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The synthesis of nanocellulose-based nanocomposites for the effective removal of hexavalent chromium ions from aqueous solution

  • Fatimah Mohammed Alzahrani , Abdelfattah Amari , Khadijah Mohammedsaleh Katubi EMAIL logo , Norah Salem Alsaiari EMAIL logo and Mohamed A. Tahoon
Published/Copyright: September 30, 2022
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Open Chemistry
From the journal Open Chemistry Volume 20 Issue 1

Abstract

The present study reports the synthesis of a polydopamine (PDA)/nanocellulose (NC) nanocomposite for the effective removal of chromium ions from water. PDA was used to modify NC surface producing a nanocomposite namely PDA/NC, by in situ polymerization of dopamine on the surface of NC. Thereafter, the as-synthesized nanocomposite was characterized using familiar techniques such as Fourier transform infrared, X-ray diffraction, X-ray photoelectron spectroscopy, ultraviolet-visible spectroscopy, and transmission electron microscopy. All results indicated the successful combination of PDA and NC in one nanocomposite. The PDA/NC nanocomposite was evaluated for the removal of hexavalent Cr(vi) ions from an aqueous solution. The adsorption conditions, such as pH, contact time, and initial Cr(vi) concentration, were optimized. Adsorption kinetic studies revealed that Cr(vi) removal on the surface of PDA/NC nanocomposite followed the pseudo-second-order kinetic model. Furthermore, isotherm studies revealed that Cr(vi) removal followed the Langmuir isotherm model with a maximum adsorption capacity (q m) of 210 mg/g. The adsorption mechanism study indicated that the Cr(vi) removal was reached via complexation, adsorption, and chemical reduction. The reusability of a PDA/NC nanocomposite for the removal of Cr(vi) ions was studied up to five cycles with acceptable results. The high adsorption capacity and multiple removal mechanisms validated the effective applicability of PDA/NC nanocomposite as a useful adsorbent for the removal of Cr(vi) ions from aqueous solution.

Keywords: nanocomposites; nanocellulose; polydopamine; adsorption; water treatment; hexavalent chromium ions

1 Introduction

Water pollution has posed a serious threat to human health and the environment [1,2,3]. The main pollutants of water are heavy metals, inorganic and organic chemicals, pesticides, and fertilizers. These pollutants mostly come from household wastes, agriculture, and chemical industries [4,5,6]. Among all pollutants, heavy metals are the most dangerous due to their high levels in water and inability to decompose [7,8]. Among all heavy metals, hexavalent chromium (Cr(vi)) is the most harmful to the environment [9,10]. Cr(vi) ions can cause genetic defects and cancer in living organisms and humans [11,12]. Therefore, industrial wastewater containing Cr(vi) ions must be treated before it is released into the environment. Several efforts have been made to remove Cr(vi) ions from aqueous solutions using many methods, including adsorption, ion exchange, photocatalysis, precipitation, and membrane separation [13,14,15,16]. Among all the methods used, adsorption is the most widely used due to its high efficiency, low cost, flexibility, and simple operation [17,18]. Several adsorbents have been investigated for the removal of Cr(vi) ions, such as biomaterials, inorganic materials, and activated carbons [19,20,21]. However, due to its low capacity, its real application in the removal of Cr(vi) ions is limited. Therefore, there is a need to develop new adsorbents to remove Cr(vi) ions from aqueous solution with high efficiency.

Cellulose is a natural biopolymer originating from biomass plants, such as vines, straws, and trees, which make it so widely distributed and used. The mentioned sources can be used to synthesize cellulose using biological, chemical, and mechanical methods. Cellulose synthesized in the nanoscale range is known as nanocellulose (NC) [22]. NC has abundant hydroxyl groups, excellent mechanical properties, and a high specific surface area, which makes it an excellent adsorbent for removing pollutants from water. NC has been widely used as an adsorbent for removing toxic dyes and heavy metals from water [23,24,25]. But, the application of NC for the removal of heavy metals is limited due to its low adsorption capacity. This limitation can be overcome by modifying the surface of NC to increase its affinity and capacity toward the target adsorbate ions.

Polydopamine (PDA) is a promising material used in various applications, such as biomedical, environmental, and energy fields, due to its ability to bind metals and adhesion efficiency [26]. PDA is synthesized by the self-polymerization of dopamine, which has a high content of amine and catechol functional groups. These functional groups enable its interaction with inorganic and organic materials via non-covalent and covalent attachment. Recently, the adsorption capacities toward organic and metallic pollutants have been enhanced by modifying different adsorbents using PDA. For instance, chitosan hydrogel beads immobilized with silver nanoparticles were coated with PDA for antimicrobial activities and adsorption activity toward dyes and heavy metals [27]. Tungsten oxide@poly(vinylidene fluoride-co-hexafluoropropylene) electrospun nanofibers were coated with PDA to form a membrane with oil rejection ability and ampicillin degradation ability [28]. In addition, magnetic graphene oxide (GO/Fe3O4) nanoparticles were coated using PDA for the high removal efficiency of fluoroquinolone antibiotics, exceeding 95% [29]. In addition, MnO2-loaded polyacrylonitrile was coated with PDA to form a composite of MnO2/PDA/polyacrylonitrile fibers for the effective removal of lead (Pb2+) ions [30]. Recently, PDA has been used to modify metal-organic framework (MOF) for the efficient removal of Pb2+ and Hg2+ heavy metals from water samples [31]. These studies show that the PDA is an excellent and promising modifier for various types of adsorbents, including magnetic nanoparticles, graphene, graphene oxides, chitosan, glass, and MOF. This is attributed to its unique chemical and physical properties, such as thermal stability, antioxidant properties, biocompatibility, binding ability, and adhesive properties.

In this context, the NC surface was functionalized using PDA to synthesize the nanocomposite (PDA/NC) that was investigated for the removal of Cr(vi) ions from the aqueous solution. The synthesized nanocomposite displayed high adsorption capacity, adsorption rate, and good reusability for the removal of Cr(vi) ions from water. The introduced adsorbent here proposes a hopeful candidate for efficient water treatment.

2 Materials and methods

2.1 Materials

Cotton pulp (99% cellulose content) was supplied by Alexandria Company for General Supplies, Egypt. Tris(hydroxymethyl)-aminomethane (Tris) was purchased from Shanghai Sinopharm Chemical Reagent. Dopamine hydrochloride and potassium dichromate (K2Cr2O7) were purchased from Sigma-Aldrich. Sodium hydroxide (NaOH), sulfuric acid (H2SO4), hydrochloric acid (HCl), and aqueous ammonium (33%) were purchased from El-Gomhouria Co., Egypt. All chemicals were analytical grade and used without modification. Distilled water was used for the preparation of all solutions.

2.2 NC synthesis

NC was synthesized according to the literature [32] with certain modifications. A hydrolysis reaction of cotton pulp using H2SO4 was used for the synthesis of NC. Briefly, 2 g of cotton pulp was crushed and ground into fine portions, followed by treatment with 2% NaOH for 12 h at room temperature. Then, the solution was filtered and washed using distilled H2O until it reached a neutral pH value. The resulting fine powder was dried and mixed with 16 mL of 65% H2SO4 for 40 min at 40°C with continuous stirring. The centrifugation at 4,000 rpm was used to obtain the product that was washed many times with distilled H2O until it reached a neutral pH value. After that, ultra-sonication at 0°C for 30 min at 20 kHz was used to disperse the hydrolyzed cellulose in H2O. Finally, the resultant NC suspension was freeze-dried to obtain the NC powder.

2.3 The synthesis of PDA particles

Typically, a mixed solvent of aqueous ammonia, ethanol, and deionized water was prepared with volumes of 1.12, 112, and 252 mL, respectively. Then, 28 mL of deionized water was used to dissolve 1.4 g of dopamine hydrochloride with continuous stirring for half hour. After that, the aqueous solution of dopamine was added to the previously prepared mixed solvent, and the reaction was left to undertake for 1 day in an open container with slow stirring. Finally, the solution was centrifuged for 15 min, and the synthesized PDA particles were collected and washed several times with deionized water.

2.4 The synthesis of PDA/NC nanocomposite

The synthesis of the PDA/NC nanocomposite was achieved through the in situ polymerization of dopamine monomer on the surface of NC. Typically, a homogenous suspension was obtained by mixing 1 g NC with 500 mL of distilled H2O under the sonication process. After that, NC suspension was provided with 0.6 g of Tris, and the solution pH was kept at 8.5 using HCl and NaOH. At room temperature and with continuous stirring for 2 days in the air, the previous solution was provided with 1 g of dopamine to initiate the polymerization reaction. The solution slowly turned from pink to black color. Then, the centrifugation of the solution at 10,000 rpm was used to collect the product, and the PDA/NC solid was washed several times with distilled H2O until the supernatant was clear. Finally, the solid PDA/NC nanocomposite was freeze-dried to be ready for characterization and application. Scheme 1 shows the synthesis of the PDA/NC nanocomposite for the removal of Cr(vi) ions.

Scheme 1 Schematic illustration of the PDA/NC nanocomposite synthesis for the removal of Cr(vi) ions.
Scheme 1

Schematic illustration of the PDA/NC nanocomposite synthesis for the removal of Cr(vi) ions.

2.5 Equipment and apparatus

To confirm the combination of PDA and NC in the nanocomposite PDA/NC, various characterization techniques were used, including X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), ultraviolet (UV)-spectroscopy, and transmission electron microscopy (TEM). Functional groups and chemical structures of materials were investigated by the Tensor II FT-IR spectrometer (Bruker, Germany) over the range of 500–4,000 cm−1. A D8 ADVANCE X-ray diffractometer from Bruker was used to obtain the XRD of materials to explore their crystalline structures. XRD was examined at a scanning rate of 5° min−1 in the range of 5–40°. The surface elements of the materials were examined using XPS (Thermo Fisher Scientific, USA). The material morphology was characterized using TEM (JEM-2100F; JEOL, Japan). N2 sorption data were determined by the Brunauer−Emmett−Teller method (BET; Tristar II Plus; Micromeritics, USA) at 77 K. The thermal stability of the materials was determined using thermogravimetric analysis (TGA; PerkinElmer, USA). A pH meter (FE28; Mettler Toledo) was used to measure the pH value of the used solutions.

