Home Physical Sciences The crystal structure of (N-([1,1′:4′,1″-terphenyl]-4,4′-diethyl)-2-(bis(pyridin-2-ylmethyl)amino)acetamide-κ4N,N,N″, O)tri(nitrato-kO, O′) samarium(III) - methanol - acetonitrile (1/1/1), C40H39SmN8O14
Article Open Access

The crystal structure of (N-([1,1′:4′,1″-terphenyl]-4,4′-diethyl)-2-(bis(pyridin-2-ylmethyl)amino)acetamide-κ4N,N,N″, O)tri(nitrato-kO, O′) samarium(III) - methanol - acetonitrile (1/1/1), C40H39SmN8O14

  • Hai-Ping Wang ORCID logo EMAIL logo , Ci-Mao Zhang , Guo-Peng Huang and Jia-Jun Liang
Published/Copyright: July 5, 2023
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 238 Issue 5

Abstract

C40H39SmN8O14, triclinic, P1̄ (no. 2), a = 8.2799(1) Å, b = 16.6666(5) Å, c = 17.1471(3) Å, α =  73.549 ( 2 ) ∘ , β =  89.123 ( 1 ) ∘ , γ = 83.045(2)°, V = 2252.2(1) Å3, Z = 2, R g t (F) = 0.0592, w R r e f (F2) = 0.1438, T = 297.71(13) K.

