Startseite Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ2N:N′-bis(cyano-κC)dicopper(I)]-water, C58H56Cu2N6O2P2
Artikel Open Access

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ2N:N′-bis(cyano-κC)dicopper(I)]-water, C58H56Cu2N6O2P2

  • Yan-Ru Zhang , Zhi-Qiang Li , Min Liu , Kai-Lun Bi und Qiong-Hua Jin EMAIL logo
Veröffentlicht/Copyright: 10. Mai 2017
Artikel downloaden (PDF)
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 232 Heft 4

Abstract

C58H56Cu2N6O2P2, monoclinic, P21/n, a = 12.0546(9) Å, b = 13.1669(10) Å, c = 16.7151(12) Å, β = 101.845(2)°, V = 2596.6(3) Å3, Z = 4, Rgt(F) = 0.0539, wRref(F2) = 0.1431, T = 293(2) K.

CCDC no.:: 1543452

Table 1

Data collection and handling.

Crystal:Yellow block
Size:0.50 × 0.45 × 0.35 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:9.3 cm−1
Diffractometer, scan mode:Bruker FRAMBO, φ and ω
2θmax, completeness:50°, >99%
N(hkl)measured, N(hkl)unique, Rint:16741, 4579, 0.082
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3177
N(param)refined:318
Programs:Bruker programs [1], SHELX [2]

The crystal structure (water molecular removed) is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Cu10.78964(4)0.68963(3)0.55963(3)0.0443(2)
N10.7374(3)0.6447(2)0.43639(18)0.0421(8)
N20.8600(3)0.5418(2)0.5637(2)0.0444(8)
N30.9496(3)0.8714(3)0.5890(3)0.0808(13)
O10.1065(3)0.0402(4)0.5911(3)0.150(2)
H1C0.0613−0.00920.59200.180*
H1D0.09280.06540.54330.180*
P10.64967(8)0.67471(7)0.62962(6)0.0369(3)
C10.6742(4)0.6953(3)0.3753(2)0.0512(11)
C20.6423(4)0.6521(4)0.2971(3)0.0668(13)
H20.59650.68840.25520.080*
C30.6781(4)0.5574(4)0.2824(3)0.0724(15)
H30.65690.52870.23070.087*
C40.7466(4)0.5037(4)0.3452(3)0.0584(12)
C50.7730(3)0.5488(3)0.4225(2)0.0449(10)
C60.8389(3)0.4950(3)0.4907(3)0.0438(10)
C70.8784(3)0.3976(3)0.4789(3)0.0575(12)
C80.9405(4)0.3484(4)0.5470(4)0.0722(15)
H80.96780.28310.54210.087*
C90.9611(4)0.3952(4)0.6202(3)0.0723(15)
H91.00320.36260.66580.087*
C100.9192(3)0.4923(3)0.6273(3)0.0543(11)
C110.7895(4)0.4034(4)0.3361(4)0.0790(17)
H110.77240.37180.28530.095*
C120.8534(4)0.3548(4)0.3991(4)0.0781(16)
H120.88240.29120.39070.094*
C130.6386(4)0.7985(3)0.3923(3)0.0749(15)
H13A0.60120.79670.43780.112*
H13B0.58730.82430.34500.112*
H13C0.70390.84180.40520.112*
C140.9411(4)0.5450(4)0.7074(3)0.0787(15)
H14A0.93580.61710.69880.118*
H14B1.01570.52810.73710.118*
H14C0.88600.52400.73810.118*
C150.5708(3)0.5558(3)0.6067(2)0.0431(9)
H15A0.62260.49880.61800.052*
H15B0.51590.54970.64150.052*
C160.5092(3)0.5530(2)0.5163(2)0.0466(10)
H16A0.43630.58660.51080.056*
H16B0.55340.59040.48380.056*
C170.5408(3)0.7720(3)0.6208(2)0.0392(9)
C180.5642(4)0.8685(3)0.5959(2)0.0535(11)
H180.63320.88170.58130.064*
C190.4853(5)0.9452(3)0.5926(3)0.0684(14)
H190.50241.01000.57650.082*
C200.3840(4)0.9278(4)0.6122(3)0.0688(14)
H200.33090.97980.60870.083*
C210.3602(4)0.8338(4)0.6373(3)0.0703(14)
H210.29080.82150.65160.084*
C220.4385(3)0.7559(3)0.6417(3)0.0579(12)
H220.42120.69190.65910.070*
C230.7008(3)0.6741(3)0.7407(2)0.0420(9)
C240.7745(4)0.7510(3)0.7720(3)0.0587(12)
H240.79540.79900.73690.070*
C250.8174(5)0.7574(4)0.8545(3)0.0776(16)
H250.86650.81000.87520.093*
C260.7881(5)0.6869(4)0.9063(3)0.0807(17)
H260.81790.69120.96210.097*
C270.7158(5)0.6109(4)0.8767(3)0.0809(16)
H270.69580.56310.91220.097*
C280.6716(4)0.6044(4)0.7937(3)0.0637(12)
H280.62160.55220.77370.076*
C290.8904(4)0.8039(3)0.5781(3)0.0492(10)

