Home Crystal structure of catena-poly[qua-(μ2-2-aminoisophthalat-κ3 O,O′:O′′)(1,10-phenanthroline-κ2 N,N′)manganese(II)] C20H15MnN3O5
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Crystal structure of catena-poly[qua-(μ2-2-aminoisophthalat-κ3 O,O′:O′′)(1,10-phenanthroline-κ2 N,N′)manganese(II)] C20H15MnN3O5

  • Guang Huang ORCID logo EMAIL logo and Xinyun Chen
Published/Copyright: July 5, 2022
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 237 Issue 5

Abstract

C20H15MnN3O5, monoclinic, P21/c (no. 14), a = 10.0223(5) Å, b = 9.3406(5) Å, c = 18.6978(10) Å, β = 99.322(6)°, V = 1727.27(16) Å3, Z = 4, R gt (F) = 0.0376, wR ref (F 2) = 0.0873, T = 250 K.

CCDC no.: 2180334

A part of the polymeric title structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.20 × 0.15 × 0.10 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.81 mm−1
Diffractometer, scan mode: SuperNova, ω
θ max, completeness: 25.7°, >99%
N(hkl)measured , N(hkl)unique, R int: 7979, 3283, 0.032
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 2674
N(param)refined: 265
Programs: CrysAlisPRO [1], Olex2 [2], SHELX [3, 4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.5508 (3) 0.1990 (3) 0.50668 (14) 0.0305 (6)
H1 0.609620 0.139784 0.536921 0.037*
C2 0.5576 (3) 0.1986 (3) 0.43244 (14) 0.0331 (6)
H2 0.619747 0.140880 0.414140 0.040*
C3 0.4717 (3) 0.2840 (3) 0.38763 (14) 0.0328 (6)
H3 0.474457 0.285050 0.338159 0.039*
C4 0.3789 (2) 0.3706 (2) 0.41619 (12) 0.0247 (5)
C5 0.2835 (3) 0.4619 (3) 0.37257 (13) 0.0316 (6)
H5 0.280302 0.462893 0.322592 0.038*
C6 0.1984 (3) 0.5460 (3) 0.40232 (13) 0.0315 (6)
H6 0.138875 0.605740 0.372801 0.038*
C7 0.1125 (3) 0.6304 (3) 0.51313 (14) 0.0333 (6)
H7 0.055037 0.696047 0.486341 0.040*
C8 0.1137 (3) 0.6170 (3) 0.58550 (14) 0.0341 (6)
H8 0.057419 0.673652 0.608681 0.041*
C9 0.1998 (3) 0.5179 (3) 0.62471 (13) 0.0298 (6)
H9 0.197231 0.507279 0.673917 0.036*
C10 0.2857 (2) 0.4522 (2) 0.52276 (12) 0.0205 (5)
C11 0.3794 (2) 0.3646 (2) 0.49119 (12) 0.0218 (5)
C12 0.1984 (3) 0.5449 (2) 0.47896 (12) 0.0256 (6)
C13 0.8255 (2) 0.1026 (2) 0.67931 (12) 0.0225 (5)
C14 0.7918 (3) −0.0064 (3) 0.62948 (13) 0.0287 (6)
H14 0.703141 −0.039440 0.621272 0.034*
C15 0.8842 (3) −0.0682 (3) 0.59135 (15) 0.0347 (6)
H15 0.858572 −0.140961 0.558025 0.042*
C16 1.0159 (3) −0.0184 (3) 0.60432 (13) 0.0297 (6)
H16 1.078388 −0.056175 0.577706 0.036*
C17 1.0575 (2) 0.0857 (2) 0.65553 (12) 0.0227 (5)
C18 0.9632 (2) 0.1485 (2) 0.69585 (12) 0.0205 (5)
C19 1.2015 (2) 0.1347 (3) 0.66327 (13) 0.0257 (6)
C20 0.7149 (2) 0.1759 (3) 0.71023 (13) 0.0241 (5)
Mn1 0.42197 (4) 0.26556 (4) 0.65206 (2) 0.02141 (13)
N1 0.2854 (2) 0.4379 (2) 0.59504 (10) 0.0234 (5)
N2 0.4650 (2) 0.2793 (2) 0.53614 (10) 0.0241 (5)
N3 1.0015 (2) 0.2508 (2) 0.74562 (11) 0.0318 (5)
H3A 1.084084 0.279467 0.753634 0.038*
H3B 0.943290 0.287508 0.769420 0.038*
O1 0.59336 (15) 0.13456 (17) 0.68564 (9) 0.0276 (4)
O2 0.74090 (17) 0.27360 (19) 0.75559 (9) 0.0314 (4)
O3 1.24981 (17) 0.22105 (19) 0.71276 (9) 0.0298 (4)
O4 1.27262 (17) 0.09332 (19) 0.61735 (10) 0.0372 (5)
O1W 0.50828 (17) 0.4159 (2) 0.73466 (9) 0.0320 (4)
H1WA 0.588535 0.405971 0.757132 0.048*
H1WB 0.470972 0.472345 0.761097 0.048*

