Home Crystal structure of 3,3′-(1,2-phenylene-bis(methylene))bis(1-vinyl- 1H-imidazol-3-ium) bis(hexafluoro phosphate)(V), C18H20F12N4P2
Article Open Access

Crystal structure of 3,3′-(1,2-phenylene-bis(methylene))bis(1-vinyl- 1H-imidazol-3-ium) bis(hexafluoro phosphate)(V), C18H20F12N4P2

  • Huang Ting , Chen Jin-Zhu , Nie Xu-Liang , Chen Jing and Xiong Wan-Ming EMAIL logo
Published/Copyright: December 10, 2020
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 236 Issue 2

Abstract

C18H20F12N4P2, monoclinic, P21/n (no. 14), a = 8.3185(9) Å, b = 21.883(2) Å, c = 13.4345(15) Å, β = 103.4730(10)°, V = 2378.3(5) Å3, Z = 4, Rgt(F) = 0.0470, wRref(F2) = 0.1305, T = 296(2) K.

CCDC no.: 2046771

The asymmetric unit of the title crystal structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Colorless block
Size:0.20 × 0.15 × 0.13 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.29 mm−1
Diffractometer, scan mode:Bruker APEX-II, φ and ω
θmax, completeness:25.5°, >99%
N(hkl)measured, N(hkl)unique, Rint:18161, 4415, 0.034
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3052
N(param)refined:455
Programs:Bruker [1], SHELX [2], [3], Diamond [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
C10.4763 (5)1.18599 (15)0.7142 (3)0.0979 (11)
H1A0.53961.17830.77970.118*
H1B0.46581.22570.68880.118*
C20.4047 (4)1.14248 (14)0.6595 (3)0.0761 (8)
H20.34241.15170.59430.091*
C30.3557 (3)1.03284 (13)0.63230 (19)0.0590 (7)
H30.30901.03470.56240.071*
C40.4709 (3)1.05921 (12)0.78921 (19)0.0592 (6)
H40.51771.08270.84630.071*
C50.4476 (3)0.99907 (12)0.78741 (18)0.0582 (6)
H50.47530.97270.84310.070*
C60.3380 (3)0.92022 (11)0.6526 (2)0.0582 (6)
H6A0.26060.92120.58640.070*
H6B0.28530.89900.69990.070*
C70.4908 (3)0.88509 (11)0.64350 (17)0.0508 (6)
C80.6405 (3)0.91448 (12)0.64981 (19)0.0579 (6)
H80.64690.95650.65990.069*
C90.7798 (3)0.88285 (13)0.6414 (2)0.0651 (7)
H90.87900.90340.64590.078*
C100.7716 (4)0.82093 (13)0.6266 (2)0.0708 (8)
H100.86510.79910.62120.085*
C110.6235 (4)0.79127 (12)0.6197 (2)0.0693 (8)
H110.61810.74920.60960.083*
C120.4829 (3)0.82245 (12)0.62748 (19)0.0582 (6)
C130.3210 (4)0.78849 (13)0.6203 (3)0.0797 (9)
H13A0.31390.77550.68820.096*
H13B0.22930.81590.59400.096*
C140.3294 (3)0.67763 (13)0.5819 (2)0.0663 (7)
H140.35280.66360.64910.080*
C150.2761 (4)0.73690 (13)0.4491 (2)0.0693 (7)
H150.25610.77170.40830.083*
C160.2795 (4)0.67949 (15)0.4170 (2)0.0733 (8)
H160.26210.66680.34930.088*
C17a0.3244 (6)0.5773 (2)0.5097 (4)0.0722 (14)
H17a0.32660.55960.57300.087*
C18a0.3318 (6)0.5427 (3)0.4348 (4)0.0873 (18)
H18Aa0.32980.55960.37100.105*
H18Ba0.33930.50060.44380.105*
C19b0.332 (3)0.5859 (7)0.4476 (18)0.080 (7)
H19b0.35950.58210.38470.096*
C20b0.304 (3)0.5424 (10)0.5032 (18)0.086 (7)
H20Ab0.27680.55070.56520.103*
H20Bb0.31010.50220.48210.103*
N10.4133 (2)1.08000 (9)0.69139 (15)0.0544 (5)
N20.3753 (2)0.98288 (9)0.68843 (14)0.0525 (5)
N30.3077 (3)0.73505 (9)0.55351 (16)0.0579 (5)
N40.3127 (3)0.64320 (9)0.50010 (19)0.0631 (6)
P10.90678 (9)0.08208 (4)0.65747 (6)0.0633 (2)
P20.29913 (10)0.84651 (4)0.94041 (6)0.0691 (3)
F1c0.3022 (16)0.9144 (3)0.9527 (8)0.126 (4)
F2d0.8909 (9)0.1495 (3)0.7115 (4)0.126 (2)
F3d0.9184 (10)0.0265 (3)0.5948 (4)0.142 (3)
F4d0.8313 (10)0.0582 (5)0.7422 (7)0.125 (3)
F5d0.7291 (6)0.0986 (5)0.5879 (3)0.129 (3)
F6d1.0827 (7)0.0783 (4)0.7256 (5)0.110 (3)
F7c0.1848 (13)0.8394 (6)1.0094 (10)0.133 (4)
F8c0.4255 (12)0.8549 (6)0.8650 (9)0.105 (4)
F9e0.1752 (16)0.7940 (5)0.9278 (6)0.177 (4)
F10e0.4209 (12)0.9020 (4)0.9698 (4)0.138 (3)
F11e0.4231 (15)0.8107 (6)1.0214 (8)0.148 (5)
F12e0.1753 (9)0.8905 (5)0.8669 (5)0.130 (3)
F13c0.4560 (14)0.8351 (7)1.0257 (6)0.114 (5)
F14e0.2214 (10)0.8689 (4)1.0347 (5)0.120 (3)
F15c0.1509 (10)0.8481 (6)0.8427 (7)0.135 (3)
F16e0.3736 (14)0.8291 (6)0.8540 (7)0.151 (5)
F17c0.3058 (18)0.7761 (3)0.9201 (9)0.155 (4)
F18d0.9838 (10)0.1046 (5)0.5689 (6)0.150 (3)
F19f0.9702 (17)0.0133 (5)0.6425 (13)0.145 (4)
F20f0.8443 (14)0.1289 (7)0.7000 (16)0.240 (10)
F21f0.7385 (11)0.0552 (5)0.5951 (6)0.102 (3)
F22f0.928 (2)0.1246 (5)0.5722 (11)0.136 (6)
F23f1.0792 (16)0.0972 (8)0.7206 (12)0.155 (7)
F24f0.875 (2)0.0354 (9)0.7402 (13)0.161 (7)

