Startseite Crystal structure of bis{μ2-(4-acetyl-phenoxy)acetato-κ2 O:O′}-bis{μ2-(4-acetyl-phenoxy)acetato-κ3 O,O′:O)- bis{(4-acetyl-phenoxy)acetato-κ2 O,O′}-bis(phenanthrolin-κ2 N,N′)didysprosium(III) tetrahydrate, C84H78N4O28Dy2
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Crystal structure of bis{μ2-(4-acetyl-phenoxy)acetato-κ2 O:O′}-bis{μ2-(4-acetyl-phenoxy)acetato-κ3 O,O′:O)- bis{(4-acetyl-phenoxy)acetato-κ2 O,O′}-bis(phenanthrolin-κ2 N,N′)didysprosium(III) tetrahydrate, C84H78N4O28Dy2

  • Li–Hua Wang , Hao–Wen Tai , Mei–Li Zhao EMAIL logo und Xi–Shi Tai ORCID logo
Veröffentlicht/Copyright: 4. April 2023
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 238 Heft 3

Abstract

C84H78N4O28Dy2, triclinic, P 1 ‾ (no. 2), a = 12.3134(5) Å, b = 12.7705(5) Å, c = 14.5150(6) Å, α = 70.852(1)°, β = 80.298(1)°, γ = 65.726(1)°, V = 1964.05(14) Å3, Z = 1, R gt (F) = 0.0381, wR ref (F 2) = 0.0682, T = 296.15 K.

CCDC no.: 2251232

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.15 × 0.12 × 0.11 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 1.98 mm−1
Diffractometer, scan mode: Bruker SMART CCD 6000, ω
θ max, completeness: 25.1°, 99%
N(hkl) measured , N(hkl) unique, R int: 54,137, 6967, 0.076
Criterion for I obs, N(hkl) gt: I obs > 2 σ(I obs), 5875
N(param) refined: 541
Programs: Bruker [1], Olex2 [2], SHELX [3], Diamond [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.6603 (4) 0.3831 (4) 0.5431 (3) 0.0356 (11)
H1 0.646478 0.452580 0.558980 0.043*
C2 0.5732 (4) 0.3351 (5) 0.5699 (3) 0.0452 (13)
H2 0.503101 0.371547 0.602651 0.054*
C3 0.5923 (4) 0.2335 (5) 0.5471 (4) 0.0525 (14)
H3 0.535186 0.199613 0.565080 0.063*
C4 0.6971 (4) 0.1798 (4) 0.4970 (3) 0.0424 (12)
C5 0.7213 (5) 0.0761 (5) 0.4677 (4) 0.0597 (15)
H5 0.665692 0.040419 0.483118 0.072*
C6 0.8217 (5) 0.0294 (5) 0.4188 (4) 0.0555 (15)
H6 0.834164 −0.037648 0.399741 0.067*
C7 0.9114 (4) 0.0798 (4) 0.3946 (3) 0.0400 (12)
C8 1.0193 (5) 0.0316 (4) 0.3452 (3) 0.0473 (13)
H8 1.035537 −0.035667 0.325214 0.057*
C9 1.1002 (5) 0.0832 (4) 0.3267 (4) 0.0483 (13)
H9 1.173247 0.050772 0.295563 0.058*
C10 1.0719 (4) 0.1866 (4) 0.3553 (3) 0.0419 (12)
H10 1.127697 0.221975 0.341283 0.050*
C11 0.8907 (4) 0.1823 (4) 0.4221 (3) 0.0309 (10)
C12 0.7810 (4) 0.2346 (4) 0.4731 (3) 0.0317 (10)
C13 0.7568 (4) 0.5763 (4) 0.3020 (3) 0.0332 (11)
C14 0.6760 (4) 0.6560 (4) 0.2181 (3) 0.0401 (12)
