Abstract
C54H34N4O12S6Mn3, monoclinic, P21/c (no. 14), a = 11.0140(4) Å, b = 22.3222(9) Å, c = 11.2886(5) Å, β = 105.436(1)°, Z = 2, V = 2675.27(19) Å3, R gt (F) = 0.0361, wR ref (F2) = 0.0846, T = 273 K.
Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Data collection and handling.
Crystal: | Block, yellow |
Size: | 0.3 × 0.2 × 0.2 mm |
Wavelength: | Mo Ka radiation, l = 0.71073 Å |
μ: | 0.999 mm−1 |
Diffractometer, scan mode: | Bruker APEX-II, φ and ω |
θmax, completeness: | 27.130°, >99.9 % |
N(hkl)measured, N(hkl)unique, Rint: | 18,414, 5917, 0.0212 |
Criterion for Iobs, N(hkl)gt: | Iobs > 2σ(Iobs), 4961 |
N(param)refined: | 415 |
Programs: | Bruker [1], Olex2 [2] |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).
x | y | z | Uiso*/Ueq | |
---|---|---|---|---|
Mn1 | 0.73967 (3) | 0.40694 (2) | 0.14482 (3) | 0.02828 (9) |
Mn2 | 0.5000 | 0.5000 | 0.0000 | 0.02615 (10) |
S1 | 0.95691 (19) | 0.67057 (8) | 0.0273 (3) | 0.0514 (4) |
S1A | 0.8134 (7) | 0.6943 (3) | 0.0527 (4) | 0.0555 (12) |
S2 | 0.6314 (4) | 0.3550 (2) | −0.4534 (3) | 0.0647 (7) |
S2A | 0.5203 (9) | 0.4195 (4) | −0.4609 (7) | 0.0774 (14) |
S3 | 0.2754 (5) | 0.2953 (2) | 0.3461 (6) | 0.0670 (10) |
S3A | 0.1959 (2) | 0.35109 (12) | 0.3206 (3) | 0.0621 (6) |
O1 | 0.87238 (17) | 0.47788 (7) | 0.10875 (17) | 0.0467 (4) |
O2 | 0.68980 (14) | 0.51176 (6) | 0.12348 (15) | 0.0371 (3) |
O3 | 0.75166 (17) | 0.36587 (8) | −0.03845 (14) | 0.0466 (4) |
O4 | 0.5896 (2) | 0.42410 (8) | −0.05724 (17) | 0.0572 (5) |
O5 | 0.57984 (15) | 0.36671 (8) | 0.18492 (16) | 0.0451 (4) |
O6 | 0.45650 (16) | 0.44745 (7) | 0.13974 (15) | 0.0418 (4) |
N1 | 0.85287 (16) | 0.32868 (8) | 0.23992 (16) | 0.0313 (4) |
N2 | 0.81628 (18) | 0.43196 (8) | 0.35117 (17) | 0.0362 (4) |
C1 | 0.8661 (2) | 0.27730 (10) | 0.1860 (2) | 0.0415 (5) |
H1 | 0.8329 | 0.2741 | 0.1014 | 0.050* |
C2 | 0.9275 (3) | 0.22775 (11) | 0.2505 (3) | 0.0528 (7) |
H2 | 0.9338 | 0.1922 | 0.2096 | 0.063* |
C3 | 0.9780 (3) | 0.23213 (12) | 0.3739 (3) | 0.0538 (7) |
H3 | 1.0200 | 0.1996 | 0.4179 | 0.065* |
C4 | 0.9670 (2) | 0.28546 (11) | 0.4347 (2) | 0.0419 (6) |
C5 | 0.90194 (19) | 0.33307 (10) | 0.3635 (2) | 0.0320 (5) |
C6 | 0.8849 (2) | 0.38844 (10) | 0.4220 (2) | 0.0342 (5) |
C7 | 0.9374 (2) | 0.39500 (13) | 0.5496 (2) | 0.0469 (6) |
C8 | 0.9154 (3) | 0.44940 (14) | 0.6029 (3) | 0.0616 (8) |
H8 | 0.9488 | 0.4559 | 0.6867 | 0.074* |
C9 | 0.8454 (3) | 0.49234 (14) | 0.5317 (3) | 0.0630 (8) |
H9 | 0.8295 | 0.5283 | 0.5662 | 0.076* |
C10 | 0.7971 (3) | 0.48216 (12) | 0.4059 (2) | 0.0506 (6) |
H10 | 0.7491 | 0.5121 | 0.3583 | 0.061* |
C11 | 1.0188 (3) | 0.29402 (15) | 0.5642 (3) | 0.0576 (8) |
H11 | 1.0623 | 0.2628 | 0.6116 | 0.069* |