  1. aOccupancy: 0.810 (10), bOccupancy: 0.190 (10), cOccupancy: 0.436 (12), dOccupancy: 0.640 (10), eOccupancy: 0.564 (12), fOccupancy: 0.360 (10).

Source of material

To a stirred solution of l-vinylimidazole (1.88 g, 0.02 mol) in toluene (25 mL) at 105 °C was added dropwise 1,2-bis(bromomethyl)benzene (2.64 g, 0.01 mol). The mixture was vigorously stirred at 105 °C for about 16–18 h, and then allowed to stand at room temperature for about 3 h. After the reaction has been completed (monitored by TLC), the toluene top phase was decanted and the product was washed with ethyl acetate and diethyl ether 3 times respectively. Then residual solvent was removed, and the product was dried in vacuum at 60 °C for 1 h to give a white powder solid in 97.57% yield. The intermediate compound (1.13 g, 0.0025 mol) and KPF6 (0.92 g, 0.005 mol) were dissolved in distilled water (25 mL). The mixture stirred for 6–8 h at 95 °C and then cooled slowly. The crystals of the target compound were obtained in 93.47% yield.

Experimental details

All H atoms were included in calculated positions and refined as riding atoms, with C-H = 0.90–0.97 Å with Uiso(H) = 1.5 Ueq(C) for methyl H atoms and 1.2 Ueq(C) for all other H atoms.

Comment

Ionic liquids generally refer to a class of low-melting salt composed of adjustable organic cations and inorganic or organic anions, and have different functions [5]. They have high chemical stability and thermodynamic stability, and have been widely applied in many fields [6], [7], [8], [9]. A series of new ionic liquids have thermal response characteristics in organic solvents or water. They provide new ideas for recycling catalysts and avoiding their leaching from solvents [10], [11]. The novel ionic liquid as catalysts can realize the catalytic process of thermally regulated phase separation catalysis, and have the characteristics of homogeneous reaction at high temperature and phase separation at low temperature [12]. Our group is still continuously synthesizing such ionic liquids in order to find a temperature-controllable ionic liquid with better catalytic performance and recovery efficiency [13], [14], [15], [16]. Based on previous research, our team is committed to synthesizing new temperature-adjusting ionic liquids by adjusting the different compositions of anions and cations; and further studying the thermal stability of such ionic liquids in water or toluene.