H14A 0.606211 0.636201 0.226051 0.048*
H14B 0.649651 0.739247 0.216655 0.048*
C15 0.5282 (5) 0.8537 (5) −0.0586 (4) 0.0560 (15)
H15 0.449390 0.907662 −0.065348 0.067*
C16 0.5710 (4) 0.7898 (5) 0.0341 (3) 0.0520 (14)
H16 0.522229 0.802457 0.089043 0.062*
C17 0.6860 (4) 0.7079 (4) 0.0437 (3) 0.0374 (11)
C18 0.7595 (4) 0.6905 (4) −0.0379 (3) 0.0419 (12)
H18 0.837444 0.634312 −0.030965 0.050*
C19 0.7166 (4) 0.7565 (4) −0.1289 (3) 0.0429 (12)
H19 0.766744 0.745733 −0.183471 0.052*
C20 0.6001 (5) 0.8392 (4) −0.1415 (3) 0.0440 (12)
C21 0.5577 (5) 0.9034 (5) −0.2418 (4) 0.0632 (16)
C22 0.4305 (6) 0.9892 (8) −0.2555 (5) 0.136 (4)
H22A 0.419158 1.033005 −0.323321 0.204*
H22B 0.411790 1.044232 −0.217880 0.204*
H22C 0.379115 0.945381 −0.234205 0.204*
C23 0.9529 (4) 0.7053 (4) 0.3739 (3) 0.0291 (10)
C24 0.9006 (5) 0.7599 (4) 0.2745 (3) 0.0458 (13)
H24A 0.939029 0.704250 0.235728 0.055*
H24B 0.816199 0.774796 0.281126 0.055*
C25 0.8752 (4) 0.9283 (4) 0.1344 (3) 0.0431 (12)
C26 0.8373 (5) 0.8817 (4) 0.0787 (4) 0.0516 (14)
H26 0.839417 0.803878 0.102679 0.062*
C27 0.7964 (5) 0.9515 (5) −0.0129 (4) 0.0521 (14)
H27 0.769738 0.920217 −0.049941 0.063*
C28 0.7938 (5) 1.0675 (4) −0.0514 (3) 0.0459 (13)
C29 0.8360 (6) 1.1093 (5) 0.0052 (4) 0.0637 (17)
H29 0.838102 1.185442 −0.019794 0.076*
C30 0.8748 (6) 1.0426 (5) 0.0970 (4) 0.0641 (17)
H30 0.900878 1.074166 0.134180 0.077*
C31 0.7459 (5) 1.1399 (5) −0.1497 (4) 0.0589 (15)
C32 0.7537 (7) 1.2603 (6) −0.1946 (4) 0.094 (2)
H32A 0.729193 1.291207 −0.260827 0.140*
H32B 0.834476 1.252560 −0.193707 0.140*
H32C 0.702539 1.314187 −0.158156 0.140*
C33 0.8186 (4) 0.5575 (4) 0.6346 (3) 0.0299 (10)
C34 0.7216 (4) 0.5837 (4) 0.7129 (3) 0.0382 (12)
H34A 0.748832 0.526195 0.775531 0.046*
H34B 0.702353 0.663387 0.717844 0.046*
C35 0.5214 (4) 0.5934 (4) 0.7511 (3) 0.0351 (11)
C36 0.5209 (4) 0.5993 (4) 0.8447 (3) 0.0414 (12)
H36 0.588654 0.595004 0.868517 0.050*
C37 0.4167 (4) 0.6119 (4) 0.9020 (3) 0.0428 (12)
H37 0.415356 0.615844 0.965064 0.051*
C38 0.3150 (4) 0.6187 (4) 0.8685 (3) 0.0359 (11)
C39 0.3177 (4) 0.6161 (4) 0.7740 (3) 0.0410 (12)
H39 0.248897 0.624390 0.749017 0.049*
C40 0.4197 (4) 0.6015 (4) 0.7163 (3) 0.0405 (12)
H40 0.420589 0.597038 0.653534 0.049*
C41 0.2082 (4) 0.6254 (4) 0.9346 (4) 0.0439 (13)
C42 0.0903 (4) 0.6617 (6) 0.8931 (4) 0.0671 (17)
H42A 0.090499 0.597734 0.872042 0.101*
