Home Physical Sciences Crystal structure of poly[diaqua-(bis(μ2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′] cobalt(II)-tetraqua-bis(1,4-bis(imidazol-1-ylmethyl)benzene)-κ1N)-cobalt(II) di(2,5-thiophenedicarboxylate) dihydrate, C68H76Co2N16O16S2
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Crystal structure of poly[diaqua-(bis(μ2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′] cobalt(II)-tetraqua-bis(1,4-bis(imidazol-1-ylmethyl)benzene)-κ1N)-cobalt(II) di(2,5-thiophenedicarboxylate) dihydrate, C68H76Co2N16O16S2

  • Jie Chen and Yang Liu ORCID logo EMAIL logo
Published/Copyright: August 22, 2023
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 238 Issue 5

Abstract

C68H76Co2N16O16S2, monoclinic, P21/c (no. 14), a = 14.097(10) Å, b = 19.208(15) Å, c = 18.998(10) Å, β = 130.71(3)°, V = 3899(5) Å3, Z = 4, Rgt(F) = 0.0361, wRref(F2) = 0.0850, T = 296.15 K.

CCDC no.: 2265323

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Reddish violet block
Size: 0.20 × 0.20 × 0.20 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.55 mm−1
Diffractometer, scan mode: φ and ω
θmax, completeness: 26.9°, >99 %
N(hkl)measured, N(hkl)unique, Rint: 22011, 8323, 0.025
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 6057
N(param)refined: 472
Programs: Bruker [1], Olex2 [2], SHELX [3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
Co2 0.0000 0.0000 0.5000 0.03791 (10)
N5 0.05048 (15) −0.00903 (9) 0.41253 (11) 0.0462 (4)
N6 0.14780 (16) 0.01207 (10) 0.35715 (12) 0.0527 (4)
N7 −0.19495 (14) −0.01773 (9) 0.37666 (11) 0.0443 (4)
N8 −0.38855 (14) 0.00622 (9) 0.24304 (10) 0.0428 (4)
O6 0.01433 (13) −0.11187 (7) 0.52386 (10) 0.0567 (4)
C21 −0.26643 (17) 0.02737 (11) 0.30597 (13) 0.0453 (5)
H21 −0.2364 0.0682 0.3004 0.054*
C22 −0.39644 (19) −0.05643 (11) 0.27472 (14) 0.0538 (5)
H22 −0.4678 −0.0835 0.2465 0.065*
C23 −0.27784 (18) −0.07089 (11) 0.35629 (14) 0.0542 (5)
H23 −0.2558 −0.1102 0.3927 0.065*
C24 0.11995 (19) 0.03631 (12) 0.40912 (15) 0.0533 (5)
H24 0.1460 0.0793 0.4388 0.064*
C25 0.0329 (2) −0.06505 (13) 0.35879 (15) 0.0590 (6)
H25 −0.0125 −0.1050 0.3476 0.071*
C26 0.0921 (2) −0.05293 (14) 0.32462 (16) 0.0638 (6)
H26 0.0944 −0.0825 0.2870 0.077*
C27 0.2367 (2) 0.04475 (14) 0.34903 (17) 0.0679 (7)
H27A 0.2321 0.0950 0.3512 0.081*
H27B 0.2120 0.0325 0.2895 0.081*
C28 0.3729 (2) 0.02097 (12) 0.42744 (16) 0.0539 (5)
C29 0.4436 (2) −0.00736 (14) 0.40689 (17) 0.0673 (7)
H29 0.4077 −0.0127 0.3453 0.081*
C30 0.4312 (2) 0.02793 (16) 0.52158 (18) 0.0754 (7)
H30 0.3861 0.0466 0.5371 0.090*
C31 −0.49140 (19) 0.04227 (12) 0.15380 (13) 0.0530 (5)
H31A −0.4790 0.0922 0.1626 0.064*
H31B −0.5711 0.0315 0.1372 0.064*
C32 −0.49528 (17) 0.02020 (11) 0.07420 (13) 0.0445 (5)