In the molecule of the title compound bond lengths and angles are very similar to those given in the literature [16]. The atoms of imidazole ring are coplanar, and the dihedral angle between the two imidazole rings and the phenyl group are 18.3(2)°, 81.0(2)° and 87.6(2)°, respectively. The torsion angles of C1-C2-N1-C3, C7-C6-N2-C3, C12-C13-N3-C14 and C18-C17-N4-C14 are −171.6(6), 100.9(5), 103.0(5) and −160.8(7)°, respectively.

Corresponding author: Xiong Wan-Ming, Knowledge Innovation Team of Organic Functional Materials and Agricultural Application of Nanchang City, College of Sciences, Jiangxi Agricultural University, Nanchang, 330045, People’s Republic of China, E-mail:

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 31760193

Funding source: Project of Science and Technology Department of Jiangxi Province

Award Identifier / Grant number: 20202BABL205003

Award Identifier / Grant number: 20192ACB60011

Funding source: The Key Research Foundation of Educational Department of Jiangxi Province of China

Award Identifier / Grant number: GJJ190181

Acknowledgements

X-ray data were collected at Instrumental Analysis Center Nanchang Hangkong University, Nanchang, 330063, People’s Republic of China.

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: National Natural Science Foundation of China (No. 31760193), Project of Science and Technology Department of Jiangxi Province (20192ACB60011 and 20202BABL205003), and the Key Research Foundation of Educational Department of Jiangxi Province of China (GJJ190181).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. APEX2, SAINT and SADABS; Bruker AXS Inc.: Madison, Wisconsin, USA, 2009.Search in Google Scholar

2. Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Search in Google Scholar

3. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

4. Brandenburg, K. DIAMOND. Visual Crystal Structure Information System. Ver. 4.0; Crystal Impact: Bonn, Germany, 2015.Search in Google Scholar

5. Dong, K., Liu, X. M., Dong, H. F., Zhang, X. P., Zhang, S. J. Multiscale studies on ionic liquids. Chem. Rev. 2017, 117, 6636–6695; https://doi.org/10.1021/acs.chemrev.6b00776.Search in Google Scholar

6. Rafiee, E., Eavani, S. A new organic-inorganic hybrid ionic liquid polyoxometalate for biodiesel production. J. Mol. Liq. 2014, 199, 96–101; https://doi.org/10.1016/j.molliq.2014.08.034.Search in Google Scholar

7. Wang, H., Zhao, Y. F., Wu, Y. Y., Li, R. P., Zhang, H. Y., Yu, B., Zhang, F. T., Xiang, J. F., Wang, Z. P., Liu, Z. M. Hydrogenation of carbon dioxide to C2-C4 hydrocarbons catalyzed by Pd(PtBu3)2-FeCl2 with ionic liquid as cocatalyst. Chemsuschem 2019, 19, 4390–4394; https://doi.org/10.1002/cssc.201901820.Search in Google Scholar

8. Richardson, P. M., Voice, A. M., Ward, I. M. Pulsed field gradient NMR self diffusion and ionic conductivity measurements for liquid electrolytes containing LiBF4 and propylene carbonate. Electrochim. Acta 2014, 130, 606–618; https://doi.org/10.1016/j.electacta.2014.03.072.Search in Google Scholar

9. Kohantorabi, M., Giannakis, S., Gholami, M. R. Supported PtxPd1−x bimetallic nanoparticles on ionic liquid-functionalized SiO2@graphene oxide nanocomposite and its application as an effective multiphasic catalyst. Appl. Catal., A 2019, 579, 30–43; https://doi.org/10.1016/j.apcata.2019.04.015.Search in Google Scholar

10. Peng, L. C., Pu, L. X., Hou, Z. B. Synthesis of a novel temperature-sensitive ionic liquid and its catalytic activity for the esterification of long-chain fatty acids. Chin. J. Synth. Chem. 2016, 24, 63–66.Search in Google Scholar

11. Wang, H., Li, B. Direct electrodeposition of aluminum nanowires from a room temperature ionic liquid: an electrochemical 2D-3D-1D process. J. Electrochem. Soc. 2018, 165, D641–D646. https://doi.org/10.1149/2.0991813jes.Search in Google Scholar