2.6 Cr(vi) removal experiments

A glass bottle was used to perform the adsorption experiments by stirring the mixture of a definite amount of PDA/NC nanocomposite with various concentrations of Cr(vi) ions solution at 25°C. The concentration of Cr(vi) ions was determined using a calibration curve by measuring the absorbance of the solution at 350 nm using a UV-visible (vis) spectrophotometer. The removal efficiency (%) and adsorption capacity (q e) of PDA/NC nanocomposite toward Cr(vi) ions can be calculated according to equations (1) and (2), respectively.

(1) Removal efficiency ( % ) = ( ( C 0 − C e ) / C 0 ) × 100 ,

(2) Adsorption capacity ( q e ) = ( ( C 0 − C e ) / m ) × V ,

where C 0, C e, m, and V denote Cr(vi) initial concentration, Cr(vi) concentration at equilibrium, the mass of PDA/NC nanocomposite in gram, and the volume of the solution in L, respectively. To study the pH effect on the Cr(vi) ions removal on the surface of synthesized materials, the adsorption experiments were performed at pH ranging from 2 to 11. The pH value was adjusted using 0.1 M of NaOH and H2SO4. The pH effect was studied using 100 mg/L of Cr(vi) solution, a volume of 10 mL, an adsorbent dose of 10 mg, and stirring for 1 day at 25°C. The Cr(vi) content after each adsorption experiment was determined using a UV-vis spectrophotometer. To study the rate of Cr(vi) ions adsorption on the surface of synthesized materials, 12 mg of adsorbent was mixed with Cr(vi) ions at different initial concentrations ranging from 200 to 300 mg/L at a pH of 3, and the solution volume of 20 mL. At different times, the Cr(vi) ions content was determined using the UV-vis spectrophotometer to study the adsorption kinetics. To study the adsorption isotherm, different concentrations of Cr(vi) ions ranging from 30 to 600 mg/L were mixed with 6 mg of adsorbent at a pH of 3 for 1 day at 25°C using a volume solution of 10 mL. After each adsorption experiment, the solution was filtered and examined for the presence of Cr(vi) ions, and the adsorption capacity was determined to study the adsorption isotherm. The reusability of PDA/NC nanocomposite for the removal of Cr(vi) ions was studied up to five successive cycles of 0.5 M NaOH and 0.5 M sodium chloride for adsorbent regeneration after each cycle. During the reusability study, 10 mL of 20 mg/L Cr(vi) ions was mixed with 6 mg of adsorbent at 25°C for 12 h at a pH of 3. Then, the solution was filtered and examined for the presence of Cr(vi) ions, and the adsorbent was regenerated as described earlier. Then, the adsorbent was rinsed in distilled water and dried to be used in the next cycle.

3 Results and discussion

3.1 Characterization of PDA/NC nanocomposite

To study the crystallinity of the synthesized materials, XRD was performed, and the results are shown in Figure 1a. According to XRD results, the NC crystalline structure was found to be present in the PDA/NC nanocomposite, demonstrating that the addition of PDA did not affect the crystallinity of NC. According to the literature [33], the XRD of PDA/NC nanocomposite revealed the presence of cellulose I due to the appearance of diffraction planes (004), (200), (110), and (1−10) at 2θ = 34.6°, 22.8°, 16.8°, and 15.8°, respectively. Furthermore, the interaction between the PDA and the NC resulted in a reduction in peak intensity in the XRD of the PDA/NC nanocomposite.

Figure 1 XRD (a), FT-IR (b), full-range XPS spectra (c), for NC (d), for PDA/NC (e), and UV-vis spectra (f) of NC and PDA/NC nanocomposite.
Figure 1

XRD (a), FT-IR (b), full-range XPS spectra (c), for NC (d), for PDA/NC (e), and UV-vis spectra (f) of NC and PDA/NC nanocomposite.

To confirm the existence of functional groups, FT-IR spectra of PDA, NC, and PDA/NC were performed, and the results are shown in Figure 1b. According to the FT-IR results, the NC spectra showed the appearance of its specific bands corresponding to vibrations of water molecules, symmetric vibrations of C–H, and stretching vibrations of OH groups that appeared at 1,641, 2,904, and 3,418 cm−1, respectively. While the spectra of the PDA/NC nanocomposite showed some modifications in the range of 1,600–1,200 cm−1 due to the addition of PDA to the NC. So, the presence of PDA was confirmed from FT-IR spectra by the appearance of bands at 1,285 and 1,509 cm−1 that correspond to the stretching vibration of C–O and the scissoring vibration of N–H, respectively [34].

Further characterization was performed using XPS spectra. The XPS full scan for NC and PDA/NC was performed as shown in Figure 1c. The XPS full scan of PDA/NC in comparison to NC showed the appearance of an additional peak at 403 eV related to N1s and confirmed the existence of PDA in the nanocomposite as reported in the literature [35]. In addition, the XPS high resolution C1s spectra were obtained for NC and PDA/NC nanocomposite, as shown in Figure 1d and e, respectively. The high resolution of C1s spectra of NC showed the appearance of four fractions at 289.1, 288.07, 286.6, and 285.1 eV that correspond to O–C═O, O–C–O/C═O, C–O, and C–C/C–H, respectively, as reported in the literature [36]. The high resolution of the C1s spectra of PDA/NC showed the appearance of the same fractions as well as the appearance of an additional fraction at 286.3 eV that corresponds to C–N, indicating a well combined PDA and NC in one composite.

Furthermore, the UV-vis spectra of both NC and PDA/NC were performed, and the results are shown in Figure 1f. The comparison of the two peaks showed the appearance of an additional peak at 280.0 nm by the addition of PDA to the surface of NC. This additional peak corresponds to the PDA parts and results from the π–π* transition as reported in a previous study [37]. All the above results indicate the well-functionalization of the NC surface with PDA.

To study morphology and the size of synthesized materials, the TEM images of NC and PDA/NC nanocomposite are shown in Figure 2a and b, respectively. According to Figure 2a, the acid hydrolysis of cotton pulp led to the successful synthesis of NC with a diameter of 13 nm. While the TEM image of the PDA/NC nanocomposite showed an increase in diameter after the addition of PDA to 15 nm. Figure 2b shows the successful functionalization of the NC surface with PDA. This functionalization was achieved as described in the literature [38] by the reaction of hydroxyl groups in NC with catechol groups in the PDA followed by the dehydration process to produce a charge-transfer complex. This functionalization is responsible for the diameter increase as well as the morphological change.

Figure 2 TEM image of (a) NC and (b) PDA/NC nanocomposite.
Figure 2

TEM image of (a) NC and (b) PDA/NC nanocomposite.

Furthermore, TGA was used to determine the thermal stability of the synthesized nanomaterials, and the results are shown in Figure 3a. According to TGA results, at 100°C, the synthesized NC showed a weight loss of 3% that resulted from the evaporation of adsorbed H2O. At 280°C, NC was degraded and, subsequently, it showed a weight loss of 71%. While at 390°C, the NC residuals were decomposed into carbon dioxide and water and showed a weight loss of 24% [39]. For PDA, the heating under a nitrogen atmosphere to 800°C showed a residual weight of 56% in a multistep loss, indicating the heterogeneous construction of PDA.

Figure 3 TGA (a) and nitrogen adsorption–desorption isotherm (b) of synthesized NC, PDA, and PDA/NC nanocomposite.
Figure 3

TGA (a) and nitrogen adsorption–desorption isotherm (b) of synthesized NC, PDA, and PDA/NC nanocomposite.

For PDA/NC nanocomposite, at 100°C, the adsorbed H2O molecules evaporated, causing a weight loss of 7%. At 280°C, the degradation of PDA and NC caused another weight loss of 31%. The weight loss of the PDA/NC nanocomposite reached 66% at a temperature of 800°C. The TGA results indicated that the PDA successfully functionalized the NC and enhanced its thermal stability. To study the effect of PDA on the improvement of NC surface area, the BET surface area was determined for NC and PDA/NC nanocomposite, and the results are shown in Figure 3b. The determined BET surface was found to be 0.75 and 107.5 m2/g for NC and PDA/NC, respectively. This enhanced surface area resulted from the addition of PDA to NC that improved the stability of the nanocomposite as well as the adsorption active site on the surface of the nanosorbent. This enhanced area will be very helpful to the uptake of more Cr(vi) ions from the aqueous solution during the adsorption process. All the above characterization techniques indicated the successful integration of PDA on the surface of NC to produce a PDA/NC nanocomposite.

3.2 Optimization of the adsorption conditions

To optimize the adsorption process of Cr(vi) ions on the surface of PDA/NC nanocomposite, the effect of different conditions like pH, initial Cr(vi) ions concentration, and contact time must be studied. Subsequently, the effect of the aforementioned conditions was studied as shown in Figure 4. The effect of initial Cr(vi) ions concentration was studied in the concentration range of 30–130 mg/L at fixed pH of 3 and room temperature, and the results are shown in Figure 4a. According to Figure 4a, the highest removal efficiency of Cr(vi) ions was reached at an initial concentration of 50 mg/L and found to equal 100%. When the initial concentration was increased from 50 to 65 mg/L, the removal efficiency decreased to 87%, and the continuous increase in initial concentration led to a gradual decrease in removal efficiency until it reached the lowest value (55%) at 130 mg/L. This behavior can be interpreted on the basis that the PDA/NC adsorbent has a fixed number of adsorption sites at a fixed dose of adsorbent. So, the low initial concentration of Cr(vi) ions can be adsorbed over sufficient numbers of active sites, and hence, the removal efficiency was increased. But, the increased initial concentration of Cr(vi) ions led to the uptake of ions corresponding to the fixed number of sites, and hence, the removal efficiency was decreased. This behavior of removal efficiency with the initial concentration of Cr(vi) ions was observed in several reported studies [40,41].