C33 −0.53145 (19) −0.04802 (12) 0.03745 (14) 0.0522 (5)
H33 −0.5521 −0.0802 0.0622 0.063*
C34 −0.46361 (19) 0.06759 (12) 0.03624 (14) 0.0517 (5)
H34 −0.4390 0.1125 0.0601 0.062*
Co1 0.0000 0.0000 1.0000 0.03560 (10)
O4 −0.02586 (11) −0.09123 (7) 0.92218 (10) 0.0523 (4)
O5 0.17879 (11) −0.03756 (7) 1.12220 (9) 0.0464 (3)
N1 −0.13990 (16) −0.13501 (10) 1.09779 (13) 0.0619 (5)
N2 −0.08703 (14) −0.05178 (9) 1.04604 (12) 0.0485 (4)
N3 −0.76241 (19) −0.26046 (10) 0.80362 (13) 0.0622 (5)
N4 −0.8839 (2) −0.17877 (13) 0.69373 (15) 0.0788 (6)
C7 −0.07604 (19) −0.11928 (11) 1.06838 (16) 0.0563 (6)
H7 −0.0305 −0.1515 1.0644 0.068*
C8 −0.1957 (2) −0.07355 (14) 1.09319 (17) 0.0654 (6)
H8 −0.2461 −0.0677 1.1084 0.079*
C9 −0.16225 (19) −0.02318 (12) 1.06198 (16) 0.0566 (6)
H9 −0.1862 0.0233 1.0528 0.068*
C10 −0.1514 (2) −0.20491 (14) 1.1253 (2) 0.0822 (9)
H10A −0.1281 −0.2017 1.1858 0.099*
H10B −0.0936 −0.2367 1.1305 0.099*
C11 −0.2856 (2) −0.23446 (12) 1.05471 (17) 0.0620 (6)
C12 −0.3491 (3) −0.23937 (19) 0.9592 (2) 0.0999 (11)
H12 −0.3090 −0.2250 0.9376 0.120*
C13 −0.4710 (3) −0.26537 (19) 0.8961 (2) 0.0959 (10)
H13 −0.5114 −0.2667 0.8332 0.115*
C14 −0.5334 (2) −0.28936 (12) 0.92560 (16) 0.0589 (6)
C15 −0.4700 (2) −0.28530 (15) 1.02004 (17) 0.0708 (7)
H15 −0.5095 −0.3009 1.0416 0.085*
C16 −0.3483 (2) −0.25827 (14) 1.08373 (18) 0.0697 (7)
H16 −0.3090 −0.2563 1.1464 0.084*
C17 −0.6683 (2) −0.31745 (14) 0.85566 (18) 0.0739 (7)
H17A −0.6751 −0.3480 0.8119 0.089*
H17B −0.6864 −0.3447 0.8887 0.089*
C18 −0.8061 (3) −0.21798 (16) 0.83548 (18) 0.0765 (7)
H18 −0.7892 −0.2220 0.8915 0.092*
C19 −0.8119 (3) −0.23441 (16) 0.71822 (18) 0.0732 (7)
H19 −0.7966 −0.2536 0.6815 0.088*
C20 −0.8801 (3) −0.16843 (16) 0.7677 (2) 0.0820 (8)
H20 −0.9217 −0.1329 0.7712 0.098*
S2 0.51070 (4) −0.24188 (2) 1.19662 (3) 0.03975 (12)
O7 0.14917 (13) −0.19548 (8) 1.00170 (13) 0.0815 (6)
O1 0.31589 (13) −0.12913 (7) 1.10923 (12) 0.0664 (5)
O2 0.66464 (13) −0.42996 (8) 1.28450 (11) 0.0626 (4)
O3 0.75653 (13) −0.32444 (8) 1.31999 (13) 0.0775 (5)
C1 0.66250 (17) −0.36465 (11) 1.27611 (13) 0.0438 (5)
C2 0.53242 (16) −0.33189 (9) 1.20577 (12) 0.0369 (4)
C3 0.41939 (17) −0.36676 (10) 1.14260 (14) 0.0447 (5)
H3 0.4126 −0.4150 1.1371 0.054*
C4 0.31408 (17) −0.32041 (10) 1.08661 (14) 0.0449 (5)
H4 0.2320 −0.3354 1.0410 0.054*
C5 0.34809 (16) −0.25083 (9) 1.10798 (12) 0.0366 (4)
C6 0.26478 (17) −0.18674 (10) 1.07019 (14) 0.0429 (4)
O8 −0.06359 (17) −0.21656 (9) 0.39331 (15) 0.0946 (7)
H5A 0.2275 −0.0025 1.1543 0.142*
H5B 0.2273 −0.0665 1.1196 0.142*
H4A −0.0951 −0.1178 0.8888 0.142*
H4B 0.0290 −0.1248 0.9439 0.142*
H6A 0.0473 −0.1365 0.5817 0.142*
H6B −0.0202 −0.1484 0.4810 0.142*
H8A −0.1342 −0.2482 0.3617 0.142*
H8B 0.0100 −0.2435 0.4305 0.142*