CCDC no.: 2240008

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless needle
Size: 0.15 × 0.14 × 0.12 mm
Wavelength: Cu Kα radiation (1.54184 Å)
μ: 10.4 mm−1
Diffractometer, scan mode: XtaLAB Synergy, ω
θmax, completeness: 74.5°, >99 %
N(hkl)measured, N(hkl)unique, Rint: 29937, 8756, 0.097
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 7434
N(param)refined: 571
Programs: SHELX [1, 2], Olex2 [3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
C1 0.5067 (17) −0.0566 (7) 0.3997 (7) 0.124 (4)
H1A 0.489595 −0.103630 0.380329 0.186*
H1B 0.436067 −0.055043 0.444319 0.186*
H1C 0.617914 −0.062362 0.417619 0.186*
C2 0.4704 (14) 0.0231 (6) 0.3328 (6) 0.091 (3)
H2A 0.526909 0.018336 0.284008 0.109*
H2B 0.354439 0.034516 0.320499 0.109*
C3 0.4806 (10) 0.1683 (5) 0.3125 (4) 0.0653 (19)
C4 0.5388 (8) 0.2342 (5) 0.3443 (4) 0.0576 (17)
C5 0.6399 (8) 0.2146 (5) 0.4132 (4) 0.0589 (17)
H5 0.679018 0.158738 0.438771 0.071*
C6 0.6819 (8) 0.2775 (5) 0.4435 (4) 0.0566 (17)
H6 0.749146 0.263555 0.489508 0.068*
C7 0.6253 (7) 0.3615 (4) 0.4064 (4) 0.0498 (15)
C8 0.5286 (8) 0.3806 (5) 0.3360 (4) 0.0551 (16)
H8 0.493158 0.436597 0.308917 0.066*
C9 0.4851 (9) 0.3178 (5) 0.3062 (4) 0.0594 (17)
H9 0.418808 0.331695 0.259895 0.071*
C10 0.6693 (7) 0.4292 (4) 0.4397 (4) 0.0480 (14)
C11 0.6820 (8) 0.4174 (4) 0.5237 (4) 0.0522 (15)
H11 0.660567 0.366528 0.559460 0.063*
C12 0.7257 (7) 0.4797 (5) 0.5540 (4) 0.0518 (16)
H12 0.733912 0.469536 0.610079 0.062*
C13 0.7584 (7) 0.5582 (4) 0.5035 (3) 0.0472 (14)
C14 0.7423 (7) 0.5696 (4) 0.4188 (3) 0.0439 (13)
C15 0.6983 (7) 0.5065 (4) 0.3890 (4) 0.0481 (15)
H15 0.687718 0.516343 0.333076 0.058*
C16 0.8057 (7) 0.6226 (5) 0.5401 (4) 0.0505 (15)
C17 0.9106 (8) 0.5978 (5) 0.6076 (4) 0.0547 (16)
H17 0.950961 0.541217 0.628436 0.066*
C18 0.9551 (8) 0.6553 (5) 0.6438 (4) 0.0622 (18)
H18 1.024822 0.637075 0.689065 0.075*
C19 0.8977 (8) 0.7409 (5) 0.6142 (4) 0.0567 (17)
C20 0.7945 (9) 0.7668 (5) 0.5461 (4) 0.0626 (18)
H20 0.757118 0.823646 0.524369 0.075*
C21 0.7473 (8) 0.7083 (5) 0.5109 (4) 0.0558 (16)
H21 0.675024 0.726195 0.466658 0.067*
C22 0.9449 (9) 0.8063 (6) 0.6495 (5) 0.069 (2)
C23 1.0742 (13) 0.8365 (7) 0.7557 (6) 0.104 (3)
H23A 0.979841 0.871895 0.766621 0.124*
H23B 1.143509 0.872006 0.718629 0.124*
C24 1.1654 (16) 0.7901 (9) 0.8332 (6) 0.132 (5)
H24A 1.246074 0.747859 0.823277 0.197*
H24B 1.090974 0.763743 0.872981 0.197*
H24C 1.217704 0.829053 0.853048 0.197*
C25 0.6745 (7) 0.6908 (4) 0.3011 (3) 0.0437 (14)
C26 0.7263 (7) 0.7703 (4) 0.2448 (3) 0.0440 (13)
H26A 0.674273 0.819327 0.259288 0.053*
H26B 0.843273 0.769610 0.248199 0.053*
C27 0.7849 (7) 0.7093 (5) 0.1357 (4) 0.0520 (16)
H27A 0.795986 0.656646 0.178831 0.062*
H27B 0.891904 0.727687 0.125225 0.062*
C28 0.7183 (8) 0.6957 (5) 0.0602 (4) 0.0580 (17)
C29 0.8218 (10) 0.6797 (7) −0.0004 (5) 0.088 (3)
H29 0.933559 0.679370 0.004580 0.106*
C30 0.7566 (13) 0.6644 (8) −0.0671 (6) 0.107 (3)
H30 0.823105 0.655293 −0.108758 0.128*
C31 0.5929 (12) 0.6628 (8) −0.0715 (5) 0.100 (4)
H31 0.546229 0.650449 −0.115093 0.120*
C32 0.4981 (10) 0.6796 (7) −0.0103 (5) 0.081 (3)
H32 0.386244 0.679375 −0.014335 0.097*
C33 0.6911 (7) 0.8591 (4) 0.1062 (4) 0.0514 (15)
H33A 0.796161 0.875177 0.115632 0.062*
H33B 0.686461 0.857182 0.050271 0.062*
C34 0.5607 (7) 0.9238 (4) 0.1184 (3) 0.0463 (14)
C35 0.5871 (9) 1.0080 (5) 0.1009 (4) 0.0558 (17)
H35 0.689015 1.024109 0.084870 0.067*
C36 0.4618 (10) 1.0663 (5) 0.1076 (4) 0.0653 (19)
H36 0.477367 1.122833 0.095558 0.078*
C37 0.3129 (10) 1.0418 (5) 0.1320 (5) 0.0662 (19)
H37 0.225704 1.081154 0.135927 0.079*
C38 0.2956 (9) 0.9572 (5) 0.1506 (4) 0.0598 (17)
H38 0.195178 0.940425 0.168592 0.072*
C39 0.9482 (14) 0.9365 (7) 0.3226 (8) 0.101 (3)
C40 1.0334 (17) 0.9256 (8) 0.3992 (8) 0.131 (5)
H40A 1.104613 0.968348 0.392570 0.197*
H40B 1.096085 0.871004 0.415389 0.197*
H40C 0.955663 0.930318 0.440320 0.197*
N1 0.7753 (5) 0.6470 (3) 0.3627 (3) 0.0439 (11)
H1 0.864473 0.666403 0.368812 0.053*
N2 0.6760 (5) 0.7733 (3) 0.1617 (3) 0.0435 (11)
N3 0.5569 (6) 0.6963 (4) 0.0547 (3) 0.0557 (14)
N4 0.4159 (6) 0.8974 (4) 0.1441 (3) 0.0481 (12)
N5 0.2837 (10) 0.5768 (5) 0.1527 (5) 0.084 (2)
N6 0.1388 (6) 0.8468 (4) 0.0433 (3) 0.0574 (15)
N7 0.1582 (6) 0.7390 (4) 0.3092 (3) 0.0498 (13)
N8 0.8829 (15) 0.9447 (8) 0.2638 (9) 0.148 (5)
O1 0.4032 (9) 0.1835 (4) 0.2501 (4) 0.0921 (19)
O2 0.5247 (7) 0.0905 (4) 0.3599 (3) 0.0766 (15)
O3 0.9154 (9) 0.8809 (5) 0.6172 (4) 0.101 (2)
O4 1.0242 (7) 0.7742 (4) 0.7203 (4) 0.0829 (17)
O5 0.5413 (5) 0.6699 (3) 0.2890 (2) 0.0526 (11)
O6 0.2455 (13) 0.5105 (5) 0.1497 (6) 0.153 (4)
O7 0.2114 (6) 0.6474 (4) 0.1122 (3) 0.0651 (13)
O8 0.4004 (7) 0.5799 (4) 0.1999 (3) 0.0747 (15)
O9 0.1059 (5) 0.8216 (3) 0.1191 (3) 0.0539 (11)
O10 0.0422 (7) 0.8912 (5) −0.0072 (3) 0.101 (2)
O11 0.2802 (5) 0.8219 (3) 0.0246 (3) 0.0596 (12)
O12 0.1569 (5) 0.6855 (3) 0.2694 (3) 0.0571 (11)
O13 0.0668 (5) 0.7394 (3) 0.3652 (3) 0.0610 (13)
O14 0.2603 (5) 0.7913 (3) 0.2872 (3) 0.0566 (11)
Sm1 0.37147 (3) 0.73754 (2) 0.16732 (2) 0.04119 (11)