C12 | 1.0058 (3) | 0.34603 (16) | 0.6181 (3) | 0.0615 (8) |
H12 | 1.0421 | 0.3505 | 0.7020 | 0.074* |
C13 | 0.7980 (2) | 0.52018 (10) | 0.10373 (19) | 0.0336 (5) |
C14 | 0.8332 (2) | 0.58191 (9) | 0.07821 (17) | 0.0321 (4) |
C15 | 0.9443 (2) | 0.59671 (10) | 0.05037 (19) | 0.0405 (5) |
H15 | 1.0054 | 0.5688 | 0.0450 | 0.049* |
H15A | 1.0084 | 0.5707 | 0.0444 | 0.049* |
C16 | 0.8193 (11) | 0.6841 (5) | 0.0531 (5) | 0.059 (2) |
H16 | 0.7850 | 0.7223 | 0.0499 | 0.070* |
C16A | 0.9406 (17) | 0.6615 (9) | 0.032 (3) | 0.056 (3) |
H16A | 1.0045 | 0.6826 | 0.0109 | 0.067* |
C17 | 0.7578 (2) | 0.63207 (11) | 0.0807 (2) | 0.0423 (5) |
H17 | 0.6797 | 0.6315 | 0.0977 | 0.051* |
H17A | 0.6799 | 0.6291 | 0.0977 | 0.051* |
C18 | 0.6616 (2) | 0.39456 (9) | −0.1044 (2) | 0.0343 (5) |
C19 | 0.6340 (2) | 0.39290 (10) | −0.2403 (2) | 0.0348 (5) |
C20 | 0.6901 (3) | 0.35426 (13) | −0.3045 (2) | 0.0518 (6) |
H20 | 0.7567 | 0.3295 | −0.2659 | 0.062* |
H20A | 0.7506 | 0.3253 | −0.2727 | 0.062* |
C21 | 0.5322 (18) | 0.4089 (8) | −0.4434 (15) | 0.097 (8) |
H21 | 0.4757 | 0.4258 | −0.5114 | 0.116* |
C21A | 0.632 (2) | 0.3691 (11) | −0.438 (2) | 0.096 (15) |
H21A | 0.6570 | 0.3512 | −0.5021 | 0.116* |
C22 | 0.5417 (3) | 0.42729 (14) | −0.3181 (3) | 0.0619 (8) |
H22 | 0.4941 | 0.4570 | −0.2942 | 0.074* |
H22A | 0.4936 | 0.4542 | −0.2869 | 0.074* |
C23 | 0.4818 (2) | 0.39585 (10) | 0.18369 (19) | 0.0315 (4) |
C24 | 0.3880 (2) | 0.36767 (10) | 0.24012 (18) | 0.0320 (4) |
C25 | 0.3990 (3) | 0.31041 (11) | 0.2909 (2) | 0.0457 (6) |
H25 | 0.4655 | 0.2843 | 0.2937 | 0.055* |
H25A | 0.4654 | 0.2847 | 0.2910 | 0.055* |
C26 | 0.2792 (2) | 0.39597 (11) | 0.2484 (2) | 0.0439 (6) |
H26 | 0.2577 | 0.4347 | 0.2202 | 0.053* |
H26A | 0.2547 | 0.4342 | 0.2188 | 0.053* |
C27 | 0.2091 (12) | 0.3628 (5) | 0.3000 (14) | 0.058 (2) |
H27 | 0.1317 | 0.3750 | 0.3102 | 0.069* |
C27A | 0.3030 (12) | 0.2960 (6) | 0.3401 (16) | 0.061 (2) |
H27A | 0.2973 | 0.2600 | 0.3797 | 0.074* |
1 Source of materials
3–Thiophenecarboxylic acid (6.0 mmol) was dissolved in 20 mL of anhydrous methanol. Mn(CH3COO)2·4H2O (3.0 mmol) dissolved in 15 mL of anhydrous methanol was added dropwise to the above 3-thiophenecarboxylic acid solution and stirred for 4 h at 55 °C. Then 1,10-phenanthroline (2.0 mmol) was dissolved in 10 mL of anhydrous methanol was added dropwise to the above solution and stirred for 3 h at 55 °C cooled and filtered. The filtrate was left for slow evaporation at room temperature. The yellow block crystals were formed 16 days later. Yield: 39.7 %. Anal. Calcd. for C54H34N4O12S6Mn3: C, 50.35; H, 2.66; N, 4.35; S, 14.94; found: C, 50.31; H, 2.70; N, 4.39; S, 14.90.
