Abstract
C25H23N7O, monoclinic, P21/c (no. 14), a = 12.2755(4) Å, b = 6.2753(2) Å, c = 30.3790(8) Å, β = 112.475(2)°, V = 2162.42(12) Å3, Z = 4, Rgt(F) = 0.0520, wRref(F2) = 0.1619, T = 293 K.
The crystal structure is shown in the figure. Tables 1–3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.
Data collection and handling.
Crystal: | Yellow, plate, size 0.08×0.314×0.476 mm |
Wavelength: | Cu Kα radiation (1.54178 Å) |
μ: | 6.99 cm−1 |
Diffractometer, scan mode: | Bruker APEX-II CCD, φ and ω scans |
2θmax: | 139.73° |
N(hkl)measured, N(hkl)unique: | 14431, 3960 |
N(param)refined: | 299 |
Programs: | SHELX [8] |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).
Atom | Site | x | y | z | Uiso |
---|---|---|---|---|---|
H(1) | 4e | −0.6136 | −1.1022 | −0.7335 | 0.079 |
H(4) | 4e | −0.6611 | −0.9932 | −0.7791 | 0.079 |
H(2) | 4e | −0.2020 | −1.0901 | −0.4479 | 0.080 |
H(3) | 4e | −0.1408 | −0.9741 | −0.4007 | 0.080 |
H(1A) | 4e | −0.8236 | −0.3584 | −0.7855 | 0.068 |
H(2A) | 4e | −0.9162 | −0.2688 | −0.8654 | 0.081 |
H(3A) | 4e | −0.8558 | −0.4192 | −0.9213 | 0.086 |
H(4A) | 4e | −0.6989 | −0.6524 | −0.8979 | 0.079 |
H(5A) | 4e | −0.6028 | −0.7391 | −0.8183 | 0.066 |
H(8A) | 4e | −0.5135 | −0.8661 | −0.6533 | 0.060 |
H(11A) | 4e | −0.6354 | −0.1745 | −0.6493 | 0.062 |
H(12A) | 4e | −0.5752 | −0.0029 | −0.5759 | 0.065 |
H(13A) | 4e | −0.4398 | −0.1705 | −0.5093 | 0.062 |
H(16A) | 4e | −0.3225 | −0.8600 | −0.5258 | 0.061 |
H(19A) | 4e | −0.0057 | −0.7339 | −0.3738 | 0.067 |
H(20A) | 4e | 0.0950 | −0.6474 | −0.2942 | 0.076 |
H(21A) | 4e | 0.0175 | −0.4045 | −0.2573 | 0.079 |
H(22A) | 4e | −0.1623 | −0.2458 | −0.3000 | 0.074 |
H(23A) | 4e | −0.2666 | −0.3384 | −0.3787 | 0.064 |
H(24A) | 4e | 0.1117 | −0.5872 | −0.4238 | 0.125 |
H(24C) | 4e | 0.1507 | −0.4449 | −0.4577 | 0.125 |
H(25A) | 4e | 0.0096 | −0.2182 | −0.5126 | 0.102 |
H(25B) | 4e | −0.1195 | −0.2128 | −0.5140 | 0.102 |
Fractional coordinates and atomic displacement parameters (Å2).
Atom | Site | x | y | z | U11 | U22 | U33 | U12 | U13 | U23 |
---|---|---|---|---|---|---|---|---|---|---|
N(1) | 4e | −0.6245(2) | −0.9865(3) | −0.75060(6) | 0.100(2) | 0.036(1) | 0.048(1) | 0.001(1) | 0.011(1) | −0.0015(8) |
N(2) | 4e | −0.6458(2) | −0.6087(3) | −0.74526(6) | 0.0559(9) | 0.0346(9) | 0.0390(8) | 0.0002(7) | 0.0082(7) | −0.0005(6) |
N(3) | 4e | −0.6221(2) | −0.4488(3) | −0.71170(6) | 0.0596(9) | 0.036(1) | 0.0408(9) | −0.0005(7) | 0.0105(7) | −0.0025(7) |
N(4) | 4e | −0.4518(2) | −0.5317(3) | −0.58683(5) | 0.0556(9) | 0.042(1) | 0.0394(8) | −0.0032(7) | 0.0115(7) | −0.0009(7) |
N(5) | 4e | −0.2830(2) | −0.4472(3) | −0.46202(6) | 0.0570(9) | 0.039(1) | 0.0415(9) | −0.0011(7) | 0.0099(7) | 0.0002(7) |
N(6) | 4e | −0.2133(2) | −0.6012(3) | −0.43220(6) | 0.0579(9) | 0.038(1) | 0.0413(9) | −0.0023(7) | 0.0115(7) | 0.0001(7) |
N(7) | 4e | −0.1667(2) | −0.9742(3) | −0.43281(7) | 0.086(1) | 0.042(1) | 0.056(1) | 0.004(1) | 0.010(1) | −0.0012(8) |
C(1) | 4e | −0.7980(2) | −0.4168(4) | −0.80800(8) | 0.061(1) | 0.046(1) | 0.050(1) | 0.007(1) | 0.008(1) | −0.0047(9) |
C(2) | 4e | −0.8537(2) | −0.3647(4) | −0.85588(8) | 0.072(1) | 0.053(1) | 0.055(1) | 0.013(1) | −0.001(1) | 0.003(1) |
C(3) | 4e | −0.8173(2) | −0.4533(4) | −0.88929(8) | 0.089(2) | 0.061(2) | 0.043(1) | 0.008(1) | 0.001(1) | 0.005(1) |
C(4) | 4e | −0.7237(2) | −0.5929(4) | −0.87523(8) | 0.076(2) | 0.071(2) | 0.043(1) | 0.003(1) | 0.015(1) | −0.001(1) |
