Startseite Crystal structure of poly[deca aqua-bis(μ 4-2-(triazol-1-yl)-benzene-1,3,5-tricarboxylato)- bis(μ 5-2-(triazol-1-yl)-benzene-1,3-dicarboxylato-5-carboxyl acid) pentamanganese(II)] dihydrate, C44H42Mn5N12O36
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Crystal structure of poly[deca aqua-bis(μ 4-2-(triazol-1-yl)-benzene-1,3,5-tricarboxylato)- bis(μ 5-2-(triazol-1-yl)-benzene-1,3-dicarboxylato-5-carboxyl acid) pentamanganese(II)] dihydrate, C44H42Mn5N12O36

  • Yan-Yan An ORCID logo EMAIL logo , Juan-Zhi Yan EMAIL logo und Dan Zhan
Veröffentlicht/Copyright: 21. Juli 2022
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 237 Heft 5

Abstract

C44H42Mn5N12O36, triclinic, P 1 ‾ (no. 2), a = 7.6398(7) Å, b = 9.9043(5) Å, c = 20.1160(13) Å, α = 87.300(5)°, β = 81.868(6)°, γ = 67.555(7)°, V = 1392.62(18) Å3, Z = 1, R gt (F) = 0.0554, wR ref (F 2) = 0.1446, T = 293(2) K.