12. Kang, Y., Liao, S., Zhao, W., Xiong, W. M., Nie, X. L. Synthesis and crystal structure characterization of temperature- controlled biimidazole ionic liquid. Chin. J. Chem. Res. Appl. 2019, 31, 2136–2140.Search in Google Scholar

13. Kong, J. H., Lan, Y. D., Chen, J., Huang, C. G., Xiong, W. M. Preparation and component analysis of biodiesel catalyzed by functionalized dication ionic liquid. Acta Agric. Univ. Jiangxiensis 2016, 38, 386–390.Search in Google Scholar

14. Xiong, W. M., Zhou, L., Lv, S. M., Nie, X. L., Chen, J., Huang, C. G. Crystal structure of 1,1′-(pentane-1,5-diyl) bis(3-methyl-1H-imidazol-3-ium) bis(hexafluoro phosphate), C9H14F12N4P2. Z. Kristallogr. NCS 2018, 233, 473–474.Search in Google Scholar

15. Huang, T., Nie, X. L., Chen, J., Zhao, W., Xiong, W. M. Crystal structure of 3-(2-ethoxy-2-oxoethyl)-1-methyl-1H-imidazol-3-ium hexafluoridophosphate(V), C8H13F6N2O2P. Z. Kristallogr. NCS 2019, 234, 1077–1079.10.1515/ncrs-2019-0273Search in Google Scholar

16. Zhou, Y. H., Huang, T., Nie, X. L., Chen, J., Xiong, W. M. Crystal structure of 3,3′-(1,2-phenylenebis(methylene))bis(1-methyl-1H- imidazol-3-ium) bis(hexafluoridophosphate), C16H20F12N4P2. Z. Kristallogr. NCS 2020, 235, 1217–1219; https://doi.org/10.1515/ncrs-2020-0268.Search in Google Scholar

Received: 2020-10-30
Accepted: 2020-11-27
Published Online: 2020-12-10
Published in Print: 2021-03-26

