10)
H33A−0.40400.4208−0.08780.030*
C34−0.3320(4)0.5108(3)0.0475(3)0.0214(9)
H34A−0.38960.56370.04610.026*
C35−0.2292(4)0.5011(3)0.1233(3)0.0215(9)
H35A−0.20100.54600.18450.026*
C36−0.2229(4)−0.1664(3)0.3820(3)0.0221(9)
H36A−0.2014−0.12140.44270.027*
C37−0.3036(4)−0.2632(3)0.3540(3)0.0254(10)
H37A−0.3492−0.29830.39140.030*
C38−0.3084(4)−0.3019(3)0.2637(3)0.0256(10)
H38A−0.3588−0.36850.22620.031*
C39−0.2319(4)−0.2286(3)0.2348(3)0.0226(9)
H39A−0.2183−0.23480.17380.027*
C40−0.1787(4)−0.1435(3)0.3082(3)0.0191(9)
C41−0.1071(4)−0.0430(3)0.3045(3)0.0175(9)
C42−0.5282(4)−0.1585(4)0.1660(3)0.0411(13)
H42A−0.5651−0.21350.11120.049*
C43−0.4483(4)−0.0661(4)0.1715(3)0.0345(12)
H43A−0.4176−0.04380.12130.041*
C44−0.4189(4)−0.0103(4)0.2601(3)0.0329(11)
H44A−0.36340.05850.28380.039*
C45−0.4810(5)−0.0675(4)0.3095(3)0.0389(12)
H45A−0.4777−0.04660.37430.047*
C46−0.5479(4)−0.1594(4)0.2519(4)0.0443(14)
H46A−0.6013−0.21540.26840.053*
C470.1791(5)0.1234(5)0.3500(4)0.0591(17)
H47A0.22510.16370.41010.089*
H47B0.23060.12570.31000.089*
H47C0.15620.05020.35730.089*
C48a−0.5099(10)0.1810(8)0.4407(8)0.068(3)
C48Ab−0.581(2)0.1862(16)0.3960(18)0.064(6)
C49a−0.478(2)0.264(2)0.397(2)0.059(3)
H49Aa−0.39910.25780.38700.089*
H49Ba−0.47220.33130.43450.089*
H49Ca−0.54210.26160.33710.089*
C49Ab−0.474(4)0.257(5)0.408(5)0.059(3)
H49Db−0.43110.27890.47330.089*
H49Eb−0.49720.31930.37840.089*
H49Fb−0.41990.22330.37960.089*
F10.5053(3)0.4827(3)0.7045(3)0.0878(14)
F20.6804(3)0.4135(2)0.7527(2)0.0635(10)
F30.5736(3)0.3913(2)0.6026(2)0.0543(8)
F40.6735(3)0.5536(2)0.67552(19)0.0501(8)

  1. aOccupancy: 0.683(11); bOccupancy: 0.317(11).

Source of materials

Blue-green crystals of [Cu(II)2(FcCOO)2(phen)2(CH3O)]BF4⋅ CH3CN were prepared by treating ferrocenecarboxylic acid (FcCOOH) with Cu(CH3CN)4BF4 in methanol in molar ratio 1:1. To the resulting solution, equivalent amounts of triethylamine and 1,10-phenantroline (phen) was added. The brown suspension was sealed in a vial that was heated and kept at 343 K for 20 h. Then the solution was cooled to room temperature and filtered, slow evaporation afforded blue-green block crystals of title complex.

Experimental details

All hydrogen atoms were positioned geometrically and allowed to ride on their parent atoms. The acetonitrile molecule shows a positional disorder.

Comment

Heterometallic complexes have attracted great attention in catalysis [4], magnetic materials [5], sensing [6], medical usage [7], etc. metalloligands are the best building blocks for the construction of heterometallic complexes [8]. Since its discovery, ferrocene has proven to be a versatile backbone for various ligands because of its rich chemistry, stability and redox properties [9]. Ferrocenecarboxylic acid is the mono-carboxylated ferrocene [10] and widely used in the modification of electrode for biosensors and electrocatalytic oxidation [11], [12], [13]. As a versatile functionalized ligand, ferrocenecarboxylate is widely used for the construction of heterometallic complexes with other metals. Among them, most of heterodimetallic complexes, such as mononuclear complexes [14], [15], [16], polymers [17], clusters [18], and MOFs [19] are reported in the last few years.