H42B 0.076873 0.732242 0.838399 0.101*
H42C 0.028030 0.678322 0.942118 0.101*
Dy1 0.91646 (2) 0.42733 (2) 0.45293 (2) 0.02417 (7)
N1 0.7619 (3) 0.3360 (3) 0.4965 (2) 0.0295 (8)
N2 0.9705 (3) 0.2368 (3) 0.4010 (2) 0.0303 (8)
O1 0.2159 (3) 0.6017 (3) 1.0224 (3) 0.0620 (10)
O2 0.6189 (3) 0.5761 (3) 0.6881 (2) 0.0441 (8)
O3 0.9002 (3) 0.5934 (3) 0.6327 (2) 0.0397 (8)
O4 0.8115 (2) 0.5006 (3) 0.5817 (2) 0.0312 (7)
O5 0.8578 (3) 0.5008 (3) 0.2878 (2) 0.0395 (8)
O6 0.7198 (3) 0.5887 (3) 0.3847 (2) 0.0408 (8)
O7 0.7389 (3) 0.6389 (3) 0.1303 (2) 0.0494 (9)
O8 0.6229 (4) 0.8857 (4) −0.3125 (3) 0.0825 (13)
O9 0.7004 (5) 1.1023 (4) −0.1929 (3) 0.0906 (15)
O10 0.9166 (3) 0.8691 (3) 0.2265 (2) 0.0552 (10)
O11 1.0091 (3) 0.7479 (3) 0.4032 (2) 0.0363 (7)
O12 0.9374 (2) 0.6100 (2) 0.42534 (19) 0.0295 (7)
O13 1.0167 (8) 0.5591 (9) 0.1299 (8) 0.234 (4)
H13A 1.083383 0.541126 0.098421 0.351*
H13B 1.020099 0.493486 0.172229 0.351*
O14 0.6706 (7) 0.8105 (7) 0.4782 (6) 0.158 (2)
H14C 0.609870 0.846849 0.514905 0.237*
H14D 0.670901 0.742923 0.477089 0.237*

1 Source of materials

The dinuclear Dy(III) complex was synthesized according to the following method: 0.1257 g dysprosium chloride hexahydrate (0.033 mmol), 0.194 g (4-acetyl-phenoxy)acetic acid (1.0 mmol), 0.040 g NaOH (1.0 mmol), and 0.090 g 1,10-phenantroline (0.5 mmol) were dissolved in 20 mL of ethanol-water (1:1, v/v) solution with stirring. Then the mixture was heated at 80 °C for 6 h. After cooling to room temperature, the solution was filtered to a small beaker, evaporated quietly and slowly. The clear light colourless block crystals of the dinuclear Dy(III) complex were collected after 10 days.

2 Experimental details

The hydrogen atoms were positioned geometrically (C–H = 0.93–0.97 Å, and O–H = 0.85–0.89 Å). Their U iso values were set to 1.2 U eq or 1.5 U eq of the parent atoms.

3 Comment

Due to their unique electronic structure and high coordination numbers, rare earth complexes show for example excellent properties in aspects such as catalyst for isoprene polymerization [5], pharmacological activity [6], copolymerization of cyclohexene oxide with cyclic anhydrides [7], magnetic property [8], selective catalytic reduction of NO with NH3 [9], and optical, electrochemical property [10]. Our research group has been working on the structure and property of metal complexes [11].

