Home Physical Sciences Hydrothermal synthesis and crystal structure of poly[aqua-(μ2-1,3-bis(4-pyridyl)propane-κ2N:N′)-(μ2-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylato-κ2O:O′)manganese(II) hydrate, C22H20Cl6N2O6Mn
Article Open Access

Hydrothermal synthesis and crystal structure of poly[aqua-(μ2-1,3-bis(4-pyridyl)propane-κ2N:N′)-(μ2-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylato-κ2O:O′)manganese(II) hydrate, C22H20Cl6N2O6Mn

  • Li Gui-Lian EMAIL logo , Shen Jia and He Yu-Ying
Published/Copyright: December 14, 2017
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 233 Issue 1

Abstract

C22H20Cl6N2O6Mn, monoclinic, P21/c (no. 14), a = 12.0080(7) Å, b = 14.9289(8) Å, c = 15.2997(8) Å, β = 103.590(2)°, V = 2665.9(3) Å3, Z = 4, Rgt(F) = 0.0428, wRref(F2) = 0.1147, T = 296 K.

CCDC no.:: 1583824

The crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Block, colorless
Size:0.43 × 0.36 × 0.29 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:1.14 mm−1
Diffractometer, scan mode:Bruker SMART, φ and ω-scans
2θmax, completeness:25.4°, >99%
N(hkl)measured, N(hkl)unique, Rint:17205, 4870, 0.047
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3725
N(param)refined:334
Programs:Bruker programs [1], SHELX [2]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Mn1−0.03103(4)0.51665(3)0.10778(3)0.02432(15)
N1−0.1423(3)0.60346(19)0.17483(18)0.0302(7)
N2−0.0562(3)0.54301(19)0.75843(19)0.0317(7)
O10.0520(2)0.72189(16)0.03397(18)0.0377(6)
O20.1088(2)0.60709(15)0.12725(15)0.0322(6)
O30.1775(2)0.56227(15)−0.04814(15)0.0288(5)
O40.2823(2)0.47397(15)0.05850(18)0.0378(6)
C1−0.0998(3)0.6783(2)0.2183(2)0.0360(9)
H1−0.03340.70270.20680.043*
C2−0.1498(3)0.7207(2)0.2793(2)0.0372(9)
H2−0.11700.77270.30760.045*
C3−0.2481(3)0.6868(2)0.2988(2)0.0297(8)
C4−0.2931(3)0.6107(2)0.2517(2)0.0357(9)
H4−0.36030.58560.26110.043*
C5−0.2392(3)0.5718(3)0.1911(2)0.0369(9)
H5−0.27190.52100.16020.044*
C6−0.3016(3)0.7294(2)0.3685(2)0.0355(9)
H6A−0.37970.70800.35990.043*
H6B−0.30470.79370.35930.043*
C7−0.2370(3)0.7099(2)0.4653(2)0.0327(8)
H7A−0.15990.73370.47520.039*
H7B−0.27510.74000.50630.039*
C8−0.2309(3)0.6102(2)0.4857(2)0.0349(9)
H8A−0.19050.58070.44580.042*
H8B−0.30800.58620.47330.042*
C9−0.1710(3)0.5889(2)0.5824(2)0.0321(8)
C10−0.0536(3)0.5933(3)0.6106(3)0.0415(10)
H10−0.01020.61200.57100.050*
C11−0.0001(3)0.5700(3)0.6978(2)0.0395(9)
H110.07940.57340.71500.047*
C12−0.1706(3)0.5416(2)0.7314(2)0.0373(9)
H12−0.21240.52420.77260.045*
C13−0.2296(3)0.5644(3)0.6464(2)0.0387(9)
H13−0.30920.56350.63170.046*
C140.2528(3)0.7016(2)0.0997(2)0.0239(7)
H140.28390.70840.16460.029*
C150.3263(3)0.6295(2)0.0643(2)0.0264(7)
H150.38680.60870.11500.032*
C160.3823(3)0.6849(2)0.0006(3)0.0343(8)
C170.2908(4)0.7196(3)−0.0776(2)0.0390(10)
C180.2303(3)0.7812(2)−0.0477(2)0.0347(9)
C190.2790(3)0.7887(2)0.0529(2)0.0266(7)
C200.4071(3)0.7755(2)0.0538(2)0.0322(8)
C210.2571(3)0.5480(2)0.0210(2)0.0259(7)
C220.1265(3)0.6766(2)0.0843(2)0.0264(7)
Cl10.25004(9)0.88878(6)0.10369(7)0.0421(3)
Cl20.12265(11)0.84501(8)−0.10694(9)0.0696(4)
Cl30.46410(10)0.86032(7)−0.00383(8)0.0524(3)
Cl40.27637(15)0.68444(9)−0.18500(7)0.0768(5)
Cl50.50094(11)0.63207(8)−0.02473(10)0.0670(4)
Cl60.49859(9)0.76513(7)0.16193(8)0.0544(3)
O5W0.0688(2)0.42052(15)0.03827(15)0.0295(5)
H1W0.04550.36820.02110.044*
H2W0.14140.42360.04900.044*
O6W0.4549(5)0.4764(4)0.2287(4)0.164(3)
H4W0.47950.42600.25110.246*
H3W0.39430.48360.18760.246*