© 2020 Huang Ting et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of 4-hydroxybenzene-1,3-diaminium dichloride, C6H10Cl2N2O
  4. The crystal structure of 3-chloropropylammonium chloride, C3H9Cl2N
  5. The crystal structure of 1-chloro-2-(dimethylamino)ethane hydrochloride, C4H11Cl2N
  6. Crystal structure of N-(2-(trifluoromethyl)phenyl)hexanamide, C13H16F3NO
  7. Redetermination of the crystal structure of para-toluidine, C7H9N 
  8. The crystal structure of bis(1,3-dihydroxy-2-methylpropan-2-aminium) carbonate, C9H24N2O7
  9. The crystal structure of 4-chloro-1-methylpiperidin-1-ium chloride, C6H13Cl2N
  10. Crystal structure of (Z)-3-(6-bromo-1H-indol-3-yl)-1,3-diphenylprop-2-en-1-one, C23H16BrNO
  11. The crystal structure of ethyl 2-amino-4-(3,5-difluorophenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H21F2NO4
  12. Crystal structure of 6,6'‐((1E,1'E)‐(propane‐1,3‐diylbis(azaneylylidene))bis(methaneylylidene))bis(3‐bromophenol), C34H32Br4N4O4
  13. The crystal structure of (E)-2-(2-((2-picolinoylhydrazono)methyl)phenoxy)acetic acid dihydrate, C15H17N3O6
  14. Crystal structure of (E)-4-bromo-N′-(3-chloro-2-hydroxybenzylidene)benzohydrazide, C14H10BrClN2O2
  15. Crystal structure of N,N′-bis(4-bromosalicylidene) ethylene-1,2-diaminopropan, C34H32Br4N4O4
  16. Crystal structure of 4-bromo-N′-[(3-bromo-2-hydroxyphenyl)methylidene]benzohydrazide methanol solvate, C15H14Br2N2O3
  17. The crystal structure of 1,2-bis(1H-benzo[d]imidazol-2-yl)ethane-1,2-diol — N-(2-aminophenyl)-3-(1H-benzo[d]imidazol-2-yl)-2,3-dihydroxypropanamide (1/1), C32H30N8O5
  18. The crystal structure of para-trifluoromethyl-aniline hemihydrate, C14H14F6N2O
  19. Redetermination of the crystal structure of 2-amino-2-methyl-propane-1,3-diole, C4H11NO2
  20. The crystal structure of methacholine chloride, C8H18ClNO2
  21. Crystal structure of 5,7,7-trimethyl-4,6,7,8-tetrahydrocyclopenta[g]isochromen-1(3H)-one, C15H18O2
  22. Crystal structure of poly[diammine-bis(μ4-4-hydroxypyridine-3-sulfonato-κ5N:O, O′:O′′:O′′)(μ2-pyrazinyl-κ2N:N′)tetrasilver(I)], C7H8Ag2N3O4S
  23. Crystal structure of ethyl (E)-5-(((3′,6′-bis(ethylamino)-3-oxospiro[isoindoline-1,9′-xanthen]-2-yl)imino)methyl)-2,4-dimethyl-1H-pyrrole-3-carboxylate — ethanol (1/1), C38H45N5O5
  24. Crystal structure of 4-bromo-N′-[(3-chloro-2-hydroxyphenyl)methylidene]benzohydrazide, C14H7Br2N2O2
  25. Redetermination of the crystal structure of 3,3,3-triphenylpropanoic acid, C21H18O2 – Deposition of hydrogen atomic coordinates
  26. Structure redetermination of dextromethorphan hydrobromide monohydrate, C18H28BrNO2 – localization of hydrogen atoms
  27. Crystal structure of tris(azido-κ1N)-(N-(2-aminoethyl)-N-methyl-1,3-propanediamine-κ3N,N′,N′′)cobalt(III), C7H19CoN12
  28. Crystal structure of tetraaqua-bis(1H-indazole-6-carboxylate-κN)cadmium (II), C16H18CdN4O8
  29. Crystal structure of dichloride-bis(1-propylimidazole-κ1N)zinc(II), C12H20Cl2N4Zn
  30. Crystal structure of (E)-resveratrol 3-O-β-D-xylopyranoside, C19H22O8
  31. Crystal structure of 3,3′-(1,2-phenylene-bis(methylene))bis(1-vinyl- 1H-imidazol-3-ium) bis(hexafluoro phosphate)(V), C18H20F12N4P2
  32. Crystal structure of diaqua[bis(benzimidazol-2-yl-methyl)amine-κ3N,N′,N″]-phthalato-κ1O-nickel(II)-methanol (1/2), C26H31N5NiO8
  33. Crystal structure of 6,7-difluoro-1-methyl-3-(trifluoromethyl)quinoxalin-2(1H)-one, C10H5F5N2O
  34. Crystal structure of dichlorido-bis(1-hexyl-1H-benzotriazole-k1N)zinc(II), C24H34N6Cl2Zn
