Abstract
C40H34N4O6SZn, triclinic P1̅ (no. 2), a = 11.157(2) Å, b = 11.867(2) Å, c = 14.141(3) Å, α = 75.30(3)°, β = 86.09(3)°, γ = 84.91(3)°, V = 1801.8(6) Å3, Z = 2, Rgt(F) = 0.0419, ωRref(F2) = 0.1063, T = 293(2) K.

The crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.
Data collection and handling.
| Crystal: | Prism, colourless |
| Size: | 0.33 × 0.22 × 0.19 mm |
| Wavelength: | Mo Kα radiation (0.71073 Å) |
| μ: | 0.79 mm−1 |
| Diffractometer, scan mode: | Bruker SMART, φ and ω-scans |
| 2θmax, completeness: | 25.5°, >97% |
| N(hkl)measured, N(hkl)unique, Rint: | 12744, 6572, 0.022 |
| Criterion for Iobs, N(hkl)gt: | Iobs > 2 σ(Iobs), 5779 |
| N(param)refined: | 471 |
| Programs: | Rigaku/MSC [1], SHELX [2] |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).
| Atom | x | y | z | Uiso*/Ueq |
|---|---|---|---|---|
| Zn1 | 0.94384(3) | 0.33679(3) | 0.26407(2) | 0.03138(11) |
| N1 | 0.92930(18) | 0.18348(18) | 0.36809(15) | 0.0323(5) |
| N2 | 0.82997(19) | 0.05301(19) | 0.47911(16) | 0.0355(5) |
| N3 | 1.12299(19) | 0.35217(19) | 0.24505(15) | 0.0344(5) |
| N4 | 1.31701(19) | 0.32032(19) | 0.20597(16) | 0.0356(5) |
| O1 | 0.14988(18) | 0.53665(16) | −0.30268(14) | 0.0456(5) |
| O2 | 0.0489(2) | 0.3892(2) | −0.2128(2) | 0.0710(7) |
| O3 | 0.69220(19) | 0.1731(2) | −0.28050(14) | 0.0546(6) |
| O4 | 0.58652(19) | 0.01337(16) | −0.16585(15) | 0.0514(5) |
| O5 | 0.89055(17) | 0.31080(17) | 0.14352(13) | 0.0430(5) |
| O6 | 0.71992(18) | 0.2523(2) | 0.22503(15) | 0.0553(6) |
| S1 | 0.61265(7) | 0.13451(6) | −0.19700(5) | 0.03993(18) |
| C1 | 1.1481(4) | 0.4153(4) | 0.0119(3) | 0.0914(13) |
| H1A | 1.0896 | 0.4643 | 0.0389 | 0.137* |
| H1B | 1.1180 | 0.4012 | −0.0458 | 0.137* |
| H1C | 1.2218 | 0.4535 | −0.0050 | 0.137* |
| C2 | 1.1707(3) | 0.3042(3) | 0.0840(2) | 0.0521(8) |
| H2A | 1.0993 | 0.2608 | 0.0943 | 0.063* |
| H2B | 1.2359 | 0.2581 | 0.0595 | 0.063* |
| C3 | 1.2029(2) | 0.3240(2) | 0.1785(2) | 0.0359(6) |
| C4 | 1.1899(2) | 0.3701(2) | 0.31838(19) | 0.0328(6) |
| C5 | 1.1536(3) | 0.4035(2) | 0.4039(2) | 0.0414(7) |
| H5 | 1.0725 | 0.4190 | 0.4196 | 0.050* |
| C6 | 1.2411(3) | 0.4127(3) | 0.4644(2) | 0.0520(8) |
| H6 | 1.2189 | 0.4358 | 0.5217 | 0.062* |
| C7 | 1.3626(3) | 0.3883(3) | 0.4420(2) | 0.0576(9) |
| H7 | 1.4193 | 0.3939 | 0.4854 | 0.069* |
| C8 | 1.4009(3) | 0.3561(3) | 0.3577(2) | 0.0492(8) |
| H8 | 1.4821 | 0.3399 | 0.3429 | 0.059* |
| C9 | 1.3118(2) | 0.3489(2) | 0.29545(19) | 0.0345(6) |
| C10 | 1.4282(2) | 0.2968(3) | 0.1501(2) | 0.0431(7) |
| H10A | 1.4171 | 0.2339 | 0.1198 | 0.052* |
| H10B | 1.4930 | 0.2708 | 0.1948 | 0.052* |