CCDC no.: 2034133

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.12 × 0.12 × 0.11 mm
Wavelength: Cu Kα radiation (1.54184 Å)
μ: 10.1 mm−1
Diffractometer, scan mode: Xcalibur,
θ max, completeness: 71.1°, >99%
N(hkl)measured, N(hkl)unique, R int: 9402, 5274, 0.052
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 4024
N(param)refined: 469
Programs: CrysAlisPRO [1, 2], SHELX [3, 4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
Mn1 0.45071 (10) 0.28163 (8) 0.39359 (3) 0.01672 (18)
Mn2 0.09647 (10) 0.37918 (8) 0.27257 (3) 0.01573 (18)
Mn3 1.000000 0.500000 0.000000 0.0165 (2)
N1 0.3360 (5) −0.1919 (4) 0.41308 (18) 0.0167 (8)
N2 0.4059 (6) −0.2316 (4) 0.51512 (19) 0.0237 (9)
N3a 0.1741 (18) −0.1842 (19) 0.4510 (6) 0.032 (3)
N3′b 0.1746 (12) −0.1000 (13) 0.4530 (4) 0.036 (2)
N4 0.7642 (5) 0.2476 (4) 0.14042 (17) 0.0143 (7)
N5 0.6311 (6) 0.3810 (4) 0.1596 (2) 0.0310 (10)
N6 0.8424 (5) 0.4011 (4) 0.0749 (2) 0.0213 (8)
O1 0.3114 (5) 0.1948 (3) 0.32006 (17) 0.0253 (7)
O2 0.4665 (5) 0.0397 (4) 0.39225 (16) 0.0248 (7)
O3 0.4345 (6) −0.4936 (4) 0.38126 (18) 0.0327 (9)
O4 0.2547 (6) −0.5069 (4) 0.30786 (19) 0.0343 (9)
O5 0.2717 (6) −0.2287 (4) 0.10105 (18) 0.0380 (10)
O6 0.3103 (6) −0.0180 (4) 0.10497 (16) 0.0306 (8)
H6 0.296782 −0.014717 0.065129 0.046*
O7 0.9507 (5) 0.2483 (3) 0.25107 (16) 0.0218 (7)
O8 0.7386 (5) 0.2312 (4) 0.33643 (16) 0.0252 (7)
O9 0.7816 (5) −0.3036 (4) 0.31846 (17) 0.0324 (9)
O10 0.9299 (5) −0.4168 (3) 0.22121 (16) 0.0227 (7)
O11 0.7504 (5) −0.0354 (4) 0.01712 (16) 0.0267 (8)
O12 0.5428 (5) 0.1776 (4) 0.06150 (17) 0.0300 (8)
O13 0.1755 (5) 0.3567 (4) 0.45747 (19) 0.0405 (10)
H13B 0.094071 0.340659 0.437700 0.061*
H13C 0.187311 0.310359 0.494270 0.061*
O14 −0.1019 (5) 0.4346 (4) 0.36933 (17) 0.0252 (8)
H14A −0.202822 0.507581 0.363504 0.038*
H14B −0.130931 0.361752 0.381934 0.038*
O15 0.2838 (5) 0.3252 (4) 0.17842 (19) 0.0398 (10)
H15C 0.380998 0.347059 0.178917 0.048*
H15B 0.315387 0.234429 0.171627 0.048*
O16 0.7442 (5) 0.6988 (3) 0.01266 (18) 0.0269 (8)
H16A 0.762504 0.764711 −0.012586 0.040*
H16B 0.650745 0.681982 0.001894 0.040*
O17 1.0954 (5) 0.5777 (4) 0.08392 (17) 0.0311 (8)
H17A 1.165719 0.623903 0.068315 0.047*
H17C 1.158958 0.504873 0.106295 0.047*
O18c 0.1901 (17) 0.1530 (15) 0.5542 (6) 0.079 (3)
H18Cc 0.084980 0.140562 0.558641 0.095*
H18Dc 0.270661 0.083422 0.573491 0.095*
O18′d 0.099 (3) 0.242 (3) 0.5697 (8) 0.082 (5)
H18Gd 0.139287 0.266968 0.602443 0.098*
H18Ed −0.021893 0.266337 0.577582 0.098*
C1 0.3725 (6) 0.0667 (5) 0.3443 (2) 0.0162 (9)
C2 0.3403 (6) −0.0531 (5) 0.3100 (2) 0.0146 (8)
C3 0.3392 (6) −0.1815 (5) 0.3416 (2) 0.0157 (9)
C4 0.3244 (6) −0.2938 (5) 0.3061 (2) 0.0164 (9)
C5 0.3092 (6) −0.2754 (5) 0.2380 (2) 0.0174 (9)
H5 0.299379 −0.349246 0.213713 0.021*
C6 0.3085 (6) −0.1486 (5) 0.2056 (2) 0.0145 (9)
C7 0.3258 (6) −0.0385 (5) 0.2416 (2) 0.0156 (9)
H7 0.327674 0.045766 0.219666 0.019*
C8 0.4714 (8) −0.2500 (6) 0.4519 (3) 0.0363 (13)
H8 0.599808 −0.298748 0.435626 0.044*
C9a 0.2164 (16) −0.210 (2) 0.5140 (7) 0.034 (3)
H9a 0.131097 −0.213067 0.551319 0.041*
C9′b 0.2247 (14) −0.1296 (15) 0.5129 (5) 0.040 (3)
H9′b 0.143744 −0.084873 0.551349 0.048*
C10 0.3365 (7) −0.4413 (5) 0.3355 (2) 0.0187 (9)
C11 0.2929 (6) −0.1360 (5) 0.1316 (2) 0.0201 (10)
C12 0.8294 (6) 0.1997 (5) 0.2785 (2) 0.0169 (9)
C13 0.7973 (6) 0.0888 (5) 0.2378 (2) 0.0145 (9)
C14 0.8128 (6) −0.0458 (5) 0.2655 (2) 0.0165 (9)
H14 0.827070 −0.062825 0.310684 0.020*
C15 0.8069 (6) −0.1557 (5) 0.2258 (2) 0.0133 (8)
C16 0.7715 (6) −0.1266 (5) 0.1596 (2) 0.0166 (9)
H16 0.768023 −0.199819 0.133118 0.020*
C17 0.7415 (6) 0.0111 (5) 0.1326 (2) 0.0152 (9)
C18 0.7663 (6) 0.1133 (5) 0.1712 (2) 0.0144 (8)
C19 0.8421 (6) −0.3046 (5) 0.2573 (2) 0.0172 (9)
C20 0.6722 (7) 0.0564 (5) 0.0646 (2) 0.0191 (10)
C22 0.8884 (7) 0.2623 (5) 0.0903 (2) 0.0233 (10)
H22 0.992806 0.185713 0.069206 0.028*
C23 0.6854 (8) 0.4694 (6) 0.1189 (3) 0.0332 (12)
H23 0.621033 0.570262 0.120204 0.040*

  1. aOccupancy: 0.399 (14). bOccupancy: 0.601 (14). cOccupancy: 0.606 (16). dOccupancy: 0.394 (16).

