Abstract
Latent heat storage represents a promising technique to achieve net zero energy buildings. This work investigates the behaviour of phase change material (PCM) inside a rectangular enclosure, which represents the geometry of a latent heat storage system. The left side of the unit is exposed to a constant temperature (Th), while the other three walls are exposed to convection heat transfer boundary condition [h= 5, 10, and 15 W/(m2 K)] and different ambient temperatures (T∞ = 297◦ and 307◦K). The ambient temperatures were selected to be at/above the melting temperature of the studied PCM (coconut oil). To study the melting process of the PCM, the continuity, Navier-Stokes and energy equation were used. The Navier-Stokes equations were modified using the Carman-Kozeny relation. The finite element method was utilized to produce numerical results. The results are presented in terms of flow and thermal fields, Nusselt number (Nu), and the melt fraction (MF) of the PCM. The results show that, when T∞ = Tm, the melting rate of the PCM slows down with increasing the convection heat transfer coefficient. While the melting rate accelerates with increasing the convection heat transfer coefficient when T∞ > Tm.
Nomenclature
A( T) Parameter is defined in Eq. (6)
B( T) Parameter is defined in Eq. (7)
C Arbitrary constant in Eq. (6)
cp Specific heat at constant pressure (J/(kg K))
D Melting interface position from the left wall (m)
D( T) Gaussian function
g Gravitational acceleration (m/s2)
h Convection heat transfer (W/(m2 K))
hf Latent heat of fusion (J/kg)
k Thermal conductivity (W/(m K))
L Enclosure height (m)
MF Melt fraction
Nu Average Nusselt number
p Pressure (Pa)
q Arbitrary constant in Eq. (6)
T Temperature (K)
ΔT Range of melt temperature of the PCM (K)
t Time (s)
u Velocity component of the liquid PCM in the x-direction (m/s)
v Velocity component of the liquid PCM in the y-direction (m/s)
x Horizontal coordinate (m)
y Vertical coordinate (m)
Greek symbols
β Coefficient of volumetric thermal expansion (1/K)
μ Dynamical viscosity (Pa s)
ρ Density (kg/m3)
∞ Ambient
Subscripts
h Hot
l Liquid
m Melting
s Solid
1 Introduction
Conventional energy resources are currently diminishing because of a growing need for energy. For instance, substantial amounts of energy are required just for heating purposes. According to Natural Resources Canada, 63 % of the energy supply is used to heat spaces and 19% to heat water [1]. Additionally, it is these same CO2-emitting sources that are considered by many to be the main reason behind global warming. As a result, scientists are zealously working on ways to reduce dependency on these resources by searching for cleaner, renewable sources of energy.
Most alternate sources of energy will require some form of thermal energy storage. Latent heat storage represents a promising technique to achieve net zero energy buildings [2].
Joulin et al. [3] numerically studied the thermal behavior of PCM installed within solar passive walls. The study included 1-D and 2-D analyses for different aspect ratios. The vertical walls were differentially heated, and the horizontal walls were insulated. The authors reported that conduction dominates in the early stage of melting process then convection takes a growing role throughout the melting process.
Mbaye and Bilgen [4] performed a numerical study to investigate the impact of heat flux and the aspect ratio of the enclosure on the melting process of PCM. The vertical walls of the enclosure were subjected to constant heat flux and constant temperature. The authors found that the ratio of the heat flux entering and leaving the enclosure is not impacted by the aspect ratio at the beginning of the melting process; as melting continues the heat flux ratio increases with an increasing aspect ratio. Also, they found that the melting process accelerates as the aspect ratio decreases.
The melting of PCM inside a tall enclosure, that was subjected to constant heat flux at one vertical side, was numerically and experimentally studied by Pala and Joshi [5]. The authors found that at the beginning of the melting process, conduction dominates; after that, convection plays a significant role in the melting process. At the final stage of the melting process, sensible heating plays a role in the thermal storage and increases the temperature of the PCM.
Alawadhi [6] numerically investigated the impact of PCM on reducing heat gain. The PCM-filled cylinders were fixed inside a roof. The PCM type, quantity, and location inside a brick were studied. Convection boundary condition above and below the roof was applied. The authors found that using and locating the PCM in the center of the brick dramatically reduces the heat gain.