| C11 | 1.4644(2) | 0.4019(2) | 0.0717(2) | 0.0380(6) |
| C12 | 1.5015(3) | 0.4979(3) | 0.0966(2) | 0.0502(8) |
| H12 | 1.5030 | 0.4975 | 0.1623 | 0.060* |
| C13 | 1.4639(3) | 0.4059(3) | −0.0266(2) | 0.0498(8) |
| H13 | 1.4397 | 0.3424 | −0.0459 | 0.060* |
| C14 | 0.6823(2) | 0.2996(3) | 0.4812(2) | 0.0462(7) |
| H14A | 0.6711 | 0.3211 | 0.4120 | 0.069* |
| H14B | 0.6619 | 0.3663 | 0.5074 | 0.069* |
| H14C | 0.6314 | 0.2385 | 0.5124 | 0.069* |
| C15 | 0.8137(2) | 0.2568(2) | 0.49975(19) | 0.0367(6) |
| H15A | 0.8633 | 0.3226 | 0.4782 | 0.044* |
| H15B | 0.8222 | 0.2258 | 0.5696 | 0.044* |
| C16 | 0.8581(2) | 0.1658(2) | 0.44899(19) | 0.0313(6) |
| C17 | 0.9476(2) | 0.0760(2) | 0.3441(2) | 0.0356(6) |
| C18 | 1.0130(3) | 0.0438(3) | 0.2673(2) | 0.0507(8) |
| H18 | 1.0558 | 0.0975 | 0.2208 | 0.061* |
| C19 | 1.0129(3) | −0.0707(3) | 0.2619(3) | 0.0617(9) |
| H19 | 1.0561 | −0.0943 | 0.2108 | 0.074* |
| C20 | 0.9491(3) | −0.1515(3) | 0.3315(3) | 0.0628(10) |
| H20 | 0.9508 | −0.2280 | 0.3258 | 0.075* |
| C21 | 0.8836(3) | −0.1211(3) | 0.4083(3) | 0.0520(8) |
| H21 | 0.8404 | −0.1748 | 0.4545 | 0.062* |
| C22 | 0.8855(2) | −0.0061(2) | 0.4135(2) | 0.0367(6) |
| C23 | 0.7453(2) | 0.0031(3) | 0.5588(2) | 0.0421(7) |
| H23A | 0.7422 | 0.0476 | 0.6078 | 0.050* |
| H23B | 0.7748 | −0.0764 | 0.5892 | 0.050* |
| C24 | 0.6186(2) | 0.0021(2) | 0.52568(19) | 0.0336(6) |
| C25 | 0.5288(2) | −0.0333(2) | 0.5964(2) | 0.0401(7) |
| H25 | 0.5474 | −0.0558 | 0.6619 | 0.048* |
| C26 | 0.5884(3) | 0.0358(3) | 0.4285(2) | 0.0433(7) |
| H26 | 0.6475 | 0.0604 | 0.3797 | 0.052* |
| C27 | 0.7878(2) | 0.2675(2) | 0.1519(2) | 0.0390(6) |
| C28 | 0.7516(2) | 0.2324(2) | 0.06298(19) | 0.0338(6) |
| C29 | 0.6646(2) | 0.1530(2) | 0.0754(2) | 0.0367(6) |
| H29 | 0.6334 | 0.1196 | 0.1380 | 0.044* |
| C30 | 0.6237(2) | 0.1230(2) | −0.0039(2) | 0.0382(6) |
| H30 | 0.5653 | 0.0695 | 0.0051 | 0.046* |
| C31 | 0.6699(2) | 0.1726(2) | −0.09701(19) | 0.0336(6) |
| C32 | 0.7588(3) | 0.2508(3) | −0.1112(2) | 0.0439(7) |
| H32 | 0.7904 | 0.2835 | −0.1737 | 0.053* |
| C33 | 0.7997(3) | 0.2792(3) | −0.0302(2) | 0.0449(7) |
| H33 | 0.8602 | 0.3304 | −0.0386 | 0.054* |
| C34 | 0.4741(2) | 0.2188(2) | −0.21835(19) | 0.0363(6) |
| C35 | 0.3680(3) | 0.1727(3) | −0.1765(2) | 0.0512(8) |
| H35 | 0.3689 | 0.0958 | −0.1393 | 0.061* |
| C36 | 0.2612(3) | 0.2405(3) | −0.1900(2) | 0.0485(8) |
| H36 | 0.1898 | 0.2091 | −0.1620 | 0.058* |
| C37 | 0.2589(2) | 0.3554(2) | −0.24478(19) | 0.0363(6) |
| C38 | 0.3652(3) | 0.3998(2) | −0.2874(2) | 0.0408(7) |
| H38 | 0.3641 | 0.4764 | −0.3253 | 0.049* |