The title complex is a dinuclear copper(II) complex with two ferrocenecarboxylato ligands, two 1,10-phenanthroline ligands and one methanolato ligand. Each Cu(II) adopts square pyramid configuration by two nitrogen atoms of the phen ligand, one oxygen atom from the methanolate and the other two from each ferrocenecarboxylato ligand. The phen ligand coordinates in bidentate fashion with an average d(Cu—N) = 2.036(3) Å [range from 2.026(3) Å to 2.043(3) Å]. Each ferrocenecarboxylato ligand bridges two copper ions (cf. the figure) with Cu1—O2 = 2.233(3) Å, Cu1—O3 = 1.951(3) Å, Cu2—O1 = 2.095(3) Å, Cu2—O4 = 1.966(3) Å, respectively. The methanolato ligand bridges two copper ions with Cu1—O5 = 1.926(3) Å, Cu2—O5 = 1.926(3) Å, respectively. Those distances are in a reasonable range [20].

Acknowledgement

We acknowledge support for the publication fee by the National Natural Science Foundation of China (grant no. 21601097 and 21571143), the Research Starting Funds for Imported Talents, Ningxia University (grant no. BQD2015002) and the Doctor’s scientific research foundation of Hezhou University (grant no. HZUBS201507).

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Received: 2017-3-1
Accepted: 2017-7-7
Published Online: 2017-8-1
Published in Print: 2017-9-26

