Startseite The crystal structure of fac-tricarbonyl((pyridin-2-yl)methanamino-κ2 N,N′)-((pyridin-2-yl)methanamino-κN)rhenium(I) nitrate, C15H16O3N4Re
Artikel Open Access

The crystal structure of fac-tricarbonyl((pyridin-2-yl)methanamino-κ2 N,N′)-((pyridin-2-yl)methanamino-κN)rhenium(I) nitrate, C15H16O3N4Re

  • Lesetja V. Ramoba ORCID logo EMAIL logo , Orbett T. Alexander ORCID logo , Frederick P. Malan ORCID logo und Amanda-Lee E. Manicum
Veröffentlicht/Copyright: 23. Mai 2023
Artikel downloaden (PDF)
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 238 Heft 4

Abstract

C15H16O3N4Re, triclinic, P1̄ (no. 2), a = 7.4939(2) Å, b = 10.1316(2) Å, c = 13.8351(3) Å, α = 103.453(2)°, β = 101.992(2)°, γ = 107.880(2)°, V = 926.98(4) Å3, Z = 2, R gt (F) = 0.0341, wR ref (F 2) = 0.0861, T = 150 K.

CCDC no.: 2259031

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Figure 1: Shows the molecular structure of C15H16O3N4Re. Hydrogen atoms were omitted for clarity.
Figure 1:

Shows the molecular structure of C15H16O3N4Re. Hydrogen atoms were omitted for clarity.

Table 1:

Data collection and handling.

Crystal: Yellow block
Size: 0.51 × 0.26 × 0.25 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 6.60 mm−1
Diffractometer, scan mode: XtaLAB Synergy R, ω
θ max, completeness: 30.9°, >99%
N(hkl)measured, N(hkl)unique, R int: 33,002, 5109, 0.093
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 4684
N(param)refined: 244
Programs: Olex2 [1], Shelx [2], [3], [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C2 0.5542 (6) 0.2674 (4) 0.6564 (3) 0.0263 (8)
C3 0.4152 (6) 0.1228 (5) 0.6221 (4) 0.0321 (10)
H3 0.389983 0.059977 0.553967 0.039*
C4 0.3175 (7) 0.0738 (5) 0.6870 (4) 0.0346 (10)
H4 0.223945 −0.023494 0.664628 0.041*
C5 0.3553 (6) 0.1673 (4) 0.7868 (4) 0.0318 (9)
H5 0.289052 0.134969 0.833464 0.038*
C6 0.4910 (6) 0.3076 (4) 0.8158 (3) 0.0256 (8)
H6 0.516936 0.371776 0.883543 0.031*
C8 0.6604 (6) 0.3271 (4) 0.5870 (3) 0.0285 (9)
H8A 0.700671 0.252123 0.547751 0.034*
H8B 0.571018 0.350405 0.536040 0.034*
C15 1.0148 (7) 0.5430 (5) 0.8787 (3) 0.0279 (9)
C17 0.7459 (6) 0.6605 (4) 0.9177 (3) 0.0261 (8)
C19 1.0016 (7) 0.7673 (5) 0.8176 (4) 0.0298 (9)
C20 0.6238 (7) 0.8696 (5) 0.7543 (4) 0.0356 (11)
C22 0.8244 (9) 1.0328 (6) 0.6952 (6) 0.0547 (17)
H22 0.877147 1.052670 0.641082 0.066*
C23 0.8821 (9) 1.1427 (6) 0.7859 (7) 0.064 (2)
H23 0.973456 1.236760 0.794702 0.077*
C24 0.8070 (11) 1.1166 (7) 0.8654 (7) 0.073 (3)
H24 0.844003 1.192570 0.929305 0.088*
C25 0.6751 (9) 0.9761 (6) 0.8503 (5) 0.0545 (16)
H25 0.622018 0.954013 0.903831 0.065*
C26 0.4813 (7) 0.7148 (5) 0.7283 (4) 0.0323 (9)
H26A 0.449452 0.698987 0.791693 0.039*
H26B 0.357827 0.697795 0.675714 0.039*
N7 0.5891 (5) 0.3581 (4) 0.7521 (3) 0.0213 (7)
N9 0.8374 (5) 0.4613 (4) 0.6476 (3) 0.0243 (7)
H9A 0.857639 0.521934 0.608376 0.029*
H9B 0.944281 0.436088 0.661486 0.029*
N11 0.1137 (5) 0.3339 (4) 0.5232 (3) 0.0317 (8)
N27 0.5714 (5) 0.6110 (4) 0.6869 (3) 0.0272 (7)
H27A 0.620875 0.640185 0.637285 0.033*
H27B 0.472664 0.521922 0.653867 0.033*
N28 0.6960 (6) 0.8964 (4) 0.6774 (4) 0.0409 (9)
O10 0.1276 (6) 0.3314 (5) 0.6135 (3) 0.0590 (11)
O12 −0.0461 (5) 0.2904 (5) 0.4542 (3) 0.0582 (11)
O13 0.2672 (5) 0.3935 (4) 0.5026 (3) 0.0351 (7)
O14 1.1457 (5) 0.5279 (4) 0.9301 (3) 0.0408 (8)
O16 0.7029 (5) 0.7072 (4) 0.9890 (3) 0.0423 (8)
O18 1.1243 (5) 0.8797 (4) 0.8349 (3) 0.0497 (10)
Re1 0.80884 (2) 0.57883 (2) 0.79542 (2) 0.01999 (7)

