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Crystal structure of tris(2,2′-bipyridine-κ2 N,N′)iron(II) triiodide – dichloromethane (2/1), C61H50Cl2Fe2I12N12

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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 238 Issue 3

Abstract

C61H50Cl2Fe2I12N12, orthorhombic, Pbcn (no. 60), a = 13.0247(4) Å, b = 17.0204(5) Å, c = 34.1475(9) Å, β = 90, V = 7570.0(4) Å3, Z = 4, Rgt (F) = 0.0694, wRref (F 2) = 0.1605, T = 293(2) K.

CCDC no.: 2247456

The molecular structure is presented in the figure. Table 1 contains the crystallographic data, and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

 

 

Table 1:

Data collection and handling.

Crystal: Black block
Size: 0.72 × 0.29 × 0.15 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 5.39 mm−1
Diffractometer, scan mode: Xcalibur, ω
θ max, completeness: 26.5°, >99%
N(hkl)measured, N(hkl)unique, R int: 56,694, 7815, 0.051
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 6480
N(param)refined: 402
Programs: CrysAlis Pro [1], Olex2 [2], Shelx [3, 4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.3331 (7) 0.5111 (6) 0.3596 (3) 0.047 (2)
H1 0.311819 0.528952 0.335156 0.057*
C2 0.4356 (8) 0.5134 (6) 0.3686 (4) 0.060 (3)
H2 0.482634 0.533029 0.350643 0.073*
C3 0.4680 (9) 0.4870 (7) 0.4037 (4) 0.068 (3)
H3 0.537244 0.488624 0.410223 0.081*
C4 0.3980 (8) 0.4579 (6) 0.4294 (3) 0.054 (2)
H4 0.419702 0.439063 0.453619 0.064*
C5 0.2956 (7) 0.4562 (5) 0.4200 (3) 0.043 (2)
C6 0.2127 (8) 0.4306 (5) 0.4449 (3) 0.046 (2)
C7 0.2272 (11) 0.3969 (7) 0.4821 (3) 0.072 (3)
H7 0.293131 0.389876 0.491942 0.086*
C8 0.1462 (12) 0.3752 (8) 0.5031 (3) 0.081 (4)
H8 0.156477 0.350440 0.527072 0.098*
C9 0.0489 (10) 0.3880 (7) 0.4906 (3) 0.068 (3)
H9 −0.007682 0.374256 0.505729 0.082*
C10 0.0375 (8) 0.4230 (6) 0.4536 (3) 0.052 (2)
H10 −0.028358 0.432876 0.444290 0.062*
C11 0.1099 (8) 0.3105 (6) 0.3720 (3) 0.055 (2)
H11 0.108070 0.309636 0.399242 0.066*
C12 0.1074 (9) 0.2399 (6) 0.3518 (4) 0.070 (3)
H12 0.104567 0.192488 0.365250 0.084*
C13 0.1092 (10) 0.2411 (6) 0.3127 (4) 0.070 (3)
H13 0.106777 0.194000 0.298897 0.084*