Figure 4 The effect of pH (a), initial concentration (b), and contact time (c) on the removal of Cr(vi) ions over the surface of PDA/NC nanocomposite.
Figure 4

The effect of pH (a), initial concentration (b), and contact time (c) on the removal of Cr(vi) ions over the surface of PDA/NC nanocomposite.

As the adsorbent–Cr(vi) interaction greatly depends on the pH value, the solution pH is an essential parameter affecting the Cr(vi) removal [42]. According to pH value, Cr(vi) species are present. At pH < 1, H2CrO4 is the main form of chromium ions. At a pH range of 2–6, Cr 2 O 7 2 − and HCrO4 − are the main forms of chromium ions. At pH > 6, CrO 4 2 − is the main form of chromium ions. This dependence of chromium existence on the pH value was explained in our previous study [43]. The effect of pH on the adsorption of Cr(vi) ions over PDA/NC nanocomposite was studied in the range of 3–11, and the results are shown in Figure 4b. According to Figure 4b, the increased pH value led to a decreased removal efficiency of Cr(vi) ions. The highest removal efficiency was reached at a pH value of 3. This behavior can be attributed to the strong interaction between the protonated surface of the PDA/NC nanocomposite at a low pH value and the anion species of chromium ions [44]. The excess H+ ions at low pH values cause protonation of functional groups on the surface of the adsorbent to form a positively charged adsorbent that can capture the negatively charged chromium ions through electrostatic interaction, and hence, the removal efficiency was increased. So, the optimum pH value for the removal of Cr(vi) ions on PDA/NC nanocomposite is 3. While at a higher pH value, the excess OH− ions were repulsed by negatively charged chromium ions and caused a decrease in the removal efficiency. This behavior of pH effect on Cr(vi) removal was observed in many reported studies [45,46].

To optimize the contact time for the removal of Cr(vi) ions on the surface of PDA/NC nanocomposite, the adsorption experiment was employed at different time intervals ranging from 0 to 1,600 min. Figure 4c displays the removal capacity of PDA/NC nanocomposite toward Cr(vi) ions at different contact times. According to Figure 4c, there are two stages of adsorption until equilibrium is reached: the slow stage and the rapid stage. The initial rapid phase showed an improved adsorption capacity of PDA/NC nanocomposite toward Cr(vi) ions. Subsequently, the optimum contact time for the adsorption of Cr(vi) ions is 6 h. Further increases in contact time over 6 h led to the appearance of a second slow phase. This phase showed a negligible effect of contact time on the adsorption of Cr(vi) ions on the surface of the PDA/NC nanocomposite. The initial stage showed a rapid and enhanced adsorption capacity toward Cr(vi) ions due to the availability of various active sites during this stage [47]. While at the second stage, the sites become saturated and the ions compete with each other for active sites [47], and the contact time has no significant effect here.

3.3 Adsorption kinetics

The controlling mechanism of Cr(vi) uptake by PDA/NC can be explained using the kinetic study. To explain the adsorption process of Cr(vi) ions on the surface of PDA/NC nanocomposite, the kinetic experimental data were fitted using two kinetic models, namely pseudo-first-order and pseudo-second-order models [48]. The pseudo-first-order and pseudo-second-order models can be expressed according to equations (3) and (4), respectively.

(3) ln q e − q t = ln q e − k 1 t ,

(4) t q t = 1 k 2 q e 2 + t / q e ,

where q t , q e, k 1, and k 2 denote the adsorption capacity at time t (min), the adsorption capacity at equilibrium, the pseudo-first-order kinetic adsorption rate constant, and the pseudo-second-order kinetic adsorption rate constant, respectively. Figure 5 shows the fitting of experimental data to pseudo-first-order and pseudo-second-order kinetic models, and their calculated parameters are tabulated in Table 1.

Figure 5 The fitting of experimental data to pseudo-first-order model (a) and pseudo-second-order model (b) for the adsorption of Cr(vi) ions on the surface of PDA/NC nanocomposite.
Figure 5

The fitting of experimental data to pseudo-first-order model (a) and pseudo-second-order model (b) for the adsorption of Cr(vi) ions on the surface of PDA/NC nanocomposite.

Table 1

The kinetic parameters of pseudo-first-order and pseudo-second-order models for the removal of Cr(vi) on the surface of PDA/NC nanocomposite

Pseudo first order Pseudo second order
q e (exp) (mg/g) q e (cal) (mg/g) K 1 R 2 q e (cal) (mg/g) K 2 R 2
123 33.42 0.0048 0.960 123.48 0.00067 0.9991

The experimental value of q e was closer to the calculated value from the pseudo-second-order model than the pseudo-first-order model. Also, the R 2 values as presented in Table 1 indicated that the removal of Cr(vi) ions on the surface of PDA/NC nanocomposite best fits the pseudo-second-order model than the pseudo-first-order model. These results indicate that the adsorption of Cr(vi) ions on the surface of the PDA/NC nanocomposite was achieved through a chemical adsorption process [49,50]. The chemical adsorption behavior indicates that the interaction between the functional groups on the surface of PDA/NC nanocomposite and the Cr(vi) ions occurred via a very strong complexation reaction.

3.4 Adsorption isotherm

To describe the adsorption process of Cr(vi) ions on the surface of PDA/NC nanocomposite, Langmuir and Freundlich isotherm models were used. The Langmuir and Freundlich isotherm models are represented according to equations (5) and (6), respectively.

(5) 1 / q e = ( 1 / q m K L ) C e + 1 / q m ,

(6) ln q e = ln K F + 1 n ln C e ,

where q m, K L, K F, and 1/n represent the maximum adsorption capacity (mg/g), Langmuir constant, Freundlich constant, and adsorption intensity factor, respectively.

Langmuir isotherm model suggests the monolayer homogenous adsorption of the adsorbate ions over the energetically similar active sites [51]. While the Freundlich isotherm model suggests the multilayer heterogeneous adsorption of the adsorbate ions [51]. The fitting of experimental data to Langmuir and Freundlich isotherm models is presented in Figure 6, and their calculated parameters were introduced in Table 2. The correlation coefficient (R 2) determines the suitability of the isotherm model to describe the adsorption process. According to the linearization curves of Langmuir and Freundlich’s isotherms shown in Figure 6 and the R 2 values in Table 2, the adsorption of Cr(vi) onto the surface of PDA/NC nanocomposite follows the Langmuir isotherm model. The results indicated that the uptake of Cr(vi) ions on the PDA/NC nanocomposite surface occurred via monolayer adsorption. In addition, the maximum adsorption capacity (q m) of PDA/NC nanocomposite is 210 mg/g, which is considered to be very high when compared to other adsorbents used for the removal of Cr(vi) ions. This enhanced adsorption capacity could be attributed to a large number of functional groups on the surface of the adsorbent due to the modification using PDA.

Figure 6 The fitting of experimental data to Langmuir isotherm (a) and Freundlich isotherm (b) for the adsorption of Cr(vi) ions on the surface of PDA/NC nanocomposite.
Figure 6

The fitting of experimental data to Langmuir isotherm (a) and Freundlich isotherm (b) for the adsorption of Cr(vi) ions on the surface of PDA/NC nanocomposite.

Table 2

The parameters of Freundlich and Langmuir isotherm models for the removal of Cr(vi) on the surface of PDA/NC nanocomposite

Langmuir Freundlich
q m (mg/g) K L R 2 K F n R 2
210 0.0148 0.988 43.30 4.35 0.911

3.5 Adsorption mechanism

The study of the removal mechanism gives a deep insight into the efficiency and action of the adsorbent during the treatment. To determine the mechanism of Cr(vi) removal on the surface of PDA/NC nanocomposite, XPS high-resolution Cr 2p spectra were performed on PDA/NC nanocomposite after the removal of Cr(vi) ions on its surface. Figure 7 shows the XPS Cr 2p spectra of the PDA/NC nanocomposite. According to Figure 7, there are two different species of chromium ions present (Cr(iii) and Cr(vi)). The integration area from the obtained spectra clearly shows the existence of these two ions on the adsorbent after water treatment. These results indicated that the Cr(vi) ions were removed from the surface of the studied adsorbent through two different mechanisms. In the first way, the catechol functional groups of PDA on the surface of NC reduced Cr(vi) to Cr(iii) and itself was oxidized to COOH– groups. Moreover, the electrons for the reduction of Cr(vi) are moved from nitrogen functional groups (catechol) of PDA as electron‐donating groups, causing the oxidation of catechol groups to COOH– groups. The formed Cr(iii) ions have vacant shell orbital that can receive lone-pair electrons from amine groups of PDA, causing the creation of a chelated complex. In a second way, the functional groups of PDA (amine and catechol) strongly chelate or electrostatically attract the Cr(vi) ions on the surface of the adsorbent. Based on the above analysis, Cr(vi) removal on the surface of PDA/NC nanocomposite was attributed to complexation, adsorption, and chemical reduction. These multiple removal mechanisms validated the effective applicability of PDA/NC nanocomposite as a perfect adsorbent for the removal of Cr(vi) ions from an aqueous solution.

Figure 7 XPS high-resolution Cr 2p spectra of PDA/NC nanocomposite after the removal of Cr(vi) ions.
Figure 7

XPS high-resolution Cr 2p spectra of PDA/NC nanocomposite after the removal of Cr(vi) ions.

3.6 Regeneration and reusability study

The reusability of any adsorbent is an important factor for use in large-scale water treatment, as it reduces the overall cost of treatment [52,53,54,55,56]. The reusability of PDA/NC nanocomposite was studied for the removal of Cr(vi) ions up to five successive cycles. Figure 8 shows the reusability study of PDA/NC nanocomposite as an adsorbent for Cr(vi) ions. Each cycle consists of an adsorption part followed by a desorption. The nanocomposite was used for the adsorption of Cr(vi) ions followed by the collection of nanocomposite and washing by NaOH and NaCl to desorb attached Cr(vi) ions and regenerate the adsorption sites. After each cycle, the solution was examined for the existence of Cr(vi) ions. According to Figure 8, the highest removal efficiency was achieved for the first cycle due to the presence of fresh unused active sites.

