Startseite Crystal structure of catena-poly[(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(4-bromobenzoate-κ2O:O′)-(μ-2-bromobenzoate-κ2O,O′)nickel(II)] – water (2/1), C30H21Br2N2NiO4.5
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Crystal structure of catena-poly[(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(4-bromobenzoate-κ2O:O′)-(μ-2-bromobenzoate-κ2O,O′)nickel(II)] – water (2/1), C30H21Br2N2NiO4.5

  • Xiaobo Bao und Chongchong Tian ORCID logo EMAIL logo
Veröffentlicht/Copyright: 11. September 2023
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 238 Heft 6

Abstract

C30H21Br2N2NiO4.5, triclinic, P 1 ‾ (no. 2), a = 8.7895(17) Å, b = 13.167(3) Å, c = 14.067(3) Å, α = 109.049(3)°, β = 92.619(3)°, γ = 108.533(3)°, V = 1438.6(5) Å3, Z = 2, R gt (F) = 0.0496, wR ref (F2) = 0.1003, T = 296(2) K.

CCDC no.: 2289678

A part of the title crystal structure is shown in the figure (the solvent water molecule and the disordered Br atom were omitted in the figure for clarity). Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Green block
Size: 0.20 × 0.18 × 0.15 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 3.49 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω
θmax, completeness: 25.0°, 99 %
N(hkl)measured, N(hkl)unique, Rint: 7392, 5043, 0.035
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 3172
N(param)refined: 371
Programs: Bruker [1], SHELX [2]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
Br1 0.62597 (11) 0.50233 (7) 0.69669 (6) 0.1071 (3)
Br2a 1.3167 (6) 1.2065 (5) −0.0047 (4) 0.0800 (11)
Br2Bb 1.3320 (18) 1.181 (2) −0.0107 (8) 0.112 (3)
Ni1 0.66499 (7) 0.99945 (5) 0.39093 (4) 0.02806 (17)
O1 0.6600 (3) 0.8845 (2) 0.4581 (2) 0.0353 (7)
O2 0.5307 (3) 0.9480 (2) 0.5850 (2) 0.0370 (7)
O3 0.8699 (3) 0.9865 (2) 0.3180 (2) 0.0366 (8)
O4 0.7440 (4) 1.0977 (3) 0.2946 (2) 0.0403 (8)
N1 0.5128 (4) 0.8612 (3) 0.2650 (2) 0.0296 (8)
N2 −0.1841 (4) 0.1361 (3) −0.4819 (2) 0.0340 (9)
C1 0.5972 (5) 0.8811 (4) 0.5368 (3) 0.0306 (10)
C2 0.6081 (5) 0.7894 (4) 0.5761 (3) 0.0320 (11)
C3 0.6993 (7) 0.7234 (4) 0.5360 (4) 0.0592 (15)
H3 0.756521 0.735655 0.484399 0.071*
C4 0.7066 (8) 0.6379 (5) 0.5721 (5) 0.0804 (19)
H4 0.769809 0.593907 0.545722 0.096*
C5 0.6188 (7) 0.6197 (5) 0.6474 (4) 0.0641 (16)
C6 0.5264 (6) 0.6833 (4) 0.6872 (4) 0.0551 (14)
H6 0.467107 0.669824 0.737669 0.066*
C7 0.5222 (6) 0.7680 (4) 0.6515 (3) 0.0437 (12)
H7 0.459730 0.812201 0.678919 0.052*
C8 0.8556 (5) 1.0561 (4) 0.2788 (3) 0.0340 (11)
C9 0.9698 (5) 1.0897 (4) 0.2084 (3) 0.0381 (12)
C10 1.0818 (6) 1.0360 (4) 0.1787 (4) 0.0536 (14)
H10 1.087833 0.979154 0.202716 0.064*
C11 1.1858 (6) 1.0677 (5) 0.1125 (4) 0.0632 (16)
H11 1.260133 1.031541 0.091387 0.076*
C12 1.1758 (6) 1.1533 (5) 0.0793 (4) 0.0559 (15)
C13 1.0684 (7) 1.2072 (5) 0.1095 (4) 0.0727 (18)
H13 1.064184 1.265173 0.086688 0.087*
C14 0.9654 (7) 1.1757 (5) 0.1743 (4) 0.0617 (16)
H14 0.892292 1.213002 0.195225 0.074*
C15 0.3997 (5) 0.8716 (4) 0.2055 (3) 0.0403 (12)
H15 0.381043 0.940653 0.225401 0.048*
C16 0.3093 (6) 0.7854 (4) 0.1162 (3) 0.0443 (13)
H16 0.233699 0.797591 0.076935 0.053*
C17 0.3315 (5) 0.6796 (4) 0.0848 (3) 0.0328 (11)
C18 0.4456 (5) 0.6683 (4) 0.1477 (3) 0.0336 (11)
H18 0.464696 0.599522 0.130885 0.040*
C19 0.5316 (5) 0.7597 (3) 0.2359 (3) 0.0327 (11)
H19 0.606759 0.749497 0.277199 0.039*
C20 0.2453 (5) 0.5857 (4) −0.0141 (3) 0.0348 (11)
C21 0.2066 (6) 0.6111 (4) −0.0983 (3) 0.0506 (14)
H21 0.234102 0.687367 −0.092786 0.061*
C22 0.1276 (6) 0.5243 (4) −0.1906 (3) 0.0507 (14)
H22 0.103719 0.543022 −0.246348 0.061*
C23 0.0834 (5) 0.4098 (4) −0.2011 (3) 0.0360 (11)
C24 0.1225 (6) 0.3853 (4) −0.1170 (3) 0.0442 (13)
H24 0.095027 0.309123 −0.122518 0.053*
C25 0.2016 (6) 0.4716 (4) −0.0246 (3) 0.0437 (13)
H25 0.225625 0.452561 0.030987 0.052*
C26 −0.0048 (5) 0.3159 (4) −0.3004 (3) 0.0340 (11)
C27 −0.1010 (6) 0.3328 (4) −0.3706 (4) 0.0533 (15)
H27 −0.107315 0.405048 −0.358468 0.064*
C28 −0.1878 (6) 0.2414 (4) −0.4592 (3) 0.0499 (14)
H28 −0.251808 0.254715 −0.505036 0.060*
C29 −0.0862 (5) 0.1205 (4) −0.4162 (3) 0.0348 (11)
H29 −0.077952 0.048372 −0.431793 0.042*
C30 0.0027 (5) 0.2067 (4) −0.3265 (3) 0.0367 (11)
H30 0.068199 0.191472 −0.283113 0.044*
O1Wc 0.5906 (16) 0.0915 (12) 0.0938 (11) 0.202 (6)
H1Ac 0.623260 0.083495 0.145620 0.302*
H1Bc 0.511424 0.112166 0.096330 0.302*

