Home The crystal structure of bis((E)-2-((tert-butylimino)methyl)-4-chlorophenolato-κ2N,O)zinc(II), C22H26Cl2N2O2Zn
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The crystal structure of bis((E)-2-((tert-butylimino)methyl)-4-chlorophenolato-κ2N,O)zinc(II), C22H26Cl2N2O2Zn

  • Qian-Zhi Yang , Yu-Xin Yang , Jin-Hao Kuang , Zhong-Yan Li EMAIL logo and Lin Yuan ORCID logo EMAIL logo
Published/Copyright: March 22, 2022
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 237 Issue 3

Abstract

C22H26Cl2N2O2Zn, monoclinic, P21/n (no. 14), a = 10.488(7) Å, b = 10.139(7) Å, c = 22.760(15) Å, β = 99.705°, V = 2386(3) Å3, Z = 4, R gt (F) = 0.0395, wR ref (F2) = 0.1053, T = 296(2) K.

CCDC no.: 2104194

The molecular structure is shown in Figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Block
Size: 039×0.37×0.32 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 1.27 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω
θmax, completeness: 25.0°, >99%
N(hkl)measured, N(hkl)unique, Rint: 21,975, 4208, 0.022
Criterion for Iobs, N(hkl)gt: Iobs > 2σ(Iobs), 3749
N(param)refined: 269
Programs: Bruker [1], SHELX [2, 3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
C1 0.5995 (3) 0.2509 (3) 0.83077 (13) 0.0468 (7)
C2 0.5307 (3) 0.3638 (3) 0.84439 (13) 0.0479 (7)
C3 0.5220 (3) 0.3852 (4) 0.90477 (15) 0.0602 (8)
H3 0.477820 0.459169 0.914832 0.072*
C4 0.5759 (4) 0.3019 (4) 0.94885 (16) 0.0676 (10)
H4 0.569398 0.319941 0.988300 0.081*
C5 0.6403 (4) 0.1904 (4) 0.93484 (16) 0.0724 (10)
C6 0.6530 (4) 0.1659 (4) 0.87754 (16) 0.0656 (9)
H6 0.697992 0.091333 0.868879 0.079*
C7 0.6265 (3) 0.2160 (3) 0.77272 (14) 0.0487 (7)
H7 0.681693 0.144516 0.771691 0.058*
C8 0.6306 (3) 0.2224 (3) 0.66711 (14) 0.0540 (8)
C9 0.6852 (7) 0.0843 (5) 0.6723 (2) 0.120 (2)
H9A 0.757108 0.080710 0.704495 0.180*
H9B 0.713665 0.060668 0.635735 0.180*
H9C 0.619537 0.023707 0.679854 0.180*
C10 0.7323 (7) 0.3157 (7) 0.6552 (3) 0.173 (4)
H10A 0.699773 0.404319 0.654814 0.259*
H10B 0.756006 0.295834 0.617272 0.259*
H10C 0.806776 0.307431 0.685913 0.259*
C11 0.5185 (6) 0.2248 (8) 0.6173 (2) 0.145 (3)
H11A 0.451245 0.168738 0.626949 0.217*
H11B 0.545499 0.193922 0.581494 0.217*
H11C 0.486592 0.313433 0.611474 0.217*
C12 0.3291 (3) 0.6265 (3) 0.61896 (12) 0.0434 (6)
C13 0.4603 (3) 0.6507 (3) 0.64277 (14) 0.0491 (7)
C14 0.5204 (4) 0.7571 (3) 0.61840 (18) 0.0690 (10)
H14 0.606939 0.774886 0.633021 0.083*
C15 0.4561 (4) 0.8352 (4) 0.57401 (18) 0.0712 (10)
H15 0.498993 0.904379 0.558884 0.085*
C16 0.3279 (4) 0.8111 (3) 0.55180 (15) 0.0609 (9)
C17 0.2658 (3) 0.7094 (3) 0.57353 (14) 0.0545 (8)
H17 0.179186 0.694087 0.558065 0.065*
C18 0.2506 (3) 0.5234 (3) 0.63836 (13) 0.0441 (6)
H18 0.163975 0.523567 0.620653 0.053*
C19 0.1828 (3) 0.3364 (3) 0.69065 (15) 0.0517 (7)
C20 0.0961 (5) 0.2880 (5) 0.6346 (2) 0.1034 (17)
H20A 0.043649 0.359561 0.616584 0.155*
H20B 0.041286 0.218665 0.644755 0.155*
H20C 0.148417 0.255011 0.607097 0.155*
C21 0.1029 (5) 0.4042 (5) 0.7313 (2) 0.0962 (15)
H21A 0.158349 0.432471 0.766995 0.144*
H21B 0.039513 0.343726 0.741398 0.144*
H21C 0.060000 0.479384 0.711273 0.144*
C22 0.2519 (4) 0.2214 (5) 0.7239 (3) 0.1036 (18)
H22A 0.304695 0.178342 0.699035 0.155*
H22B 0.189494 0.160066 0.734129 0.155*
H22C 0.305548 0.252541 0.759530 0.155*
Cl1 0.7118 (2) 0.08261 (17) 0.99087 (6) 0.1442 (7)
Cl2 0.24555 (13) 0.91344 (12) 0.49620 (5) 0.0953 (4)
N1 0.5846 (2) 0.2705 (2) 0.72221 (10) 0.0431 (5)
N2 0.2841 (2) 0.4317 (2) 0.67665 (11) 0.0420 (5)
O1 0.4771 (2) 0.4484 (2) 0.80495 (10) 0.0632 (6)
O2 0.5291 (2) 0.5823 (2) 0.68545 (11) 0.0637 (6)
Zn1 0.46723 (3) 0.42824 (3) 0.72054 (2) 0.04662 (14)