Figure 8 Reusability of PDA/NC nanocomposite for the removal of Cr(vi) ions up to five cycles.
Figure 8

Reusability of PDA/NC nanocomposite for the removal of Cr(vi) ions up to five cycles.

After that, the removal efficiency decreased from one cycle to another until it reached the minimum efficiency in the fifth cycle. The nanocomposite lost 92% of its efficiency in the last cycle. This means that most of the adsorption sites on the surface of PDA/NC nanocomposites cannot be regenerated, and subsequently, poor reusability results. This can be attributed to the mechanism of removal as the sites removed Cr(vi) by adsorption can be regenerated, while the sites removed Cr(vi) by reduction (which involved the oxidation of catechol groups to carboxylic groups) cannot be regenerated as reported in the literature [57].

3.7 Comparative study

The PDA/NC nanocomposite synthesized in the present study showed a high adsorption capacity. This adsorption capacity was compared with the capacities of previously reported adsorbents for Cr(vi) removal as presented in Table 3. According to the comparison in Table 3, the PDA/NC nanocomposite showed excellent adsorption capacity compared to other reported adsorbents.

Table 3

The comparison between different adsorbents for the removal of Cr(vi) ions

Adsorbent Adsorption capacity (mg/g) References
PDA/NC 210 This study
NiCo-LDH 100 [58]
Ppy/Fe3O4 magnetic nanocomposite 169.4 [59]
Fe2O3@SiO2 153 [60]
Magnetic SiO2@CoFe2O4 nanoparticles 136.4 [61]
Bentonite clay@MnFe2O4 composite 178.57 [47]
Sodium alginate-polyaniline 73.34 [62]
Stacked CS 131.58 [63]
Polyacrylonitrile/NH2 156 [64]
Fe3O4@SBA-15-PDA/HBP-NH2 66.5 [65]
Mn-incorporated ferrihydrite 48.5 [66]
ppy@magnetic chitosan 105.0 [67]

4 Conclusion

In this work, PDA-functionalized NC was fabricated using in situ polymerization of dopamine on the surface of NC. The as-synthesized PDA/NC nanocomposite was well characterized, indicating the successful fabrication of the hybrid nanocomposite. The PDA/NC nanocomposite showed a higher BET surface area than NC that attributed to the addition of PDA on the surface of NC. Moreover, the PDA/NC nanocomposite showed enhanced thermal stability compared to its parts. The synthesized adsorbent showed good adsorption toward Cr(vi) ions from an aqueous solution at optimum conditions of pH, contact time, and initial concentration. The study of adsorption kinetics indicated that the removal of Cr(vi) follows the pseudo-second-order kinetic model. The study of adsorption isotherm indicated the monolayer removal of Cr(vi) on the energetically identical active sites. In addition, the maximum adsorption capacity (q m) was found to be 210 mg/g. The removal mechanism was studied, indicating the elimination of Cr(vi) ions from aqueous solution in three ways, including adsorption, complexation, and chemical reduction. The reusability of the synthesized nanocomposite was studied for up to five cycles, with poor results attributed to the mechanism of removal and damaged active sites. According to the results, the PDA/NC nanocomposite is a promising candidate for the removal of Cr(vi) ions from water.

Acknowledgment

The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through the research groups program under Grant No. GRP/88/43. Furthermore, this research was funded by Princess Nourah bint Abdulrahman University Researchers Supporting Project No. PNURSP2022R42, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

  1. Funding information: This research was funded by the Deanship of Scientific Research at King Khalid University under grant number GRP/88/43. Additionally, this research was funded by Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2022R42), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

  2. Author contributions: All authors contributed equally to this study.

  3. Conflict of interest: The authors declare that they have no conflicts of interest.

  4. Ethical approval: The conducted research is not related to either human or animal use.

  5. Data availability statement: The research data used to support the findings of this study are included within the article.

References

[1] Siddeeg SM, Amari A, Tahoon MA, Alsaiari NS, Rebah FB. Removal of meloxicam, piroxicam and Cd+2 by Fe3O4/SiO2/glycidyl methacrylate-S-SH nanocomposite loaded with laccase. Alex Eng J. 2020;59(2):905–14. 10.1016/j.aej.2020.03.018.Search in Google Scholar

[2] Tahoon MA, Siddeeg SM, Salem Alsaiari N, Mnif W, Ben Rebah F. Effective heavy metals removal from water using nanomaterials: A review. Processes. 2020;8(6):645. 10.3390/pr8060645.Search in Google Scholar

[3] Alzahrani FM, Alsaiari NS, Katubi KM, Amari A, Ben Rebah F, Tahoon MA. Synthesis of polymer-based magnetic nanocomposite for multi-pollutants removal from water. Polymers. 2021;13(11):1742. 10.3390/polym13111742.Search in Google Scholar PubMed PubMed Central

[4] Singh C, Tiwari S, Singh JS. Biochar: A sustainable tool in soil pollutant bioremediation. Bioremediation of industrial waste for environmental safety. Singapore: Springer; 2020. p. 475–94.10.1007/978-981-13-3426-9_19Search in Google Scholar

[5] El-Gaayda J, Titchou FE, Oukhrib R, Yap P-S, Liu T, Hamdani M, et al. Natural flocculants for the treatment of wastewaters containing dyes or heavy metals: A state-of-the-art review. J Environ Chem Eng. 2021;9:106060. 10.1016/j.jece.2021.106060.Search in Google Scholar

[6] Bankole MT, Abdulkareem AS, Mohammed IA, Ochigbo SS, Tijani JO, Abubakre OK, et al. Selected heavy metals removal from electroplating wastewater by purified and polyhydroxylbutyrate functionalized carbon nanotubes adsorbents. Sci Rep. 2019;9(1):1–19. 10.1038/s41598-018-37899-4.Search in Google Scholar PubMed PubMed Central

[7] Su Y-Q, Zhao Y-J, Wu N, Chen Y-E, Zhang W-J, Qiao D-R, et al. Chromium removal from solution by five photosynthetic bacteria isolates. Appl Microbiol Biotechnol. 2018;102(4):1983–95. 10.1007/s00253-017-8690-x.Search in Google Scholar PubMed

[8] Venkateswarlu S, Panda A, Kim E, Yoon M. Biopolymer-coated magnetite nanoparticles and metal–organic framework ternary composites for cooperative Pb (II) adsorption. ACS Appl Nano Mater. 2018;1(8):4198–210. 10.1021/acsanm.8b00957.Search in Google Scholar

[9] Islam MA, Angove MJ, Morton DW, Pramanik BK, Awual MR. A mechanistic approach of chromium (VI) adsorption onto manganese oxides and boehmite. J Environ Chem Eng. 2020;8(2):103515. 10.1016/j.jece.2019.103515.Search in Google Scholar

[10] Liu W, Yang L, Xu S, Chen Y, Liu B, Li Z, et al. Efficient removal of hexavalent chromium from water by an adsorption–reduction mechanism with sandwiched nanocomposites. RSC Adv. 2018;8(27):15087–93. 10.1039/C8RA01805G.Search in Google Scholar

[11] Fei X, Ling Y, Shan Q, Hei D, Jia W. Catalytic effect of a semiconductor on the removal of hexavalent chromium from aqueous solution by γ-ray irradiation. Water Air Soil Pollut. 2017;228(9):1–6. 10.1007/s11270-017-3535-x.Search in Google Scholar

[12] Hmamou M, Sbihi K, Ammary B, Bellaouchou A. Study of chromium adsorption by iron hydroxide. Mater Today Proc. 2020;24:52–9. 10.1016/j.matpr.2019.07.528.Search in Google Scholar

[13] Xiao X, Deng Y, Xue J, Gao Y. Adsorption of chromium by functionalized metal organic frameworks from aqueous solution. Environ Technol. 2021;42(12):1930–42. 10.1080/09593330.2019.1683618.Search in Google Scholar PubMed

[14] Peng H, Guo J. Removal of chromium from wastewater by membrane filtration, chemical precipitation, ion exchange, adsorption electrocoagulation, electrochemical reduction, electrodialysis, electrodeionization, photocatalysis and nanotechnology: A review. Environ Chem Lett. 2020;18:2055–68. 10.1007/s10311-020-01058-x.Search in Google Scholar

[15] Zhao Z, An H, Lin J, Feng M, Murugadoss V, Ding T, et al. Progress on the photocatalytic reduction removal of chromium contamination. Chem Rec. 2019;19(5):873–82. 10.1002/tcr.201800153.Search in Google Scholar PubMed

[16] Dognani G, Hadi P, Ma H, Cabrera FC, Job AE, Agostini D.L.S, Hsiao BS., Effective chromium removal from water by polyaniline-coated electrospun adsorbent membrane. Chem Eng J. 2019;372:341–51. 10.1016/j.cej.2019.04.154.Search in Google Scholar

[17] Amari A, Elboughdiri N, Ghernaout D, Lajimi RH, Alshahrani AM, Tahoon MA, et al. Multifunctional crosslinked chitosan/nitrogen-doped graphene quantum dot for wastewater treatment. Ain Shams Eng J. 2021;12:4007–14. 10.1016/j.asej.2021.02.024.Search in Google Scholar

[18] Dai Y, Sun Q, Wang W, Lu L, Liu M, Li J, et al. Utilizations of agricultural waste as adsorbent for the removal of contaminants: A review. Chemosphere. 2018;211:235–53. 10.1016/j.chemosphere.2018.06.179.Search in Google Scholar PubMed

[19] Fotsing PN, Woumfo ED, Mezghich S, Mignot M, Mofaddel N, Le Derf F, et al. Surface modification of biomaterials based on cocoa shell with improved nitrate and Cr (vi) removal. RSC Adv. 2020;10(34):20009–19. 10.1039/D0RA03027A.Search in Google Scholar PubMed PubMed Central