  1. aOccupancy: 0.65 (3), bOccupancy: 0.35 (3), cOccupancy: 0.5.

1 Source of material

A mixture of Ni(NO3)2·6H2O (1 mmol, 290.8 mg), 1,4-di(pyridin-4-yl)benzene (dpb) (1 mmol, 232.3 mg), 4-bromobenzoic acid (Hbba) (2 mmol, 402.0 mg), N, N-dimethylacetamide (1 mL) and H2O (3 mL) were sealed in a 25 mL vial and heated at 393 K for three days. Green block crystals were collected.

2 Experimental details

The C-bound H atoms were placed in idealized positions (C–H = 0.93 Å) and refined by the riding model with Uiso(H) = 1.2 Ueq(C). The O-bound H atoms were refined with restrained bond lengths (O–H = 0.82 Å). The Uiso(H) = 1.5 Ueq(O). One Br atom is disordered over two positions. The two parts overlapped each other with site occupation factors of 0.65 and 0.35.

3 Comment

As a halogenobenzoic acid, 4-bromobenzoic acid was widely used as organic ligand to construct various metal coordination polymers [3], [4], [5], [6], [7], [8], [9]. However, the Ni(II) coordination polymers based on 4-bromobenzoic acid were rarely reported. From the Cambridge Structural Database (Version 5.44, April 2023), only three structures of Ni(II) coordination polymers were found [10], [11], [12]. To further explore this research area, we chose 4-bromobenzoic acid (bbaH) as the organic ligand and the rigid N-containing ligand of 1,4-di(pyridin-4-yl)benzene (dpb) as the auxiliary bridging ligand [13] to generate a new Ni(II) coordination polymer.

The asymmetric unit consists of one Ni(II) cation, one dpb ligand, two bba− ligands and one half of a free water solvent. The bond distances of Ni–O/N (2.020(3)–2.157(3) Å) are all in normal ranges and the bond angles around Ni(II) cation vary from 61.27(1)° to 179.18(14)°. The Ni(II) cation is six coordinated by four O atoms from three bba− ligands and two N atoms from two symmetry related dpb ligands to furnish a distorted octahedral coordination geometry. The deprotonated bba− ligands adopt a bidentate chelate mode and a bidentate bridging mode, to link the neighboring Ni(II) cations forming a Ni2(COO)4 subunit (see the figure).