1 Source of material

Thiophenedicarboxylic acid (H2tdc) (0.173 g, 1 mmol), 1,4-bis(imidazol-1-ylmethyl)benzene (bix) (0.22 g, 1 mmol) and CoCl2·6H2O (0.238 g, 1 mmol) were dissolved in deionized water (10 mL). The mixture was stirred rigorously and heated for 1 h. Then, the reaction solution was filtered. Subsequently, the clean solution was set aside to allow it slow evaporation at room temperature. Purple block crystals were obtained about ten days later.

2 Experimental details

2.1 Comment

The 2,5-thiophenedicarboxylic acid (H2tdc) is an efficient ligand in construction of functional coordination compounds due to its rigid skeleton and plentiful coordination modes, particularly in combination with the N-containing neutral heterocycle molecules [4], [5], [6], [7]. Herein, a new Co(II) complex from H2tdc and 1,4-bis(imidazol-1-ylmethyl)benzene was successfully prepared by slow evaporation under ambient conditions.

The asymmetric unit contains two Co(II) ions, one fully deprotonated tdc2− anion, two bix ligands (1,4-bis(imidazol-1-ylmethyl)benzene) and three water molecules. Both Co(II) ions are six-coordinated, but they have different coordination environments. Co1 is ligated to four O atoms from water molecules and two N atoms from terminal bix molecules. While Co2 is surrounded by four N atoms from four bridging bix molecules and two O atoms from two water molecules. Thus, Co2 can be linked together by the bridging bix molecules, resulting into 2D networks. The uncoordinated tdc2− anion exists as counterions against the cation frameworks and have H-bonding interactions with the water molecules bonded to Co1, giving the distances of O5–H5B⋯O1, O6–H6B⋯O2, O6–H6A⋯O3 and O5–H5A⋯O4 with 1.87, 1.84, 1.82 and 1.94 Å, respectively. The Co1 entity is anchored in the pores of the Co2 2D networks, stabilized by the H-bonding interaction of O7–H7A⋯N4 with a distance of 1.85 Å. Bond lengths and angles are all in the expected ranges [8, 9].

Corresponding author: Yang Liu, Key Laboratory of Functional Organometallic Materials, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang City, Hunan Province, People’s Republic of China, E-mail:

Funding source: the Foundation of Key Laboratory of Functional Metal-Organic Compounds of Hunan Province 2022HSKFJJ027

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work has been funded by the Foundation of Key Laboratory of Functional Metal-Organic Compounds, University of Hunan Province (2022HSKFJJ027).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2023-05-28
Accepted: 2023-07-19
Published Online: 2023-08-22
Published in Print: 2023-10-26

