Home The crystal structure of tetra(1-ethylimidazole-κ 1 N)-[μ 4-imidazole-4,5-dicarboxylato-κ 4 O, N, O′, N′]-trioxido-divanadium, C25H33N10O7V2
Article Open Access

The crystal structure of tetra(1-ethylimidazole-κ 1 N)-[μ 4-imidazole-4,5-dicarboxylato-κ 4 O, N, O′, N′]-trioxido-divanadium, C25H33N10O7V2

  • Na Li , Xiao-Jie Wang ORCID logo EMAIL logo , Yu-Cai Qin and Jing-Yun Wang
Published/Copyright: April 14, 2023
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 238 Issue 3

Abstract

C25H33N10O7V2, triclinic, P 1 ‾ (no. 2), a = 10.3933(4) Å, b = 12.5655(5) Å, c = 14.1841(5) Å, α = 65.373(1)°, β =  70.351 ( 1 ) ∘ , γ =  88.052 ( 2 ) ∘ , V = 1573.62(11) Å3, Z = 2, R gt (F) = 0.0362, wR ref (F 2) = 0.0885, T = 173 K.

CCDC no.: 2251358

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Purple block
Size: 0.26 × 0.18 × 0.12 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.65 mm−1
Diffractometer, scan mode: φ and ω
θ max, completeness: 25.4°, 99%
N(hkl)measured, N(hkl)unique, R int: 13,171, 5733, 0.038
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 4326
N(param)refined: 441
Programs: Bruker [1], Olex2 [2], SHELX [3, 4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.2837 (3) 0.8382 (2) 0.56417 (19) 0.0217 (6)
H1 0.304385 0.921621 0.526685 0.026*
C2 0.2237 (3) 0.6562 (2) 0.60165 (19) 0.0182 (5)
C3 0.2558 (3) 0.6569 (2) 0.68855 (19) 0.0191 (5)
C4 0.1891 (2) 0.5672 (2) 0.56758 (19) 0.0179 (5)
C5 0.2755 (3) 0.5708 (2) 0.79107 (19) 0.0200 (6)
C6 0.6149 (3) 0.8189 (3) 0.8402 (2) 0.0347 (7)
H6 0.646550 0.895157 0.780268 0.042*
C7 0.5999 (3) 0.6589 (3) 0.9882 (2) 0.0344 (7)
H7 0.617384 0.601812 1.050696 0.041*
C8 0.4974 (3) 0.6493 (2) 0.9532 (2) 0.0278 (6)
H8 0.429060 0.583195 0.987680 0.033*
C11 0.5331 (3) 0.8559 (2) 0.3084 (2) 0.0233 (6)
H11 0.522576 0.921362 0.326391 0.028*
C12 0.6280 (3) 0.7207 (2) 0.2579 (2) 0.0312 (7)
H12 0.693193 0.673448 0.235017 0.037*
C13 0.4910 (3) 0.7083 (3) 0.2788 (2) 0.0304 (7)
H13 0.443460 0.650278 0.271836 0.036*
C14 0.7885 (3) 0.8590 (3) 0.2671 (2) 0.0357 (7)
H14A 0.826470 0.793323 0.314290 0.043*
H14B 0.776768 0.920251 0.295134 0.043*
C15 0.8896 (3) 0.9106 (3) 0.1490 (3) 0.0454 (8)
H15A 0.900830 0.850571 0.120654 0.068*
H15B 0.978668 0.936338 0.147234 0.068*
H15C 0.854659 0.978313 0.102740 0.068*
C16 0.1187 (3) 0.7002 (3) 0.2434 (2) 0.0286 (6)
H16 0.051046 0.642482 0.307502 0.034*
C17 0.2464 (3) 0.8057 (3) 0.0699 (2) 0.0304 (7)
H17 0.285718 0.835845 −0.008517 0.036*
C18 0.2815 (3) 0.8445 (3) 0.1346 (2) 0.0296 (7)
H18 0.350260 0.908074 0.108818 0.035*
C21 −0.0872 (3) 0.6773 (2) 0.5116 (2) 0.0243 (6)
H21 −0.064010 0.603493 0.511737 0.029*
C22 −0.2066 (3) 0.8131 (3) 0.5446 (3) 0.0386 (8)