Source of material

The mixtures of chlorendic acid (H2clda, 38.9 mg, 0.1 mmol), 1,3-bis(4-pyridyl)propane (bpp, 39.8 mg, 0.2 mmol) Mn(OAc)2⋅4H2O (49.1 mg, 0.2 mmol), and H2O (7 mL) was placed in a 23 mL teflon-lined autoclave at 393 K for 4 days, then cooled to room temperature. Colourless block crystals were obtained in ca. 62% yield. Elemental analysis calcd. (%) for C22H20Cl6N2O6Mn: C, 39.12; H, 3.02; N, 4.16. Found: C, 39.09; H, 2.98; N, 4.14.

Experimental details

Hydrogen atoms were placed in their geometrically idealized positions and constrained to ride on their parent atoms.

Discussion

The coordination polymers assembled by metal ions, multicarboxylate ligands and N-donor coligands are rapidly increasing not only owing to their versatile intriguing architectures but also for their potential applications in many areas [3], [4], [5], [6], [7], [8], [9]. In multi-carboxylate ligands, rigid benzene multicarboxylate ligands have been widely applied for the synthesis and assembly of various coordination polymers. Recently, the steric, non-coplanar backbone carboxylate ligands for the formation of coordination polymers has been some investigated [10], [11], [12]. Among them, chlorendic acid (H2clda), which can display biological activity with the steric and non-coplanar features is rarely reported as an educt of a dicarboxylate ligand. Furthermore, the six Cl atoms in the chlorendic acid may alter its spatial conformation and steric hindrance and further influence coordination modes. Therefore, we select chlorendic acid (H2clda), as a precusor of the main ligand and the bpp (1,3-di(4-pyridyl)propane) as a N-donor auxiliary linker [13, 14] to construct the target compound.

The crystal structure determination reveals that the compound features a one-dimensional chain structure. The asymmetric unit contains one Mn(II) ion, one clda dianion, one bpp molecule, one coordinated water and one free water molecule (A: −x, 1 − y, −z; B: −x, 1 − y, 1 − z) (cf. the figure). The Mn(II) ion shows a six-coordinated environment with distorted octahedral manner [MnN2O4] by two N atoms from two symmetry-related bpp ligands (N1, N2B), four oxygen atoms (O2, O3A, O5W, O5WA) from two symmetry-related clda dianions and two coordinating water molecules. The Mn-O bond lengths are in the range of 2.120(2) to 2.367(2) Å, and the Mn-N bond lengths are 2.252(3) and 2.272(3) Å, respectively. Two Mn(II) neighbours are connected by two clda dianions adopting monodentate coordination mode (cf. the figure). The μ2-bridging mode of the dianionic dicarboxylato ligand is a well known feature for such ligands [15]. Two coordinated water molecules adopt a bridging-coordination mode to form one dinuclear unit with the Mn⋯Mn distance of 3.5825(7) Å. The adjacent dinuclear moieties are extended along the c direction by paired bpp co-ligands to produce a 1D coordination polymer with the Mn⋯Mn separation of 11.8592(9) Å. In the complex, as the result of the presence of one coordinated water molecule, there exist intra-chain hydrogen bonding interactions between the coordinated water and the carboxylate oxygen atoms of the clda dianions (O(5W)-H(1W)⋯O(1): d = 2.663(3) Å and O(5W)-H(2W)⋯O(4): d = 2.663 Å). The adjacent chains are interlinked by inter-chain hydrogen bonds via the participation of the O atoms from free water molecules and carboxylate O atom and Cl atom from clda anion (O(6W)-H(3W)⋯O(4): d = 2.923(6) Å and O(6W)-H(4W)⋯Cl(6): d = 3.552(6) Å) to form a three-dimensional supramolecular structure.