2 Experimental details
A suitable crystal was selected and mounted on a Bruker Smart APEX—II CCD. Hydrogen atoms were placed in their geometrically idealized positions and constrained to ride on their parent atoms.
3 Comment
Metal complexes are considered as promising anticancer drugs [3]. Thiophene carboxylates and its metal complexes have attracted extensive attention. Some of these metal complexes have excellent biological activities [4, 5]. We report herein a new trinuclear manganese metal complex constructed by 3-thiophenecarboxylate and 1,10-phenanthroline ligands. The title complex has a trinuclear structure, in which three Mn(II) ions are connected by O atoms of 3-thiophenecarboxylates. In the complex, each Mn(II) ion is six-coordinated in a distorted octahedral environment, in which one Mn(II) ion is coordinated by six O atoms of the 3-thiophenecarboxylato ligand, whereas the other two Mn(II) ions are coordinated by four O atoms and two N atoms from the 3-thiophenecarboxylato ligand and 1,10-phenanthroline ligand, respectively. The bond distances of Mn–N are 2.2464 (17) and 2.3245(18) Å, bond lengths of Mn–O are 2.1204 (14)–2.465(2) Å, respectively, which are similar with the references [6, 7]. The complex is has a centrosymmetric structure, and the symmetry center is the Mn2(II) ion.
Funding source: Transverse Research Project of Dezhou University
Award Identifier / Grant number: HXKT2022144 and HXKT2022212
Funding source: Bidding Subject of Dezhou University
Award Identifier / Grant number: 3010040205
Funding source: Shandong Province College Students Innovation and Entrepreneurship Training Program Project
Award Identifier / Grant number: 901569
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This study was supported by the Transverse Research Project of Dezhou University (No. HXKT2022144 and No. HXKT2022212), the Bidding Subject of Dezhou University (No. 3010040205) and the Shandong Province College Students Innovation and Entrepreneurship Training Program Project (No. 901569).
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
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© 2023 the author(s), published by De Gruyter, Berlin/Boston
This work is licensed under the Creative Commons Attribution 4.0 International License.
Articles in the same Issue
- Frontmatter
- New Crystal Structures
- Crystal structure of bis(dimethylammonium) poly[(μ4-1,1′-(1,4-phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato))-κ6O1, N2:O2:O3:O1′,N2′]nickel (II)], C22H26N6NiO8
- Hydrothermal synthesis and crystal structure of catena-poly[diaqua-bis(μ2-4-((pyridin-4-ylmethyl)amino)benzoato-κ2N:O)cobalt(II)] – 4,4′-bipyridine – water (1/2/2)
- Crystal structure of (2S,3S,4S,5S, Z)-2,3,5,6-tetrakis(benzyloxy)-4-hydroxyhexanal oxime, C34H37NO6
- The crystal structure of hexakis(3-thiophenecarboxylato-κ2O,O″)-bis(1,10-phenanthroline-κ2N,N′) trimanganese(II), C54H34N4O12S6Mn3