Source of material

All chemicals were available from commercial sources. MnCl2·6H2O (0.171 mmol), 2-(4H-1,2,4-triazol-4-yl)benzene-1,3,5-tricarboxylic acid (0.097 mmol) and H2O/CH3CN (4 mL, 1:3 v/v) were placed in a 15 mL PTFE vessel sealed with stainless steel reactor, heated to 120 °C for three days. Colorless crystals of the title compound with a yield of 49% were obtained through the cooling process (2 °C h−1). Elemental analysis found/calcd. (%) for C44H42Mn5N12O36: C 33.22/33.34, H 2.64/2.56, N 10.57/10.43. IR data (KBr, cm−1): 3426 (s), 1037 (s), 1614 (s), 1380 (m), 668 (m), 651 (m), 469 (w), 3727 (w), 2967 (w), 1285 (w), 784 (w), 589 (w), 530 (w), 415 (w).

Experimental details

Hydrogen atoms were generated geometrically. CCDC number 2034133 contains the crystallographic data, which has been deposited in Cambridge Crystallographic Database.

Comment

As a class of porous metal-organic framework materials, MOFs have aroused great attention and focused research due to their structural diversities and the prospects of application in the area of specific gas separation and subsequent storage, heterogeneous catalysis, fluorescence, magnetism, and electrochemistry, etc. [5], [6], [7 and references cited there].

With the development of coordination chemistry, the functionally bi-topic ligands including amino polycarboxylic acid [8] and N-containing aromatic carboxylic acid [9] are of considerable interest. Triazole-modified aromatic carboxylic compounds represent the most important class of heteropolydentate ligands capable of forming mono-, bi-, and polynuclear complexes with inorganic metals [10–13]. We herein report the synthesis and crystal structure of a novel complex [Mn5(μ4–L3−)2(μ5–HL2−)2(H2O)10]·2H2O (1) (H3L = 2-(4H-1,2,4-triazol-4-yl)benzene-1,3,5-tricarboxylic acid). The formula of 1 is established by elemental analysis. Single crystal X-ray diffraction analysis reveals that compound 1 crystallized in the triclinic space group P 1 ‾ , possessing a 3D structure. The asymmetric unit consists of two and a half crystallographically independent Mn(II) ions, one fully-deprotonated L3− and one partly deprotonated HL2− ligand, five aqua ligands as well as one lattice water molecule (cf. left part of the figure). The six-coordinated Mn1 ion is finished by four O atoms (O1, O2, O3i, O8; i = x, y+1, z) and one N atom from four L3−anions and one water molecule to form a distorted octahedral geometry, with the Mn–O length range of 2.180–2.352 Å. The Mn2 ion is surrounded by four oxygen atoms (O1, O4i, O7iii, O10iv; i = x, y+1, z, iii = x−1, y, z, iv = x−1, y+1, z,) on the equatorial plane, and two water molecules (O14, O15) in the axial positions. Mn3 ion is coordinated by water molecules: O16, O17, O16v, O17v (v = −x+2, −y+1, −z) and two N atoms from HL2− and L3− anions. Mn1 and Mn2 ions are joined by two carboxylate groups to form a [Mn2O2] unit with the Mn⃛Mn separation of 3.719 Å. And each [Mn2O2] unit is surrounded by four aromatic tricarboxylic acid molecules, which results in a three-dimensional framework (cf. right part of the figure).

Corresponding authors: Yan-Yan An and Juan-Zhi Yan, Department of Materials Science and Chemical Engineering, Taiyuan University, Taiyuan 030032, P. R. China, E-mail: , .