Source of material

0.10 mmol MnCl2·4H2O (0.0198 g), 0.10 mmol 2-aminoisophthalic acid (0.0181 g), 0.10 mmol 1,10-phenanthroline monohydrate (0.0198 g), and 0.20 mmol NaOH (0.008 g) was mixed well under stirring, then transferred to a 25 mL Teflon-lined reactor, heated at 413 K in an oven for 72 h, then cooled naturally. The crystals were washed with deionized water and air-dried, yield 78% based on Mn.

Experimental details

The structure was solved by direct methods with the SHELXS program. All H-atoms from C and N atoms were positioned with idealized geometry and refined isotropically (U iso(H) = 1.2U eq(C) using a riding model with C–H = 0.95 Å and N–H = 0.86 Å. The H-atoms from O atoms positioned with Q peaks refined isotropically with the distance of O–H = 0.85 Å (U iso(H) = 1.5U eq(O)).

Comment

Mn(II) can coordinate 1,10-phenanthroline with isophthalate or its derivatives to build complexes, including isophthalate [5], [6], [7], [8], [9], 4-bromoisophthalate [10], 5-methylisophthalate [11], 5-aminoiodoisophthalate [12], 5-amino-2,4,6-triiodoisophthalate [13], 5-bromoisophthalate [14], 5-iodoisophthalate [15], 5-(pyridin-4-yl)isophthalate [16], 5-phenyl-3,5-dicarboxylate [17], 5-t-butylisophthalate [18], 5-hydroxyisophthalate [19, 20], 5-nitroisophthalate [21, 22], and 5-ferroceneisophthalate [23], etc. To the best of our knowledge, there is no record of 2-substituted isophthalate based Mn(II) complexes with 1,10-phenanthroline. Thus, we reported the title complex.

The asymmetric unit consists of one Mn(II) cation, one 2-amino-isophthalate anion, one 1,10-phenanthroline and one water molecule. The Mn(II) is hexa-coordinated to form an distorted octahedron by two nitrogen atoms from one 1,10-phenanthroline, three oxygen atoms from two 2-aminoisophthalate ligands, and one atom from the coordinating water molecule. The Mn–N distances are 2.265 and 2.281 Å, and the Mn–O distances are in the range of 2.120–2.265 Å, respectively, which agree with similar reported results [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23]. The Mn(II) cations are linked by the 2-aminoisophthalates to generate 1D structure, further forming a 3D supramolecular structure by hydrogen bonds O1–H1WB⃛O1 and O1–H1WA⃛O2 and π⃛π weak interaction of the 1,10-phenanthroline molecules.