The main aim of this article is to study the effect of convection heat transfer conditions on the melting of PCM. The PCM fills a square enclosure. The left wall of the enclosure is isothermally heated, while the top, right, and bottom walls are exposed to convection boundary condition.
2 Physical and mathematical models
The energy storage system can be approximated by a 2-D enclosure. A schematic diagram of the enclosure system is shown in Figure 1. Initially, the solid form of the PCM occupies the enclosure. The initial temperature of the PCM is assumed to be equal to its melting temperature. The left vertical wall of the enclosure is maintained at constant temperature (Th) which is above the melting temperature (Tm) of the PCM. The remaining three walls are applied to convection boundary condition. The following assumptions are applied: the liquid phase of PCM is a Newtonian and incompressible fluid, all thermophysical properties of the PCM are assumed to be constant, the Boussinesq model is used in the buoyancy force term. In addition, in the energy equations, the internal heat generation and the viscous dissipation effect are neglected, and laminar fluid motion is assumed.

Schematic illustration of (a) the thermal storage system, (b) the physical model of the thermal storage unit
Conservation equations of mass (continuity), momentum, and energy (in the liquid and solid regions) are used to model the complete flow and thermal fields as shown below [3, 7].
In the above equations, ρl is the density of the liquid PCM, t is the time, u and v are the velocity components of the liquid PCM in the x and y-directions, p is the pressure, μ is the dynamic viscosity of PCM, g is the gravity, β is the coefficient of thermal expansion of the liquid PCM, T is the temperature, Tm is the melting temperature of the PCM, kl is the thermal conductivity of the liquid PCM, cpl is the specific heat at constant pressure of the liquid PCM, ks is the thermal conductivity of the solid PCM, ρs is the density of the solid PCM, and cps is the specific heat at constant pressure of the solid PCM.
In the momentum equations Eqs. (2) and (3), Kozeny-Carman relation is used to model the flow within the interface. The parameter A(T) in Eqs. (2) and (3) is defined to achieve a gradual reduction of the velocities of the liquid PCM from a finite value in the liquid zone to zero in the solid zone. To implement Kozeny-Carman relation, parameter A( T) is defined as [8]
where C and q are arbitrary constants of value of 105 and 10−3, respectively. B( T) can be defined as [8]
where ΔT is the range of temperatures over which the melting process occurs. If the PCM is a pure material, ΔT is zero, and the mushy zone is thin. On the other hand, if the PCM is an impure material, ΔT is greater than zero, and the mushy zone is wider than that for pure material.
B(T) is zero when the temperature is lower than Tm, while it is one when the temperature is higher than Tm. Equations (6) and (7) can be used to calculate the thermophysical properties of the PCM, as follows [8]
s and l stand for the solid and liquid phases of the PCM, respectively, and hf is the latent heat of fusion of the PCM. D(T), which is a Gaussian function, is used to determine the latent heat over a temperature range ΔT. D(T) can be calculated from [8]
The boundary and initial conditions of the thermal storage unit can be written as:
where h is the convection heat transfer coefficient, T∞ is the ambient temperature, L is the height of the unit, and D is the position of the melting interface starting from the left wall.
The averaged Nusselt number is calculated from [9]
3 Numerical procedure
The governing equations, Eqs. (1-5), with the boundary and initial conditions are numerically solved using the finite element method. For this purpose, a numerical scheme was built using the commercial software COMSOL 4.3b. To avoid the results dependency on the mesh size, a careful examination is conducted. Four element sizes were tested, 2522 (fine), 6580 (finer), 16986 (extra fine), and 26544 (extremely fine) elements, as shown in Figure 2. The independency test is conducted for the case at h=10W/(m2 K) and T∞ = 297◦K. Insignificant differences are observed among the four cases. However, for the lower numbered elements, 2522, the solution witnesses a slight fluctuation. The two higher numbered cases, 16986 and 26544, consume more time to complete the solution. As a result, the finer meshing of 6580-elements is selected in the present work. The proposed discretization numerical scheme consists of 5964 triangular elements and 616 quadrilateral elements. The time step is 10 s. The simulation is aborted when the relative tolerance is smaller than 10−3 for the continuity, momentum, and energy equations.