Funding source: Natural Science Foundation of Shanxi Province

Award Identifier / Grant number: 202103021223002

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 21671124

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: We gratefully acknowledge support by the Natural Science Foundation of Shanxi Province (202103021223002) and National Natural Science Foundation of China (21671124).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-03-21
Accepted: 2022-07-04
Published Online: 2022-07-21
Published in Print: 2022-10-26

© 2022 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of 3-(1-(2-((5-methylthiophen-2-yl)methylene)hydrazinyl)ethylidene)chroman-2,4-dione, C17H14N2O3S
  4. Crystal structure of chlorido-(η 6-toluene)(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)ruthenium(II) hexafluoridophosphate(V) ─ acetone (1/1) C22H26ClN2ORuPF6
  5. Crystal structure of 4-(((2-(3-(1-(3-(3-cyanophenyl)-6-oxopyridazin-1(6H)-yl)ethyl)phenyl) pyrimidin-5-yl)oxy)methyl)-1-methylpiperidin-1-ium chloride monohydrate, C30H33N6O2Cl
  6. The crystal structure of 2-chloro-N-((2-chlorophenyl)carbamoyl)nicotinamide, C13H9Cl2N3O2
  7. Crystal structure of 9-(t-butyl)-3,11-dihydro-6H-pyrazolo [1,5-a]pyrrolo[3′,2′:5,6]pyrido[4,3-d]pyrimidin-6-one hemihydrate, C30H32N10O3
  8. Crystal structure of di-μ2-hydroxido-tetrakis(6-methylpyridine-2-carboxylato-k2 N,O) diiron(III) trihydrate C28H32Fe2N4O13
  9. Crystal structure of catena-poly[qua-(μ2-2-aminoisophthalat-κ3 O,O′:O′′)(1,10-phenanthroline-κ2 N,N′)manganese(II)] C20H15MnN3O5
  10. Crystal structure of poly[(bis(isothiocyano)-bis(μ 2-(E)-N′-(pyridin-4-ylmethylene)isonicotinohydrazide))iron(II) – methanol – 1,4-dioxane (1/2/2), C36H44FeN10O8S2
  11. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl)propylidene)-4-hydroxybenzohydrazide, C16H15ClN2O3
  12. Crystal structure of bis(μ2-benzoato-k2O:O′)-bis(μ2-benzoato-k3O,O′:O′)dinitrato-k2O,O′-bis(phenanthroline-k2 N,N′)dierbium(III), C52H36Er2N6O14
  13. Crystal structure of 4-ethyl-2-{[(4-nitrophenyl)methyl]sulfanyl}-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C14H12N4O3S
  14. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3- (phenylamino)hexadecahydro-1H-cyclopenta[α] phenanthren-17-yl)ethan-1-one, C27H39NO
  15. Crystal structre of 1,4-bis(bromomethyl)-2,3,5,6-tetramethylbenzene, C12H16Br2
  16. Crystal structure of 2-(adamantan-1-yl)-5-(3,5-dinitrophenyl)-1,3,4-oxadiazole, C18H18N4O5
  17. Crystal structure of (E)-N′-benzylidene-4-nitrobenzohydrazide – methanol (1/1), C15H15N3O4
  18. The crystal structure of 3-(2-bromophenyl)-1,5-di-p-tolylpentane-1,5-dione, C25H23BrO2
  19. Crystal structure of catena-poly[(μ 2-4,4′-bipyridine-κ2 N:N′)-bis(4-bromobenzoato-κ1 O)zinc(II)], C24H16Br2N2O4Zn
  20. Crystal structure of 1,1′-(1,2-ethanediyl)bis(pyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2 S:S)zinc(II), C20H14N6ZnS4
  21. Crystal structure of pentacarbonyl-(μ2-propane-1,3-dithiolato-κ4 S:S,S′:S′)-(diphenyl(o-tolyl)phosphine-κ1 P)diiron (Fe-Fe), C27H23Fe2O5PS2
  22. The crystal structure of the cocrystal 4-hydroxy-3,5-dimethoxybenzoic acid–pyrazine-2-carboxamide(1/1), C14H15N3O6