Acknowledgements

This work was supported by the Foundation of Science and Technology of Henan Province (grant no. 162102210304).

References

Bruker: APEX2, SAINT and SADABS. Brucker AXS Inc., Madison, WI, USA (2009).Search in Google Scholar

Sheldrick, G. M.: SHELXT-Integrated space-group and crystal-structure determination. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053273314026370Search in Google Scholar

Xuan, W. M.; Zhu, C. F.; Liu, Y.; Cui, Y.: Mesoporous metal-organic framework materials. Chem. Soc. Rev. 41 (2012) 1677–1695.10.1039/C1CS15196GSearch in Google Scholar

Zhu, Q. L.; Xu, Q.: Metal-organic framework composites. Chem. Soc. Rev. 43 (2014) 5468–5512.10.1039/C3CS60472ASearch in Google Scholar

McGuirk, C. M.; Katz, M. J.; Stern, C. L.; Sarjeant, A. A.; Hupp, J. T.; Farha, O. K.; Mirkin, C. A.: Turning on catalysis: incorporation of a hydrogen-bond-donating squaramide moiety into a Zr metal-organic framework. J. Am. Chem. Soc. 137 (2015) 919–925.10.1021/ja511403tSearch in Google Scholar

Xie, S. L.; Wang, H. F.; Liu, Z. H.; Dai, R.; Huang, L. Z.: Fluorescent metal-organic framework based on pyrene chromophore for sensing of nitrobenzene. RSC Adv. 5 (2015) 7121–7124.10.1039/C4RA10835CSearch in Google Scholar

Li, G. L.; Yin, W. D.; Liu, G. Z.; Ma, L. F.; Wang, L. Y.: Syntheses, structures and magnetic properties of four coordination polymers based on nitrobenzene dicarboxylate and various N-donor coligands. J. Solid State Chem. 220 (2014) 1–8.10.1016/j.jssc.2014.08.007Search in Google Scholar

Wang, Y. L.; Fu, J. H.; Wei, J. J.; Xu, X.; Li, X. F.; Liu, Q. Y.: New thiolated nitrophenylhydrazone crystals for nonlinear optics. Cryst. Growth Des. 12 (2012) 4663–4668.10.1021/cg300889xSearch in Google Scholar

Tang, Q.; Zhou, Z.; Chen, Z. F.: Single-layer [Cu2Br(IN)2]n coordination polymer (CP): electronic and magnetic properties, and implication for molecular sensors. J. Phys. Chem. C 116 (2012) 4119–4125.10.1021/jp211779wSearch in Google Scholar

Zhang, J.; Chen, S. M.; Nieto, R. A.; Wu, T.; Feng, P. Y.; Bu, X. H.: A tale of three carboxylates: Cooperative asymmetric crystallization of a three-dimensional microporous framework from achiral precursors. Angew. Chem. Int. Ed. 49 (2010) 1267–1270.10.1002/anie.200906248Search in Google Scholar

Geraghty, M.; Sheridan, V.; McCanna, M.; Devereuxb, M.; McKee, V.: Synthesis and anti-candida activity of copper(II) and manganese(II) carboxylate complexes: X-ray crystal structures of [Cu(sal)(bipy)]⋅C2H5OH⋅H2O and [Cu(norb)(phen)2]⋅6⋅5H2O (salH2 = salicylic acid; norbH2 = cis-5-norbornene-endo-2,3-dicarboxylic acid; bipy = 2,2′-bipyridine; phen = 1,10-phenanthroline). Polyhedron 18 (1999) 2931–2939.10.1016/S0277-5387(99)00201-6Search in Google Scholar

Xin, L. Y.; Liu, G. Z.; Ma, L. F.; Wang, L. Y.: Coligand-regulated assembly, fluorescence, and magnetic properties of Co(II) and Cd(II) complexes with a non-coplanar dicarboxylate. J. Solid State Chem 206 (2013) 233–241.10.1016/j.jssc.2013.08.010Search in Google Scholar

Li, G. L.; Liu, G. Z.; Xin, L. Y.; Li, X. L.; Ma, L. F.; Wang, L. Y.: Syntheses, structures and fluorescence properties of four Zn/Cd(II) coordination polymers with 3-nitrobenzene-1,2-dicarboxylate and dipyridyl-typed coligands. J. Inorg. Organomet. Polym. 25 (2015) 694–701.10.1007/s10904-014-0147-4Search in Google Scholar