  35. The crystal structre of 2-(4-bromophenyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine, C16H12BBrN2
  36. Crystal structure of diethyl 3,9-bis(4-fluorophenyl)-6,12-diphenyl-3,9-diazapentacyclo[6.4.0.02,7.04,11]dodecane-1,5-dicarboxylate, C40H36F2N2O4
  37. Crystal structure of (E)-7-methoxy-2-((5-methoxypyridin-3-yl)methylene)-3,4- dihydronaphthalen-1(2H)-one, C18H17NO3
  38. Crystal structure of (E)-2-chloro-6-(((1,3-dihydroxy-2-(oxidomethyl)propan-2-yl)imino)methyl)phenolate-κ3N,O,O’)manganese(IV), C22H24Cl2MnN2O8
  39. The crystal structure of α-(meta-methoxyphenoxy)-ortho-tolylic acid, C15H14O4
  40. The crystal structure of N-(2-chloroethyl)-N,N-diethylammonium chloride, C6H15Cl2N
  41. The crystal structure of tris(2,3,4,6,7,8,9,10-octahydro-1H-pyrimido[1,2-a]azepin-5-ium) trihydrodecavanadate(V), C27H54N6O28V10
  42. Crystal structure of 1,3-bis(octyl)benzimidazolium perchlorate C23H39ClN2O4
  43. Crystal structure of tetrakis[(Z)-(2-(1-(furan-2-yl)-2-methylpropylidene)-1-phenylhydrazin-1-ido-κ2N,N′)] zirconium(IV), C56H60N8O4Zr
  44. The crystal structure of 2-(naphthalen-2-yloxy)-4-phenyl-6-(prop-2-yn-1-yloxy)-1,3,5-triazine, C22H15N3O2
  45. The crystal structure of trimethylsulfonium tris(trifluoromethylsulfonyl)methanide, C7H9F9O6S4
  46. Crystal structure of 4-bromo-N′-[3,5-dichloro-2-hydroxyphenyl)methylidene]benzohydrazide methanol solvate, C15H13BrCl2N2O3
  47. The crystal structure of 4-(4-bromophenyl)-2-(3-(4-bromophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)thiazole, C24H16Br2FN3S
  48. The crystal structure of N-(adamantan-1-yl)-piperidine-1-carbothioamide, C16H26N2S
  49. The crystal structure of 1-phenyl-N-(4,5,6,7-tetrabromo-1,3-dioxoisoindolin-2-yl)-5-(thiophen-2-yl)-1H-pyrazole-3-carboxamide-dimethylformamide (1/1) C22H10Br4N4O3S
  50. The crystal structure of benzeneseleninic acid anhydride, C12H10O3Se2
  51. The crystal structure of diphenyalmine hydrochloride antimony trichloride co-crystallizate, C12H12Cl4NSb – Localization of hydrogen atoms
  52. The crystal structure of para-nitrobenzylbromide, C7H6BrNO2 – A second polymorph and correction of 3D coordinates
  53. Crystal structure of catena-poly[(5H-pyrrolo[3,2-b:4,5-b′]dipyridine-κ2N,N′)-(μ4-hexaoxidodivanadato)dizinc(II)],C10H9N3O6V2Zn
  54. Crystal structure of N,N′-(2-hydroxypropane-1,3-diyl)bis(pyridine-2-aldimine)-κ5N,N′,N′′,N′′′,O]-tris(nitrato-κ2O,O′) cerium(III), C15H16CeN7O10
  55. Synthesis and crystal structure of oktakis(dimethylsulphoxide-κ1O)gadolinium(III) [tetrabromido-μ2-bromido-μ2-sulfido-di-μ3-sulfido-μ4-sulfido-tetracopper(I)-tungsten(VI)], C16H48O8S12Br5Cu4GdW
  56. Crystal structure of {tris((1H-benzo[d]imidazol-2- yl)methyl)amine-κ4N,N′,N′′,N′′′}-(succinato-κ2O,O′)nickel(II) – methanol (1/4), C32H41N7NiO8
  57. Crystal structure of catena-poly[trans-tetraaqua(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-k2N:N′)cobalt(II)] dinitrate – 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) – water (1/3/2), C72H68CoN18O12
  58. Crystal structure of bis(μ2-2-oxido-2-phenylacetate-κ3O:O,O′)-bis(1-isopropoxy-2-oxo-2-phenylethan-1-olato-κ2O,O′)-bis(propan-2-olato-κ1O)dititanium(IV), C44H52O14Ti2
  59. The crystal structure of 5-carboxy-2-(hydroxymethyl)-1H-imidazol-3-ium-4-carboxylate, C6H8N2O6
  60. The crystal structure of 2,6-dibromo-4-fluoroaniline, C6H4Br2FN
  61. The crystal structure of 4-chloro-N-(2-phenoxyphenyl)benzamide, C19H14ClNO2
  62. The crystal structure of 2-methyl-β-naphthothiazole, C12H9NS
https://doi.org/10.1515/ncrs-2020-0555
Creative Commons
BY 4.0