H22 −0.280223 0.851901 0.571493 0.046*
C23 −0.0753 (3) 0.8617 (3) 0.4795 (2) 0.0312 (7)
H23 −0.040789 0.941996 0.452220 0.037*
C24 −0.3350 (3) 0.6078 (3) 0.6257 (2) 0.0380 (8)
H24A −0.391693 0.618163 0.692279 0.046*
H24B −0.305735 0.527927 0.650840 0.046*
C25 −0.4202 (3) 0.6173 (3) 0.5567 (3) 0.0462 (9)
H25A −0.453423 0.694739 0.534922 0.069*
H25B −0.498874 0.555272 0.599840 0.069*
H25C −0.364034 0.608123 0.490169 0.069*
N1 0.2938 (2) 0.77216 (18) 0.66340 (16) 0.0205 (5)
N2 0.2412 (2) 0.77246 (18) 0.52482 (16) 0.0199 (5)
N3 0.5071 (2) 0.75076 (18) 0.85937 (17) 0.0232 (5)
N4 0.6742 (3) 0.7673 (2) 0.9157 (2) 0.0371 (6)
N5 0.4308 (2) 0.79277 (19) 0.31190 (17) 0.0225 (5)
N6 0.6537 (2) 0.8153 (2) 0.27624 (18) 0.0256 (5)
N7 0.2010 (2) 0.77671 (19) 0.24488 (16) 0.0231 (5)
N8 0.1429 (2) 0.7144 (2) 0.13961 (18) 0.0304 (6)
N9 0.0011 (2) 0.77588 (18) 0.45882 (16) 0.0214 (5)
N10 −0.2126 (2) 0.6962 (2) 0.56419 (19) 0.0307 (6)
O1 0.19169 (17) 0.61322 (15) 0.46655 (13) 0.0194 (4)
O2 0.16089 (19) 0.46137 (15) 0.63101 (14) 0.0258 (4)
O3 0.2392 (2) 0.46473 (16) 0.83405 (15) 0.0293 (5)
O4 0.33995 (19) 0.62254 (15) 0.82895 (14) 0.0253 (4)
O5 0.27083 (19) 0.86327 (17) 0.82264 (14) 0.0274 (4)
O6 0.50398 (19) 0.89838 (15) 0.65755 (13) 0.0243 (4)
O7 0.22472 (19) 0.94104 (16) 0.33137 (14) 0.0260 (4)
V1 0.38325 (4) 0.79850 (4) 0.76216 (3) 0.01819 (12)
V2 0.21698 (4) 0.80033 (4) 0.37792 (3) 0.01870 (12)
C9a 0.7945 (14) 0.828 (2) 0.915 (2) 0.054 (5)
H9Aa 0.782259 0.814432 0.992014 0.064*
H9Ba 0.803103 0.913690 0.869643 0.064*
C10a 0.9231 (11) 0.7787 (17) 0.869 (2) 0.067 (4)
H10Aa 0.913741 0.693559 0.914111 0.100*
H10Ba 1.003205 0.817352 0.868860 0.100*
H10Ca 0.935582 0.793521 0.792310 0.100*
C9′b 0.8064 (12) 0.8059 (19) 0.9178 (17) 0.057 (4)
H9′Ab 0.821092 0.748200 0.985421 0.068*
H9′Bb 0.801139 0.883130 0.921248 0.068*
C10′b 0.9264 (8) 0.8169 (13) 0.8177 (14) 0.070 (3)
H10Db 0.936384 0.739270 0.817106 0.106*
H10Eb 1.010527 0.846865 0.819975 0.106*
H10Fb 0.910566 0.871599 0.750421 0.106*
C19c 0.049 (2) 0.6577 (19) 0.110 (2) 0.030 (4)
H19Ac 0.045447 0.712126 0.036463 0.036*
H19Bc −0.044885 0.638786 0.165483 0.036*
C20c 0.1041 (19) 0.5449 (18) 0.105 (2) 0.048 (4)
H20Ac 0.199977 0.563442 0.054481 0.071*
H20Bc 0.048262 0.510366 0.079031 0.071*
H20Cc 0.099066 0.488426 0.179660 0.071*
C19′d 0.0823 (16) 0.6386 (13) 0.1056 (14) 0.046 (3)
H19Cd 0.117168 0.672550 0.023611 0.055*
H19Dd −0.018800 0.638803 0.131127 0.055*
C20′d 0.1133 (14) 0.5134 (9) 0.1501 (12) 0.058 (3)
H20Dd 0.213124 0.512054 0.123949 0.087*
H20Ed 0.070160 0.468308 0.124163 0.087*
H20Fd 0.076723 0.478170 0.231400 0.087*

  1. aOccupancy: 0.44 (3), bOccupancy: 0.56 (3), cOccupancy: 0.35 (3), dOccupancy: 0.65 (3).