- Crystal structure of catena-poly[(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(4-bromobenzoate-κ2O:O′)-(μ-2-bromobenzoate-κ2O,O′)nickel(II)] – water (2/1), C30H21Br2N2NiO4.5
- The crystal structure of poly[(μ3-1,3-phenylenedioxydiacetate-κ5O,O,O′,O″,O‴)-bis(4′-(4-(1H-imidazol-1-yl)phenyl)-4,2′:6′,4″-terpyridine-kN) cadmium(II)], C58H42CdN10O6
- The crystal structure of 5-chloro-6′-methyl-3-(4-(methylsulfonyl)phenyl)-[2,3′-bipyridin]-1′-ium 4-methylbenzenesulfonate
- Crystal structure of poly[(μ-benzoato)-(μ-cis-4–hydroxy-D-proline)lithium], C12H14LiNO5
- The crystal structure of catena-poly[aqua-(4-iodopyridine-2,6-dicarboxylato-κ3N,O,O′)-copper(II)] monohydrate, C7H6NO6ICu
- The crystal structure of catena-[diaqua-(4-acetylphenoxyacetato-κ2O,O)-bis(4-acetylphenoxyacetato-κ3O,O:O)-dihydrate-lanthanum(III)]–4,4′-bipyridine (2/1), C35H35NO14La
- The crystal structure of catena-poly[(4-iodopyridine-2,6-dicarboxylato-κ4 O,N,O′,O′′)(4-imidazol-1-yl-pyridine-κN)copper(II)], C15H9N4O4ICu
- Crystal structure of polybis(μ 4-3,5-dicarboxylatopyrazol-1-yl)-bis(N,N-dimethylformamide)tri-copper(II)–acetonitrile (1/2), C20H22Cu3N8O10
- Crystal structure of poly[(μ2-5-hydroxy-isophthalato-κ4O,O′:O″,O‴)-(μ2-1,5-bis(imidazol-2-methyl)pentane-κ2N:N′)cadmium(II)], C21H24CdN4O5
- The crystal structure of poly[bis(μ2-1,4-bi(1-imidazolyl)benzene-κ2N:N′)bis(μ2-4,4′-methylenebis(3-hydroxy-2-naphthoate)-κ2O:O′)cobalt(II)], C35H24CoN4O6
- The crystal structure of a cobalt-vanadium-oxido hydrate
- The crystal structure of catena-poly[(μ 2-2H-1,2,3-triazole-4,5-dicarboxylato-κ 2 O, O′)-(μ 2-1,3-bis((1H-imidazol-1-yl)methyl)benzene-κ 2 N,N′) zinc(II)], C18H15N7O4Zn
- Crystal structure of poly[diaqua-(bis(m2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′-manganese] dichloride, C28H32MnN8O2Cl2
- The crystal structure of 9,10-dimethoxy-5,6-dihydro-[1,3]dioxolo[4,5-g]isoquinolino [3,2-a]isoquinolin-7-ium (E)-3-(4-nitrophenyl)acrylate pentahydrate, C29H34N2O13
- Crystal structure of poly[(μ6-ammoniotris(methylene))tris(hydrogen phosphonato)cadmium(II)], C3H10CdNO9P3
- Crystal structure of Zn2[(1,1′-(hexane-1,6-diyl)bis(3-(pyridin-3-yl)urea))·(H2O)2·(DMF)2·(SO4)2], C24H50N8O18S2Zn2
- The crystal structure of 2-anilino-1,4-naphthoquinone, C10H11NO2
- Crystal structure of (E)-2-(2-(4-(diethylamino)styryl)-1-ethyl-1,4-dihydroquinolin-4-yl) malononitrile, C26H26N4
- Crystal structure of ethyl 2-((2,6-dichloro-4-(cyanomethyl)phenyl) amino)benzoate, C17H14Cl2N2O2
- Synthesis and crystal structure of 2-(3-oxo-3-phenylpropyl)isoindoline-1,3-dione, C17H13NO3
- The crystal structure of bis(acetonitrile-κ1N)tetrakis(μ2-2,6-difluorobenzoato-κ2O:O′)rhodium(II) (Rh–Rh), C32H18F8O8N2Rh2
- The crystal structure of a new polymorph of 6-hydroxy-2-naphthoic acid, C11H8O3
- The crystal structure of [(8-carboxymethoxy-quinoline-2-carboxylate-κ4N,O,O,O)-2,2′-bipyridine-κ2N-copper(II)] tetrahydrate, C22H23N3O9Cu