Corresponding author: Guang Huang, Sino-Portugal Belt and Road Joint Laboratory on Science of Cultural Heritage Conservation, City University of Macau, Macau, P. R. China; and Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Zhuhai, Guangdong, P. R. China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. CrysAlisPro 1.171.38.43f; Rigaku OD, 2015.Search in Google Scholar

2. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339–341. https://doi.org/10.1107/s0021889808042726.Search in Google Scholar

3. Sheldrick, G. M. Crystal structure refinement with Shelxl. Acta Crystallogr. 2015, C71, 3–8. https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

4. Sheldrick, G. Using phases to determine the space group. Acta Crystallogr. 2018, A74, a353. https://doi.org/10.1107/s0108767318096472.Search in Google Scholar

5. Tan, X. S., Sun, J., Xiang, D. F., Tang, W. X. Synthesis, crystal structure and magnetic properties of an isophthalate-bridged manganese(II) chain complex. Inorg. Chim. Acta. 1997, 255, 157–161. https://doi.org/10.1016/s0020-1693(96)05396-0.Search in Google Scholar

6. Devereux, M., McCann, M., Leon, V., Geraghty, M., McKee, V., Wikaira, J. Synthesis and biogical activity of manganese (II) complexes of phthalic and isophtalic acid: X-ray crystal structures of [Mn(ph)(Phen)2(H2O)2]·4H2O, [Mn(Phen)2(H2O)]2(Isoph)(Phen)·12H2O and {[Mn(Isoph)(bipy)]4·2.75bipy} (phH2 = phthalic acid; isoph = isophathalic acid; phen = 1,10-phenanthrolin; bipy = 2,2-bipyridine). Met. Based Drugs 2000, 7, 275–288. https://doi.org/10.1155/mbd.2000.275.Search in Google Scholar

7. Nie, J., Liu, L., Luo, Y., Xu, D. Synthesis and structure of a polymeric 1,3-benzenedicarboxylato complex of Mn(II) with phenanthorine. J. Coord. Chem. 2001, 53, 365–371. https://doi.org/10.1080/00958970108022623.Search in Google Scholar

8. Bi, W.-H., Sun, D.-F., Cao, R., Li, X., Shi, Q. Hydrothermal synthesis and crystal structure of [Mn(phen)-(m-phth)]n (phen=1,10-phenanthroline, m-phth=isophthalate). Chin. J. Chem. 2004, 22, 271–274.10.1002/cjoc.20040220312Search in Google Scholar

9. Liu, D.-W., Zhang, L., Niu, S.-Y., Li, L., Shi, Z.-F., Jin, J., Chi, Y.-X. Synthesis, crystal structure and photo-physical property of manganese(II) coordination polymers. Chin. J. Inorg. Chem. 2009, 25, 2175–2181.Search in Google Scholar

10. Xiao, H.-P., Hu, M.-L., Yuan, J.-X. Bis(μ-4-bromo-isophthalato)-bis-[bis(1,10-phenanthroline)-manganese(II)] tetrahydrate. Acta Crystallogr. 2005, E61, m443–m445. https://doi.org/10.1107/s1600536805003004.Search in Google Scholar

11. Yu, Z.-L., Hu, J.-L. catena–Poly[[(1,10-phenanthroline) manganese(II)]-μ3-5-methyl-isophthalato]. Acta Crystallogr. 2008, E64, m1522. https://doi.org/10.1107/s1600536808036362.Search in Google Scholar

12. Wang, J.-J., Bao, Q.-L., Chen, J.-X. Two 2-D layered coordination polymers based on 5-aminoisophthalate and 1,10-phenanthroline. J. Coord. Chem. 2013, 66, 2578–2586. https://doi.org/10.1080/00958972.2013.813939.Search in Google Scholar

13. Zhang, K.-L., Chang, Y., Zhang, J.-B., Yuan, L.-M., Deng, Y., Diao, G.-W., Ng, S. W. Synthesis, crystal structures and characterization of four coordination polymers based on 5-amino-2,4,6-triiodoisophthalic acid. J. Solid State Chem. 2011, 184, 1263–1272. https://doi.org/10.1016/j.jssc.2011.03.050.Search in Google Scholar

14. Wang, C.-C., Gao, F., Guo, X,-X., Jing, H.-P., Wang, P., Gao, S.-J. Hydrothermal syntheses and photocatalytic performance of three Mn-based coordination complexes constructed from 1,10-phenanthroline and polycarboxylic acids. Trans. Met. Chem. 2016, 41, 375–385. https://doi.org/10.1007/s11243-016-0033-8.Search in Google Scholar

