Home Crystal structure of bis(μ2-azido-κ2N:N)-tetrakis(azido-κ1N)-tetrakis(1,10-phenanthroline-κ2N,N′)dibismuth(III), C48H32N26Bi2
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Crystal structure of bis(μ2-azido-κ2N:N)-tetrakis(azido-κ1N)-tetrakis(1,10-phenanthroline-κ2N,N′)dibismuth(III), C48H32N26Bi2

  • Zhi-Guo Zhong , Jing Li and Yu-Quan Feng ORCID logo EMAIL logo
Published/Copyright: August 4, 2023
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 238 Issue 5

Abstract

C48H32N26Bi2, triclinic, P 1 ‾ (no. 2), a = 9.781(5) Å, b = 11.667(6) Å, c = 11.973(7) Å, α = 83.816(10)°, β = 74.471(10)°, γ = 66.120(8)°, V = 1203.7 (11) Å3, Z = 1, Rgt(F) = 0.0435, wRref(F2) = 0.1035, T = 293 K.

CCDC no.: 2285148

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Yellow block
Size: 0.26 × 0.21 × 0.18 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 7.37 mm−1
Diffractometer, scan mode: φ and ω
θmax, completeness: 25.1°, 99 %
N(hkl)measured, N(hkl)unique, Rint: 7846, 4254, 0.032
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 3351
N(param)refined: 343
Programs: Bruker [1], Olex2 [2, 3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
Bi1 0.14456 (3) 0.89825 (3) 0.83876 (3) 0.04363 (14)
C1 0.3471 (10) 1.0973 (9) 0.7947 (8) 0.052 (2)
H1 0.3842 (10) 1.0490 (9) 0.8555 (8) 0.062 (3)*
C2 0.4088 (11) 1.1824 (10) 0.7426 (9) 0.060 (3)
H2 0.4865 (11) 1.1913 (10) 0.7672 (9) 0.072 (3)*
C3 0.3542 (11) 1.2531 (10) 0.6546 (10) 0.066 (3)
H3 0.3973 (11) 1.3090 (10) 0.6169 (10) 0.079 (3)*
C4 0.2337 (11) 1.2432 (10) 0.6195 (9) 0.059 (3)
C5 0.1796 (10) 1.1533 (9) 0.6751 (8) 0.051 (2)
C6 0.0584 (9) 1.1373 (9) 0.6420 (7) 0.046 (2)
C7 −0.0054 (12) 1.2188 (10) 0.5573 (9) 0.063 (3)
C8 0.0547 (14) 1.3070 (10) 0.5043 (10) 0.076 (3)
H8 0.0109 (14) 1.3597 (10) 0.4482 (10) 0.091 (4)*
C9 0.1713 (13) 1.3181 (11) 0.5311 (10) 0.075 (3)
H9 0.2117 (13) 1.3750 (11) 0.4917 (10) 0.090 (4)*
C10 −0.1298 (11) 1.2039 (10) 0.5307 (9) 0.064 (3)
H10 −0.1787 (11) 1.2566 (10) 0.4768 (9) 0.076 (3)*
C11 −0.1783 (11) 1.1131 (11) 0.5833 (8) 0.064 (3)
H11 −0.2595 (11) 1.1033 (11) 0.5650 (8) 0.077 (4)*
C12 −0.1066 (10) 1.0353 (10) 0.6644 (8) 0.056 (3)
H12 −0.1392 (10) 0.9723 (10) 0.6984 (8) 0.067 (3)*
C13 0.5433 (12) 0.7864 (11) 0.8344 (14) 0.096 (5)
H13 0.5462 (12) 0.8319 (11) 0.7657 (14) 0.115 (6)*
C14 0.6823 (13) 0.7326 (11) 0.8829 (13) 0.086 (3)
H14 0.7749 (13) 0.7410 (11) 0.8479 (13) 0.103 (4)*
C15 0.6581 (17) 0.6697 (13) 0.9846 (14) 0.103 (4)
H15 0.7429 (17) 0.6374 (13) 1.0168 (14) 0.124 (5)*
C16 0.5454 (16) 0.6468 (12) 1.0433 (13) 0.087 (4)
C17 0.4161 (14) 0.7014 (10) 0.9890 (12) 0.079 (4)
C18 0.2834 (14) 0.6792 (9) 1.0445 (9) 0.063 (3)
C19 0.2739 (16) 0.6045 (10) 1.1502 (12) 0.084 (4)
C20 0.401 (2) 0.5616 (14) 1.1937 (15) 0.116 (5)
H20 0.397 (2) 0.5170 (14) 1.2629 (15) 0.139 (6)*
C21 0.5253 (15) 0.5779 (11) 1.1469 (11) 0.081 (3)
H21 0.6068 (15) 0.5428 (11) 1.1825 (11) 0.098 (4)*
C22 0.1409 (19) 0.5832 (13) 1.1887 (13) 0.097 (4)
H22 0.1316 (19) 0.5356 (13) 1.2556 (13) 0.117 (5)*
C23 0.0280 (18) 0.6241 (12) 1.1394 (12) 0.102 (5)
H23 −0.0591 (18) 0.6058 (12) 1.1680 (12) 0.122 (6)*
C24 0.0436 (14) 0.6966 (10) 1.0415 (10) 0.072 (3)
H24 −0.0377 (14) 0.7284 (10) 1.0056 (10) 0.087 (4)*
N1 0.2352 (8) 1.0808 (7) 0.7616 (6) 0.0478 (18)
N2 0.0086 (8) 1.0484 (7) 0.6951 (6) 0.050 (2)
N3 0.4181 (8) 0.7697 (8) 0.8881 (8) 0.062 (2)
N4 0.1632 (10) 0.7236 (7) 0.9958 (7) 0.058 (2)
N5 0.0269 (9) 0.7798 (8) 0.7840 (8) 0.068 (3)
N6 0.0867 (9) 0.6760 (9) 0.7631 (7) 0.054 (2)
N7 0.1408 (14) 0.5752 (11) 0.7396 (12) 0.107 (4)
N8 0.3295 (14) 0.8334 (12) 0.6514 (9) 0.101 (3)
N9 0.3992 (16) 0.7350 (14) 0.6343 (11) 0.108 (4)
N10 0.5003 (19) 0.6176 (15) 0.5956 (15) 0.162 (6)
N11 0.1249 (8) 1.0022 (7) 1.0353 (6) 0.0491 (19)
N12 0.2372 (8) 0.9873 (6) 1.0674 (6) 0.0463 (18)
N13 0.3426 (9) 0.9750 (9) 1.0968 (8) 0.072 (3)

