Startseite Crystal structure of catena-poly[trans-tetraaqua(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-k2N:N′)cobalt(II)] dinitrate – 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) – water (1/3/2), C72H68CoN18O12
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Crystal structure of catena-poly[trans-tetraaqua(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-k2N:N′)cobalt(II)] dinitrate – 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) – water (1/3/2), C72H68CoN18O12

  • Huixing Li ORCID logo EMAIL logo , Xinlong Han und Bin Cao
Veröffentlicht/Copyright: 13. Januar 2021
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 236 Heft 2

Abstract

C72H68CoN18O12, triclinic, P1‾ (no. 2), a = 9.2801(10) Å, b = 11.6017(11) Å, c = 16.4968(15) Å, α = 96.294(8)°, β = 96.371(8)°, γ = 105.025(9)°, V = 1687.0(3) Å3, Z = 1, Rgt(F) = 0.0631, wRref(F2) = 0.1043, T = 293(2) K.

CCDC no.: 2051182

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Purple block
Size:0.25 × 0.23 × 0.20 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.33 mm−1
Diffractometer, scan mode:Bruker APEX-II, φ and ω
θmax, completeness:25.0°, >99%
N(hkl)measured, N(hkl)unique, Rint:11546, 5939, 0.081
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3359
N(param)refined:505
Programs:Bruker [1], SHELX [2]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Co11.0000001.0000000.5000000.0353 (2)
O11.0038 (3)0.8289 (2)0.44874 (16)0.0541 (8)
H1A1.0705 (19)0.7956 (18)0.466 (2)0.081*
H1B0.9293 (18)0.7712 (14)0.4250 (19)0.081*
O21.1532 (3)1.0772 (2)0.42165 (13)0.0459 (7)
H2A1.158 (4)1.0397 (18)0.3752 (8)0.069*
H2B1.163 (4)1.1499 (7)0.4138 (14)0.069*
N10.8093 (3)0.9885 (2)0.41180 (16)0.0358 (7)
N20.6616 (3)0.9836 (2)0.29555 (16)0.0350 (7)
N30.7781 (4)0.2720 (3)0.4883 (2)0.0570 (10)
N40.6408 (4)0.2913 (3)0.3748 (2)0.0481 (9)
N50.3760 (4)0.3408 (3)−0.2191 (2)0.0506 (9)
N60.2387 (4)0.3217 (3)−0.3417 (2)0.0698 (12)
N70.1667 (4)0.3067 (3)0.3836 (2)0.0612 (10)
N80.1175 (3)0.4093 (3)0.28392 (19)0.0450 (8)
C10.8038 (4)0.9973 (3)0.3322 (2)0.0389 (10)
H10.8876891.0111800.3048490.047*
C20.6624 (4)0.9681 (3)0.4258 (2)0.0450 (10)
H20.6301820.9575000.4765240.054*
C30.5711 (4)0.9656 (3)0.3555 (2)0.0497 (11)
H30.4673040.9540030.3491930.060*
C40.6161 (4)0.9879 (3)0.2102 (2)0.0334 (9)
C50.4714 (4)0.9269 (3)0.1737 (2)0.0441 (10)
H50.4040500.8820630.2037980.053*
C60.4277 (4)0.9330 (3)0.0921 (2)0.0478 (11)
H60.3292250.8930420.0682770.057*
C70.5244 (4)0.9962 (3)0.04438 (18)0.0348 (9)
C80.6685 (4)1.0564 (3)0.0828 (2)0.0564 (12)
H80.7365701.1004780.0527230.068*
C90.7140 (4)1.0527 (3)0.1652 (2)0.0542 (12)
H90.8114621.0944680.1897720.065*
C100.6345 (5)0.2678 (4)0.5039 (3)0.0612 (12)
H100.6009400.2587940.5544850.073*
C110.5491 (5)0.2788 (4)0.4344 (3)0.0590 (12)
H110.4479780.2779560.4284530.071*
C120.7769 (4)0.2861 (3)0.4109 (3)0.0542 (11)
H120.8602630.2920130.3834470.065*
C130.6016 (4)0.3016 (3)0.2902 (2)0.0433 (10)
C140.4634 (4)0.2341 (3)0.2476 (3)0.0550 (12)
H140.3954160.1831140.2742120.066*