1 Source of material

Fac-[Re(N,N) (CO)3(H2O)] (N,N = (2-picolylamine- κ 2 N,N') (20 mg, 0.051 mmol) was dissolved in methanol (5 mL) and 2-picolylamine (5.36 mL, 0.051 mmol) dissolved in (10 mL) methanol was added. The solution was then stirred for 30 min and then refluxed for 24 h at room temperature and the light yellow solution was left to crystallize (Yield = 15.25 mg, 84 %; FTIR (cm−1) Vco: 2024, 1909).

2 Experimental details

All hydrogen atoms were positioned geometrically using a riding model, with fixed C–HAromatic = 0.97 Å. The H atoms isotropic displacement parameters were fixed; U iso (H) = 1.2U eq (C) for aromatic, allowing them to ride on the parent atom. The graphics were obtained using the mercury program with 50 % probability ellipsoids. All the H-atoms on the title structure were omitted for clarity.

3 Comment

Since the inception of the [2 + 1] mixed ligand model by Mundwiler and co-workers [5], rhenium(I) tricarbonyl complexes of fac-[Re(CO)3]+ synthon have been exploited for various applications [6], [7], [8]. The stable organometallic precursor has three tightly coordinated CO ligands and three water molecules, the latter of which can be readily substituted by suitable ligand systems to produce relatively stable octahedral tricarbonyl complexes [9], [10], [11]. Furthermore, the nuclear properties of the two radionuclides of rhenium, 186Re (t 1/2 = 90 h; E max = 1.07 MeV) and 188Re (t 1/2 = 17 h; E max = 2.12 MeV) which are high-energy beta emitters, ideal for radiotherapy related research, intrigued many research groups across the world [11], [12], [13]. Subsequently, there has been a reasonable pursuit of technetium tricarbonyl chemistry since this radionuclide work in tandem with the above-discussed rhenium tricarbonyl system [14], [15], [16].

In this work, three labile aqua ligands in the fac-[Re(CO)3(OH2)3]+ synthon are first bidentately substituted in the equatorial position by 2-picolylamine, and then monodentately in the axial position by the same ligand, by incorporating the [2 + 1] mixed ligand model. The title compound (see the Figure 1) is balanced by a nitrate ( N O 3 − ) counter ion, revealing that the overall charge of the complex bears a +1 charge. The structure exhibits an octahedral distortion as seen in the Re1–N7–C2–C8–N9 five-membered ring bite angle of 75.81 ( 13 ) ∘ . The bond distances between rhenium and the bonded carbonyl ligands range from 1.908(5) to 1.921(5) Å, and the rhenium to nitrogen bond distances range from 2.186(3) Å to 2.236(4) Å. The reported bond distances and bite angles correlate well with the bond distances and bite angles of other structures reported in the literature [5, 6, 9].

Corresponding author: Lesetja V. Ramoba, Department of Chemistry, Tshwane, University of Technology, 0001, Pretoria, South Africa, E-mail:

Funding source: NRF

Award Identifier / Grant number: 113629

Acknowledgements

The authors would like to thank the National Research Foundation of South Africa (Grant No. 129468), Tshwane University of Technology, and the University of Pretoria for institutional and financial support.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: NRF (Thuthuka grant specific number 113629).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Cryst. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Suche in Google Scholar

2. Sheldrick, G. M. A short history of SHELX. Acta Cryst. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Suche in Google Scholar PubMed

3. Sheldrick, G. M. SHELXTL – integrated space-group and crystal-structure determination. Acta Cryst. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Suche in Google Scholar

4. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Cryst. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Suche in Google Scholar

5. Mundwiler, S., Kündig, M., Ortner, K., Alberto, R. A new [2 + 1] mixed ligand concept based on [99(m)Tc(OH2)3(CO)3]+: a basic study. Dalton Trans 2004, 9, 1320–1328; https://doi.org/10.1039/b400220b.Suche in Google Scholar PubMed