Source of material

(E)-2-((tert-Butylimino)methyl)-4-chlorophenol (1.16 g, 5.5 mmol), zinc acetate monohydrate (0.50 g, 2.5 mmol) and ethanol (80 mL) were heated and stirred at 373 K for 6 h, then cooled to room temperature, resulting in a yellow solution. Crystals of the title compound were obtained by slow evaporation within three days.

Experimental details

All hydrogen atoms were identified in difference Fourier syntheses. The Uiso values of the hydrogen atoms of methyl groups were set to 1.5Ueq(C) and the Uiso values of all other hydrogen atoms were set to 1.2Ueq(C).

Comment

Salicylaldehyde Schiff base is a kind of ligand, which can form complexes with many metal ions [4], [5], [6], [7]. Salicylaldehyde Schiff base metal complexes are widely used in catalysis and so on [8], [9], [10].

The crystal structure shows that the zinc complex has a distorted tetrahedral structure and the Zn is four-coordinated by two phenol oxygen atoms and imine nitrogen atoms of two Schiff bases. The Zn–O distance (O1–Zn1 = 1.917(3) Å; O2–Zn1 = 1.917(2) Å) and the Zn–N length (N1–Zn1 = 2.014(3) Å; N2–Zn1 = 2.010(3) Å) are similar to those seen in related complexes [11, 12]. The C=N bond distance is 1.285(4) Å (C7=N1) and 1.282(4) Å (C18=N2), respectively. The O–Zn–N bond angles are 97.81(9)° (O1–Zn1–N1) and 98.11(10)° (O2–Zn1–N2). Moreover, the coordination of the two NO bidentate chelate ligands to the Zn ion results in the formation of two six-membered rings.

Corresponding authors: Zhong-Yan Li and Lin Yuan, College of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou, Hunan 425199, P. R. China, E-mail: (Z.-Y. Li), (L. Yuan) (L. Yuan)

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: Natural Science Foundation of Hunan Province of China (2021JJ30291), the Scientific Research Fund of Hunan Provincial Education Department (21A0518, 21C0691), Undergraduate Training Program for Innovation and Entrepreneurship of Hunan Province of China ([2021]197-3585), Undergraduate Training Program for Innovation and Entrepreneurship of Hunan University of Science and Enginerring (2021), Yongzhou Guiding Science and Technology Plan (2021), the construct program of applied characteristic discipline in Hunan University of Science and Engineering.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. APEX3, SAINT-Plus, XPREP; Bruker AXS Inc.: Madison, Wisconsin, USA, 2016.Search in Google Scholar