Source of material

A mixture of CuCN (0.0179 g, 0.2 mmol), 2,9-dimethyl-1,10-phenanthroline (dmp) (0.0434 g, 0.2 mmol) and 1,4-bis(diphenylphosphino)butane (dppb) (0.0853 g, 0.2 mmol) were dissolved in a mixture of CH3CN and CH2Cl2 (10 mL, v/v = 1:1). After being stirred for 6 hours at room temperature, the liquid was filtered. Subsequent slow evaporation of the filtrate resulted in the formation of yellow block crystals.

Experimental details

Hydrogen atoms were placed on calculated positions and refined using a riding model. The highest residual electron density peak (0.67 e−3Å) is located 2.29 Å away from the water oxygen atom; however, refinement of disorder did not lead to a significant improvement of the model.

Discussion

Mononuclar and binuclear copper(I) complexes containing diphosphine and N-heterocyclic ligands have been the focus of several investigations in the last few years because of their luminescence properties, interesting structures and novel reactivity performances [3], [4], [5]. During our previous work, a number of mixed-ligand coordination compounds of copper(I) salts with heterocyclic nitrogen ligands and diphosphanes were prepared and structurally characterized [6], [7]. Among numerous multi-functional ligands, 1,4-bis(diphenylphosphino)butane(dppb) is a good ligand candidate because its bridging ability is very suitable to lock two Cu(I) atoms together to form a Cu2(dppb) core structure.

The crystal structure of the title complex shows that the copper(I) atom is coordinated by one phosphorus atom from dppb ligand, two nitrogen atoms from dmp and one carbon atom from cyanide anion. The coordination mode of the title complex is similar to that of compound [{Cu(dmp)(CN)}] [8]. The angles around Cu atom are in the range of 79.13(12)°–120.14(13)°. The coordination geometry around each Cu atom indicates a distorted tetrahedron. The N—Cu–N bond angle (79.13(12)°) in the complex is comparable to that in [{Cu(dmp)(CN)}](79.1(3)°) [9], while it is smaller than that in [Cu(dmp)2]2[TCNQI2](82.85°) (TCNQ = tetracyanoquinodimethanide) [10]. At 2.11(3) and 2.118(3) Å, the two Cu—N(dmp) bond distances are similar and shorter than the Cu-P bond distance, 2.250(1) Å, but are longer than the Cu-N(dmp) distances in [Cu(dmp)-(DPEphos)]+[2.104(3) and 2.084(3) Å] (dmp = 2,9-dimethyl-1,10-phenanthroline DPEphos = bis[2-(diphenylphosphino)phenyl]-ether) [11]. The Cu—C bond distance 1.919(4) Å in the title complex is longer than that observed in [Cu(dmp)(CN)] (1.897(1) Å) [9]. The CN- ligand receives two hydrogen bonds from two symmetry-related water molecules O1—H1C⋯N3 [O1⋯N3 = 2.914(6), O1—H1C⋯N3 = 177.6(3)°] and O1—H1D⋯N3 [O1⋯N3 = 3.168(7)°, O1—H1D⋯N3 = 177.6(3)°], The resulting hydrogen-bonded motif is described by the second level graph set R2,4(8) [12].

In summary, a new Cu(I)-dppb-dmp complex was synthesized. The research plays a role in designing and synthesizing new Cu(I) complexes of N-heterocyclic and PP type ligands.

Acknowledgement

This work has been supported by Beijing Natural Science Foundation (Grant No. 2172017 & No. 2172012).