Li, G. L.; Liu, G. Z.; Huang, L. L.; Li, L.; Zhang, X.: Ancillary ligand-mediated syntheses, structures and fluorescence of three Zn/Cd(II) coordination polymers based on nitrobenzene dicarboxylate. J. Inorg. Organomet. Polym. 24 (2014) 617–623.10.1007/s10904-014-0024-1Search in Google Scholar

Wu, H.-X.; Zhang, H.-Y.; Xin, L.-Y.: Crystal structure of diaquabis(bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate-κ4O,O′:O′′,O′′′)bis(2,2′-bipyridine-κ2N,N′)dicadmium(II) hydrate. Z. Kristallogr. NCS 231 (2016) 101–103.10.1515/ncrs-2015-0051Search in Google Scholar

Received: 2017-7-1
Accepted: 2017-11-3
Published Online: 2017-12-14
Published in Print: 2018-1-26

©2018 Li Gui-Lian et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Articles in the same Issue

  1. Cover and Frontmatter
  2. Editorial 2018
  3. Crystal structure of dimethanol-bis{3-(((2-oxidonaphthalen-1-yl)methylene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N:O′}dizinc(II), C42H30Zn2N2O10
  4. Crystal structure of aqua-bis{[2,6-dimethyl-N-(pyridin-2-ylmethylene)aniline-κ2N,N′]}zinc(II) triflate monohydrate [ZnC29H31N4O]CF3SO3⋅H2O
  5. Crystal structure of (E)-1-(4-{[(E)-4-Diethylamino-2-hydroxybenzene methylene]amino}phenyl)ethanone methoxy oxime, C20H27ClN3O3
  6. Crystal structure of (E)-1-(4-(((E)-4-(diethylamino)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one oxime, C19H23N3O2
  7. Crystal structure of poly[(μ2-1,4-bis((2-ethyl-1H-benzo[d]imidazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-sulfonyldibenzoato-κ2O:O′)zinc(II)], C40H34N4O6SZn
  8. Crystal structure of catena-poly[diaqua(μ3-pyrazine-2,3-dicarboxylato-κ4O,N:O′:O′′)zinc(II)] 1.25 hydrate, C6H8.5N2O7.25Zn
  9. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(tri-m-tolyl phosphane-κP)rhenium(I), C29H28O5PRe
  10. Crystal structure of bis(μ2-methanolato-κ2O:O)-bis(methanol-κ1O)-bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,O′,N}dichromium(III), C38H36Cr2N2O14
  11. Crystal structure of poly[aqua-(μ3-pyridine-3,5-dicarboxylato-κ5O,O′:O′′,O′′′,N)zinc(II)], C7H7NO6Zn
  12. Crystal structure of bis((1-(((4-(((benzyloxy)imino)methyl)phenyl)imino)methyl)naphthalen-2-yl)oxy-κ2O,N)copper(II), C52H42CuN4O4
  13. Crystal structure of bis{5-(diethylamino)-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2O,N}cobalt(II), C40H38CoN4O6
  14. Crystal structure of diaqua-bis(N,N-dimethylformamide-κ1O)-bis{3-((5-chloro-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ4N,O,O′:O′}dinickel(II), C38H34Ni2Cl2N4O12
  15. Crystal structure of tetrakis(methanol-κO)bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}bicobalt(II), C38H38Co2N2O14
  16. Crystal structure of (S)-tert-butyl-(1-hydroxypropan-2-yl)carbamate, C8H17NO3