1 Source of material

The titled compound Bi2(μ2–N3)2(C12H8N2)4(N3)4 was prepared through the hydrothermal method. The mixture of Bi(NO3)3·5H2O (0.36 g), phen (C12H8N2, 0.08 g), NaN3 (0.29 g) and H2O (5.2 mL) was transferred into a 50 mL Teflon-lined stainless steel vessel and heated at 140 °C for 130 h. After cooling to RT, the block yellow crystals were obtained, washed with distilled water and dried at RT (yield: 76 % based on Bi(NO3)3·5H2O).

2 Experimental details

The H atoms of the C atoms from the organic ligands were positioned geometrically and refined using a riding model, with C–H = 0.93 Å, with Uiso(H) = 1.2 times Ueq(C). Two restrictive refinements, isor and delu, were applied to deal with partially distorted nitrogen and carbon atoms in the structure.

3 Comment

It is an effective way to construct novel compounds by using linear azide anions with flexible coordination modes and various metal cations [4, 5]. The N atom at both ends of the azide ion can coordinate directly with the metal cation or link as a bridge atom with two/three metal cations to form a compound with new structural features [6]. Herein, using two types of nitrogen-containing ligands, azide (N3−) and 1,10-phenanthroline (phen), we prepared a new binuclear coordination compound Bi2(μ2–N3)2(C12H8N2)4(N3)4 based on Bi3+ cations by means of hydrothermal method. Within its molecular structure (Figure), each Bi3+ cation is coordinated with eight surrounding nitrogen atoms, of which four nitrogen atoms are from two different phen ligands and four N atoms belong to four surrounding azide anions, resulting in the formation of a {BiN8} hexagonal bipyramidal geometric configuration. The distances of Bi–N bonds are in the range of 2.356(8)–2.689(7) Å. The bond angles of N–Bi–N are in the scope of 61.9(3)–152.7(3)°. The mentioned parameters of bond lengths and angles are consistent with those of previously known Bi3+-containing complexes [7–10] and fall within their normal range. It is worth noting that the azide ions exhibit two kinds of coordination modes: the single coordination and the bridging coordination of the terminal N atoms. The two Bi3+ cations are bridged by two terminal N atoms of different azide groups to generate a binuclear structure. The flexible coordination modes of the azide anions in the title compound can be observed in the compounds that we reported previously. The distance of Bi⋯Bi is 4.386 Å. In addition, there are π–π stacking interactions between phenanthroline molecules in its packing scheme [centroid-to–centroid distances: 3.808(6) Å(Cg1-Cg1 i , i: –x, 2–y, 1–z), 5.479(8) Å(Cg2–Cg3 ii , ii: 1–x, 1–y, 2–z) and 3.504(8) Å(Cg2-Cg4 ii , ii: 1–x, 1–y, 2–z), Cg1, Cg2, Cg3 and Cg4 are the centroids of 6–MRs involving atoms N(2)/C(6),C(10)–C(12); N(1)/C(1)–C(5); N(3)/C(13)–C(17) and C(16)–C(20), respectively].

Corresponding author: Yu-Quan Feng, College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was financially supported by the National Natural Science Foundation of China (no. 21601095) and the National Natural Science Foundation Project Cultivation Fund of Nanyang Normal University (no. 2023PY004).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2023-07-06
Accepted: 2023-07-28
Published Online: 2023-08-04
Published in Print: 2023-10-26