6. Ramoba, L. V., Alexander, O. T., Visser, H. G., Manicum, A. The crystal structure of fac-tricarbonyl (1,10-phenanthroline-κ2N,N′)-(pyrazole-κN) rhenium(I)nitrate, C18H16O3N4Re. Z. Kristallogr. N. Cryst. Struct. 2020, 235, 1203–1205; https://doi.org/10.1515/ncrs-2020-0249.Suche in Google Scholar

7. Probst, B., Rodenberg, A., Guttentag, M., Hamm, P., Alberto, R. A highly stable rhenium- cobalt system for photocatalytic H2 production: unravelling the performance-limiting steps. Inorg. Chem. 2010, 49, 6453–6460; https://doi.org/10.1021/ic100036v.Suche in Google Scholar PubMed

8. Mukherjee, J., Siewert, I. Manganese and rhenium tricarbonyl complexes equipped with proton relays in the electrochemical CO2 reduction reaction. Eur. J. Inorg. Chem 2020, 46, 4319–4333; https://doi.org/10.1002/ejic.202000738.Suche in Google Scholar

9. Moremi, J. M., Vatsha, B., Alexander, O. T., Makgopa, K., Manicum, A. The crystal structure of fac-tricarbonyl(4,4-dimethyl-2,2-dipyridyl-κ2-N,N′) (pyrazole-κN)rhenium(I)nitrate, C18H12O3N4Re. Z. Kristallogr. N. Cryst. Struct. 2020, 236, 33–35; https://doi.org/10.1515/ncrs-2020-0458.Suche in Google Scholar

10. Manicum, A., Alexander, O. T., Schutte–Smith, M., Visser, H. G. Synthesis, characterization and substitution reactions of fac-[Re(O,O′-bid)(CO)3(P)] complexes, using the “2 + 1” mixed ligand model. J. Mol. Struct. 2020, 1209, 127953; https://doi.org/10.1016/j.molstruc.2020.127953.Suche in Google Scholar

11. Triantis, C., Shegani, A., Kiritsis, C., Ischyropoulou, M., Roupa, I., Psycharis, V., Raptopoulou, C., Kyprinidou, P., Pelecanou, M., Pirmettis, I., Papadopoulos, M. S. Dicarbonylcis-[M(CO)3(N,O)(C)(P)] (M = Re, 99mTc) complexes with a new [2 + 1 + 1] donor atom combination. Inorg. Chem. 2018, 57, 8354–8363; https://doi.org/10.1021/acs.inorgchem.8b01014.Suche in Google Scholar PubMed

12. Karges, J., Cohen, S. M. Rhenium (V) complexes as cysteine-targeting coordinate covalent warheads. J. Med. Chem. 2023, 66, 3088–3105; https://doi.org/10.1021/acs.jmedchem.2c02074.Suche in Google Scholar PubMed PubMed Central

13. Yu, S. H., Patra, M., Ferrari, S., Garcia, P. R., Veldhuis, N. A., Kaminskas, L. M., Graham, B., Quinn, J. F., Whittaker, M. R., Gasser, G., Davis, T. P. Linker chemistry dictates the delivery of a phototoxic organometallic rhenium (I) complex to human cervical cancer cells from core crosslinked star polymer nanoparticles. J. Mat. Chem. 2018, 6, 7805–7810; https://doi.org/10.1039/c8tb02464b.Suche in Google Scholar PubMed

14. Manicum, A., Schutte-Smith, M., Visser, H. G., Pretorius, C., Roodt, A. Crystal structure of tetraethylammonium fac-tricarbonyl(hexaflouroacetylacetonato-κ2O,O′)-(nitrito-κ-O) rhenium(I), C16H21O8N2F6Re. Z. Kristallogr. N. Cryst. Struct. 2016, 231, 263–266; https://doi.org/10.1515/ncrs-2015-0115.Suche in Google Scholar

15. Dilworth, J. R., Pascu, S. I. The radiopharmaceutical chemistry of technetium and rhenium. In The Chemistry of Molecular Imaging; Long, N., Wong, W.-T., Eds., 1st ed.; John Wiley & Sons, Inc.: Cambridge, MA, 2015.10.1002/9781118854754.ch6Suche in Google Scholar

16. Kama, D. V., Brink, A., Alberto, R., Roodt, A. Exploring structural implications of diphosphinamine ligands in medicine and catalysis. Acta Cryst 2021, 77, C1015; https://doi.org/10.1107/s010876732108764x.Suche in Google Scholar
Received: 2023-04-04
Accepted: 2023-04-26
Published Online: 2023-05-23
Published in Print: 2023-08-28