References

1 Bruker. APEX2, SAINT and SADABS. Brucker AXS Inc., Madison, Wisconsin, USA, (2009).Suche in Google Scholar

2 Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Suche in Google Scholar PubMed

3 Khalaji, A. D.; Amirnasr, M.; Welter, R.: Synthesis and x-ray crystal structure of the dinuclear copper(I) complex [Cu2((Me-Pk)2En)(PPh3)4](ClO4)2⋅2CHCl3. J. Coord. Chem. 36 (2010) 835–837.10.1134/S1070328410110084Suche in Google Scholar

4 Babashkina, M. G.; Safin, D. A.; Klein, A.; Bolte, M.: Synthesis, characterisation and luminescent properties of mixed-ligand copper(I) complexes incorporating N-thiophosphorylated thioureas and phosphane ligands. Eur. J. Inorg. Chem. 25 (2010) 4018–4026.10.1002/ejic.201000165Suche in Google Scholar

5 Gan, X.; Yao, Z. F.; Zhang, J. F.; Li, Z.; Fu, W. F.: Synthesis, characterization, and spectroscopic properties of binuclear copper(I) complexes with NN-NN, NNOH, NCN, and phosphine ligands. Coord. J. Chem. 63 (2010) 2800–2811.10.1080/00958972.2010.502965Suche in Google Scholar

6 Jin, Q. H.; Zhou, L. L.; Xu, L. J.; Zhang, Y. Y.; Zhang, C. L.; Lu, X. M.: Synthesis, characterization and crystal structures of supramolecular complexes of copper(II)(2,2′-biimidazole) induced by inorganic counter anions. Polyhedron 29 (2010) 317–327.10.1016/j.poly.2009.05.052Suche in Google Scholar

7 Jin, Q. H.; Chen, L. M.; Li, P. Z.; Deng, S. F.; Wang, R.: The synthesis, structure, and characterization of three novel 1D nitrogen-heterocyclic copper(I)-diphosphine polymers. Inorg. Chim. Acta 362 (2009) 5224–5230.10.1016/j.ica.2009.09.035Suche in Google Scholar

8 Dessy, G.; Fares, V.; Morpurgo, G. O.: The polymeric structure of [μ-cyanomono(2,9-dimethyl-1,10-phenanthroline)copper(I)]n (C15H12CuN3)n. Cryst. Struct. Commun 11 (1982) 1805–1809.Suche in Google Scholar

9 Morpurgo, G. O.; Dessy, G.; Fares, V.: Crystal structures and spectroscopic properties of the polymeric adducts formed from Cu(CN) and Cu( NCS) with 2,9-dimethyl-1,10-phenanthroline. J. Chem. Soc. Dalton Trans. 5 (1984) 785–791.10.1039/dt9840000785Suche in Google Scholar

10 Hoffmann, S. K.; Corvan, P. J.; Singh, P.; Sethulekshmi, C. N.; Metzger, R. M.; Hatfield, W. E.: Crystal structure and excited triplet-state electron paramagnetic resonance of the a-bonded TCNQ dimer in bis(2,9-dimethyl- 1,10-phenanthroline) copper(I) tetracyanoquinodimethanide, [Cu(DMP)2]2[TCNQ]2. J. Am. Chem. Soc. 105 (1983) 4608–4617.10.1021/ja00352a016Suche in Google Scholar

11 Kuang, S. M.; Cuttell, D. G.; McMillin, D. R.; Fanwick, P. E.; Walton, R. A.: Synthesis and structural characterization of Cu(I) and Ni(II) complexes that contain the bis[2-(diphenylphosphino)phenyl]ether ligand. novel emission properties for the Cu(I) species. Inorg. Chem. 41 (2002) 3313–3322.10.1021/ic0201809Suche in Google Scholar

12 Etter, M. C.; MacDonald, J. C.; Bernstein, J.: Graph-set analysis of hydrogen-bond patterns in organic crystals. Acta Crystallogr. B46 (1990) 256–262.10.1107/S0108768189012929Suche in Google Scholar PubMed

Received: 2016-11-8
Accepted: 2017-4-17
Published Online: 2017-5-10
Published in Print: 2017-7-26

