Home Crystal structure of hexacarbonyl bis(μ2-2-methoxybenzenethiolato-κ2S)pyridine(triphenylphosphane)dirhenium(I), C43H34NO8PS2Re2
Article Open Access

Crystal structure of hexacarbonyl bis(μ2-2-methoxybenzenethiolato-κ2S)pyridine(triphenylphosphane)dirhenium(I), C43H34NO8PS2Re2

  • Pheello Isaac Nkoe EMAIL logo , Renier Koen , Alice Brink and Marietjie Schutte-Smith
Published/Copyright: March 23, 2016
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 231 Issue 2

Abstract

C43H34NO8PS2Re2, monoclinic, P21/c (no. 14), a = 12.165(8) Å, b = 19.027(11) Å, c = 18.848(14) Å, β = 108.735(2)°, V = 4131(5) Å3, Z = 4, Rgt(F) = 0.0308, wRref(F2) = 0.0683, T = 100(2) K.

CCDC no.:: 1454873

The crystal structure is shown in the figure. Tables 1–3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Yellow, cuboid, size 0.125×0.229×0.319 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:60.47 cm−1
Diffractometer, scan mode:Bruker APEX-II CCD, φ and ω scans
2θmax:56°
N(hkl)measured, N(hkl)unique:82039, 9952
N(param)refined:514
Programs:Bruker Programs [22], WinGX [23], SHELX [20], Diamond [24]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomSitexyzUiso
H(12)4e0.67340.27900.90690.050
H(13)4e0.85400.27110.99900.069
H(14)4e0.89690.17801.08210.080
H(15)4e0.76310.08821.06990.067
H(16)4e0.58190.09450.97820.050
H(22)4e0.45230.34300.80510.068
H(23)4e0.51210.39630.71130.089
H(24)4e0.59890.32990.64110.080
H(25)4e0.62370.21100.66220.072
H(26)4e0.56040.15690.75190.052
H(32)4e0.27130.29060.81020.048
H(33)4e0.18760.37790.86440.059
H(34)4e0.26640.40280.99110.062
H(35)4e0.42030.33771.06590.060
H(36)4e0.50430.25011.01310.047
H(42)4e0.1685−0.00750.59320.050
H(43)4e0.2042−0.09420.51590.062
H(44)4e0.3890−0.11000.50990.063
H(45)4e0.5422−0.04450.58480.052
H(47A)4e0.70340.07370.71740.104
H(47B)4e0.66030.04240.63420.104
H(47C)4e0.6693−0.00760.70410.104
H(52)4e0.13760.02770.87110.061
H(53)4e−0.0024−0.00500.92460.086
H(54)4e−0.15620.06940.91710.100
H(55)4e−0.16620.17990.86230.092
H(57A)4e−0.08240.33050.78200.152
H(57B)4e−0.08140.29900.86090.152
H(57C)4e−0.17450.27150.78500.152
H(61)4e0.21260.21720.56210.084
H(62)4e0.25740.33060.53940.114
H(63)4e0.21350.42300.60680.105
H(64)4e0.11990.39740.69380.079
H(65)4e0.07580.28190.71260.058
Table 3:

Fractional coordinates and atomic displacement parameters (Å2).