C(5) | 4e | −0.6662(2) | −0.6452(4) | −0.82769(7) | 0.056(1) | 0.056(1) | 0.047(1) | 0.001(1) | 0.0117(9) | −0.0012(9) |
C(6) | 4e | −0.7041(2) | −0.5566(3) | −0.79432(7) | 0.051(1) | 0.036(1) | 0.039(1) | −0.0034(8) | 0.0059(8) | 0.0004(8) |
C(7) | 4e | −0.6052(2) | −0.8019(3) | −0.72498(7) | 0.055(1) | 0.034(1) | 0.044(1) | 0.0012(8) | 0.0108(8) | 0.0015(8) |
C(8) | 4e | −0.5516(2) | −0.7663(3) | −0.67680(7) | 0.060(1) | 0.039(1) | 0.041(1) | 0.0016(9) | 0.0089(9) | 0.0039(8) |
C(9) | 4e | −0.5662(2) | −0.5490(3) | −0.67040(7) | 0.052(1) | 0.038(1) | 0.0382(9) | −0.0023(8) | 0.0110(8) | 0.0018(8) |
C(10) | 4e | −0.5306(2) | −0.4334(3) | −0.62505(7) | 0.052(1) | 0.040(1) | 0.042(1) | −0.0048(8) | 0.0139(8) | 0.0004(8) |
C(11) | 4e | −0.5798(2) | −0.2368(4) | −0.62224(7) | 0.059(1) | 0.043(1) | 0.046(1) | 0.0002(9) | 0.0125(9) | 0.0021(9) |
C(12) | 4e | −0.5448(2) | −0.1358(4) | −0.57860(7) | 0.067(1) | 0.040(1) | 0.053(1) | 0.004(1) | 0.020(1) | −0.0031(9) |
C(13) | 4e | −0.4641(2) | −0.2347(4) | −0.53914(7) | 0.065(1) | 0.043(1) | 0.044(1) | −0.0053(9) | 0.0183(9) | −0.0059(9) |
C(14) | 4e | −0.4194(2) | −0.4323(3) | −0.54462(7) | 0.055(1) | 0.041(1) | 0.040(1) | −0.0087(9) | 0.0156(8) | −0.0023(8) |
C(15) | 4e | −0.3346(2) | −0.5464(3) | −0.50350(7) | 0.052(1) | 0.042(1) | 0.042(1) | −0.0062(9) | 0.0149(8) | −0.0009(8) |
C(16) | 4e | −0.2994(2) | −0.7607(3) | −0.50121(7) | 0.063(1) | 0.042(1) | 0.043(1) | −0.0058(9) | 0.0163(9) | −0.0050(8) |
C(17) | 4e | −0.2241(2) | −0.7916(3) | −0.45515(7) | 0.061(1) | 0.037(1) | 0.048(1) | −0.0018(9) | 0.0168(9) | −0.0006(8) |
C(18) | 4e | −0.1475(2) | −0.5478(3) | −0.38371(7) | 0.054(1) | 0.039(1) | 0.039(1) | −0.0061(8) | 0.0108(8) | 0.0013(8) |
C(19) | 4e | −0.0382(2) | −0.6383(4) | −0.35886(8) | 0.059(1) | 0.053(1) | 0.050(1) | 0.001(1) | 0.014(1) | −0.003(1) |
C(20) | 4e | 0.0225(2) | −0.5845(4) | −0.31124(8) | 0.059(1) | 0.064(2) | 0.051(1) | 0.002(1) | 0.004(1) | 0.004(1) |
C(21) | 4e | −0.0235(2) | −0.4395(4) | −0.28914(8) | 0.074(2) | 0.068(2) | 0.042(1) | −0.005(1) | 0.008(1) | −0.004(1) |
C(22) | 4e | −0.1314(2) | −0.3460(4) | −0.31464(8) | 0.070(1) | 0.061(2) | 0.048(1) | −0.003(1) | 0.017(1) | −0.009(1) |
C(23) | 4e | −0.1937(2) | −0.4007(4) | −0.36178(7) | 0.058(1) | 0.050(1) | 0.047(1) | −0.0018(9) | 0.0145(9) | −0.0020(9) |
O(1) | 4e | −0.0115(2) | −0.3851(4) | −0.46234(7) | 0.093(1) | 0.086(2) | 0.077(1) | 0.000(1) | 0.034(1) | −0.009(1) |
C(24) | 4e | 0.0856(3) | −0.5253(5) | −0.4554(1) | 0.085(2) | 0.081(2) | 0.081(2) | 0.006(2) | 0.029(2) | 0.001(2) |
C(25) | 4e | −0.0519(3) | −0.3042(5) | −0.5088(1) | 0.096(2) | 0.084(2) | 0.071(2) | −0.000(2) | 0.027(2) | 0.003(2) |
Source of material
A mixture of pyridine-2,6-bis-(3-oxo-3-propanenitrile) (0.21 g, 1 mmol) and phenylhydrazine (0.30 g, 3 mmol) in absolute ethanol (10 mL) in the presence of a few drops of pipridine was refluxed for 5 hrs. The reaction mixture was cooled to room temperature, the formed solid was filtered off, washed with cooled ethanol, dried and crystallized from 1,4-dioxane to afford yellow crystals of the title compound in 90% yield (m.p. 241–242°C [1]).
Experimental details
Cell refinement and data reduction were carried out by Bruker SAINT [8]. The hydrogen atoms were idealized and refined using a riding model (with the follwing options of the SHELX programm [9]: AFIX 43 for aromatic hydrogen atoms, AFIX 23 for −CH2− groups and AFIX 3 for −NH2 groups).