- The crystal structure of ethyl 4-hydroxy-2-(4-methoxyphenyl)-5-oxo-1-(2-oxo-2H-chromen-6-yl)-2,5-dihydro-1H-pyrrole-3-carboxylate, C23H19NO7
- Crystal structure of 7-hydroxy-3,4-dihydronaphthalen-1(2H)-one, C10H10O2
- Crystal structure of bis(tetrapropylammonium) dodecacarbonyltetratelluridotetraferrate(2-), (Pr4N)2[Fe4Te4(CO)12]
- The crystal structure of poly[bis(μ2−3−aminopyridine−4−carboxylato−κ2N:O)Zinc(II)], [Zn(C6H5N2O2)2] n
- The crystal structure of methyl 5-nitro-2-(tosyloxy)benzoate, C15H13NO7S
- The crystal structure of 18-crown-6 ― tetraaqua-dichlorido-di-μ2-chloridodicopper(II) (2/1), C12H32O10Cu2Cl4
- Crystal structure of 6,6a,7,8,9,10-hexahydro-5H-pyrazino [2,3-e]pyrido[1,2-a]pyrazine, C10H14N4
- Crystal structure of catena-poly-{diaqua-bis[μ-(((4-chlorophenyl)sulfonyl)glycinato-κO)](μ2-4, 4′-bipyridine-κ2N:N′)cobalt(II)} dihydrate, C26H30Cl2CoN4O12S2
- Crystal structure of bis{N′-[1,3-diphenylprop-2-en-1-ylidene]-N-phenylcarbamohydrazonothioato}zinc(II), C44H36N6S2Zn
- Crystal structure of tetraaqua-bis(((4-chlorophenyl)sulfonyl)glycinato-κO)cobalt(II) dihydrate, C16H26Cl2CoN2O14S2
- Crystal structure of 2-(5-phenyl-1-(quinolin-2-yl)-4,5-dihydro-1H-pyrazol-3-yl)phenol, C24H19N3O
- Crystal structure of 2-((2-fluoro-4-(trifluoromethyl)phenyl)(hydroxy)methyl)-7-methoxy-3,4-dihydronaphthalen-1((2H))-one, C19H16F4O3
- Crystal structure of 2-amino-4-(2-fluoro-3-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
- Crystal structure of (2-phenylimino methylquinoline-κ 2 N,N′)-bis(1–phenylpyrazole-κ 2 C,N)-iridium(III) hexafluorophosphate, C34H26F6IrN6P
- Crystal structure of (3-hydroxy-4-methoxyphenyl)(pyrrolidin-1-yl)methanone, C12H15NO3
- The crystal structure of bis(trimethylsulfoxonium) catena-poly[µ2-hexabromido-indium(III)sodium(I)] C6H18O2S2NaInBr6
- Crystal structure of N-cyclopropyl-3-hydroxy-4-methoxybenzamide, C11H13NO3
- The crystal structure of (bis(benzimidazol-2-yl-methyl)amine-κ3N,N′,N″ )-(dihydrogen L-malate-κ2O,O ′)copper(II) perchlorate dihydrate, CuC20H24ClN5O12
- Crystal structure of (1E,1′E)-4,4′-(9,9-diethyl-9H-fluorene-2,7-diyl)dibenzaldehyde dioxime, C31H28N2O2
- Crystal structure of diethyl 1,9-bis(4-fluorophenyl)-4,6-diphenylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta [b]pyridine-3,7(2H)-dicarboxylate, C40H36F2N2O4
- Crystal structure of bis(benzene-1 carboxylato-O 3,5-carboxyl-κ1O)-[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) ─ benzene-1,3,5-tricarboxylic acid ─ water (1/2/4), C52H66N4NiO28
- Crystal structure of 1,4-dibromo-2,5-bis(2-methoxyethoxy)benzene-1,4-diol, C12H16Br2O4
- Crystal structure of dicarbonyl[N,N′-(1,2-dimethyl-1,2-ethanediylidene)bis[2,6-bis(1-methylethyl)benzenamine]-N,N′]nickel(0), C30H40N2NiO2
- Crystal structure of 1,4-dibromo-2,5-bis(prop-2-yn-1-yloxy)benzene, C12H8Br2O2
- Crystal structure of O-(3-(benzo[d]thiazol-2-yl)naphthalen-2-yl) O-phenyl carbonothioate, C24H15NO2S2