Here we report a new dinuclear Dy(III) complex which was synthesized using a facile one-pot method with dysprosium chloride hexahydrate, (4-acetyl-phenoxy)acetic acid, NaOH, and 1,10-phenantroline as materials. Single crystal X-ray diffraction analysis shows that the dinuclear Dy(III) complex crystallizes in the triclinic space group P 1 ‾ . The molecular structure of the dinuclear Dy(III) complex is shown in Figure. The asymmetrical unit of dinuclear Dy(III) complex consists of one Dy(III), three (4-acetyl-phenoxy)acetate ligands, one 1,10-phenantroline ligand, and two uncoordinated water molecules. Each Dy(III) atom is nine-coordinated by seven oxygen atoms (O3a, O4, O5, O6, O11a, O12, O12a, or O3, O4a, O5a, O6a, O11, O12, O12a) from five (4-acetyl-phenoxy)acetate ligands and two nitrogen atoms (N1, N2, or N1a, N2a) from one 1,10-phenantroline ligand. The carboxylate groups of (4-acetyl-phenoxy)acetate ligands display three different coordination modes: four adopt two different bridging modes and the other two adopt a simple k2O,O′ chelating mode (see the figure). The Dy–O bond lengths range from 2.319(3) to 2.541(3) Å, and the Dy–N bond lengths range from 2.514(3) to 2.575(3) Å, respectively. Two symmetry-related Dy(III) ions are connected by four carboxylate groups to form a dinuclear [Dy2(COO)4] unit with a Dy···Dy distance of 3.911 Å.

Corresponding author: Zhao Mei–Li, College of Chemistry and Chemical Engineering, Weifang University, Weifang, Shandong 261061, P.R. China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: National Natural Science Foundation of China (No. 21171132, https://doi.org/10.13039/501100001809), the Natural Science Foundation of Shandong (ZR2014BL003, https://doi.org/10.13039/501100007129), the Project of Shandong Province Higher Educational Science and Technology Program (J14LC01, https://doi.org/10.13039/501100015642) and Science Foundation of Weifang (2020ZJ1054).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2023-02-22
Accepted: 2023-03-23
Accepted: 2023-03-23
Published Online: 2023-04-04
Published in Print: 2023-06-27

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of phenyl(3,3-dichloro-1,3-dihydro-2H-pyrrolo[2,3-b]pyridin-2-one)methanone, C7H4Cl2N2O
  4. Crystal structure of poly[diaqua-bis(μ 2-1,4-diaminobutane-N:N′)cobalt(II)] dichloride, C8H28Cl2CoN4O2
  5. Synthesis and crystal structure of (4aR,7S)-7-hydroxy-7-isopropyl-1,1-dimethyldecahydro-2H,6H-8a,4a-(epoxymethano)phenanthren-12-one, C20H32O3
  6. The crystal structure of 1-(2-chlorobenzyl)-3-(3,5-dichlorophenyl)urea, C14H11Cl3N2O
  7. Crystal structure of tetrapropylammonium-1,3,5-thiadiazole-5-amido-2-carbamate – 1,2,4-thiadiazole-3,5-diamine – water (1/1/1), C17H37N9O3S2
  8. Tetrabutylammonium 1,3,5-thiadiazole-5-amido-2-carbamate—1,2,4-thiadiazole-3,5-diamine— water (1/1/1), C21H45N9O3S2
  9. The crystal structure of ((E)-2,4-dichloro-6-(((2-hydroxy-5-nitrophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Cl2MnN5O4