The mesh independency test at h = 10 W/(m2K) and T∞ = 307◦K
4 Results and discussion
In the present work, a numerical study was conducted to investigate the impact of convection heat transfer condition on the melting process of PCM. Individually, the impact of the convection heat transfer coefficient and ambient temperature were investigated. Carman-Kozeny relation was used to simulate the liquid-solid interface. Coconut oil was chosen as the PCM because its melting temperature is close to the comfortable temperature range of occupied spaces, in air conditioning sector, of 293.5◦ - 296.5◦K (20.5◦ - 23.5◦C) [10]. The thermophysical properties of coconut oil are listed in Table 1.
Thermophysical properties of coconut oil
| Properties (units) | Coconut oil | |
|---|---|---|
| Solid | Liquid | |
| ρ (kg/m3) | 920 | 918 |
| μ (Pa s) | - | 0.0268 |
| cp (K/(kg K)) | 3.750 | 1.670 |
| k (W/(m K)) | 0.166 | 0.166 |
| β (1/K) | 0.7 × 10−3 | |
| hf (J/kg) | 103.000 | |
| Tm (K) | 297 | |
A validation was performed to confirm the capability of the built model. The present model was validated by comparing the liquid-solid interface evolution gained from this model with the experimental results of Gau and Viskanta [11]. As shown in Figure 3, a good agreement was achieved. The insignificant discrepancies may have resulted from the theoretical assumptions.
![Figure 3 Comparison of interface position during melting of gallium between Gau and Viskanta [11] and the present study](/document/doi/10.1515/phys-2018-0108/asset/graphic/j_phys-2018-0108_fig_003.jpg)
Comparison of interface position during melting of gallium between Gau and Viskanta [11] and the present study
Figure 4 shows the effect of the convection heat transfer coefficient on the flow and thermal fields at 1500 s, when T∞ = Tm = 297◦K, Figure 4(a), and T∞ > Tm = 307◦K, Figure 4(b). The studied convection heat transfer coefficients were [h= 5, 10, and 15 W/(m2 K)]. The arrows in Figure 4 represent the flow field, and the counters represent the thermal field where the blue region is the solid PCM and the colored region is the liquid PCM. As the PCM that is adjacent to the hot walls heats up and melts, it becomes lighter due to low density. The relatively low-density melted PCM rises along the hot wall assisted by the buoyancy force, then it heads right. The impermeability of the upper wall forces the melted PCM to move to the liquid-solid interface, convecting the thermal energy with it. As the warm melted PCM hits the cold liquid-solid interface, it transfers thermal energy to the solid PCM. As a result, the liquid PCM becomes less warm, and its density increases. The increment in the PCM density drives the melted PCM down along the liquid-solid interface. While flowing along the liquid-solid interface, the melted PCM keeps transferring the thermal energy to the liquid-solid interface [12]. However, the amount of transferred thermal energy to the liquid-solid interface from the melted PCM decreases along the liquid-solid interface. The nonuniform heat transferred results in a higher amount of melted PCM in the top of the unit. The value of convection heat transfer coefficient and the ambient temperature play a significant role on the rate of the melting process and the shape of the solid PCM throughout the melting process. For the same h, when T∞ = 297◦K (= Tm), Figure 4(a), the melting process solely starts from the left wall. However, when T∞ = 307◦K (> Tm), Figure 4(b), the melting process occurs starting from the left, top, and right walls. Although the unit was also exposed to ambient temperature from the bottom, insignificant effects result from exposing the bottom wall. The high temperatures of the side and top walls assist in initiating the melting of the PCM from the top and the right walls besides the melting due to heating from the left wall. With changing h, the rate of melting of the PCM differs according to T∞. When T∞ equals Tm, the rate of dissipating heat from the unit to the ambient increases with increasing h. As a result, the melting rate decreases with increasing h, as shown in Figure 4(a). The left wall of the unit is heated at a temperature that is higher than the melting temperature of the PCM. When the PCM melts, the melted PCM temperature becomes higher than the melting temperature. In the case when T∞ equals Tm, a heat loss occurs from the hot melted PCM to the ambient. The heat loss is increased by increasing h, which subsequently deaccelerates the melting rate. Figure 4(b) shows the acceleration in the melting process when increasing h under the condition of T∞ is higher than Tm. In this case, the rate of heating the PCM from the ambient increases due to increasing h. When the ambient temperature T∞ is higher than Tm, the ambient becomes a heat source to melt the solid PCM. As T∞ is higher, the melting becomes faster [13]. In addition, as h increases, the heat transfers faster from the ambient to the unit, and subsequently the PCM melts faster.