C14 0.1145 (8) 0.3109 (7) 0.2924 (3) 0.059 (3)
H14 0.116415 0.311893 0.265195 0.071*
C15 0.1169 (7) 0.3801 (5) 0.3142 (3) 0.044 (2)
C16 0.1236 (6) 0.4584 (6) 0.2968 (3) 0.041 (2)
C17 0.1326 (9) 0.4731 (7) 0.2571 (3) 0.061 (3)
H17 0.135524 0.431461 0.239561 0.073*
C18 0.1373 (10) 0.5490 (7) 0.2436 (3) 0.068 (3)
H18 0.143214 0.558910 0.216868 0.082*
C19 0.1330 (10) 0.6110 (7) 0.2702 (3) 0.066 (3)
H19 0.136088 0.663062 0.262059 0.079*
C20 0.1241 (8) 0.5912 (5) 0.3091 (3) 0.045 (2)
H20 0.120228 0.632005 0.327124 0.054*
C21 −0.1048 (7) 0.4392 (6) 0.3625 (3) 0.049 (2)
H21 −0.081288 0.388414 0.358053 0.059*
C22 −0.2084 (8) 0.4557 (8) 0.3564 (3) 0.064 (3)
H22 −0.252542 0.417051 0.347045 0.077*
C23 −0.2439 (8) 0.5293 (8) 0.3644 (3) 0.063 (3)
H23 −0.313024 0.541409 0.361078 0.076*
C24 −0.1752 (8) 0.5860 (7) 0.3776 (3) 0.059 (3)
H24 −0.198229 0.636597 0.382834 0.071*
C25 −0.0747 (7) 0.5679 (5) 0.3829 (2) 0.042 (2)
C26 0.0031 (7) 0.6218 (5) 0.3976 (2) 0.0375 (18)
C27 −0.0191 (9) 0.6968 (6) 0.4114 (3) 0.053 (2)
H27 −0.085126 0.717115 0.409243 0.064*
C28 0.0578 (11) 0.7405 (6) 0.4281 (3) 0.069 (3)
H28 0.044940 0.790726 0.437663 0.083*
C29 0.1518 (10) 0.7091 (6) 0.4304 (3) 0.061 (3)
H29 0.204705 0.737545 0.442006 0.074*
C30 0.1710 (8) 0.6351 (6) 0.4159 (3) 0.053 (2)
H30 0.237305 0.614976 0.417354 0.063*
C31 0.500000 0.4784 (13) 0.250000 0.089 (6)
H31Aa 0.478277 0.444905 0.271435 0.106*
H31Ba 0.521724 0.444904 0.228566 0.106*
Cl1 0.4034 (5) 0.5325 (5) 0.2358 (3) 0.203 (4)
Fe1 0.11257 (9) 0.48480 (7) 0.37793 (3) 0.0328 (3)
I1 0.81878 (6) 0.23650 (5) 0.31024 (2) 0.0692 (2)
I2 0.60101 (6) 0.27721 (4) 0.31379 (2) 0.05317 (19)
I3 0.38621 (6) 0.31501 (5) 0.31996 (3) 0.0726 (2)
I4 0.60213 (9) 0.70436 (8) 0.42937 (4) 0.1127 (4)
I5 0.44135 (7) 0.65181 (5) 0.48069 (2) 0.0738 (3)
I6 0.28363 (11) 0.59529 (11) 0.53402 (5) 0.1374 (5)
N1 0.2632 (5) 0.4843 (4) 0.3845 (2) 0.0385 (15)
N2 0.1173 (6) 0.4426 (4) 0.4313 (2) 0.0404 (16)
N3 0.1149 (5) 0.3791 (4) 0.3537 (2) 0.0398 (16)
N4 0.1206 (5) 0.5176 (4) 0.3228 (2) 0.0387 (16)
N5 −0.0379 (5) 0.4938 (4) 0.37451 (19) 0.0361 (15)
N6 0.0980 (5) 0.5919 (4) 0.39992 (19) 0.0353 (15)