  10. The crystal structure of aqua-bis{2-bromo-6-((2-(2-phenylacetyl)hydrazineylidene)methyl)phenolato-κ3 N,O,O′}-dimethylformamide-κ1 O-erbium(III) chloride – dimethylformamide – water (1/2/1), C39H49N7O9Br2ClEr
  11. Crystal structure of (diaqua-bis(phenanthroline-K 2 N,N′)-tetrakis(m 2-3,4,5,6-tetrafluorophthalato-K 4 O,O:O′:O″;K 2 O:O′)dierbium (III) phenanthroline (1/2), C80H38Er2F16N8O18
  12. Crystal structure of (E)-7-methoxy-2-(4-methoxy-2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C20H17F3O3
  13. The crystal structure of 4–(4,4,5,5–tetramethyl–1,3,2–dioxaborolan–2–yl)morpholine, C10H20BNO3
  14. The crystal structure of catena–poly[aqua(1-naphthoato-κ 2 O,O′)-(μ-1-naphthoato-κ 4 O:O,O′:O′)lead(II)], C22H16O5Pb
  15. The crystal structure of 1-(4-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  16. The crystal structure of 4-(pyren-1-yl)butyl-4-nitrobenzoate, C27H21NO4
  17. Crystal structure of cyclo-(bis(µ2-3,3′-(1H-imidazole-3-ium-1,3-diyl)dipropionato-κ4 O,O′:O″,O″′)-dinitrato-κ2 O,O′-tetraoxido-diuranium(VI) C18H22N6O18U2
  18. The crystal structure of catena-[nitrato-κ 2 O,O′-(μ 3-3-iodobenzene-1,2-dicarboxylato-κ 4 O:O′:O″,O‴)-(2,2′:6′,2″-terpyridine-κ 3 N,N′,N″)lanthanum(III)], C23H14IN4O7La
  19. Redetermination of crystal structure of [bis(pyridin-2-ylmethyl)amine-κ 3 N,Nʹ,Nʺ]chloridopalladium(II) chloride monohydrate
  20. Crystal structure of catena-poly[triaqua-[bis(m2-4-(1H-1,2,4-triazol-1-yl)benzoato-k2O:O')-(4-(1H-1,2,4-triazol-1-yl)benzoato-k1O)-praseodymium (III) monohydrate], C27H26N9O10Pr
  21. Crystal structure of trans-diaqua-bis(methyl methylcarbamohydrazonothioato-κ2 N,N′) nickel(II) iodide semihydrate, C6H22N6O2NiS2I2·0.5H2O
  22. The crystal structure of 2-(2-fluoro-4-methyl-5-((2,2,2-trifluoroethyl)thio)phenyl)isoindolin-1-one, C17H13F4NOS
  23. The crystal structure of di-μ-1-naphthylacetato-κ 3 O,O′:O;κ 3 O:O,O′-bis[(1-naphthylacetato-κ 2 O,O′)(2,2′-bipyridine-κ 2 N,N′)lead(II)] monohydrate, C68H54N4O9Pb2
  24. Crystal structure of tetrapropylammonium guanidinium 4,4′-sulfonyldibenzoate monohydrate, C27H44N4O7S
  25. Crystal structure of bis(tetrapropylammonium) terephthalate – 1-(diaminomethylene)thiourea – water (1/2/4) C18H40N5O4S
  26. Crystal structure of (E)-7-fluoro-2-(4-morpholinobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C21H20FNO2
  27. The crystal structure of poly[diaqua-bis(μ 3-5-bromobenzene-1,3-dicarboxylato-κ 3 O,O,O′)-(μ 2-1,3-bis-(4-pyridyl)-propane-κ 2 N,N′)-dizinc(II))] – 5-bromobenzene-1,3-dicarboxylic acid [2/1], C37H29Br3N2O14Zn2
  28. The crystal structure of 2-bromo-1,3-phenylene bis(4-methylbenzenesulfonate), C20H17BrO6S2
  29. Crystal structure of europium dichromium icosaaluminum, EuCr2Al20
  30. The crystal structure of N′1,N′3-di((E)-benzylidene) isophthalohydrazide dihydrate, C 22 H 22 N 4 O 4
  31. Crystal structure of 7α,11α-dihydroxy-15-oxo-ent-kauran-16-en-19,6β-olide, C20H26O5