15. Zang, S.-Q., Fan, Y.-J., Li, J.-B., Hou, H.-W., Mak, T. C. W. Halogen bonding in the assembly of coordination polymers based on 5-iodo-isophthalic acid. Cryst. Growth Des. 2011, 11, 3395–3405. https://doi.org/10.1021/cg200022j.Search in Google Scholar

16. Gao, Z.-Q., Li, H.-J., Kirillov, A. M., Gu, J.-Z. Syntheses, crystal structures and magnetic properties of cobalt(II) and manganese(II) coordination polymers constructed from 5-(pyridin-4-yl)isophthalate ligands. Chin. J. Struct. Chem. 2014, 33, 626–634.Search in Google Scholar

17. Jiang, J., Huang, W., Xu, J., Pan, F.-F., Wu, D.-Y. Influence of steric hindrance of N-heterocyclic ancillary ligands on the structur and magnetic properties of manganese(II) coordination polymers. Z. Anorg. Allg. Chem. 2016, 642, 197–202. https://doi.org/10.1002/zaac.201500707.Search in Google Scholar

18. Jin, R.-F., Yang, S.-Y., Li, H.-M., Long, L.-S., Huang, R.-B., Zheng, L.-S. Effect of ionic radius on the assemblies of first row transition metal-5-tert-butylisophthalates-(2,2′-bipyridine or phenanthroline) coordination compounds. CrystEngComm 2012, 14, 1301–1316. https://doi.org/10.1039/c1ce05959a.Search in Google Scholar

19. Skakle, J. M. S., Foreman, M. R. S. J., Plater, M. J. catena–Poly-[[[(1,10-phenanthroline)-manganese(II)]-μ-(1-hydroxybenzene-3,5-dicarboxylato)]hydrate]. Acta Crystallogr. 2001, E57, m373–m375. https://doi.org/10.1107/s1600536801011758.Search in Google Scholar

20. Kariem, M., Yawer, M., Sheikh, H. N. Solvent induced synthesis, structure and properties of coordination polymers based on 5-hydroxyisophthalic acid as linker and 1,10-phenanthroline as auxiliary ligand. J. Solid State Chem. 2015, 231, 239–247. https://doi.org/10.1016/j.jssc.2015.08.036.Search in Google Scholar

21. Wang, H.-D., Li, M.-M., He, H.-Y., Jiang, F.-B. Poly[bis-(μ-3-5-nitroisophthalato)bis(1,10-phenanthroline) dimanganese(II)]. Acta Crystallogr. 2009, E65, m416. https://doi.org/10.1107/s1600536809009052.Search in Google Scholar PubMed PubMed Central

22. Li, X. M., Wang, Q.-W., Liu, B., Wang, Z.-T. Hydrothermal synthesis and crystal structure of a Mn(II) coordination polymer assembled by 5-nitroisophthalic acid and 1,10-phenanthroline. Chin. J. Inorg. Chem. 2011, 27, 1207–1211.Search in Google Scholar

23. Li, X., Wu, B.-L., Liu, W., Niu, C.-Y., Niu, Y.-Y., Zhang, H.-Y. Syntheses, crystal structures, and magnetic properties of five new coordination compounds bearing ferrocenedicarboxylate ligands. J. Coord. Chem. 2009, 62, 3142–3156. https://doi.org/10.1080/00958970903045280.Search in Google Scholar
Received: 2022-04-08
Accepted: 2022-06-20
Published Online: 2022-07-05
Published in Print: 2022-10-26