C150.4269 (4)0.2425 (4)0.1661 (3)0.0579 (12)
H150.3323610.1983850.1386230.069*
C160.5262 (4)0.3146 (3)0.1234 (2)0.0430 (10)
C170.6656 (4)0.3813 (3)0.1673 (2)0.0539 (11)
H170.7353480.4307100.1407840.065*
C180.7010 (4)0.3745 (3)0.2497 (2)0.0524 (11)
H180.7939410.4202200.2782050.063*
C190.4886 (4)0.3222 (3)0.0343 (3)0.0454 (10)
C200.3460 (5)0.2666 (4)−0.0087 (3)0.0613 (12)
H200.2723450.2240950.0190950.074*
C210.3093 (4)0.2721 (4)−0.0913 (3)0.0636 (13)
H210.2127240.232601−0.1182750.076*
C220.4141 (4)0.3354 (3)−0.1338 (2)0.0461 (10)
C230.5564 (4)0.3932 (4)−0.0931 (3)0.0607 (12)
H230.6287510.438122−0.1205280.073*
C240.5901 (4)0.3837 (3)−0.0109 (3)0.0581 (12)
H240.6877280.4213110.0153200.070*
C250.2369 (5)0.3047 (4)−0.2648 (3)0.0675 (14)
H250.1492810.271190−0.2435650.081*
C260.3871 (6)0.3714 (4)−0.3473 (3)0.0792 (15)
H260.4244730.393081−0.3951060.095*
C270.4713 (5)0.3843 (4)−0.2733 (3)0.0766 (15)
H270.5752130.416802−0.2610920.092*
C280.1692 (5)0.4196 (4)0.4179 (3)0.0702 (14)
H280.1880470.4478730.4740740.084*
C290.1398 (5)0.4853 (4)0.3572 (3)0.0636 (13)
H290.1357700.5649450.3639920.076*
C300.1349 (4)0.3041 (4)0.3042 (3)0.0558 (12)
H300.1253480.2366410.2657190.067*
C310.0848 (4)0.4368 (3)0.2028 (2)0.0438 (10)
C320.0821 (4)0.5500 (3)0.1893 (2)0.0515 (11)
H320.1033780.6113640.2338030.062*
C330.0486 (4)0.5747 (3)0.1112 (2)0.0512 (11)
H330.0460780.6525780.1039570.061*
C340.0180 (4)0.4864 (3)0.0423 (2)0.0418 (10)
C350.0209 (4)0.3720 (3)0.0576 (2)0.0537 (11)
H35−0.0000310.3102920.0133620.064*
C360.0534 (4)0.3462 (3)0.1357 (3)0.0562 (12)
H360.0544750.2683100.1436280.067*
O30.0674 (4)0.8692 (4)0.1503 (3)0.1113 (15)
O40.1134 (5)1.0287 (4)0.2370 (3)0.1302 (19)
O5Aa0.0664 (13)1.0425 (10)0.1122 (7)0.113 (4)
N9a0.0805 (10)0.9815 (12)0.1664 (9)0.083 (3)
O1WAa0.1943 (11)0.8175 (8)0.3102 (6)0.107 (3)
H1WAa0.1461020.8397480.3471100.161*
H1WBa0.1503630.8214270.2629400.161*
O5Ba0.1640 (15)0.8836 (13)0.2780 (8)0.161 (6)
N9Ba0.1127 (11)0.9224 (11)0.2226 (8)0.086 (3)
O1WBa0.0484 (14)1.0747 (9)0.0584 (6)0.118 (4)
H1WCa0.0032601.0465260.0097720.177*
H1WDa0.1112601.0356760.0715620.177*

  1. a Occupancy: 0.5

Source of material

All chemicals and solvents were of analytical grade and used without further purification. The title compound was prepared by the hydrothermal method. A mixture of Co(NO3)2⋅6H2O (1 mmol, 0.291 g), 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) (bibp) (1 mmol, 0.288 g), dimethylformamide (6 ml) and H2O (2 ml) were placed in a 25 mL Teflon-lined autoclave at 413 K for 72 h, then cooled to room temperature. Purple block crystals were obtained.

Experimental details

H atoms bound to C atoms were placed in calculated positions and refined as riding on their parent atoms, with C–H = 0.93 Å and with Uiso(H) = 1.2 Ueq(C). The O-bound H atoms were located in a difference Fourier map and refined with a distance restraint of O–H = 0.85 Å, and with Uiso(H) set to 1.5 Ueq(O). The uncoordinated water molecules and the nitrate anions are disordered over two postions in this structure.