  32. Crystal structure of 4-chloro-N′-[(1E)-pyridin-3-ylmethylidene]benzohydrazide, C13H10ClN3O
  33. The crystal structure of (Z)-3-(1-(2-((E)-4-isopropylbenzylidene)hydrazinyl)ethylidene) chroman-2,4-dione, C21H20N2O3
  34. Crystal structure of E-7-fluoro-2-(2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H12F4O
  35. Crystal structure of bis(6-aminopyridine-2-carboxylato–k2O,N)-bis(N,N-dimethylformamide-k1 O)zinc(II), C18H24N6O6Zn
  36. Crystal structure of 5-(adamantan-1-yl)-3-[(4-{[2-(trifluoromethyl)phenyl]-methyl}piperazin-1-yl)methyl]-1,3,4-oxadiazole-2(3H)-thione, C25H31F3N4OS
  37. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea – water (2/2/1), C30H72N10O7S2
  38. Crystal structure of tris(2,2′-bipyridine-κ2 N,N′)iron(II) triiodide – dichloromethane (2/1), C61H50Cl2Fe2I12N12
  39. Crystal structure of 2-amino-3-[2-(1,3,3-trimethyl-1,3-dihydro-indol-2-ylidene)-ethylideneamino]-but-2-enedinitrile, C17H17N5
  40. The crystal structure of 1-(2-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  41. Crystal structure of potassium bis(pentaselenido-κ 2 Se 1,Se 5)palladate(II), K2[Pd(Se5)2]
  42. The crystal structure of 5,10-bis(2-methoxyethyl)-5,10-dihydro-[1,2,3,4]tetrathiocino[5,6-b:8, 7-b′]diindole, C22H22N2O2S4
  43. The crystal structure of 4-(4-iodophenyl)-5H-1,2,3-dithiazole-5-thione, C8H4INS3
  44. Crystal structure of bis{μ2-(4-acetyl-phenoxy)acetato-κ2 O:O′}-bis{μ2-(4-acetyl-phenoxy)acetato-κ3 O,O′:O)- bis{(4-acetyl-phenoxy)acetato-κ2 O,O′}-bis(phenanthrolin-κ2 N,N′)didysprosium(III) tetrahydrate, C84H78N4O28Dy2
  45. Crystal structure of Eu2Pd3.37(1)Zn13.63(1)
  46. Crystal structure of 2-methoxy-4-(methoxy-carbonyl)phenyl 2-chloro-4-fluorobenzoate, C16H12ClFO5
  47. Crystal structure of catena-poly[bis(μ2-dicyanamide-κ2 N:N′)-bis(4-vinylpyridine-κN)-copper(II)], C18H14CuN8
  48. The crystal structure of iguratimod-dimethylformamide (1/1), C17H14N2O6S·C3H7NO
  49. Synthesis and crystal structure of 1-((3R,10S,13S,17S)-10,13-dimethyl-3-(m-tolylamino)hexadecahydro-1H-cyclopenta[α]phenanthren-17-yl)ethan-1-one, C28H41NO
  50. The crystal structure of diaqua-bis(4-bromo-2-formylphenoxy)zinc(II), C14H12Br2O6Zn
  51. The crystal structure of tetra(1-ethylimidazole-κ 1 N)-[μ 4-imidazole-4,5-dicarboxylato-κ 4 O, N, O′, N′]-trioxido-divanadium, C25H33N10O7V2
  52. The crystal structure of (E)-N′-(1-(4-fluorophenyl)propylidene)-2-hydroxybenzohydrazide, C16H15FN2O2
https://doi.org/10.1515/ncrs-2023-0086
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of phenyl(3,3-dichloro-1,3-dihydro-2H-pyrrolo[2,3-b]pyridin-2-one)methanone, C7H4Cl2N2O
  4. Crystal structure of poly[diaqua-bis(μ 2-1,4-diaminobutane-N:N′)cobalt(II)] dichloride, C8H28Cl2CoN4O2
  5. Synthesis and crystal structure of (4aR,7S)-7-hydroxy-7-isopropyl-1,1-dimethyldecahydro-2H,6H-8a,4a-(epoxymethano)phenanthren-12-one, C20H32O3
  6. The crystal structure of 1-(2-chlorobenzyl)-3-(3,5-dichlorophenyl)urea, C14H11Cl3N2O