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of a polymorph of potassium picrate, C6H2KN3O7
  4. The crystal structure of (1E,2E)-1,2-bis(quinolin-2-ylmethylene)hydrazine, C20H14N4
  5. 5-Amino-2-chloro-4-fluoro-N-(N-isopropyl-N-methylsulfamoyl) benzamide, C11H15O3ClFN3S
  6. Crystal structure of trans-N 1,N 8-bis(2-cyanoethyl)-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, C22H42N6
  7. The crystal structure of [N-{[2-(oxy)-4-methoxyphenyl](phenyl)methylidene}alaninato]-diphenyl-silicon(IV) – chloroform (1/1), C29H25NO4Si·CHCl3
  8. Crystal structure of tetracarbonyl-{μ-[N-(diphenylphosphanyl)-N,P,P-triphenylphosphinous amide]}-bis[μ-(phenylmethanethiolato)]diiron (Fe–Fe), C48H39Fe2NO4P2S2
  9. Crystal structure of baryte from Mine du Pradet (France)
  10. The crystal structure of [(2,2′-bipyridine-6-carboxylato-κ3 N,N,O)-(6-phenylpyridine-2-carboxylate-κ2 N,O)copper(II)] monohydrate, C23H17N3O5Cu
  11. Crystal structure of bis(μ-benzeneselenolato)-(μ-[N-benzyl-N-(diphenylphosphanyl)-P,P-diphenylphosphinous amide])-tetracarbonyl diiron (Fe–Fe), C47H37Fe2NO4P2Se2
  12. The crystal structure of diaqua-methanol-κ1 O- (3-thiophenecarboxylato-κO)-(2,2′-dipyridyl-κ2 N,N′)manganese(II) 3-thiophenecarboxylate, C21H22N2O7S2Mn
  13. Crystal structure of catena-poly[tetrakis(butyl)-μ2-2-((oxido(phenyl)methylene)hydrazineylidene)propanoato-κ4 O:O,O′,N-μ2-2-((oxido(phenyl)methylene)hydrazineylidene)propanoato-κ4 O,N,O′:N′-ditin(IV)], C34H50N6O6Sn2
  14. Crystal structure of 4-chloro-N′-[(1E)-(2-nitrophenyl)methylidene]benzohydrazide, C14H10ClN3O3
  15. The crystal structure of 3-(1′-deoxy-3′,5′-O-dibenzy-β-d-ribosyl)adenine dichloromethane solvate, C49H52Cl2N10O6
  16. The crystal structure of (Z)-4-amino-N′-(1-(o-tolyl)ethylidene)benzohydrazide, C16H17N3O
  17. The co-crystal structure of etoricoxib–phthalic acid (1/1), C18H15ClN2O2S·C8H6O4
  18. Crystal structure of (glycinto-κ 2 O,N ′)-[5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ 4 N,N ′,N ″,N ‴]nickel(II) perchlorate monohydrate C18H42ClN5NiO7
  19. The crystal structure of catena-poly[bis(1-ethylimidazole-k1 N)-(μ 2-benzene-1-carboxyl-3,5-dicarboxylato-κ 2 O, O′)zinc(II)], C19H20N4O6Zn
  20. Crystal structure of 3-(thiazol-2-ylcarbamoyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid, C11H12N2O4S
  21. Rietveld structure analysis of keatite, a rare, metastable SiO2 polymorph
  22. Crystal structure of catena-poly[(μ2-isophthalato-k3 O,O′:O″)(4-(4-pyridyl)-2,5-dipyrazylpyridine-k3 N,N′,N″)cobalt(II)] trihydrate C26H22N6O7Co1
  23. Crystal structure of 3,5–di-O-benzoyl-1,2-O-isopropylidene-α–D-ribose, C22H22O7
  24. The crystal structure of fac-tricarbonyl(6-bromo-2,2-bipyridine-κ2 N,N)-(nitrato-κO)rhenium(I), C13H7BrN3O6Re
  25. The crystal structure of (E)-N′-(4-hydroxy-3-methoxybenzylidene)-2-naphthohydrazide monohydrate, C19H18N2O4
  26. The crystal structure of 5,5′-diselanediyl-bis(2-hydroxybenzaldehyde), C14H10O4Se2
  27. The crystal structure of catena-poly[diaqua-m2-dicyanido-κ2 C:N-dicyanido-κ1 C-bis(4-(pyridin-4-yl)benzaldehyde-κ1N)iron(II)-platinum(II), C28H22N6O4PtFe
  28. Redetermination of the crystal structure of 5,14-dihydro-6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)tetra-azacyclotetradecine, C32H28N4
  29. Crystal structure of poly[(μ3-2-(3,5-dicarboxyphenyl) benzimidazole-6-carboxylato-κ4O:O:O′:O″)lead(II)] monohydrate, C16H10N2O7Pb
  30. The crystal structure of fac-tricarbonyl(2-pyridin-2-yl-quinoline-κ2 N,N′)-(pyrazole-κN)rhenium(I)nitrate, C20H14N4O3ReNO3
  31. Crystal structure of dibromo-dicarbonyl-bis(tricyclohexylphosphine)-osmium(II) dichloromethane solvate, C38H66Br2O2OsP2
  32. Crystal structure of poly[bis(μ 2-2,6-bis(1-imidazoly)pyridine-κ 2 N:N′)copper(II)] diperchlorate dihydrate, C22H22Cl2CuN10O10
  33. The crystal structure of fac-tricarbonyl(N-benzoyl-N,N-cyclohexylmethylcarbamimidothioato-κ2 S,O)-(pyridine-κN)rhenium(I), C23H24N3O4ReS
  34. Crystal structure of (E)-7-fluoro-2-(4-fluorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C17H12F2O