  1. aOccupancy: 0.5.

1 Source of materials

The precursor, [Fe(CO)4I2] was prepared according to the literature’s methods [5, 6]. The 2,2′-bipyridine was commercially available from the Aladdin Chemical Technology Co., Ltd. By following the literature’s methods with modifications [7], [8], [9], [10], the title complex was synthesized reacting the precursor with 1.5 equivalent of 2,2′-bipyridine in hexane under an inert atmosphere at room temperature. The volatiles were removed by vacuum, and residues were washed by diethyl ether. Black precipitates were crushed out from its dichloromethane solution with the addition of hexane.

2 Experimental details

Crystals of the title complex were obtained by a layer-to-layer diffusion of hexane into its dichloromethane solution. The single crystals suitable for X-ray diffraction analysis experiment were selected and covered by silicone grease, and then mounted on a Gemini diffractometer (Xcalibur, Eos). The crystallographic data were collected on CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018). Using Olex2 [2], the structure was solved with intrinsic phasing methods in Shelxt [3] program and refined by least squares minimization with the Shelxl package [4]. All hydrogen atoms were located by geometrical calculation. The crystallographic data in CIF file can be obtained from the Supplementary Materials or the Cambridge Structural Database with the CCDC number (2247456).

3 Comment

The precursor [Fe(CO)4I2], first reported by Hieber and co-workers [11], is a universal reactant for the preparation of iron carbonyls and ferrous complexes. Owning to its versatile activity, the derivatives from CO-substitution or iodine-substitution have been widely reported [5], [6], [7], [8], [9], [10]. For example, the reaction of amine with the precursor would probably result to the aminium salts containing a monoiron anion fac-[Fe(CO)3I3]− [7], the amine-coordinated complexes [8], or even the ferracyclic carbamoyl complexes [12, 13]. The ferracyclic carbamoyl complexes have been receiving arising interest for that they are structural relevant to the active site of [Fe]-hydrogenase. However, the products are highly dependence to the reaction conditions which should be carefully controlled.

Herein, the reaction of 2,2′-bipyridine with the precursor affords the title complex without carbonyls. The iron (II) is coordinated by three 2,2′-bipyridine ligands in an octahedral molecular geometry. Additionally, the forming of the triiodide anion indicates an iodine free radical-involved pathway of the reaction [8, 9]. Bond lengths and angles are in the expected ranges [14, 15].

Corresponding authors: Jinxiao Zhang, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541006, China, E-mail: ; and Zhiyin Xiao, College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001, China, E-mail:

Funding source: Jiaxing University

Award Identifier / Grant number: CD70619031

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by Jiaxing University (CD70619031).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Agilent Technologies. CrysAlisPro; Agilent Technologies: Santa Clara, CA, USA, 2017.Search in Google Scholar

2. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. Olex2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Search in Google Scholar

3. Sheldrick, G. Shelxt – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Search in Google Scholar

4. Sheldrick, G. Crystal structure refinement with Shelxl. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

5. Xiao, Z., Wei, Z., Long, L., Wang, Y., Evans, D. J., Liu, X. Diiron carbonyl complexes possessing a {Fe(II)Fe(II)} core: synthesis, characterisation, and electrochemical investigation. Dalton Trans. 2011, 40, 4291–4299; https://doi.org/10.1039/c0dt01465f.Search in Google Scholar PubMed

6. Xiao, Z., Jiang, R., Jin, J., Yang, X., Xu, B., Liu, X., He, Y., He, Y. Diiron(ii) pentacarbonyl complexes as CO-releasing molecules: their synthesis, characterization, CO-releasing behaviour and biocompatibility. Dalton Trans. 2019, 48, 468–477; https://doi.org/10.1039/c8dt03982h.Search in Google Scholar PubMed

7. Yang, X., Jin, J., Guo, Z., Xiao, Z., Chen, N., Jiang, X., He, Y., Liu, X. The monoiron anion fac-[Fe(CO)3I3]− and its organic aminium salts: their preparation, CO-release, and cytotoxicity. New J. Chem. 2020, 44, 10300–10308; https://doi.org/10.1039/d0nj01182g.Search in Google Scholar

8. Guo, J., Guo, Z., Xiao, Z., Jin, J., Yang, X., He, Y., Liu, X. Further exploration of the reaction between cis-[Fe(CO)4I2] and alkylamines: an aminium salt of fac-[Fe(CO)3I3]− or an amine-bound complex of fac-[Fe(CO)3I2(NH2R)]? Appl. Organomet. Chem. 2021, 35, e6280; https://doi.org/10.1002/aoc.6280.Search in Google Scholar