Discussion
A series of pyrazole derivatives were found to possess interesting pharmacological activities that include antirheumatic, anti-inflammatory, antipyretic and analgesic properties [2, 3]. Pyrazole and fused heterocyclic pyrazole derivatives constute an interesting class of heterocycles due to their synthetic versatility and effective biological activities [4]. Pyrazolo[3,4-d]pyridine derivatives have been found to possess antitumor and antileukemia activity [5]. On the other hand, a number of new 6-substituted 3-(pyridine-4-yl) 1,2,4-triazole[3,4-b][1,3,4]thiadiazoles were synthesized and evaluated for their pharmacological activity. Some of them exhibited moderate MAO, antimalarial and in vitro antitumor activity [6]. Substituted pyrazolo[5,4-b]pyridine/pyrid-6-ones and pyrazolo[5,4-d]thiazines have been prepared and activities against antifungal strains were found, such as: Aspergillus niger, Helminthosporium oryzae and Pyricularia oryzae [7].
The asymmetric unit of the title structure contains one molecule in addition to one half of a dioxan molecule. The title molecule is composed of pyridine ring attached to two pyrazole rings at ortho position. Intermolecular hydrogen bonds are present in the crystal structure. The bond distances and angles between donor and acceptor are 2.29 Å and 162° for N1—H1⋯N3ii as well as 2.42 Å and 161° for N7—H2⋯N5ii (Symmetry code: (ii) x, y − 1, z.), respectively.
Acknowledgements:
The project was financially supported by King Saud University, Vice Deanship of Research Chairs.
References
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©2016 Abd El-Galil E. Amr et al., published by De Gruyter.
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.
Artikel in diesem Heft
- Cover and Frontmatter
- Crystal structure of fac-hexacarbonylbisμ2-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ3N,N′:O-dirhenium(I) tetrahydrate, C30H22N4O18Re2
- The crystal structure of bis(4-(2,4-dimethylphenyl)piperazin-1-yl)methane, C25H36N4
- Crystal structure of bis(triphenylphosphine-κP)bis(μ2-1H,1′H-2,2′-biimidazole-κ3N,N′:N′)disilver(I) bis(tetrafluoroborate), C48H42Ag2B2F8N8P2
- The crystal structure of 1,2-bis(2-pyrazinecarboxamido)-benzene, C16H12N6O2
- Redetermination of the crystal structure of 3-bromobenzoic acid, C7H5BrO2
- Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidocuprate(II), (C20H20P)2[CuBr4]
- Crystal structure of 2-(4-bromophenyl)-1,3-dimethyl-2,3-dihydro-1H-perimidine, C19H17BrN2
- Crystal structure of trans-diaqua-bis(3-(pyrazin-2-yl)-5-(pyridin-4-yl)1,2,4-triazol-1-ido-κ2N,N′)-cobalt(II),C22H18CoN12O2
- Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MnN6O12S2
- Crystal structure of butyl 2-(3,5-dimethyl-1,1-dioxido-2H-1,2,6-thiadiazin-4-yl)benzoate, C16H20N2O4S
- Crystal structure of hexaaquabis(μ2-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)bis(μ3-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)tetra-manganese(II) dihydrate, C48H40Mn4N24O16
- Crystal structure of catena-poly[diaqua-bis(μ2-1,3-di(pyridin-4-yl)propane-κ2N:N′)cadmate(II)] bis(2-aminoisonicotinate) tetrahydrate, C38H50CdN8O10
- Crystal structure of succinic acid — 4-((pyridin-4-ylmethyl)sulfanylpyridine (1/1), C15H16N2O4S
- Crystal structure of tetrakis(μ2-acetato-κ2O:O′)bis(2-((pyridin-4-ylmethyl)sulfanyl)pyridine-κN)dicopper(II), C30H32N4O8S2Cu2
- Crystal structure of 1-((2R,3S)-2,3-dimethyl-2,3-dihydro-4H-benzo[b][1,4]oxazin-4-yl)-2-phenoxyethan-1-one, C18H19NO3
- Crystal structure of tetramethylammonium sulfanilate, C10H18N2O3S
- Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C20H25NO4
- Crystal structure of 2-(4-acetyl-2,6-dimethylphenyl)-5,6-dichloro-1H-isoindole-1,3(2H)-dione, C18H13Cl2NO3
- Crystal structure of diaqua-bis(μ3-2-methyl-6-oxidopyridinium-4-carboxylato-κ3O:O′:O′′)neodymium(III) chloride, C14H16ClN2O8Nd
- Crystal structure of 5-methoxy-4-methyl-2-(2-methylbenzyl)-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H15N3O2
- The crystal structure of 1-(4-(2-chloroethoxy)phenyl)ethanone
- Crystal structure of (E)-4-(2-(4-(diethylamino)phenyl)diazen-1-ium-1-yl)benzenesulfonate monohydrate