© 2022 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  50. Crystal structure of (E)-7-bromo-2-(4-methoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H15BrO2
  51. Crystal structure of dichlorido-tetrakis((E)-(RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol-κ 1 N)cadmium(II), C60H68O4N12Cl10Cd
  52. Crystal structure of diaqua-diphenanthroline-κ2 N,N′-bis(μ2-2-carboxy-3,4,5,6-tetrafluorobenzoato-κ2 O:O′)-bis(μ2-tetrafluorophthalato-κ3 O,O′:O′)didysprosium(III) – phenanthroline (1/2), C80H38Dy2F16N8O18
  53. Crystal structure of bis(μ2-2-oxido-2-phenylacetato-κ3 O,O′:O′)-bis(N-oxido-benzamide-κ2 O,O′)-bis(propan-2-olato-κ1 O)dititanium(IV), C36H38N2O12Ti2
  54. Crystal structure of poly[diaqua-(μ2-1H-benzo[d][1,2,3]triazole-5-carboxylato-κ2 O:O′)(μ2-oxalato-κ4O,O:O″,O′″)europium(III)] monohydrate, C9H10N3O9Eu
  55. Crystal structure of bis((N-methyl-2-oxyethyl)amine)-bis(μ 2-N,N,N-tris(2-oxoethyl)amine)-bis(isopropoxy)-bis(μ 3-oxo)tetratitanium(IV)– isopropanol (1/2), C34H76N4O16Ti4
  56. Synthesis and crystal structure of ethyl 4-((4-iodobenzyl)amino)benzoate, C16H16INO2
  57. Crystal structure of (Z)-2-(tert-butyl)-5-((5-(tert- butyl)-2H-pyrrol-2-ylidene)(mesityl)methyl)-1H-pyrrole, C26H34N2
  58. Crystal structure of dimethylammonium poly[μ4-1,1′-(1,4- phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato-κ6 N,O:O′:N′,O″:O‴) manganese(II)], C22H26MnN6O8
https://doi.org/10.1515/ncrs-2022-0182
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of 3-(1-(2-((5-methylthiophen-2-yl)methylene)hydrazinyl)ethylidene)chroman-2,4-dione, C17H14N2O3S
  4. Crystal structure of chlorido-(η 6-toluene)(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)ruthenium(II) hexafluoridophosphate(V) ─ acetone (1/1) C22H26ClN2ORuPF6
  5. Crystal structure of 4-(((2-(3-(1-(3-(3-cyanophenyl)-6-oxopyridazin-1(6H)-yl)ethyl)phenyl) pyrimidin-5-yl)oxy)methyl)-1-methylpiperidin-1-ium chloride monohydrate, C30H33N6O2Cl
  6. The crystal structure of 2-chloro-N-((2-chlorophenyl)carbamoyl)nicotinamide, C13H9Cl2N3O2
  7. Crystal structure of 9-(t-butyl)-3,11-dihydro-6H-pyrazolo [1,5-a]pyrrolo[3′,2′:5,6]pyrido[4,3-d]pyrimidin-6-one hemihydrate, C30H32N10O3
  8. Crystal structure of di-μ2-hydroxido-tetrakis(6-methylpyridine-2-carboxylato-k2 N,O) diiron(III) trihydrate C28H32Fe2N4O13
  9. Crystal structure of catena-poly[qua-(μ2-2-aminoisophthalat-κ3 O,O′:O′′)(1,10-phenanthroline-κ2 N,N′)manganese(II)] C20H15MnN3O5
  10. Crystal structure of poly[(bis(isothiocyano)-bis(μ 2-(E)-N′-(pyridin-4-ylmethylene)isonicotinohydrazide))iron(II) – methanol – 1,4-dioxane (1/2/2), C36H44FeN10O8S2
  11. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl)propylidene)-4-hydroxybenzohydrazide, C16H15ClN2O3
  12. Crystal structure of bis(μ2-benzoato-k2O:O′)-bis(μ2-benzoato-k3O,O′:O′)dinitrato-k2O,O′-bis(phenanthroline-k2 N,N′)dierbium(III), C52H36Er2N6O14
  13. Crystal structure of 4-ethyl-2-{[(4-nitrophenyl)methyl]sulfanyl}-6-oxo-1,6-dihydropyrimidine-5-carbonitrile, C14H12N4O3S