©2017 Yan-Ru Zhang et al., published by De Gruyter.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Crystal structure of poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)manganese(II)] bis(4-chlorobenzenesulfonate) – 4,4′-bipyridine – water (1/1/2) C42H40Cl2MnN6O10S2
  3. The crystal structure of 1,2-bis[2-methyl-5-(3-cyanophenyl)-3-thienyl]-3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H16F6N2S2
  4. Crystal structure of the first characterized polymeric copper and sodium complex diaqua-(tris-acetato-κO,O′)(μ2-acetato-κO′′)dinatrium copper(II) monohydrate, C8H18CuNa2O11
  5. The crystal structure of the Schiff base (E)-2,6-diisopropyl-N-(pyridin-3-yl-methylene)aniline, C18H22N2
  6. Crystal structure of methyl 2,7,7-trimethyl-4-(4-nitrophenyl)-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylate, C20H22N2O5
  7. Crystal structure of bis(1,3-bis(diphenylphosphino)propane-κ2P,P′)silver(I) trifluorosulfonate–methanol (1:0.5), [Ag(C27H26P2)]SO3CF3⋅0.5CH3OH
  8. Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ2N:N′-bis(cyano-κC)dicopper(I)]-water, C58H56Cu2N6O2P2
  9. Crystal structure of N2,N6-bis(1-hydrazinyl-2-methyl-1-oxopropan-2-yl) pyridine-2,6-dicarboxamide, C15H23N7O4
  10. Crystal structure of 1,3-dimethyl-2-phenyl-1H-perimidin-3-ium iodide, C19H17IN2
  11. Crystal structure of diaqua-(2,2′-(butane-1,4-diyl)-bis(5-carboxy-1H-imidazole-4-carboxylato)-κ4O,O′,N,N′)cadmium(II) monohydrate, C14H18O11N4Cd
  12. Crystal structure of ethyl (E)-3-(cyclopropylamino)-2-(2,4-dichloro-5-fluorobenzoyl) acrylate, C15H14Cl2FNO3
  13. Crystal structure of bis-(1-(4-chlorophenyl)-3-phenyl-4-thenoyl-1H-pyrazol-5-ol-κ2O,O′)-(N,N-dimethylformamide)zinc(II), C43H31Cl2N5O5S2Zn
  14. Crystal structure of tetrakis(μ3-2-(N-(2-hydroxyethyl)amino)ethoxo)-tetrachloro-tetra-cobalt(II) methanol solvate, C17H44Cl4Co4N4O9
  15. Crystal structure of 3-amino-1-(4-bromophenyl)-9-methoxy-1H-benzo[f]chromene-2-carbonitrile, C21H15BrN2O2
  16. Crystal structure of 2-amino-4-(4-isopropyl-phenyl)-3-cyano-5-oxo-4H,5H-pyrano[3,2-c]chromene, C22H18N2O3
  17. Crystal structure of 3-amino-8-methoxy-1-(4-methoxy phenyl)-1H-benzo[f]chromene-2-carbonitrile, C22H18N2O3
  18. Crystal structure of monoaqua-[6,6′-((1E,1′E)-(1,2-phenylene bis(azanylylidene))bis(methanylylidene))bis(4-bromo-2-nitrophenolato-κ4N,N′,O,O′)]zinc(II), C20H12Br2N4O7Zn
  19. Crystal structure of 11-(4-(dimethylamino)phenyl)-17-hydroxy-13-methyl-17-(prop-1-yn-1-yl)-1,2,6,7,8,11,12,13,14,15,16,17-dodecahydro-3H-cyclopenta[a]phenanthren-3-one – acetonitril (1/2), C33H41N3O2
  20. Crystal structure of tert-butyl (phenylsulfinyl)carbamate, C11H15NO3S
  21. Crystal structure of catena-poly{diaqua-bis(3-(1H-1,2,4-triazol-1-yl)benzoato-κ2O:N)copper(II)} monohydrate, C18H18CuN6O7
  22. Crystal structure of tetraaqua-bis(3-(4H-1,2,4-triazol-4-yl)benzoato-κN)cobalt(II), C18H20CoN6O8
  23. The crystal structure of 4-bromo-N-cyclopropyl-2,5-difluorobenzenesulfonamide, C9H8BrF2NO2S
  24. Crystal structure of ([3,3′-bipyridine]-6,6′-dicarboxylato-κ2O:O′)-bis(1,2-bis(4-pyridyl)ethane-κ2N:N′)disilver(I) dihydrate, C37H35Ag2N5O6
  25. The crystal structure of (4-(1H-1,2,4-triazol-1-yl)benzoato-κN)-[4-(1H-1,2,4-triazol-1-yl)benzoic acid-κN]silver(I), C18H13AgN6O4
  26. Crystal structure of 3-(4-methoxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one, C17H16O2
  27. Crystal structure of bis(2-((E)-((4-((E)-1-(ethoxyimino)ethyl)phenyl)imino)methyl)-5-methoxyphenolato-κ2O,N)copper(II), C36H38CuN4O6
  28. Crystal structure of poly[1,2-bis(1,2,4-triazol-4-yl)ethane-κ2N:N′]silver(I) bromate monohydrate]silver(I), C6H10AgBrN6O4
  29. The crystal structure of 2,3,5-triphenyl-2,3-dihydro-1H-tetrazol-1-ium 2,3-dioxoindoline-5-sulfonate, C27H19N5O5S
  30. Crystal structure of 3-(2-amino-1,3-selenazol-4-yl)-2H-chromen-2-one – dimethylformamide (1/1), C15H15N3O3Se