1 Source of materials

NH4VO3 (0.34 g, 2 mmol), VO(acac)2 (0.265 g, 1 mmol), 4,5-imidazoledicarboxylic acid (0.16 g, 1 mmol) in 7 mL N-ethylimidazole was sealed in a 25 mL Teflon-lined stainless steel autoclave and was heated under autogenous pressure at 120 °C for 4320 min and then cooled to room temperature. Purple block crystals were collected.

2 Experimental details

The structure was solved by Direct Methods with the SHELXS-2018 program. All H-atoms from C and N atoms were positioned with idealized geometry and refined isotropically (U iso(H) = 1.2U eq(C)) using a riding model with C–H = 0.930Å. The C9, C10 and C19, C20 atoms of ethyl group are processed with PART [3] instruction.

3 Comment

The coordination chemistry of vanadium has developed rapidly, especially in the organic catalysis and biological activity [5], [6], [7], [8], [9]. In fact, the vanadium can display a variety of coordination numbers (such as 4, tetrahedron; 5, square-pyramid or trigonal bipyramid; 6, octahedron) and a wide range of the accessible oxidation states from +5 to +2, which greatly enriched the structural types of vanadium complexes [10], [11], [12]. On the other hand, the complex coordination number and oxidation states pose an extremely challenge for precise synthesis of target products [13], [14], [15]. So it is highly desirable to develop a controllable synthesis of vanadium complexes. In this text, we provide a simple one-pot method for preparing a dinuclear vanadium coordination compound. Single crystal X-ray diffraction shows that the title compound has two independent vanadium atoms V1 and V2, which adopted entirely different coordination modes. The coordination of V1 can be seen as tetragonal pyramid, which is completed by two N atoms and one O atom from one N-ethylimidazole and 4,5-imidazoledicarboxylic acid, respectively, and two V=O double bonds. The V2 has a distorted octahedron and the equatorial plane contains four N atoms from three N-ethylimidazole and 4,5-imidazoledicarboxylic acid, respectively, and the two vertexes are two O atoms. 4,5-imidazoledicarboxylate anion is a tetradentate-bridge for two vanadium atoms.

Corresponding author: Xiao-Jie Wang, School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun, Liaoning Province 113001, P.R. China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: Liaoning Revitalization Talents Program (XLYC2007130), and Talent Scientific Research Fund of Liaoning Petrochemical University (2016XJJL-019).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. SAINT v8.40A; Bruker AXS Inc: Madison, Wisconsin, USA, 2016.Search in Google Scholar

2. Bourhis, L. J., Dolomanov, O. V., Gildea, R. J., Howard, J. A. K., Puschmann, H. The anatomy of a comprehensive constrained, restrained refinement program for the modern computing environment—Olex2 dissected. Acta Crystallogr. 2015, A71, 59–75; https://doi.org/10.1107/s2053273314022207.Search in Google Scholar PubMed PubMed Central

3. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar PubMed PubMed Central

4. Sheldrick, G. Using phases to determine the space group. Acta Crystallogr. 2018, A74, a353; https://doi.org/10.1107/s0108767318096472.Search in Google Scholar

5. Masayuki, K. Aerobic oxidation of organic compounds catalyzed by vanadium compounds. Coord. Chem. Rev. 2011, 255, 2281–2302; https://doi.org/10.1016/j.ccr.2011.04.001.Search in Google Scholar

6. Chen, B.-K., Huang, X.-Q., Wang, B., Lin, Z.-G., Hu, J.-F., Chi, Y.-N., Hu, C.-W. Three new imidazole-functionalized hexanuclear oxidovanadium clusters with exceptional catalytic oxidation properties for alcohols. Chem. Eur J. 2013, 19, 4408–4413; https://doi.org/10.1002/chem.201203854.Search in Google Scholar PubMed