Corresponding author: Chongchong Tian, College of Pharmacy, Jiangsu Vocational College of Medicine, 224005, Yancheng, Jiangsu, People’s Republic of China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: Natural Science Foundation of the Jiangsu Higher Education Institutions of China (18KJB320004).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. APEX2, SAINT and SADABS; Bruker AXS Inc.: Madison, Wisconsin, USA, 2008.Suche in Google Scholar

2. Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Suche in Google Scholar PubMed

3. Bai, X., Xing, Y., Liu, S. Crystal structure of catena-poly[(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-κ2N:N′)-bis(4-bromobenzoate-κ1O)zinc(II)], C64H44Br4N8O8Zn2. Z. Kristallogr. N. Cryst. Struct. 2022, 237, 149–151; https://doi.org/10.1515/ncrs-2021-0413.Suche in Google Scholar

4. Zhuo, X. Crystal structure of catena-poly[(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-κ2N:N′)-bis(4-bromobenzoate-κ1O)cobalt(II)], C32H22Br2CoN4O4. Z. Kristallogr. N. Cryst. Struct. 2022, 237, 399–401; https://doi.org/10.1515/ncrs-2022-0035.Suche in Google Scholar

5. Yang, X., Luo, Y. Crystal structure of catena-poly[(μ2-4,4′-bipyridine-κ2N:N′)-bis(4-bromobenzoate-κ1O)zinc(II)], C24H16Br2N2O4Zn. Z. Kristallogr. N. Cryst. Struct. 2022, 237, 833–835; https://doi.org/10.1515/ncrs-2022-0122.Suche in Google Scholar

6. Akintayo, D. C., Munzeiwa, W. A., Jonnalagadda, S. B., Omondi, B. Zn(II) pyridinyl amine complexes, synthesis and crystal structure studies: a comparative study of the effect of nuclearity and benzoate type on the ring-opening polymerization of cyclic esters. Polyhedron 2022, 213, 115589; https://doi.org/10.1016/j.poly.2021.115589.Suche in Google Scholar

7. Yao, H., Calvez, G., Daiguebonne, C., Suffren, Y., Bernot, K., Roisnel, T., Guillou, O. Synthesis, crystal structure, and luminescence properties of the iso-reticular series of lanthanide coordination polymers synthesized from hexa-lanthanide molecular precursors. Inorg. Chem. 2022, 61, 4895–4908; https://doi.org/10.1021/acs.inorgchem.1c03654.Suche in Google Scholar PubMed

8. Ridenour, J. A., Schofield, M. H., Cahill, C. L. Structural and computational investigation of halogen bonding effects on spectroscopic properties within a series of halogenated uranyl benzoates. Cryst. Growth Des. 2020, 20, 1311–1318; https://doi.org/10.1021/acs.cgd.9b01567.Suche in Google Scholar

9. Ridenour, J. A., Carter, K. P., Butcher, R. J., Cahill, C. L. RE-p-halobenzoic acid-terpyridine complexes, Part II: structural diversity, supramolecular assembly, and luminescence properties in a series of p-bromobenzoic acid rare-earth hybrid materials. CrystEngComm 2017, 19, 1172–1189; https://doi.org/10.1039/c6ce02355j.Suche in Google Scholar

10. Zhang, Y., Lv, R., Wang, J., Yang, L., Liao, S., Tian, J., Gu, W., Liu, X. Two novel μ6–O2− bridged Co14/Ni14 hydroxamate clusters packed in distorted face-centered cubic patterns. Dalton Trans. 2016, 45, 3247–3250; https://doi.org/10.1039/c5dt03974f.Suche in Google Scholar PubMed

11. Sekiya, R., Nishikiori, S. Synthesis, X-ray crystal structures and inclusion properties of a hydrogen-bonded coordination polymer [Ni(SCN)2(pppeH)2]·(guest)x. CrystEngComm 2011, 13, 6405–6414; https://doi.org/10.1039/c1ce05566f.Suche in Google Scholar

12. Wang, X., Zhang, J., Hou, J., Zhang, J., Liu, G., Lin, H. Three new complexes based on a flexible bis(benzimidazole) ligand and rigid/flexible organic carboxylates. J. Chem. Crystallogr. 2011, 41, 1579–1585; https://doi.org/10.1007/s10870-011-0143-2.Suche in Google Scholar

13. Shi-Jun, C., Shi-Hui, L., Yan, Z. Crystal structure of catena-poly[triaqua-(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(3′,5-dicarboxy-[1,1′-biphenyl]-3,4′-dicarboxylato-κO)nickel(II)]. Z. Kristallogr. N. Cryst. Struct. 2020, 235, 1119–1121. https://doi.org/10.1515/ncrs-2020-0196.Suche in Google Scholar
Received: 2023-06-11
Accepted: 2023-08-20
Published Online: 2023-09-11
Published in Print: 2023-12-15