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of 4-hydroxybenzene-1,3-diaminium dichloride, C6H10Cl2N2O
  4. The crystal structure of 3-chloropropylammonium chloride, C3H9Cl2N
  5. The crystal structure of 1-chloro-2-(dimethylamino)ethane hydrochloride, C4H11Cl2N
  6. Crystal structure of N-(2-(trifluoromethyl)phenyl)hexanamide, C13H16F3NO
  7. Redetermination of the crystal structure of para-toluidine, C7H9N 
  8. The crystal structure of bis(1,3-dihydroxy-2-methylpropan-2-aminium) carbonate, C9H24N2O7
  9. The crystal structure of 4-chloro-1-methylpiperidin-1-ium chloride, C6H13Cl2N
  10. Crystal structure of (Z)-3-(6-bromo-1H-indol-3-yl)-1,3-diphenylprop-2-en-1-one, C23H16BrNO
  11. The crystal structure of ethyl 2-amino-4-(3,5-difluorophenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carboxylate, C20H21F2NO4
  12. Crystal structure of 6,6'‐((1E,1'E)‐(propane‐1,3‐diylbis(azaneylylidene))bis(methaneylylidene))bis(3‐bromophenol), C34H32Br4N4O4
  13. The crystal structure of (E)-2-(2-((2-picolinoylhydrazono)methyl)phenoxy)acetic acid dihydrate, C15H17N3O6
  14. Crystal structure of (E)-4-bromo-N′-(3-chloro-2-hydroxybenzylidene)benzohydrazide, C14H10BrClN2O2
  15. Crystal structure of N,N′-bis(4-bromosalicylidene) ethylene-1,2-diaminopropan, C34H32Br4N4O4
  16. Crystal structure of 4-bromo-N′-[(3-bromo-2-hydroxyphenyl)methylidene]benzohydrazide methanol solvate, C15H14Br2N2O3
  17. The crystal structure of 1,2-bis(1H-benzo[d]imidazol-2-yl)ethane-1,2-diol — N-(2-aminophenyl)-3-(1H-benzo[d]imidazol-2-yl)-2,3-dihydroxypropanamide (1/1), C32H30N8O5
  18. The crystal structure of para-trifluoromethyl-aniline hemihydrate, C14H14F6N2O
  19. Redetermination of the crystal structure of 2-amino-2-methyl-propane-1,3-diole, C4H11NO2
  20. The crystal structure of methacholine chloride, C8H18ClNO2
  21. Crystal structure of 5,7,7-trimethyl-4,6,7,8-tetrahydrocyclopenta[g]isochromen-1(3H)-one, C15H18O2
  22. Crystal structure of poly[diammine-bis(μ4-4-hydroxypyridine-3-sulfonato-κ5N:O, O′:O′′:O′′)(μ2-pyrazinyl-κ2N:N′)tetrasilver(I)], C7H8Ag2N3O4S
  23. Crystal structure of ethyl (E)-5-(((3′,6′-bis(ethylamino)-3-oxospiro[isoindoline-1,9′-xanthen]-2-yl)imino)methyl)-2,4-dimethyl-1H-pyrrole-3-carboxylate — ethanol (1/1), C38H45N5O5
  24. Crystal structure of 4-bromo-N′-[(3-chloro-2-hydroxyphenyl)methylidene]benzohydrazide, C14H7Br2N2O2
  25. Redetermination of the crystal structure of 3,3,3-triphenylpropanoic acid, C21H18O2 – Deposition of hydrogen atomic coordinates
  26. Structure redetermination of dextromethorphan hydrobromide monohydrate, C18H28BrNO2 – localization of hydrogen atoms
  27. Crystal structure of tris(azido-κ1N)-(N-(2-aminoethyl)-N-methyl-1,3-propanediamine-κ3N,N′,N′′)cobalt(III), C7H19CoN12
  28. Crystal structure of tetraaqua-bis(1H-indazole-6-carboxylate-κN)cadmium (II), C16H18CdN4O8
  29. Crystal structure of dichloride-bis(1-propylimidazole-κ1N)zinc(II), C12H20Cl2N4Zn
  30. Crystal structure of (E)-resveratrol 3-O-β-D-xylopyranoside, C19H22O8
  31. Crystal structure of 3,3′-(1,2-phenylene-bis(methylene))bis(1-vinyl- 1H-imidazol-3-ium) bis(hexafluoro phosphate)(V), C18H20F12N4P2
  32. Crystal structure of diaqua[bis(benzimidazol-2-yl-methyl)amine-κ3N,N′,N″]-phthalato-κ1O-nickel(II)-methanol (1/2), C26H31N5NiO8
  33. Crystal structure of 6,7-difluoro-1-methyl-3-(trifluoromethyl)quinoxalin-2(1H)-one, C10H5F5N2O
  34. Crystal structure of dichlorido-bis(1-hexyl-1H-benzotriazole-k1N)zinc(II), C24H34N6Cl2Zn
  35. The crystal structre of 2-(4-bromophenyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine, C16H12BBrN2