Comment

Imidazole is a versatile N-donor organic ligand in construction of coordination polymers because of the potential coordination sites [3], [4], [5]. As a imidazole derivative, 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) (bibp) was widely used to synthesise coordination polymers due to different coordination modes of the bibp ligand [6], [7], [8], [9], [10], [11].

The asymmetric unit of the crystal structure consists of half of a Co(II) center located on a crystallographic inversion center, one half of a bibp ligand, two coordinated water molecules, one and a half free bibp ligands (see the Figure). The nitrate counter anion and one more uncoordinated water molecule are both disordered and not shown in the Figure. The Co(II) ion is six-coordinated by four O atoms from two pairs of symmetry related water molecules (Co–O = 2.081(2)–2.120(2) Å), and two N atoms from two symmetry related bibp ligands (Co–N = 2.129(3) Å), forming a distorted octahedral geometry. The coordinated bibp ligands link adjacent Co(II) ions into a polymeric chain structure with the Co–Co distance of 18.008 Å along the c axis. In the crystal structure, O–H…O and O–H…N hydrogen bonds link molecules and ions into a three-dimensional supermolecular framework.

Corresponding author: Huixing Li, Henan Key Laboratory of Industrial Microbial Resources and Fermentation Technology, Nanyang Institute of Technology, 473004, Nanyang, Henan, People’s Republic of China; and School of Biological and Chemical Engineering, Nanyang Institute of Technology, 473004, Nanyang, Henan, People’s Republic of China, E-mail:

Funding source: Natural Science Foundation of Henan Province of China

Award Identifier / Grant number: 182300410151

Funding source: Scientific and Technological Project of Henan Province

Award Identifier / Grant number: 162102210114

Funding source: Key Scientific Research Project of College and University in Henan Province

Award Identifier / Grant number: 17A610003

Funding source: Henan Key Laboratory of Industrial Microbial Resources and Fermentation Technology Open Project

Award Identifier / Grant number: HIMFT20200206

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: Natural Science Foundation of Henan Province of China (182300410151), Scientific and Technological Project of Henan Province (162102210114), Key Scientific Research Project of College and University in Henan Province (17A610003) and Henan Key Laboratory of Industrial Microbial Resources and Fermentation Technology Open Project (HIMFT20200206).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. APEX2, SAINT and SADABS; Bruker AXS Inc.: Madison, Wisconsin, USA, 2008.Suche in Google Scholar

2. Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Suche in Google Scholar PubMed

3. Sun, Y., Chen, Y., Wang, D. Crystal structure of poly[bis(μ3-(1-(3,5- di(1H-imidazol-1-yl)phenyl)-1H-imidazole-κ3N:N′:N′′)cobalt(II)] dinitrate – N,N- dimethylformamide (1/4), C42H52N18O10Co. Z. Kristallogr. NCS 2020, 235, 1303–1305; https://doi.org/10.1515/ncrs-2020-0285.Suche in Google Scholar

4. Li, T., Xing, Z. Crystal structure of hexa-μ2-chlorido-μ4- oxidotetrakis (1-vinyl-1H-imidazole-κN) tetracopper(II), C20H24Cu4Cl6N8O. Z. Kristallogr. NCS 2019, 234, 363–365; https://doi.org/10.1515/ncrs-2018-0421.Suche in Google Scholar

5. Çetinkaya, F., Kürkçüoğlu, G. S., Yeşilel, O. Z., Hökelek, T., Dal, H. One-dimensional cyano-bridged heterometallic (Cu/Ni and Cu/Pd) complexes with 1-ethylimidazole. Polyhedron 2012, 47, 126–133; https://doi.org/10.1016/j.poly.2012.08.041.Suche in Google Scholar

6. Hu, Q., Zheng, Q.-M., Ma, X.-R., Lai, Z.-Z., Ye, T.-Q., Qin, L. One luminescence probe and the impact of dye-adsorption on the luminescent property. Polyhedron 2020, 177, 114323; https://doi.org/10.1016/j.poly.2019.114323.Suche in Google Scholar

7. Voda, I., Makhloufi, G., Druta, V., Lozan, V., Shova, S., Bourosh, P., Kravtsov, V., Janiak, C. Mixed-ligand coordination compounds based on the rigid 4,4′-bis(1-imidazolyl)biphenyl and pyridinedicarboxylate ligands. Inorg. Chim. Acta. 2018, 482, 526–534; https://doi.org/10.1016/j.ica.2018.06.038.Suche in Google Scholar