1 Source of materials

All chemicals were purchased and used as received without further purification. Diethyl 2 ′ -(2-(bis(pyridin-2-ylmethyl)amino)acetamido)-[1,1 ′ :4 ′ , 1 ″ -terphenyl]-4,4 ″ -dicarboxylate (L) was prepared according to previous literature reports [4, 5]. A solution of L (6.3 mg, 0.01 mmol) in acetonitrile (5 mL) was added to a stirred solution of Sm(NO3)3·6H2O (4.5 mg, 0.01 mmol) in acetonitrile (5 mL) at room temperature for 1 h. After filtration, slow diffusion of diethyl ether into the filtrate over 72 h afforded block crystals.

2 Experimental details

All C-bound hydrogen atoms were refined isotropically on calculated positions using a riding model with their U iso values constrained to 1.5 times the U eq of their pivot atoms for terminal sp3 carbon atoms and 1.2 times for all other carbon atoms. One methanol molecule has been removed by solvent mask because it was too unordered: A solvent mask was calculated and 31 electrons were found in a volume of 190 Å3 in 1 void per unit cell.

3 Comment

A tripodal ligand constructed by pyridine and amide could sensitize lanthanide cations which have fascinating optical properties such as long-lived, line-shaped, and position-defined luminescence and the lanthanide complexes have been studied in light-conversion molecular devices and organic light-emitting devices [6], [7], [8], [9]. Some of them have a strong light absorption yield, the multidentate chelate tripodal ligands could coordinated with a lanthanide cation by a helical wrapping configuration of the ligand to build a well-protected coordination environment. In other words, the coordination structures could influence the energy transfer to regulate the luminescence behavior of the lanthanide complexes.

The crystal structure of the complex is shown in the figure. In the asymmetric unit the tripodal ligand takes a fan-like configuration to coordinated to the Sm(III) ion with three bidentate N O 3 − anions and a free acetonitrile and a methanol molecule being present in the structure. One apical N, two pyridine N, one amide O, and six nitrate O atoms participate in the coordination of the Sm(III) center to form a 10-coordinating environment. The bond lengths of coordination bonds formed by Sm3+ and tripod are as follows: the Sm1–O5 bond length is 2.442 (4) Å, the Sm1–N2 bond length is 2.654 (4) Å, the Sm1–N3 bond length is 2.638 (5) Å, the Sm1–N4 bond length is 2.649 (5) Å, similar to that reported in Ref. [10]. The bond lengths formed by Sm3+ and six O atoms from three double-toothed N O 3 − are respectively: the Sm1–O7 bond length is 2.497(5) Å, the Sm1–O8 bond length is 2.509(6) Å, the Sm1–O9 bond length is 2.477(4) Å, the Sm1–O11 bond length is 2.526(4) Å, the Sm1–O12 bond length is 2.528(4) Å, the Sm1–O14 bond length is 2.581(5) Å, similar to that reported in Ref. [11].

Corresponding author: Hai-Ping Wang, School of Biotechnology and Health Sciences, Wuyi Universty, Guangdong 529020, P.R. China, E-mail:

Acknowledgements

We gratefully acknowledge support by the NSFC of China (21703291) and the NSF of Guangdong Province (2017A030310258).

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: NSFC of China (21703291) and the NSF of Guangdong Province (2017A030310258).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

2. Sheldrick, G. M. SHELXTL – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Search in Google Scholar PubMed PubMed Central

3. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Search in Google Scholar

4. Zhang, G., Bi, S., Song, L., Wang, F., Yu, J., Wang, L. New diketopyrrolopyrrole (DPP) derivative as fluorescent probe for Zn2+. Dyes Pigments 2013, 99, 779–786; https://doi.org/10.1016/j.dyepig.2013.06.027.Search in Google Scholar

5. Alezi, D., Jia, J., Bhat, P. M., Shurenko, A., Solovyeva, V., Chen, Z., Belmabkhout, Y., Eddaoudi, M. Reticular chemistry for the construction of highly porous aluminum-based nia-metal–organic frameworks. Inorg. Chem. 2022, 61, 10661–10666; https://doi.org/10.1021/acs.inorgchem.2c00756.Search in Google Scholar PubMed