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  54. Crystal structure of 2-(3,5,5-trimethylcyclohex-2-en-1-ylidene)malononitrile, C12H14N2
  55. Crystal structure of chlorido-(5-nitro-2-phenylpyridine-κ2N,C)-[(methylsulfinyl)methane-κ1S]platinum(II), C13H13ClN2O3PtS
  56. The crystal structure of the co-crystal 1,4-dioxane–4,6-bis(nitroimino)-1,3,5-triazinan-2-one(2/1), C11H19N7O9
  57. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-dimethyl-1H-pyrazol-4-amine di-methanol solvate, C18H20N6·2(CH3OH)
  58. Crystal structure of catena-poly[bis(μ2-azido-k2N:N′)-(nitrato-K2N:N′)-bis(1,10-phenanthroline-K2N:N′)samarium(III)], C24H16N11O3Sm
  59. Crystal structure of (Z)-2-(4-((5-bromopentyl)oxy)benzylidene)-4,5,6-trimethoxybenzofuran-3(2H)-one, C23H25BrO6
  60. Crystal structure of bis(3,5-dimethyl-1H-pyrazol-4-ammonium) tetrafluoroterephthate, 2[C5H10N3][C8F4O4]
  61. Crystal structure of 2-amino-4-(2-fluoro-4-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  62. Crystal structure of 6-(pyridin-3-yl)-1,3,5-triazine-2,4-diamine-sebacic acid (2/1), C13H17N6O2
https://doi.org/10.1515/ncrs-2023-0258
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of (N-([1,1′:4′,1″-terphenyl]-4,4′-diethyl)-2-(bis(pyridin-2-ylmethyl)amino)acetamide-κ4N,N,N″, O)tri(nitrato-kO, O′) samarium(III) - methanol - acetonitrile (1/1/1), C40H39SmN8O14
  4. The crystal structure of 6,6′-(((2-(dimethylamino)ethyl)azanediyl)bis(methylene))bis(2-chloro-4-methyl phenolate-κ4N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV), C27H27Cl2N3O6Ti
  5. N′-[(1E)-(4–Fluorophenyl)methylidene]adamantane-1-carbohydrazide, C18H21FN2O
  6. Crystal structure of 4-bromo-3-nitro-1H-pyrazole-5-carboxylic acid monohydrate, C4H2N3BrO4·H2O
  7. Crystal structure of dipyridine-k1N-tris(2,2,6,6-tetramethyl-5-oxohept-3-en-3-olato-k2O,O′)dysprosium(III), DyC43H67O6N2
  8. Crystal structure of cyclo[tetraiodido-bis{μ2-1-[(benzotriazol-1-yl)methyl]-1-H-1,3-(2-isopropyl-imidazol)-k2N:N}dicadmiun(II)], C26H30N10Cd2I4
  9. The crystal structure of tert-butyl (E)-3-(2-(benzylideneamino)phenyl)-1H-indole-1-carboxylate, C26H24N2O2
  10. The crystal structure of 4-(3-carboxy-1-cyclopropyl-6-fluoro-8-methoxy-4-oxo-1,4- dihydroquinolin-7-yl)-2-methylpiperazin-1-ium 2,5-dihydroxybenzoate methanol solvate, C27H32FN3O9
  11. Crystal structure of (μ2-1-(4,4′-bipyridine-κ2N:N′)-bis[diaqua-(4-iodopyridine-2,6-dicarboxylato-κ3O,N,O′)–cobalt(II)], C24H20Co2I2N4O12
  12. The crystal structure of dimethyl 4,4′-(10,20-diphenylporphyrin-5,15-diyl)dibenzoate dichloromethane solvate, C49H36N4O4Cl2
  13. (E)-2-((E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-ylidene)hydrazine-1-carbothioamide C14H23N3S1
  14. The crystal structure of [1-(4-(trifluoromethyl)phenyl)-3,4-dihydroquinolin-2(1H)-one], C16H12F3NO
  15. Crystal structure of (E)-2-amino-N′-((3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene)benzohydrazide – dimethylformamide – water (1/1/2), C15H16N4O3·C3H7NO·2H2O