  17. Crystal structure of 4-(4′-(pyridin-4-yl)-[1,1′-biphenyl]-4-yl)pyridin-1-ium catena-poly[{5-carboxy-4′-methyl-[1,1′-biphenyl]-3-carboxylato-κ2O,O′}-(μ2-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-κ4O,O′:O′′,O′′′)lead(II)], C52H40N2O9Pb
  18. Crystal structure of catena-poly[diaqua-(μ2-5-methylisophthalato-κ2O:O′)(μ2-1,4-bis((1H-1,2,4-triazol-1-yl)methyl)benzene-κ2N:N′)], NiC21H22O6N6
  19. Crystal structure of the salt tris(guanidinium) tris(tetrapropylammonium) bis(pyridine-2,4,6-tricarboxylate) – water (1/10), C55H126N14O22
  20. Crystal structure of 5-hydroxy-2-(4-hydroxy-3-methoxyphenyl)-3,7,8-trimethoxy-4H-chromen-4-one, C19H18O8
  21. Crystal structure of poly{[μ2-1,1′-(sulfonylbis(4,1-phenylene))bis(2-methyl-1H-imidazole)-κ2N:N′][μ2-4,4′-oxydibenzoato-κ2O:O′]cobalt(II)} hemihydrate, C34H27N4O7.5SCo
  22. The crystal structure of 25,27-(2,2′-[(2-thioxo-1,3-dithiole-4,5-diyl)disulfanediyl]diethanolate)-26,28-dihydroxycalix[4]arene — dichloromethane (1/1), C36H32Cl2O4S5
  23. The crystal structure of 1,2-bis(3-(pyridin-3-yl)-1,2,4-oxadiazol-5-yl)ethane, C16H12N6O2
  24. Crystal structure of 1-benzyl-3-((4-bromophenyl)amino)-4-(4-methoxyphenyl)-1H-pyrrole-2,5-dione, C24H19BrN2O3
  25. Crystal structure of bis(2-((allylcarbamothioyl)imino)-4-methylthiazol-3-ido-κ2N,S)palladium(II), C16H20N6PdS4
  26. Crystal structure of pyrimidine-2,5-dicarboxylic acid 1.5 hydrate, C12H14N4O11
  27. Crystal structure of trans-diaqua-bis(1H-pyrazole-3-carboxylato-κ2N,O)manganese(II), C8H10N4O6Mn
  28. Crystal structure of catena-(μ3-5-bromoisophthatato-κO,O′: O′′,O′′′′)-(1,2-bis(imidazol-1-yl)ethane-κN:N′)cobalt(II), C16H13CoN4O4Br
  29. Investigation of the compound La5Zn2−xPb1 + x (x = 0.20–0.32)
  30. Crystal structure of (OC-6-13)-diaqua-bis(3,5-di(pyridin-3-yl)-4H-1,2,4-triazol-4-amine-κ1N)-bis(dicyanamido-κ1N)zinc(II) tetrahydrate, ZnC28H32N18O6
  31. Crystal structure of Ga0.62(3)Sb0.38(3)Pd3
  32. Crystal structure of Ga0.47(1)Sb0.53(1)Pd2
  33. A derivative of the Corey lactone – crystal structure of (3aR,4S,5R,6aS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate, C21H30O5Si
  34. A Corey lactone: crystal structure of (3aR,4R,5R,6aS)-5-benzoyloxy-4(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one, C15H16O5
  35. Hydrothermal synthesis and crystal structure of poly[aqua-(μ2-1,3-bis(4-pyridyl)propane-κ2N:N′)-(μ2-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylato-κ2O:O′)manganese(II) hydrate, C22H20Cl6N2O6Mn
  36. Crystal structure of 2-acetylpyrrole S-methylthiosemicarbazonium hydroiodide, C8H13IN4S
  37. Crystal structure of [N,N-bis((pyrrol-2-yl)ethylidene)butane-1,4-diamine-κ4N,N′,N′′,N′′′]-nickel(II), C16H20N4Ni
  38. Crystal structure of poly[aqua-(μ5-2,5-dicarboxybenzoato-κ5O:O:O′:O′′:O′′′)sodium(I)], C9H7NaO7
  39. Crystal structure of bis(N′-((1H-pyrrol-2-yl)methylene)-1-methylthio-methanethiohydrazido-κ2S,N)nickel(II), C14H16N6NiS4