| C39 | 0.4733(3) | 0.3327(2) | −0.2747(2) | 0.0423(7) |
| H39 | 0.5445 | 0.3637 | −0.3037 | 0.051* |
| C40 | 0.1411(3) | 0.4308(3) | −0.2530(2) | 0.0404(7) |
Source of material
The title compound was prepared under the hydrothermal conditions. A mixture of 1,4-bis(2-ethylbenzimidazol-1-ylmethyl) benzene (73.2 mg, 0.2 mmol), Zn(Ac)2⋅2H2O (21.9 mg, 0.1 mmol), 4,4′-sulfonyldibenzoic acid (H2sb; 32.8 mg, 0.2 mmol), and H2O (10 mL) were placed in a teflon-lined stainless steel vessel, heated to 160 °C for 4 days, and then cooled to room temperature for 24 h. Colorless block crystals of the title complex were obtained.
Experimental details
The hydrogen atoms were placed at calculated positions and refined as riding atoms with isotropic displacement parameters.
Discussion
Metal–organic frameworks (MOFs) with entangled architectures, such as the most common interpenetrating nets, polyrotaxane structures, self-penetrating nets etc., are of great attention [3], [4], [5], [6]. It is not only because of their intrinsic aesthetic appeal and complicated molecular architectures as well as topological features [7], [8], [9], [10], [11], [12], but also for their potential application, such as gas adsorption, molecular electronic devices, and so on [13], [14], [15]. Compared to the interpenetrating nets (the polymeric equivalents of catenanes and rotaxanes) and other intertwining nets, the self-penetrating frameworks, have attracted much higher interest [16], [17].
The title structure consists of a 1,4-bis(2-ethylbenzimidazol-1-ylmethyl) benzene (beb), one 4,4′-sulfonyldibenzoate (sb2−), and one Zn(II) ion in the asymmetric unit. The Zn(II) ion presents a distorted tetrahedral coordination geometry, ligated by two oxygen atoms (O1A and O5) from two symmetry-related carboxylate groups of 4,4′-sulfonyldibenzoate and two nitrogen atoms N1 and N3) from different beb ligands. The bond lengths are Zn(1)—O(1A) = 1.9249(19) Å, Zn(1)—O(5) = 1.9471(18) Å, Zn(1)—N(1) = 2.039(2) Å, and Zn(1)—N(3) = Zn1 2.017(2) Å, respectively. They are in the normal range [18].
In the title complex, two beb ligands adopt symmetric trans-conformation with the Ndonor⋯N—Csp3⋯C torsion of 30.496° and 28.589° [19], respectively. Each Zn(II) ion links two beb and two sb2− resulting in a 2D sheet structure, similarily to related structures. The two sheets give parallel (2D → 2D) catenation.
Acknowledgements
This work was financially supported by the Science and technology research key project of the Education Department of Henan Province (2014A150025) and the Provincial cultivation fund of Luoyang normal university (2013-PYJJ-005).