  7. Crystal structure of tetrapropylammonium-1,3,5-thiadiazole-5-amido-2-carbamate – 1,2,4-thiadiazole-3,5-diamine – water (1/1/1), C17H37N9O3S2
  8. Tetrabutylammonium 1,3,5-thiadiazole-5-amido-2-carbamate—1,2,4-thiadiazole-3,5-diamine— water (1/1/1), C21H45N9O3S2
  9. The crystal structure of ((E)-2,4-dichloro-6-(((2-hydroxy-5-nitrophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Cl2MnN5O4
  10. The crystal structure of aqua-bis{2-bromo-6-((2-(2-phenylacetyl)hydrazineylidene)methyl)phenolato-κ3 N,O,O′}-dimethylformamide-κ1 O-erbium(III) chloride – dimethylformamide – water (1/2/1), C39H49N7O9Br2ClEr
  11. Crystal structure of (diaqua-bis(phenanthroline-K 2 N,N′)-tetrakis(m 2-3,4,5,6-tetrafluorophthalato-K 4 O,O:O′:O″;K 2 O:O′)dierbium (III) phenanthroline (1/2), C80H38Er2F16N8O18
  12. Crystal structure of (E)-7-methoxy-2-(4-methoxy-2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C20H17F3O3
  13. The crystal structure of 4–(4,4,5,5–tetramethyl–1,3,2–dioxaborolan–2–yl)morpholine, C10H20BNO3
  14. The crystal structure of catena–poly[aqua(1-naphthoato-κ 2 O,O′)-(μ-1-naphthoato-κ 4 O:O,O′:O′)lead(II)], C22H16O5Pb
  15. The crystal structure of 1-(4-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  16. The crystal structure of 4-(pyren-1-yl)butyl-4-nitrobenzoate, C27H21NO4
  17. Crystal structure of cyclo-(bis(µ2-3,3′-(1H-imidazole-3-ium-1,3-diyl)dipropionato-κ4 O,O′:O″,O″′)-dinitrato-κ2 O,O′-tetraoxido-diuranium(VI) C18H22N6O18U2
  18. The crystal structure of catena-[nitrato-κ 2 O,O′-(μ 3-3-iodobenzene-1,2-dicarboxylato-κ 4 O:O′:O″,O‴)-(2,2′:6′,2″-terpyridine-κ 3 N,N′,N″)lanthanum(III)], C23H14IN4O7La
  19. Redetermination of crystal structure of [bis(pyridin-2-ylmethyl)amine-κ 3 N,Nʹ,Nʺ]chloridopalladium(II) chloride monohydrate
  20. Crystal structure of catena-poly[triaqua-[bis(m2-4-(1H-1,2,4-triazol-1-yl)benzoato-k2O:O')-(4-(1H-1,2,4-triazol-1-yl)benzoato-k1O)-praseodymium (III) monohydrate], C27H26N9O10Pr
  21. Crystal structure of trans-diaqua-bis(methyl methylcarbamohydrazonothioato-κ2 N,N′) nickel(II) iodide semihydrate, C6H22N6O2NiS2I2·0.5H2O
  22. The crystal structure of 2-(2-fluoro-4-methyl-5-((2,2,2-trifluoroethyl)thio)phenyl)isoindolin-1-one, C17H13F4NOS
  23. The crystal structure of di-μ-1-naphthylacetato-κ 3 O,O′:O;κ 3 O:O,O′-bis[(1-naphthylacetato-κ 2 O,O′)(2,2′-bipyridine-κ 2 N,N′)lead(II)] monohydrate, C68H54N4O9Pb2
  24. Crystal structure of tetrapropylammonium guanidinium 4,4′-sulfonyldibenzoate monohydrate, C27H44N4O7S
  25. Crystal structure of bis(tetrapropylammonium) terephthalate – 1-(diaminomethylene)thiourea – water (1/2/4) C18H40N5O4S
  26. Crystal structure of (E)-7-fluoro-2-(4-morpholinobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C21H20FNO2
  27. The crystal structure of poly[diaqua-bis(μ 3-5-bromobenzene-1,3-dicarboxylato-κ 3 O,O,O′)-(μ 2-1,3-bis-(4-pyridyl)-propane-κ 2 N,N′)-dizinc(II))] – 5-bromobenzene-1,3-dicarboxylic acid [2/1], C37H29Br3N2O14Zn2