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  60. Crystal structure of bis(3,5-dimethyl-1H-pyrazol-4-ammonium) tetrafluoroterephthate, 2[C5H10N3][C8F4O4]
  61. Crystal structure of 2-amino-4-(2-fluoro-4-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  62. Crystal structure of 6-(pyridin-3-yl)-1,3,5-triazine-2,4-diamine-sebacic acid (2/1), C13H17N6O2
https://doi.org/10.1515/ncrs-2023-0312
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of (N-([1,1′:4′,1″-terphenyl]-4,4′-diethyl)-2-(bis(pyridin-2-ylmethyl)amino)acetamide-κ4N,N,N″, O)tri(nitrato-kO, O′) samarium(III) - methanol - acetonitrile (1/1/1), C40H39SmN8O14
  4. The crystal structure of 6,6′-(((2-(dimethylamino)ethyl)azanediyl)bis(methylene))bis(2-chloro-4-methyl phenolate-κ4N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV), C27H27Cl2N3O6Ti
  5. N′-[(1E)-(4–Fluorophenyl)methylidene]adamantane-1-carbohydrazide, C18H21FN2O
  6. Crystal structure of 4-bromo-3-nitro-1H-pyrazole-5-carboxylic acid monohydrate, C4H2N3BrO4·H2O
  7. Crystal structure of dipyridine-k1N-tris(2,2,6,6-tetramethyl-5-oxohept-3-en-3-olato-k2O,O′)dysprosium(III), DyC43H67O6N2
  8. Crystal structure of cyclo[tetraiodido-bis{μ2-1-[(benzotriazol-1-yl)methyl]-1-H-1,3-(2-isopropyl-imidazol)-k2N:N}dicadmiun(II)], C26H30N10Cd2I4
  9. The crystal structure of tert-butyl (E)-3-(2-(benzylideneamino)phenyl)-1H-indole-1-carboxylate, C26H24N2O2
  10. The crystal structure of 4-(3-carboxy-1-cyclopropyl-6-fluoro-8-methoxy-4-oxo-1,4- dihydroquinolin-7-yl)-2-methylpiperazin-1-ium 2,5-dihydroxybenzoate methanol solvate, C27H32FN3O9
  11. Crystal structure of (μ2-1-(4,4′-bipyridine-κ2N:N′)-bis[diaqua-(4-iodopyridine-2,6-dicarboxylato-κ3O,N,O′)–cobalt(II)], C24H20Co2I2N4O12
  12. The crystal structure of dimethyl 4,4′-(10,20-diphenylporphyrin-5,15-diyl)dibenzoate dichloromethane solvate, C49H36N4O4Cl2
  13. (E)-2-((E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-ylidene)hydrazine-1-carbothioamide C14H23N3S1
  14. The crystal structure of [1-(4-(trifluoromethyl)phenyl)-3,4-dihydroquinolin-2(1H)-one], C16H12F3NO
  15. Crystal structure of (E)-2-amino-N′-((3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene)benzohydrazide – dimethylformamide – water (1/1/2), C15H16N4O3·C3H7NO·2H2O
  16. Crystal structure of 3-(4-bromophenyl)-5-methyl-1H-pyrazole, C10H9BrN2
  17. Crystal structure of 1,10-phenanthrolinium bromide dihydrate, C12H9N2Br
  18. Crystal structure of N-(4′-chloro-[1,1′-biphenyl]-2-yl)formamide, C13H10ClNO
  19. The crystal structure of nitroterephthalic acid, C8H5NO6
  20. Crystal structure of (2-((4-bromo-2,6-dichlorophenyl)amino)phenyl) (morpholino)methanone, C17H15BrCl2N2O2