  35. Synthesis and crystal structure of 1-((3R,10S,13S, 17S)-3-((2-methoxyphenyl)amino)-10,13-dimethylhexadecahydro-1H-cyclopenta[α]phenanthren-17-yl)ethan-1-one, C28H41NO2
  36. The crystal structure of fac-tricarbonyl((pyridin-2-yl)methanamino-κ2 N,N′)-((pyridin-2-yl)methanamino-κN)rhenium(I) nitrate, C15H16O3N4Re
  37. The crystal structure of (1-(pyridin-2-yl)-N-(pyridin-2-ylmethyl)-N-((1-(4-vinylbenzyl)-1H-benzo[d]imidazol-2-yl)methyl)methanamine-κ 4 N,N′,N″,N‴)tris(nitrato-kO,O′)-erbium(III), C29H27ErN8O9
  38. Crystal structure of tetracene-5,12-dione, C18H10O2
  39. Crystal structure of (3R,3aS,6R,6aR)-6-hexyl-3-methyltetrahydrofuro[3,4-b]furan-2,4-dione, C13H20O4
  40. The crystal structure of N′1,N′3-bis((E)-thiophen-2-ylmethylene)isophthalohydrazide monohydrate, C18H16N4O3S2
  41. Crystal structure of methyl ((4-aminobenzyl)sulfonyl)-L-prolinate, C13H18N2O4S
  42. Crystal structure of (E)-3-(3-methoxybenzylidene)benzofuran-2(3H)-one, C16H12O3
  43. Synthesis and crystal structure (E)-1-(4-bromo-2-hydroxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C11H12BrNO2
  44. Synthesis and crystal structure of (S,E)-4-hydroxy-3-(2-((4aR,6aS,7R,10aS,10bR)-3,3,6a,10b-tetramethyl-8-methylenedecahydro-1H-naphtho[2,1-d][1,3]dioxin-7-yl)ethylidene)dihydrofuran-2(3H)-one, C23H34O5
  45. The crystal structure of N,N′-(1,2-phenylene)bis (2-((2-oxopropyl)selanyl)benzamide), C26H24N2O4Se2
  46. The crystal structure of 1-ethyl-2-nitro-imidazole oxide, C5H7N3O3
  47. The crystal structure of 2-(2-fluorophenyl)naphtho[2,1-d]thiazole, C17H10FNS
  48. Crystal structure of (E)-2,4-di-tert-butyl-6-(((2-fluorophenyl)imino) methyl)phenol, C21H26FNO
  49. Synthesis and crystal structure of 3-methyl-2-(methylthio)-4H-chromen-4-one, C12H12O2S
  50. Crystal structure of dithieno[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene-5,10-dione, C14H4O2S4
  51. The crystal structure of dimethyl 2,2ʹ-((adamantane-1,3-diylbis(4,1-phenylene)) bis(oxy))diacetate, C28H32O6
  52. The crystal structure of N-(6-chloro-2-methyl-2H-indazol-5-yl)acetamide, C10H10ClN3O
  53. Crystal structure of triaqua-(5-bromoisophthalato-κ1 O)-(2,2′-bipyridine-κ2 N:N′)nickel(II) hydrate, C18H19BrN2NiO8
  54. The crystal structure of 2-amino-4-carboxypyridin-1-ium perchlorate, C6H7ClN2O6
  55. The crystal structure of catena-poly[5-aminonicotinic acid-k1 N-m2-bromido-copper(I)], Cu(C6N2H6O2)Br
  56. The crystal structure of 2,2-bis(3-methoxyphenyl)-1-tosyl-1,2-dihydro- 2λ4,3λ4  -[1,3,2]diazaborolo[4,5,1-ij]quinoline - dichloromethane (1/1)
  57. The crystal structure of catena-poly[bis(6-phenylpyridine-2-carboxylato-κ2 N,O)-(μ2-4,4′-bipyridne-κ2 N:N)cadmium(II)], C34H24N4O4Cd
  58. The crystal structure of 5,7-dinitropyrazolo[5,1-b]quinazolin-9(4H)-one, C10H5N5O5
  59. Crystal structure of rac-1,8-bis(2-carbamoylethyl)-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, C22H46N6O2
  60. The crystal structure of (E)-N ′-(2-bromobenzylidene)-2-naphthohydrazide, C36H26Br2N4O2
  61. The crystal structure of 5-nitronaphthoquinone, C10H5NO4
  62. The crystal structure of (S, R p )-4–benzhydrylideneamino-12-(4-tert-butyl oxazolin-2-yl)[2.2]paracyclophane, C36H36N2O
  63. Synthesis and crystal structure of 2-(2-oxo-2-(o-tolyl)ethyl)-4H-chromen-4-one, C18H14O3
  64. Crystal structure of 2-(thiazol-2-yl)hexahydro-1H-4,7-epoxyisoindole-1,3(2H)-dione, C11H10N2O3S
  65. Crystal structure of N-(diaminomethylene)-1-(dimethylamino)-1-iminiomethanaminium dichloride, C4H13Cl2N5
  66. Crystal structure of poly[(μ3-3, 5-dichloro-2-hydroxy-benzoato-κ4 Cl,O:O′:O″) silver(I)], C7H3AgCl2O3
  67. The crystal structure of tetrakis(1-isopropylimidazole-κ1 N)-[μ2- imidazole-4,5-dicarboxylato-κ4 O,N,O′,N′)]- trioxido-divanadium, C29H41N10O7V2
  68. Crystal structure of catena-[(μ3-bromido)-(1H-1,2,4-triazol-1-yl)benzoato-κ1 N)copper(I)], C9H7BrCuN3O2
  69. The crystal structure of (E)-4-fluoro-N′-(1-(2-hydroxyphenyl)propylidene)benzohydrazide, C16H15FN2O2
https://doi.org/10.1515/ncrs-2023-0164
Creative Commons
BY 4.0