9. Guo, Z., Jin, J., Xiao, Z., Chen, N., Jiang, X., Liu, X., Wu, L., He, Y., Zhang, S. Four iron(II) carbonyl complexes containing both pyridyl and halide ligands: their synthesis, characterization, stability, and anticancer activity. Appl. Organomet. Chem. 2021, 35, e6045; https://doi.org/10.1002/aoc.6045.Search in Google Scholar

10. Luo, J.-B., Guo, J.-Z., Xiao, Z.-Y., Zhong, W., Li, X.-M., Liu, X.-M. Preparation of dicarbonyl iron compounds with a bidentate phosphine and their CO release behaviors upon irradiation. Chin. J. Inorg. Chem. 2022, 38, 1241–1251.Search in Google Scholar

11. Hieber, W., Bader, G. Reaktionen und Derivate des Eisencarbonyls, II.: Neuartige Kohlenoxyd–Verbindungen von Eisenhalogeniden. Ber. Dtsch. Chem. Ges. 1928, 61, 1717–1722; https://doi.org/10.1002/cber.19280610825.Search in Google Scholar

12. Turrell, P. J., Wright, J. A., Peck, J. N. T., Oganesyan, V. S., Pickett, C. J. The third hydrogenase: a ferracyclic carbamoyl with close structural analogy to the active site of Hmd. Angew. Chem. Int. Ed. 2010, 49, 7508–7511; https://doi.org/10.1002/anie.201004189.Search in Google Scholar PubMed

13. Turrell, P. J., Hill, A. D., Ibrahim, S. K., Wright, J. A., Pickett, C. J. Ferracyclic carbamoyl complexes related to the active site of [Fe]-hydrogenase. Dalton Trans. 2013, 42, 8140–8146; https://doi.org/10.1039/c3dt50642h.Search in Google Scholar PubMed

14. Fan, L.-Q., Wu, J.-H. Crystal structure of tris(2,2′- bipyridine)iron(II) catena-bis((tris-μ-iodo)- plumbate(II)), [Fe(C10H8N2)3][PbI3]2. Z. Kristallogr. N. Cryst. Struct. 2008, 223, 72–74; https://doi.org/10.1524/ncrs.2008.0032.Search in Google Scholar

15. Pinto, M. F., deCardoso, P. B., Barroso, S., Martins, A. M., Royo, B. Chelating bis–N-heterocyclic carbene complexes of iron(II) containing bipyridyl ligands as catalyst precursors for oxidation of alcohols. Dalton Trans. 2016, 45, 13541–13546; https://doi.org/10.1039/c6dt02718k.Search in Google Scholar PubMed

Received: 2023-02-20
Accepted: 2023-03-09
Published Online: 2023-03-23
Published in Print: 2023-06-27