6. Feng, W.-X., Yin, S.-Y., Pan, M., Wang, H.-P., Fan, Y.-N., Lü, X.-Q., Su, C.-Y. PMMA-copolymerized color tunable and pure white-light emitting Eu3+—Tb3+ containing Ln-metallopolymers. J. Mater. Chem. C 2017, 5, 1742–1750; https://doi.org/10.1039/c6tc04851j.Search in Google Scholar

7. Kataoka, Y., Paul, D., Miyake, H., Shinoda, S., Tsukube, H. A Cl– anion-responsive luminescent Eu3+ complex with a chiral tripod: ligand substituent effects on ternary complex stoichiometry and anion sensing selectivity. Dalton Trans. 2007, 2784–2791; https://doi.org/10.1039/b703944a.Search in Google Scholar PubMed

8. Kataoka, Y., Paul, D., Miyake, H., Yaita, T., Miyoshi, E., Mori, H., Tsukamoto, S., Tatewaki, H., Shinoda, S., Tsukube, H. Experimental and theoretical approaches toward anion-responsive tripod–lanthanide complexes: mixed-donor ligand effects on lanthanide complexation and luminescence sensing profiles. Chem. Eur J. 2008, 14, 5258–5266; https://doi.org/10.1002/chem.200701898.Search in Google Scholar PubMed

9. Sa, J. P., Guénée, L., Pal, P., Hamacek, J. Lanthanide podands with a short tripodal ligand: the missing piece of puzzle. Eur. J. Inorg. Chem. 2020, 2021, 276–282; https://doi.org/10.1002/ejic.202000861.Search in Google Scholar

10. Li, X.-L., Zhang, X.-L., Hu, M., Zhu, C., Chen, C., Wang, A.-L. Homochiral mono- and dinuclear SmIII complexes showing the effect of nuclearity on their photophysical properties. Polyhedron 2016, 111, 94–100; https://doi.org/10.1016/j.poly.2016.03.043.Search in Google Scholar

11. Chen, X.-L., Shen, Y.-J., Gao, C., Yang, J., Sun, X., Zhang, X., Yang, Y.-D., Wei, G.-P., Xiang, J.-F., Sessler, J. L., Gong, H.-Y. Regulating the structures of self-assembled mechanically interlocked moleculecular constructs via dianion precursor substituent effects. J. Am. Chem. Soc. 2020, 142, 7443–7455; https://doi.org/10.1021/jacs.9b13473.Search in Google Scholar PubMed

Received: 2023-04-04
Accepted: 2023-06-08
Published Online: 2023-07-05
Published in Print: 2023-10-26