7. Liu, D., Chen, B.-K., Li, J., Lin, Z.-G., Li, P.-H., Zhen, N., Chi, Y.-N., Hu, C.-W. Imidazole-functionalized polyoxometalate catalysts for the oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran using atmospheric O2. Inorg. Chem. 2021, 60, 3909–3916; https://doi.org/10.1021/acs.inorgchem.0c03698.Search in Google Scholar PubMed

8. Manas, S., Martins, L.-M., Silvaa, F.-C., Pombeiro, A.-J. Vanadium complexes: recent progress in oxidation catalysis. Coord. Chem. Rev. 2015, 301, 200–239; https://doi.org/10.1016/j.ccr.2015.01.020.Search in Google Scholar

9. Langeslay, R.-R., Kaphan, D.-M., Marshall, C.-L., Stair, P.-C., Sattelberger, A.-P., Delferro, M. Catalytic applications of vanadium: a mechanistic perspective. Chem. Rev. 2019, 119, 2128–2191; https://doi.org/10.1021/acs.chemrev.8b00245.Search in Google Scholar PubMed

10. Zhang, G., Luan, J., Wang, X.-J. The crystal structure of tetra(1-methylimidazole-κ1 N)-(sulfate-κ1 O)vanadate, C16H24N8O5SV. Z. Kristallogr. N. Cryst. Struct. 2020, 235, 1295–1296; https://doi.org/10.1515/ncrs-2020-0276.Search in Google Scholar

11. Griffin, S.-E., Adamczyk, O.-V., Schafer, L.-L. Vanadium pyridonates: dimerization, redox behaviour, and metal-ligand cooperativity. Dalton Trans. 2022, 51, 14654–14663; https://doi.org/10.1039/d2dt02177c.Search in Google Scholar PubMed

12. Antonova, E., Seidlhofer, B., Wang, J., Hinz, M., Bensch, W. Controlling nucleation and crystal growth of a distinct polyoxovanadate cluster: an in situ energy dispersive X-ray diffraction study under solvothermal conditions. Chem. Eur J. 2012, 18, 15316–15322; https://doi.org/10.1002/chem.201202107.Search in Google Scholar PubMed

13. Aureliano, M., Fraqueza, G., Ohlin, C.-A. Ion pumps as biological targets for decavanadate. Dalton Trans. 2013, 42, 11770–11777; https://doi.org/10.1039/c3dt50462j.Search in Google Scholar PubMed

14. Hu, X.-K., Wang, H., Huang, B., Li, N., Hu, K.-H., Wu, B.-L., Xiao, Z.-C., Wei, Y.-G., Wu, P.-F. A new scheme for rational design and synthesis of polyoxovanadate hybrids with high antitumor activities. J. Inorg. Biochem. 2019, 193, 130–132; https://doi.org/10.1016/j.jinorgbio.2019.01.013.Search in Google Scholar PubMed

15. Dankhoff, K., Ahmad, A., Weber, B., Biersack, B., Schobert, R. Anticancer properties of a new non-oxido vanadium(IV) complex with a catechol-modified 3,3′-diindolylmethane ligand. J. Inorg. Biochem. 2019, 1943, 1–6; https://doi.org/10.1016/j.jinorgbio.2019.02.005.Search in Google Scholar PubMed

Received: 2023-03-10
Accepted: 2023-03-24
Published Online: 2023-04-14
Published in Print: 2023-06-27