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of a polymorph of potassium picrate, C6H2KN3O7
  4. The crystal structure of (1E,2E)-1,2-bis(quinolin-2-ylmethylene)hydrazine, C20H14N4
  5. 5-Amino-2-chloro-4-fluoro-N-(N-isopropyl-N-methylsulfamoyl) benzamide, C11H15O3ClFN3S
  6. Crystal structure of trans-N 1,N 8-bis(2-cyanoethyl)-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, C22H42N6
  7. The crystal structure of [N-{[2-(oxy)-4-methoxyphenyl](phenyl)methylidene}alaninato]-diphenyl-silicon(IV) – chloroform (1/1), C29H25NO4Si·CHCl3
  8. Crystal structure of tetracarbonyl-{μ-[N-(diphenylphosphanyl)-N,P,P-triphenylphosphinous amide]}-bis[μ-(phenylmethanethiolato)]diiron (Fe–Fe), C48H39Fe2NO4P2S2
  9. Crystal structure of baryte from Mine du Pradet (France)
  10. The crystal structure of [(2,2′-bipyridine-6-carboxylato-κ3 N,N,O)-(6-phenylpyridine-2-carboxylate-κ2 N,O)copper(II)] monohydrate, C23H17N3O5Cu
  11. Crystal structure of bis(μ-benzeneselenolato)-(μ-[N-benzyl-N-(diphenylphosphanyl)-P,P-diphenylphosphinous amide])-tetracarbonyl diiron (Fe–Fe), C47H37Fe2NO4P2Se2
  12. The crystal structure of diaqua-methanol-κ1 O- (3-thiophenecarboxylato-κO)-(2,2′-dipyridyl-κ2 N,N′)manganese(II) 3-thiophenecarboxylate, C21H22N2O7S2Mn
  13. Crystal structure of catena-poly[tetrakis(butyl)-μ2-2-((oxido(phenyl)methylene)hydrazineylidene)propanoato-κ4 O:O,O′,N-μ2-2-((oxido(phenyl)methylene)hydrazineylidene)propanoato-κ4 O,N,O′:N′-ditin(IV)], C34H50N6O6Sn2
  14. Crystal structure of 4-chloro-N′-[(1E)-(2-nitrophenyl)methylidene]benzohydrazide, C14H10ClN3O3
  15. The crystal structure of 3-(1′-deoxy-3′,5′-O-dibenzy-β-d-ribosyl)adenine dichloromethane solvate, C49H52Cl2N10O6
  16. The crystal structure of (Z)-4-amino-N′-(1-(o-tolyl)ethylidene)benzohydrazide, C16H17N3O
  17. The co-crystal structure of etoricoxib–phthalic acid (1/1), C18H15ClN2O2S·C8H6O4
  18. Crystal structure of (glycinto-κ 2 O,N ′)-[5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ 4 N,N ′,N ″,N ‴]nickel(II) perchlorate monohydrate C18H42ClN5NiO7
  19. The crystal structure of catena-poly[bis(1-ethylimidazole-k1 N)-(μ 2-benzene-1-carboxyl-3,5-dicarboxylato-κ 2 O, O′)zinc(II)], C19H20N4O6Zn
  20. Crystal structure of 3-(thiazol-2-ylcarbamoyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid, C11H12N2O4S
  21. Rietveld structure analysis of keatite, a rare, metastable SiO2 polymorph
  22. Crystal structure of catena-poly[(μ2-isophthalato-k3 O,O′:O″)(4-(4-pyridyl)-2,5-dipyrazylpyridine-k3 N,N′,N″)cobalt(II)] trihydrate C26H22N6O7Co1
  23. Crystal structure of 3,5–di-O-benzoyl-1,2-O-isopropylidene-α–D-ribose, C22H22O7
  24. The crystal structure of fac-tricarbonyl(6-bromo-2,2-bipyridine-κ2 N,N)-(nitrato-κO)rhenium(I), C13H7BrN3O6Re