AtomSitexyzU11U22U33U12U13U23
C(1)4e0.3698(4)0.0675(2)0.9270(3)0.047(3)0.036(3)0.046(3)−0.001(2)0.019(2)0.004(2)
C(2)4e0.2817(4)−0.0078(2)0.7962(3)0.036(3)0.033(2)0.042(3)0.001(2)0.015(2)0.004(2)
C(3)4e0.5058(4)0.0381(2)0.8376(2)0.037(3)0.024(2)0.037(3)−0.002(2)0.010(2)0.000(2)
C(4)4e0.0449(4)0.1110(3)0.5494(3)0.027(2)0.059(3)0.044(3)−0.001(2)0.005(2)0.001(3)
C(5)4e−0.0645(4)0.1549(2)0.6478(3)0.039(3)0.043(3)0.042(3)0.001(2)0.013(2)0.006(2)
C(6)4e0.0393(4)0.0354(3)0.6709(3)0.035(3)0.045(3)0.047(3)−0.001(2)0.014(2)−0.002(2)
C(11)4e0.6093(4)0.1869(2)0.9323(2)0.030(2)0.034(2)0.034(3)0.002(2)0.009(2)−0.006(2)
C(12)4e0.6910(4)0.2397(2)0.9398(3)0.034(3)0.041(3)0.047(3)−0.002(2)0.009(2)−0.008(2)
C(13)4e0.7979(5)0.2353(3)0.9949(3)0.042(3)0.064(4)0.060(4)−0.008(3)0.006(3)−0.017(3)
C(14)4e0.8239(5)0.1799(3)1.0436(3)0.041(3)0.086(5)0.057(4)0.003(3)−0.007(3)−0.017(3)
C(15)4e0.7444(5)0.1273(3)1.0368(3)0.051(3)0.062(4)0.042(3)0.010(3)0.000(3)0.007(3)
C(16)4e0.6371(4)0.1308(2)0.9819(3)0.036(3)0.046(3)0.036(3)0.007(2)0.000(2)0.003(2)
C(21)4e0.5005(4)0.2444(2)0.7882(2)0.039(3)0.030(2)0.028(2)−0.009(2)0.010(2)−0.000(2)
C(22)4e0.4866(5)0.3154(3)0.7759(3)0.075(4)0.038(3)0.068(4)−0.002(3)0.038(3)0.009(3)
C(23)4e0.5229(6)0.3472(3)0.7201(4)0.096(5)0.045(3)0.091(5)−0.007(3)0.045(4)0.022(3)
C(24)4e0.5737(5)0.3081(3)0.6785(3)0.085(5)0.073(4)0.051(4)−0.032(4)0.034(3)0.004(3)
C(25)4e0.5879(5)0.2382(3)0.6908(3)0.071(4)0.063(4)0.058(4)−0.032(3)0.038(3)−0.017(3)
C(26)4e0.5509(4)0.2063(2)0.7446(3)0.054(3)0.036(3)0.044(3)−0.012(2)0.020(3)−0.005(2)
C(31)4e0.3985(3)0.2620(2)0.9061(2)0.026(2)0.025(2)0.031(2)−0.003(2)0.009(2)−0.004(2)
C(32)4e0.3029(4)0.3001(2)0.8623(3)0.040(3)0.033(2)0.040(3)0.001(2)0.004(2)−0.003(2)
C(33)4e0.2530(4)0.3523(2)0.8945(3)0.039(3)0.034(3)0.069(4)0.005(2)0.011(3)−0.006(3)
C(34)4e0.2988(5)0.3664(3)0.9696(3)0.049(3)0.047(3)0.066(4)−0.001(2)0.030(3)−0.018(3)
C(35)4e0.3905(5)0.3285(3)1.0136(3)0.055(3)0.065(3)0.035(3)0.002(3)0.022(3)−0.013(3)
C(36)4e0.4404(4)0.2763(2)0.9820(3)0.039(3)0.048(3)0.035(3)0.007(2)0.016(2)−0.003(2)
C(41)4e0.3337(4)0.0284(2)0.6346(2)0.037(2)0.028(2)0.031(2)−0.001(2)0.015(2)−0.001(2)
C(42)4e0.2451(4)−0.0139(2)0.5914(3)0.040(3)0.036(3)0.051(3)−0.001(2)0.017(2)−0.007(2)
C(43)4e0.2661(5)−0.0657(2)0.5454(3)0.050(3)0.040(3)0.062(4)−0.009(2)0.016(3)−0.022(3)
C(44)4e0.3755(5)−0.0755(2)0.5427(3)0.065(4)0.037(3)0.061(4)0.005(3)0.027(3)−0.013(3)
C(45)4e0.4660(4)−0.0364(2)0.5863(3)0.046(3)0.039(3)0.050(3)0.008(2)0.024(3)−0.005(2)
C(46)4e0.4468(4)0.0155(2)0.6334(2)0.037(2)0.033(2)0.034(3)0.000(2)0.013(2)0.002(2)
C(47)4e0.6509(4)0.0400(3)0.6839(4)0.040(3)0.080(4)0.093(5)−0.003(3)0.027(3)−0.023(4)
C(51)4e0.0723(4)0.1236(2)0.8356(3)0.035(3)0.046(3)0.035(3)−0.003(2)0.013(2)−0.008(2)
C(52)4e0.0762(5)0.0592(3)0.8693(3)0.051(3)0.057(3)0.052(3)−0.004(3)0.027(3)0.001(3)
C(53)4e−0.0074(6)0.0394(3)0.9006(3)0.084(5)0.080(4)0.071(4)−0.019(4)0.053(4)−0.004(3)
C(54)4e−0.0974(6)0.0837(4)0.8970(4)0.073(5)0.105(5)0.101(6)−0.025(4)0.066(5)−0.015(5)
C(55)4e−0.1036(5)0.1493(4)0.8644(4)0.057(4)0.106(5)0.084(5)0.008(4)0.045(4)−0.018(4)
C(56)4e−0.0171(4)0.1709(3)0.8342(3)0.045(3)0.061(4)0.058(4)0.007(3)0.026(3)−0.015(3)
C(57)4e−0.0946(6)0.2881(4)0.8079(5)0.076(5)0.085(5)0.151(8)0.039(4)0.048(5)−0.014(5)
C(61)4e0.1935(5)0.2543(3)0.5898(4)0.074(4)0.055(4)0.101(5)0.013(3)0.054(4)0.024(3)
C(62)4e0.2206(6)0.3217(4)0.5759(5)0.094(5)0.065(4)0.150(8)0.012(4)0.075(6)0.050(5)
C(63)4e0.1944(6)0.3759(3)0.6149(5)0.068(5)0.046(4)0.140(7)−0.010(3)0.022(5)0.034(4)
C(64)4e0.1400(5)0.3607(3)0.6660(4)0.059(4)0.042(3)0.077(5)0.003(3)−0.006(3)0.009(3)
C(65)4e0.1144(4)0.2917(3)0.6772(3)0.040(3)0.039(3)0.056(4)0.000(2)0.001(2)0.006(2)
N(6)4e0.1417(3)0.2381(2)0.6401(2)0.031(2)0.039(2)0.055(3)0.005(2)0.012(2)0.012(2)
O(1)4e0.3731(3)0.0579(2)0.9874(2)0.079(3)0.080(3)0.035(2)−0.006(2)0.023(2)0.014(2)
O(2)4e0.2407(3)−0.0619(2)0.7810(2)0.061(2)0.030(2)0.076(3)−0.013(2)0.013(2)−0.004(2)
O(3)4e0.5943(3)0.0118(2)0.8468(2)0.041(2)0.049(2)0.064(3)0.018(2)0.013(2)0.002(2)
O(4)4e0.0181(4)0.1013(2)0.4867(2)0.058(3)0.117(3)0.041(3)−0.008(2)0.007(2)−0.006(2)
O(5)4e−0.1589(3)0.1663(2)0.6436(2)0.029(2)0.081(3)0.079(3)0.008(2)0.022(2)0.004(2)
O(6)4e0.0012(3)−0.0178(2)0.6794(2)0.059(2)0.045(2)0.087(3)−0.019(2)0.022(2)0.001(2)
O(46)4e0.5329(3)0.0567(2)0.6778(2)0.032(2)0.050(2)0.058(2)−0.001(2)0.016(2)−0.014(2)
O(56)4e−0.0153(3)0.2345(2)0.8021(2)0.055(2)0.060(2)0.085(3)0.024(2)0.031(2)−0.001(2)
P(1)4e0.46485(9)0.19625(5)0.86182(6)0.0293(6)0.0253(5)0.0277(6)0.0000(4)0.0086(5)−0.0009(5)
S(1)4e0.30648(9)0.10391(5)0.68347(6)0.0274(5)0.0283(5)0.0305(6)−0.0001(4)0.0102(4)−0.0007(4)
S(2)4e0.17499(9)0.15229(5)0.79238(6)0.0299(6)0.0301(6)0.0384(7)0.0021(4)0.0140(5)0.0003(5)
Re(1)4e0.35833(2)0.08222(2)0.82395(2)0.02838(9)0.02323(9)0.0292(1)0.00071(7)0.01005(7)0.00105(7)
Re(2)4e0.09088(2)0.12764(2)0.65538(2)0.02553(9)0.0337(1)0.0361(1)0.00031(7)0.00939(8)0.00241(8)

Source of material

fac-[NEt4]2[Re(CO)3Br3] (50 mg, 6.5 × 10−5 mol), as prepared according to the method described by Alberto et al. [21], and 2-methoxythiophenol were dissolved in methanol (10 mL). Triphenylphosphine (17.05 mg, 6.5 × 10−5 mol) and sodium bicarbonate (5.5 mg, 6.5 × 10−5 mol) were added to the solution. After stirring for 48 hours at room temperature a yellow precipitate was obtained. The product was filtered, dried and weighed. Yield: 22 mg (29%). Yellow crystals were obtained from recrystallization in a 3:1 ratio of dichloromethane: methanol. IR (cm−1, KBr): 2026, 2008, 1933, 1902. 1H NMR (300 MHz) δ = 7.76 (d, 2H), 7.65 (d, 11H), 7.41 (m, 7H), 7.26 (d, 5H), 7.15 (d, 2H), 6.91 (d, 4H), 3.83 (s, 6H). Pyridine did not form part of the synthetic or crystallization procedure of the title compound but we suspect the pyridine in the reported structure came from a neighbouring solution where pyridine was used for the recrystallization of another complex.

Experimental details

The methoxy and aromatic H atoms were placed in geometrically idealized positions and constrained to ride on their parent atoms, with C—H = 0.93 and 0.96 Å and Uiso(H) = 1.5Ueq(C) and 1.2Ueq(C), respectively. The highest peak (1.62 e Å−3) is located 0.86 Å from Re1 and the deepest hole (−1.22 e Å−3) is situated 0.75 Å from Re1.

Discussion

The title compound, Re2C43H34NO8PS2 is synthesized from the Re(I)-tricarbonyl precursor which is currently under investigation in radiopharmaceutical research [1, 2]. The organometallic fragment fac-[M(CO)3]+ (M = Tc/Re) is used as a versatile synthon for the conjugation of biomolecules with technetium or rhenium [3–7]. One of the major advantages in using the fac-[M(CO)3]+ (M = Tc/Re) core is its high stability and efficient preparation in aqueous media. It also has the potential of exchanging specifically the labile solvent ligands (i.e. water) to allow for the coordination of multidentate ligand systems [8, 9]. This contribution forms part of a long-term study to investigate different aspects of middle and late transition metal centers when coordinated to O, N and S donor ligands [10–19].