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of phenyl(3,3-dichloro-1,3-dihydro-2H-pyrrolo[2,3-b]pyridin-2-one)methanone, C7H4Cl2N2O
  4. Crystal structure of poly[diaqua-bis(μ 2-1,4-diaminobutane-N:N′)cobalt(II)] dichloride, C8H28Cl2CoN4O2
  5. Synthesis and crystal structure of (4aR,7S)-7-hydroxy-7-isopropyl-1,1-dimethyldecahydro-2H,6H-8a,4a-(epoxymethano)phenanthren-12-one, C20H32O3
  6. The crystal structure of 1-(2-chlorobenzyl)-3-(3,5-dichlorophenyl)urea, C14H11Cl3N2O
  7. Crystal structure of tetrapropylammonium-1,3,5-thiadiazole-5-amido-2-carbamate – 1,2,4-thiadiazole-3,5-diamine – water (1/1/1), C17H37N9O3S2
  8. Tetrabutylammonium 1,3,5-thiadiazole-5-amido-2-carbamate—1,2,4-thiadiazole-3,5-diamine— water (1/1/1), C21H45N9O3S2
  9. The crystal structure of ((E)-2,4-dichloro-6-(((2-hydroxy-5-nitrophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Cl2MnN5O4
  10. The crystal structure of aqua-bis{2-bromo-6-((2-(2-phenylacetyl)hydrazineylidene)methyl)phenolato-κ3 N,O,O′}-dimethylformamide-κ1 O-erbium(III) chloride – dimethylformamide – water (1/2/1), C39H49N7O9Br2ClEr
  11. Crystal structure of (diaqua-bis(phenanthroline-K 2 N,N′)-tetrakis(m 2-3,4,5,6-tetrafluorophthalato-K 4 O,O:O′:O″;K 2 O:O′)dierbium (III) phenanthroline (1/2), C80H38Er2F16N8O18
  12. Crystal structure of (E)-7-methoxy-2-(4-methoxy-2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C20H17F3O3
  13. The crystal structure of 4–(4,4,5,5–tetramethyl–1,3,2–dioxaborolan–2–yl)morpholine, C10H20BNO3
  14. The crystal structure of catena–poly[aqua(1-naphthoato-κ 2 O,O′)-(μ-1-naphthoato-κ 4 O:O,O′:O′)lead(II)], C22H16O5Pb
  15. The crystal structure of 1-(4-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  16. The crystal structure of 4-(pyren-1-yl)butyl-4-nitrobenzoate, C27H21NO4
  17. Crystal structure of cyclo-(bis(µ2-3,3′-(1H-imidazole-3-ium-1,3-diyl)dipropionato-κ4 O,O′:O″,O″′)-dinitrato-κ2 O,O′-tetraoxido-diuranium(VI) C18H22N6O18U2
  18. The crystal structure of catena-[nitrato-κ 2 O,O′-(μ 3-3-iodobenzene-1,2-dicarboxylato-κ 4 O:O′:O″,O‴)-(2,2′:6′,2″-terpyridine-κ 3 N,N′,N″)lanthanum(III)], C23H14IN4O7La
  19. Redetermination of crystal structure of [bis(pyridin-2-ylmethyl)amine-κ 3 N,Nʹ,Nʺ]chloridopalladium(II) chloride monohydrate
  20. Crystal structure of catena-poly[triaqua-[bis(m2-4-(1H-1,2,4-triazol-1-yl)benzoato-k2O:O')-(4-(1H-1,2,4-triazol-1-yl)benzoato-k1O)-praseodymium (III) monohydrate], C27H26N9O10Pr
  21. Crystal structure of trans-diaqua-bis(methyl methylcarbamohydrazonothioato-κ2 N,N′) nickel(II) iodide semihydrate, C6H22N6O2NiS2I2·0.5H2O
  22. The crystal structure of 2-(2-fluoro-4-methyl-5-((2,2,2-trifluoroethyl)thio)phenyl)isoindolin-1-one, C17H13F4NOS
  23. The crystal structure of di-μ-1-naphthylacetato-κ 3 O,O′:O;κ 3 O:O,O′-bis[(1-naphthylacetato-κ 2 O,O′)(2,2′-bipyridine-κ 2 N,N′)lead(II)] monohydrate, C68H54N4O9Pb2
  24. Crystal structure of tetrapropylammonium guanidinium 4,4′-sulfonyldibenzoate monohydrate, C27H44N4O7S
  25. Crystal structure of bis(tetrapropylammonium) terephthalate – 1-(diaminomethylene)thiourea – water (1/2/4) C18H40N5O4S