2. Sheldrick, G. M. SHELXTL – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Search in Google Scholar

3. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

4. Khorshidifard, M., Rudbari, H. A., Askari, B., Sahihi, M., Farsani, M. R., Jalilian, F., Bruno, G. Cobalt(II), copper(II), zinc(II) and palladium(II) Schiff base complexes: synthesis, characterization and catalytic performance in selective oxidation of sulfides using hydrogen peroxide under solvent-free conditions. Polyhedron 2015, 95, 1–13; https://doi.org/10.1016/j.poly.2015.03.041.Search in Google Scholar

5. Behzad, M., Ghomi, L. S., Damercheli, M., Mehravi, B., Ardestani, M. S., Jahromi, H. S., Abbasi, Z. Crystal structures and in vitro anticancer studies on new unsymmetrical copper(II) Schiff base complexes derived from meso-1,2-diphenyl-1,2-ethylenediamine: a comparison with related symmetrical ones. J. Coord. Chem. 2016, 69, 2469–2481; https://doi.org/10.1080/00958972.2016.1198786.Search in Google Scholar

6. Peng, G., Qian, Y.-F., Wang, Z.-W., Chen, Y., Yadav, T., Fink, K., Ren, X.-M. Tuning the coordination geometry and magnetic relaxation of Co(II) single-ion magnets by varying the ligand substitutions. Cryst. Growth Des. 2021, 21, 1035–1044; https://doi.org/10.1021/acs.cgd.0c01372.Search in Google Scholar

7. Dayan, S., Tercan, M., Özdemir, F. A., Aykutog̃lu, G., Özdemir, N., Şerbetçi, Z., Dinçer, M., Dayan, O. Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety. Polyhedron 2021, 1996, 115106; https://doi.org/10.1016/j.poly.2021.115106.Search in Google Scholar

8. Cozzi, P. G. Metal-Salen Schiff base complexes in catalysis: practical aspects. Chem. Soc. Rev 2004, 33, 410–421; https://doi.org/10.1039/b307853c.Search in Google Scholar

9. Raman, N., Raja, S. J. DNA cleavage, structural elucidation and anti-microbial studies of three novel mixed ligand Schiff base complexes of copper(II). J. Serb. Chem. Soc. 2007, 72, 983–992; https://doi.org/10.2298/jsc0710983r.Search in Google Scholar

10. Yilmaz, I., Cukurovali, A. Synthesis, characterization and antimicrobial activity of the Schiff bases derived from 2,4-disubstituted thiazoles and 3-methoxysalicylaldehyde, and their cobalt(II), copper(II), nickel(II) and zinc(II) complexes. Trans. Met. Chem. 2003, 28, 399–404.10.1023/A:1023630209043Search in Google Scholar

11. Tsai, M.-J., Su, Y.-T., Wu, J.-Y. Anion effect on the formation of zinc-salicyaldimine compounds in neutral and anionic complex forms: synthesis, characterization, 1H NMR studies, and photophysical properties. Eur. J. Inorg. Chem. 2021, 21, 1035–1044.10.1002/ejic.202100377Search in Google Scholar

12. Khorshidifard, M., Rudbari, H. A., Askari, B., Sahihi, M., Farsani, M. R., Jalilian, F., Bruno, G. Cobalt(II), copper(II), zinc(II) and palladium(II) Schiff base complexes: synthesis, characterization and catalytic performance in selective oxidation of sulfides using hydrogen peroxide under solvent-free conditions. Polyhedron 2015, 95, 1–13; https://doi.org/10.1016/j.poly.2015.03.041.Search in Google Scholar
Received: 2022-01-25
Accepted: 2022-03-11
Published Online: 2022-03-22
Published in Print: 2022-06-27