  16. Crystal structure of 3-(4-bromophenyl)-5-methyl-1H-pyrazole, C10H9BrN2
  17. Crystal structure of 1,10-phenanthrolinium bromide dihydrate, C12H9N2Br
  18. Crystal structure of N-(4′-chloro-[1,1′-biphenyl]-2-yl)formamide, C13H10ClNO
  19. The crystal structure of nitroterephthalic acid, C8H5NO6
  20. Crystal structure of (2-((4-bromo-2,6-dichlorophenyl)amino)phenyl) (morpholino)methanone, C17H15BrCl2N2O2
  21. Crystal structure of tetraaqua-bis(ethanol-κO)-tetrakis(μ2-trifluoroacetate-κ2O:O′)-bis(trifluoroacetate-κ2O)digadolinium(III) Gd2C16H20O18F18
  22. The crystal structure of dimethyl 4,4′-[10,20-bis(2,6-difluorophenyl)porphyrin-5,15-diyl]dibenzoate chloroform solvate, C50H32Cl6F4N4O4
  23. The crystal structure of N,N′-((nitroazanediyl)bis(methylene))diacetamide, C6H12O4N4
  24. The crystal structure of [bis(2,2′-bipyridine-6-carboxylato-κ3N,N,O)magnesium(II)]dihydrate, C22H18N4O6Mg
  25. Crystal structure of poly[diaqua-(bis(μ2-1,4-bis(imidazol-1-ylmethyl)benzene)-κ2N,N′] cobalt(II)-tetraqua-bis(1,4-bis(imidazol-1-ylmethyl)benzene)-κ1N)-cobalt(II) di(2,5-thiophenedicarboxylate) dihydrate, C68H76Co2N16O16S2
  26. Crystal structure of poly[chlorido-μ2-chlorido-(μ2-1-[(2-ethyl-4-methyl-1H-imidazol-1-yl)methyl]-1H-benzotriazole-κN:N’)cadmium(II)], C13H15CdN5Cl2
  27. The crystal structure of (4-hydroxybenzenesulfonate)-k1O-6,6′-((1E,1′E)- (ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene)) bis(2-methoxyphenol)-κ2N,N,μ2O,O,κ2O, O)-(methanol)-cobalt(II) sodium(I), C25H27CoN2NaO9S
  28. Crystal structure of (1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl)(4-((2-methyl-6-(trifluoromethyl)pyrimidin-4-yl)amino)piperidin-1-yl)methanone, C17H18F6N6O
  29. Crystal structure of bis{[(cyclohexylimino)(phenylimino)-l5-(methyl)diethylazane-κ2N:N′]-(ethyl)-zinc(II)]}, C38H62N6Zn2
  30. Crystal structure of 2-[(4-bromobenzyl)thio]-5-(5-bromothiophen-2-yl)-1,3,4-oxadiazole, C13H8Br2N2OS2
  31. Crystal structure of 10-methoxy-7,11b,12,13-tetrahydro-6H-pyrazino [2′,3′:5,6]pyrazino[2,1-a]isoquinoline, C15H16N4O
  32. The crystal structure of 1-propyl-2-nitro-imidazole oxide, C6H9N3O3
  33. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid–2-ethoxybenzamide (1/1), C17H16N2O8
  34. The structure of RUB-1, (C8H16N)6[B6Si48O108], a boron containing levyne-type zeolite, occluding N-methyl-quinuclidinium in the cage-like pores
  35. The crystal structure of diaqua-(naphthalene-4,5-dicarboxylate-1,8-dicarboxylic anhydride-κ1O)-(4′-(4-(1H-benzimidazolyl-1-yl)phenyl)-2,2′:6′,2″-terpyridine-κ3N,N′,N″)–manganese(II) dihydrate, C42H27MnN5O9·2H2O
  36. Crystal structure of 6,6′-((1E,1′E)-hydrazine-1,2-diylidenebis(methanylylidene))bis (3-(3-bromopropoxy)phenol), C20H22Br2N2O4
  37. The crystal structure of 3-(2-hydroxyphenyl)-4-phenyl-6-(p-tolyl)-2H-pyran-2-one, C24H18O3
  38. Crystal structure of bis(μ2-2-(1,5-dimethyl–3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)-(nitrato-κ2O,O′)dicobalt(II), C36H32Co2N8O4