©2017 Kuanguan Liu et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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  26. Crystal structure of diaqua-bis(5′-(pyridin-1-ium-4-yl)-1H-[3,3′-bi(1,2,4-triazol)]-2′-ide-κ2N,N′)cobalt(II) — bis(5-(pyridin-4-yl-κN)-1H,1′H-3,3′-bi(1,2,4-triazole))octamolybdate – water (2/1/8), C27H33CoMo4N21O19
  27. Crystal structure of 3-cyclohexyl-2-(cyclohexylimino)-2,3-dihydro-6,8-diiodo-4H-1,3-benzoxazin-4-one, C20H24I2N2O2
  28. Crystal structure of dinitrato-κO-bis(tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ4N,N′,N′′,N′′′)-(μ2-cyclohexane-1,4-dicarboxylato-κ4O,O′:O′′,O′′′)dimanganese(II) – methanol – water (1/6/2), C62H80Mn2N16O18
  29. Crystal structure of bis(2-hydroxyethyl(phenyl)carbamodithioate)nickel(II), C18H20N2NiO2S4
  30. Crystal structure of methyl 1-(4-fluorobenzyl)-4-methoxy-5-oxopyrrolidine-3-carboxylate, C14H16FNO4
  31. Crystal structure of di-μ-iodido-bis(6-(p-tolyl)-2,2′-bipyridine-κ2N,N′)dicopper(I) — 2-(diphenylphosphoryl)benzoic acid (1/2), C36H29CuIN2O3P
  32. Crystal structure of 2-amino-4-(3-bromo-4-fluoro-phenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H16BrFN2O2
  33. Crystal structure of bis(μ2-2-chlorobenzoato-κ3O,O′:O′)-(2-chlorobenzoato-κO)-(2-chlorobenzoato-κO,O′)-bis(1,10-phenanthroline-κ2N,N′)-dicadmium(II) monohydrate, C52H36Cd2Cl4N4O10
  34. Crystal structure of 2-(8a-methyl-5-oxo-hexahydroimidazo [1,2-a]pyridin-1(5H)-yl)-2-oxoethyl acetate, C12H18N2O4
  35. Crystal structure of (E)-N,N-diethyl-2-(5-nitrothiazol-2-yl)-1-phenylethen-1-amine, C15H17N3O2S
  36. Crystal structure of diazido-dimethanolato-bis(μ2-2-(((3-oxidopropyl)imino)methyl)phenolato-κ4O:O,O′,N)dimanganese(III), C22H28Mn2N8O6
  37. The crystal structure of bis(2-(2,2,2-trifluoroacetyl)-3,4-dihydronaphthalen-1-olato-κ2O,O′)copper(II), C24H16CuF6O4
  38. Crystal structure of hexaaquanickel(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40N6NiO12S2
  39. Crystal structure of catena-poly[aqua-(μ2-hexamethylenetetramine-κ2N:N′)-bis(2,6-difluorobenzoato-κ2O:O′)cadmium(II)]monohydrate, C20H22CdF4N4O6
  40. Crystal structure of 3-benzyl-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C15H12N2OS
  41. Crystal structure of bis(μ2-ferrocenecarboxylato-κ2O:O′)-bis(1,10-phenanthroline-κ2N,N′)-(μ2-methanolato-κ2O,O)dicopper(II) tetrafluoroborate – acetonitrile (1/1), C49H40BCu2F4Fe2N5O5
  42. The crystal structure of tetrakis(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane-κP)silver(I) chloride dihydrate, C24H60AgClN12O6P4
  43. Crystal structure of 5-ethyl-2-(p-tolyl)-1,3-dioxane-5-carboxylic acid, C14H18O4
  44. Crystal structure of 2-(4-fluorophenyl)-1,3-dimethyl-1H-perimidin-3-ium iodide, C19H16ClIN2
  45. Crystal structure of catena-poly[(μ2-hexamethylenetetramine-κ2N:N′)-tetrakis(μ2-2,6-difluorobenzoato-κ2O:O′)dicopper(II)], C34H24Cu2F8N4O8
  46. Crystal structure of ethyl 3-hydroxy-5-methyl-2-(4-(m-tolyl)-1H-1,2,3-triazol-1-yl)-[1,1′-biphenyl]-4- carboxylate, C25H24N3O3
  47. The crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-κ2O,O′)-(diphenylcyclohexylphosphine-κP)rhodium(I), C24H25NO3PRh
  48. Crystal structure of bis((pyrazin-2-ylmethyl)(pyrazine-2-carbonyl)amido-κ3N,N′,N′′)copper(II), C20H16CuN10O2
  49. Crystal structure of catena-poly[tetraaqua-(μ2-succinonitrile-κ2N:N′)cobalt(II)] dinitrate, C4H12CoN4O10
  50. The crystal structure of 1,1′-bisisoquinoline, C18H12N2