The dinuclear structure (Figure) crystallized with one crystallographically independent molecule in the asymmetric unit. The dinuclear molecule has a Re2(μ-S)2 unit at the center. Each sulfido-bridge is asymmetrical, with unequal Re—S distances of 2.5006(13) Å, [Re(1)—S(2)]; 2.5507(13) Å, [Re(1)—S(1)]; 2.4974(13) Å, [Re(2)—S(2)] and 2.5439(15) Å, [Re(2)—S(1)]. The bond angle Re(2)—S(1)—Re(1) and Re(2)—S(2)—Re(1) are 98.01(3)° and 100.59(4)° and S(2)—Re(1)—S(1) and S(2)—Re(2)—S(1) are 76.26(4)° and 76.44(4)°, respectively. The bond distances and angles, when compared to the structures reported by Gerber et al. [18] and Vanitha et al. [19], were found to be similar. The Re—Re distance is derived as 3.845 Å. The dinuclear complex consists of two distorted octahedral Re(I) fragments. The Re(I) centers are each coordinated by three carbonyl ligands and two mono-charged sulphur atoms as monodentate ligands. Re(2) is coordinated to a pyridine ligand in the sixth position with a 2.234(4) Å [Re(2)—N(1)] bond distance. Pyridine is a soft ligand that coordinates very easily to the Re(I) centre. Re(1) on the other hand is coordinated to a triphenylphosphine ligand in the sixth position with a bond distance of 2.5103(12) Å [Re(1)—P(1)]. Therefore, the reaction of 2-methoxythiophenol with fac-[NEt4]2[Re(CO)3Br3] formed a neutral dinuclear complex.

Corresponding author: Pheello Isaac Nkoe, Department of Chemistry, University of the Free State, P. O. Box 339, Bloemfontein 9300, South Africa, e-mail:

Acknowledgements:

Financial assistance from the University of the Free State is gratefully acknowledged. We also express our gratitude towards PETLabs Pharmaceuticals, SASOL, Thuthuka, the South African National Research Foundation (SA-NRF/THRIP) and Prof A. Roodt. This work is based on the research supported in part by the National Research Foundations of South-Africa and the Thuthuka Programme (Grant specific unique reference numbers (UID) 84913 and 84266).

References

1. Schutte, M.; Visser, H. G.: Aquatricarbonyl(4-carboxypyridine-2-carboxylato-k2N, O2)rhenium(I). Acta Crystallogr. E64 (2008) m1226–01227.10.1107/S160053680802761XSearch in Google Scholar

2. Brink, A.; Visser, H. G.; Roodt, A.: Activation of rhenium(I) toward substitution in fac-[Re(N,O′-Bid)(CO)3(HOCH3)] by Schiff-base bidentate ligands (N,O′-Bid). Inorg. Chem. 52 (2013) 8950–8961.10.1021/ic401115jSearch in Google Scholar

3. Alberto, R.; Schibi, R.; Schubiger, A. P.; Abram, U.; Pietzsch, H.-J.; Johannsen, B.: First application of fac-[99mTc(OH2)3(CO)3]+ in bioorganometallic chemistry: design, structure, and in vitro affinity of a 5-HT1A receptor ligand labeled with 99mTc. J. Am. Chem. Soc. 121 (1999) 6076–6077.10.1021/ja990765aSearch in Google Scholar

4. Schutte, M.; Roodt, A.; Visser, H. G.: Coordinated aqua vs methanol substitution kinetics in fac -Re(I) tricarbonyl tropolonato complexes. Inorg. Chem. 51 (2012) 11996–12006.10.1021/ic301891uSearch in Google Scholar

5. Brink, A.; Visser, H. G.; Roodt, A. Solid state isostructural behavior and quantified limiting substitution kinetics in Schiff-base bidentate ligand complex fac-[Re(O,N-Bid)(CO)3(MeOH)]n. Inorg. Chem. 53 (2014) 12480–12488.10.1021/ic5019168Search in Google Scholar

6. Waibel, R.; Alberto, R.; Willuda, J.; Finnern, R.; Schibi, R.; Stichelberger, A.; Egli, A.; Abram, U.; Mach, J.-P.; Plückthum, A.; Schubiger, P. A.: Stable one-step technetium-99m labeling of His-tagged recombinant proteins with a novel Tc(I)-carbonyl complex. Nat. Biotechnol. 17 (1999) 187–901.10.1038/12890Search in Google Scholar

7. Werner, K.; Marten, W.; Christian, M. J.; Franziska, E.; Hans-Jürgen, P.: Bromotricarbonyl{15-[2-(methylsulfanyl)ethylsulfanyl]pentadecanoic acid-κ2S,S′}rhenium(I). Acta Crystallogr. E62 (2006) m1660–m1662.10.1107/S1600536806024081Search in Google Scholar

8. Henrik, B.; Ulrich, A.: Tricarbonyl complexes of rhenium (I) and technetium (I) with thiourea derivatives. J. Organomet. 689 (2004) 2066–2072.10.1016/j.jorganchem.2004.03.017Search in Google Scholar

9. Alberto, R.; Schibli, R.; Waibel, R.; Abram, U.; Schchubiger, A. P.: Basic aqueous chemistry of [M(OH2)3(CO)3]+ (M = Re, Tc) directed towards radiopharmaceutical application. Coord. Chem. Rev. 190–192 (1999) 9001–9019.10.1016/S0010-8545(99)00128-9Search in Google Scholar

10. Roodt, A.; Basson, S. S.; Leipoldt, J. G.: Studies on the substitution reaction of dioxotetracyanometalate systems with bidentate ligands: kinetics of the reaction between aquaoxotetracyanotungstate(IV) and 2-pyridinecarboxylate ions. Polyhedron 13 (1994) 599–607.10.1016/S0277-5387(00)84737-3Search in Google Scholar

11. Graham, D. E.; Lamprecht, G. J.; Potgieter, I. M.; Roodt, A.; Leipoldt, J. G.: Observed trans influence of donor atoms in monocharged bidentate ligands-crystal- structure of acetone solvate of 2-carboxyquinolinatocarbonyltriphenylphosphinerhodium(I). Transition Met. Chem. 16(2) (1991) 193–195.10.1007/BF01032832Search in Google Scholar

12. Van Aswegen, K. G.; Leipoldt, J. G.; Potgieter, I. M.; Lamprecht, G. J.: The crystal-structure of the acetone adduct of trans-methyliodo-8-hydroxyquinolinatocarbonyltriphenylphosphinerhodium(III). Transition Met. Chem. 16 (1991) 369–371.10.1007/BF01024085Search in Google Scholar

13. Purcell, W.; Roodt, A.; Basson, S. S.; Leipoldt, J. G.: Kinetic-study of the reaction between trans-tetracyanodioxorhenate(V) and thiocyanate ions. Transition Met. Chem. 14 (1989) 224–226.10.1007/BF01043801Search in Google Scholar

14. Kemp, G.; Roodt, A.; Purcell, W.; Koch, K.: Unprecedented N,S,O Co-ordination of the doubly deprotonated anion of N-benzoyl-N′-phenylthiourea(H2L2) bridging two rhodium(I) centres: crystal structure of the acetone solvate of [(PPh3)2(CO)Rh(μ-L2-κN′:κO,S)Rh(PPh3)(CO)]. J. Chem. Soc., Dalton Trans. 23 (1997) 4481–4483.10.1039/a705887jSearch in Google Scholar