- Crystal structure of 2,2′-[(1E)-prop-1-ene-1,2-diyldisulfanediyl]bis(5-methyl-2,5-dihydro-1,3,4-thiadiazole, C9H10N4S4
- Crystal structure of poly [μ2-acetato-κ3-O,O′:O′)diaqua(μ3-isophthalato-κ4O,O′:O′′:O′′′)cerium(III)] monohydrate (C10H13O9Ce)
- Crystal structure of tris((2-(2,2-dicyanovinyl)phenoxy)ethyl)amine, C36H27N7O3
- Crystal structure of catena[diaqua-bis(μ2-1,3-bis((1H-tetrazol-1-yl)methyl)benzene-κ2N:N′)copper(II)] dinitrate, C20H24CuN18O8
- Crystal structure of (4-(1H-imidazol-5-yl)benzoic acid-κN) (4-(1H-imidazol-5-yl)benzoato-κN)silver(I), C20H15N4O4Ag
- Crystal structure of 2-amino-3-cyano-7,7-dimethyl-5-oxo-4-(3,4,5-trifluorophenyl)-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C18H15F3N2O2
- Crystal structure of (2-(2-chlorophenyl)-5-ethyl-1,3-dioxan-5-yl)methanol hemihydrate, C13H17ClO3 · 0.5 H2O
- Crystal structure of catena-poly[diaqua-bis(benzene-1,2,4,5-tetracarboxylato-κN)(m2-2-(1H-1,2,4-trizol-1-ylmethyl)-1H-3,1-benzimidazol-3-ium-κ2O:O′)zinc(II)] dihydrate, C30H30N10O12Zn
- Crystal structure of [2,2′-((((ethane-1,2-diylbis(oxy-κ2O,O′))bis(2,1-phenylene))bis(azanylylidene-κ2N,N′))bis(methanylylidene))diphenolato-κ2O′′,O′′′]zinc(II), C28H22N2O4Zn
- Crystal structure of (E)-1-(3,4-dimethoxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C13H17NO3
- Crystal structure of bis(2-fluoro-4-nitrophenyl) terephthalate C20H10F2N2O8
- Crystal structure of catena-[aqua((4-carboxyphenyl)acetato-κO)(μ2-(4-carboxyphenyl)acetato-κ2O:O′)bis(4,4′-ethene-1,2-diyldipyridine-κN)manganese(II)], C42H36N4O9Mn
- Crystal structure of N′-(2-hydroxybenzylidene)-3,4-dimethyl-1H-pyrrole-2-carbohydrazide, C14H15N3O2
- Crystal structure of bis(8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato-κ2O,O′)copper(II) benzene-1,4-dicarboxylate dihydrate, C36H42CuN10O12
- Crystal structure of diaquabis(μ2-biphenyl-2,2′-dicarboxylato-κ2O:O′)bis(1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-3-quinolinecarboxylato)zinc(II), C60H56N6Zn2O16F2
- Crystal structure of 2-amino-4-(4-fluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13FN2O2
- The crystal structure of hexaqua(μ2-3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-1κ2O,O′;2κO′)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κO)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κ2O,O′)digadolinium(III) octahydrate, C60H76Gd2N18O32
- Crystal structure of hexacarbonyl bis(μ2-2-methoxybenzenethiolato-κ2S)pyridine(triphenylphosphane)dirhenium(I), C43H34NO8PS2Re2
- Crystal structure of 14-((1-(benzyloxycarbonyl-amino)-2-methylpropan-2-yl)sulfanyl)acetate Mutilin, C34H49NO6S
- Crystal structure of 2-methoxy-6-(((2-(1-methyl-1H-benzo[d] imidazol-2-yl)phenyl)imino)methyl)phenol — ethanol (1/1), C24H25N3O3
- Crystal structure of 2-(bis(methylthio)methylene)-1-phenylbutane-1,3-dione, C13H14O2S2
- Crystal structure of (E)-2-(bis(methylthio)methylene)-1-phenyl-3-(2-phenylhydrazono)butan-1-one, C19H20N2OS2
- Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ2N,N′)zinc(II)
- Crystal structure of bis(1-methyl-1H-tetrazole-5-thiolato)mercury(II)
- Crystal structure of (E)-2-styryl-1-ferrocenylsulfonyl-1H-imidazo[4,5-b]pyridine, C24H19FeN3O2S
- Crystal structure of aquabis(1-cyclopropyl-6-fluoro-4-oxo-7-(piperazin-4-ium-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O,O′)copper(II) thiophene-2,5-dicarboxylate trihydrate, [Cu(C17H18N3FO3)2(H2O)](C6H2SO4)·3(H2O)
- Crystal structure of 2-amino-4-(2,6-dichlorophenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H16Cl2N2O2
- Crystal structure of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5·5·0·05·9·03·11]dodecane 1/3 hydrate, C6H8N12O13
- Crystal structure of monocarbonyl(N-nitroso-N-oxido-phenylamine-κ2O,O′)(triphenylarsine-κAs)rhodium(I), C25H20AsN2O3Rh
- The crystal structure of 1-(4-(4-chlorophenoxy)-2-chlorophenyl)ethanone, C14H10Cl2O2
- Crystal structure of N,N-diethyl-2-(2-(6-(4-methoxybenzyl)-7-oxo-7H-thiazolo[3,3-b][1,2,4]triazin-3-yl)phenoxy)acetamide, C25H26N4O4S
- Crystal structure of tetraqua((E)-4,4′-(diazene-1,2-diyl)bis(5-oxo-4,5-dihydro-1,2,4-triazol-1-ide)-κ2N:O)barium(II), C4H10N8O6Ba
- Crystal structure of 2-amino-4-(3-phenoxyphenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C22H18N2O3