[20] Gallo-Cordova A, Morales MDP, Mazarío E. Effect of the surface charge on the adsorption capacity of chromium (VI) of iron oxide magnetic nanoparticles prepared by microwave-assisted synthesis. Water. 2019;11(11):2372. 10.3390/w11112372.Search in Google Scholar

[21] Tu B, Wen R, Wang K, Cheng Y, Deng Y, Cao W, et al. Efficient removal of aqueous hexavalent chromium by activated carbon derived from Bermuda grass. J Colloid Interface Sci. 2020;560:649–58. 10.1016/j.jcis.2019.10.103.Search in Google Scholar PubMed

[22] Wei J, Yang Z, Sun Y, Wang C, Fan J, Kang G, et al. Nanocellulose-based magnetic hybrid aerogel for adsorption of heavy metal ions from water. J Mater Sci. 2019;54(8):6709–18. 10.1007/s10853-019-03322-0.Search in Google Scholar

[23] Qiao A, Cui M, Huang R, Ding G, Qi W, He Z, et al. Advances in nanocellulose-based materials as adsorbents of heavy metals and dyes. Carbohydr Polym. 2021;272:118471. 10.1016/j.carbpol.2021.118471.Search in Google Scholar PubMed

[24] Tshikovhi A, Mishra SB, Mishra AK. Nanocellulose-based composites for the removal of contaminants from wastewater. Int J Biol Macromol. 2020;152:616–32. 10.1016/j.ijbiomac.2020.02.221.Search in Google Scholar PubMed

[25] Faiz Norrrahim MN, Mohd Kasim NA, Knight VF, Mohamad Misenan MS, Janudin N, Ahmad Shah NA, et al. Nanocellulose: A bioadsorbent for chemical contaminant remediation. RSC Adv. 2021;11(13):7347–68. 10.1039/D0RA08005E.Search in Google Scholar

[26] Liu Y, Ai K, Lu L. Polydopamine and its derivative materials: Synthesis and promising applications in energy, environmental, and biomedical fields. Chem Rev. 2014;114(9):5057–115. 10.1021/cr400407a.Search in Google Scholar PubMed

[27] Wang T, Kuttappan D, Amalaradjou MA, Luo Y, Luo Y. Polydopamine-coated chitosan hydrogel beads for synthesis and immobilization of silver nanoparticles to simultaneously enhance antimicrobial activity and adsorption kinetics. Adv Compos Hybrid Mater. 2021;4(3):696–706. 10.1007/s42114-021-00305-1.Search in Google Scholar

[28] Mavukkandy MO, Ibrahim Y, Almarzooqi F, Naddeo V, Karanikolos GN, Alhseinat E, et al. Synthesis of polydopamine coated tungsten oxide@poly (vinylidene fluoride-co-hexafluoropropylene) electrospun nanofibers as multifunctional membranes for water applications. Chem Eng J. 2022;427:131021. 10.1016/j.cej.2021.131021.Search in Google Scholar

[29] Tan F, Liu M, Ren S. Preparation of polydopamine-coated graphene oxide/Fe3O4 imprinted nanoparticles for selective removal of fluoroquinolone antibiotics in water. Sci Rep. 2017;7(1):1–9. 10.1038/s41598-017-06303-y.Search in Google Scholar PubMed PubMed Central

[30] Li Y, Zhao R, Chao S, Sun B, Wang C, Li X. Polydopamine coating assisted synthesis of MnO2 loaded inorganic/organic composite electrospun fiber adsorbent for efficient removal of Pb2+ from water. Chem Eng J. 2018;344:277–89. 10.1016/j.cej.2018.03.044.Search in Google Scholar

[31] Sun DT, Peng L, Reeder WS, Moosavi SM, Tiana D, Britt DK, et al. Rapid, selective heavy metal removal from water by a metal–organic framework/polydopamine composite. ACS Cent Sci. 2018;4(3):349–56. 10.1021/acscentsci.7b00605.Search in Google Scholar PubMed PubMed Central

[32] Neto WPF, Silvério HA, Dantas NO, Pasquini D. Extraction and characterization of cellulose nanocrystals from agro-industrial residue–Soy hulls. Ind Crop Prod. 2013;42:480–8. 10.1016/j.indcrop.2012.06.041.Search in Google Scholar

[33] French AD. Idealized powder diffraction patterns for cellulose polymorphs. Cellulose. 2014;21(2):885–96. 10.1007/s10570-013-0030-4.Search in Google Scholar

[34] Liu W, Li Y, Meng X, Liu G, Hu S, Pan F, et al. Embedding dopamine nanoaggregates into a poly (dimethylsiloxane) membrane to confer controlled interactions and free volume for enhanced separation performance. J Mater Chem A. 2013;1(11):3713–23. 10.1039/C3TA00766A.Search in Google Scholar

[35] Yu Y, Shapter JG, Popelka-Filcoff R, Bennett JW, Ellis AV. Copper removal using bio-inspired polydopamine coated natural zeolites. J Hazard Mater. 2014;273:174–82. 10.1016/j.jhazmat.2014.03.048.Search in Google Scholar PubMed

[36] Chao C, Liu J, Wang J, Zhang Y, Zhang B, Zhang Y, et al. Surface modification of halloysite nanotubes with dopamine for enzyme immobilization. ACS Appl Mater Interfaces. 2013;5(21):10559–64. 10.1021/am4022973.Search in Google Scholar PubMed

[37] Huang S, Yang L, Liu M, Phua SL, Yee WA, Liu W, et al. Complexes of polydopamine-modified clay and ferric ions as the framework for pollutant-absorbing supramolecular hydrogels. Langmuir. 2013;29(4):1238–44. 10.1021/la303855t.Search in Google Scholar PubMed

[38] Xu Q, Kong Q, Liu Z, Zhang J, Wang X, Liu R, et al. Polydopamine-coated cellulose microfibrillated membrane as high performance lithium-ion battery separator. RSC Adv. 2014;4(16):7845–50. 10.1039/C3RA45879B.Search in Google Scholar

[39] Poletto M, Pistor V, Santana RMC, Zattera AJ. Materials produced from plant biomass: Part II: Evaluation of crystallinity and degradation kinetics of cellulose. Mater Res. 2012;15:421–7. 10.1590/S1516-14392012005000048.Search in Google Scholar

[40] Khalil U, Shakoor MB, Ali S, Rizwan M, Alyemeni MN, Wijaya L. Adsorption-reduction performance of tea waste and rice husk biochars for Cr (VI) elimination from wastewater. J Saudi Chem Soc. 2020;24(11):799–810. 10.1016/j.jscs.2020.07.001.Search in Google Scholar

[41] Prajapati AK, Das S, Mondal MK. Exhaustive studies on toxic Cr (VI) removal mechanism from aqueous solution using activated carbon of Aloe vera waste leaves. J Mol Liq. 2020;307:112956. 10.1016/j.molliq.2020.112956.Search in Google Scholar

[42] Tran HN, Nguyen DT, Le GT, Tomul F, Lima EC, Woo SH, et al. Adsorption mechanism of hexavalent chromium onto layered double hydroxides-based adsorbents: A systematic in-depth review. J Hazard Mater. 2019;373:258–70. 10.1016/j.jhazmat.2019.03.018.Search in Google Scholar PubMed

[43] Alsaiari NS, Katubi KM, Alzahrani FM, Amari A, Osman H, Rebah FB, et al. Synthesis, characterization and application of polypyrrole functionalized nanocellulose for the removal of Cr (VI) from aqueous solution. Polymers. 2021;13(21):3691. 10.3390/polym13213691.Search in Google Scholar PubMed PubMed Central

[44] Fan S, Wang Y, Li Y, Tang J, Wang Z, Tang J, et al. Facile synthesis of tea waste/Fe3O4 nanoparticle composite for hexavalent chromium removal from aqueous solution. RSC Adv. 2017;7(13):7576–90. 10.1039/C6RA27781K.Search in Google Scholar

[45] Liu C, Jin R-N, Ouyang X-k, Wang Y-G. Adsorption behavior of carboxylated cellulose nanocrystal–polyethyleneimine composite for removal of Cr (VI) ions. Appl Surf Sci. 2017;408:77–87. 10.1016/j.apsusc.2017.02.265.Search in Google Scholar

[46] Zhang K, Li H, Xu X, Yu H. Synthesis of reduced graphene oxide/NiO nanocomposites for the removal of Cr (VI) from aqueous water by adsorption. Microporous Mesoporous Mater. 2018;255:7–14. 10.1016/j.micromeso.2017.07.037.Search in Google Scholar

[47] Ahmadi A, Foroutan R, Esmaeili H, Tamjidi S. The role of bentonite clay and bentonite clay@ MnFe2O4 composite and their physico-chemical properties on the removal of Cr (III) and Cr (VI) from aqueous media. Environ Sci Pollut Res. 2020;27:1–14. 10.1007/s11356-020-07756-x.Search in Google Scholar PubMed

[48] Ho Y-S, McKay G. Kinetic models for the sorption of dye from aqueous solution by wood. Process Saf Environ Prot. 1998;76(2):183–91. 10.1205/095758298529326.Search in Google Scholar

[49] Eltaweil AS, El-Monaem EMA, Mohy-Eldin MS, Omer AM. Fabrication of attapulgite/magnetic aminated chitosan composite as efficient and reusable adsorbent for Cr (VI) ions. Sci Rep. 2021;11(1):1–15. 10.1038/s41598-021-96145-6.Search in Google Scholar PubMed PubMed Central

[50] Wang X, Liu X, Xiao C, Zhao H, Zhang M, Zheng N, et al. Triethylenetetramine-modified hollow Fe3O4/SiO2/chitosan magnetic nanocomposites for removal of Cr (VI) ions with high adsorption capacity and rapid rate. Microporous Mesoporous Mater. 2020;297:110041. 10.1016/j.micromeso.2020.110041.Search in Google Scholar

[51] Sadeghi MM, Rad AS, Ardjmand M, Mirabi A. Functionalization of SBA-15 by dithiooxamide towards removal of Co (II) ions from real samples: Isotherm, thermodynamic and kinetic studies. Adv Powder Technol. 2019;30(9):1823–34. 10.1016/j.apt.2019.05.028.Search in Google Scholar