15. Roodt, A.; Visser, H. G.; Brink, A.: Structure/reactivity relationships and mechanism from X-ray data and spectroscopic kinetic analysis. Crystallogr. Rev. 17 (2011) 241–280.10.1080/0889311X.2011.593032Search in Google Scholar

16. Schutte, M.; Kemp, G.; Visser, H. G.; Roodt, A.: Tuning the reactivity in classic low-spin d6 rhenium(I) tricarbonyl radiopharmaceutical synthon by selective bidentate ligand variation. Inorg. Chem. 50(24) (2011) 12486–12498.10.1021/ic2013792Search in Google Scholar PubMed

17. Sacht, C.; Datt, M. S.; Otto, S.; Roodt, A.: Synthesis, characterisation and coordination chemistry of novel chiral N,N-dialkyl-N-menthyloxycarbonylthioureas. Crystal and molecular structures of N,N-diethyl-Ar′-(-)(3LR)-methyloxycarbonylthiourea and m-(S,S)-[Pt(L)Cl(DMSO)][where HL = N-(+)(3JR)-menthyloxycarbonyl-A′-morpholinothiourea or W-benzoylAr′,W-diethylthiourea]. J. Chem. Soc. Dalton Trans. 24 (2000) 4579–4586.10.1039/b007589mSearch in Google Scholar

18. Gerber, T. I. A.; Betz, R.; Booysen, I. N.; Potgieter, K. C.; Mayer, P.: Coordination of bidentate aniline dirivatives to the fac-[Re(CO)3]+ core. Polyhedron. 30 (2011) 1739–1745.10.1016/j.poly.2011.04.019Search in Google Scholar

19. Vanitha, A.; Sathiya, P.; Sangilipandi, S.; Shaikh, M. M.; Bala, M.: One-pot synthesis of sulphur bridged dinuclear rhenium metallacycles via addition of S—S bond across Re—Re bond. J. Organomet. Chem. 695 (2010) 1458–1463.10.1016/j.jorganchem.2010.02.027Search in Google Scholar

20. Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed

21. Alberto, R.; Schibli, R.; Schubiger, P. A.; Abram, U.; Kaden, T. A.: Synthesis and structure of technetium(I) and rhenium(I) tricarbonyl complexes with bis(diphenylthiophosphoryl)amide, {M(CO)3[(Ph2PS)2N](CH3CN)}. Polyhedron. 15 (1996) 1079–1089.10.1016/0277-5387(95)00361-4Search in Google Scholar

22. Bruker: APEX2 (Version 2012.10–0), SAINT (version 8.27B), SADABS. Bruker AXS Inc., Madison, Wisconsin, USA 2004.Search in Google Scholar

23. Farrugia, L. J.: WinGX: suite for small-molecule single-crystal crystallography. J. Appl. Crystallogr. 32 (1999) 837–838.10.1107/S0021889899006020Search in Google Scholar

24. Brandenburg, K.: DIAMOND. Crystal Impact GbR, Bonn, Germany 2006.Search in Google Scholar

Received: 2015-7-3
Accepted: 2016-2-29
Published Online: 2016-3-23
Published in Print: 2016-6-1