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©2018 Chunying Xu et al., published by De Gruyter, Berlin/Boston
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Artikel in diesem Heft
- Cover and Frontmatter
- Editorial 2018
- Crystal structure of dimethanol-bis{3-(((2-oxidonaphthalen-1-yl)methylene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N:O′}dizinc(II), C42H30Zn2N2O10
- Crystal structure of aqua-bis{[2,6-dimethyl-N-(pyridin-2-ylmethylene)aniline-κ2N,N′]}zinc(II) triflate monohydrate [ZnC29H31N4O]CF3SO3⋅H2O
- Crystal structure of (E)-1-(4-{[(E)-4-Diethylamino-2-hydroxybenzene methylene]amino}phenyl)ethanone methoxy oxime, C20H27ClN3O3
- Crystal structure of (E)-1-(4-(((E)-4-(diethylamino)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one oxime, C19H23N3O2
- Crystal structure of poly[(μ2-1,4-bis((2-ethyl-1H-benzo[d]imidazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-sulfonyldibenzoato-κ2O:O′)zinc(II)], C40H34N4O6SZn
- Crystal structure of catena-poly[diaqua(μ3-pyrazine-2,3-dicarboxylato-κ4O,N:O′:O′′)zinc(II)] 1.25 hydrate, C6H8.5N2O7.25Zn
- Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(tri-m-tolyl phosphane-κP)rhenium(I), C29H28O5PRe
- Crystal structure of bis(μ2-methanolato-κ2O:O)-bis(methanol-κ1O)-bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,O′,N}dichromium(III), C38H36Cr2N2O14
- Crystal structure of poly[aqua-(μ3-pyridine-3,5-dicarboxylato-κ5O,O′:O′′,O′′′,N)zinc(II)], C7H7NO6Zn
- Crystal structure of bis((1-(((4-(((benzyloxy)imino)methyl)phenyl)imino)methyl)naphthalen-2-yl)oxy-κ2O,N)copper(II), C52H42CuN4O4
- Crystal structure of bis{5-(diethylamino)-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2O,N}cobalt(II), C40H38CoN4O6
- Crystal structure of diaqua-bis(N,N-dimethylformamide-κ1O)-bis{3-((5-chloro-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ4N,O,O′:O′}dinickel(II), C38H34Ni2Cl2N4O12
- Crystal structure of tetrakis(methanol-κO)bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}bicobalt(II), C38H38Co2N2O14
- Crystal structure of (S)-tert-butyl-(1-hydroxypropan-2-yl)carbamate, C8H17NO3
- Crystal structure of 4-(4′-(pyridin-4-yl)-[1,1′-biphenyl]-4-yl)pyridin-1-ium catena-poly[{5-carboxy-4′-methyl-[1,1′-biphenyl]-3-carboxylato-κ2O,O′}-(μ2-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-κ4O,O′:O′′,O′′′)lead(II)], C52H40N2O9Pb
- Crystal structure of catena-poly[diaqua-(μ2-5-methylisophthalato-κ2O:O′)(μ2-1,4-bis((1H-1,2,4-triazol-1-yl)methyl)benzene-κ2N:N′)], NiC21H22O6N6
- Crystal structure of the salt tris(guanidinium) tris(tetrapropylammonium) bis(pyridine-2,4,6-tricarboxylate) – water (1/10), C55H126N14O22
- Crystal structure of 5-hydroxy-2-(4-hydroxy-3-methoxyphenyl)-3,7,8-trimethoxy-4H-chromen-4-one, C19H18O8
- Crystal structure of poly{[μ2-1,1′-(sulfonylbis(4,1-phenylene))bis(2-methyl-1H-imidazole)-κ2N:N′][μ2-4,4′-oxydibenzoato-κ2O:O′]cobalt(II)} hemihydrate, C34H27N4O7.5SCo