8. Li, Z.-X., Gou, X.-F., Jie, W., Zha, G., Wang, T., Xu, Y. One pillared- layer α–Po framework with a rare tetracobalt-formate (4, 4) sheet exhibiting a field-induced magnetic transition. Inorg. Chem. Commun. 2014, 41, 58–61; https://doi.org/10.1016/j.inoche.2013.12.019.Suche in Google Scholar

9. Zhang, W., Hao, L. Coordination polymers (NiII and CoII) based on the rigid bridging ligand, 4,4′-bis(imidazol-1-yl)biphenyl, with (46) topology. J. Coord. Chem. 2013, 66, 2100–2117; https://doi.org/10.1080/00958972.2013.798653.Suche in Google Scholar

10. Zhang, C.-L., Qin, L., Zheng, H.-G. Synthesis, characterization and crystal structure of one Co(II) complex with 4,4′-bisimidazolylbiphenyl and m-phthalic acid. Inorg. Chem. Commun. 2013, 36, 192–194; https://doi.org/10.1016/j.inoche.2013.09.014.Suche in Google Scholar

11. Li, Z.-X., Zhao, J.-P., Sañudo, E. C., Ma, H., Pan, Z.-D., Zeng, Y.-F., Bu, X.-H. New 3D coordination polymers constructed from pillared metal- formate Kagomĺayers exhibiting spin canting only in the nickel(II) complex. Inorg. Chem. 2009, 48, 11601–11607; https://doi.org/10.1021/ic901564y.Suche in Google Scholar PubMed

Received: 2020-11-04
Accepted: 2020-12-18
Published Online: 2021-01-13
Published in Print: 2021-03-26