  21. Crystal structure of tetraaqua-bis(ethanol-κO)-tetrakis(μ2-trifluoroacetate-κ2O:O′)-bis(trifluoroacetate-κ2O)digadolinium(III) Gd2C16H20O18F18
  22. The crystal structure of dimethyl 4,4′-[10,20-bis(2,6-difluorophenyl)porphyrin-5,15-diyl]dibenzoate chloroform solvate, C50H32Cl6F4N4O4
  23. The crystal structure of N,N′-((nitroazanediyl)bis(methylene))diacetamide, C6H12O4N4
  24. The crystal structure of [bis(2,2′-bipyridine-6-carboxylato-κ3N,N,O)magnesium(II)]dihydrate, C22H18N4O6Mg
  25. Crystal structure of poly[diaqua-(bis(μ2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′] cobalt(II)-tetraqua-bis(1,4-bis(imidazol-1-ylmethyl)benzene)-κ1N)-cobalt(II) di(2,5-thiophenedicarboxylate) dihydrate, C68H76Co2N16O16S2
  26. Crystal structure of poly[chlorido-μ2-chlorido-(μ2-1-[(2-ethyl-4-methyl-1H-imidazol-1-yl)methyl]-1H-benzotriazole-κN:N’)cadmium(II)], C13H15CdN5Cl2
  27. The crystal structure of (4-hydroxybenzenesulfonate)-k1O-6,6′-((1E,1′E)- (ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene)) bis(2-methoxyphenol)-κ2N,N,μ2O,O,κ2O, O)-(methanol)-cobalt(II) sodium(I), C25H27CoN2NaO9S
  28. Crystal structure of (1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl)(4-((2-methyl-6-(trifluoromethyl)pyrimidin-4-yl)amino)piperidin-1-yl)methanone, C17H18F6N6O
  29. Crystal structure of bis{[(cyclohexylimino)(phenylimino)-l5-(methyl)diethylazane-κ2N:N′]-(ethyl)-zinc(II)]}, C38H62N6Zn2
  30. Crystal structure of 2-[(4-bromobenzyl)thio]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C13H8Br2N2OS2
  31. Crystal structure of 10-methoxy-7,11b,12,13-tetrahydro-6H-pyrazino [2′,3′:5,6]pyrazino[2,1-a]isoquinoline, C15H16N4O
  32. The crystal structure of 1-propyl-2-nitro-imidazole oxide, C6H9N3O3
  33. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid–2-ethoxybenzamide (1/1), C17H16N2O8
  34. The structure of RUB-1, (C8H16N)6[B6Si48O108], a boron containing levyne-type zeolite, occluding N-methyl-quinuclidinium in the cage-like pores
  35. The crystal structure of diaqua-(naphthalene-4,5-dicarboxylate-1,8-dicarboxylic anhydride-κ1O)-(4′-(4-(1H-benzimidazolyl-1-yl)phenyl)-2,2′:6′,2″-terpyridine-κ3N,N′,N″)–manganese(II) dihydrate, C42H27MnN5O9·2H2O
  36. Crystal structure of 6,6′-((1E,1′E)-hydrazine-1,2-diylidenebis(methanylylidene))bis (3-(3-bromopropoxy)phenol), C20H22Br2N2O4
  37. The crystal structure of 3-(2-hydroxyphenyl)-4-phenyl-6-(p-tolyl)-2H-pyran-2-one, C24H18O3
  38. Crystal structure of bis(μ2-2-(1,5-dimethyl–3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)-(nitrato-κ2O,O′)dicobalt(II), C36H32Co2N8O4
  39. Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α] phenanthren-3-one O-(4-fluorobenzoyl) oxime, C28H36FNO2
  40. The crystal structure of 4-aminiumbiphenyl benzenesulfonate, C18H17NO3S