Flow (arrows) and thermal fields (contours) for different convection heat transfer coefficient (h = 5, 10, and 15 W/(m2K)) at 1500 s (a) T∞ = 297◦K, (b) T∞ (= 307◦K) > Tm
The effect of convection heat transfer coefficient h and the ambient temperature Tm on Nu, along the left wall of the unit, is shown in Figure 5. As soon as the melting starts, a thin layer of liquid PCM is formed, and conduction becomes the dominant heat transfer mode. Conduction is dominant in this stage of the melting process because the viscous force overcomes the buoyancy force due to the scant liquid PCM layer [14]. In this stage, the heat transfer decreases with time due to increasing the temperature of the vicinity liquid along the left wall. Then Nu arises when the liquid PCM layer becomes wider, and the viscous force decreases while the buoyancy force increases. As heating progresses, the temperature of the liquid PCM increases leading to a drop in the convection heat transfer rate, and as a result Nu reduces. Figure 5 shows that at the beginning of the melting process, both h and T∞ have an insignificant effect on Nu. After that, there is a positive effect of increasing h on improving Nu for both T∞ values. A similar improvement in Nu is obtained with increasing T∞ for all the studied values of h.

Effect of convection heat transfer coefficient and ambient temperature on Nu
Figure 6 shows the effect of the convection heat transfer coefficient h and the ambient temperature T∞ on the melt fraction of the PCM, MF. The PCM melts faster at the early stages of the melting process because of the high temperature difference between the hot walls and the melted PCM adjacent to the hot walls [15]. However, the melting rate decreases with time as the liquid PCM temperature increases which reduces the heat transfer rate to the unit. When T∞ equals Tm, reducing h assists the PCM to melt faster. Where by reducing h, the heat losses from the unit decreases. While increasing h, in the case of T∞ is higher than Tm, the heat transfer rate to the unit increases. As a result, the melting rate increases.

Effect of convection heat transfer coefficient and ambient temperature on the melt fraction of the PCM
5 Conclusions
A numerical study was performed to investigate the behavior of the melting process under convection heat transfer condition. Besides the governing equations of the fluid flow and energy, Carman-Kozeny relation was applied to simulate the liquid-solid interface. COMSOL 4.3b software, which is based on finite element method, was used to build the numerical model of the present study. It can be concluded that the melting rate increases with increasing h when T∞ is higher than Tm. In this case, the unit is exposed to a higher heating rate. When T∞ equals Tm, increasing h leads to increasing the heat loss from the unit. As a result, the melting rate of the PCM decreases.
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© 2018 M. S. M. Al-Jethelah et al., published by De Gruyter
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.
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- Computational methods and traveling wave solutions for the fourth-order nonlinear Ablowitz-Kaup-Newell-Segur water wave dynamical equation via two methods and its applications
- Siewert solutions of transcendental equations, generalized Lambert functions and physical applications
- Numerical solution of mixed convection flow of an MHD Jeffery fluid over an exponentially stretching sheet in the presence of thermal radiation and chemical reaction
- A new three-dimensional chaotic flow with one stable equilibrium: dynamical properties and complexity analysis
- Dynamics of a dry-rebounding drop: observations, simulations, and modeling
- Modeling the initial mechanical response and yielding behavior of gelled crude oil
- Lie symmetry analysis and conservation laws for the time fractional simplified modified Kawahara equation
- Solitary wave solutions of two KdV-type equations
- Applying industrial tomography to control and optimization flow systems
- Reconstructing time series into a complex network to assess the evolution dynamics of the correlations among energy prices
- An optimal solution for software testing case generation based on particle swarm optimization
- Optimal system, nonlinear self-adjointness and conservation laws for generalized shallow water wave equation
- Alternative methods for solving nonlinear two-point boundary value problems
- Global model simulation of OH production in pulsed-DC atmospheric pressure helium-air plasma jets
- Experimental investigation on optical vortex tweezers for microbubble trapping
- Joint measurements of optical parameters by irradiance scintillation and angle-of-arrival fluctuations
- M-polynomials and topological indices of hex-derived networks
- Generalized convergence analysis of the fractional order systems
- Porous flow characteristics of solution-gas drive in tight oil reservoirs