  23. The crystal structure of dichlorido-bis((RS)-2-(4-chlorophenyl)-2-(1,2,4-triazol-1-ylmethyl)hexanenitrile-κ1 N)zinc(II), C30H34Cl4N8Zn
  24. Crystal structure of the cocrystal 2,4,6-triamino-1,3,5-triazine – 1H-isoindole-1,3(2H)-dione – methanol (1/1/1), C12H15N7O3
  25. The crystal structure of methyl 4-((3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)methyl) benzoate, C23H28O3
  26. Crystal structure of (poly[µ2-(1H-pyrazol-1-yl)methyl]-1H-benzotriazole-κ 2 N:N)-(nitrato-κ 2 O:O′) silver(I), C9H8AgN7O3
  27. Crystal structure of tetraaqua-bis[4-(1H-1,2,4-triazol-1-yl)benzoato-k1 N]cadmium(II), C18H20CdN6O8
  28. The crystal structure of diaqua-bis(pyrazolo[1,5-a]pyrimidine-3-carboxylato-κ2N,O)nickel(II) dihydrate, C14H16N6O8Ni
  29. Crystal structure of poly[μ2-aqua-aqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2 N:N′)-(μ2-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ2 O:O′)-(μ4-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ5 O,O′:O″:O′″:O′″)dicobalt(II)] – water – dimethylformamide (1/1/1) C44H43N11O12Co2
  30. Crystal structure of N-((Z)-amino(((E)-amino(phenylamino)methylene) amino)methylene)benzenaminium chloride – benzo[f]isoquinolino[3,4-b][1,8]naphthyridine – tetrahydrofurane (1/2/2), C60H54ClN11O2
  31. The crystal structure of Chrysosplenol D, C18H16O8
  32. Crystal structure of poly[deca aqua-bis(μ 4-2-(triazol-1-yl)-benzene-1,3,5-tricarboxylato)- bis(μ 5-2-(triazol-1-yl)-benzene-1,3-dicarboxylato-5-carboxyl acid) pentamanganese(II)] dihydrate, C44H42Mn5N12O36
  33. Synthesis and crystal structure of (E)-1-(4-(((E)-3-(tert-butyl)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C20H24N2O2
  34. The crystal structure of 4,4′-dichloro-6,6′-dimethoxy-2,2′,3,3′,5,5′- hexanitroazobenzene, C14H6N8O14Cl2
  35. Crystal structure of N 2,N 4-dimesitylpentane-2,4-diamine, C23H34N2
  36. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ 6O6)potassium(2-methylphenylamino)ethyl-2-methylphenylamide ammoniate (1/3.5), [K(18-crown-6)](o-CH3C6H4)NH(CH2)2N(o-CH3C6H4) 3.5 NH3, C28H53.5KN5.5O6
  37. The crystal structure of N′,N″,2-tris((E)-5-chloro-2-hydroxybenzylidene)hydrazine-1-carbohydrazonhydrazide hydrochloride – methanol (1/3), C25H30Cl4N6O6
  38. Crystal structure of (E)-7-bromo-2-(3,5-dimethoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C19H17BrO3
  39. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl) ethylidene)-4-hydroxybenzohydrazide, C15H13ClN2O3
  40. {2-(((2-aminoethyl)imino)methyl)-6-bromophenolato-κ3 N,N′,O}iron(III) nitrate, C18H20Br2FeN5O5
  41. Crystal structure of 2-(tert-pentyl)anthracene-9,10-dione, C19H18O2
  42. Crystal structure of 5,5′-(1,4-phenylene)bis(1H-imidazol-3-ium) bis(2-(2-(carboxymethyl)phenyl)acetate), C32H30N4O8
  43. Crystal structure of N 2,N 6-bis(2-(((E)-naphthalen-1-ylmethylene)amino)phenyl)pyridine-2,6-dicarboxamide, C41H29N5O2
  44. The crystal structure of 3-amino-1,2,4-triazolium 2,4,5-trinitroimidazolate, C5H5O6N9
  45. Hydrogen bonded dimers in the crystal structure of 2-chloro-N-(phenylcarbamoyl)nicotinamide, C26H20Cl2N6O4