  26. Crystal structure of (E)-7-fluoro-2-(4-morpholinobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C21H20FNO2
  27. The crystal structure of poly[diaqua-bis(μ 3-5-bromobenzene-1,3-dicarboxylato-κ 3 O,O,O′)-(μ 2-1,3-bis-(4-pyridyl)-propane-κ 2 N,N′)-dizinc(II))] – 5-bromobenzene-1,3-dicarboxylic acid [2/1], C37H29Br3N2O14Zn2
  28. The crystal structure of 2-bromo-1,3-phenylene bis(4-methylbenzenesulfonate), C20H17BrO6S2
  29. Crystal structure of europium dichromium icosaaluminum, EuCr2Al20
  30. The crystal structure of N′1,N′3-di((E)-benzylidene) isophthalohydrazide dihydrate, C 22 H 22 N 4 O 4
  31. Crystal structure of 7α,11α-dihydroxy-15-oxo-ent-kauran-16-en-19,6β-olide, C20H26O5
  32. Crystal structure of 4-chloro-N′-[(1E)-pyridin-3-ylmethylidene]benzohydrazide, C13H10ClN3O
  33. The crystal structure of (Z)-3-(1-(2-((E)-4-isopropylbenzylidene)hydrazinyl)ethylidene) chroman-2,4-dione, C21H20N2O3
  34. Crystal structure of E-7-fluoro-2-(2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H12F4O
  35. Crystal structure of bis(6-aminopyridine-2-carboxylato–k2O,N)-bis(N,N-dimethylformamide-k1 O)zinc(II), C18H24N6O6Zn
  36. Crystal structure of 5-(adamantan-1-yl)-3-[(4-{[2-(trifluoromethyl)phenyl]-methyl}piperazin-1-yl)methyl]-1,3,4-oxadiazole-2(3H)-thione, C25H31F3N4OS
  37. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea – water (2/2/1), C30H72N10O7S2
  38. Crystal structure of tris(2,2′-bipyridine-κ2 N,N′)iron(II) triiodide – dichloromethane (2/1), C61H50Cl2Fe2I12N12
  39. Crystal structure of 2-amino-3-[2-(1,3,3-trimethyl-1,3-dihydro-indol-2-ylidene)-ethylideneamino]-but-2-enedinitrile, C17H17N5
  40. The crystal structure of 1-(2-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  41. Crystal structure of potassium bis(pentaselenido-κ 2 Se 1,Se 5)palladate(II), K2[Pd(Se5)2]
  42. The crystal structure of 5,10-bis(2-methoxyethyl)-5,10-dihydro-[1,2,3,4]tetrathiocino[5,6-b:8, 7-b′]diindole, C22H22N2O2S4
  43. The crystal structure of 4-(4-iodophenyl)-5H-1,2,3-dithiazole-5-thione, C8H4INS3
  44. Crystal structure of bis{μ2-(4-acetyl-phenoxy)acetato-κ2 O:O′}-bis{μ2-(4-acetyl-phenoxy)acetato-κ3 O,O′:O)- bis{(4-acetyl-phenoxy)acetato-κ2 O,O′}-bis(phenanthrolin-κ2 N,N′)didysprosium(III) tetrahydrate, C84H78N4O28Dy2
  45. Crystal structure of Eu2Pd3.37(1)Zn13.63(1)
  46. Crystal structure of 2-methoxy-4-(methoxy-carbonyl)phenyl 2-chloro-4-fluorobenzoate, C16H12ClFO5
  47. Crystal structure of catena-poly[bis(μ2-dicyanamide-κ2 N:N′)-bis(4-vinylpyridine-κN)-copper(II)], C18H14CuN8
  48. The crystal structure of iguratimod-dimethylformamide (1/1), C17H14N2O6S·C3H7NO
  49. Synthesis and crystal structure of 1-((3R,10S,13S,17S)-10,13-dimethyl-3-(m-tolylamino)hexadecahydro-1H-cyclopenta[α]phenanthren-17-yl)ethan-1-one, C28H41NO
  50. The crystal structure of diaqua-bis(4-bromo-2-formylphenoxy)zinc(II), C14H12Br2O6Zn
  51. The crystal structure of tetra(1-ethylimidazole-κ 1 N)-[μ 4-imidazole-4,5-dicarboxylato-κ 4 O, N, O′, N′]-trioxido-divanadium, C25H33N10O7V2
  52. The crystal structure of (E)-N′-(1-(4-fluorophenyl)propylidene)-2-hydroxybenzohydrazide, C16H15FN2O2
https://doi.org/10.1515/ncrs-2023-0110
Creative Commons
BY 4.0