- Complementary wave solutions for the long-short wave resonance model via the extended trial equation method and the generalized Kudryashov method
- A Note on Koide’s Doubly Special Parametrization of Quark Masses
- On right-angled spherical Artin monoid of type Dn
- Gas flow regimes judgement in nanoporous media by digital core analysis
- 4 + n-dimensional water and waves on four and eleven-dimensional manifolds
- Stabilization and Analytic Approximate Solutions of an Optimal Control Problem
- On the equations of electrodynamics in a flat or curved spacetime and a possible interaction energy
- New prediction method for transient productivity of fractured five-spot patterns in low permeability reservoirs at high water cut stages
- The collinear equilibrium points in the restricted three body problem with triaxial primaries
- Detection of the damage threshold of fused silica components and morphologies of repaired damage sites based on the beam deflection method
- On the bivariate spectral quasi-linearization method for solving the two-dimensional Bratu problem
- Ion acoustic quasi-soliton in an electron-positron-ion plasma with superthermal electrons and positrons
- Analysis of projectile motion in view of conformable derivative
- Computing multiple ABC index and multiple GA index of some grid graphs
- Terahertz pulse imaging: A novel denoising method by combing the ant colony algorithm with the compressive sensing
- Characteristics of microscopic pore-throat structure of tight oil reservoirs in Sichuan Basin measured by rate-controlled mercury injection
- An activity window model for social interaction structure on Twitter
- Transient thermal regime trough the constitutive matrix applied to asynchronous electrical machine using the cell method
- On the zagreb polynomials of benzenoid systems
- Integrability analysis of the partial differential equation describing the classical bond-pricing model of mathematical finance
- The Greek parameters of a continuous arithmetic Asian option pricing model via Laplace Adomian decomposition method
- Quantifying the global solar radiation received in Pietermaritzburg, KwaZulu-Natal to motivate the consumption of solar technologies
- Sturm-Liouville difference equations having Bessel and hydrogen atom potential type
- Study on the response characteristics of oil wells after deep profile control in low permeability fractured reservoirs
- Depiction and analysis of a modified theta shaped double negative metamaterial for satellite application
- An attempt to geometrize electromagnetism
- Structure of traveling wave solutions for some nonlinear models via modified mathematical method
- Thermo-convective instability in a rotating ferromagnetic fluid layer with temperature modulation
- Construction of new solitary wave solutions of generalized Zakharov-Kuznetsov-Benjamin-Bona-Mahony and simplified modified form of Camassa-Holm equations
- Effect of magnetic field and heat source on Upper-convected-maxwell fluid in a porous channel
- Physical cues of biomaterials guide stem cell fate of differentiation: The effect of elasticity of cell culture biomaterials
- Shooting method analysis in wire coating withdrawing from a bath of Oldroyd 8-constant fluid with temperature dependent viscosity
- Rank correlation between centrality metrics in complex networks: an empirical study
- Special Issue: The 18th International Symposium on Electromagnetic Fields in Mechatronics, Electrical and Electronic Engineering
- Modeling of electric and heat processes in spot resistance welding of cross-wire steel bars
- Dynamic characteristics of triaxial active control magnetic bearing with asymmetric structure
- Design optimization of an axial-field eddy-current magnetic coupling based on magneto-thermal analytical model
- Thermal constitutive matrix applied to asynchronous electrical machine using the cell method
- Temperature distribution around thin electroconductive layers created on composite textile substrates
- Model of the multipolar engine with decreased cogging torque by asymmetrical distribution of the magnets
- Analysis of spatial thermal field in a magnetic bearing
- Use of the mathematical model of the ignition system to analyze the spark discharge, including the destruction of spark plug electrodes
- Assessment of short/long term electric field strength measurements for a pilot district
- Simulation study and experimental results for detection and classification of the transient capacitor inrush current using discrete wavelet transform and artificial intelligence
- Magnetic transmission gear finite element simulation with iron pole hysteresis
- Pulsed excitation terahertz tomography – multiparametric approach
- Low and high frequency model of three phase transformer by frequency response analysis measurement
- Multivariable polynomial fitting of controlled single-phase nonlinear load of input current total harmonic distortion