[52] Alzahrani FM, Alsaiari NS, Katubi KM, Amari A, Elkhaleefa AM, Rebah FB, et al. Magnetic nitrogen-doped porous carbon nanocomposite for Pb (II) adsorption from aqueous solution. Molecules. 2021;26(16):4809. 10.3390/molecules26164809.Search in Google Scholar PubMed PubMed Central

[53] Mohammadi H, Ghaedi M, Fazeli M, Sabzehmeidani MM. Removal of hexavalent chromium ions and Acid Red 18 by superparamagnetic CoFe2O4/polyaniline nanocomposites under external ultrasonic fields. Microporous Mesoporous Mater. 2021;324:111275. 10.1016/j.micromeso.2021.111275.Search in Google Scholar

[54] Alsaiari NS, Amari A, Katubi KM, Alzahrani FM, Harharah HN, Rebah FB, et al. The biocatalytic degradation of organic dyes using laccase immobilized magnetic nanoparticles. Appl Sci. 2021;11(17):8216. 10.3390/app11178216.Search in Google Scholar

[55] Alsaiari NS, Amari A, Katubi KM, Alzahrani FM, Rebah FB, Tahoon MA. The synthesis of magnetic nitrogen-doped graphene oxide nanocomposite for the removal of reactive orange 12 dye. Adsorpt Sci Technol. 2022;2022:9417542. 10.1155/2022/9417542.Search in Google Scholar

[56] Alzahrani FM, Alsaiari NS, Katubi KM, Amari A, Tahoon MA. Synthesis, characterization, and application of magnetized lanthanum (III)-based metal-organic framework for the organic dye removal from water. Adsorpt Sci Technol. 2022;2022:3513829. 10.1155/2022/3513829.Search in Google Scholar

[57] Xu Q, Wang Y, Jin L, Wang Y, Qin M. Adsorption of Cu (II), Pb (II) and Cr (VI) from aqueous solutions using black wattle tannin-immobilized nanocellulose. J Hazard Mater. 2017;339:91–9. 10.1016/j.jhazmat.2017.06.005.Search in Google Scholar PubMed

[58] Hu H, Liu J, Xu Z, Zhang L, Cheng B, Ho W. Hierarchical porous Ni/Co-LDH hollow dodecahedron with excellent adsorption property for Congo red and Cr (VI) ions. Appl Surf Sci. 2019;478:981–90. 10.1016/j.apsusc.2019.02.008.Search in Google Scholar

[59] Bhaumik M, Maity A, Srinivasu V, Onyango MS. Enhanced removal of Cr (VI) from aqueous solution using polypyrrole/Fe3O4 magnetic nanocomposite. J Hazard Mater. 2011;190(1–3):381–90. 10.1016/j.jhazmat.2011.03.062.Search in Google Scholar PubMed

[60] Sobhanardakani S, Jafari A, Zandipak R, Meidanchi A. Removal of heavy metal (Hg (II) and Cr (VI)) ions from aqueous solutions using Fe2O3@ SiO2 thin films as a novel adsorbent. Process Saf Environ Prot. 2018;120:348–57. 10.1016/j.psep.2018.10.002.Search in Google Scholar

[61] Santhosh C, Daneshvar E, Kollu P, Peräniemi S, Grace AN, Bhatnagar A. Magnetic SiO2@CoFe2O4 nanoparticles decorated on graphene oxide as efficient adsorbents for the removal of anionic pollutants from water. Chem Eng J. 2017;322:472–87. 10.1016/j.cej.2017.03.144.Search in Google Scholar

[62] Karthik R, Meenakshi S. Removal of Cr (VI) ions by adsorption onto sodium alginate-polyaniline nanofibers. Int J Biol Macromol. 2015;72:711–7. 10.1016/j.ijbiomac.2014.09.023.Search in Google Scholar PubMed

[63] Li L, Li Y, Cao L, Yang C. Enhanced chromium (VI) adsorption using nanosized chitosan fibers tailored by electrospinning. Carbohydr Polym. 2015;125:206–13. 10.1016/j.carbpol.2015.02.037.Search in Google Scholar PubMed

[64] Avila M, Burks T, Akhtar F, Göthelid M, Lansåker PC, Toprak MS, et al. Surface functionalized nanofibers for the removal of chromium (VI) from aqueous solutions. Chem Eng J. 2014;245:201–9. 10.1016/j.cej.2014.02.034.Search in Google Scholar

[65] Liu F, Wang A, Xiang M, Hu Q, Hu B. Effective adsorption and immobilization of Cr (VI) and U (VI) from aqueous solution by magnetic amine-functionalized SBA-15. Sep Purif Technol. 2021;282:120042. 10.1016/j.seppur.2021.120042.Search in Google Scholar

[66] Liang C, Fu F, Tang B. Mn-incorporated ferrihydrite for Cr (VI) immobilization: Adsorption behavior and the fate of Cr (VI) during aging. J Hazard Mater. 2021;417:126073. 10.1016/j.jhazmat.2021.126073.Search in Google Scholar PubMed

[67] Alsaiari NS, Amari A, Katubi KM, Alzahrani FM, Rebah FB, Tahoon MA. Innovative magnetite based polymeric nanocomposite for simultaneous removal of methyl orange and hexavalent chromium from water. Processes. 2021;9(4):576. 10.3390/pr9040576.Search in Google Scholar
Received: 2022-04-15
Revised: 2022-09-09
Accepted: 2022-09-13
Published Online: 2022-09-30