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of bis(dimethylammonium) poly[(μ4-1,1′-(1,4-phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato))-κ6O1, N2:O2:O3:O1′,N2′]nickel (II)], C22H26N6NiO8
  4. Hydrothermal synthesis and crystal structure of catena-poly[diaqua-bis(μ2-4-((pyridin-4-ylmethyl)amino)benzoato-κ2N:O)cobalt(II)] – 4,4′-bipyridine – water (1/2/2)
  5. Crystal structure of (2S,3S,4S,5S, Z)-2,3,5,6-tetrakis(benzyloxy)-4-hydroxyhexanal oxime, C34H37NO6
  6. The crystal structure of hexakis(3-thiophenecarboxylato-κ2O,O″)-bis(1,10-phenanthroline-κ2N,N′) trimanganese(II), C54H34N4O12S6Mn3
  7. Crystal structure of catena-poly[(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(4-bromobenzoate-κ2O:O′)-(μ-2-bromobenzoate-κ2O,O′)nickel(II)] – water (2/1), C30H21Br2N2NiO4.5
  8. The crystal structure of poly[(μ3-1,3-phenylenedioxydiacetate-κ5O,O,O′,O″,O‴)-bis(4′-(4-(1H-imidazol-1-yl)phenyl)-4,2′:6′,4″-terpyridine-kN) cadmium(II)], C58H42CdN10O6
  9. The crystal structure of 5-chloro-6′-methyl-3-(4-(methylsulfonyl)phenyl)-[2,3′-bipyridin]-1′-ium 4-methylbenzenesulfonate
  10. Crystal structure of poly[(μ-benzoato)-(μ-cis-4–hydroxy-D-proline)lithium], C12H14LiNO5
  11. The crystal structure of catena-poly[aqua-(4-iodopyridine-2,6-dicarboxylato-κ3N,O,O′)-copper(II)] monohydrate, C7H6NO6ICu
  12. The crystal structure of catena-[diaqua-(4-acetylphenoxyacetato-κ2O,O)-bis(4-acetylphenoxyacetato-κ3O,O:O)-dihydrate-lanthanum(III)]–4,4′-bipyridine (2/1), C35H35NO14La
  13. The crystal structure of catena-poly[(4-iodopyridine-2,6-dicarboxylato-κ4 O,N,O′,O′′)(4-imidazol-1-yl-pyridine-κN)copper(II)], C15H9N4O4ICu
  14. Crystal structure of polybis(μ 4-3,5-dicarboxylatopyrazol-1-yl)-bis(N,N-dimethylformamide)tri-copper(II)–acetonitrile (1/2), C20H22Cu3N8O10
  15. Crystal structure of poly[(μ2-5-hydroxy-isophthalato-κ4O,O′:O″,O‴)-(μ2-1,5-bis(imidazol-2-methyl)pentane-κ2N:N′)cadmium(II)], C21H24CdN4O5
  16. The crystal structure of poly[bis(μ2-1,4-bi(1-imidazolyl)benzene-κ2N:N′)bis(μ2-4,4′-methylenebis(3-hydroxy-2-naphthoate)-κ2O:O′)cobalt(II)], C35H24CoN4O6
  17. The crystal structure of a cobalt-vanadium-oxido hydrate
  18. The crystal structure of catena-poly[(μ 2-2H-1,2,3-triazole-4,5-dicarboxylato-κ 2 O, O′)-(μ 2-1,3-bis((1H-imidazol-1-yl)methyl)benzene-κ 2 N,N′) zinc(II)], C18H15N7O4Zn
  19. Crystal structure of poly[diaqua-(bis(m2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′-manganese] dichloride, C28H32MnN8O2Cl2
  20. The crystal structure of 9,10-dimethoxy-5,6-dihydro-[1,3]dioxolo[4,5-g]isoquinolino [3,2-a]isoquinolin-7-ium (E)-3-(4-nitrophenyl)acrylate pentahydrate, C29H34N2O13
  21. Crystal structure of poly[(μ6-ammoniotris(methylene))tris(hydrogen phosphonato)cadmium(II)], C3H10CdNO9P3
  22. Crystal structure of Zn2[(1,1′-(hexane-1,6-diyl)bis(3-(pyridin-3-yl)urea))·(H2O)2·(DMF)2·(SO4)2], C24H50N8O18S2Zn2
  23. The crystal structure of 2-anilino-1,4-naphthoquinone, C10H11NO2
  24. Crystal structure of (E)-2-(2-(4-(diethylamino)styryl)-1-ethyl-1,4-dihydroquinolin-4-yl) malononitrile, C26H26N4
  25. Crystal structure of ethyl 2-((2,6-dichloro-4-(cyanomethyl)phenyl) amino)benzoate, C17H14Cl2N2O2