  51. Crystal structure of bis(hydroxydi(pyridin-2-yl)methanolato-κ3N,N′,O)cobalt(III) perchlorate dihydrate, C22H22ClCoN4O10
https://doi.org/10.1515/ncrs-2017-0058
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of 2-(2-ethoxyphenyl)-7-propyl-5-methylimidazo[5,1-f][1,2,4]triazin-4(3H)-one, C17H20N4O2
  3. Crystal structure of catena-poly[aqua-(μ3-1,3,5-benzenetricarboxylato-κ3O:O′:O′′)-[μ3hydroxy-(1,3-di-(μ2-1,2,4-triazole-4-yl)benzoato-κ2N:N′)copper(II)], C19H16Cu2N6O9
  4. Crystal structure of poly[aqua-(μ3-3,5-di(4H-1,2,4-triazolyl-4-κ3N,N′:N′′)benzenecarboxylato)silver(I)], C11H9AgN6O3
  5. Crystal structure of tetrapropylammonium hydrogen carbonate, C13H29NO3
  6. Crystal structure of poly[μ2-acetato-κ3-O,O′:O′)diaqua(μ3-isophthalato-κ4O,O′:O′′:O′′′)yttrium(III)] monohydrate, C20H24O17Y2
  7. Crystal structure of catena-poly[dichlorido-(μ2-4-(1H-pyrazol-3-yl)-pyridine-κ2N,N′)]cadmium(II), C48H42Cd3Cl16N18
  8. Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C30H54N2O7
  9. Crystal structure of poly[(thiophene-3,4-dicarboxylato-κ1O)bis[1,2-bis(4-pyridyl)ethane-κ2N:N′]silver(I)] octahydrate, C30H42Ag2N4O12S
  10. The crystal structure of amine-(4-(1H-1,2,4-triazol-1-yl)benzoato-κN)silver(I) dihydrate, C9H13AgN4O4
  11. Crystal structure of poly[tetrakis(μ2-cyanido-κ2N:O)-cyanido-tris(pyridine)dicobalt(II/III)], C20H15Co2N8
  12. Crystal structure of bis(pyridine)-bis(2-formyl-4,6-dichlorophenolato)cobalt(II), C24H16Cl4CoN2O4
  13. Crystal structure of (E)-1-(4-(((E)-5-bromo-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H15BrN2O2
  14. Crystal structure of catena-poly[(μ2-3-(1H-pyrazol-4-yl)-5-(pyridin-4-yl)-1,2,4-triazole-κ N:N′)-bis(benzoato-κO)zinc(II)], C24H18N6O4Zn
  15. Hydrothermal synthesis and crystal structure of a poly[aqua-(μ4-4-(carboxylatomethyl)benzoato-κ4O:O′:O′′:O′′′)-(μ2-1-(4-(1H-imidazol-1-yl)benzyl)-1H-1,2,4-triazole-κ2N:N′) dimanganese(II)], [Mn2(C9H6O4)2(C12H11N5)(H2O)]
  16. Crystal structure of diaqua-catena-poly[diaqua-bis(μ2-5-(4-(1H-1,2,4-triazol-1-yl)phenyl)tetrazol-2-ido-κ2N:N′)cobalt(II)] dihydrate, C20H24CoN14O4
  17. Crystal structure of bis(μ3-2,2′-azanediylbis(ethan-1-olato)-κ5O:O,N,O′:O′)-tetrachlorido-bis(μ2-2-((2-hydroxyethyl)amino)ethan-1-olato-κ3N,O:O)dicobalt(II)dicobalt(III), C16H38Cl4Co4N4O8
  18. Crystal structure of poly[μ4-(4-(carboxylatomethyl)benzoato-κ4O:O′:O′′:O′′′)-(2-(4-(1H-imidazol-1-yl)phenyl)-1H-benzo[d]imidazole-κN)manganese(II)] [Mn(C9H6O4)(C16H12N4)]
  19. Crystal structure of 4-chloro-6-phenylpyrimidine, C10H7ClN2
  20. The crystal structure of [6-methoxy-2-(2,2,2-trifluoroacetyl)-3,4-dihydronaphthalen-1(2H)-one]difluoroborane, C13H10BF5O3
  21. Crystal structure of 3,3′-(butane-1,4-diylbis(azanylylidene))bis(1-phenylbut-1-en-1-olato)-κ4N,N′,O,O′]copper(II), C24H26N2O2Cu
  22. Crystal structure of tetraaqua-bis((E)-N′-(2-bromobenzylidene)isonicotinohydrazide-κN)zinc(II) dinitrate, C26H28N8O12Br2Zn
  23. Crystal structure of 2-amino-4-(4-bromophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13BrN2O2
  24. A single crystal study on tert-butyl-4-((4-(4-bromo-2-fluorophenylamino)-6-methoxyquinazolin-7-yloxy)methyl)piperidine-1-carboxylate, C26H30BrFN4O4
  25. Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato-κ3O,O′,N)zinc(II), C36H26N2O4Zn