  46. The crystal structure of 4,4′-bipyridine-5,6,7-trihydroxy-2-phenyl-4H-chromen-4-one-water(1/2/2), C40H32N2O12
  47. Crystal structure of N,N'-bis(4-fluoro-salicylaldehyde)-3,6-dioxa-1,8-diaminooctane, C20H22F2N2O4
  48. Crystal structure of 3-(1,3-dinitropropan-2-yl)-4H-chromen-4-one, C12H10N2O6
  49. The crystal structure of (4-(2-bromoethoxy)-phenyl)(phenyl)methanone, C15H13BrO2
  50. Crystal structure of (E)-7-bromo-2-(4-methoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H15BrO2
  51. Crystal structure of dichlorido-tetrakis((E)-(RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol-κ 1 N)cadmium(II), C60H68O4N12Cl10Cd
  52. Crystal structure of diaqua-diphenanthroline-κ2 N,N′-bis(μ2-2-carboxy-3,4,5,6-tetrafluorobenzoato-κ2 O:O′)-bis(μ2-tetrafluorophthalato-κ3 O,O′:O′)didysprosium(III) – phenanthroline (1/2), C80H38Dy2F16N8O18
  53. Crystal structure of bis(μ2-2-oxido-2-phenylacetato-κ3 O,O′:O′)-bis(N-oxido-benzamide-κ2 O,O′)-bis(propan-2-olato-κ1 O)dititanium(IV), C36H38N2O12Ti2
  54. Crystal structure of poly[diaqua-(μ2-1H-benzo[d][1,2,3]triazole-5-carboxylato-κ2 O:O′)(μ2-oxalato-κ4O,O:O″,O′″)europium(III)] monohydrate, C9H10N3O9Eu
  55. Crystal structure of bis((N-methyl-2-oxyethyl)amine)-bis(μ 2-N,N,N-tris(2-oxoethyl)amine)-bis(isopropoxy)-bis(μ 3-oxo)tetratitanium(IV)– isopropanol (1/2), C34H76N4O16Ti4
  56. Synthesis and crystal structure of ethyl 4-((4-iodobenzyl)amino)benzoate, C16H16INO2
  57. Crystal structure of (Z)-2-(tert-butyl)-5-((5-(tert- butyl)-2H-pyrrol-2-ylidene)(mesityl)methyl)-1H-pyrrole, C26H34N2
  58. Crystal structure of dimethylammonium poly[μ4-1,1′-(1,4- phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato-κ6 N,O:O′:N′,O″:O‴) manganese(II)], C22H26MnN6O8
https://doi.org/10.1515/ncrs-2022-0136
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of 3-(1-(2-((5-methylthiophen-2-yl)methylene)hydrazinyl)ethylidene)chroman-2,4-dione, C17H14N2O3S
  4. Crystal structure of chlorido-(η 6-toluene)(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)ruthenium(II) hexafluoridophosphate(V) ─ acetone (1/1) C22H26ClN2ORuPF6
  5. Crystal structure of 4-(((2-(3-(1-(3-(3-cyanophenyl)-6-oxopyridazin-1(6H)-yl)ethyl)phenyl) pyrimidin-5-yl)oxy)methyl)-1-methylpiperidin-1-ium chloride monohydrate, C30H33N6O2Cl
  6. The crystal structure of 2-chloro-N-((2-chlorophenyl)carbamoyl)nicotinamide, C13H9Cl2N3O2
  7. Crystal structure of 9-(t-butyl)-3,11-dihydro-6H-pyrazolo [1,5-a]pyrrolo[3′,2′:5,6]pyrido[4,3-d]pyrimidin-6-one hemihydrate, C30H32N10O3
  8. Crystal structure of di-μ2-hydroxido-tetrakis(6-methylpyridine-2-carboxylato-k2 N,O) diiron(III) trihydrate C28H32Fe2N4O13
  9. Crystal structure of catena-poly[qua-(μ2-2-aminoisophthalat-κ3 O,O′:O′′)(1,10-phenanthroline-κ2 N,N′)manganese(II)] C20H15MnN3O5
  10. Crystal structure of poly[(bis(isothiocyano)-bis(μ 2-(E)-N′-(pyridin-4-ylmethylene)isonicotinohydrazide))iron(II) – methanol – 1,4-dioxane (1/2/2), C36H44FeN10O8S2
  11. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl)propylidene)-4-hydroxybenzohydrazide, C16H15ClN2O3
  12. Crystal structure of bis(μ2-benzoato-k2O:O′)-bis(μ2-benzoato-k3O,O′:O′)dinitrato-k2O,O′-bis(phenanthroline-k2 N,N′)dierbium(III), C52H36Er2N6O14