  26. Synthesis and crystal structure of 2-(3-oxo-3-phenylpropyl)isoindoline-1,3-dione, C17H13NO3
  27. The crystal structure of bis(acetonitrile-κ1N)tetrakis(μ2-2,6-difluorobenzoato-κ2O:O′)rhodium(II) (Rh–Rh), C32H18F8O8N2Rh2
  28. The crystal structure of a new polymorph of 6-hydroxy-2-naphthoic acid, C11H8O3
  29. The crystal structure of [(8-carboxymethoxy-quinoline-2-carboxylate-κ4N,O,O,O)-2,2′-bipyridine-κ2N-copper(II)] tetrahydrate, C22H23N3O9Cu
  30. The crystal structure of ethyl 4-hydroxy-2-(4-methoxyphenyl)-5-oxo-1-(2-oxo-2H-chromen-6-yl)-2,5-dihydro-1H-pyrrole-3-carboxylate, C23H19NO7
  31. Crystal structure of 7-hydroxy-3,4-dihydronaphthalen-1(2H)-one, C10H10O2
  32. Crystal structure of bis(tetrapropylammonium) dodecacarbonyltetratelluridotetraferrate(2-), (Pr4N)2[Fe4Te4(CO)12]
  33. The crystal structure of poly[bis(μ2−3−aminopyridine−4−carboxylato−κ2N:O)Zinc(II)], [Zn(C6H5N2O2)2] n
  34. The crystal structure of methyl 5-nitro-2-(tosyloxy)benzoate, C15H13NO7S
  35. The crystal structure of 18-crown-6 ― tetraaqua-dichlorido-di-μ2-chloridodicopper(II) (2/1), C12H32O10Cu2Cl4
  36. Crystal structure of 6,6a,7,8,9,10-hexahydro-5H-pyrazino [2,3-e]pyrido[1,2-a]pyrazine, C10H14N4
  37. Crystal structure of catena-poly-{diaqua-bis[μ-(((4-chlorophenyl)sulfonyl)glycinato-κO)](μ2-4, 4′-bipyridine-κ2N:N′)cobalt(II)} dihydrate, C26H30Cl2CoN4O12S2
  38. Crystal structure of bis{N′-[1,3-diphenylprop-2-en-1-ylidene]-N-phenylcarbamohydrazonothioato}zinc(II), C44H36N6S2Zn
  39. Crystal structure of tetraaqua-bis(((4-chlorophenyl)sulfonyl)glycinato-κO)cobalt(II) dihydrate, C16H26Cl2CoN2O14S2
  40. Crystal structure of 2-(5-phenyl-1-(quinolin-2-yl)-4,5-dihydro-1H-pyrazol-3-yl)phenol, C24H19N3O
  41. Crystal structure of 2-((2-fluoro-4-(trifluoromethyl)phenyl)(hydroxy)methyl)-7-methoxy-3,4-dihydronaphthalen-1((2H))-one, C19H16F4O3
  42. Crystal structure of 2-amino-4-(2-fluoro-3-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  43. Crystal structure of (2-phenylimino methylquinoline-κ 2 N,N′)-bis(1–phenylpyrazole-κ 2 C,N)-iridium(III) hexafluorophosphate, C34H26F6IrN6P
  44. Crystal structure of (3-hydroxy-4-methoxyphenyl)(pyrrolidin-1-yl)methanone, C12H15NO3
  45. The crystal structure of bis(trimethylsulfoxonium) catena-poly[µ2-hexabromido-indium(III)sodium(I)] C6H18O2S2NaInBr6
  46. Crystal structure of N-cyclopropyl-3-hydroxy-4-methoxybenzamide, C11H13NO3
  47. The crystal structure of (bis(benzimidazol-2-yl-methyl)amine-κ3N,N′,N″ )-(dihydrogen L-malate-κ2O,O ′)copper(II) perchlorate dihydrate, CuC20H24ClN5O12
  48. Crystal structure of (1E,1′E)-4,4′-(9,9-diethyl-9H-fluorene-2,7-diyl)dibenzaldehyde dioxime, C31H28N2O2
  49. Crystal structure of diethyl 1,9-bis(4-fluorophenyl)-4,6-diphenylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta [b]pyridine-3,7(2H)-dicarboxylate, C40H36F2N2O4
  50. Crystal structure of bis(benzene-1 carboxylato-O 3,5-carboxyl-κ1O)-[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) ─ benzene-1,3,5-tricarboxylic acid ─ water (1/2/4), C52H66N4NiO28
  51. Crystal structure of 1,4-dibromo-2,5-bis(2-methoxyethoxy)benzene-1,4-diol, C12H16Br2O4