- Crystal structure of diethylammonium 5-((4-fluorophenyl)(6-hydroxy-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl)-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate, C23H30FN5O6
- Crystal structure of 2-amino-4-(3,5-difluoro-phenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12F2N2O2
- Crystal structure of tris(N-nitroso-N-oxyanilino-κ2O, O′) oxidoniobium(V), C18H15N6O7Nb
- Crystal structure of 1-(5-benzoyl-4-methyl-2-(phenylamino)thiophen-3-yl)ethan-1-one, a structure with Z′ = 6, C20H17NO2S
- Crystal structure of diethyl-3-methyl-4-phenylthieno[2,3-b]thiophene-2,5-dicarboxylate, C19H18O4S2
- Crystal structure of 3,5-dicarboxybenzoate — benzene-1,3,5-tricarboxylic acid (1/1), C24H22N2O12
- The crystal structure of 2-chloro-1,3-bis(2,4,6-trimethylphenyl)-4,4-dimethyl-1,3,2λ3,4-diazaphosphasiletidine
- Crystal structure of hexaquamanganese(II) bis(hexaborato-κ3O,O′,O′′)manganese(II) dihydrate, B12H28Mn2O34
- Crystal structure of 1-propyl-3-methylimidazolium pentaborate, [C7H13N2][B5O6(OH)4]
- Crystal structure of 13-(4-fluorophenyl)-11,13-dihydro-1H-benzo[h]indazolo[6,7-b] [1, 6]naphthyridin-12(6H)-one — dimethylformamide — water (1/2/1), C29H31FN6O4
- Crystal structure of 1-(2-chlorophenyl)-2-(2-nitrophenyl)ethan-1-ol, C14H12ClNO3
- Crystal structure of (Z)-2-((2-bromo-1-phenylvinyl)oxy)benzonitrile, C15H10BrNO
- Crystal structure of tetrachlorido(1E,1′E)-N,N′-((1,4-phenylenebis(propane-2,2-diyl))bis(4,1-phenylene))bis(1-(pyridin-2-yl-κN)methanimine-κN)dizinc(II), C36H34N4Zn2Cl4
- Crystal structure of 2,6-bis(3-methylpyridinyl)hexahydro-4,8-ethenopyrrolo-[3,4-f]isoindole-1,3,5,7(2H,6H)-tetrone, C24H20N4O4
- Crystal structure of trans-bis(2-methylmaleato-κ2O,O′) bis(piperazinium-κN) cobalt(II) trihydrate, C18H36CoN4O11
- Crystal structure of (E)-4-chloro-N′-(4-(diethylamino)benzylidene)benzohydrazide, C18H20ClN3O
- Crystal structure of 3,6-di(1H-imidazol-1-yl)-9H-carbazole, C18H13N5
- Crystal structure of 4-(4-pyridinyl)-1-naphthoic acid, C16H11NO2
- Crystal structure of 1,1′-diformyl-4,4′-(6H,12H-5,11-methano-dibenzo[b,f][11,5]diazocine-2,8-diyl)dibenzene, C29H22N2O2
- Crystal structure of N′-(adamantan-2-ylidene)pyridine-3-carbohydrazide, C16H19N3O
- Crystal structure of 1,1′-(butane-1,4-diyl)bis(5-methyl-1H-pyrazole-3-carbaldehyde), C14H18N4O2
- Crystal structure of methyl 8-hydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylate, C21H34O3
- Crystal structure of 6-oxo-4-propyl-2-(propylthio)-1,6-dihydropyrimidine-5-carbonitrile, C11H15N3OS
- Crystal structure of poly[diacetato(μ2-1,4-bis(1H-imidazol-1-yl)benzene-κ2N:N′)nickel(II)], C26H22N8NiO4
- Crystal structure of bis(2,4-dibromo-6-{(E)[(4-fluorobenzyl)imino]methyl}phenolato-κ2N,O) copper(II), C28H18Br4F2N2O2Cu
- Crystal structure of 1-(adamantan-1-yl)-3-phenylthiourea, C17H22N2S
- Crystal structure of 3-(6-(5-amino-1-phenyl-1H-pyrazol-3-yl)pyridin-2-yl)-1-phenyl-1H-pyrazol-5-amine – dioxan (2/1), C25H23N7O
- Crystal structure of 5-ethyl-6-[(3-methylphenyl)sulfanyl]pyrimidine-2,4(1H,3H)-dione, C13H14N2O2S
- Crystal structure of (((1E,1′E)-(cyclohexane-1,2-diylbis(azanylylidene-κ2N,N′))bis(methanylylidene))bis(2,1-phenylene))bis((2,6-diisopropylphenyl)amide-κ2N′′,N′′′)manganese(II), C44H54N4Mn
- Crystal structure of prop-2-en-1-yl 2-oxo-2H-1-benzopyran-3-carboxylate, C13H10O4
- Crystal structure of bis(μ2-2-((3-methylphenyl)imino)methylphenolato-κ2N,O:O)hexacarbonyldimanganese(I), C34H24Mn2N2O8
- Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxybut-2-en-1-one C9H12N2O2
- Crystal structure of 2,2′-[pentane-1,5-diylbis(oxy)]dibenzaldehyde, C19H20O4
- Crystal structure of 2-phenyl-5,6,7,8-tetrahydro-4H-benzo[4,5]thieno[2,3-d][1,3]oxazin-4-one, C16H13NO2S
- Crystal structure of (E)-1-(2-chlorophenyl)-N-(4-chlorophenyl)methanimine, C13H9Cl2N
- Crystal structure of ethyl 2-amino-5-bromothiazole-4-carboxylate, C6H7BrN2O2S
- Crystal structure of 2-benzylisothiouronium tetraphenylborate, C32H31BN2S
- Crystal structure of poly[(μ2-biphenyl-2,2′-dicarboxylato-κ4O,O′:O′′,O′′′)(μ2-4,4′-bipyridine-κ2N:N′)copper(II)], C24H16CuN2O4
- Crystal structure of (η5-pentamethylcyclopentadienyl)titanium(III)dichloride (THF), C14H23Cl2OTi