© 2020 Huixing Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

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  2. New Crystal Structures
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  55. Synthesis and crystal structure of oktakis(dimethylsulphoxide-κ1O)gadolinium(III) [tetrabromido-μ2-bromido-μ2-sulfido-di-μ3-sulfido-μ4-sulfido-tetracopper(I)-tungsten(VI)], C16H48O8S12Br5Cu4GdW
  56. Crystal structure of {tris((1H-benzo[d]imidazol-2- yl)methyl)amine-κ4N,N′,N′′,N′′′}-(succinato-κ2O,O′)nickel(II) – methanol (1/4), C32H41N7NiO8
  57. Crystal structure of catena-poly[trans-tetraaqua(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-k2N:N′)cobalt(II)] dinitrate – 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) – water (1/3/2), C72H68CoN18O12
  58. Crystal structure of bis(μ2-2-oxido-2-phenylacetate-κ3O:O,O′)-bis(1-isopropoxy-2-oxo-2-phenylethan-1-olato-κ2O,O′)-bis(propan-2-olato-κ1O)dititanium(IV), C44H52O14Ti2
  59. The crystal structure of 5-carboxy-2-(hydroxymethyl)-1H-imidazol-3-ium-4-carboxylate, C6H8N2O6
  60. The crystal structure of 2,6-dibromo-4-fluoroaniline, C6H4Br2FN
  61. The crystal structure of 4-chloro-N-(2-phenoxyphenyl)benzamide, C19H14ClNO2
  62. The crystal structure of 2-methyl-β-naphthothiazole, C12H9NS
https://doi.org/10.1515/ncrs-2020-0572
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of 4-hydroxybenzene-1,3-diaminium dichloride, C6H10Cl2N2O
  4. The crystal structure of 3-chloropropylammonium chloride, C3H9Cl2N
  5. The crystal structure of 1-chloro-2-(dimethylamino)ethane hydrochloride, C4H11Cl2N
  6. Crystal structure of N-(2-(trifluoromethyl)phenyl)hexanamide, C13H16F3NO
  7. Redetermination of the crystal structure of para-toluidine, C7H9N 
  8. The crystal structure of bis(1,3-dihydroxy-2-methylpropan-2-aminium) carbonate, C9H24N2O7
  9. The crystal structure of 4-chloro-1-methylpiperidin-1-ium chloride, C6H13Cl2N
  10. Crystal structure of (Z)-3-(6-bromo-1H-indol-3-yl)-1,3-diphenylprop-2-en-1-one, C23H16BrNO
  11. The crystal structure of ethyl 2-amino-4-(3,5-difluorophenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H21F2NO4
  12. Crystal structure of 6,6'‐((1E,1'E)‐(propane‐1,3‐diylbis(azaneylylidene))bis(methaneylylidene))bis(3‐bromophenol), C34H32Br4N4O4
  13. The crystal structure of (E)-2-(2-((2-picolinoylhydrazono)methyl)phenoxy)acetic acid dihydrate, C15H17N3O6
  14. Crystal structure of (E)-4-bromo-N′-(3-chloro-2-hydroxybenzylidene)benzohydrazide, C14H10BrClN2O2
  15. Crystal structure of N,N′-bis(4-bromosalicylidene) ethylene-1,2-diaminopropan, C34H32Br4N4O4
  16. Crystal structure of 4-bromo-N′-[(3-bromo-2-hydroxyphenyl)methylidene]benzohydrazide methanol solvate, C15H14Br2N2O3
  17. The crystal structure of 1,2-bis(1H-benzo[d]imidazol-2-yl)ethane-1,2-diol — N-(2-aminophenyl)-3-(1H-benzo[d]imidazol-2-yl)-2,3-dihydroxypropanamide (1/1), C32H30N8O5
  18. The crystal structure of para-trifluoromethyl-aniline hemihydrate, C14H14F6N2O
  19. Redetermination of the crystal structure of 2-amino-2-methyl-propane-1,3-diole, C4H11NO2
  20. The crystal structure of methacholine chloride, C8H18ClNO2
  21. Crystal structure of 5,7,7-trimethyl-4,6,7,8-tetrahydrocyclopenta[g]isochromen-1(3H)-one, C15H18O2
  22. Crystal structure of poly[diammine-bis(μ4-4-hydroxypyridine-3-sulfonato-κ5N:O, O′:O′′:O′′)(μ2-pyrazinyl-κ2N:N′)tetrasilver(I)], C7H8Ag2N3O4S
  23. Crystal structure of ethyl (E)-5-(((3′,6′-bis(ethylamino)-3-oxospiro[isoindoline-1,9′-xanthen]-2-yl)imino)methyl)-2,4-dimethyl-1H-pyrrole-3-carboxylate — ethanol (1/1), C38H45N5O5
  24. Crystal structure of 4-bromo-N′-[(3-chloro-2-hydroxyphenyl)methylidene]benzohydrazide, C14H7Br2N2O2
  25. Redetermination of the crystal structure of 3,3,3-triphenylpropanoic acid, C21H18O2 – Deposition of hydrogen atomic coordinates
  26. Structure redetermination of dextromethorphan hydrobromide monohydrate, C18H28BrNO2 – localization of hydrogen atoms
  27. Crystal structure of tris(azido-κ1N)-(N-(2-aminoethyl)-N-methyl-1,3-propanediamine-κ3N,N′,N′′)cobalt(III), C7H19CoN12
  28. Crystal structure of tetraaqua-bis(1H-indazole-6-carboxylate-κN)cadmium (II), C16H18CdN4O8
  29. Crystal structure of dichloride-bis(1-propylimidazole-κ1N)zinc(II), C12H20Cl2N4Zn