  36. Crystal structure of diethyl 3,9-bis(4-fluorophenyl)-6,12-diphenyl-3,9-diazapentacyclo[6.4.0.02,7.04,11]dodecane-1,5-dicarboxylate, C40H36F2N2O4
  37. Crystal structure of (E)-7-methoxy-2-((5-methoxypyridin-3-yl)methylene)-3,4- dihydronaphthalen-1(2H)-one, C18H17NO3
  38. Crystal structure of (E)-2-chloro-6-(((1,3-dihydroxy-2-(oxidomethyl)propan-2-yl)imino)methyl)phenolate-κ3N,O,O’)manganese(IV), C22H24Cl2MnN2O8
  39. The crystal structure of α-(meta-methoxyphenoxy)-ortho-tolylic acid, C15H14O4
  40. The crystal structure of N-(2-chloroethyl)-N,N-diethylammonium chloride, C6H15Cl2N
  41. The crystal structure of tris(2,3,4,6,7,8,9,10-octahydro-1H-pyrimido[1,2-a]azepin-5-ium) trihydrodecavanadate(V), C27H54N6O28V10
  42. Crystal structure of 1,3-bis(octyl)benzimidazolium perchlorate C23H39ClN2O4
  43. Crystal structure of tetrakis[(Z)-(2-(1-(furan-2-yl)-2-methylpropylidene)-1-phenylhydrazin-1-ido-κ2N,N′)] zirconium(IV), C56H60N8O4Zr
  44. The crystal structure of 2-(naphthalen-2-yloxy)-4-phenyl-6-(prop-2-yn-1-yloxy)-1,3,5-triazine, C22H15N3O2
  45. The crystal structure of trimethylsulfonium tris(trifluoromethylsulfonyl)methanide, C7H9F9O6S4
  46. Crystal structure of 4-bromo-N′-[3,5-dichloro-2-hydroxyphenyl)methylidene]benzohydrazide methanol solvate, C15H13BrCl2N2O3
  47. The crystal structure of 4-(4-bromophenyl)-2-(3-(4-bromophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)thiazole, C24H16Br2FN3S
  48. The crystal structure of N-(adamantan-1-yl)-piperidine-1-carbothioamide, C16H26N2S
  49. The crystal structure of 1-phenyl-N-(4,5,6,7-tetrabromo-1,3-dioxoisoindolin-2-yl)-5-(thiophen-2-yl)-1H-pyrazole-3-carboxamide-dimethylformamide (1/1) C22H10Br4N4O3S
  50. The crystal structure of benzeneseleninic acid anhydride, C12H10O3Se2
  51. The crystal structure of diphenyalmine hydrochloride antimony trichloride co-crystallizate, C12H12Cl4NSb – Localization of hydrogen atoms
  52. The crystal structure of para-nitrobenzylbromide, C7H6BrNO2 – A second polymorph and correction of 3D coordinates
  53. Crystal structure of catena-poly[(5H-pyrrolo[3,2-b:4,5-b′]dipyridine-κ2N,N′)-(μ4-hexaoxidodivanadato)dizinc(II)],C10H9N3O6V2Zn
  54. Crystal structure of N,N′-(2-hydroxypropane-1,3-diyl)bis(pyridine-2-aldimine)-κ5N,N′,N′′,N′′′,O]-tris(nitrato-κ2O,O′) cerium(III), C15H16CeN7O10
  55. Synthesis and crystal structure of oktakis(dimethylsulphoxide-κ1O)gadolinium(III) [tetrabromido-μ2-bromido-μ2-sulfido-di-μ3-sulfido-μ4-sulfido-tetracopper(I)-tungsten(VI)], C16H48O8S12Br5Cu4GdW
  56. Crystal structure of {tris((1H-benzo[d]imidazol-2- yl)methyl)amine-κ4N,N′,N′′,N′′′}-(succinato-κ2O,O′)nickel(II) – methanol (1/4), C32H41N7NiO8
  57. Crystal structure of catena-poly[trans-tetraaqua(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-k2N:N′)cobalt(II)] dinitrate – 1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol) – water (1/3/2), C72H68CoN18O12
  58. Crystal structure of bis(μ2-2-oxido-2-phenylacetate-κ3O:O,O′)-bis(1-isopropoxy-2-oxo-2-phenylethan-1-olato-κ2O,O′)-bis(propan-2-olato-κ1O)dititanium(IV), C44H52O14Ti2
  59. The crystal structure of 5-carboxy-2-(hydroxymethyl)-1H-imidazol-3-ium-4-carboxylate, C6H8N2O6
  60. The crystal structure of 2,6-dibromo-4-fluoroaniline, C6H4Br2FN
  61. The crystal structure of 4-chloro-N-(2-phenoxyphenyl)benzamide, C19H14ClNO2
  62. The crystal structure of 2-methyl-β-naphthothiazole, C12H9NS
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 8.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2020-0555/html
Scroll to top button