- The crystal structure of 25,27-(2,2′-[(2-thioxo-1,3-dithiole-4,5-diyl)disulfanediyl]diethanolate)-26,28-dihydroxycalix[4]arene — dichloromethane (1/1), C36H32Cl2O4S5
- The crystal structure of 1,2-bis(3-(pyridin-3-yl)-1,2,4-oxadiazol-5-yl)ethane, C16H12N6O2
- Crystal structure of 1-benzyl-3-((4-bromophenyl)amino)-4-(4-methoxyphenyl)-1H-pyrrole-2,5-dione, C24H19BrN2O3
- Crystal structure of bis(2-((allylcarbamothioyl)imino)-4-methylthiazol-3-ido-κ2N,S)palladium(II), C16H20N6PdS4
- Crystal structure of pyrimidine-2,5-dicarboxylic acid 1.5 hydrate, C12H14N4O11
- Crystal structure of trans-diaqua-bis(1H-pyrazole-3-carboxylato-κ2N,O)manganese(II), C8H10N4O6Mn
- Crystal structure of catena-(μ3-5-bromoisophthatato-κO,O′: O′′,O′′′′)-(1,2-bis(imidazol-1-yl)ethane-κN:N′)cobalt(II), C16H13CoN4O4Br
- Investigation of the compound La5Zn2−xPb1 + x (x = 0.20–0.32)
- Crystal structure of (OC-6-13)-diaqua-bis(3,5-di(pyridin-3-yl)-4H-1,2,4-triazol-4-amine-κ1N)-bis(dicyanamido-κ1N)zinc(II) tetrahydrate, ZnC28H32N18O6
- Crystal structure of Ga0.62(3)Sb0.38(3)Pd3
- Crystal structure of Ga0.47(1)Sb0.53(1)Pd2
- A derivative of the Corey lactone – crystal structure of (3aR,4S,5R,6aS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate, C21H30O5Si
- A Corey lactone: crystal structure of (3aR,4R,5R,6aS)-5-benzoyloxy-4(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one, C15H16O5
- Hydrothermal synthesis and crystal structure of poly[aqua-(μ2-1,3-bis(4-pyridyl)propane-κ2N:N′)-(μ2-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylato-κ2O:O′)manganese(II) hydrate, C22H20Cl6N2O6Mn
- Crystal structure of 2-acetylpyrrole S-methylthiosemicarbazonium hydroiodide, C8H13IN4S
- Crystal structure of [N,N-bis((pyrrol-2-yl)ethylidene)butane-1,4-diamine-κ4N,N′,N′′,N′′′]-nickel(II), C16H20N4Ni
- Crystal structure of poly[aqua-(μ5-2,5-dicarboxybenzoato-κ5O:O:O′:O′′:O′′′)sodium(I)], C9H7NaO7
- Crystal structure of bis(N′-((1H-pyrrol-2-yl)methylene)-1-methylthio-methanethiohydrazido-κ2S,N)nickel(II), C14H16N6NiS4
- Crystal structure of 1-(4-((benzo[d][1,3]dioxol-5-yloxy)methyl)phenethyl)-4-(3-chlorophenyl) piperazin-1-ium chloride, C26H28Cl2N2O3
- Crystal structure of 2-(4-(2-(4-(2-fluorophenyl)piperazin-1-yl)ethyl)benzyl)benzo[d]isothiazol-3(2H)-one 1,1-dioxide, C26H26FN3O3S – a saccharin dervative
- Crystal structure of 3-(2-dimethylaminoethyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C12H15N3OS
- Crystal structure of 3-(3-dimethylaminopropyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C13H17N3OS
- The crystal structure of trans-tetraaqua-bis(p-tolylsulfinato-κO)calcium(II)), C14H22O8S2Ca
- The crystal structure of (E)-N′-(pyridin-2-ylmethylene)pyrazine-2-carbohydrazide, C11H9N5O
- Crystal structure of (E)-3-(pyren-1-yl)-1-(pyridin-4-yl)prop-2-en-1-one, C24H15NO
- Crystal structure of catena-poly[diaqua-(μ2-tartrato-κ4O,O′:O′′,O′′′)cobalt(II)], C4H8CoO8
- Crystal structure of 4-chloro-2-methyl-6-(4-(trifluoromethoxy)phenyl)pyrimidine, C12H8ClF3N2O
- Crystal structure of 1-(4-fluorophenyl)-N-(5-((triphenylstannyl)thio)thiophen-2-yl)methanimine, C27H20FN3S2Sn