  31. Crystal structure of diethyl 3,3′-(diazene-1,2-diyl)(E)-dibenzoate, C18H18N2O4
  32. Crystal structure of cis-bis((1H-benzimidazol-2-yl)methanol-κN,O)-bis(isothiocyanato-κN)nickel(II), C18H16N6NiO2S2
  33. Crystal structure of bis(2-(2′-hydroxy-5′-methoxyphenyl)-1H-benzimidazole)boron – tetrahydrofuran (1/1), C36H37N4O6B
  34. Crystal structure of poly[aqua-bis(nitrato-κ2O,O′)-(μ3-1,3-benzimidazol-3-ium-1,3-diacetato-κ4O,O′:O′′:O′′′)dysprosium(III)], C11H11DyN4O11
  35. Crystal structure of n-butyl-tris(dicyclo-hexylamido)hafnium(IV), C40H75HfN3
  36. Crystal structure of (E)-1-[1-(3-chloro-4-fluoro-phenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine, C28H20Cl2F2N8O8
  37. The crystal structure of ethyl 4-((2-hydroxybenzyl)amino)benzoate, a Schiff base, C16H17NO3
  38. Crystal structure of 3-(2-(4-isobutylphenyl)propanoyl)-1-methylimidazolidine-2,4-dione, C17H22N2O3
  39. Crystal structure of poly[(μ3-2-(pyrazin-2-ylthio)acetato-κ3N:O:S)silver(I)], C6H5AgN2O2S
  40. Crystal structure of (E)-1-(3-((E)-((2-hydroxynaphthalen-1-yl)methylene)amino)phenyl)ethanone O-benzyl oxime, C26H22N2O2
  41. Crystal structure of (E)-2,3-dihydroxybenzaldehyde O-(2-((((E)-1-(2,5-dihydroxyphenyl)ethylidene)amino)oxy)ethyl) oxime monohydrate, C17H20N2O7
  42. Crystal structure of 4-(chloromethyl)-3-nitrobenzoic acid, C8H6ClNO4
  43. Crystal stucture of 4-((10H-phenothiazin-10-yl)methyl)-2,6-di-tert-butylphenol, C27H31NOS
  44. The crystal structure of ethyl 1-(4-nitrophenyl)-5-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C13H10F3N3O4
  45. Crystal structure of catena-poly[di-(μ3-oxido-κ3O:O:O)-tetraoxido-(μ2-5′-(pyrazin-2-yl)-1H,2′H-3,3′-bi(1,2,4-triazole)-κ2N:N′)dimolybdenum(VI)], C8H6Mo2N8O6
  46. Crystal structure of (3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O,O′:O′′,O′′′)-bis(tris(2-pyridylmethyl)amine-κ4N,N′,N′′,N′′′))-dizinc(II) bis(hexafluorophosphate(V)), C42H38F12N8O4P2Zn2
  47. Crystal structure of catena-poly[hexakis(μ2-2-acetylphenolato-κ3O:O,O′)trimanganese(II)], C48H42Mn3O12
  48. The crystal structure of 2,2-difluoro-4-(trifluoromethyl)-2,5-dihydro-[1,3,2]dioxaborinino[5,4-c]chromen-3-ium-2-uide, C11H6BF5O3
  49. Crystal structure of methyl (E)-2-(4-(diethylamino)-2-hydroxybenzylidene)hydrazine-1-carboxylate, C13H19N3O3
  50. The crystal structure of tert-butyl 2,6-dihydropyrrolo[3,4-c]pyrazole-5(4H)-carboxylate, C10H15N3O2
  51. Crystal structure of 1,1-bis(η5-adamantylcyclopentadienyl)-3-phenyl-2-trimethylsilyl-2,3-dihydroisotitanazole, C42H55NSiTi
  52. Crystal structure of 2-(4-(2-(4-benzylpiperazin-1-yl)ethyl)benzyl)isoindoline-1,3-dione, C28H29N3O2
  53. Important impurity of Flupirtine – a single crystal study on ethyl (6-amino-5-((ethoxycarbonyl)amino)pyridin-2-yl)(4-fluorobenzyl)carbamate, C18H21FN4O4
  54. Crystal structure of ethyl 3-(4-methoxyphenyl)-1-(2-(4-methoxyphenyl)-2-oxoethyl)-1H-pyrazole-5-carboxylate, C22H22N2O5
  55. Crystal structure of 2,3,9,10-tetramethoxy-5,6-dihydroisoquinolino[2,1-b]isoquinolin-7-ium 5-hydroxy-3-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-olate methanol solvate, C37H35N1O10
  56. The crystal structure of the inner salt of 2-[(aminoiminomethyl)amino]ethylcarbamic acid [systematic name: (2-((diaminomethylene)ammonio)ethyl)carbamate], C4H10N4O2
  57. Crystal structure of (8-hydroxy-5-nitroquinolinium) perchlorate – 8-hydroxy-5-nitroquinoline (1/1), C18H13ClN4O10
  58. The crystal structure of (5-methyl-1,2,4-oxadiazol-3-yl)ferrocene, C13H12FeN2O
  59. Crystal structure of methyl 1-(2-(fluorosulfonyl)ethyl)-2-oxocyclopentanecarboxylate, C9H13FO5S
  60. Crystal structure of the triclinic modification of 1-methyl-4-nitroimidzole, C4H5N3O2
  61. Corrigendum
  62. Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O
https://doi.org/10.1515/ncrs-2016-0285
Creative Commons
BY-NC-ND 3.0

Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Crystal structure of poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)manganese(II)] bis(4-chlorobenzenesulfonate) – 4,4′-bipyridine – water (1/1/2) C42H40Cl2MnN6O10S2
  3. The crystal structure of 1,2-bis[2-methyl-5-(3-cyanophenyl)-3-thienyl]-3,3,4,4,5,5-hexafluoro-cyclopent-1-ene, C29H16F6N2S2
  4. Crystal structure of the first characterized polymeric copper and sodium complex diaqua-(tris-acetato-κO,O′)(μ2-acetato-κO′′)dinatrium copper(II) monohydrate, C8H18CuNa2O11
  5. The crystal structure of the Schiff base (E)-2,6-diisopropyl-N-(pyridin-3-yl-methylene)aniline, C18H22N2
  6. Crystal structure of methyl 2,7,7-trimethyl-4-(4-nitrophenyl)-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylate, C20H22N2O5
  7. Crystal structure of bis(1,3-bis(diphenylphosphino)propane-κ2P,P′)silver(I) trifluorosulfonate–methanol (1:0.5), [Ag(C27H26P2)]SO3CF3⋅0.5CH3OH
  8. Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ2N:N′-bis(cyano-κC)dicopper(I)]-water, C58H56Cu2N6O2P2
  9. Crystal structure of N2,N6-bis(1-hydrazinyl-2-methyl-1-oxopropan-2-yl) pyridine-2,6-dicarboxamide, C15H23N7O4
  10. Crystal structure of 1,3-dimethyl-2-phenyl-1H-perimidin-3-ium iodide, C19H17IN2
  11. Crystal structure of diaqua-(2,2′-(butane-1,4-diyl)-bis(5-carboxy-1H-imidazole-4-carboxylato)-κ4O,O′,N,N′)cadmium(II) monohydrate, C14H18O11N4Cd
  12. Crystal structure of ethyl (E)-3-(cyclopropylamino)-2-(2,4-dichloro-5-fluorobenzoyl) acrylate, C15H14Cl2FNO3
  13. Crystal structure of bis-(1-(4-chlorophenyl)-3-phenyl-4-thenoyl-1H-pyrazol-5-ol-κ2O,O′)-(N,N-dimethylformamide)zinc(II), C43H31Cl2N5O5S2Zn
  14. Crystal structure of tetrakis(μ3-2-(N-(2-hydroxyethyl)amino)ethoxo)-tetrachloro-tetra-cobalt(II) methanol solvate, C17H44Cl4Co4N4O9
  15. Crystal structure of 3-amino-1-(4-bromophenyl)-9-methoxy-1H-benzo[f]chromene-2-carbonitrile, C21H15BrN2O2
  16. Crystal structure of 2-amino-4-(4-isopropyl-phenyl)-3-cyano-5-oxo-4H,5H-pyrano[3,2-c]chromene, C22H18N2O3
  17. Crystal structure of 3-amino-8-methoxy-1-(4-methoxy phenyl)-1H-benzo[f]chromene-2-carbonitrile, C22H18N2O3
  18. Crystal structure of monoaqua-[6,6′-((1E,1′E)-(1,2-phenylene bis(azanylylidene))bis(methanylylidene))bis(4-bromo-2-nitrophenolato-κ4N,N′,O,O′)]zinc(II), C20H12Br2N4O7Zn
  19. Crystal structure of 11-(4-(dimethylamino)phenyl)-17-hydroxy-13-methyl-17-(prop-1-yn-1-yl)-1,2,6,7,8,11,12,13,14,15,16,17-dodecahydro-3H-cyclopenta[a]phenanthren-3-one – acetonitril (1/2), C33H41N3O2
  20. Crystal structure of tert-butyl (phenylsulfinyl)carbamate, C11H15NO3S