  28. The crystal structure of 2-bromo-1,3-phenylene bis(4-methylbenzenesulfonate), C20H17BrO6S2
  29. Crystal structure of europium dichromium icosaaluminum, EuCr2Al20
  30. The crystal structure of N′1,N′3-di((E)-benzylidene) isophthalohydrazide dihydrate, C 22 H 22 N 4 O 4
  31. Crystal structure of 7α,11α-dihydroxy-15-oxo-ent-kauran-16-en-19,6β-olide, C20H26O5
  32. Crystal structure of 4-chloro-N′-[(1E)-pyridin-3-ylmethylidene]benzohydrazide, C13H10ClN3O
  33. The crystal structure of (Z)-3-(1-(2-((E)-4-isopropylbenzylidene)hydrazinyl)ethylidene) chroman-2,4-dione, C21H20N2O3
  34. Crystal structure of E-7-fluoro-2-(2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H12F4O
  35. Crystal structure of bis(6-aminopyridine-2-carboxylato–k2O,N)-bis(N,N-dimethylformamide-k1 O)zinc(II), C18H24N6O6Zn
  36. Crystal structure of 5-(adamantan-1-yl)-3-[(4-{[2-(trifluoromethyl)phenyl]-methyl}piperazin-1-yl)methyl]-1,3,4-oxadiazole-2(3H)-thione, C25H31F3N4OS
  37. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea – water (2/2/1), C30H72N10O7S2
  38. Crystal structure of tris(2,2′-bipyridine-κ2 N,N′)iron(II) triiodide – dichloromethane (2/1), C61H50Cl2Fe2I12N12
  39. Crystal structure of 2-amino-3-[2-(1,3,3-trimethyl-1,3-dihydro-indol-2-ylidene)-ethylideneamino]-but-2-enedinitrile, C17H17N5
  40. The crystal structure of 1-(2-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  41. Crystal structure of potassium bis(pentaselenido-κ 2 Se 1,Se 5)palladate(II), K2[Pd(Se5)2]
  42. The crystal structure of 5,10-bis(2-methoxyethyl)-5,10-dihydro-[1,2,3,4]tetrathiocino[5,6-b:8, 7-b′]diindole, C22H22N2O2S4
  43. The crystal structure of 4-(4-iodophenyl)-5H-1,2,3-dithiazole-5-thione, C8H4INS3
  44. Crystal structure of bis{μ2-(4-acetyl-phenoxy)acetato-κ2 O:O′}-bis{μ2-(4-acetyl-phenoxy)acetato-κ3 O,O′:O)- bis{(4-acetyl-phenoxy)acetato-κ2 O,O′}-bis(phenanthrolin-κ2 N,N′)didysprosium(III) tetrahydrate, C84H78N4O28Dy2
  45. Crystal structure of Eu2Pd3.37(1)Zn13.63(1)
  46. Crystal structure of 2-methoxy-4-(methoxy-carbonyl)phenyl 2-chloro-4-fluorobenzoate, C16H12ClFO5
  47. Crystal structure of catena-poly[bis(μ2-dicyanamide-κ2 N:N′)-bis(4-vinylpyridine-κN)-copper(II)], C18H14CuN8
  48. The crystal structure of iguratimod-dimethylformamide (1/1), C17H14N2O6S·C3H7NO
  49. Synthesis and crystal structure of 1-((3R,10S,13S,17S)-10,13-dimethyl-3-(m-tolylamino)hexadecahydro-1H-cyclopenta[α]phenanthren-17-yl)ethan-1-one, C28H41NO
  50. The crystal structure of diaqua-bis(4-bromo-2-formylphenoxy)zinc(II), C14H12Br2O6Zn
  51. The crystal structure of tetra(1-ethylimidazole-κ 1 N)-[μ 4-imidazole-4,5-dicarboxylato-κ 4 O, N, O′, N′]-trioxido-divanadium, C25H33N10O7V2
  52. The crystal structure of (E)-N′-(1-(4-fluorophenyl)propylidene)-2-hydroxybenzohydrazide, C16H15FN2O2
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Heruntergeladen am 1.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2023-0086/html
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