- Crystal structure of methyl (Z)-2-(5-fluoro-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate, C10H8FN3OS2
- Crystal structure of tert-butyl (Z)-4-(2-(5-methoxy-3-(2-((methylthio)carbonothioyl)hydrazono)-2-oxoindolin-1-yl)ethyl)piperazine-1-carboxylate, C22H31N5O4S2
- The crystal structure of (E)-2-((2-(o-tolylcarbamothioyl)hydrazono)methyl)benzoic acid, C16H15N3O2S
- Crystal structure of 2-chloro-1,3-di-tert-pentyl-4,4-diphenyl-1,3,2λ3,4-diazaphosphasiletidine, C22H32ClN2PSi
- Crystal structure of tetramethyl 5,5′-(buta-1,3-diyne-1,4-diyl)diisophthalate, C24H18O8
- Crystal structural of 2-amino-4-(4-methoxyphenyl)-3-cyano-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C19H20N2O3
- Crystal structure of 1,3,5-tris((trimethylsilyl)methyl)-1,3,5-triazinane-2,4,6-trione, C15H33N3O3Si3
- The crystal structure of bis(2-benzoyl-5-hydroxylphenolato-κ2O,O′)copper(II), C26H18CuO6
- Crystal structure of 2,6-bis(3-(pyrazin-2-yl)-1H-1,2,4-triazol-5-yl)pyridine – 1-ethyl-3-methyl-1H-imidazol-3-ium bromide (1/1), C23H22N13Br
- The crystal structure of (E)-N-benzyl-N′-benzylidene-4-methylbenzenesulfonohydrazide, C21H20N2O2S
- Crystal structure of ethyl (E)-5-((2-(3-hydroxybenzoyl)hydrazono)methyl)-3,4-dimethyl-1H-pyrrole-2-carboxylate – water – ethanol (1/1/1), C19H27N3O6
- The crystal structure of (E)-4-(3-ethoxy-2-hydroxybenzylideneamino)benzoic acid, C16H15NO4
- Crystal structure of (μ2-N,N′-bis((pyridin-4-yl)methyl)ethanediamide-κ2N:N′)-tetrakis(diethylcarbamodithioato-κ2S,S′)dizinc(II), C34H54N8O2S8Zn2
Artikel in diesem Heft
- Cover and Frontmatter
- Editorial 2018
- Crystal structure of dimethanol-bis{3-(((2-oxidonaphthalen-1-yl)methylene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N:O′}dizinc(II), C42H30Zn2N2O10
- Crystal structure of aqua-bis{[2,6-dimethyl-N-(pyridin-2-ylmethylene)aniline-κ2N,N′]}zinc(II) triflate monohydrate [ZnC29H31N4O]CF3SO3⋅H2O
- Crystal structure of (E)-1-(4-{[(E)-4-Diethylamino-2-hydroxybenzene methylene]amino}phenyl)ethanone methoxy oxime, C20H27ClN3O3
- Crystal structure of (E)-1-(4-(((E)-4-(diethylamino)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one oxime, C19H23N3O2
- Crystal structure of poly[(μ2-1,4-bis((2-ethyl-1H-benzo[d]imidazol-1-yl)methyl)benzene-κ2N:N′)-(μ2-4,4′-sulfonyldibenzoato-κ2O:O′)zinc(II)], C40H34N4O6SZn
- Crystal structure of catena-poly[diaqua(μ3-pyrazine-2,3-dicarboxylato-κ4O,N:O′:O′′)zinc(II)] 1.25 hydrate, C6H8.5N2O7.25Zn
- Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(tri-m-tolyl phosphane-κP)rhenium(I), C29H28O5PRe
- Crystal structure of bis(μ2-methanolato-κ2O:O)-bis(methanol-κ1O)-bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,O′,N}dichromium(III), C38H36Cr2N2O14
- Crystal structure of poly[aqua-(μ3-pyridine-3,5-dicarboxylato-κ5O,O′:O′′,O′′′,N)zinc(II)], C7H7NO6Zn
- Crystal structure of bis((1-(((4-(((benzyloxy)imino)methyl)phenyl)imino)methyl)naphthalen-2-yl)oxy-κ2O,N)copper(II), C52H42CuN4O4