  52. Crystal structure of dicarbonyl[N,N′-(1,2-dimethyl-1,2-ethanediylidene)bis[2,6-bis(1-methylethyl)benzenamine]-N,N′]nickel(0), C30H40N2NiO2
  53. Crystal structure of 1,4-dibromo-2,5-bis(prop-2-yn-1-yloxy)benzene, C12H8Br2O2
  54. Crystal structure of O-(3-(benzo[d]thiazol-2-yl)naphthalen-2-yl) O-phenyl carbonothioate, C24H15NO2S2
  55. The crystal structure of (E)-4-fluoro-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H15FN2O2
  56. Crystal structure of (E)-1-(benzo[d]thiazol-2-yl)-N-(4,5-dihydropyren-2-yl)methanimine, C24H16N2S
  57. Crystal structure of 3-((4-bromophenyl)thio)-1H-indole, C14H10BrNS
  58. Synthesis and crystal structure of 1-((7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carboxylate monohydrate, C22H22N2O9
  59. Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α]phenanthren-3-one O-(methacryloyl) oxime, C50H74N2O4
  60. Crystal structure of the hydrogen storage active phase La12Mg46LiMn
  61. The crystal structure of the salt: 4-((1,3-dioxoisoindolin-2-yl)carbamoyl)pyridine-1-ium 2-carboxybenzoate, C14H10N3O3·C8H5O4
  62. Crystal structure of (2-(2-pyridine)-benzimidazole-κ2 N,N′)-bis(1-phenylpyrazole-κ2 C,N)iridium(III) hexafluorophosphate, C30H22F6IrN7P
  63. Crystal structure of dichlorido-bis[2-(2,4-difluorophenyl)pyridine-κ1N]platinum(II), C22H14Cl2F4N2Pt
  64. Crystal structure of (5R,8R,9R,10R,12R,13R,14R, 17S,17Z)-2-((3-fluoropyridin-4-yl)methylene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C36H52FNO3
https://doi.org/10.1515/ncrs-2023-0276
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of bis(dimethylammonium) poly[(μ4-1,1′-(1,4-phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato))-κ6O1, N2:O2:O3:O1′,N2′]nickel (II)], C22H26N6NiO8
  4. Hydrothermal synthesis and crystal structure of catena-poly[diaqua-bis(μ2-4-((pyridin-4-ylmethyl)amino)benzoato-κ2N:O)cobalt(II)] – 4,4′-bipyridine – water (1/2/2)
  5. Crystal structure of (2S,3S,4S,5S, Z)-2,3,5,6-tetrakis(benzyloxy)-4-hydroxyhexanal oxime, C34H37NO6
  6. The crystal structure of hexakis(3-thiophenecarboxylato-κ2O,O″)-bis(1,10-phenanthroline-κ2N,N′) trimanganese(II), C54H34N4O12S6Mn3
  7. Crystal structure of catena-poly[(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(4-bromobenzoate-κ2O:O′)-(μ-2-bromobenzoate-κ2O,O′)nickel(II)] – water (2/1), C30H21Br2N2NiO4.5
  8. The crystal structure of poly[(μ3-1,3-phenylenedioxydiacetate-κ5O,O,O′,O″,O‴)-bis(4′-(4-(1H-imidazol-1-yl)phenyl)-4,2′:6′,4″-terpyridine-kN) cadmium(II)], C58H42CdN10O6
  9. The crystal structure of 5-chloro-6′-methyl-3-(4-(methylsulfonyl)phenyl)-[2,3′-bipyridin]-1′-ium 4-methylbenzenesulfonate
  10. Crystal structure of poly[(μ-benzoato)-(μ-cis-4–hydroxy-D-proline)lithium], C12H14LiNO5
  11. The crystal structure of catena-poly[aqua-(4-iodopyridine-2,6-dicarboxylato-κ3N,O,O′)-copper(II)] monohydrate, C7H6NO6ICu
  12. The crystal structure of catena-[diaqua-(4-acetylphenoxyacetato-κ2O,O)-bis(4-acetylphenoxyacetato-κ3O,O:O)-dihydrate-lanthanum(III)]–4,4′-bipyridine (2/1), C35H35NO14La
  13. The crystal structure of catena-poly[(4-iodopyridine-2,6-dicarboxylato-κ4 O,N,O′,O′′)(4-imidazol-1-yl-pyridine-κN)copper(II)], C15H9N4O4ICu