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of (N-([1,1′:4′,1″-terphenyl]-4,4′-diethyl)-2-(bis(pyridin-2-ylmethyl)amino)acetamide-κ4N,N,N″, O)tri(nitrato-kO, O′) samarium(III) - methanol - acetonitrile (1/1/1), C40H39SmN8O14
  4. The crystal structure of 6,6′-(((2-(dimethylamino)ethyl)azanediyl)bis(methylene))bis(2-chloro-4-methyl phenolate-κ4N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV), C27H27Cl2N3O6Ti
  5. N′-[(1E)-(4–Fluorophenyl)methylidene]adamantane-1-carbohydrazide, C18H21FN2O
  6. Crystal structure of 4-bromo-3-nitro-1H-pyrazole-5-carboxylic acid monohydrate, C4H2N3BrO4·H2O
  7. Crystal structure of dipyridine-k1N-tris(2,2,6,6-tetramethyl-5-oxohept-3-en-3-olato-k2O,O′)dysprosium(III), DyC43H67O6N2
  8. Crystal structure of cyclo[tetraiodido-bis{μ2-1-[(benzotriazol-1-yl)methyl]-1-H-1,3-(2-isopropyl-imidazol)-k2N:N}dicadmiun(II)], C26H30N10Cd2I4
  9. The crystal structure of tert-butyl (E)-3-(2-(benzylideneamino)phenyl)-1H-indole-1-carboxylate, C26H24N2O2
  10. The crystal structure of 4-(3-carboxy-1-cyclopropyl-6-fluoro-8-methoxy-4-oxo-1,4- dihydroquinolin-7-yl)-2-methylpiperazin-1-ium 2,5-dihydroxybenzoate methanol solvate, C27H32FN3O9
  11. Crystal structure of (μ2-1-(4,4′-bipyridine-κ2N:N′)-bis[diaqua-(4-iodopyridine-2,6-dicarboxylato-κ3O,N,O′)–cobalt(II)], C24H20Co2I2N4O12
  12. The crystal structure of dimethyl 4,4′-(10,20-diphenylporphyrin-5,15-diyl)dibenzoate dichloromethane solvate, C49H36N4O4Cl2
  13. (E)-2-((E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-ylidene)hydrazine-1-carbothioamide C14H23N3S1
  14. The crystal structure of [1-(4-(trifluoromethyl)phenyl)-3,4-dihydroquinolin-2(1H)-one], C16H12F3NO
  15. Crystal structure of (E)-2-amino-N′-((3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene)benzohydrazide – dimethylformamide – water (1/1/2), C15H16N4O3·C3H7NO·2H2O
  16. Crystal structure of 3-(4-bromophenyl)-5-methyl-1H-pyrazole, C10H9BrN2
  17. Crystal structure of 1,10-phenanthrolinium bromide dihydrate, C12H9N2Br
  18. Crystal structure of N-(4′-chloro-[1,1′-biphenyl]-2-yl)formamide, C13H10ClNO
  19. The crystal structure of nitroterephthalic acid, C8H5NO6
  20. Crystal structure of (2-((4-bromo-2,6-dichlorophenyl)amino)phenyl) (morpholino)methanone, C17H15BrCl2N2O2
  21. Crystal structure of tetraaqua-bis(ethanol-κO)-tetrakis(μ2-trifluoroacetate-κ2O:O′)-bis(trifluoroacetate-κ2O)digadolinium(III) Gd2C16H20O18F18
  22. The crystal structure of dimethyl 4,4′-[10,20-bis(2,6-difluorophenyl)porphyrin-5,15-diyl]dibenzoate chloroform solvate, C50H32Cl6F4N4O4
  23. The crystal structure of N,N′-((nitroazanediyl)bis(methylene))diacetamide, C6H12O4N4
  24. The crystal structure of [bis(2,2′-bipyridine-6-carboxylato-κ3N,N,O)magnesium(II)]dihydrate, C22H18N4O6Mg
  25. Crystal structure of poly[diaqua-(bis(μ2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′] cobalt(II)-tetraqua-bis(1,4-bis(imidazol-1-ylmethyl)benzene)-κ1N)-cobalt(II) di(2,5-thiophenedicarboxylate) dihydrate, C68H76Co2N16O16S2
  26. Crystal structure of poly[chlorido-μ2-chlorido-(μ2-1-[(2-ethyl-4-methyl-1H-imidazol-1-yl)methyl]-1H-benzotriazole-κN:N’)cadmium(II)], C13H15CdN5Cl2
  27. The crystal structure of (4-hydroxybenzenesulfonate)-k1O-6,6′-((1E,1′E)- (ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene)) bis(2-methoxyphenol)-κ2N,N,μ2O,O,κ2O, O)-(methanol)-cobalt(II) sodium(I), C25H27CoN2NaO9S
  28. Crystal structure of (1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl)(4-((2-methyl-6-(trifluoromethyl)pyrimidin-4-yl)amino)piperidin-1-yl)methanone, C17H18F6N6O
  29. Crystal structure of bis{[(cyclohexylimino)(phenylimino)-l5-(methyl)diethylazane-κ2N:N′]-(ethyl)-zinc(II)]}, C38H62N6Zn2
  30. Crystal structure of 2-[(4-bromobenzyl)thio]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C13H8Br2N2OS2
  31. Crystal structure of 10-methoxy-7,11b,12,13-tetrahydro-6H-pyrazino [2′,3′:5,6]pyrazino[2,1-a]isoquinoline, C15H16N4O