- Crystal structure of bis{5-(diethylamino)-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2O,N}cobalt(II), C40H38CoN4O6
- Crystal structure of diaqua-bis(N,N-dimethylformamide-κ1O)-bis{3-((5-chloro-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ4N,O,O′:O′}dinickel(II), C38H34Ni2Cl2N4O12
- Crystal structure of tetrakis(methanol-κO)bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}bicobalt(II), C38H38Co2N2O14
- Crystal structure of (S)-tert-butyl-(1-hydroxypropan-2-yl)carbamate, C8H17NO3
- Crystal structure of 4-(4′-(pyridin-4-yl)-[1,1′-biphenyl]-4-yl)pyridin-1-ium catena-poly[{5-carboxy-4′-methyl-[1,1′-biphenyl]-3-carboxylato-κ2O,O′}-(μ2-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-κ4O,O′:O′′,O′′′)lead(II)], C52H40N2O9Pb
- Crystal structure of catena-poly[diaqua-(μ2-5-methylisophthalato-κ2O:O′)(μ2-1,4-bis((1H-1,2,4-triazol-1-yl)methyl)benzene-κ2N:N′)], NiC21H22O6N6
- Crystal structure of the salt tris(guanidinium) tris(tetrapropylammonium) bis(pyridine-2,4,6-tricarboxylate) – water (1/10), C55H126N14O22
- Crystal structure of 5-hydroxy-2-(4-hydroxy-3-methoxyphenyl)-3,7,8-trimethoxy-4H-chromen-4-one, C19H18O8
- Crystal structure of poly{[μ2-1,1′-(sulfonylbis(4,1-phenylene))bis(2-methyl-1H-imidazole)-κ2N:N′][μ2-4,4′-oxydibenzoato-κ2O:O′]cobalt(II)} hemihydrate, C34H27N4O7.5SCo
- The crystal structure of 25,27-(2,2′-[(2-thioxo-1,3-dithiole-4,5-diyl)disulfanediyl]diethanolate)-26,28-dihydroxycalix[4]arene — dichloromethane (1/1), C36H32Cl2O4S5
- The crystal structure of 1,2-bis(3-(pyridin-3-yl)-1,2,4-oxadiazol-5-yl)ethane, C16H12N6O2
- Crystal structure of 1-benzyl-3-((4-bromophenyl)amino)-4-(4-methoxyphenyl)-1H-pyrrole-2,5-dione, C24H19BrN2O3
- Crystal structure of bis(2-((allylcarbamothioyl)imino)-4-methylthiazol-3-ido-κ2N,S)palladium(II), C16H20N6PdS4
- Crystal structure of pyrimidine-2,5-dicarboxylic acid 1.5 hydrate, C12H14N4O11
- Crystal structure of trans-diaqua-bis(1H-pyrazole-3-carboxylato-κ2N,O)manganese(II), C8H10N4O6Mn
- Crystal structure of catena-(μ3-5-bromoisophthatato-κO,O′: O′′,O′′′′)-(1,2-bis(imidazol-1-yl)ethane-κN:N′)cobalt(II), C16H13CoN4O4Br
- Investigation of the compound La5Zn2−xPb1 + x (x = 0.20–0.32)
- Crystal structure of (OC-6-13)-diaqua-bis(3,5-di(pyridin-3-yl)-4H-1,2,4-triazol-4-amine-κ1N)-bis(dicyanamido-κ1N)zinc(II) tetrahydrate, ZnC28H32N18O6
- Crystal structure of Ga0.62(3)Sb0.38(3)Pd3
- Crystal structure of Ga0.47(1)Sb0.53(1)Pd2
- A derivative of the Corey lactone – crystal structure of (3aR,4S,5R,6aS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate, C21H30O5Si
- A Corey lactone: crystal structure of (3aR,4R,5R,6aS)-5-benzoyloxy-4(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one, C15H16O5
- Hydrothermal synthesis and crystal structure of poly[aqua-(μ2-1,3-bis(4-pyridyl)propane-κ2N:N′)-(μ2-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylato-κ2O:O′)manganese(II) hydrate, C22H20Cl6N2O6Mn
- Crystal structure of 2-acetylpyrrole S-methylthiosemicarbazonium hydroiodide, C8H13IN4S