  21. Crystal structure of catena-poly{diaqua-bis(3-(1H-1,2,4-triazol-1-yl)benzoato-κ2O:N)copper(II)} monohydrate, C18H18CuN6O7
  22. Crystal structure of tetraaqua-bis(3-(4H-1,2,4-triazol-4-yl)benzoato-κN)cobalt(II), C18H20CoN6O8
  23. The crystal structure of 4-bromo-N-cyclopropyl-2,5-difluorobenzenesulfonamide, C9H8BrF2NO2S
  24. Crystal structure of ([3,3′-bipyridine]-6,6′-dicarboxylato-κ2O:O′)-bis(1,2-bis(4-pyridyl)ethane-κ2N:N′)disilver(I) dihydrate, C37H35Ag2N5O6
  25. The crystal structure of (4-(1H-1,2,4-triazol-1-yl)benzoato-κN)-[4-(1H-1,2,4-triazol-1-yl)benzoic acid-κN]silver(I), C18H13AgN6O4
  26. Crystal structure of 3-(4-methoxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one, C17H16O2
  27. Crystal structure of bis(2-((E)-((4-((E)-1-(ethoxyimino)ethyl)phenyl)imino)methyl)-5-methoxyphenolato-κ2O,N)copper(II), C36H38CuN4O6
  28. Crystal structure of poly[1,2-bis(1,2,4-triazol-4-yl)ethane-κ2N:N′]silver(I) bromate monohydrate]silver(I), C6H10AgBrN6O4
  29. The crystal structure of 2,3,5-triphenyl-2,3-dihydro-1H-tetrazol-1-ium 2,3-dioxoindoline-5-sulfonate, C27H19N5O5S
  30. Crystal structure of 3-(2-amino-1,3-selenazol-4-yl)-2H-chromen-2-one – dimethylformamide (1/1), C15H15N3O3Se
  31. Crystal structure of diethyl 3,3′-(diazene-1,2-diyl)(E)-dibenzoate, C18H18N2O4
  32. Crystal structure of cis-bis((1H-benzimidazol-2-yl)methanol-κN,O)-bis(isothiocyanato-κN)nickel(II), C18H16N6NiO2S2
  33. Crystal structure of bis(2-(2′-hydroxy-5′-methoxyphenyl)-1H-benzimidazole)boron – tetrahydrofuran (1/1), C36H37N4O6B
  34. Crystal structure of poly[aqua-bis(nitrato-κ2O,O′)-(μ3-1,3-benzimidazol-3-ium-1,3-diacetato-κ4O,O′:O′′:O′′′)dysprosium(III)], C11H11DyN4O11
  35. Crystal structure of n-butyl-tris(dicyclo-hexylamido)hafnium(IV), C40H75HfN3
  36. Crystal structure of (E)-1-[1-(3-chloro-4-fluoro-phenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine, C28H20Cl2F2N8O8
  37. The crystal structure of ethyl 4-((2-hydroxybenzyl)amino)benzoate, a Schiff base, C16H17NO3
  38. Crystal structure of 3-(2-(4-isobutylphenyl)propanoyl)-1-methylimidazolidine-2,4-dione, C17H22N2O3
  39. Crystal structure of poly[(μ3-2-(pyrazin-2-ylthio)acetato-κ3N:O:S)silver(I)], C6H5AgN2O2S
  40. Crystal structure of (E)-1-(3-((E)-((2-hydroxynaphthalen-1-yl)methylene)amino)phenyl)ethanone O-benzyl oxime, C26H22N2O2
  41. Crystal structure of (E)-2,3-dihydroxybenzaldehyde O-(2-((((E)-1-(2,5-dihydroxyphenyl)ethylidene)amino)oxy)ethyl) oxime monohydrate, C17H20N2O7
  42. Crystal structure of 4-(chloromethyl)-3-nitrobenzoic acid, C8H6ClNO4