©2016 Pheello Isaac Nkoe et al., published by De Gruyter.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of fac-hexacarbonylbisμ2-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ3N,N′:O-dirhenium(I) tetrahydrate, C30H22N4O18Re2
  3. The crystal structure of bis(4-(2,4-dimethylphenyl)piperazin-1-yl)methane, C25H36N4
  4. Crystal structure of bis(triphenylphosphine-κP)bis(μ2-1H,1′H-2,2′-biimidazole-κ3N,N′:N′)disilver(I) bis(tetrafluoroborate), C48H42Ag2B2F8N8P2
  5. The crystal structure of 1,2-bis(2-pyrazinecarboxamido)-benzene, C16H12N6O2
  6. Redetermination of the crystal structure of 3-bromobenzoic acid, C7H5BrO2
  7. Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidocuprate(II), (C20H20P)2[CuBr4]
  8. Crystal structure of 2-(4-bromophenyl)-1,3-dimethyl-2,3-dihydro-1H-perimidine, C19H17BrN2
  9. Crystal structure of trans-diaqua-bis(3-(pyrazin-2-yl)-5-(pyridin-4-yl)1,2,4-triazol-1-ido-κ2N,N′)-cobalt(II),C22H18CoN12O2
  10. Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MnN6O12S2
  11. Crystal structure of butyl 2-(3,5-dimethyl-1,1-dioxido-2H-1,2,6-thiadiazin-4-yl)benzoate, C16H20N2O4S
  12. Crystal structure of hexaaquabis(μ2-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)bis(μ3-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)tetra-manganese(II) dihydrate, C48H40Mn4N24O16
  13. Crystal structure of catena-poly[diaqua-bis(μ2-1,3-di(pyridin-4-yl)propane-κ2N:N′)cadmate(II)] bis(2-aminoisonicotinate) tetrahydrate, C38H50CdN8O10
  14. Crystal structure of succinic acid — 4-((pyridin-4-ylmethyl)sulfanylpyridine (1/1), C15H16N2O4S
  15. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)bis(2-((pyridin-4-ylmethyl)sulfanyl)pyridine-κN)dicopper(II), C30H32N4O8S2Cu2
  16. Crystal structure of 1-((2R,3S)-2,3-dimethyl-2,3-dihydro-4H-benzo[b][1,4]oxazin-4-yl)-2-phenoxyethan-1-one, C18H19NO3
  17. Crystal structure of tetramethylammonium sulfanilate, C10H18N2O3S
  18. Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C20H25NO4
  19. Crystal structure of 2-(4-acetyl-2,6-dimethylphenyl)-5,6-dichloro-1H-isoindole-1,3(2H)-dione, C18H13Cl2NO3
  20. Crystal structure of diaqua-bis(μ3-2-methyl-6-oxidopyridinium-4-carboxylato-κ3O:O′:O′′)neodymium(III) chloride, C14H16ClN2O8Nd
  21. Crystal structure of 5-methoxy-4-methyl-2-(2-methylbenzyl)-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H15N3O2
  22. The crystal structure of 1-(4-(2-chloroethoxy)phenyl)ethanone
  23. Crystal structure of (E)-4-(2-(4-(diethylamino)phenyl)diazen-1-ium-1-yl)benzenesulfonate monohydrate
  24. Crystal structure of 2,2′-[(1E)-prop-1-ene-1,2-diyldisulfanediyl]bis(5-methyl-2,5-dihydro-1,3,4-thiadiazole, C9H10N4S4
  25. Crystal structure of poly [μ2-acetato-κ3-O,O′:O′)diaqua(μ3-isophthalato-κ4O,O′:O′′:O′′′)cerium(III)] monohydrate (C10H13O9Ce)
  26. Crystal structure of tris((2-(2,2-dicyanovinyl)phenoxy)ethyl)amine, C36H27N7O3
  27. Crystal structure of catena[diaqua-bis(μ2-1,3-bis((1H-tetrazol-1-yl)methyl)benzene-κ2N:N′)copper(II)] dinitrate, C20H24CuN18O8
  28. Crystal structure of (4-(1H-imidazol-5-yl)benzoic acid-κN) (4-(1H-imidazol-5-yl)benzoato-κN)silver(I), C20H15N4O4Ag
  29. Crystal structure of 2-amino-3-cyano-7,7-dimethyl-5-oxo-4-(3,4,5-trifluorophenyl)-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C18H15F3N2O2
  30. Crystal structure of (2-(2-chlorophenyl)-5-ethyl-1,3-dioxan-5-yl)methanol hemihydrate, C13H17ClO3 · 0.5 H2O
  31. Crystal structure of catena-poly[diaqua-bis(benzene-1,2,4,5-tetracarboxylato-κN)(m2-2-(1H-1,2,4-trizol-1-ylmethyl)-1H-3,1-benzimidazol-3-ium-κ2O:O′)zinc(II)] dihydrate, C30H30N10O12Zn
  32. Crystal structure of [2,2′-((((ethane-1,2-diylbis(oxy-κ2O,O′))bis(2,1-phenylene))bis(azanylylidene-κ2N,N′))bis(methanylylidene))diphenolato-κ2O′′,O′′′]zinc(II), C28H22N2O4Zn
  33. Crystal structure of (E)-1-(3,4-dimethoxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C13H17NO3
  34. Crystal structure of bis(2-fluoro-4-nitrophenyl) terephthalate C20H10F2N2O8
  35. Crystal structure of catena-[aqua((4-carboxyphenyl)acetato-κO)(μ2-(4-carboxyphenyl)acetato-κ2O:O′)bis(4,4′-ethene-1,2-diyldipyridine-κN)manganese(II)], C42H36N4O9Mn
  36. Crystal structure of N′-(2-hydroxybenzylidene)-3,4-dimethyl-1H-pyrrole-2-carbohydrazide, C14H15N3O2
  37. Crystal structure of bis(8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato-κ2O,O′)copper(II) benzene-1,4-dicarboxylate dihydrate, C36H42CuN10O12
  38. Crystal structure of diaquabis(μ2-biphenyl-2,2′-dicarboxylato-κ2O:O′)bis(1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-3-quinolinecarboxylato)zinc(II), C60H56N6Zn2O16F2
  39. Crystal structure of 2-amino-4-(4-fluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13FN2O2
  40. The crystal structure of hexaqua(μ2-3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-1κ2O,O′;2κO′)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κO)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κ2O,O′)digadolinium(III) octahydrate, C60H76Gd2N18O32
  41. Crystal structure of hexacarbonyl bis(μ2-2-methoxybenzenethiolato-κ2S)pyridine(triphenylphosphane)dirhenium(I), C43H34NO8PS2Re2
  42. Crystal structure of 14-((1-(benzyloxycarbonyl-amino)-2-methylpropan-2-yl)sulfanyl)acetate Mutilin, C34H49NO6S
  43. Crystal structure of 2-methoxy-6-(((2-(1-methyl-1H-benzo[d] imidazol-2-yl)phenyl)imino)methyl)phenol — ethanol (1/1), C24H25N3O3
  44. Crystal structure of 2-(bis(methylthio)methylene)-1-phenylbutane-1,3-dione, C13H14O2S2
  45. Crystal structure of (E)-2-(bis(methylthio)methylene)-1-phenyl-3-(2-phenylhydrazono)butan-1-one, C19H20N2OS2
  46. Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ2N,N′)zinc(II)
  47. Crystal structure of bis(1-methyl-1H-tetrazole-5-thiolato)mercury(II)
  48. Crystal structure of (E)-2-styryl-1-ferrocenylsulfonyl-1H-imidazo[4,5-b]pyridine, C24H19FeN3O2S
  49. Crystal structure of aquabis(1-cyclopropyl-6-fluoro-4-oxo-7-(piperazin-4-ium-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O,O′)copper(II) thiophene-2,5-dicarboxylate trihydrate, [Cu(C17H18N3FO3)2(H2O)](C6H2SO4)·3(H2O)
  50. Crystal structure of 2-amino-4-(2,6-dichlorophenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H16Cl2N2O2