  14. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3- (phenylamino)hexadecahydro-1H-cyclopenta[α] phenanthren-17-yl)ethan-1-one, C27H39NO
  15. Crystal structre of 1,4-bis(bromomethyl)-2,3,5,6-tetramethylbenzene, C12H16Br2
  16. Crystal structure of 2-(adamantan-1-yl)-5-(3,5-dinitrophenyl)-1,3,4-oxadiazole, C18H18N4O5
  17. Crystal structure of (E)-N′-benzylidene-4-nitrobenzohydrazide – methanol (1/1), C15H15N3O4
  18. The crystal structure of 3-(2-bromophenyl)-1,5-di-p-tolylpentane-1,5-dione, C25H23BrO2
  19. Crystal structure of catena-poly[(μ 2-4,4′-bipyridine-κ2 N:N′)-bis(4-bromobenzoato-κ1 O)zinc(II)], C24H16Br2N2O4Zn
  20. Crystal structure of 1,1′-(1,2-ethanediyl)bis(pyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2 S:S)zinc(II), C20H14N6ZnS4
  21. Crystal structure of pentacarbonyl-(μ2-propane-1,3-dithiolato-κ4 S:S,S′:S′)-(diphenyl(o-tolyl)phosphine-κ1 P)diiron (Fe-Fe), C27H23Fe2O5PS2
  22. The crystal structure of the cocrystal 4-hydroxy-3,5-dimethoxybenzoic acid–pyrazine-2-carboxamide(1/1), C14H15N3O6
  23. The crystal structure of dichlorido-bis((RS)-2-(4-chlorophenyl)-2-(1,2,4-triazol-1-ylmethyl)hexanenitrile-κ1 N)zinc(II), C30H34Cl4N8Zn
  24. Crystal structure of the cocrystal 2,4,6-triamino-1,3,5-triazine – 1H-isoindole-1,3(2H)-dione – methanol (1/1/1), C12H15N7O3
  25. The crystal structure of methyl 4-((3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)methyl) benzoate, C23H28O3
  26. Crystal structure of (poly[µ2-(1H-pyrazol-1-yl)methyl]-1H-benzotriazole-κ 2 N:N)-(nitrato-κ 2 O:O′) silver(I), C9H8AgN7O3
  27. Crystal structure of tetraaqua-bis[4-(1H-1,2,4-triazol-1-yl)benzoato-k1 N]cadmium(II), C18H20CdN6O8
  28. The crystal structure of diaqua-bis(pyrazolo[1,5-a]pyrimidine-3-carboxylato-κ2N,O)nickel(II) dihydrate, C14H16N6O8Ni
  29. Crystal structure of poly[μ2-aqua-aqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2 N:N′)-(μ2-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ2 O:O′)-(μ4-4,4′-(1H-1,2,4-triazole-3,5-diyl)dibenzoato-κ5 O,O′:O″:O′″:O′″)dicobalt(II)] – water – dimethylformamide (1/1/1) C44H43N11O12Co2
  30. Crystal structure of N-((Z)-amino(((E)-amino(phenylamino)methylene) amino)methylene)benzenaminium chloride – benzo[f]isoquinolino[3,4-b][1,8]naphthyridine – tetrahydrofurane (1/2/2), C60H54ClN11O2
  31. The crystal structure of Chrysosplenol D, C18H16O8
  32. Crystal structure of poly[deca aqua-bis(μ 4-2-(triazol-1-yl)-benzene-1,3,5-tricarboxylato)- bis(μ 5-2-(triazol-1-yl)-benzene-1,3-dicarboxylato-5-carboxyl acid) pentamanganese(II)] dihydrate, C44H42Mn5N12O36
  33. Synthesis and crystal structure of (E)-1-(4-(((E)-3-(tert-butyl)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C20H24N2O2
  34. The crystal structure of 4,4′-dichloro-6,6′-dimethoxy-2,2′,3,3′,5,5′- hexanitroazobenzene, C14H6N8O14Cl2
  35. Crystal structure of N 2,N 4-dimesitylpentane-2,4-diamine, C23H34N2