  40. Crystal structure of 1-(4-((benzo[d][1,3]dioxol-5-yloxy)methyl)phenethyl)-4-(3-chlorophenyl) piperazin-1-ium chloride, C26H28Cl2N2O3
  41. Crystal structure of 2-(4-(2-(4-(2-fluorophenyl)piperazin-1-yl)ethyl)benzyl)benzo[d]isothiazol-3(2H)-one 1,1-dioxide, C26H26FN3O3S – a saccharin dervative
  42. Crystal structure of 3-(2-dimethylaminoethyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C12H15N3OS
  43. Crystal structure of 3-(3-dimethylaminopropyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C13H17N3OS
  44. The crystal structure of trans-tetraaqua-bis(p-tolylsulfinato-κO)calcium(II)), C14H22O8S2Ca
  45. The crystal structure of (E)-N′-(pyridin-2-ylmethylene)pyrazine-2-carbohydrazide, C11H9N5O
  46. Crystal structure of (E)-3-(pyren-1-yl)-1-(pyridin-4-yl)prop-2-en-1-one, C24H15NO
  47. Crystal structure of catena-poly[diaqua-(μ2-tartrato-κ4O,O′:O′′,O′′′)cobalt(II)], C4H8CoO8
  48. Crystal structure of 4-chloro-2-methyl-6-(4-(trifluoromethoxy)phenyl)pyrimidine, C12H8ClF3N2O
  49. Crystal structure of 1-(4-fluorophenyl)-N-(5-((triphenylstannyl)thio)thiophen-2-yl)methanimine, C27H20FN3S2Sn
  50. Crystal structure of methyl (Z)-2-(5-fluoro-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate, C10H8FN3OS2
  51. Crystal structure of tert-butyl (Z)-4-(2-(5-methoxy-3-(2-((methylthio)carbonothioyl)hydrazono)-2-oxoindolin-1-yl)ethyl)piperazine-1-carboxylate, C22H31N5O4S2
  52. The crystal structure of (E)-2-((2-(o-tolylcarbamothioyl)hydrazono)methyl)benzoic acid, C16H15N3O2S
  53. Crystal structure of 2-chloro-1,3-di-tert-pentyl-4,4-diphenyl-1,3,2λ3,4-diazaphosphasiletidine, C22H32ClN2PSi
  54. Crystal structure of tetramethyl 5,5′-(buta-1,3-diyne-1,4-diyl)diisophthalate, C24H18O8
  55. Crystal structural of 2-amino-4-(4-methoxyphenyl)-3-cyano-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C19H20N2O3
  56. Crystal structure of 1,3,5-tris((trimethylsilyl)methyl)-1,3,5-triazinane-2,4,6-trione, C15H33N3O3Si3
  57. The crystal structure of bis(2-benzoyl-5-hydroxylphenolato-κ2O,O′)copper(II), C26H18CuO6
  58. Crystal structure of 2,6-bis(3-(pyrazin-2-yl)-1H-1,2,4-triazol-5-yl)pyridine – 1-ethyl-3-methyl-1H-imidazol-3-ium bromide (1/1), C23H22N13Br
  59. The crystal structure of (E)-N-benzyl-N′-benzylidene-4-methylbenzenesulfonohydrazide, C21H20N2O2S
  60. Crystal structure of ethyl (E)-5-((2-(3-hydroxybenzoyl)hydrazono)methyl)-3,4-dimethyl-1H-pyrrole-2-carboxylate – water – ethanol (1/1/1), C19H27N3O6
  61. The crystal structure of (E)-4-(3-ethoxy-2-hydroxybenzylideneamino)benzoic acid, C16H15NO4
  62. Crystal structure of (μ2-N,N′-bis((pyridin-4-yl)methyl)ethanediamide-κ2N:N′)-tetrakis(diethylcarbamodithioato-κ2S,S′)dizinc(II), C34H54N8O2S8Zn2
https://doi.org/10.1515/ncrs-2017-0187
Creative Commons
BY-NC-ND 4.0