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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https://doi.org/10.1515/ncrs-2023-0075
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of phenyl(3,3-dichloro-1,3-dihydro-2H-pyrrolo[2,3-b]pyridin-2-one)methanone, C7H4Cl2N2O
  4. Crystal structure of poly[diaqua-bis(μ 2-1,4-diaminobutane-N:N′)cobalt(II)] dichloride, C8H28Cl2CoN4O2
  5. Synthesis and crystal structure of (4aR,7S)-7-hydroxy-7-isopropyl-1,1-dimethyldecahydro-2H,6H-8a,4a-(epoxymethano)phenanthren-12-one, C20H32O3
  6. The crystal structure of 1-(2-chlorobenzyl)-3-(3,5-dichlorophenyl)urea, C14H11Cl3N2O
  7. Crystal structure of tetrapropylammonium-1,3,5-thiadiazole-5-amido-2-carbamate – 1,2,4-thiadiazole-3,5-diamine – water (1/1/1), C17H37N9O3S2
  8. Tetrabutylammonium 1,3,5-thiadiazole-5-amido-2-carbamate—1,2,4-thiadiazole-3,5-diamine— water (1/1/1), C21H45N9O3S2
  9. The crystal structure of ((E)-2,4-dichloro-6-(((2-hydroxy-5-nitrophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Cl2MnN5O4
  10. The crystal structure of aqua-bis{2-bromo-6-((2-(2-phenylacetyl)hydrazineylidene)methyl)phenolato-κ3 N,O,O′}-dimethylformamide-κ1 O-erbium(III) chloride – dimethylformamide – water (1/2/1), C39H49N7O9Br2ClEr
  11. Crystal structure of (diaqua-bis(phenanthroline-K 2 N,N′)-tetrakis(m 2-3,4,5,6-tetrafluorophthalato-K 4 O,O:O′:O″;K 2 O:O′)dierbium (III) phenanthroline (1/2), C80H38Er2F16N8O18
  12. Crystal structure of (E)-7-methoxy-2-(4-methoxy-2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C20H17F3O3
  13. The crystal structure of 4–(4,4,5,5–tetramethyl–1,3,2–dioxaborolan–2–yl)morpholine, C10H20BNO3
  14. The crystal structure of catena–poly[aqua(1-naphthoato-κ 2 O,O′)-(μ-1-naphthoato-κ 4 O:O,O′:O′)lead(II)], C22H16O5Pb
  15. The crystal structure of 1-(4-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  16. The crystal structure of 4-(pyren-1-yl)butyl-4-nitrobenzoate, C27H21NO4
  17. Crystal structure of cyclo-(bis(µ2-3,3′-(1H-imidazole-3-ium-1,3-diyl)dipropionato-κ4 O,O′:O″,O″′)-dinitrato-κ2 O,O′-tetraoxido-diuranium(VI) C18H22N6O18U2
  18. The crystal structure of catena-[nitrato-κ 2 O,O′-(μ 3-3-iodobenzene-1,2-dicarboxylato-κ 4 O:O′:O″,O‴)-(2,2′:6′,2″-terpyridine-κ 3 N,N′,N″)lanthanum(III)], C23H14IN4O7La
  19. Redetermination of crystal structure of [bis(pyridin-2-ylmethyl)amine-κ 3 N,Nʹ,Nʺ]chloridopalladium(II) chloride monohydrate
  20. Crystal structure of catena-poly[triaqua-[bis(m2-4-(1H-1,2,4-triazol-1-yl)benzoato-k2O:O')-(4-(1H-1,2,4-triazol-1-yl)benzoato-k1O)-praseodymium (III) monohydrate], C27H26N9O10Pr
  21. Crystal structure of trans-diaqua-bis(methyl methylcarbamohydrazonothioato-κ2 N,N′) nickel(II) iodide semihydrate, C6H22N6O2NiS2I2·0.5H2O
  22. The crystal structure of 2-(2-fluoro-4-methyl-5-((2,2,2-trifluoroethyl)thio)phenyl)isoindolin-1-one, C17H13F4NOS
  23. The crystal structure of di-μ-1-naphthylacetato-κ 3 O,O′:O;κ 3 O:O,O′-bis[(1-naphthylacetato-κ 2 O,O′)(2,2′-bipyridine-κ 2 N,N′)lead(II)] monohydrate, C68H54N4O9Pb2
  24. Crystal structure of tetrapropylammonium guanidinium 4,4′-sulfonyldibenzoate monohydrate, C27H44N4O7S
  25. Crystal structure of bis(tetrapropylammonium) terephthalate – 1-(diaminomethylene)thiourea – water (1/2/4) C18H40N5O4S