  25. The crystal structure of (E)-N′-(4-hydroxy-3-methoxybenzylidene)-2-naphthohydrazide monohydrate, C19H18N2O4
  26. The crystal structure of 5,5′-diselanediyl-bis(2-hydroxybenzaldehyde), C14H10O4Se2
  27. The crystal structure of catena-poly[diaqua-m2-dicyanido-κ2 C:N-dicyanido-κ1 C-bis(4-(pyridin-4-yl)benzaldehyde-κ1N)iron(II)-platinum(II), C28H22N6O4PtFe
  28. Redetermination of the crystal structure of 5,14-dihydro-6,17-dimethyl-8,15-diphenyldibenzo(b,i)(1,4,8,11)tetra-azacyclotetradecine, C32H28N4
  29. Crystal structure of poly[(μ3-2-(3,5-dicarboxyphenyl) benzimidazole-6-carboxylato-κ4O:O:O′:O″)lead(II)] monohydrate, C16H10N2O7Pb
  30. The crystal structure of fac-tricarbonyl(2-pyridin-2-yl-quinoline-κ2 N,N′)-(pyrazole-κN)rhenium(I)nitrate, C20H14N4O3ReNO3
  31. Crystal structure of dibromo-dicarbonyl-bis(tricyclohexylphosphine)-osmium(II) dichloromethane solvate, C38H66Br2O2OsP2
  32. Crystal structure of poly[bis(μ 2-2,6-bis(1-imidazoly)pyridine-κ 2 N:N′)copper(II)] diperchlorate dihydrate, C22H22Cl2CuN10O10
  33. The crystal structure of fac-tricarbonyl(N-benzoyl-N,N-cyclohexylmethylcarbamimidothioato-κ2 S,O)-(pyridine-κN)rhenium(I), C23H24N3O4ReS
  34. Crystal structure of (E)-7-fluoro-2-(4-fluorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C17H12F2O
  35. Synthesis and crystal structure of 1-((3R,10S,13S, 17S)-3-((2-methoxyphenyl)amino)-10,13-dimethylhexadecahydro-1H-cyclopenta[α]phenanthren-17-yl)ethan-1-one, C28H41NO2
  36. The crystal structure of fac-tricarbonyl((pyridin-2-yl)methanamino-κ2 N,N′)-((pyridin-2-yl)methanamino-κN)rhenium(I) nitrate, C15H16O3N4Re
  37. The crystal structure of (1-(pyridin-2-yl)-N-(pyridin-2-ylmethyl)-N-((1-(4-vinylbenzyl)-1H-benzo[d]imidazol-2-yl)methyl)methanamine-κ 4 N,N′,N″,N‴)tris(nitrato-kO,O′)-erbium(III), C29H27ErN8O9
  38. Crystal structure of tetracene-5,12-dione, C18H10O2
  39. Crystal structure of (3R,3aS,6R,6aR)-6-hexyl-3-methyltetrahydrofuro[3,4-b]furan-2,4-dione, C13H20O4
  40. The crystal structure of N′1,N′3-bis((E)-thiophen-2-ylmethylene)isophthalohydrazide monohydrate, C18H16N4O3S2
  41. Crystal structure of methyl ((4-aminobenzyl)sulfonyl)-L-prolinate, C13H18N2O4S
  42. Crystal structure of (E)-3-(3-methoxybenzylidene)benzofuran-2(3H)-one, C16H12O3
  43. Synthesis and crystal structure (E)-1-(4-bromo-2-hydroxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C11H12BrNO2
  44. Synthesis and crystal structure of (S,E)-4-hydroxy-3-(2-((4aR,6aS,7R,10aS,10bR)-3,3,6a,10b-tetramethyl-8-methylenedecahydro-1H-naphtho[2,1-d][1,3]dioxin-7-yl)ethylidene)dihydrofuran-2(3H)-one, C23H34O5
  45. The crystal structure of N,N′-(1,2-phenylene)bis (2-((2-oxopropyl)selanyl)benzamide), C26H24N2O4Se2