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of phenyl(3,3-dichloro-1,3-dihydro-2H-pyrrolo[2,3-b]pyridin-2-one)methanone, C7H4Cl2N2O
  4. Crystal structure of poly[diaqua-bis(μ 2-1,4-diaminobutane-N:N′)cobalt(II)] dichloride, C8H28Cl2CoN4O2
  5. Synthesis and crystal structure of (4aR,7S)-7-hydroxy-7-isopropyl-1,1-dimethyldecahydro-2H,6H-8a,4a-(epoxymethano)phenanthren-12-one, C20H32O3
  6. The crystal structure of 1-(2-chlorobenzyl)-3-(3,5-dichlorophenyl)urea, C14H11Cl3N2O
  7. Crystal structure of tetrapropylammonium-1,3,5-thiadiazole-5-amido-2-carbamate – 1,2,4-thiadiazole-3,5-diamine – water (1/1/1), C17H37N9O3S2
  8. Tetrabutylammonium 1,3,5-thiadiazole-5-amido-2-carbamate—1,2,4-thiadiazole-3,5-diamine— water (1/1/1), C21H45N9O3S2
  9. The crystal structure of ((E)-2,4-dichloro-6-(((2-hydroxy-5-nitrophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Cl2MnN5O4
  10. The crystal structure of aqua-bis{2-bromo-6-((2-(2-phenylacetyl)hydrazineylidene)methyl)phenolato-κ3 N,O,O′}-dimethylformamide-κ1 O-erbium(III) chloride – dimethylformamide – water (1/2/1), C39H49N7O9Br2ClEr
  11. Crystal structure of (diaqua-bis(phenanthroline-K 2 N,N′)-tetrakis(m 2-3,4,5,6-tetrafluorophthalato-K 4 O,O:O′:O″;K 2 O:O′)dierbium (III) phenanthroline (1/2), C80H38Er2F16N8O18
  12. Crystal structure of (E)-7-methoxy-2-(4-methoxy-2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C20H17F3O3
  13. The crystal structure of 4–(4,4,5,5–tetramethyl–1,3,2–dioxaborolan–2–yl)morpholine, C10H20BNO3
  14. The crystal structure of catena–poly[aqua(1-naphthoato-κ 2 O,O′)-(μ-1-naphthoato-κ 4 O:O,O′:O′)lead(II)], C22H16O5Pb
  15. The crystal structure of 1-(4-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  16. The crystal structure of 4-(pyren-1-yl)butyl-4-nitrobenzoate, C27H21NO4
  17. Crystal structure of cyclo-(bis(µ2-3,3′-(1H-imidazole-3-ium-1,3-diyl)dipropionato-κ4 O,O′:O″,O″′)-dinitrato-κ2 O,O′-tetraoxido-diuranium(VI) C18H22N6O18U2
  18. The crystal structure of catena-[nitrato-κ 2 O,O′-(μ 3-3-iodobenzene-1,2-dicarboxylato-κ 4 O:O′:O″,O‴)-(2,2′:6′,2″-terpyridine-κ 3 N,N′,N″)lanthanum(III)], C23H14IN4O7La
  19. Redetermination of crystal structure of [bis(pyridin-2-ylmethyl)amine-κ 3 N,Nʹ,Nʺ]chloridopalladium(II) chloride monohydrate
  20. Crystal structure of catena-poly[triaqua-[bis(m2-4-(1H-1,2,4-triazol-1-yl)benzoato-k2O:O')-(4-(1H-1,2,4-triazol-1-yl)benzoato-k1O)-praseodymium (III) monohydrate], C27H26N9O10Pr
  21. Crystal structure of trans-diaqua-bis(methyl methylcarbamohydrazonothioato-κ2 N,N′) nickel(II) iodide semihydrate, C6H22N6O2NiS2I2·0.5H2O
  22. The crystal structure of 2-(2-fluoro-4-methyl-5-((2,2,2-trifluoroethyl)thio)phenyl)isoindolin-1-one, C17H13F4NOS
  23. The crystal structure of di-μ-1-naphthylacetato-κ 3 O,O′:O;κ 3 O:O,O′-bis[(1-naphthylacetato-κ 2 O,O′)(2,2′-bipyridine-κ 2 N,N′)lead(II)] monohydrate, C68H54N4O9Pb2
  24. Crystal structure of tetrapropylammonium guanidinium 4,4′-sulfonyldibenzoate monohydrate, C27H44N4O7S
  25. Crystal structure of bis(tetrapropylammonium) terephthalate – 1-(diaminomethylene)thiourea – water (1/2/4) C18H40N5O4S
  26. Crystal structure of (E)-7-fluoro-2-(4-morpholinobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C21H20FNO2