  26. Crystal structure of (E)-7-fluoro-2-(4-morpholinobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C21H20FNO2
  27. The crystal structure of poly[diaqua-bis(μ 3-5-bromobenzene-1,3-dicarboxylato-κ 3 O,O,O′)-(μ 2-1,3-bis-(4-pyridyl)-propane-κ 2 N,N′)-dizinc(II))] – 5-bromobenzene-1,3-dicarboxylic acid [2/1], C37H29Br3N2O14Zn2
  28. The crystal structure of 2-bromo-1,3-phenylene bis(4-methylbenzenesulfonate), C20H17BrO6S2
  29. Crystal structure of europium dichromium icosaaluminum, EuCr2Al20
  30. The crystal structure of N′1,N′3-di((E)-benzylidene) isophthalohydrazide dihydrate, C 22 H 22 N 4 O 4
  31. Crystal structure of 7α,11α-dihydroxy-15-oxo-ent-kauran-16-en-19,6β-olide, C20H26O5
  32. Crystal structure of 4-chloro-N′-[(1E)-pyridin-3-ylmethylidene]benzohydrazide, C13H10ClN3O
  33. The crystal structure of (Z)-3-(1-(2-((E)-4-isopropylbenzylidene)hydrazinyl)ethylidene) chroman-2,4-dione, C21H20N2O3
  34. Crystal structure of E-7-fluoro-2-(2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H12F4O
  35. Crystal structure of bis(6-aminopyridine-2-carboxylato–k2O,N)-bis(N,N-dimethylformamide-k1 O)zinc(II), C18H24N6O6Zn
  36. Crystal structure of 5-(adamantan-1-yl)-3-[(4-{[2-(trifluoromethyl)phenyl]-methyl}piperazin-1-yl)methyl]-1,3,4-oxadiazole-2(3H)-thione, C25H31F3N4OS
  37. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea – water (2/2/1), C30H72N10O7S2
  38. Crystal structure of tris(2,2′-bipyridine-κ2 N,N′)iron(II) triiodide – dichloromethane (2/1), C61H50Cl2Fe2I12N12
  39. Crystal structure of 2-amino-3-[2-(1,3,3-trimethyl-1,3-dihydro-indol-2-ylidene)-ethylideneamino]-but-2-enedinitrile, C17H17N5
  40. The crystal structure of 1-(2-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  41. Crystal structure of potassium bis(pentaselenido-κ 2 Se 1,Se 5)palladate(II), K2[Pd(Se5)2]
  42. The crystal structure of 5,10-bis(2-methoxyethyl)-5,10-dihydro-[1,2,3,4]tetrathiocino[5,6-b:8, 7-b′]diindole, C22H22N2O2S4
  43. The crystal structure of 4-(4-iodophenyl)-5H-1,2,3-dithiazole-5-thione, C8H4INS3
  44. Crystal structure of bis{μ2-(4-acetyl-phenoxy)acetato-κ2 O:O′}-bis{μ2-(4-acetyl-phenoxy)acetato-κ3 O,O′:O)- bis{(4-acetyl-phenoxy)acetato-κ2 O,O′}-bis(phenanthrolin-κ2 N,N′)didysprosium(III) tetrahydrate, C84H78N4O28Dy2
  45. Crystal structure of Eu2Pd3.37(1)Zn13.63(1)
  46. Crystal structure of 2-methoxy-4-(methoxy-carbonyl)phenyl 2-chloro-4-fluorobenzoate, C16H12ClFO5
  47. Crystal structure of catena-poly[bis(μ2-dicyanamide-κ2 N:N′)-bis(4-vinylpyridine-κN)-copper(II)], C18H14CuN8
  48. The crystal structure of iguratimod-dimethylformamide (1/1), C17H14N2O6S·C3H7NO
  49. Synthesis and crystal structure of 1-((3R,10S,13S,17S)-10,13-dimethyl-3-(m-tolylamino)hexadecahydro-1H-cyclopenta[α]phenanthren-17-yl)ethan-1-one, C28H41NO
  50. The crystal structure of diaqua-bis(4-bromo-2-formylphenoxy)zinc(II), C14H12Br2O6Zn
  51. The crystal structure of tetra(1-ethylimidazole-κ 1 N)-[μ 4-imidazole-4,5-dicarboxylato-κ 4 O, N, O′, N′]-trioxido-divanadium, C25H33N10O7V2
  52. The crystal structure of (E)-N′-(1-(4-fluorophenyl)propylidene)-2-hydroxybenzohydrazide, C16H15FN2O2
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