  39. Synthesis and crystal structure of (3E,5S,10S,13S,14S,17Z)-17-ethylidene-10,13-dimethylhexadecahydro-3H-cyclopenta[α] phenanthren-3-one O-(4-fluorobenzoyl) oxime, C28H36FNO2
  40. The crystal structure of 4-aminiumbiphenyl benzenesulfonate, C18H17NO3S
  41. Synthesis and crystal structure of 1-(7-hydroxy-3-(4-hydroxy-3-nitrophenyl)-4-oxo-4H-chromen-8-yl)-N,N-dimethylmethanaminiumnitrate, C18H17N3O9
  42. Crystal structure of N-(Ar)-N′-(Ar′)-formamidine, C14H12Br2N2O
  43. The crystal structure of 4-(2,4-dichlorophenyl)-2-(4-fluorophenyl)-5-methyl-1H-imidazole, C16H11Cl2FN2
  44. Crystal structure of 1-(4–chlorophenyl)-4-benzoyl-3-methyl-1H-pyrazol-5-ol, C17H13ClN2O2
  45. The crystal structure of 5-amino-1-methyl-4-nitroimidazole, C4H6O2N4
  46. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene-N,N′-bis(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-1,3,2-diazaborol-2-yl)-l2-germenediamine, C63H94B2GeN8
  47. The crystal structure of (bromido, chlorido)-tricarbonyl-(5,5′-dimethyl-2,2′-bipyridine)-rhenium(I), C15H12Br0.2Cl0.8N2O3Re1
  48. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-bis(propan-2-yl)-1H-pyrazol-4-amine, C26H36N6
  49. The crystal structure of poly[2-(4-carboxypyridin-3-yl)terephthalpoly[diaqua-(μ4-2-(6-carboxylatopyridin-3-yl)terephthalato-κ5O,N:O′:O″,O‴)]) cadmium(II)] dihydrate, C28H20Cd3N2O16
  50. Crystal structure of [tetraaqua-bis((3-carboxy-5-(pyridin-4-yl)benzoate-κ1N)cobalt(II)] tetrahydrate, C26H32CoN2O16
  51. Crystal structure of bis(μ2-azido-κ2N:N)-tetrakis(azido-κ1N)-tetrakis(1,10-phenanthroline-κ2N,N′)dibismuth(III), C48H32N26Bi2
  52. Crystal structure of (Z)-N-(4-(4-(4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenoxy)butoxy)phenyl)acetamide, C30H31NO8
  53. Crystal structure of poly[diaqua-(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)-bis(μ2-5-carboxybenzene-1,3-dicarboxylato-O,O′:O″)-aqua-di-zinc dihydrate solvate], C27H28N4O16Zn2
  54. Crystal structure of 2-(3,5,5-trimethylcyclohex-2-en-1-ylidene)malononitrile, C12H14N2
  55. Crystal structure of chlorido-(5-nitro-2-phenylpyridine-κ2N,C)-[(methylsulfinyl)methane-κ1S]platinum(II), C13H13ClN2O3PtS
  56. The crystal structure of the co-crystal 1,4-dioxane–4,6-bis(nitroimino)-1,3,5-triazinan-2-one(2/1), C11H19N7O9
  57. Crystal structure of [N(E),N′(E)]-N,N′-(1,4-phenylenedimethylidyne)bis-3,5-dimethyl-1H-pyrazol-4-amine di-methanol solvate, C18H20N6·2(CH3OH)
  58. Crystal structure of catena-poly[bis(μ2-azido-k2N:N′)-(nitrato-K2N:N′)-bis(1,10-phenanthroline-K2N:N′)samarium(III)], C24H16N11O3Sm
  59. Crystal structure of (Z)-2-(4-((5-bromopentyl)oxy)benzylidene)-4,5,6-trimethoxybenzofuran-3(2H)-one, C23H25BrO6
  60. Crystal structure of bis(3,5-dimethyl-1H-pyrazol-4-ammonium) tetrafluoroterephthate, 2[C5H10N3][C8F4O4]
  61. Crystal structure of 2-amino-4-(2-fluoro-4-(trifluoromethyl)phenyl)-9-methoxy-1,4,5,6-tetrahydrobenzo[h]quinazolin-3-ium chloride, C20H18ClF4N3O
  62. Crystal structure of 6-(pyridin-3-yl)-1,3,5-triazine-2,4-diamine-sebacic acid (2/1), C13H17N6O2
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