  51. Crystal structure of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5·5·0·05·9·03·11]dodecane 1/3 hydrate, C6H8N12O13
  52. Crystal structure of monocarbonyl(N-nitroso-N-oxido-phenylamine-κ2O,O′)(triphenylarsine-κAs)rhodium(I), C25H20AsN2O3Rh
  53. The crystal structure of 1-(4-(4-chlorophenoxy)-2-chlorophenyl)ethanone, C14H10Cl2O2
  54. Crystal structure of N,N-diethyl-2-(2-(6-(4-methoxybenzyl)-7-oxo-7H-thiazolo[3,3-b][1,2,4]triazin-3-yl)phenoxy)acetamide, C25H26N4O4S
  55. Crystal structure of tetraqua((E)-4,4′-(diazene-1,2-diyl)bis(5-oxo-4,5-dihydro-1,2,4-triazol-1-ide)-κ2N:O)barium(II), C4H10N8O6Ba
  56. Crystal structure of 2-amino-4-(3-phenoxyphenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C22H18N2O3
  57. Crystal structure of diethylammonium 5-((4-fluorophenyl)(6-hydroxy-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl)-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate, C23H30FN5O6
  58. Crystal structure of 2-amino-4-(3,5-difluoro-phenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12F2N2O2
  59. Crystal structure of tris(N-nitroso-N-oxyanilino-κ2O, O′) oxidoniobium(V), C18H15N6O7Nb
  60. Crystal structure of 1-(5-benzoyl-4-methyl-2-(phenylamino)thiophen-3-yl)ethan-1-one, a structure with Z′ = 6, C20H17NO2S
  61. Crystal structure of diethyl-3-methyl-4-phenylthieno[2,3-b]thiophene-2,5-dicarboxylate, C19H18O4S2
  62. Crystal structure of 3,5-dicarboxybenzoate — benzene-1,3,5-tricarboxylic acid (1/1), C24H22N2O12
  63. The crystal structure of 2-chloro-1,3-bis(2,4,6-trimethylphenyl)-4,4-dimethyl-1,3,2λ3,4-diazaphosphasiletidine
  64. Crystal structure of hexaquamanganese(II) bis(hexaborato-κ3O,O′,O′′)manganese(II) dihydrate, B12H28Mn2O34
  65. Crystal structure of 1-propyl-3-methylimidazolium pentaborate, [C7H13N2][B5O6(OH)4]
  66. Crystal structure of 13-(4-fluorophenyl)-11,13-dihydro-1H-benzo[h]indazolo[6,7-b] [1, 6]naphthyridin-12(6H)-one — dimethylformamide — water (1/2/1), C29H31FN6O4
  67. Crystal structure of 1-(2-chlorophenyl)-2-(2-nitrophenyl)ethan-1-ol, C14H12ClNO3
  68. Crystal structure of (Z)-2-((2-bromo-1-phenylvinyl)oxy)benzonitrile, C15H10BrNO
  69. Crystal structure of tetrachlorido(1E,1′E)-N,N′-((1,4-phenylenebis(propane-2,2-diyl))bis(4,1-phenylene))bis(1-(pyridin-2-yl-κN)methanimine-κN)dizinc(II), C36H34N4Zn2Cl4
  70. Crystal structure of 2,6-bis(3-methylpyridinyl)hexahydro-4,8-ethenopyrrolo-[3,4-f]isoindole-1,3,5,7(2H,6H)-tetrone, C24H20N4O4
  71. Crystal structure of trans-bis(2-methylmaleato-κ2O,O′) bis(piperazinium-κN) cobalt(II) trihydrate, C18H36CoN4O11
  72. Crystal structure of (E)-4-chloro-N′-(4-(diethylamino)benzylidene)benzohydrazide, C18H20ClN3O
  73. Crystal structure of 3,6-di(1H-imidazol-1-yl)-9H-carbazole, C18H13N5
  74. Crystal structure of 4-(4-pyridinyl)-1-naphthoic acid, C16H11NO2
  75. Crystal structure of 1,1′-diformyl-4,4′-(6H,12H-5,11-methano-dibenzo[b,f][11,5]diazocine-2,8-diyl)dibenzene, C29H22N2O2
  76. Crystal structure of N′-(adamantan-2-ylidene)pyridine-3-carbohydrazide, C16H19N3O
  77. Crystal structure of 1,1′-(butane-1,4-diyl)bis(5-methyl-1H-pyrazole-3-carbaldehyde), C14H18N4O2
  78. Crystal structure of methyl 8-hydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylate, C21H34O3
  79. Crystal structure of 6-oxo-4-propyl-2-(propylthio)-1,6-dihydropyrimidine-5-carbonitrile, C11H15N3OS
  80. Crystal structure of poly[diacetato(μ2-1,4-bis(1H-imidazol-1-yl)benzene-κ2N:N′)nickel(II)], C26H22N8NiO4
  81. Crystal structure of bis(2,4-dibromo-6-{(E)[(4-fluorobenzyl)imino]methyl}phenolato-κ2N,O) copper(II), C28H18Br4F2N2O2Cu
  82. Crystal structure of 1-(adamantan-1-yl)-3-phenylthiourea, C17H22N2S
  83. Crystal structure of 3-(6-(5-amino-1-phenyl-1H-pyrazol-3-yl)pyridin-2-yl)-1-phenyl-1H-pyrazol-5-amine – dioxan (2/1), C25H23N7O
  84. Crystal structure of 5-ethyl-6-[(3-methylphenyl)sulfanyl]pyrimidine-2,4(1H,3H)-dione, C13H14N2O2S
  85. Crystal structure of (((1E,1′E)-(cyclohexane-1,2-diylbis(azanylylidene-κ2N,N′))bis(methanylylidene))bis(2,1-phenylene))bis((2,6-diisopropylphenyl)amide-κ2N′′,N′′′)manganese(II), C44H54N4Mn
  86. Crystal structure of prop-2-en-1-yl 2-oxo-2H-1-benzopyran-3-carboxylate, C13H10O4
  87. Crystal structure of bis(μ2-2-((3-methylphenyl)imino)methylphenolato-κ2N,O:O)hexacarbonyldimanganese(I), C34H24Mn2N2O8
  88. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxybut-2-en-1-one C9H12N2O2
  89. Crystal structure of 2,2′-[pentane-1,5-diylbis(oxy)]dibenzaldehyde, C19H20O4
  90. Crystal structure of 2-phenyl-5,6,7,8-tetrahydro-4H-benzo[4,5]thieno[2,3-d][1,3]oxazin-4-one, C16H13NO2S
  91. Crystal structure of (E)-1-(2-chlorophenyl)-N-(4-chlorophenyl)methanimine, C13H9Cl2N
  92. Crystal structure of ethyl 2-amino-5-bromothiazole-4-carboxylate, C6H7BrN2O2S
  93. Crystal structure of 2-benzylisothiouronium tetraphenylborate, C32H31BN2S
  94. Crystal structure of poly[(μ2-biphenyl-2,2′-dicarboxylato-κ4O,O′:O′′,O′′′)(μ2-4,4′-bipyridine-κ2N:N′)copper(II)], C24H16CuN2O4
  95. Crystal structure of (η5-pentamethylcyclopentadienyl)titanium(III)dichloride (THF), C14H23Cl2OTi
  96. Crystal structure of 3-ferrocenylsulfonyl-2-(4-methoxyphenyl)-3H-imidazo[4,5-b]pyridine, C23H19FeN3O3S
  97. Crystal structure of 2-benzoyl-3-(4-fluorophenyl)cyclopropane-1,1-dicarbonitrile, C18H11FN2O
  98. Crystal structure of 1,6-ditosyl-1,6-diazecane, C22H30N2O4S2
  99. Crystal structure of N-phenyl-2-(pyridin-4-ylcarbonyl)hydrazinecarboxamide with Z′ = 4, C13H12N4O2
  100. Crystal structure of N,N-bis(diphenylphosphanyl)cyclohexylamine, C30H31NP2
  101. Crystal structure of 3-(4-hydroxy-3-methoxyphenyl)-N-phenylpropanamide, C16H17NO3
  102. Crystal structure of 6-(2-fluorophenyl)-3-phenyl-[1,2,4]-triazolo[3,4-b][1,3,4]thiadiazole, C15H9FN4S
  103. Crystal structure of catena-poly[aqua(dicyanoazanido-2κN-μ2-dicyanoazanido-1κN:2κN′)(μ2-2-methoxy-6-(((2-((3-methoxy-2-oxidobenzylidene)amino)ethyl)imino)methyl)phenolato-1κ2N,N′,2κ2O,O′,1κ2O′′,O′′′:2κ2O′′,O′′′)cadmium(II)copper(II)], C22H20CdCuN8O5
https://doi.org/10.1515/ncrs-2015-0139
Creative Commons
BY-NC-ND 3.0