  14. Crystal structure of polybis(μ 4-3,5-dicarboxylatopyrazol-1-yl)-bis(N,N-dimethylformamide)tri-copper(II)–acetonitrile (1/2), C20H22Cu3N8O10
  15. Crystal structure of poly[(μ2-5-hydroxy-isophthalato-κ4O,O′:O″,O‴)-(μ2-1,5-bis(imidazol-2-methyl)pentane-κ2N:N′)cadmium(II)], C21H24CdN4O5
  16. The crystal structure of poly[bis(μ2-1,4-bi(1-imidazolyl)benzene-κ2N:N′)bis(μ2-4,4′-methylenebis(3-hydroxy-2-naphthoate)-κ2O:O′)cobalt(II)], C35H24CoN4O6
  17. The crystal structure of a cobalt-vanadium-oxido hydrate
  18. The crystal structure of catena-poly[(μ 2-2H-1,2,3-triazole-4,5-dicarboxylato-κ 2 O, O′)-(μ 2-1,3-bis((1H-imidazol-1-yl)methyl)benzene-κ 2 N,N′) zinc(II)], C18H15N7O4Zn
  19. Crystal structure of poly[diaqua-(bis(m2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′-manganese] dichloride, C28H32MnN8O2Cl2
  20. The crystal structure of 9,10-dimethoxy-5,6-dihydro-[1,3]dioxolo[4,5-g]isoquinolino [3,2-a]isoquinolin-7-ium (E)-3-(4-nitrophenyl)acrylate pentahydrate, C29H34N2O13
  21. Crystal structure of poly[(μ6-ammoniotris(methylene))tris(hydrogen phosphonato)cadmium(II)], C3H10CdNO9P3
  22. Crystal structure of Zn2[(1,1′-(hexane-1,6-diyl)bis(3-(pyridin-3-yl)urea))·(H2O)2·(DMF)2·(SO4)2], C24H50N8O18S2Zn2
  23. The crystal structure of 2-anilino-1,4-naphthoquinone, C10H11NO2
  24. Crystal structure of (E)-2-(2-(4-(diethylamino)styryl)-1-ethyl-1,4-dihydroquinolin-4-yl) malononitrile, C26H26N4
  25. Crystal structure of ethyl 2-((2,6-dichloro-4-(cyanomethyl)phenyl) amino)benzoate, C17H14Cl2N2O2
  26. Synthesis and crystal structure of 2-(3-oxo-3-phenylpropyl)isoindoline-1,3-dione, C17H13NO3
  27. The crystal structure of bis(acetonitrile-κ1N)tetrakis(μ2-2,6-difluorobenzoato-κ2O:O′)rhodium(II) (Rh–Rh), C32H18F8O8N2Rh2
  28. The crystal structure of a new polymorph of 6-hydroxy-2-naphthoic acid, C11H8O3
  29. The crystal structure of [(8-carboxymethoxy-quinoline-2-carboxylate-κ4N,O,O,O)-2,2′-bipyridine-κ2N-copper(II)] tetrahydrate, C22H23N3O9Cu
  30. The crystal structure of ethyl 4-hydroxy-2-(4-methoxyphenyl)-5-oxo-1-(2-oxo-2H-chromen-6-yl)-2,5-dihydro-1H-pyrrole-3-carboxylate, C23H19NO7
  31. Crystal structure of 7-hydroxy-3,4-dihydronaphthalen-1(2H)-one, C10H10O2
  32. Crystal structure of bis(tetrapropylammonium) dodecacarbonyltetratelluridotetraferrate(2-), (Pr4N)2[Fe4Te4(CO)12]
  33. The crystal structure of poly[bis(μ2−3−aminopyridine−4−carboxylato−κ2N:O)Zinc(II)], [Zn(C6H5N2O2)2] n
  34. The crystal structure of methyl 5-nitro-2-(tosyloxy)benzoate, C15H13NO7S
  35. The crystal structure of 18-crown-6 ― tetraaqua-dichlorido-di-μ2-chloridodicopper(II) (2/1), C12H32O10Cu2Cl4
  36. Crystal structure of 6,6a,7,8,9,10-hexahydro-5H-pyrazino [2,3-e]pyrido[1,2-a]pyrazine, C10H14N4
  37. Crystal structure of catena-poly-{diaqua-bis[μ-(((4-chlorophenyl)sulfonyl)glycinato-κO)](μ2-4, 4′-bipyridine-κ2N:N′)cobalt(II)} dihydrate, C26H30Cl2CoN4O12S2
  38. Crystal structure of bis{N′-[1,3-diphenylprop-2-en-1-ylidene]-N-phenylcarbamohydrazonothioato}zinc(II), C44H36N6S2Zn
  39. Crystal structure of tetraaqua-bis(((4-chlorophenyl)sulfonyl)glycinato-κO)cobalt(II) dihydrate, C16H26Cl2CoN2O14S2