  32. The crystal structure of 1-propyl-2-nitro-imidazole oxide, C6H9N3O3
  33. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid–2-ethoxybenzamide (1/1), C17H16N2O8
  34. The structure of RUB-1, (C8H16N)6[B6Si48O108], a boron containing levyne-type zeolite, occluding N-methyl-quinuclidinium in the cage-like pores
  35. The crystal structure of diaqua-(naphthalene-4,5-dicarboxylate-1,8-dicarboxylic anhydride-κ1O)-(4′-(4-(1H-benzimidazolyl-1-yl)phenyl)-2,2′:6′,2″-terpyridine-κ3N,N′,N″)–manganese(II) dihydrate, C42H27MnN5O9·2H2O
  36. Crystal structure of 6,6′-((1E,1′E)-hydrazine-1,2-diylidenebis(methanylylidene))bis (3-(3-bromopropoxy)phenol), C20H22Br2N2O4
  37. The crystal structure of 3-(2-hydroxyphenyl)-4-phenyl-6-(p-tolyl)-2H-pyran-2-one, C24H18O3
  38. Crystal structure of bis(μ2-2-(1,5-dimethyl–3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)-(nitrato-κ2O,O′)dicobalt(II), C36H32Co2N8O4
  39. Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α] phenanthren-3-one O-(4-fluorobenzoyl) oxime, C28H36FNO2
  40. The crystal structure of 4-aminiumbiphenyl benzenesulfonate, C18H17NO3S
  41. Synthesis and crystal structure of 1-(7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)-N,N-dimethylmethanaminiumnitrate, C18H17N3O9
  42. Crystal structure of N-(Ar)-N′-(Ar′)-formamidine, C14H12Br2N2O
  43. The crystal structure of 4-(2,4-dichlorophenyl)-2-(4-fluorophenyl)-5-methyl-1H-imidazole, C16H11Cl2FN2
  44. Crystal structure of 1-(4–chlorophenyl)-4-benzoyl-3-methyl-1H-pyrazol-5-ol, C17H13ClN2O2
  45. The crystal structure of 5-amino-1-methyl-4-nitroimidazole, C4H6O2N4
  46. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene-N,N′-bis(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-1,3,2-diazaborol-2-yl)-l2-germenediamine, C63H94B2GeN8
  47. The crystal structure of (bromido, chlorido)-tricarbonyl-(5,5′-dimethyl-2,2′-bipyridine)-rhenium(I), C15H12Br0.2Cl0.8N2O3Re1
  48. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-bis(propan-2-yl)-1H-pyrazol-4-amine, C26H36N6
  49. The crystal structure of poly[2-(4-carboxypyridin-3-yl)terephthalpoly[diaqua-(μ4-2-(6-carboxylatopyridin-3-yl)terephthalato-κ5O,N:O′:O″,O‴)]) cadmium(II)] dihydrate, C28H20Cd3N2O16
  50. Crystal structure of [tetraaqua-bis((3-carboxy-5-(pyridin-4-yl)benzoate-κ1N)cobalt(II)] tetrahydrate, C26H32CoN2O16
  51. Crystal structure of bis(μ2-azido-κ2N:N)-tetrakis(azido-κ1N)-tetrakis(1,10-phenanthroline-κ2N,N′)dibismuth(III), C48H32N26Bi2
  52. Crystal structure of (Z)-N-(4-(4-(4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenoxy)butoxy)phenyl)acetamide, C30H31NO8
  53. Crystal structure of poly[diaqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)-bis(μ2-5-carboxybenzene-1,3-dicarboxylato-O,O′:O″)-aqua-di-zinc dihydrate solvate], C27H28N4O16Zn2
  54. Crystal structure of 2-(3,5,5-trimethylcyclohex-2-en-1-ylidene)malononitrile, C12H14N2
  55. Crystal structure of chlorido-(5-nitro-2-phenylpyridine-κ2N,C)-[(methylsulfinyl)methane-κ1S]platinum(II), C13H13ClN2O3PtS
  56. The crystal structure of the co-crystal 1,4-dioxane–4,6-bis(nitroimino)-1,3,5-triazinan-2-one(2/1), C11H19N7O9
  57. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-dimethyl-1H-pyrazol-4-amine di-methanol solvate, C18H20N6·2(CH3OH)
  58. Crystal structure of catena-poly[bis(μ2-azido-k2N:N′)-(nitrato-K2N:N′)-bis(1,10-phenanthroline-K2N:N′)samarium(III)], C24H16N11O3Sm
  59. Crystal structure of (Z)-2-(4-((5-bromopentyl)oxy)benzylidene)-4,5,6-trimethoxybenzofuran-3(2H)-one, C23H25BrO6
  60. Crystal structure of bis(3,5-dimethyl-1H-pyrazol-4-ammonium) tetrafluoroterephthate, 2[C5H10N3][C8F4O4]
  61. Crystal structure of 2-amino-4-(2-fluoro-4-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  62. Crystal structure of 6-(pyridin-3-yl)-1,3,5-triazine-2,4-diamine-sebacic acid (2/1), C13H17N6O2
https://doi.org/10.1515/ncrs-2023-0163
Creative Commons
BY 4.0