  26. Crystal structure of diaqua-bis(5′-(pyridin-1-ium-4-yl)-1H-[3,3′-bi(1,2,4-triazol)]-2′-ide-κ2N,N′)cobalt(II) — bis(5-(pyridin-4-yl-κN)-1H,1′H-3,3′-bi(1,2,4-triazole))octamolybdate – water (2/1/8), C27H33CoMo4N21O19
  27. Crystal structure of 3-cyclohexyl-2-(cyclohexylimino)-2,3-dihydro-6,8-diiodo-4H-1,3-benzoxazin-4-one, C20H24I2N2O2
  28. Crystal structure of dinitrato-κO-bis(tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ4N,N′,N′′,N′′′)-(μ2-cyclohexane-1,4-dicarboxylato-κ4O,O′:O′′,O′′′)dimanganese(II) – methanol – water (1/6/2), C62H80Mn2N16O18
  29. Crystal structure of bis(2-hydroxyethyl(phenyl)carbamodithioate)nickel(II), C18H20N2NiO2S4
  30. Crystal structure of methyl 1-(4-fluorobenzyl)-4-methoxy-5-oxopyrrolidine-3-carboxylate, C14H16FNO4
  31. Crystal structure of di-μ-iodido-bis(6-(p-tolyl)-2,2′-bipyridine-κ2N,N′)dicopper(I) — 2-(diphenylphosphoryl)benzoic acid (1/2), C36H29CuIN2O3P
  32. Crystal structure of 2-amino-4-(3-bromo-4-fluoro-phenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H16BrFN2O2
  33. Crystal structure of bis(μ2-2-chlorobenzoato-κ3O,O′:O′)-(2-chlorobenzoato-κO)-(2-chlorobenzoato-κO,O′)-bis(1,10-phenanthroline-κ2N,N′)-dicadmium(II) monohydrate, C52H36Cd2Cl4N4O10
  34. Crystal structure of 2-(8a-methyl-5-oxo-hexahydroimidazo [1,2-a]pyridin-1(5H)-yl)-2-oxoethyl acetate, C12H18N2O4
  35. Crystal structure of (E)-N,N-diethyl-2-(5-nitrothiazol-2-yl)-1-phenylethen-1-amine, C15H17N3O2S
  36. Crystal structure of diazido-dimethanolato-bis(μ2-2-(((3-oxidopropyl)imino)methyl)phenolato-κ4O:O,O′,N)dimanganese(III), C22H28Mn2N8O6
  37. The crystal structure of bis(2-(2,2,2-trifluoroacetyl)-3,4-dihydronaphthalen-1-olato-κ2O,O′)copper(II), C24H16CuF6O4
  38. Crystal structure of hexaaquanickel(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40N6NiO12S2
  39. Crystal structure of catena-poly[aqua-(μ2-hexamethylenetetramine-κ2N:N′)-bis(2,6-difluorobenzoato-κ2O:O′)cadmium(II)]monohydrate, C20H22CdF4N4O6
  40. Crystal structure of 3-benzyl-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C15H12N2OS
  41. Crystal structure of bis(μ2-ferrocenecarboxylato-κ2O:O′)-bis(1,10-phenanthroline-κ2N,N′)-(μ2-methanolato-κ2O,O)dicopper(II) tetrafluoroborate – acetonitrile (1/1), C49H40BCu2F4Fe2N5O5
  42. The crystal structure of tetrakis(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane-κP)silver(I) chloride dihydrate, C24H60AgClN12O6P4
  43. Crystal structure of 5-ethyl-2-(p-tolyl)-1,3-dioxane-5-carboxylic acid, C14H18O4
  44. Crystal structure of 2-(4-fluorophenyl)-1,3-dimethyl-1H-perimidin-3-ium iodide, C19H16ClIN2
  45. Crystal structure of catena-poly[(μ2-hexamethylenetetramine-κ2N:N′)-tetrakis(μ2-2,6-difluorobenzoato-κ2O:O′)dicopper(II)], C34H24Cu2F8N4O8
  46. Crystal structure of ethyl 3-hydroxy-5-methyl-2-(4-(m-tolyl)-1H-1,2,3-triazol-1-yl)-[1,1′-biphenyl]-4- carboxylate, C25H24N3O3
  47. The crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-κ2O,O′)-(diphenylcyclohexylphosphine-κP)rhodium(I), C24H25NO3PRh
  48. Crystal structure of bis((pyrazin-2-ylmethyl)(pyrazine-2-carbonyl)amido-κ3N,N′,N′′)copper(II), C20H16CuN10O2
  49. Crystal structure of catena-poly[tetraaqua-(μ2-succinonitrile-κ2N:N′)cobalt(II)] dinitrate, C4H12CoN4O10
  50. The crystal structure of 1,1′-bisisoquinoline, C18H12N2
  51. Crystal structure of bis(hydroxydi(pyridin-2-yl)methanolato-κ3N,N′,O)cobalt(III) perchlorate dihydrate, C22H22ClCoN4O10
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