  30. Crystal structure of (E)-resveratrol 3-O-β-D-xylopyranoside, C19H22O8
  31. Crystal structure of 3,3′-(1,2-phenylene-bis(methylene))bis(1-vinyl- 1H-imidazol-3-ium) bis(hexafluoro phosphate)(V), C18H20F12N4P2
  32. Crystal structure of diaqua[bis(benzimidazol-2-yl-methyl)amine-κ3N,N′,N″]-phthalato-κ1O-nickel(II)-methanol (1/2), C26H31N5NiO8
  33. Crystal structure of 6,7-difluoro-1-methyl-3-(trifluoromethyl)quinoxalin-2(1H)-one, C10H5F5N2O
  34. Crystal structure of dichlorido-bis(1-hexyl-1H-benzotriazole-k1N)zinc(II), C24H34N6Cl2Zn
  35. The crystal structre of 2-(4-bromophenyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine, C16H12BBrN2
  36. Crystal structure of diethyl 3,9-bis(4-fluorophenyl)-6,12-diphenyl-3,9-diazapentacyclo[6.4.0.02,7.04,11]dodecane-1,5-dicarboxylate, C40H36F2N2O4
  37. Crystal structure of (E)-7-methoxy-2-((5-methoxypyridin-3-yl)methylene)-3,4- dihydronaphthalen-1(2H)-one, C18H17NO3
  38. Crystal structure of (E)-2-chloro-6-(((1,3-dihydroxy-2-(oxidomethyl)propan-2-yl)imino)methyl)phenolate-κ3N,O,O’)manganese(IV), C22H24Cl2MnN2O8
  39. The crystal structure of α-(meta-methoxyphenoxy)-ortho-tolylic acid, C15H14O4
  40. The crystal structure of N-(2-chloroethyl)-N,N-diethylammonium chloride, C6H15Cl2N
  41. The crystal structure of tris(2,3,4,6,7,8,9,10-octahydro-1H-pyrimido[1,2-a]azepin-5-ium) trihydrodecavanadate(V), C27H54N6O28V10
  42. Crystal structure of 1,3-bis(octyl)benzimidazolium perchlorate C23H39ClN2O4
  43. Crystal structure of tetrakis[(Z)-(2-(1-(furan-2-yl)-2-methylpropylidene)-1-phenylhydrazin-1-ido-κ2N,N′)] zirconium(IV), C56H60N8O4Zr
  44. The crystal structure of 2-(naphthalen-2-yloxy)-4-phenyl-6-(prop-2-yn-1-yloxy)-1,3,5-triazine, C22H15N3O2
  45. The crystal structure of trimethylsulfonium tris(trifluoromethylsulfonyl)methanide, C7H9F9O6S4
  46. Crystal structure of 4-bromo-N′-[3,5-dichloro-2-hydroxyphenyl)methylidene]benzohydrazide methanol solvate, C15H13BrCl2N2O3
  47. The crystal structure of 4-(4-bromophenyl)-2-(3-(4-bromophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)thiazole, C24H16Br2FN3S
  48. The crystal structure of N-(adamantan-1-yl)-piperidine-1-carbothioamide, C16H26N2S
  49. The crystal structure of 1-phenyl-N-(4,5,6,7-tetrabromo-1,3-dioxoisoindolin-2-yl)-5-(thiophen-2-yl)-1H-pyrazole-3-carboxamide-dimethylformamide (1/1) C22H10Br4N4O3S
  50. The crystal structure of benzeneseleninic acid anhydride, C12H10O3Se2
  51. The crystal structure of diphenyalmine hydrochloride antimony trichloride co-crystallizate, C12H12Cl4NSb – Localization of hydrogen atoms
  52. The crystal structure of para-nitrobenzylbromide, C7H6BrNO2 – A second polymorph and correction of 3D coordinates
  53. Crystal structure of catena-poly[(5H-pyrrolo[3,2-b:4,5-b′]dipyridine-κ2N,N′)-(μ4-hexaoxidodivanadato)dizinc(II)],C10H9N3O6V2Zn
  54. Crystal structure of N,N′-(2-hydroxypropane-1,3-diyl)bis(pyridine-2-aldimine)-κ5N,N′,N′′,N′′′,O]-tris(nitrato-κ2O,O′) cerium(III), C15H16CeN7O10
  55. Synthesis and crystal structure of oktakis(dimethylsulphoxide-κ1O)gadolinium(III) [tetrabromido-μ2-bromido-μ2-sulfido-di-μ3-sulfido-μ4-sulfido-tetracopper(I)-tungsten(VI)], C16H48O8S12Br5Cu4GdW
  56. Crystal structure of {tris((1H-benzo[d]imidazol-2- yl)methyl)amine-κ4N,N′,N′′,N′′′}-(succinato-κ2O,O′)nickel(II) – methanol (1/4), C32H41N7NiO8
  57. Crystal structure of catena-poly[trans-tetraaqua(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-k2N:N′)cobalt(II)] dinitrate – 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) – water (1/3/2), C72H68CoN18O12
  58. Crystal structure of bis(μ2-2-oxido-2-phenylacetate-κ3O:O,O′)-bis(1-isopropoxy-2-oxo-2-phenylethan-1-olato-κ2O,O′)-bis(propan-2-olato-κ1O)dititanium(IV), C44H52O14Ti2
  59. The crystal structure of 5-carboxy-2-(hydroxymethyl)-1H-imidazol-3-ium-4-carboxylate, C6H8N2O6
  60. The crystal structure of 2,6-dibromo-4-fluoroaniline, C6H4Br2FN
  61. The crystal structure of 4-chloro-N-(2-phenoxyphenyl)benzamide, C19H14ClNO2
  62. The crystal structure of 2-methyl-β-naphthothiazole, C12H9NS
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Heruntergeladen am 6.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2020-0572/html
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