  41. Synthesis and crystal structure of 1-(7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)-N,N-dimethylmethanaminiumnitrate, C18H17N3O9
  42. Crystal structure of N-(Ar)-N′-(Ar′)-formamidine, C14H12Br2N2O
  43. The crystal structure of 4-(2,4-dichlorophenyl)-2-(4-fluorophenyl)-5-methyl-1H-imidazole, C16H11Cl2FN2
  44. Crystal structure of 1-(4–chlorophenyl)-4-benzoyl-3-methyl-1H-pyrazol-5-ol, C17H13ClN2O2
  45. The crystal structure of 5-amino-1-methyl-4-nitroimidazole, C4H6O2N4
  46. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene-N,N′-bis(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-1,3,2-diazaborol-2-yl)-l2-germenediamine, C63H94B2GeN8
  47. The crystal structure of (bromido, chlorido)-tricarbonyl-(5,5′-dimethyl-2,2′-bipyridine)-rhenium(I), C15H12Br0.2Cl0.8N2O3Re1
  48. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-bis(propan-2-yl)-1H-pyrazol-4-amine, C26H36N6
  49. The crystal structure of poly[2-(4-carboxypyridin-3-yl)terephthalpoly[diaqua-(μ4-2-(6-carboxylatopyridin-3-yl)terephthalato-κ5O,N:O′:O″,O‴)]) cadmium(II)] dihydrate, C28H20Cd3N2O16
  50. Crystal structure of [tetraaqua-bis((3-carboxy-5-(pyridin-4-yl)benzoate-κ1N)cobalt(II)] tetrahydrate, C26H32CoN2O16
  51. Crystal structure of bis(μ2-azido-κ2N:N)-tetrakis(azido-κ1N)-tetrakis(1,10-phenanthroline-κ2N,N′)dibismuth(III), C48H32N26Bi2
  52. Crystal structure of (Z)-N-(4-(4-(4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenoxy)butoxy)phenyl)acetamide, C30H31NO8
  53. Crystal structure of poly[diaqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)-bis(μ2-5-carboxybenzene-1,3-dicarboxylato-O,O′:O″)-aqua-di-zinc dihydrate solvate], C27H28N4O16Zn2
  54. Crystal structure of 2-(3,5,5-trimethylcyclohex-2-en-1-ylidene)malononitrile, C12H14N2
  55. Crystal structure of chlorido-(5-nitro-2-phenylpyridine-κ2N,C)-[(methylsulfinyl)methane-κ1S]platinum(II), C13H13ClN2O3PtS
  56. The crystal structure of the co-crystal 1,4-dioxane–4,6-bis(nitroimino)-1,3,5-triazinan-2-one(2/1), C11H19N7O9
  57. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-dimethyl-1H-pyrazol-4-amine di-methanol solvate, C18H20N6·2(CH3OH)
  58. Crystal structure of catena-poly[bis(μ2-azido-k2N:N′)-(nitrato-K2N:N′)-bis(1,10-phenanthroline-K2N:N′)samarium(III)], C24H16N11O3Sm
  59. Crystal structure of (Z)-2-(4-((5-bromopentyl)oxy)benzylidene)-4,5,6-trimethoxybenzofuran-3(2H)-one, C23H25BrO6
  60. Crystal structure of bis(3,5-dimethyl-1H-pyrazol-4-ammonium) tetrafluoroterephthate, 2[C5H10N3][C8F4O4]
  61. Crystal structure of 2-amino-4-(2-fluoro-4-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  62. Crystal structure of 6-(pyridin-3-yl)-1,3,5-triazine-2,4-diamine-sebacic acid (2/1), C13H17N6O2
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