  27. The crystal structure of poly[diaqua-bis(μ 3-5-bromobenzene-1,3-dicarboxylato-κ 3 O,O,O′)-(μ 2-1,3-bis-(4-pyridyl)-propane-κ 2 N,N′)-dizinc(II))] – 5-bromobenzene-1,3-dicarboxylic acid [2/1], C37H29Br3N2O14Zn2
  28. The crystal structure of 2-bromo-1,3-phenylene bis(4-methylbenzenesulfonate), C20H17BrO6S2
  29. Crystal structure of europium dichromium icosaaluminum, EuCr2Al20
  30. The crystal structure of N′1,N′3-di((E)-benzylidene) isophthalohydrazide dihydrate, C 22 H 22 N 4 O 4
  31. Crystal structure of 7α,11α-dihydroxy-15-oxo-ent-kauran-16-en-19,6β-olide, C20H26O5
  32. Crystal structure of 4-chloro-N′-[(1E)-pyridin-3-ylmethylidene]benzohydrazide, C13H10ClN3O
  33. The crystal structure of (Z)-3-(1-(2-((E)-4-isopropylbenzylidene)hydrazinyl)ethylidene) chroman-2,4-dione, C21H20N2O3
  34. Crystal structure of E-7-fluoro-2-(2-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H12F4O
  35. Crystal structure of bis(6-aminopyridine-2-carboxylato–k2O,N)-bis(N,N-dimethylformamide-k1 O)zinc(II), C18H24N6O6Zn
  36. Crystal structure of 5-(adamantan-1-yl)-3-[(4-{[2-(trifluoromethyl)phenyl]-methyl}piperazin-1-yl)methyl]-1,3,4-oxadiazole-2(3H)-thione, C25H31F3N4OS
  37. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea – water (2/2/1), C30H72N10O7S2
  38. Crystal structure of tris(2,2′-bipyridine-κ2 N,N′)iron(II) triiodide – dichloromethane (2/1), C61H50Cl2Fe2I12N12
  39. Crystal structure of 2-amino-3-[2-(1,3,3-trimethyl-1,3-dihydro-indol-2-ylidene)-ethylideneamino]-but-2-enedinitrile, C17H17N5
  40. The crystal structure of 1-(2-chlorophenyl)-3-cycloheptylurea, C14H19ClN2O
  41. Crystal structure of potassium bis(pentaselenido-κ 2 Se 1,Se 5)palladate(II), K2[Pd(Se5)2]
  42. The crystal structure of 5,10-bis(2-methoxyethyl)-5,10-dihydro-[1,2,3,4]tetrathiocino[5,6-b:8, 7-b′]diindole, C22H22N2O2S4
  43. The crystal structure of 4-(4-iodophenyl)-5H-1,2,3-dithiazole-5-thione, C8H4INS3
  44. Crystal structure of bis{μ2-(4-acetyl-phenoxy)acetato-κ2 O:O′}-bis{μ2-(4-acetyl-phenoxy)acetato-κ3 O,O′:O)- bis{(4-acetyl-phenoxy)acetato-κ2 O,O′}-bis(phenanthrolin-κ2 N,N′)didysprosium(III) tetrahydrate, C84H78N4O28Dy2
  45. Crystal structure of Eu2Pd3.37(1)Zn13.63(1)
  46. Crystal structure of 2-methoxy-4-(methoxy-carbonyl)phenyl 2-chloro-4-fluorobenzoate, C16H12ClFO5
  47. Crystal structure of catena-poly[bis(μ2-dicyanamide-κ2 N:N′)-bis(4-vinylpyridine-κN)-copper(II)], C18H14CuN8
  48. The crystal structure of iguratimod-dimethylformamide (1/1), C17H14N2O6S·C3H7NO
  49. Synthesis and crystal structure of 1-((3R,10S,13S,17S)-10,13-dimethyl-3-(m-tolylamino)hexadecahydro-1H-cyclopenta[α]phenanthren-17-yl)ethan-1-one, C28H41NO
  50. The crystal structure of diaqua-bis(4-bromo-2-formylphenoxy)zinc(II), C14H12Br2O6Zn
  51. The crystal structure of tetra(1-ethylimidazole-κ 1 N)-[μ 4-imidazole-4,5-dicarboxylato-κ 4 O, N, O′, N′]-trioxido-divanadium, C25H33N10O7V2
  52. The crystal structure of (E)-N′-(1-(4-fluorophenyl)propylidene)-2-hydroxybenzohydrazide, C16H15FN2O2
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 29.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2023-0110/html
Scroll to top button