- Crystal structure of 3-ferrocenylsulfonyl-2-(4-methoxyphenyl)-3H-imidazo[4,5-b]pyridine, C23H19FeN3O3S
- Crystal structure of 2-benzoyl-3-(4-fluorophenyl)cyclopropane-1,1-dicarbonitrile, C18H11FN2O
- Crystal structure of 1,6-ditosyl-1,6-diazecane, C22H30N2O4S2
- Crystal structure of N-phenyl-2-(pyridin-4-ylcarbonyl)hydrazinecarboxamide with Z′ = 4, C13H12N4O2
- Crystal structure of N,N-bis(diphenylphosphanyl)cyclohexylamine, C30H31NP2
- Crystal structure of 3-(4-hydroxy-3-methoxyphenyl)-N-phenylpropanamide, C16H17NO3
- Crystal structure of 6-(2-fluorophenyl)-3-phenyl-[1,2,4]-triazolo[3,4-b][1,3,4]thiadiazole, C15H9FN4S
- Crystal structure of catena-poly[aqua(dicyanoazanido-2κN-μ2-dicyanoazanido-1κN:2κN′)(μ2-2-methoxy-6-(((2-((3-methoxy-2-oxidobenzylidene)amino)ethyl)imino)methyl)phenolato-1κ2N,N′,2κ2O,O′,1κ2O′′,O′′′:2κ2O′′,O′′′)cadmium(II)copper(II)], C22H20CdCuN8O5
Artikel in diesem Heft
- Cover and Frontmatter
- Crystal structure of fac-hexacarbonylbisμ2-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ3N,N′:O-dirhenium(I) tetrahydrate, C30H22N4O18Re2
- The crystal structure of bis(4-(2,4-dimethylphenyl)piperazin-1-yl)methane, C25H36N4
- Crystal structure of bis(triphenylphosphine-κP)bis(μ2-1H,1′H-2,2′-biimidazole-κ3N,N′:N′)disilver(I) bis(tetrafluoroborate), C48H42Ag2B2F8N8P2
- The crystal structure of 1,2-bis(2-pyrazinecarboxamido)-benzene, C16H12N6O2
- Redetermination of the crystal structure of 3-bromobenzoic acid, C7H5BrO2
- Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidocuprate(II), (C20H20P)2[CuBr4]
- Crystal structure of 2-(4-bromophenyl)-1,3-dimethyl-2,3-dihydro-1H-perimidine, C19H17BrN2
- Crystal structure of trans-diaqua-bis(3-(pyrazin-2-yl)-5-(pyridin-4-yl)1,2,4-triazol-1-ido-κ2N,N′)-cobalt(II),C22H18CoN12O2
- Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MnN6O12S2
- Crystal structure of butyl 2-(3,5-dimethyl-1,1-dioxido-2H-1,2,6-thiadiazin-4-yl)benzoate, C16H20N2O4S
- Crystal structure of hexaaquabis(μ2-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)bis(μ3-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)tetra-manganese(II) dihydrate, C48H40Mn4N24O16
- Crystal structure of catena-poly[diaqua-bis(μ2-1,3-di(pyridin-4-yl)propane-κ2N:N′)cadmate(II)] bis(2-aminoisonicotinate) tetrahydrate, C38H50CdN8O10
- Crystal structure of succinic acid — 4-((pyridin-4-ylmethyl)sulfanylpyridine (1/1), C15H16N2O4S
- Crystal structure of tetrakis(μ2-acetato-κ2O:O′)bis(2-((pyridin-4-ylmethyl)sulfanyl)pyridine-κN)dicopper(II), C30H32N4O8S2Cu2
- Crystal structure of 1-((2R,3S)-2,3-dimethyl-2,3-dihydro-4H-benzo[b][1,4]oxazin-4-yl)-2-phenoxyethan-1-one, C18H19NO3
- Crystal structure of tetramethylammonium sulfanilate, C10H18N2O3S
- Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C20H25NO4
- Crystal structure of 2-(4-acetyl-2,6-dimethylphenyl)-5,6-dichloro-1H-isoindole-1,3(2H)-dione, C18H13Cl2NO3
- Crystal structure of diaqua-bis(μ3-2-methyl-6-oxidopyridinium-4-carboxylato-κ3O:O′:O′′)neodymium(III) chloride, C14H16ClN2O8Nd
- Crystal structure of 5-methoxy-4-methyl-2-(2-methylbenzyl)-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H15N3O2
- The crystal structure of 1-(4-(2-chloroethoxy)phenyl)ethanone
- Crystal structure of (E)-4-(2-(4-(diethylamino)phenyl)diazen-1-ium-1-yl)benzenesulfonate monohydrate
- Crystal structure of 2,2′-[(1E)-prop-1-ene-1,2-diyldisulfanediyl]bis(5-methyl-2,5-dihydro-1,3,4-thiadiazole, C9H10N4S4
- Crystal structure of poly [μ2-acetato-κ3-O,O′:O′)diaqua(μ3-isophthalato-κ4O,O′:O′′:O′′′)cerium(III)] monohydrate (C10H13O9Ce)
- Crystal structure of tris((2-(2,2-dicyanovinyl)phenoxy)ethyl)amine, C36H27N7O3
- Crystal structure of catena[diaqua-bis(μ2-1,3-bis((1H-tetrazol-1-yl)methyl)benzene-κ2N:N′)copper(II)] dinitrate, C20H24CuN18O8
- Crystal structure of (4-(1H-imidazol-5-yl)benzoic acid-κN) (4-(1H-imidazol-5-yl)benzoato-κN)silver(I), C20H15N4O4Ag
- Crystal structure of 2-amino-3-cyano-7,7-dimethyl-5-oxo-4-(3,4,5-trifluorophenyl)-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C18H15F3N2O2
- Crystal structure of (2-(2-chlorophenyl)-5-ethyl-1,3-dioxan-5-yl)methanol hemihydrate, C13H17ClO3 · 0.5 H2O