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of (N-([1,1′:4′,1″-terphenyl]-4,4′-diethyl)-2-(bis(pyridin-2-ylmethyl)amino)acetamide-κ4N,N,N″, O)tri(nitrato-kO, O′) samarium(III) - methanol - acetonitrile (1/1/1), C40H39SmN8O14
  4. The crystal structure of 6,6′-(((2-(dimethylamino)ethyl)azanediyl)bis(methylene))bis(2-chloro-4-methyl phenolate-κ4N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV), C27H27Cl2N3O6Ti
  5. N′-[(1E)-(4–Fluorophenyl)methylidene]adamantane-1-carbohydrazide, C18H21FN2O
  6. Crystal structure of 4-bromo-3-nitro-1H-pyrazole-5-carboxylic acid monohydrate, C4H2N3BrO4·H2O
  7. Crystal structure of dipyridine-k1N-tris(2,2,6,6-tetramethyl-5-oxohept-3-en-3-olato-k2O,O′)dysprosium(III), DyC43H67O6N2
  8. Crystal structure of cyclo[tetraiodido-bis{μ2-1-[(benzotriazol-1-yl)methyl]-1-H-1,3-(2-isopropyl-imidazol)-k2N:N}dicadmiun(II)], C26H30N10Cd2I4
  9. The crystal structure of tert-butyl (E)-3-(2-(benzylideneamino)phenyl)-1H-indole-1-carboxylate, C26H24N2O2
  10. The crystal structure of 4-(3-carboxy-1-cyclopropyl-6-fluoro-8-methoxy-4-oxo-1,4- dihydroquinolin-7-yl)-2-methylpiperazin-1-ium 2,5-dihydroxybenzoate methanol solvate, C27H32FN3O9
  11. Crystal structure of (μ2-1-(4,4′-bipyridine-κ2N:N′)-bis[diaqua-(4-iodopyridine-2,6-dicarboxylato-κ3O,N,O′)–cobalt(II)], C24H20Co2I2N4O12
  12. The crystal structure of dimethyl 4,4′-(10,20-diphenylporphyrin-5,15-diyl)dibenzoate dichloromethane solvate, C49H36N4O4Cl2
  13. (E)-2-((E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-ylidene)hydrazine-1-carbothioamide C14H23N3S1
  14. The crystal structure of [1-(4-(trifluoromethyl)phenyl)-3,4-dihydroquinolin-2(1H)-one], C16H12F3NO
  15. Crystal structure of (E)-2-amino-N′-((3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene)benzohydrazide – dimethylformamide – water (1/1/2), C15H16N4O3·C3H7NO·2H2O
  16. Crystal structure of 3-(4-bromophenyl)-5-methyl-1H-pyrazole, C10H9BrN2
  17. Crystal structure of 1,10-phenanthrolinium bromide dihydrate, C12H9N2Br
  18. Crystal structure of N-(4′-chloro-[1,1′-biphenyl]-2-yl)formamide, C13H10ClNO
  19. The crystal structure of nitroterephthalic acid, C8H5NO6
  20. Crystal structure of (2-((4-bromo-2,6-dichlorophenyl)amino)phenyl) (morpholino)methanone, C17H15BrCl2N2O2
  21. Crystal structure of tetraaqua-bis(ethanol-κO)-tetrakis(μ2-trifluoroacetate-κ2O:O′)-bis(trifluoroacetate-κ2O)digadolinium(III) Gd2C16H20O18F18
  22. The crystal structure of dimethyl 4,4′-[10,20-bis(2,6-difluorophenyl)porphyrin-5,15-diyl]dibenzoate chloroform solvate, C50H32Cl6F4N4O4
  23. The crystal structure of N,N′-((nitroazanediyl)bis(methylene))diacetamide, C6H12O4N4
  24. The crystal structure of [bis(2,2′-bipyridine-6-carboxylato-κ3N,N,O)magnesium(II)]dihydrate, C22H18N4O6Mg
  25. Crystal structure of poly[diaqua-(bis(μ2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′] cobalt(II)-tetraqua-bis(1,4-bis(imidazol-1-ylmethyl)benzene)-κ1N)-cobalt(II) di(2,5-thiophenedicarboxylate) dihydrate, C68H76Co2N16O16S2
  26. Crystal structure of poly[chlorido-μ2-chlorido-(μ2-1-[(2-ethyl-4-methyl-1H-imidazol-1-yl)methyl]-1H-benzotriazole-κN:N’)cadmium(II)], C13H15CdN5Cl2
  27. The crystal structure of (4-hydroxybenzenesulfonate)-k1O-6,6′-((1E,1′E)- (ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene)) bis(2-methoxyphenol)-κ2N,N,μ2O,O,κ2O, O)-(methanol)-cobalt(II) sodium(I), C25H27CoN2NaO9S
  28. Crystal structure of (1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl)(4-((2-methyl-6-(trifluoromethyl)pyrimidin-4-yl)amino)piperidin-1-yl)methanone, C17H18F6N6O
  29. Crystal structure of bis{[(cyclohexylimino)(phenylimino)-l5-(methyl)diethylazane-κ2N:N′]-(ethyl)-zinc(II)]}, C38H62N6Zn2
  30. Crystal structure of 2-[(4-bromobenzyl)thio]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C13H8Br2N2OS2
  31. Crystal structure of 10-methoxy-7,11b,12,13-tetrahydro-6H-pyrazino [2′,3′:5,6]pyrazino[2,1-a]isoquinoline, C15H16N4O