Articles in the same Issue

  1. Cover and Frontmatter
  2. Editorial 2018
  3. Crystal structure of dimethanol-bis{3-(((2-oxidonaphthalen-1-yl)methylene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N:O′}dizinc(II), C42H30Zn2N2O10
  4. Crystal structure of aqua-bis{[2,6-dimethyl-N-(pyridin-2-ylmethylene)aniline-κ2N,N′]}zinc(II) triflate monohydrate [ZnC29H31N4O]CF3SO3⋅H2O
  5. Crystal structure of (E)-1-(4-{[(E)-4-Diethylamino-2-hydroxybenzene methylene]amino}phenyl)ethanone methoxy oxime, C20H27ClN3O3
  6. Crystal structure of (E)-1-(4-(((E)-4-(diethylamino)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one oxime, C19H23N3O2
  7. Crystal structure of poly[(μ2-1,4-bis((2-ethyl-1H-benzo[d]imidazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-sulfonyldibenzoato-κ2O:O′)zinc(II)], C40H34N4O6SZn
  8. Crystal structure of catena-poly[diaqua(μ3-pyrazine-2,3-dicarboxylato-κ4O,N:O′:O′′)zinc(II)] 1.25 hydrate, C6H8.5N2O7.25Zn
  9. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(tri-m-tolyl phosphane-κP)rhenium(I), C29H28O5PRe
  10. Crystal structure of bis(μ2-methanolato-κ2O:O)-bis(methanol-κ1O)-bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,O′,N}dichromium(III), C38H36Cr2N2O14
  11. Crystal structure of poly[aqua-(μ3-pyridine-3,5-dicarboxylato-κ5O,O′:O′′,O′′′,N)zinc(II)], C7H7NO6Zn
  12. Crystal structure of bis((1-(((4-(((benzyloxy)imino)methyl)phenyl)imino)methyl)naphthalen-2-yl)oxy-κ2O,N)copper(II), C52H42CuN4O4
  13. Crystal structure of bis{5-(diethylamino)-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2O,N}cobalt(II), C40H38CoN4O6
  14. Crystal structure of diaqua-bis(N,N-dimethylformamide-κ1O)-bis{3-((5-chloro-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ4N,O,O′:O′}dinickel(II), C38H34Ni2Cl2N4O12
  15. Crystal structure of tetrakis(methanol-κO)bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}bicobalt(II), C38H38Co2N2O14
  16. Crystal structure of (S)-tert-butyl-(1-hydroxypropan-2-yl)carbamate, C8H17NO3
  17. Crystal structure of 4-(4′-(pyridin-4-yl)-[1,1′-biphenyl]-4-yl)pyridin-1-ium catena-poly[{5-carboxy-4′-methyl-[1,1′-biphenyl]-3-carboxylato-κ2O,O′}-(μ2-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-κ4O,O′:O′′,O′′′)lead(II)], C52H40N2O9Pb
  18. Crystal structure of catena-poly[diaqua-(μ2-5-methylisophthalato-κ2O:O′)(μ2-1,4-bis((1H-1,2,4-triazol-1-yl)methyl)benzene-κ2N:N′)], NiC21H22O6N6
  19. Crystal structure of the salt tris(guanidinium) tris(tetrapropylammonium) bis(pyridine-2,4,6-tricarboxylate) – water (1/10), C55H126N14O22
  20. Crystal structure of 5-hydroxy-2-(4-hydroxy-3-methoxyphenyl)-3,7,8-trimethoxy-4H-chromen-4-one, C19H18O8
  21. Crystal structure of poly{[μ2-1,1′-(sulfonylbis(4,1-phenylene))bis(2-methyl-1H-imidazole)-κ2N:N′][μ2-4,4′-oxydibenzoato-κ2O:O′]cobalt(II)} hemihydrate, C34H27N4O7.5SCo
  22. The crystal structure of 25,27-(2,2′-[(2-thioxo-1,3-dithiole-4,5-diyl)disulfanediyl]diethanolate)-26,28-dihydroxycalix[4]arene — dichloromethane (1/1), C36H32Cl2O4S5
  23. The crystal structure of 1,2-bis(3-(pyridin-3-yl)-1,2,4-oxadiazol-5-yl)ethane, C16H12N6O2
  24. Crystal structure of 1-benzyl-3-((4-bromophenyl)amino)-4-(4-methoxyphenyl)-1H-pyrrole-2,5-dione, C24H19BrN2O3
  25. Crystal structure of bis(2-((allylcarbamothioyl)imino)-4-methylthiazol-3-ido-κ2N,S)palladium(II), C16H20N6PdS4
  26. Crystal structure of pyrimidine-2,5-dicarboxylic acid 1.5 hydrate, C12H14N4O11
  27. Crystal structure of trans-diaqua-bis(1H-pyrazole-3-carboxylato-κ2N,O)manganese(II), C8H10N4O6Mn
  28. Crystal structure of catena-(μ3-5-bromoisophthatato-κO,O′: O′′,O′′′′)-(1,2-bis(imidazol-1-yl)ethane-κN:N′)cobalt(II), C16H13CoN4O4Br
  29. Investigation of the compound La5Zn2−xPb1 + x (x = 0.20–0.32)
  30. Crystal structure of (OC-6-13)-diaqua-bis(3,5-di(pyridin-3-yl)-4H-1,2,4-triazol-4-amine-κ1N)-bis(dicyanamido-κ1N)zinc(II) tetrahydrate, ZnC28H32N18O6