- Crystal structure of catena-poly[diaqua-bis(benzene-1,2,4,5-tetracarboxylato-κN)(m2-2-(1H-1,2,4-trizol-1-ylmethyl)-1H-3,1-benzimidazol-3-ium-κ2O:O′)zinc(II)] dihydrate, C30H30N10O12Zn
- Crystal structure of [2,2′-((((ethane-1,2-diylbis(oxy-κ2O,O′))bis(2,1-phenylene))bis(azanylylidene-κ2N,N′))bis(methanylylidene))diphenolato-κ2O′′,O′′′]zinc(II), C28H22N2O4Zn
- Crystal structure of (E)-1-(3,4-dimethoxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C13H17NO3
- Crystal structure of bis(2-fluoro-4-nitrophenyl) terephthalate C20H10F2N2O8
- Crystal structure of catena-[aqua((4-carboxyphenyl)acetato-κO)(μ2-(4-carboxyphenyl)acetato-κ2O:O′)bis(4,4′-ethene-1,2-diyldipyridine-κN)manganese(II)], C42H36N4O9Mn
- Crystal structure of N′-(2-hydroxybenzylidene)-3,4-dimethyl-1H-pyrrole-2-carbohydrazide, C14H15N3O2
- Crystal structure of bis(8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato-κ2O,O′)copper(II) benzene-1,4-dicarboxylate dihydrate, C36H42CuN10O12
- Crystal structure of diaquabis(μ2-biphenyl-2,2′-dicarboxylato-κ2O:O′)bis(1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-3-quinolinecarboxylato)zinc(II), C60H56N6Zn2O16F2
- Crystal structure of 2-amino-4-(4-fluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13FN2O2
- The crystal structure of hexaqua(μ2-3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-1κ2O,O′;2κO′)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κO)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κ2O,O′)digadolinium(III) octahydrate, C60H76Gd2N18O32
- Crystal structure of hexacarbonyl bis(μ2-2-methoxybenzenethiolato-κ2S)pyridine(triphenylphosphane)dirhenium(I), C43H34NO8PS2Re2
- Crystal structure of 14-((1-(benzyloxycarbonyl-amino)-2-methylpropan-2-yl)sulfanyl)acetate Mutilin, C34H49NO6S
- Crystal structure of 2-methoxy-6-(((2-(1-methyl-1H-benzo[d] imidazol-2-yl)phenyl)imino)methyl)phenol — ethanol (1/1), C24H25N3O3
- Crystal structure of 2-(bis(methylthio)methylene)-1-phenylbutane-1,3-dione, C13H14O2S2
- Crystal structure of (E)-2-(bis(methylthio)methylene)-1-phenyl-3-(2-phenylhydrazono)butan-1-one, C19H20N2OS2
- Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ2N,N′)zinc(II)
- Crystal structure of bis(1-methyl-1H-tetrazole-5-thiolato)mercury(II)
- Crystal structure of (E)-2-styryl-1-ferrocenylsulfonyl-1H-imidazo[4,5-b]pyridine, C24H19FeN3O2S
- Crystal structure of aquabis(1-cyclopropyl-6-fluoro-4-oxo-7-(piperazin-4-ium-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O,O′)copper(II) thiophene-2,5-dicarboxylate trihydrate, [Cu(C17H18N3FO3)2(H2O)](C6H2SO4)·3(H2O)
- Crystal structure of 2-amino-4-(2,6-dichlorophenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H16Cl2N2O2
- Crystal structure of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5·5·0·05·9·03·11]dodecane 1/3 hydrate, C6H8N12O13
- Crystal structure of monocarbonyl(N-nitroso-N-oxido-phenylamine-κ2O,O′)(triphenylarsine-κAs)rhodium(I), C25H20AsN2O3Rh
- The crystal structure of 1-(4-(4-chlorophenoxy)-2-chlorophenyl)ethanone, C14H10Cl2O2
- Crystal structure of N,N-diethyl-2-(2-(6-(4-methoxybenzyl)-7-oxo-7H-thiazolo[3,3-b][1,2,4]triazin-3-yl)phenoxy)acetamide, C25H26N4O4S
- Crystal structure of tetraqua((E)-4,4′-(diazene-1,2-diyl)bis(5-oxo-4,5-dihydro-1,2,4-triazol-1-ide)-κ2N:O)barium(II), C4H10N8O6Ba
- Crystal structure of 2-amino-4-(3-phenoxyphenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C22H18N2O3
- Crystal structure of diethylammonium 5-((4-fluorophenyl)(6-hydroxy-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl)-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate, C23H30FN5O6
- Crystal structure of 2-amino-4-(3,5-difluoro-phenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12F2N2O2
- Crystal structure of tris(N-nitroso-N-oxyanilino-κ2O, O′) oxidoniobium(V), C18H15N6O7Nb
- Crystal structure of 1-(5-benzoyl-4-methyl-2-(phenylamino)thiophen-3-yl)ethan-1-one, a structure with Z′ = 6, C20H17NO2S
- Crystal structure of diethyl-3-methyl-4-phenylthieno[2,3-b]thiophene-2,5-dicarboxylate, C19H18O4S2
- Crystal structure of 3,5-dicarboxybenzoate — benzene-1,3,5-tricarboxylic acid (1/1), C24H22N2O12
- The crystal structure of 2-chloro-1,3-bis(2,4,6-trimethylphenyl)-4,4-dimethyl-1,3,2λ3,4-diazaphosphasiletidine