  13. Crystal structure of 4-ethyl-2-{[(4-nitrophenyl)methyl]sulfanyl}-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C14H12N4O3S
  14. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3- (phenylamino)hexadecahydro-1H-cyclopenta[α] phenanthren-17-yl)ethan-1-one, C27H39NO
  15. Crystal structre of 1,4-bis(bromomethyl)-2,3,5,6-tetramethylbenzene, C12H16Br2
  16. Crystal structure of 2-(adamantan-1-yl)-5-(3,5-dinitrophenyl)-1,3,4-oxadiazole, C18H18N4O5
  17. Crystal structure of (E)-N′-benzylidene-4-nitrobenzohydrazide – methanol (1/1), C15H15N3O4
  18. The crystal structure of 3-(2-bromophenyl)-1,5-di-p-tolylpentane-1,5-dione, C25H23BrO2
  19. Crystal structure of catena-poly[(μ 2-4,4′-bipyridine-κ2 N:N′)-bis(4-bromobenzoato-κ1 O)zinc(II)], C24H16Br2N2O4Zn
  20. Crystal structure of 1,1′-(1,2-ethanediyl)bis(pyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2 S:S)zinc(II), C20H14N6ZnS4
  21. Crystal structure of pentacarbonyl-(μ2-propane-1,3-dithiolato-κ4 S:S,S′:S′)-(diphenyl(o-tolyl)phosphine-κ1 P)diiron (Fe-Fe), C27H23Fe2O5PS2
  22. The crystal structure of the cocrystal 4-hydroxy-3,5-dimethoxybenzoic acid–pyrazine-2-carboxamide(1/1), C14H15N3O6
  23. The crystal structure of dichlorido-bis((RS)-2-(4-chlorophenyl)-2-(1,2,4-triazol-1-ylmethyl)hexanenitrile-κ1 N)zinc(II), C30H34Cl4N8Zn
  24. Crystal structure of the cocrystal 2,4,6-triamino-1,3,5-triazine – 1H-isoindole-1,3(2H)-dione – methanol (1/1/1), C12H15N7O3
  25. The crystal structure of methyl 4-((3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)methyl) benzoate, C23H28O3
  26. Crystal structure of (poly[µ2-(1H-pyrazol-1-yl)methyl]-1H-benzotriazole-κ 2 N:N)-(nitrato-κ 2 O:O′) silver(I), C9H8AgN7O3
  27. Crystal structure of tetraaqua-bis[4-(1H-1,2,4-triazol-1-yl)benzoato-k1 N]cadmium(II), C18H20CdN6O8
  28. The crystal structure of diaqua-bis(pyrazolo[1,5-a]pyrimidine-3-carboxylato-κ2N,O)nickel(II) dihydrate, C14H16N6O8Ni
  29. Crystal structure of poly[μ2-aqua-aqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2 N:N′)-(μ2-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ2 O:O′)-(μ4-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ5 O,O′:O″:O′″:O′″)dicobalt(II)] – water – dimethylformamide (1/1/1) C44H43N11O12Co2
  30. Crystal structure of N-((Z)-amino(((E)-amino(phenylamino)methylene) amino)methylene)benzenaminium chloride – benzo[f]isoquinolino[3,4-b][1,8]naphthyridine – tetrahydrofurane (1/2/2), C60H54ClN11O2
  31. The crystal structure of Chrysosplenol D, C18H16O8
  32. Crystal structure of poly[deca aqua-bis(μ 4-2-(triazol-1-yl)-benzene-1,3,5-tricarboxylato)- bis(μ 5-2-(triazol-1-yl)-benzene-1,3-dicarboxylato-5-carboxyl acid) pentamanganese(II)] dihydrate, C44H42Mn5N12O36
  33. Synthesis and crystal structure of (E)-1-(4-(((E)-3-(tert-butyl)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C20H24N2O2
  34. The crystal structure of 4,4′-dichloro-6,6′-dimethoxy-2,2′,3,3′,5,5′- hexanitroazobenzene, C14H6N8O14Cl2
  35. Crystal structure of N 2,N 4-dimesitylpentane-2,4-diamine, C23H34N2