  31. Crystal structure of Ga0.62(3)Sb0.38(3)Pd3
  32. Crystal structure of Ga0.47(1)Sb0.53(1)Pd2
  33. A derivative of the Corey lactone – crystal structure of (3aR,4S,5R,6aS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate, C21H30O5Si
  34. A Corey lactone: crystal structure of (3aR,4R,5R,6aS)-5-benzoyloxy-4(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one, C15H16O5
  35. Hydrothermal synthesis and crystal structure of poly[aqua-(μ2-1,3-bis(4-pyridyl)propane-κ2N:N′)-(μ2-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylato-κ2O:O′)manganese(II) hydrate, C22H20Cl6N2O6Mn
  36. Crystal structure of 2-acetylpyrrole S-methylthiosemicarbazonium hydroiodide, C8H13IN4S
  37. Crystal structure of [N,N-bis((pyrrol-2-yl)ethylidene)butane-1,4-diamine-κ4N,N′,N′′,N′′′]-nickel(II), C16H20N4Ni
  38. Crystal structure of poly[aqua-(μ5-2,5-dicarboxybenzoato-κ5O:O:O′:O′′:O′′′)sodium(I)], C9H7NaO7
  39. Crystal structure of bis(N′-((1H-pyrrol-2-yl)methylene)-1-methylthio-methanethiohydrazido-κ2S,N)nickel(II), C14H16N6NiS4
  40. Crystal structure of 1-(4-((benzo[d][1,3]dioxol-5-yloxy)methyl)phenethyl)-4-(3-chlorophenyl) piperazin-1-ium chloride, C26H28Cl2N2O3
  41. Crystal structure of 2-(4-(2-(4-(2-fluorophenyl)piperazin-1-yl)ethyl)benzyl)benzo[d]isothiazol-3(2H)-one 1,1-dioxide, C26H26FN3O3S – a saccharin dervative
  42. Crystal structure of 3-(2-dimethylaminoethyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C12H15N3OS
  43. Crystal structure of 3-(3-dimethylaminopropyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C13H17N3OS
  44. The crystal structure of trans-tetraaqua-bis(p-tolylsulfinato-κO)calcium(II)), C14H22O8S2Ca
  45. The crystal structure of (E)-N′-(pyridin-2-ylmethylene)pyrazine-2-carbohydrazide, C11H9N5O
  46. Crystal structure of (E)-3-(pyren-1-yl)-1-(pyridin-4-yl)prop-2-en-1-one, C24H15NO
  47. Crystal structure of catena-poly[diaqua-(μ2-tartrato-κ4O,O′:O′′,O′′′)cobalt(II)], C4H8CoO8
  48. Crystal structure of 4-chloro-2-methyl-6-(4-(trifluoromethoxy)phenyl)pyrimidine, C12H8ClF3N2O
  49. Crystal structure of 1-(4-fluorophenyl)-N-(5-((triphenylstannyl)thio)thiophen-2-yl)methanimine, C27H20FN3S2Sn
  50. Crystal structure of methyl (Z)-2-(5-fluoro-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate, C10H8FN3OS2
  51. Crystal structure of tert-butyl (Z)-4-(2-(5-methoxy-3-(2-((methylthio)carbonothioyl)hydrazono)-2-oxoindolin-1-yl)ethyl)piperazine-1-carboxylate, C22H31N5O4S2
  52. The crystal structure of (E)-2-((2-(o-tolylcarbamothioyl)hydrazono)methyl)benzoic acid, C16H15N3O2S
  53. Crystal structure of 2-chloro-1,3-di-tert-pentyl-4,4-diphenyl-1,3,2λ3,4-diazaphosphasiletidine, C22H32ClN2PSi
  54. Crystal structure of tetramethyl 5,5′-(buta-1,3-diyne-1,4-diyl)diisophthalate, C24H18O8
  55. Crystal structural of 2-amino-4-(4-methoxyphenyl)-3-cyano-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C19H20N2O3
  56. Crystal structure of 1,3,5-tris((trimethylsilyl)methyl)-1,3,5-triazinane-2,4,6-trione, C15H33N3O3Si3
  57. The crystal structure of bis(2-benzoyl-5-hydroxylphenolato-κ2O,O′)copper(II), C26H18CuO6
  58. Crystal structure of 2,6-bis(3-(pyrazin-2-yl)-1H-1,2,4-triazol-5-yl)pyridine – 1-ethyl-3-methyl-1H-imidazol-3-ium bromide (1/1), C23H22N13Br
  59. The crystal structure of (E)-N-benzyl-N′-benzylidene-4-methylbenzenesulfonohydrazide, C21H20N2O2S
  60. Crystal structure of ethyl (E)-5-((2-(3-hydroxybenzoyl)hydrazono)methyl)-3,4-dimethyl-1H-pyrrole-2-carboxylate – water – ethanol (1/1/1), C19H27N3O6
  61. The crystal structure of (E)-4-(3-ethoxy-2-hydroxybenzylideneamino)benzoic acid, C16H15NO4
  62. Crystal structure of (μ2-N,N′-bis((pyridin-4-yl)methyl)ethanediamide-κ2N:N′)-tetrakis(diethylcarbamodithioato-κ2S,S′)dizinc(II), C34H54N8O2S8Zn2
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 3.1.2026 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2017-0187/html
Scroll to top button