  46. The crystal structure of 1-ethyl-2-nitro-imidazole oxide, C5H7N3O3
  47. The crystal structure of 2-(2-fluorophenyl)naphtho[2,1-d]thiazole, C17H10FNS
  48. Crystal structure of (E)-2,4-di-tert-butyl-6-(((2-fluorophenyl)imino) methyl)phenol, C21H26FNO
  49. Synthesis and crystal structure of 3-methyl-2-(methylthio)-4H-chromen-4-one, C12H12O2S
  50. Crystal structure of dithieno[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene-5,10-dione, C14H4O2S4
  51. The crystal structure of dimethyl 2,2ʹ-((adamantane-1,3-diylbis(4,1-phenylene)) bis(oxy))diacetate, C28H32O6
  52. The crystal structure of N-(6-chloro-2-methyl-2H-indazol-5-yl)acetamide, C10H10ClN3O
  53. Crystal structure of triaqua-(5-bromoisophthalato-κ1 O)-(2,2′-bipyridine-κ2 N:N′)nickel(II) hydrate, C18H19BrN2NiO8
  54. The crystal structure of 2-amino-4-carboxypyridin-1-ium perchlorate, C6H7ClN2O6
  55. The crystal structure of catena-poly[5-aminonicotinic acid-k1 N-m2-bromido-copper(I)], Cu(C6N2H6O2)Br
  56. The crystal structure of 2,2-bis(3-methoxyphenyl)-1-tosyl-1,2-dihydro- 2λ4,3λ4  -[1,3,2]diazaborolo[4,5,1-ij]quinoline - dichloromethane (1/1)
  57. The crystal structure of catena-poly[bis(6-phenylpyridine-2-carboxylato-κ2 N,O)-(μ2-4,4′-bipyridne-κ2 N:N)cadmium(II)], C34H24N4O4Cd
  58. The crystal structure of 5,7-dinitropyrazolo[5,1-b]quinazolin-9(4H)-one, C10H5N5O5
  59. Crystal structure of rac-1,8-bis(2-carbamoylethyl)-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, C22H46N6O2
  60. The crystal structure of (E)-N ′-(2-bromobenzylidene)-2-naphthohydrazide, C36H26Br2N4O2
  61. The crystal structure of 5-nitronaphthoquinone, C10H5NO4
  62. The crystal structure of (S, R p )-4–benzhydrylideneamino-12-(4-tert-butyl oxazolin-2-yl)[2.2]paracyclophane, C36H36N2O
  63. Synthesis and crystal structure of 2-(2-oxo-2-(o-tolyl)ethyl)-4H-chromen-4-one, C18H14O3
  64. Crystal structure of 2-(thiazol-2-yl)hexahydro-1H-4,7-epoxyisoindole-1,3(2H)-dione, C11H10N2O3S
  65. Crystal structure of N-(diaminomethylene)-1-(dimethylamino)-1-iminiomethanaminium dichloride, C4H13Cl2N5
  66. Crystal structure of poly[(μ3-3, 5-dichloro-2-hydroxy-benzoato-κ4 Cl,O:O′:O″) silver(I)], C7H3AgCl2O3
  67. The crystal structure of tetrakis(1-isopropylimidazole-κ1 N)-[μ2- imidazole-4,5-dicarboxylato-κ4 O,N,O′,N′)]- trioxido-divanadium, C29H41N10O7V2
  68. Crystal structure of catena-[(μ3-bromido)-(1H-1,2,4-triazol-1-yl)benzoato-κ1 N)copper(I)], C9H7BrCuN3O2
  69. The crystal structure of (E)-4-fluoro-N′-(1-(2-hydroxyphenyl)propylidene)benzohydrazide, C16H15FN2O2
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 10.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2023-0164/html
Button zum nach oben scrollen