© 2022 Qian-Zhi Yang et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of (E)-(4-imidazol-1-yl-phenyl)-(2-methoxy-benzylidene)-amine monohydrate, C17H17N3O2
  4. Crystal structure of 6-methyl-3-(pyrrolidine-1-carbonyl)-2H-chromen-2-one, C15H15N1O3
  5. Crystal structure of 4-methyl-4-nitropentanoic acid, C6H11NO4
  6. The crystal structure of (E)-3-(furan-2-yl)acrylonitrile, C7H5NO
  7. Crystal structure of 3-(difluoromethyl)-1-methyl-N-(4,11,11-trimethyl-1,2,3,4-tetrahydro-1,4-methanoacridin-9-yl)-1H-pyrazole-4-carboxamide monohydrate, C23H26F2N4O3
  8. Crystal structure of 2-(4-bromobenzyloxy)-6-chloropyridine, C12H9BrClNO
  9. Crystal structure of N-(4-bromo-2,6-dichloro-phenyl)pyrazin-2-amine, C10H6BrCl2N3
  10. Crystal structure of (E)-1-(2–nitrophenyl)-3-phenylprop-2-en-1-one, C15H11NO3
  11. The crystal structure of (E)-3-chloro-2-(2-(4-fluorobenzylidene)hydrazinyl)pyridine, C12H9ClFN3
  12. Crystal structure of (E)-amino(2-(thiazol-2-ylmethylene)hydrazineyl)methaniminium nitrate, C10H16N12O6S2
  13. Crystal structure of 9-methoxy-2,3,4,4a,5,6-hexahydro-1H-pyrido [1′,2′:1,6]pyrazino[2,3-b]quinoxaline, C15H18N4O
  14. The crystal structure bis(dimethylsulfoxide-κ1O)-dipyridine-κ1 N-bis(m2-(Z)-3-methyl-2-oxido-N-((Z)-oxido(phenyl)methylene)benzohydrazonato-κ5)trinickel(II) - dimethylsulfoxide (1/2), C48H56N6Ni3O10S4
  15. Crystal structure of bis(bis(triphenylphosphine)iminium) tetradecacarbonyltetratelluridopentaferrate(2-), (PPN)2[Fe5Te4(CO)14]
  16. Crystal structure of 4-Hydroxy-3-(naphthalen-2-ylthio)pent-3-en-2-one, C15H14O2S
  17. The crystal structure of [(1,10-phenanthroline-κ2 N,N)-bis(6-phenylpyridine-2-carboxylate-κ2 N,O)nickel(II)] monohydrate, C36H26N4O5Ni
  18. Crystal structure of 3,3′-(pyridine-2,6-diylbis(methylene))bis(1-propyl-1H-imidazol-3-ium) ditetrafluoroborate, C19H27B2F8N5
  19. The crystal structure of (E)-1-(4-aminophenyl)-3-(p-tolyl)prop-2-en-1-one, C16H15NO
  20. The crystal structure of poly[(μ2-terephthalato-κ4O,O′: O″,O‴)-(μ4-terephthalato-κ4O:O′:O″:O‴)-{μ4-(1,2,4,5-tetrakis(1,2,4-triazol-1-ylmethyl)-benzene-κ4O:O′:O″,O‴)}dicadmium(II)] – water – acetronitrile (1/2/2), C38H36N14O10Cd2
  21. The crystal structure of diaqua-bis(6-phenylpyridine-2-carboxylato-κ2 N,O)cobalt(II)–water–N,N-dimethylformamide(1/2/1), C27H31N3O9Co
  22. The co-crystal structure of 4-hydroxy-3-methoxybenzoic acid – 4,4′-bipyridine, C8H8O4·C10H8N2
  23. Crystal structure of catena-poly[(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-κ2N:N′)-bis(4-bromobenzoate-κ1O)cobalt(II)], C32H22Br2CoN4O4
  24. Crystal structure of (E)-5-propyl-4-((pyridin-2-ylmethylene)amino)-2,4-dihydro-3H-1,2,4-triazole-3-thione – methanol (1/1), C11H13N5S