- Optimal design of a for middle-low-speed maglev trains
- Eddy current modeling in linear and nonlinear multifilamentary composite materials
- The visual attention saliency map for movie retrospection
- AC/DC current ratio in a current superimposition variable flux reluctance machine
- Influence of material uncertainties on the RLC parameters of wound inductors modeled using the finite element method
- Cogging force reduction in linear tubular flux switching permanent-magnet machines
- Modeling hysteresis curves of La(FeCoSi)13 compound near the transition point with the GRUCAD model
- Electro-magneto-hydrodynamic lubrication
- 3-D Electromagnetic field analysis of wireless power transfer system using K computer
- Simplified simulation technique of rotating, induction heated, calender rolls for study of temperature field control
- Design, fabrication and testing of electroadhesive interdigital electrodes
- A method to reduce partial discharges in motor windings fed by PWM inverter
- Reluctance network lumped mechanical & thermal models for the modeling and predesign of concentrated flux synchronous machine
- Special Issue Applications of Nonlinear Dynamics
- Study on dynamic characteristics of silo-stock-foundation interaction system under seismic load
- Microblog topic evolution computing based on LDA algorithm
- Modeling the creep damage effect on the creep crack growth behavior of rotor steel
- Neighborhood condition for all fractional (g, f, n′, m)-critical deleted graphs
- Chinese open information extraction based on DBMCSS in the field of national information resources
- 10.1515/phys-2018-0079
- CPW-fed circularly-polarized antenna array with high front-to-back ratio and low-profile
- Intelligent Monitoring Network Construction based on the utilization of the Internet of things (IoT) in the Metallurgical Coking Process
- Temperature detection technology of power equipment based on Fiber Bragg Grating
- Research on a rotational speed control strategy of the mandrel in a rotary steering system
- Dynamic load balancing algorithm for large data flow in distributed complex networks
- Super-structured photonic crystal fiber Bragg grating biosensor image model based on sparse matrix
- Fractal-based techniques for physiological time series: An updated approach
- Analysis of the Imaging Characteristics of the KB and KBA X-ray Microscopes at Non-coaxial Grazing Incidence
- Application of modified culture Kalman filter in bearing fault diagnosis
- Exact solutions and conservation laws for the modified equal width-Burgers equation
- On topological properties of block shift and hierarchical hypercube networks
- Elastic properties and plane acoustic velocity of cubic Sr2CaMoO6 and Sr2CaWO6 from first-principles calculations
- A note on the transmission feasibility problem in networks
- Ontology learning algorithm using weak functions
- Diagnosis of the power frequency vacuum arc shape based on 2D-PIV
- Parametric simulation analysis and reliability of escalator truss
- A new algorithm for real economy benefit evaluation based on big data analysis
- Synergy analysis of agricultural economic cycle fluctuation based on ant colony algorithm
- Multi-level encryption algorithm for user-related information across social networks
- Multi-target tracking algorithm in intelligent transportation based on wireless sensor network
- Fast recognition method of moving video images based on BP neural networks
- Compressed sensing image restoration algorithm based on improved SURF operator
- Design of load optimal control algorithm for smart grid based on demand response in different scenarios
- Face recognition method based on GA-BP neural network algorithm
- Optimal path selection algorithm for mobile beacons in sensor network under non-dense distribution
- Localization and recognition algorithm for fuzzy anomaly data in big data networks
- Urban road traffic flow control under incidental congestion as a function of accident duration
- Optimization design of reconfiguration algorithm for high voltage power distribution network based on ant colony algorithm
- Feasibility simulation of aseismic structure design for long-span bridges
- Construction of renewable energy supply chain model based on LCA
- The tribological properties study of carbon fabric/ epoxy composites reinforced by nano-TiO2 and MWNTs
- A text-Image feature mapping algorithm based on transfer learning
- Fast recognition algorithm for static traffic sign information
- Topical Issue: Clean Energy: Materials, Processes and Energy Generation
- An investigation of the melting process of RT-35 filled circular thermal energy storage system
- Numerical analysis on the dynamic response of a plate-and-frame membrane humidifier for PEMFC vehicles under various operating conditions
- Energy converting layers for thin-film flexible photovoltaic structures
- Effect of convection heat transfer on thermal energy storage unit