© 2022 Fatimah Mohammed Alzahrani et al., published by De Gruyter

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  62. Clinical comprehensive and experimental assessment of the radioprotective effect of Annona muricata leaf extract to prevent cellular damage in the ileum tissue
  63. Effect of WC content on ultrasonic properties, thermal and electrical conductivity of WC–Co–Ni–Cr composites
  64. Influence of various class cleaning agents for prosthesis on Co–Cr alloy surface
  65. The synthesis of nanocellulose-based nanocomposites for the effective removal of hexavalent chromium ions from aqueous solution
  66. Study on the influence of physical interlayers on the remaining oil production under different development modes
  67. Optimized linear regression control of DC motor under various disturbances
  68. Influence of different sample preparation strategies on hypothesis-driven shotgun proteomic analysis of human saliva
  69. Determination of flow distance of the fluid metal due to fluidity in ductile iron casting by artificial neural networks approach
  70. Investigation of mechanical activation effect on high-volume natural pozzolanic cements
  71. In vitro: Anti-coccidia activity of Calotropis procera leaf extract on Eimeria papillata oocysts sporulation and sporozoite
  72. Determination of oil composition of cowpea (Vigna unguiculata L.) seeds under influence of organic fertilizer forms
  73. Activated partial thromboplastin time maybe associated with the prognosis of papillary thyroid carcinoma
  74. Treatment of rat brain ischemia model by NSCs-polymer scaffold transplantation
  75. Lead and cadmium removal with native yeast from coastal wetlands
  76. Characterization of electroless Ni-coated Fe–Co composite using powder metallurgy
  77. Ferrate synthesis using NaOCl and its application for dye removal
  78. Antioxidant, antidiabetic, and anticholinesterase potential of Chenopodium murale L. extracts using in vitro and in vivo approaches
  79. Study on essential oil, antioxidant activity, anti-human prostate cancer effects, and induction of apoptosis by Equisetum arvense
  80. Experimental study on turning machine with permanent magnetic cutting tool
  81. Numerical simulation and mathematical modeling of the casting process for pearlitic spheroidal graphite cast iron
  82. Design, synthesis, and cytotoxicity evaluation of novel thiophene, pyrimidine, pyridazine, and pyridine: Griseofulvin heterocyclic extension derivatives
  83. Isolation and identification of promising antibiotic-producing bacteria
  84. Ultrasonic-induced reversible blood–brain barrier opening: Safety evaluation into the cellular level
  85. Evaluation of phytochemical and antioxidant potential of various extracts from traditionally used medicinal plants of Pakistan
  86. Effect of calcium lactate in standard diet on selected markers of oxidative stress and inflammation in ovariectomized rats
  87. Identification of crucial salivary proteins/genes and pathways involved in pathogenesis of temporomandibular disorders
  88. Zirconium-modified attapulgite was used for removing of Cr(vi) in aqueous solution
  89. The stress distribution of different types of restorative materials in primary molar
  90. Reducing surface heat loss in steam boilers
  91. Deformation behavior and formability of friction stir processed DP600 steel
  92. Synthesis and characterization of bismuth oxide/commercial activated carbon composite for battery anode
  93. Phytochemical analysis of Ziziphus jujube leaf at different foliar ages based on widely targeted metabolomics
  94. Effects of in ovo injection of black cumin (Nigella sativa) extract on hatching performance of broiler eggs
  95. Separation and evaluation of potential antioxidant, analgesic, and anti-inflammatory activities of limonene-rich essential oils from Citrus sinensis (L.)
  96. Bioactivity of a polyhydroxy gorgostane steroid from Xenia umbellata
  97. BiCAM-based automated scoring system for digital logic circuit diagrams
  98. Analysis of standard systems with solar monitoring systems
  99. Structural and spectroscopic properties of voriconazole and fluconazole – Experimental and theoretical studies
  100. New plant resistance inducers based on polyamines
  101. Experimental investigation of single-lap bolted and bolted/bonded (hybrid) joints of polymeric plates
  102. Investigation of inlet air pressure and evaporative cooling of four different cogeneration cycles
  103. Review Articles
  104. Comprehensive review on synthesis, physicochemical properties, and application of activated carbon from the Arecaceae plants for enhanced wastewater treatment
  105. Research progress on speciation analysis of arsenic in traditional Chinese medicine
  106. Recent modified air-assisted liquid–liquid microextraction applications for medicines and organic compounds in various samples: A review
  107. An insight on Vietnamese bio-waste materials as activated carbon precursors for multiple applications in environmental protection
  108. Antimicrobial activities of the extracts and secondary metabolites from Clausena genus – A review
  109. Bioremediation of organic/heavy metal contaminants by mixed cultures of microorganisms: A review
  110. Sonodynamic therapy for breast cancer: A literature review
  111. Recent progress of amino acid transporters as a novel antitumor target
  112. Aconitum coreanum Rapaics: Botany, traditional uses, phytochemistry, pharmacology, and toxicology
  113. Corrigendum
  114. Corrigendum to “Petrology and geochemistry of multiphase post-granitic dikes: A case study from the Gabal Serbal area, Southwestern Sinai, Egypt”
  115. Corrigendum to “Design of a Robust sliding mode controller for bioreactor cultures in overflow metabolism via an interdisciplinary approach”
  116. Corrigendum to “Statistical analysis on the radiological assessment and geochemical studies of granite rocks in the north of Um Taghir area, Eastern Desert, Egypt”
  117. Corrigendum to “Aroma components of tobacco powder from different producing areas based on gas chromatography ion mobility spectrometry”
  118. Corrigendum to “Mechanical properties, elastic moduli, transmission factors, and gamma-ray-shielding performances of Bi2O3–P2O5–B2O3–V2O5 quaternary glass system”
  119. Erratum
  120. Erratum to “Copper(ii) complexes supported by modified azo-based ligands: Nucleic acid binding and molecular docking studies”
  121. Special Issue on Applied Biochemistry and Biotechnology (ABB 2021)
  122. Study of solidification and stabilization of heavy metals by passivators in heavy metal-contaminated soil
  123. Human health risk assessment and distribution of VOCs in a chemical site, Weinan, China
  124. Preparation and characterization of Sparassis latifolia β-glucan microcapsules
  125. Special Issue on the Conference of Energy, Fuels, Environment 2020
  126. Improving the thermal performance of existing buildings in light of the requirements of the EU directive 2010/31/EU in Poland
  127. Special Issue on Ethnobotanical, Phytochemical and Biological Investigation of Medicinal Plants
  128. Study of plant resources with ethnomedicinal relevance from district Bagh, Azad Jammu and Kashmir, Pakistan
  129. Studies on the chemical composition of plants used in traditional medicine in Congo
  130. Special Issue on Applied Chemistry in Agriculture and Food Science
  131. Strip spraying technology for precise herbicide application in carrot fields
  132. Special Issue on Pharmacology and Metabolomics of Ethnobotanical and Herbal Medicine
  133. Phytochemical profiling, antibacterial and antioxidant properties of Crocus sativus flower: A comparison between tepals and stigmas
  134. Antioxidant and antimicrobial properties of polyphenolics from Withania adpressa (Coss.) Batt. against selected drug-resistant bacterial strains
  135. Integrating network pharmacology and molecular docking to explore the potential mechanism of Xinguan No. 3 in the treatment of COVID-19
  136. Chemical composition and in vitro and in vivo biological assortment of fixed oil extracted from Ficus benghalensis L.
  137. A review of the pharmacological activities and protective effects of Inonotus obliquus triterpenoids in kidney diseases
  138. Ethnopharmacological study of medicinal plants in Kastamonu province (Türkiye)
  139. Protective effects of asperuloside against cyclophosphamide-induced urotoxicity and hematotoxicity in rats
  140. Special Issue on Essential Oil, Extraction, Phytochemistry, Advances, and Application
  141. Identification of volatile compounds and antioxidant, antibacterial, and antifungal properties against drug-resistant microbes of essential oils from the leaves of Mentha rotundifolia var. apodysa Briq. (Lamiaceae)
  142. Phenolic contents, anticancer, antioxidant, and antimicrobial capacities of MeOH extract from the aerial parts of Trema orientalis plant
  143. Chemical composition and antimicrobial activity of essential oils from Mentha pulegium and Rosmarinus officinalis against multidrug-resistant microbes and their acute toxicity study
  144. Special Issue on Marine Environmental Sciences and Significance of the Multidisciplinary Approaches
  145. An insightful overview of the distribution pattern of polycyclic aromatic hydrocarbon in the marine sediments of the Red Sea
  146. Antifungal–antiproliferative norcycloartane-type triterpenes from the Red Sea green alga Tydemania expeditionis
  147. Solvent effect, dipole moment, and DFT studies of multi donor–acceptor type pyridine derivative
  148. An extensive assessment on the distribution pattern of organic contaminants in the aerosols samples in the Middle East
  149. Special Issue on 4th IC3PE
  150. Energetics of carboxylic acid–pyridine heterosynthon revisited: A computational study of intermolecular hydrogen bond domination on phenylacetic acid–nicotinamide cocrystals
  151. A review: Silver–zinc oxide nanoparticles – organoclay-reinforced chitosan bionanocomposites for food packaging
  152. Green synthesis of magnetic activated carbon from peanut shells functionalized with TiO2 photocatalyst for Batik liquid waste treatment
  153. Coagulation activity of liquid extraction of Leucaena leucocephala and Sesbania grandiflora on the removal of turbidity
  154. Hydrocracking optimization of palm oil over NiMoO4/activated carbon catalyst to produce biogasoline and kerosine
  155. Special Issue on Pharmacology and metabolomics of ethnobotanical and herbal medicine
  156. Cynarin inhibits PDGF-BB-induced proliferation and activation in hepatic stellate cells through PPARγ
  157. Special Issue on The 1st Malaysia International Conference on Nanotechnology & Catalysis (MICNC2021)
  158. Surfactant evaluation for enhanced oil recovery: Phase behavior and interfacial tension
  159. Topical Issue on phytochemicals, biological and toxicological analysis of aromatic medicinal plants
  160. Phytochemical analysis of leaves and stems of Physalis alkekengi L. (Solanaceae)
  161. Phytochemical and pharmacological profiling of Trewia nudiflora Linn. leaf extract deciphers therapeutic potentials against thrombosis, arthritis, helminths, and insects
  162. Pergularia tomentosa coupled with selenium nanoparticles salvaged lead acetate-induced redox imbalance, inflammation, apoptosis, and disruption of neurotransmission in rats’ brain
  163. Protective effect of Allium atroviolaceum-synthesized SeNPs on aluminum-induced brain damage in mice
  164. Mechanism study of Cordyceps sinensis alleviates renal ischemia–reperfusion injury
  165. Plant-derived bisbenzylisoquinoline alkaloid tetrandrine prevents human podocyte injury by regulating the miR-150-5p/NPHS1 axis
  166. Network pharmacology combined with molecular docking to explore the anti-osteoporosis mechanisms of β-ecdysone derived from medicinal plants
  167. Chinese medicinal plant Polygonum cuspidatum ameliorates silicosis via suppressing the Wnt/β-catenin pathway
  168. Special Issue on Advanced Nanomaterials for Energy, Environmental and Biological Applications - Part I
  169. Investigation of improved optical and conductivity properties of poly(methyl methacrylate)–MXenes (PMMA–MXenes) nanocomposite thin films for optoelectronic applications
  170. Special Issue on Applied Biochemistry and Biotechnology (ABB 2022)
  171. Model predictive control for precision irrigation of a Quinoa crop
https://doi.org/10.1515/chem-2022-0215
Keywords for this article
nanocomposites; nanocellulose; polydopamine; adsorption; water treatment; hexavalent chromium ions
Creative Commons
BY 4.0