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of fac-hexacarbonylbisμ2-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ3N,N′:O-dirhenium(I) tetrahydrate, C30H22N4O18Re2
  3. The crystal structure of bis(4-(2,4-dimethylphenyl)piperazin-1-yl)methane, C25H36N4
  4. Crystal structure of bis(triphenylphosphine-κP)bis(μ2-1H,1′H-2,2′-biimidazole-κ3N,N′:N′)disilver(I) bis(tetrafluoroborate), C48H42Ag2B2F8N8P2
  5. The crystal structure of 1,2-bis(2-pyrazinecarboxamido)-benzene, C16H12N6O2
  6. Redetermination of the crystal structure of 3-bromobenzoic acid, C7H5BrO2
  7. Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidocuprate(II), (C20H20P)2[CuBr4]
  8. Crystal structure of 2-(4-bromophenyl)-1,3-dimethyl-2,3-dihydro-1H-perimidine, C19H17BrN2
  9. Crystal structure of trans-diaqua-bis(3-(pyrazin-2-yl)-5-(pyridin-4-yl)1,2,4-triazol-1-ido-κ2N,N′)-cobalt(II),C22H18CoN12O2
  10. Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MnN6O12S2
  11. Crystal structure of butyl 2-(3,5-dimethyl-1,1-dioxido-2H-1,2,6-thiadiazin-4-yl)benzoate, C16H20N2O4S
  12. Crystal structure of hexaaquabis(μ2-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)bis(μ3-3-(6-carboxylatopyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazol-1-ido)tetra-manganese(II) dihydrate, C48H40Mn4N24O16
  13. Crystal structure of catena-poly[diaqua-bis(μ2-1,3-di(pyridin-4-yl)propane-κ2N:N′)cadmate(II)] bis(2-aminoisonicotinate) tetrahydrate, C38H50CdN8O10
  14. Crystal structure of succinic acid — 4-((pyridin-4-ylmethyl)sulfanylpyridine (1/1), C15H16N2O4S
  15. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)bis(2-((pyridin-4-ylmethyl)sulfanyl)pyridine-κN)dicopper(II), C30H32N4O8S2Cu2
  16. Crystal structure of 1-((2R,3S)-2,3-dimethyl-2,3-dihydro-4H-benzo[b][1,4]oxazin-4-yl)-2-phenoxyethan-1-one, C18H19NO3
  17. Crystal structure of tetramethylammonium sulfanilate, C10H18N2O3S
  18. Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C20H25NO4
  19. Crystal structure of 2-(4-acetyl-2,6-dimethylphenyl)-5,6-dichloro-1H-isoindole-1,3(2H)-dione, C18H13Cl2NO3
  20. Crystal structure of diaqua-bis(μ3-2-methyl-6-oxidopyridinium-4-carboxylato-κ3O:O′:O′′)neodymium(III) chloride, C14H16ClN2O8Nd
  21. Crystal structure of 5-methoxy-4-methyl-2-(2-methylbenzyl)-2,4-dihydro-3H-1,2,4-triazol-3-one, C12H15N3O2
  22. The crystal structure of 1-(4-(2-chloroethoxy)phenyl)ethanone
  23. Crystal structure of (E)-4-(2-(4-(diethylamino)phenyl)diazen-1-ium-1-yl)benzenesulfonate monohydrate
  24. Crystal structure of 2,2′-[(1E)-prop-1-ene-1,2-diyldisulfanediyl]bis(5-methyl-2,5-dihydro-1,3,4-thiadiazole, C9H10N4S4
  25. Crystal structure of poly [μ2-acetato-κ3-O,O′:O′)diaqua(μ3-isophthalato-κ4O,O′:O′′:O′′′)cerium(III)] monohydrate (C10H13O9Ce)
  26. Crystal structure of tris((2-(2,2-dicyanovinyl)phenoxy)ethyl)amine, C36H27N7O3
  27. Crystal structure of catena[diaqua-bis(μ2-1,3-bis((1H-tetrazol-1-yl)methyl)benzene-κ2N:N′)copper(II)] dinitrate, C20H24CuN18O8
  28. Crystal structure of (4-(1H-imidazol-5-yl)benzoic acid-κN) (4-(1H-imidazol-5-yl)benzoato-κN)silver(I), C20H15N4O4Ag
  29. Crystal structure of 2-amino-3-cyano-7,7-dimethyl-5-oxo-4-(3,4,5-trifluorophenyl)-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C18H15F3N2O2
  30. Crystal structure of (2-(2-chlorophenyl)-5-ethyl-1,3-dioxan-5-yl)methanol hemihydrate, C13H17ClO3 · 0.5 H2O
  31. Crystal structure of catena-poly[diaqua-bis(benzene-1,2,4,5-tetracarboxylato-κN)(m2-2-(1H-1,2,4-trizol-1-ylmethyl)-1H-3,1-benzimidazol-3-ium-κ2O:O′)zinc(II)] dihydrate, C30H30N10O12Zn
  32. Crystal structure of [2,2′-((((ethane-1,2-diylbis(oxy-κ2O,O′))bis(2,1-phenylene))bis(azanylylidene-κ2N,N′))bis(methanylylidene))diphenolato-κ2O′′,O′′′]zinc(II), C28H22N2O4Zn
  33. Crystal structure of (E)-1-(3,4-dimethoxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C13H17NO3
  34. Crystal structure of bis(2-fluoro-4-nitrophenyl) terephthalate C20H10F2N2O8
  35. Crystal structure of catena-[aqua((4-carboxyphenyl)acetato-κO)(μ2-(4-carboxyphenyl)acetato-κ2O:O′)bis(4,4′-ethene-1,2-diyldipyridine-κN)manganese(II)], C42H36N4O9Mn
  36. Crystal structure of N′-(2-hydroxybenzylidene)-3,4-dimethyl-1H-pyrrole-2-carbohydrazide, C14H15N3O2
  37. Crystal structure of bis(8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato-κ2O,O′)copper(II) benzene-1,4-dicarboxylate dihydrate, C36H42CuN10O12
  38. Crystal structure of diaquabis(μ2-biphenyl-2,2′-dicarboxylato-κ2O:O′)bis(1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-3-quinolinecarboxylato)zinc(II), C60H56N6Zn2O16F2
  39. Crystal structure of 2-amino-4-(4-fluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13FN2O2
  40. The crystal structure of hexaqua(μ2-3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-1κ2O,O′;2κO′)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κO)(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κ2O,O′)digadolinium(III) octahydrate, C60H76Gd2N18O32
  41. Crystal structure of hexacarbonyl bis(μ2-2-methoxybenzenethiolato-κ2S)pyridine(triphenylphosphane)dirhenium(I), C43H34NO8PS2Re2
  42. Crystal structure of 14-((1-(benzyloxycarbonyl-amino)-2-methylpropan-2-yl)sulfanyl)acetate Mutilin, C34H49NO6S
  43. Crystal structure of 2-methoxy-6-(((2-(1-methyl-1H-benzo[d] imidazol-2-yl)phenyl)imino)methyl)phenol — ethanol (1/1), C24H25N3O3
  44. Crystal structure of 2-(bis(methylthio)methylene)-1-phenylbutane-1,3-dione, C13H14O2S2
  45. Crystal structure of (E)-2-(bis(methylthio)methylene)-1-phenyl-3-(2-phenylhydrazono)butan-1-one, C19H20N2OS2
  46. Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl)aniline-κ2N,N′)zinc(II)
  47. Crystal structure of bis(1-methyl-1H-tetrazole-5-thiolato)mercury(II)
  48. Crystal structure of (E)-2-styryl-1-ferrocenylsulfonyl-1H-imidazo[4,5-b]pyridine, C24H19FeN3O2S
  49. Crystal structure of aquabis(1-cyclopropyl-6-fluoro-4-oxo-7-(piperazin-4-ium-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O,O′)copper(II) thiophene-2,5-dicarboxylate trihydrate, [Cu(C17H18N3FO3)2(H2O)](C6H2SO4)·3(H2O)
  50. Crystal structure of 2-amino-4-(2,6-dichlorophenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H16Cl2N2O2