- The crystal structure of (E)-4-fluoro-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H15FN2O2
- Crystal structure of (E)-1-(benzo[d]thiazol-2-yl)-N-(4,5-dihydropyren-2-yl)methanimine, C24H16N2S
- Crystal structure of 3-((4-bromophenyl)thio)-1H-indole, C14H10BrNS
- Synthesis and crystal structure of 1-((7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carboxylate monohydrate, C22H22N2O9
- Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α]phenanthren-3-one O-(methacryloyl) oxime, C50H74N2O4
- Crystal structure of the hydrogen storage active phase La12Mg46LiMn
- The crystal structure of the salt: 4-((1,3-dioxoisoindolin-2-yl)carbamoyl)pyridine-1-ium 2-carboxybenzoate, C14H10N3O3·C8H5O4
- Crystal structure of (2-(2-pyridine)-benzimidazole-κ2 N,N′)-bis(1-phenylpyrazole-κ2 C,N)iridium(III) hexafluorophosphate, C30H22F6IrN7P
- Crystal structure of dichlorido-bis[2-(2,4-difluorophenyl)pyridine-κ1N]platinum(II), C22H14Cl2F4N2Pt
- Crystal structure of (5R,8R,9R,10R,12R,13R,14R, 17S,17Z)-2-((3-fluoropyridin-4-yl)methylene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C36H52FNO3
Articles in the same Issue
- Frontmatter
- New Crystal Structures
- Crystal structure of bis(dimethylammonium) poly[(μ4-1,1′-(1,4-phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato))-κ6O1, N2:O2:O3:O1′,N2′]nickel (II)], C22H26N6NiO8
- Hydrothermal synthesis and crystal structure of catena-poly[diaqua-bis(μ2-4-((pyridin-4-ylmethyl)amino)benzoato-κ2N:O)cobalt(II)] – 4,4′-bipyridine – water (1/2/2)
- Crystal structure of (2S,3S,4S,5S, Z)-2,3,5,6-tetrakis(benzyloxy)-4-hydroxyhexanal oxime, C34H37NO6
- The crystal structure of hexakis(3-thiophenecarboxylato-κ2O,O″)-bis(1,10-phenanthroline-κ2N,N′) trimanganese(II), C54H34N4O12S6Mn3
- Crystal structure of catena-poly[(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(4-bromobenzoate-κ2O:O′)-(μ-2-bromobenzoate-κ2O,O′)nickel(II)] – water (2/1), C30H21Br2N2NiO4.5
- The crystal structure of poly[(μ3-1,3-phenylenedioxydiacetate-κ5O,O,O′,O″,O‴)-bis(4′-(4-(1H-imidazol-1-yl)phenyl)-4,2′:6′,4″-terpyridine-kN) cadmium(II)], C58H42CdN10O6
- The crystal structure of 5-chloro-6′-methyl-3-(4-(methylsulfonyl)phenyl)-[2,3′-bipyridin]-1′-ium 4-methylbenzenesulfonate
- Crystal structure of poly[(μ-benzoato)-(μ-cis-4–hydroxy-D-proline)lithium], C12H14LiNO5
- The crystal structure of catena-poly[aqua-(4-iodopyridine-2,6-dicarboxylato-κ3N,O,O′)-copper(II)] monohydrate, C7H6NO6ICu
- The crystal structure of catena-[diaqua-(4-acetylphenoxyacetato-κ2O,O)-bis(4-acetylphenoxyacetato-κ3O,O:O)-dihydrate-lanthanum(III)]–4,4′-bipyridine (2/1), C35H35NO14La
- The crystal structure of catena-poly[(4-iodopyridine-2,6-dicarboxylato-κ4 O,N,O′,O′′)(4-imidazol-1-yl-pyridine-κN)copper(II)], C15H9N4O4ICu
- Crystal structure of polybis(μ 4-3,5-dicarboxylatopyrazol-1-yl)-bis(N,N-dimethylformamide)tri-copper(II)–acetonitrile (1/2), C20H22Cu3N8O10