  32. The crystal structure of 1-propyl-2-nitro-imidazole oxide, C6H9N3O3
  33. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid–2-ethoxybenzamide (1/1), C17H16N2O8
  34. The structure of RUB-1, (C8H16N)6[B6Si48O108], a boron containing levyne-type zeolite, occluding N-methyl-quinuclidinium in the cage-like pores
  35. The crystal structure of diaqua-(naphthalene-4,5-dicarboxylate-1,8-dicarboxylic anhydride-κ1O)-(4′-(4-(1H-benzimidazolyl-1-yl)phenyl)-2,2′:6′,2″-terpyridine-κ3N,N′,N″)–manganese(II) dihydrate, C42H27MnN5O9·2H2O
  36. Crystal structure of 6,6′-((1E,1′E)-hydrazine-1,2-diylidenebis(methanylylidene))bis (3-(3-bromopropoxy)phenol), C20H22Br2N2O4
  37. The crystal structure of 3-(2-hydroxyphenyl)-4-phenyl-6-(p-tolyl)-2H-pyran-2-one, C24H18O3
  38. Crystal structure of bis(μ2-2-(1,5-dimethyl–3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)-(nitrato-κ2O,O′)dicobalt(II), C36H32Co2N8O4
  39. Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α] phenanthren-3-one O-(4-fluorobenzoyl) oxime, C28H36FNO2
  40. The crystal structure of 4-aminiumbiphenyl benzenesulfonate, C18H17NO3S
  41. Synthesis and crystal structure of 1-(7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)-N,N-dimethylmethanaminiumnitrate, C18H17N3O9
  42. Crystal structure of N-(Ar)-N′-(Ar′)-formamidine, C14H12Br2N2O
  43. The crystal structure of 4-(2,4-dichlorophenyl)-2-(4-fluorophenyl)-5-methyl-1H-imidazole, C16H11Cl2FN2
  44. Crystal structure of 1-(4–chlorophenyl)-4-benzoyl-3-methyl-1H-pyrazol-5-ol, C17H13ClN2O2
  45. The crystal structure of 5-amino-1-methyl-4-nitroimidazole, C4H6O2N4
  46. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene-N,N′-bis(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-1,3,2-diazaborol-2-yl)-l2-germenediamine, C63H94B2GeN8
  47. The crystal structure of (bromido, chlorido)-tricarbonyl-(5,5′-dimethyl-2,2′-bipyridine)-rhenium(I), C15H12Br0.2Cl0.8N2O3Re1
  48. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-bis(propan-2-yl)-1H-pyrazol-4-amine, C26H36N6
  49. The crystal structure of poly[2-(4-carboxypyridin-3-yl)terephthalpoly[diaqua-(μ4-2-(6-carboxylatopyridin-3-yl)terephthalato-κ5O,N:O′:O″,O‴)]) cadmium(II)] dihydrate, C28H20Cd3N2O16
  50. Crystal structure of [tetraaqua-bis((3-carboxy-5-(pyridin-4-yl)benzoate-κ1N)cobalt(II)] tetrahydrate, C26H32CoN2O16
  51. Crystal structure of bis(μ2-azido-κ2N:N)-tetrakis(azido-κ1N)-tetrakis(1,10-phenanthroline-κ2N,N′)dibismuth(III), C48H32N26Bi2
  52. Crystal structure of (Z)-N-(4-(4-(4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenoxy)butoxy)phenyl)acetamide, C30H31NO8
  53. Crystal structure of poly[diaqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)-bis(μ2-5-carboxybenzene-1,3-dicarboxylato-O,O′:O″)-aqua-di-zinc dihydrate solvate], C27H28N4O16Zn2
  54. Crystal structure of 2-(3,5,5-trimethylcyclohex-2-en-1-ylidene)malononitrile, C12H14N2
  55. Crystal structure of chlorido-(5-nitro-2-phenylpyridine-κ2N,C)-[(methylsulfinyl)methane-κ1S]platinum(II), C13H13ClN2O3PtS
  56. The crystal structure of the co-crystal 1,4-dioxane–4,6-bis(nitroimino)-1,3,5-triazinan-2-one(2/1), C11H19N7O9
  57. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-dimethyl-1H-pyrazol-4-amine di-methanol solvate, C18H20N6·2(CH3OH)
  58. Crystal structure of catena-poly[bis(μ2-azido-k2N:N′)-(nitrato-K2N:N′)-bis(1,10-phenanthroline-K2N:N′)samarium(III)], C24H16N11O3Sm
  59. Crystal structure of (Z)-2-(4-((5-bromopentyl)oxy)benzylidene)-4,5,6-trimethoxybenzofuran-3(2H)-one, C23H25BrO6
  60. Crystal structure of bis(3,5-dimethyl-1H-pyrazol-4-ammonium) tetrafluoroterephthate, 2[C5H10N3][C8F4O4]
  61. Crystal structure of 2-amino-4-(2-fluoro-4-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  62. Crystal structure of 6-(pyridin-3-yl)-1,3,5-triazine-2,4-diamine-sebacic acid (2/1), C13H17N6O2
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 20.12.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2023-0163/html
Scroll to top button