  43. Crystal stucture of 4-((10H-phenothiazin-10-yl)methyl)-2,6-di-tert-butylphenol, C27H31NOS
  44. The crystal structure of ethyl 1-(4-nitrophenyl)-5-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C13H10F3N3O4
  45. Crystal structure of catena-poly[di-(μ3-oxido-κ3O:O:O)-tetraoxido-(μ2-5′-(pyrazin-2-yl)-1H,2′H-3,3′-bi(1,2,4-triazole)-κ2N:N′)dimolybdenum(VI)], C8H6Mo2N8O6
  46. Crystal structure of (3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ4O,O′:O′′,O′′′)-bis(tris(2-pyridylmethyl)amine-κ4N,N′,N′′,N′′′))-dizinc(II) bis(hexafluorophosphate(V)), C42H38F12N8O4P2Zn2
  47. Crystal structure of catena-poly[hexakis(μ2-2-acetylphenolato-κ3O:O,O′)trimanganese(II)], C48H42Mn3O12
  48. The crystal structure of 2,2-difluoro-4-(trifluoromethyl)-2,5-dihydro-[1,3,2]dioxaborinino[5,4-c]chromen-3-ium-2-uide, C11H6BF5O3
  49. Crystal structure of methyl (E)-2-(4-(diethylamino)-2-hydroxybenzylidene)hydrazine-1-carboxylate, C13H19N3O3
  50. The crystal structure of tert-butyl 2,6-dihydropyrrolo[3,4-c]pyrazole-5(4H)-carboxylate, C10H15N3O2
  51. Crystal structure of 1,1-bis(η5-adamantylcyclopentadienyl)-3-phenyl-2-trimethylsilyl-2,3-dihydroisotitanazole, C42H55NSiTi
  52. Crystal structure of 2-(4-(2-(4-benzylpiperazin-1-yl)ethyl)benzyl)isoindoline-1,3-dione, C28H29N3O2
  53. Important impurity of Flupirtine – a single crystal study on ethyl (6-amino-5-((ethoxycarbonyl)amino)pyridin-2-yl)(4-fluorobenzyl)carbamate, C18H21FN4O4
  54. Crystal structure of ethyl 3-(4-methoxyphenyl)-1-(2-(4-methoxyphenyl)-2-oxoethyl)-1H-pyrazole-5-carboxylate, C22H22N2O5
  55. Crystal structure of 2,3,9,10-tetramethoxy-5,6-dihydroisoquinolino[2,1-b]isoquinolin-7-ium 5-hydroxy-3-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-olate methanol solvate, C37H35N1O10
  56. The crystal structure of the inner salt of 2-[(aminoiminomethyl)amino]ethylcarbamic acid [systematic name: (2-((diaminomethylene)ammonio)ethyl)carbamate], C4H10N4O2
  57. Crystal structure of (8-hydroxy-5-nitroquinolinium) perchlorate – 8-hydroxy-5-nitroquinoline (1/1), C18H13ClN4O10
  58. The crystal structure of (5-methyl-1,2,4-oxadiazol-3-yl)ferrocene, C13H12FeN2O
  59. Crystal structure of methyl 1-(2-(fluorosulfonyl)ethyl)-2-oxocyclopentanecarboxylate, C9H13FO5S
  60. Crystal structure of the triclinic modification of 1-methyl-4-nitroimidzole, C4H5N3O2
  61. Corrigendum
  62. Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 4.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2016-0285/html?srsltid=AfmBOopbmJjNmDREd0dl-J6mC_z75-f1_beNsqkAAH8gcx8IrustkGCe
Button zum nach oben scrollen