  25. The crystal structure of (Z)-4-bromo-6-(((1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)amino)methylene)cyclohexa-2,4-dien-1-one monohydrate, C11H16BrNO5
  26. Crystal structure of bis(tetrapropylammonium) nonaselenidotetrastannate(IV), (Pr4N)2[Sn4Se9]
  27. Crystal structure of 2,6-di-tert-butyl-4-(4-chlorobenzylidene)cyclohexa-2,5-dien-1-one, C21H25ClO
  28. Crystal structure of (2,2′-((naphthalen-1-ylmethyl)azanediyl)diacetato-κ3 N,O,O′)-(1,10-phenanthroline-κ2 N,N′)-copper(II) trihydrate, CuC27H27N3O7
  29. The crystal structure of tetrakis(6-phenylpyridine-2-carboxylato-κ2N,O)-bis(1H-pyrazol-3-ylamine-κ2 N:N)dicobalt(II) dihydrate, C27H23N5O5Co
  30. The crystal structure of bis((E)-2-((tert-butylimino)methyl)-4-chlorophenolato-κ2N,O)zinc(II), C22H26Cl2N2O2Zn
  31. The crystal structure of poly[diaqua-(μ3-5-nitrobenzene-1,2,3-tricarboxylato-κ3O:O′:O′)-(μ2-4,4′-dipyridylamine-κ2N:N′)copper(II)], C38H30Cu3N8O20
  32. The crystal structure of (E)-1-ferrocenyl-3-(naphthalen-1-yl)prop-2-en-1-one, C23H18FeO
  33. The crystal structure of (E)-1-ferrocenyl-3-(4-isopropylphenyl)prop-2-en-1-one, C22H22FeO
  34. Crystal structure of 6-hydroxy-2,2-dimethyl-4Hbenzo[d][1,3]dioxin-4-one, C10H10O4
  35. The crystal structure of (2E,4E)-1-ferrocenyl-5-phenylpenta-2,4-dien-1-one, C21H18FeO
  36. Crystal structure of alaninato-κ2N,O-bis(hydroxylamido-κ2N,O)-oxido-vanadium(V), C3H10N3O5V
  37. Crystal structure of catena-poly[aqua-bis[μ2-6-(1H-imidazol-1-yl)nicotinato-κ2 N,O]copper(II)], C18H14N6O5Cu
  38. Crystal structure of diethyl 4,6-diphenyl-1,9-di-p-tolylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta[b]pyridine-3,5(2H)-dicarboxylate, C42H42N2O4
  39. The crystal structure of cobalt cadmium bis(hydrogenphosphate) bis(phosphate(V)) tetrahydrate, H10O20P4Co3.14Cd1.86
  40. Crystal structure of dimethyl 1,4,6,9-tetraphenylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta[b]pyridine-3,7(2H)-dicarboxylate, C38H34N2O4
  41. Crystal structure of (Z)-4-(furan-2-yl((4-iodophenyl)amino)methylene)-5-methyl-2(p-tolyl)-2,4-dihydro-3H-pyrazol-3-one, C21H16I N3O2
  42. Crystal structure of (E)-1-(4-(3,5-dimethoxystyryl)phenyl)-7-ethylheptanedioate, C25H30O6
  43. Crystal structure of 6-bromo-2-(4-chlorophenyl)chroman-4-one (6-bromo-4′-chloroflavanone), C15H10BrClO2
  44. The crystal structure of 2-(benzhydryloxy)-3-nitropyridine, C18H14N2O3
  45. The crystal structure of 1,3(4,1)-dipyridin-1-iuma-2(1,8)-diethynylanthracena-5(1,3)-benzenacyclohexaphane-11,31-diium bis(hexafluoridophosphate), C36H24F12N2P2
  46. Crystal structure of 3,6-di-tert-butyl-1-iodo-9-methyl-8-(pyren-1-ylethynyl)-9H-carbazole, C39H34IN
  47. The cocrystal 2-(dimethylammonio)-5-nitrobenzoate – 2-(dimethylamino)-5-nitrobenzoic acid, C9H10N2O4
  48. Crystal structure of 5-nitroquinazolin-4(3H)-one, C8H5N3O3
https://doi.org/10.1515/ncrs-2022-0049