- Crystal structure of hexaquamanganese(II) bis(hexaborato-κ3O,O′,O′′)manganese(II) dihydrate, B12H28Mn2O34
- Crystal structure of 1-propyl-3-methylimidazolium pentaborate, [C7H13N2][B5O6(OH)4]
- Crystal structure of 13-(4-fluorophenyl)-11,13-dihydro-1H-benzo[h]indazolo[6,7-b] [1, 6]naphthyridin-12(6H)-one — dimethylformamide — water (1/2/1), C29H31FN6O4
- Crystal structure of 1-(2-chlorophenyl)-2-(2-nitrophenyl)ethan-1-ol, C14H12ClNO3
- Crystal structure of (Z)-2-((2-bromo-1-phenylvinyl)oxy)benzonitrile, C15H10BrNO
- Crystal structure of tetrachlorido(1E,1′E)-N,N′-((1,4-phenylenebis(propane-2,2-diyl))bis(4,1-phenylene))bis(1-(pyridin-2-yl-κN)methanimine-κN)dizinc(II), C36H34N4Zn2Cl4
- Crystal structure of 2,6-bis(3-methylpyridinyl)hexahydro-4,8-ethenopyrrolo-[3,4-f]isoindole-1,3,5,7(2H,6H)-tetrone, C24H20N4O4
- Crystal structure of trans-bis(2-methylmaleato-κ2O,O′) bis(piperazinium-κN) cobalt(II) trihydrate, C18H36CoN4O11
- Crystal structure of (E)-4-chloro-N′-(4-(diethylamino)benzylidene)benzohydrazide, C18H20ClN3O
- Crystal structure of 3,6-di(1H-imidazol-1-yl)-9H-carbazole, C18H13N5
- Crystal structure of 4-(4-pyridinyl)-1-naphthoic acid, C16H11NO2
- Crystal structure of 1,1′-diformyl-4,4′-(6H,12H-5,11-methano-dibenzo[b,f][11,5]diazocine-2,8-diyl)dibenzene, C29H22N2O2
- Crystal structure of N′-(adamantan-2-ylidene)pyridine-3-carbohydrazide, C16H19N3O
- Crystal structure of 1,1′-(butane-1,4-diyl)bis(5-methyl-1H-pyrazole-3-carbaldehyde), C14H18N4O2
- Crystal structure of methyl 8-hydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylate, C21H34O3
- Crystal structure of 6-oxo-4-propyl-2-(propylthio)-1,6-dihydropyrimidine-5-carbonitrile, C11H15N3OS
- Crystal structure of poly[diacetato(μ2-1,4-bis(1H-imidazol-1-yl)benzene-κ2N:N′)nickel(II)], C26H22N8NiO4
- Crystal structure of bis(2,4-dibromo-6-{(E)[(4-fluorobenzyl)imino]methyl}phenolato-κ2N,O) copper(II), C28H18Br4F2N2O2Cu
- Crystal structure of 1-(adamantan-1-yl)-3-phenylthiourea, C17H22N2S
- Crystal structure of 3-(6-(5-amino-1-phenyl-1H-pyrazol-3-yl)pyridin-2-yl)-1-phenyl-1H-pyrazol-5-amine – dioxan (2/1), C25H23N7O
- Crystal structure of 5-ethyl-6-[(3-methylphenyl)sulfanyl]pyrimidine-2,4(1H,3H)-dione, C13H14N2O2S
- Crystal structure of (((1E,1′E)-(cyclohexane-1,2-diylbis(azanylylidene-κ2N,N′))bis(methanylylidene))bis(2,1-phenylene))bis((2,6-diisopropylphenyl)amide-κ2N′′,N′′′)manganese(II), C44H54N4Mn
- Crystal structure of prop-2-en-1-yl 2-oxo-2H-1-benzopyran-3-carboxylate, C13H10O4
- Crystal structure of bis(μ2-2-((3-methylphenyl)imino)methylphenolato-κ2N,O:O)hexacarbonyldimanganese(I), C34H24Mn2N2O8
- Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxybut-2-en-1-one C9H12N2O2
- Crystal structure of 2,2′-[pentane-1,5-diylbis(oxy)]dibenzaldehyde, C19H20O4
- Crystal structure of 2-phenyl-5,6,7,8-tetrahydro-4H-benzo[4,5]thieno[2,3-d][1,3]oxazin-4-one, C16H13NO2S
- Crystal structure of (E)-1-(2-chlorophenyl)-N-(4-chlorophenyl)methanimine, C13H9Cl2N
- Crystal structure of ethyl 2-amino-5-bromothiazole-4-carboxylate, C6H7BrN2O2S
- Crystal structure of 2-benzylisothiouronium tetraphenylborate, C32H31BN2S
- Crystal structure of poly[(μ2-biphenyl-2,2′-dicarboxylato-κ4O,O′:O′′,O′′′)(μ2-4,4′-bipyridine-κ2N:N′)copper(II)], C24H16CuN2O4
- Crystal structure of (η5-pentamethylcyclopentadienyl)titanium(III)dichloride (THF), C14H23Cl2OTi
- Crystal structure of 3-ferrocenylsulfonyl-2-(4-methoxyphenyl)-3H-imidazo[4,5-b]pyridine, C23H19FeN3O3S
- Crystal structure of 2-benzoyl-3-(4-fluorophenyl)cyclopropane-1,1-dicarbonitrile, C18H11FN2O
- Crystal structure of 1,6-ditosyl-1,6-diazecane, C22H30N2O4S2
- Crystal structure of N-phenyl-2-(pyridin-4-ylcarbonyl)hydrazinecarboxamide with Z′ = 4, C13H12N4O2
- Crystal structure of N,N-bis(diphenylphosphanyl)cyclohexylamine, C30H31NP2
- Crystal structure of 3-(4-hydroxy-3-methoxyphenyl)-N-phenylpropanamide, C16H17NO3
- Crystal structure of 6-(2-fluorophenyl)-3-phenyl-[1,2,4]-triazolo[3,4-b][1,3,4]thiadiazole, C15H9FN4S
- Crystal structure of catena-poly[aqua(dicyanoazanido-2κN-μ2-dicyanoazanido-1κN:2κN′)(μ2-2-methoxy-6-(((2-((3-methoxy-2-oxidobenzylidene)amino)ethyl)imino)methyl)phenolato-1κ2N,N′,2κ2O,O′,1κ2O′′,O′′′:2κ2O′′,O′′′)cadmium(II)copper(II)], C22H20CdCuN8O5