- Crystal structure of [N,N-bis((pyrrol-2-yl)ethylidene)butane-1,4-diamine-κ4N,N′,N′′,N′′′]-nickel(II), C16H20N4Ni
- Crystal structure of poly[aqua-(μ5-2,5-dicarboxybenzoato-κ5O:O:O′:O′′:O′′′)sodium(I)], C9H7NaO7
- Crystal structure of bis(N′-((1H-pyrrol-2-yl)methylene)-1-methylthio-methanethiohydrazido-κ2S,N)nickel(II), C14H16N6NiS4
- Crystal structure of 1-(4-((benzo[d][1,3]dioxol-5-yloxy)methyl)phenethyl)-4-(3-chlorophenyl) piperazin-1-ium chloride, C26H28Cl2N2O3
- Crystal structure of 2-(4-(2-(4-(2-fluorophenyl)piperazin-1-yl)ethyl)benzyl)benzo[d]isothiazol-3(2H)-one 1,1-dioxide, C26H26FN3O3S – a saccharin dervative
- Crystal structure of 3-(2-dimethylaminoethyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C12H15N3OS
- Crystal structure of 3-(3-dimethylaminopropyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C13H17N3OS
- The crystal structure of trans-tetraaqua-bis(p-tolylsulfinato-κO)calcium(II)), C14H22O8S2Ca
- The crystal structure of (E)-N′-(pyridin-2-ylmethylene)pyrazine-2-carbohydrazide, C11H9N5O
- Crystal structure of (E)-3-(pyren-1-yl)-1-(pyridin-4-yl)prop-2-en-1-one, C24H15NO
- Crystal structure of catena-poly[diaqua-(μ2-tartrato-κ4O,O′:O′′,O′′′)cobalt(II)], C4H8CoO8
- Crystal structure of 4-chloro-2-methyl-6-(4-(trifluoromethoxy)phenyl)pyrimidine, C12H8ClF3N2O
- Crystal structure of 1-(4-fluorophenyl)-N-(5-((triphenylstannyl)thio)thiophen-2-yl)methanimine, C27H20FN3S2Sn
- Crystal structure of methyl (Z)-2-(5-fluoro-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate, C10H8FN3OS2
- Crystal structure of tert-butyl (Z)-4-(2-(5-methoxy-3-(2-((methylthio)carbonothioyl)hydrazono)-2-oxoindolin-1-yl)ethyl)piperazine-1-carboxylate, C22H31N5O4S2
- The crystal structure of (E)-2-((2-(o-tolylcarbamothioyl)hydrazono)methyl)benzoic acid, C16H15N3O2S
- Crystal structure of 2-chloro-1,3-di-tert-pentyl-4,4-diphenyl-1,3,2λ3,4-diazaphosphasiletidine, C22H32ClN2PSi
- Crystal structure of tetramethyl 5,5′-(buta-1,3-diyne-1,4-diyl)diisophthalate, C24H18O8
- Crystal structural of 2-amino-4-(4-methoxyphenyl)-3-cyano-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C19H20N2O3
- Crystal structure of 1,3,5-tris((trimethylsilyl)methyl)-1,3,5-triazinane-2,4,6-trione, C15H33N3O3Si3
- The crystal structure of bis(2-benzoyl-5-hydroxylphenolato-κ2O,O′)copper(II), C26H18CuO6
- Crystal structure of 2,6-bis(3-(pyrazin-2-yl)-1H-1,2,4-triazol-5-yl)pyridine – 1-ethyl-3-methyl-1H-imidazol-3-ium bromide (1/1), C23H22N13Br
- The crystal structure of (E)-N-benzyl-N′-benzylidene-4-methylbenzenesulfonohydrazide, C21H20N2O2S
- Crystal structure of ethyl (E)-5-((2-(3-hydroxybenzoyl)hydrazono)methyl)-3,4-dimethyl-1H-pyrrole-2-carboxylate – water – ethanol (1/1/1), C19H27N3O6
- The crystal structure of (E)-4-(3-ethoxy-2-hydroxybenzylideneamino)benzoic acid, C16H15NO4
- Crystal structure of (μ2-N,N′-bis((pyridin-4-yl)methyl)ethanediamide-κ2N:N′)-tetrakis(diethylcarbamodithioato-κ2S,S′)dizinc(II), C34H54N8O2S8Zn2