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of (E)-(4-imidazol-1-yl-phenyl)-(2-methoxy-benzylidene)-amine monohydrate, C17H17N3O2
  4. Crystal structure of 6-methyl-3-(pyrrolidine-1-carbonyl)-2H-chromen-2-one, C15H15N1O3
  5. Crystal structure of 4-methyl-4-nitropentanoic acid, C6H11NO4
  6. The crystal structure of (E)-3-(furan-2-yl)acrylonitrile, C7H5NO
  7. Crystal structure of 3-(difluoromethyl)-1-methyl-N-(4,11,11-trimethyl-1,2,3,4-tetrahydro-1,4-methanoacridin-9-yl)-1H-pyrazole-4-carboxamide monohydrate, C23H26F2N4O3
  8. Crystal structure of 2-(4-bromobenzyloxy)-6-chloropyridine, C12H9BrClNO
  9. Crystal structure of N-(4-bromo-2,6-dichloro-phenyl)pyrazin-2-amine, C10H6BrCl2N3
  10. Crystal structure of (E)-1-(2–nitrophenyl)-3-phenylprop-2-en-1-one, C15H11NO3
  11. The crystal structure of (E)-3-chloro-2-(2-(4-fluorobenzylidene)hydrazinyl)pyridine, C12H9ClFN3
  12. Crystal structure of (E)-amino(2-(thiazol-2-ylmethylene)hydrazineyl)methaniminium nitrate, C10H16N12O6S2
  13. Crystal structure of 9-methoxy-2,3,4,4a,5,6-hexahydro-1H-pyrido [1′,2′:1,6]pyrazino[2,3-b]quinoxaline, C15H18N4O
  14. The crystal structure bis(dimethylsulfoxide-κ1O)-dipyridine-κ1 N-bis(m2-(Z)-3-methyl-2-oxido-N-((Z)-oxido(phenyl)methylene)benzohydrazonato-κ5)trinickel(II) - dimethylsulfoxide (1/2), C48H56N6Ni3O10S4
  15. Crystal structure of bis(bis(triphenylphosphine)iminium) tetradecacarbonyltetratelluridopentaferrate(2-), (PPN)2[Fe5Te4(CO)14]
  16. Crystal structure of 4-Hydroxy-3-(naphthalen-2-ylthio)pent-3-en-2-one, C15H14O2S
  17. The crystal structure of [(1,10-phenanthroline-κ2 N,N)-bis(6-phenylpyridine-2-carboxylate-κ2 N,O)nickel(II)] monohydrate, C36H26N4O5Ni
  18. Crystal structure of 3,3′-(pyridine-2,6-diylbis(methylene))bis(1-propyl-1H-imidazol-3-ium) ditetrafluoroborate, C19H27B2F8N5
  19. The crystal structure of (E)-1-(4-aminophenyl)-3-(p-tolyl)prop-2-en-1-one, C16H15NO
  20. The crystal structure of poly[(μ2-terephthalato-κ4O,O′: O″,O‴)-(μ4-terephthalato-κ4O:O′:O″:O‴)-{μ4-(1,2,4,5-tetrakis(1,2,4-triazol-1-ylmethyl)-benzene-κ4O:O′:O″,O‴)}dicadmium(II)] – water – acetronitrile (1/2/2), C38H36N14O10Cd2
  21. The crystal structure of diaqua-bis(6-phenylpyridine-2-carboxylato-κ2 N,O)cobalt(II)–water–N,N-dimethylformamide(1/2/1), C27H31N3O9Co
  22. The co-crystal structure of 4-hydroxy-3-methoxybenzoic acid – 4,4′-bipyridine, C8H8O4·C10H8N2
  23. Crystal structure of catena-poly[(μ2-1,1′-(biphenyl-4,4′-diyl)bis(1H-imidazol)-κ2N:N′)-bis(4-bromobenzoate-κ1O)cobalt(II)], C32H22Br2CoN4O4
  24. Crystal structure of (E)-5-propyl-4-((pyridin-2-ylmethylene)amino)-2,4-dihydro-3H-1,2,4-triazole-3-thione – methanol (1/1), C11H13N5S
  25. The crystal structure of (Z)-4-bromo-6-(((1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)amino)methylene)cyclohexa-2,4-dien-1-one monohydrate, C11H16BrNO5