- Crystal structure of poly[(μ2-5-hydroxy-isophthalato-κ4O,O′:O″,O‴)-(μ2-1,5-bis(imidazol-2-methyl)pentane-κ2N:N′)cadmium(II)], C21H24CdN4O5
- The crystal structure of poly[bis(μ2-1,4-bi(1-imidazolyl)benzene-κ2N:N′)bis(μ2-4,4′-methylenebis(3-hydroxy-2-naphthoate)-κ2O:O′)cobalt(II)], C35H24CoN4O6
- The crystal structure of a cobalt-vanadium-oxido hydrate
- The crystal structure of catena-poly[(μ 2-2H-1,2,3-triazole-4,5-dicarboxylato-κ 2 O, O′)-(μ 2-1,3-bis((1H-imidazol-1-yl)methyl)benzene-κ 2 N,N′) zinc(II)], C18H15N7O4Zn
- Crystal structure of poly[diaqua-(bis(m2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′-manganese] dichloride, C28H32MnN8O2Cl2
- The crystal structure of 9,10-dimethoxy-5,6-dihydro-[1,3]dioxolo[4,5-g]isoquinolino [3,2-a]isoquinolin-7-ium (E)-3-(4-nitrophenyl)acrylate pentahydrate, C29H34N2O13
- Crystal structure of poly[(μ6-ammoniotris(methylene))tris(hydrogen phosphonato)cadmium(II)], C3H10CdNO9P3
- Crystal structure of Zn2[(1,1′-(hexane-1,6-diyl)bis(3-(pyridin-3-yl)urea))·(H2O)2·(DMF)2·(SO4)2], C24H50N8O18S2Zn2
- The crystal structure of 2-anilino-1,4-naphthoquinone, C10H11NO2
- Crystal structure of (E)-2-(2-(4-(diethylamino)styryl)-1-ethyl-1,4-dihydroquinolin-4-yl) malononitrile, C26H26N4
- Crystal structure of ethyl 2-((2,6-dichloro-4-(cyanomethyl)phenyl) amino)benzoate, C17H14Cl2N2O2
- Synthesis and crystal structure of 2-(3-oxo-3-phenylpropyl)isoindoline-1,3-dione, C17H13NO3
- The crystal structure of bis(acetonitrile-κ1N)tetrakis(μ2-2,6-difluorobenzoato-κ2O:O′)rhodium(II) (Rh–Rh), C32H18F8O8N2Rh2
- The crystal structure of a new polymorph of 6-hydroxy-2-naphthoic acid, C11H8O3
- The crystal structure of [(8-carboxymethoxy-quinoline-2-carboxylate-κ4N,O,O,O)-2,2′-bipyridine-κ2N-copper(II)] tetrahydrate, C22H23N3O9Cu
- The crystal structure of ethyl 4-hydroxy-2-(4-methoxyphenyl)-5-oxo-1-(2-oxo-2H-chromen-6-yl)-2,5-dihydro-1H-pyrrole-3-carboxylate, C23H19NO7
- Crystal structure of 7-hydroxy-3,4-dihydronaphthalen-1(2H)-one, C10H10O2
- Crystal structure of bis(tetrapropylammonium) dodecacarbonyltetratelluridotetraferrate(2-), (Pr4N)2[Fe4Te4(CO)12]
- The crystal structure of poly[bis(μ2−3−aminopyridine−4−carboxylato−κ2N:O)Zinc(II)], [Zn(C6H5N2O2)2] n
- The crystal structure of methyl 5-nitro-2-(tosyloxy)benzoate, C15H13NO7S
- The crystal structure of 18-crown-6 ― tetraaqua-dichlorido-di-μ2-chloridodicopper(II) (2/1), C12H32O10Cu2Cl4
- Crystal structure of 6,6a,7,8,9,10-hexahydro-5H-pyrazino [2,3-e]pyrido[1,2-a]pyrazine, C10H14N4
- Crystal structure of catena-poly-{diaqua-bis[μ-(((4-chlorophenyl)sulfonyl)glycinato-κO)](μ2-4, 4′-bipyridine-κ2N:N′)cobalt(II)} dihydrate, C26H30Cl2CoN4O12S2
- Crystal structure of bis{N′-[1,3-diphenylprop-2-en-1-ylidene]-N-phenylcarbamohydrazonothioato}zinc(II), C44H36N6S2Zn
- Crystal structure of tetraaqua-bis(((4-chlorophenyl)sulfonyl)glycinato-κO)cobalt(II) dihydrate, C16H26Cl2CoN2O14S2