  36. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ 6O6)potassium(2-methylphenylamino)ethyl-2-methylphenylamide ammoniate (1/3.5), [K(18-crown-6)](o-CH3C6H4)NH(CH2)2N(o-CH3C6H4) 3.5 NH3, C28H53.5KN5.5O6
  37. The crystal structure of N′,N″,2-tris((E)-5-chloro-2-hydroxybenzylidene)hydrazine-1-carbohydrazonhydrazide hydrochloride – methanol (1/3), C25H30Cl4N6O6
  38. Crystal structure of (E)-7-bromo-2-(3,5-dimethoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C19H17BrO3
  39. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl) ethylidene)-4-hydroxybenzohydrazide, C15H13ClN2O3
  40. {2-(((2-aminoethyl)imino)methyl)-6-bromophenolato-κ3 N,N′,O}iron(III) nitrate, C18H20Br2FeN5O5
  41. Crystal structure of 2-(tert-pentyl)anthracene-9,10-dione, C19H18O2
  42. Crystal structure of 5,5′-(1,4-phenylene)bis(1H-imidazol-3-ium) bis(2-(2-(carboxymethyl)phenyl)acetate), C32H30N4O8
  43. Crystal structure of N 2,N 6-bis(2-(((E)-naphthalen-1-ylmethylene)amino)phenyl)pyridine-2,6-dicarboxamide, C41H29N5O2
  44. The crystal structure of 3-amino-1,2,4-triazolium 2,4,5-trinitroimidazolate, C5H5O6N9
  45. Hydrogen bonded dimers in the crystal structure of 2-chloro-N-(phenylcarbamoyl)nicotinamide, C26H20Cl2N6O4
  46. The crystal structure of 4,4′-bipyridine-5,6,7-trihydroxy-2-phenyl-4H-chromen-4-one-water(1/2/2), C40H32N2O12
  47. Crystal structure of N,N'-bis(4-fluoro-salicylaldehyde)-3,6-dioxa-1,8-diaminooctane, C20H22F2N2O4
  48. Crystal structure of 3-(1,3-dinitropropan-2-yl)-4H-chromen-4-one, C12H10N2O6
  49. The crystal structure of (4-(2-bromoethoxy)-phenyl)(phenyl)methanone, C15H13BrO2
  50. Crystal structure of (E)-7-bromo-2-(4-methoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C18H15BrO2
  51. Crystal structure of dichlorido-tetrakis((E)-(RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol-κ 1 N)cadmium(II), C60H68O4N12Cl10Cd
  52. Crystal structure of diaqua-diphenanthroline-κ2 N,N′-bis(μ2-2-carboxy-3,4,5,6-tetrafluorobenzoato-κ2 O:O′)-bis(μ2-tetrafluorophthalato-κ3 O,O′:O′)didysprosium(III) – phenanthroline (1/2), C80H38Dy2F16N8O18
  53. Crystal structure of bis(μ2-2-oxido-2-phenylacetato-κ3 O,O′:O′)-bis(N-oxido-benzamide-κ2 O,O′)-bis(propan-2-olato-κ1 O)dititanium(IV), C36H38N2O12Ti2
  54. Crystal structure of poly[diaqua-(μ2-1H-benzo[d][1,2,3]triazole-5-carboxylato-κ2 O:O′)(μ2-oxalato-κ4O,O:O″,O′″)europium(III)] monohydrate, C9H10N3O9Eu
  55. Crystal structure of bis((N-methyl-2-oxyethyl)amine)-bis(μ 2-N,N,N-tris(2-oxoethyl)amine)-bis(isopropoxy)-bis(μ 3-oxo)tetratitanium(IV)– isopropanol (1/2), C34H76N4O16Ti4
  56. Synthesis and crystal structure of ethyl 4-((4-iodobenzyl)amino)benzoate, C16H16INO2
  57. Crystal structure of (Z)-2-(tert-butyl)-5-((5-(tert- butyl)-2H-pyrrol-2-ylidene)(mesityl)methyl)-1H-pyrrole, C26H34N2
  58. Crystal structure of dimethylammonium poly[μ4-1,1′-(1,4- phenylenebis(methylene))bis(1H-pyrazole-3,5-dicarboxylato-κ6 N,O:O′:N′,O″:O‴) manganese(II)], C22H26MnN6O8
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