  36. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ 6O6)potassium(2-methylphenylamino)ethyl-2-methylphenylamide ammoniate (1/3.5), [K(18-crown-6)](o-CH3C6H4)NH(CH2)2N(o-CH3C6H4) 3.5 NH3, C28H53.5KN5.5O6
  37. The crystal structure of N′,N″,2-tris((E)-5-chloro-2-hydroxybenzylidene)hydrazine-1-carbohydrazonhydrazide hydrochloride – methanol (1/3), C25H30Cl4N6O6
  38. Crystal structure of (E)-7-bromo-2-(3,5-dimethoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C19H17BrO3
  39. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl) ethylidene)-4-hydroxybenzohydrazide, C15H13ClN2O3
  40. {2-(((2-aminoethyl)imino)methyl)-6-bromophenolato-κ3 N,N′,O}iron(III) nitrate, C18H20Br2FeN5O5
  41. Crystal structure of 2-(tert-pentyl)anthracene-9,10-dione, C19H18O2
  42. Crystal structure of 5,5′-(1,4-phenylene)bis(1H-imidazol-3-ium) bis(2-(2-(carboxymethyl)phenyl)acetate), C32H30N4O8
  43. Crystal structure of N 2,N 6-bis(2-(((E)-naphthalen-1-ylmethylene)amino)phenyl)pyridine-2,6-dicarboxamide, C41H29N5O2
  44. The crystal structure of 3-amino-1,2,4-triazolium 2,4,5-trinitroimidazolate, C5H5O6N9
  45. Hydrogen bonded dimers in the crystal structure of 2-chloro-N-(phenylcarbamoyl)nicotinamide, C26H20Cl2N6O4
  46. The crystal structure of 4,4′-bipyridine-5,6,7-trihydroxy-2-phenyl-4H-chromen-4-one-water(1/2/2), C40H32N2O12
  47. Crystal structure of N,N'-bis(4-fluoro-salicylaldehyde)-3,6-dioxa-1,8-diaminooctane, C20H22F2N2O4
  48. Crystal structure of 3-(1,3-dinitropropan-2-yl)-4H-chromen-4-one, C12H10N2O6
  49. The crystal structure of (4-(2-bromoethoxy)-phenyl)(phenyl)methanone, C15H13BrO2
  50. Crystal structure of (E)-7-bromo-2-(4-methoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H15BrO2
  51. Crystal structure of dichlorido-tetrakis((E)-(RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol-κ 1 N)cadmium(II), C60H68O4N12Cl10Cd
  52. Crystal structure of diaqua-diphenanthroline-κ2 N,N′-bis(μ2-2-carboxy-3,4,5,6-tetrafluorobenzoato-κ2 O:O′)-bis(μ2-tetrafluorophthalato-κ3 O,O′:O′)didysprosium(III) – phenanthroline (1/2), C80H38Dy2F16N8O18
  53. Crystal structure of bis(μ2-2-oxido-2-phenylacetato-κ3 O,O′:O′)-bis(N-oxido-benzamide-κ2 O,O′)-bis(propan-2-olato-κ1 O)dititanium(IV), C36H38N2O12Ti2
  54. Crystal structure of poly[diaqua-(μ2-1H-benzo[d][1,2,3]triazole-5-carboxylato-κ2 O:O′)(μ2-oxalato-κ4O,O:O″,O′″)europium(III)] monohydrate, C9H10N3O9Eu
  55. Crystal structure of bis((N-methyl-2-oxyethyl)amine)-bis(μ 2-N,N,N-tris(2-oxoethyl)amine)-bis(isopropoxy)-bis(μ 3-oxo)tetratitanium(IV)– isopropanol (1/2), C34H76N4O16Ti4
  56. Synthesis and crystal structure of ethyl 4-((4-iodobenzyl)amino)benzoate, C16H16INO2
  57. Crystal structure of (Z)-2-(tert-butyl)-5-((5-(tert- butyl)-2H-pyrrol-2-ylidene)(mesityl)methyl)-1H-pyrrole, C26H34N2
  58. Crystal structure of dimethylammonium poly[μ4-1,1′-(1,4- phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato-κ6 N,O:O′:N′,O″:O‴) manganese(II)], C22H26MnN6O8
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Heruntergeladen am 7.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2022-0136/html?lang=de
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