  51. Crystal structure of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5·5·0·05·9·03·11]dodecane 1/3 hydrate, C6H8N12O13
  52. Crystal structure of monocarbonyl(N-nitroso-N-oxido-phenylamine-κ2O,O′)(triphenylarsine-κAs)rhodium(I), C25H20AsN2O3Rh
  53. The crystal structure of 1-(4-(4-chlorophenoxy)-2-chlorophenyl)ethanone, C14H10Cl2O2
  54. Crystal structure of N,N-diethyl-2-(2-(6-(4-methoxybenzyl)-7-oxo-7H-thiazolo[3,3-b][1,2,4]triazin-3-yl)phenoxy)acetamide, C25H26N4O4S
  55. Crystal structure of tetraqua((E)-4,4′-(diazene-1,2-diyl)bis(5-oxo-4,5-dihydro-1,2,4-triazol-1-ide)-κ2N:O)barium(II), C4H10N8O6Ba
  56. Crystal structure of 2-amino-4-(3-phenoxyphenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C22H18N2O3
  57. Crystal structure of diethylammonium 5-((4-fluorophenyl)(6-hydroxy-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl)-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate, C23H30FN5O6
  58. Crystal structure of 2-amino-4-(3,5-difluoro-phenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12F2N2O2
  59. Crystal structure of tris(N-nitroso-N-oxyanilino-κ2O, O′) oxidoniobium(V), C18H15N6O7Nb
  60. Crystal structure of 1-(5-benzoyl-4-methyl-2-(phenylamino)thiophen-3-yl)ethan-1-one, a structure with Z′ = 6, C20H17NO2S
  61. Crystal structure of diethyl-3-methyl-4-phenylthieno[2,3-b]thiophene-2,5-dicarboxylate, C19H18O4S2
  62. Crystal structure of 3,5-dicarboxybenzoate — benzene-1,3,5-tricarboxylic acid (1/1), C24H22N2O12
  63. The crystal structure of 2-chloro-1,3-bis(2,4,6-trimethylphenyl)-4,4-dimethyl-1,3,2λ3,4-diazaphosphasiletidine
  64. Crystal structure of hexaquamanganese(II) bis(hexaborato-κ3O,O′,O′′)manganese(II) dihydrate, B12H28Mn2O34
  65. Crystal structure of 1-propyl-3-methylimidazolium pentaborate, [C7H13N2][B5O6(OH)4]
  66. Crystal structure of 13-(4-fluorophenyl)-11,13-dihydro-1H-benzo[h]indazolo[6,7-b] [1, 6]naphthyridin-12(6H)-one — dimethylformamide — water (1/2/1), C29H31FN6O4
  67. Crystal structure of 1-(2-chlorophenyl)-2-(2-nitrophenyl)ethan-1-ol, C14H12ClNO3
  68. Crystal structure of (Z)-2-((2-bromo-1-phenylvinyl)oxy)benzonitrile, C15H10BrNO
  69. Crystal structure of tetrachlorido(1E,1′E)-N,N′-((1,4-phenylenebis(propane-2,2-diyl))bis(4,1-phenylene))bis(1-(pyridin-2-yl-κN)methanimine-κN)dizinc(II), C36H34N4Zn2Cl4
  70. Crystal structure of 2,6-bis(3-methylpyridinyl)hexahydro-4,8-ethenopyrrolo-[3,4-f]isoindole-1,3,5,7(2H,6H)-tetrone, C24H20N4O4
  71. Crystal structure of trans-bis(2-methylmaleato-κ2O,O′) bis(piperazinium-κN) cobalt(II) trihydrate, C18H36CoN4O11
  72. Crystal structure of (E)-4-chloro-N′-(4-(diethylamino)benzylidene)benzohydrazide, C18H20ClN3O
  73. Crystal structure of 3,6-di(1H-imidazol-1-yl)-9H-carbazole, C18H13N5
  74. Crystal structure of 4-(4-pyridinyl)-1-naphthoic acid, C16H11NO2
  75. Crystal structure of 1,1′-diformyl-4,4′-(6H,12H-5,11-methano-dibenzo[b,f][11,5]diazocine-2,8-diyl)dibenzene, C29H22N2O2
  76. Crystal structure of N′-(adamantan-2-ylidene)pyridine-3-carbohydrazide, C16H19N3O
  77. Crystal structure of 1,1′-(butane-1,4-diyl)bis(5-methyl-1H-pyrazole-3-carbaldehyde), C14H18N4O2
  78. Crystal structure of methyl 8-hydroxy-3-isopropyl-5a,8-dimethyl-2,3,4,5,5a,6,7,8,10a,10b-decahydrocyclohepta[e]indene-3a(1H)-carboxylate, C21H34O3
  79. Crystal structure of 6-oxo-4-propyl-2-(propylthio)-1,6-dihydropyrimidine-5-carbonitrile, C11H15N3OS
  80. Crystal structure of poly[diacetato(μ2-1,4-bis(1H-imidazol-1-yl)benzene-κ2N:N′)nickel(II)], C26H22N8NiO4
  81. Crystal structure of bis(2,4-dibromo-6-{(E)[(4-fluorobenzyl)imino]methyl}phenolato-κ2N,O) copper(II), C28H18Br4F2N2O2Cu
  82. Crystal structure of 1-(adamantan-1-yl)-3-phenylthiourea, C17H22N2S
  83. Crystal structure of 3-(6-(5-amino-1-phenyl-1H-pyrazol-3-yl)pyridin-2-yl)-1-phenyl-1H-pyrazol-5-amine – dioxan (2/1), C25H23N7O
  84. Crystal structure of 5-ethyl-6-[(3-methylphenyl)sulfanyl]pyrimidine-2,4(1H,3H)-dione, C13H14N2O2S
  85. Crystal structure of (((1E,1′E)-(cyclohexane-1,2-diylbis(azanylylidene-κ2N,N′))bis(methanylylidene))bis(2,1-phenylene))bis((2,6-diisopropylphenyl)amide-κ2N′′,N′′′)manganese(II), C44H54N4Mn
  86. Crystal structure of prop-2-en-1-yl 2-oxo-2H-1-benzopyran-3-carboxylate, C13H10O4
  87. Crystal structure of bis(μ2-2-((3-methylphenyl)imino)methylphenolato-κ2N,O:O)hexacarbonyldimanganese(I), C34H24Mn2N2O8
  88. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxybut-2-en-1-one C9H12N2O2
  89. Crystal structure of 2,2′-[pentane-1,5-diylbis(oxy)]dibenzaldehyde, C19H20O4
  90. Crystal structure of 2-phenyl-5,6,7,8-tetrahydro-4H-benzo[4,5]thieno[2,3-d][1,3]oxazin-4-one, C16H13NO2S
  91. Crystal structure of (E)-1-(2-chlorophenyl)-N-(4-chlorophenyl)methanimine, C13H9Cl2N
  92. Crystal structure of ethyl 2-amino-5-bromothiazole-4-carboxylate, C6H7BrN2O2S
  93. Crystal structure of 2-benzylisothiouronium tetraphenylborate, C32H31BN2S
  94. Crystal structure of poly[(μ2-biphenyl-2,2′-dicarboxylato-κ4O,O′:O′′,O′′′)(μ2-4,4′-bipyridine-κ2N:N′)copper(II)], C24H16CuN2O4
  95. Crystal structure of (η5-pentamethylcyclopentadienyl)titanium(III)dichloride (THF), C14H23Cl2OTi
  96. Crystal structure of 3-ferrocenylsulfonyl-2-(4-methoxyphenyl)-3H-imidazo[4,5-b]pyridine, C23H19FeN3O3S
  97. Crystal structure of 2-benzoyl-3-(4-fluorophenyl)cyclopropane-1,1-dicarbonitrile, C18H11FN2O
  98. Crystal structure of 1,6-ditosyl-1,6-diazecane, C22H30N2O4S2
  99. Crystal structure of N-phenyl-2-(pyridin-4-ylcarbonyl)hydrazinecarboxamide with Z′ = 4, C13H12N4O2
  100. Crystal structure of N,N-bis(diphenylphosphanyl)cyclohexylamine, C30H31NP2
  101. Crystal structure of 3-(4-hydroxy-3-methoxyphenyl)-N-phenylpropanamide, C16H17NO3
  102. Crystal structure of 6-(2-fluorophenyl)-3-phenyl-[1,2,4]-triazolo[3,4-b][1,3,4]thiadiazole, C15H9FN4S
  103. Crystal structure of catena-poly[aqua(dicyanoazanido-2κN-μ2-dicyanoazanido-1κN:2κN′)(μ2-2-methoxy-6-(((2-((3-methoxy-2-oxidobenzylidene)amino)ethyl)imino)methyl)phenolato-1κ2N,N′,2κ2O,O′,1κ2O′′,O′′′:2κ2O′′,O′′′)cadmium(II)copper(II)], C22H20CdCuN8O5
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 7.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2015-0139/html
Scroll to top button