- Crystal structure of 2-(5-phenyl-1-(quinolin-2-yl)-4,5-dihydro-1H-pyrazol-3-yl)phenol, C24H19N3O
- Crystal structure of 2-((2-fluoro-4-(trifluoromethyl)phenyl)(hydroxy)methyl)-7-methoxy-3,4-dihydronaphthalen-1((2H))-one, C19H16F4O3
- Crystal structure of 2-amino-4-(2-fluoro-3-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
- Crystal structure of (2-phenylimino methylquinoline-κ 2 N,N′)-bis(1–phenylpyrazole-κ 2 C,N)-iridium(III) hexafluorophosphate, C34H26F6IrN6P
- Crystal structure of (3-hydroxy-4-methoxyphenyl)(pyrrolidin-1-yl)methanone, C12H15NO3
- The crystal structure of bis(trimethylsulfoxonium) catena-poly[µ2-hexabromido-indium(III)sodium(I)] C6H18O2S2NaInBr6
- Crystal structure of N-cyclopropyl-3-hydroxy-4-methoxybenzamide, C11H13NO3
- The crystal structure of (bis(benzimidazol-2-yl-methyl)amine-κ3N,N′,N″ )-(dihydrogen L-malate-κ2O,O ′)copper(II) perchlorate dihydrate, CuC20H24ClN5O12
- Crystal structure of (1E,1′E)-4,4′-(9,9-diethyl-9H-fluorene-2,7-diyl)dibenzaldehyde dioxime, C31H28N2O2
- Crystal structure of diethyl 1,9-bis(4-fluorophenyl)-4,6-diphenylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta [b]pyridine-3,7(2H)-dicarboxylate, C40H36F2N2O4
- Crystal structure of bis(benzene-1 carboxylato-O 3,5-carboxyl-κ1O)-[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) ─ benzene-1,3,5-tricarboxylic acid ─ water (1/2/4), C52H66N4NiO28
- Crystal structure of 1,4-dibromo-2,5-bis(2-methoxyethoxy)benzene-1,4-diol, C12H16Br2O4
- Crystal structure of dicarbonyl[N,N′-(1,2-dimethyl-1,2-ethanediylidene)bis[2,6-bis(1-methylethyl)benzenamine]-N,N′]nickel(0), C30H40N2NiO2
- Crystal structure of 1,4-dibromo-2,5-bis(prop-2-yn-1-yloxy)benzene, C12H8Br2O2
- Crystal structure of O-(3-(benzo[d]thiazol-2-yl)naphthalen-2-yl) O-phenyl carbonothioate, C24H15NO2S2
- The crystal structure of (E)-4-fluoro-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H15FN2O2
- Crystal structure of (E)-1-(benzo[d]thiazol-2-yl)-N-(4,5-dihydropyren-2-yl)methanimine, C24H16N2S
- Crystal structure of 3-((4-bromophenyl)thio)-1H-indole, C14H10BrNS
- Synthesis and crystal structure of 1-((7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carboxylate monohydrate, C22H22N2O9
- Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α]phenanthren-3-one O-(methacryloyl) oxime, C50H74N2O4
- Crystal structure of the hydrogen storage active phase La12Mg46LiMn
- The crystal structure of the salt: 4-((1,3-dioxoisoindolin-2-yl)carbamoyl)pyridine-1-ium 2-carboxybenzoate, C14H10N3O3·C8H5O4
- Crystal structure of (2-(2-pyridine)-benzimidazole-κ2 N,N′)-bis(1-phenylpyrazole-κ2 C,N)iridium(III) hexafluorophosphate, C30H22F6IrN7P
- Crystal structure of dichlorido-bis[2-(2,4-difluorophenyl)pyridine-κ1N]platinum(II), C22H14Cl2F4N2Pt
- Crystal structure of (5R,8R,9R,10R,12R,13R,14R, 17S,17Z)-2-((3-fluoropyridin-4-yl)methylene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C36H52FNO3