Articles in the same Issue

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  2. Photocatalytic degradation of Rhodamine B in aqueous phase by bimetallic metal-organic framework M/Fe-MOF (M = Co, Cu, and Mg)
  3. Assessment of using electronic portal imaging device for analysing bolus material utilised in radiation therapy
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  5. Simulation of gamma-ray shielding properties for materials of medical interest
  6. Environmental impact assesment regulation applications and their analysis in Turkey
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  9. Design of a Robust sliding mode controller for bioreactor cultures in overflow metabolism via an interdisciplinary approach
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  11. Bridging chiral de-tert-butylcalix[4]arenes: Optical resolution based on column chromatography and structural characterization
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  13. Comparison of the yield and purity of plasma exosomes extracted by ultracentrifugation, precipitation, and membrane-based approaches
  14. Bioactive triterpenoids from Indonesian medicinal plant Syzygium aqueum
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  19. Statistical analysis on the radiological assessment and geochemical studies of granite rocks in the north of Um Taghir area, Eastern Desert, Egypt
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  42. Quantification of biomarkers and evaluation of antioxidant, anti-inflammatory, and cytotoxicity properties of Dodonaea viscosa grown in Saudi Arabia using HPTLC technique
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  58. Impact of benzimidazole functional groups on the n-doping properties of benzimidazole derivatives
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  61. A focusing study on radioprotective and antioxidant effects of Annona muricata leaf extract in the circulation and liver tissue: Clinical and experimental studies
  62. Clinical comprehensive and experimental assessment of the radioprotective effect of Annona muricata leaf extract to prevent cellular damage in the ileum tissue
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  64. Influence of various class cleaning agents for prosthesis on Co–Cr alloy surface
  65. The synthesis of nanocellulose-based nanocomposites for the effective removal of hexavalent chromium ions from aqueous solution
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  67. Optimized linear regression control of DC motor under various disturbances
  68. Influence of different sample preparation strategies on hypothesis-driven shotgun proteomic analysis of human saliva
  69. Determination of flow distance of the fluid metal due to fluidity in ductile iron casting by artificial neural networks approach
  70. Investigation of mechanical activation effect on high-volume natural pozzolanic cements
  71. In vitro: Anti-coccidia activity of Calotropis procera leaf extract on Eimeria papillata oocysts sporulation and sporozoite
  72. Determination of oil composition of cowpea (Vigna unguiculata L.) seeds under influence of organic fertilizer forms
  73. Activated partial thromboplastin time maybe associated with the prognosis of papillary thyroid carcinoma
  74. Treatment of rat brain ischemia model by NSCs-polymer scaffold transplantation
  75. Lead and cadmium removal with native yeast from coastal wetlands
  76. Characterization of electroless Ni-coated Fe–Co composite using powder metallurgy
  77. Ferrate synthesis using NaOCl and its application for dye removal
  78. Antioxidant, antidiabetic, and anticholinesterase potential of Chenopodium murale L. extracts using in vitro and in vivo approaches
  79. Study on essential oil, antioxidant activity, anti-human prostate cancer effects, and induction of apoptosis by Equisetum arvense
  80. Experimental study on turning machine with permanent magnetic cutting tool
  81. Numerical simulation and mathematical modeling of the casting process for pearlitic spheroidal graphite cast iron
  82. Design, synthesis, and cytotoxicity evaluation of novel thiophene, pyrimidine, pyridazine, and pyridine: Griseofulvin heterocyclic extension derivatives
  83. Isolation and identification of promising antibiotic-producing bacteria
  84. Ultrasonic-induced reversible blood–brain barrier opening: Safety evaluation into the cellular level
  85. Evaluation of phytochemical and antioxidant potential of various extracts from traditionally used medicinal plants of Pakistan
  86. Effect of calcium lactate in standard diet on selected markers of oxidative stress and inflammation in ovariectomized rats
  87. Identification of crucial salivary proteins/genes and pathways involved in pathogenesis of temporomandibular disorders
  88. Zirconium-modified attapulgite was used for removing of Cr(vi) in aqueous solution
  89. The stress distribution of different types of restorative materials in primary molar
  90. Reducing surface heat loss in steam boilers
  91. Deformation behavior and formability of friction stir processed DP600 steel
  92. Synthesis and characterization of bismuth oxide/commercial activated carbon composite for battery anode
  93. Phytochemical analysis of Ziziphus jujube leaf at different foliar ages based on widely targeted metabolomics
  94. Effects of in ovo injection of black cumin (Nigella sativa) extract on hatching performance of broiler eggs
  95. Separation and evaluation of potential antioxidant, analgesic, and anti-inflammatory activities of limonene-rich essential oils from Citrus sinensis (L.)
  96. Bioactivity of a polyhydroxy gorgostane steroid from Xenia umbellata
  97. BiCAM-based automated scoring system for digital logic circuit diagrams
  98. Analysis of standard systems with solar monitoring systems
  99. Structural and spectroscopic properties of voriconazole and fluconazole – Experimental and theoretical studies
  100. New plant resistance inducers based on polyamines
  101. Experimental investigation of single-lap bolted and bolted/bonded (hybrid) joints of polymeric plates
  102. Investigation of inlet air pressure and evaporative cooling of four different cogeneration cycles
  103. Review Articles
  104. Comprehensive review on synthesis, physicochemical properties, and application of activated carbon from the Arecaceae plants for enhanced wastewater treatment
  105. Research progress on speciation analysis of arsenic in traditional Chinese medicine
  106. Recent modified air-assisted liquid–liquid microextraction applications for medicines and organic compounds in various samples: A review
  107. An insight on Vietnamese bio-waste materials as activated carbon precursors for multiple applications in environmental protection
  108. Antimicrobial activities of the extracts and secondary metabolites from Clausena genus – A review
  109. Bioremediation of organic/heavy metal contaminants by mixed cultures of microorganisms: A review
  110. Sonodynamic therapy for breast cancer: A literature review
  111. Recent progress of amino acid transporters as a novel antitumor target
  112. Aconitum coreanum Rapaics: Botany, traditional uses, phytochemistry, pharmacology, and toxicology
  113. Corrigendum
  114. Corrigendum to “Petrology and geochemistry of multiphase post-granitic dikes: A case study from the Gabal Serbal area, Southwestern Sinai, Egypt”
  115. Corrigendum to “Design of a Robust sliding mode controller for bioreactor cultures in overflow metabolism via an interdisciplinary approach”
  116. Corrigendum to “Statistical analysis on the radiological assessment and geochemical studies of granite rocks in the north of Um Taghir area, Eastern Desert, Egypt”
  117. Corrigendum to “Aroma components of tobacco powder from different producing areas based on gas chromatography ion mobility spectrometry”
  118. Corrigendum to “Mechanical properties, elastic moduli, transmission factors, and gamma-ray-shielding performances of Bi2O3–P2O5–B2O3–V2O5 quaternary glass system”
  119. Erratum
  120. Erratum to “Copper(ii) complexes supported by modified azo-based ligands: Nucleic acid binding and molecular docking studies”
  121. Special Issue on Applied Biochemistry and Biotechnology (ABB 2021)
  122. Study of solidification and stabilization of heavy metals by passivators in heavy metal-contaminated soil
  123. Human health risk assessment and distribution of VOCs in a chemical site, Weinan, China
  124. Preparation and characterization of Sparassis latifolia β-glucan microcapsules
  125. Special Issue on the Conference of Energy, Fuels, Environment 2020
  126. Improving the thermal performance of existing buildings in light of the requirements of the EU directive 2010/31/EU in Poland
  127. Special Issue on Ethnobotanical, Phytochemical and Biological Investigation of Medicinal Plants
  128. Study of plant resources with ethnomedicinal relevance from district Bagh, Azad Jammu and Kashmir, Pakistan
  129. Studies on the chemical composition of plants used in traditional medicine in Congo
  130. Special Issue on Applied Chemistry in Agriculture and Food Science
  131. Strip spraying technology for precise herbicide application in carrot fields
  132. Special Issue on Pharmacology and Metabolomics of Ethnobotanical and Herbal Medicine
  133. Phytochemical profiling, antibacterial and antioxidant properties of Crocus sativus flower: A comparison between tepals and stigmas
  134. Antioxidant and antimicrobial properties of polyphenolics from Withania adpressa (Coss.) Batt. against selected drug-resistant bacterial strains
  135. Integrating network pharmacology and molecular docking to explore the potential mechanism of Xinguan No. 3 in the treatment of COVID-19
  136. Chemical composition and in vitro and in vivo biological assortment of fixed oil extracted from Ficus benghalensis L.
  137. A review of the pharmacological activities and protective effects of Inonotus obliquus triterpenoids in kidney diseases
  138. Ethnopharmacological study of medicinal plants in Kastamonu province (Türkiye)
  139. Protective effects of asperuloside against cyclophosphamide-induced urotoxicity and hematotoxicity in rats
  140. Special Issue on Essential Oil, Extraction, Phytochemistry, Advances, and Application
  141. Identification of volatile compounds and antioxidant, antibacterial, and antifungal properties against drug-resistant microbes of essential oils from the leaves of Mentha rotundifolia var. apodysa Briq. (Lamiaceae)
  142. Phenolic contents, anticancer, antioxidant, and antimicrobial capacities of MeOH extract from the aerial parts of Trema orientalis plant
  143. Chemical composition and antimicrobial activity of essential oils from Mentha pulegium and Rosmarinus officinalis against multidrug-resistant microbes and their acute toxicity study
  144. Special Issue on Marine Environmental Sciences and Significance of the Multidisciplinary Approaches
  145. An insightful overview of the distribution pattern of polycyclic aromatic hydrocarbon in the marine sediments of the Red Sea
  146. Antifungal–antiproliferative norcycloartane-type triterpenes from the Red Sea green alga Tydemania expeditionis
  147. Solvent effect, dipole moment, and DFT studies of multi donor–acceptor type pyridine derivative
  148. An extensive assessment on the distribution pattern of organic contaminants in the aerosols samples in the Middle East
  149. Special Issue on 4th IC3PE
  150. Energetics of carboxylic acid–pyridine heterosynthon revisited: A computational study of intermolecular hydrogen bond domination on phenylacetic acid–nicotinamide cocrystals
  151. A review: Silver–zinc oxide nanoparticles – organoclay-reinforced chitosan bionanocomposites for food packaging
  152. Green synthesis of magnetic activated carbon from peanut shells functionalized with TiO2 photocatalyst for Batik liquid waste treatment
  153. Coagulation activity of liquid extraction of Leucaena leucocephala and Sesbania grandiflora on the removal of turbidity
  154. Hydrocracking optimization of palm oil over NiMoO4/activated carbon catalyst to produce biogasoline and kerosine
  155. Special Issue on Pharmacology and metabolomics of ethnobotanical and herbal medicine
  156. Cynarin inhibits PDGF-BB-induced proliferation and activation in hepatic stellate cells through PPARγ
  157. Special Issue on The 1st Malaysia International Conference on Nanotechnology & Catalysis (MICNC2021)
  158. Surfactant evaluation for enhanced oil recovery: Phase behavior and interfacial tension
  159. Topical Issue on phytochemicals, biological and toxicological analysis of aromatic medicinal plants
  160. Phytochemical analysis of leaves and stems of Physalis alkekengi L. (Solanaceae)
  161. Phytochemical and pharmacological profiling of Trewia nudiflora Linn. leaf extract deciphers therapeutic potentials against thrombosis, arthritis, helminths, and insects
  162. Pergularia tomentosa coupled with selenium nanoparticles salvaged lead acetate-induced redox imbalance, inflammation, apoptosis, and disruption of neurotransmission in rats’ brain
  163. Protective effect of Allium atroviolaceum-synthesized SeNPs on aluminum-induced brain damage in mice
  164. Mechanism study of Cordyceps sinensis alleviates renal ischemia–reperfusion injury
  165. Plant-derived bisbenzylisoquinoline alkaloid tetrandrine prevents human podocyte injury by regulating the miR-150-5p/NPHS1 axis
  166. Network pharmacology combined with molecular docking to explore the anti-osteoporosis mechanisms of β-ecdysone derived from medicinal plants
  167. Chinese medicinal plant Polygonum cuspidatum ameliorates silicosis via suppressing the Wnt/β-catenin pathway
  168. Special Issue on Advanced Nanomaterials for Energy, Environmental and Biological Applications - Part I
  169. Investigation of improved optical and conductivity properties of poly(methyl methacrylate)–MXenes (PMMA–MXenes) nanocomposite thin films for optoelectronic applications
  170. Special Issue on Applied Biochemistry and Biotechnology (ABB 2022)
  171. Model predictive control for precision irrigation of a Quinoa crop
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