  26. Crystal structure of bis(tetrapropylammonium) nonaselenidotetrastannate(IV), (Pr4N)2[Sn4Se9]
  27. Crystal structure of 2,6-di-tert-butyl-4-(4-chlorobenzylidene)cyclohexa-2,5-dien-1-one, C21H25ClO
  28. Crystal structure of (2,2′-((naphthalen-1-ylmethyl)azanediyl)diacetato-κ3 N,O,O′)-(1,10-phenanthroline-κ2 N,N′)-copper(II) trihydrate, CuC27H27N3O7
  29. The crystal structure of tetrakis(6-phenylpyridine-2-carboxylato-κ2N,O)-bis(1H-pyrazol-3-ylamine-κ2 N:N)dicobalt(II) dihydrate, C27H23N5O5Co
  30. The crystal structure of bis((E)-2-((tert-butylimino)methyl)-4-chlorophenolato-κ2N,O)zinc(II), C22H26Cl2N2O2Zn
  31. The crystal structure of poly[diaqua-(μ3-5-nitrobenzene-1,2,3-tricarboxylato-κ3O:O′:O′)-(μ2-4,4′-dipyridylamine-κ2N:N′)copper(II)], C38H30Cu3N8O20
  32. The crystal structure of (E)-1-ferrocenyl-3-(naphthalen-1-yl)prop-2-en-1-one, C23H18FeO
  33. The crystal structure of (E)-1-ferrocenyl-3-(4-isopropylphenyl)prop-2-en-1-one, C22H22FeO
  34. Crystal structure of 6-hydroxy-2,2-dimethyl-4Hbenzo[d][1,3]dioxin-4-one, C10H10O4
  35. The crystal structure of (2E,4E)-1-ferrocenyl-5-phenylpenta-2,4-dien-1-one, C21H18FeO
  36. Crystal structure of alaninato-κ2N,O-bis(hydroxylamido-κ2N,O)-oxido-vanadium(V), C3H10N3O5V
  37. Crystal structure of catena-poly[aqua-bis[μ2-6-(1H-imidazol-1-yl)nicotinato-κ2 N,O]copper(II)], C18H14N6O5Cu
  38. Crystal structure of diethyl 4,6-diphenyl-1,9-di-p-tolylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta[b]pyridine-3,5(2H)-dicarboxylate, C42H42N2O4
  39. The crystal structure of cobalt cadmium bis(hydrogenphosphate) bis(phosphate(V)) tetrahydrate, H10O20P4Co3.14Cd1.86
  40. Crystal structure of dimethyl 1,4,6,9-tetraphenylhexahydro-3H-2,7,3,5-(epimethanetriyliminomethanetriyl)cyclopenta[b]pyridine-3,7(2H)-dicarboxylate, C38H34N2O4
  41. Crystal structure of (Z)-4-(furan-2-yl((4-iodophenyl)amino)methylene)-5-methyl-2(p-tolyl)-2,4-dihydro-3H-pyrazol-3-one, C21H16I N3O2
  42. Crystal structure of (E)-1-(4-(3,5-dimethoxystyryl)phenyl)-7-ethylheptanedioate, C25H30O6
  43. Crystal structure of 6-bromo-2-(4-chlorophenyl)chroman-4-one (6-bromo-4′-chloroflavanone), C15H10BrClO2
  44. The crystal structure of 2-(benzhydryloxy)-3-nitropyridine, C18H14N2O3
  45. The crystal structure of 1,3(4,1)-dipyridin-1-iuma-2(1,8)-diethynylanthracena-5(1,3)-benzenacyclohexaphane-11,31-diium bis(hexafluoridophosphate), C36H24F12N2P2
  46. Crystal structure of 3,6-di-tert-butyl-1-iodo-9-methyl-8-(pyren-1-ylethynyl)-9H-carbazole, C39H34IN
  47. The cocrystal 2-(dimethylammonio)-5-nitrobenzoate – 2-(dimethylamino)-5-nitrobenzoic acid, C9H10N2O4
  48. Crystal structure of 5-nitroquinazolin-4(3H)-one, C8H5N3O3
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