  40. Crystal structure of 2-(5-phenyl-1-(quinolin-2-yl)-4,5-dihydro-1H-pyrazol-3-yl)phenol, C24H19N3O
  41. Crystal structure of 2-((2-fluoro-4-(trifluoromethyl)phenyl)(hydroxy)methyl)-7-methoxy-3,4-dihydronaphthalen-1((2H))-one, C19H16F4O3
  42. Crystal structure of 2-amino-4-(2-fluoro-3-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  43. Crystal structure of (2-phenylimino methylquinoline-κ 2 N,N′)-bis(1–phenylpyrazole-κ 2 C,N)-iridium(III) hexafluorophosphate, C34H26F6IrN6P
  44. Crystal structure of (3-hydroxy-4-methoxyphenyl)(pyrrolidin-1-yl)methanone, C12H15NO3
  45. The crystal structure of bis(trimethylsulfoxonium) catena-poly[µ2-hexabromido-indium(III)sodium(I)] C6H18O2S2NaInBr6
  46. Crystal structure of N-cyclopropyl-3-hydroxy-4-methoxybenzamide, C11H13NO3
  47. The crystal structure of (bis(benzimidazol-2-yl-methyl)amine-κ3N,N′,N″ )-(dihydrogen L-malate-κ2O,O ′)copper(II) perchlorate dihydrate, CuC20H24ClN5O12
  48. Crystal structure of (1E,1′E)-4,4′-(9,9-diethyl-9H-fluorene-2,7-diyl)dibenzaldehyde dioxime, C31H28N2O2
  49. Crystal structure of diethyl 1,9-bis(4-fluorophenyl)-4,6-diphenylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta [b]pyridine-3,7(2H)-dicarboxylate, C40H36F2N2O4
  50. Crystal structure of bis(benzene-1 carboxylato-O 3,5-carboxyl-κ1O)-[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) ─ benzene-1,3,5-tricarboxylic acid ─ water (1/2/4), C52H66N4NiO28
  51. Crystal structure of 1,4-dibromo-2,5-bis(2-methoxyethoxy)benzene-1,4-diol, C12H16Br2O4
  52. Crystal structure of dicarbonyl[N,N′-(1,2-dimethyl-1,2-ethanediylidene)bis[2,6-bis(1-methylethyl)benzenamine]-N,N′]nickel(0), C30H40N2NiO2
  53. Crystal structure of 1,4-dibromo-2,5-bis(prop-2-yn-1-yloxy)benzene, C12H8Br2O2
  54. Crystal structure of O-(3-(benzo[d]thiazol-2-yl)naphthalen-2-yl) O-phenyl carbonothioate, C24H15NO2S2
  55. The crystal structure of (E)-4-fluoro-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H15FN2O2
  56. Crystal structure of (E)-1-(benzo[d]thiazol-2-yl)-N-(4,5-dihydropyren-2-yl)methanimine, C24H16N2S
  57. Crystal structure of 3-((4-bromophenyl)thio)-1H-indole, C14H10BrNS
  58. Synthesis and crystal structure of 1-((7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carboxylate monohydrate, C22H22N2O9
  59. Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α]phenanthren-3-one O-(methacryloyl) oxime, C50H74N2O4
  60. Crystal structure of the hydrogen storage active phase La12Mg46LiMn
  61. The crystal structure of the salt: 4-((1,3-dioxoisoindolin-2-yl)carbamoyl)pyridine-1-ium 2-carboxybenzoate, C14H10N3O3·C8H5O4
  62. Crystal structure of (2-(2-pyridine)-benzimidazole-κ2 N,N′)-bis(1-phenylpyrazole-κ2 C,N)iridium(III) hexafluorophosphate, C30H22F6IrN7P
  63. Crystal structure of dichlorido-bis[2-(2,4-difluorophenyl)pyridine-κ1N]platinum(II), C22H14Cl2F4N2Pt
  64. Crystal structure of (5R,8R,9R,10R,12R,13R,14R, 17S,17Z)-2-((3-fluoropyridin-4-yl)methylene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C36H52FNO3
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Heruntergeladen am 7.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2023-0276/html
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