Home Crystal structure of poly[aqua-(2,2′-bipyridine-κN,N′)-(μ4-5,5′-(hexane-1,6-diyl)-bis(oxy)diisophthalato κ8O1,O2:O3,O4:O5,O6:O7,O8)manganese(II)], C21H21MnN2O7
Article Open Access

Crystal structure of poly[aqua-(2,2′-bipyridine-κN,N′)-(μ4-5,5′-(hexane-1,6-diyl)-bis(oxy)diisophthalato κ8O1,O2:O3,O4:O5,O6:O7,O8)manganese(II)], C21H21MnN2O7

  • Lu Liu EMAIL logo , Jin Zhang , Huiling Gao and Shaoxin Deng
Published/Copyright: March 13, 2017
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 232 Issue 3

Abstract

C21H21MnN2O7, triclinic, P1̅, a = 8.6230(17) Å, b = 9.967(2) Å, c = 13.257(3) Å, α = 80.92(3)°, β = 78.53(3)°, γ = 84.75(3)°, V = 1100.5(4) Å3, Z = 2, Rgt(F) = 0.0555, wRref(F2) = 0.1474, T = 293(2) K.

CCDC no.:: 1532295

A part of the title crystal structure is shown in the figure. The asymmetric unit is labeled. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1

Data collection and handling.

Crystal:Colourless irregular-shaped
Size:0.22 × 0.19 × 0.17 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:6.4 cm−1
Diffractometer, scan mode:Rigaku Saturn 724, φ and ω
2θmax, completeness:50°, >99%
N(hkl)measured, N(hkl)unique, Rint:11218, 3866, 0.043
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3284
N(param)refined:280
Programs:SHELX [13], CrystalClear [14]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Mn1−0.03641(6)−0.14986(6)0.81828(4)0.0296(2)
O10.1150(4)0.0067(3)0.7292(2)0.0441(8)
O2−0.0345(3)0.0890(3)0.8626(2)0.0421(7)
O30.1570(4)0.7127(3)0.7393(3)0.0546(9)
O4−0.0561(4)0.6128(3)0.8193(2)0.0472(8)
O50.0545(3)−0.2088(3)0.9609(2)0.0441(7)
H50.0199−0.15381.00100.066*
H5A0.0932−0.28500.98500.066*
O60.5510(3)0.3257(3)0.6254(3)0.0485(8)
O70.1953(5)0.5369(4)0.0013(3)0.0864(13)
H7B0.15780.48430.06370.130*
H7A0.26070.5122−0.02240.130*
N1−0.2868(4)−0.1574(4)0.9094(3)0.0371(8)
N2−0.2038(4)−0.1227(3)0.7037(3)0.0362(8)
C1−0.1537(6)−0.1055(5)0.6004(3)0.0493(12)
H1−0.0481−0.08810.57410.059*
C2−0.2519(7)−0.1125(5)0.5317(4)0.0581(13)
H2−0.2139−0.09830.46040.070*
C3−0.4074(6)−0.1409(5)0.5704(4)0.0556(13)
H3−0.4756−0.14800.52550.067*
C4−0.4608(6)−0.1587(5)0.6760(3)0.0473(11)
H4−0.5656−0.17790.70340.057*
C5−0.3569(5)−0.1477(4)0.7416(3)0.0345(9)
C6−0.4030(5)−0.1623(4)0.8565(3)0.0391(10)
C7−0.5582(6)−0.1750(7)0.9064(4)0.0712(17)
H7−0.6376−0.17690.86850.085*
C8−0.5945(6)−0.1849(8)1.0138(4)0.081(2)
H8−0.6985−0.19411.04880.098*
C9−0.4753(6)−0.1809(7)1.0678(4)0.0661(16)
H9−0.4966−0.18701.13990.079*
C10−0.3246(5)−0.1676(5)1.0129(3)0.0510(12)
H10−0.2437−0.16561.04970.061*
C110.0734(4)0.1011(4)0.7832(3)0.0303(8)
C120.1582(4)0.2307(4)0.7514(3)0.0276(8)
C130.0819(5)0.3546(4)0.7751(3)0.0303(8)
H13−0.02290.35810.80990.036*
C140.1632(5)0.4721(4)0.7466(3)0.0311(9)
C150.3209(5)0.4670(4)0.6958(3)0.0333(9)
H150.37510.54630.67690.040*
C160.3967(4)0.3439(4)0.6736(3)0.0324(9)
C170.3136(4)0.2256(4)0.6997(3)0.0297(8)
H170.36310.14330.68230.036*
C180.0830(5)0.6078(4)0.7692(3)0.0370(9)
C190.6468(5)0.4419(5)0.6046(4)0.0453(11)
H19A0.64830.47610.66900.054*
H19B0.60270.51400.55830.054*
C200.8120(5)0.3985(5)0.5552(4)0.0453(11)
H20A0.80870.35840.49360.054*
H20B0.85740.33000.60340.054*
C210.9155(5)0.5191(5)0.5253(4)0.0436(11)
H21A0.91750.55910.58710.052*
H21B0.86890.58740.47750.052*

Source of material

The title compound was prepared under hydrothermal conditions. A mixture of 5,5′-(hexane-1,6-diyl)-bis(oxy)diisophthalic acid (22.1 mg, 0.05 mmol), 2,2′-bipyridine (15.6 mg, 0.1 mmol), manganese(II) actetate tetrahydrate (24.5 mg, 0.1 mmol), sodium hydroxide solution (0.2 mol/L, 0.5 mL) and H2O (10 mL) were placed in a Teflon-lined stainless steel vessel, heated to 130 °C for 3 day, and then cooled to room temperature. Colorless irregular-shaped crystals of the title compound were obtained.

Experimental details

The structure was solved by direct methods and refined with the SHELX crystallographic software package [13]. The hydrogen atoms were placed at calculated positions and refined as riding atoms with isotropic displacement parameters.

Discussion

Metal-organic frameworks (MOFs) with boundless network structures have been a vibrant research field and aroused considerable attention from both academia and industry [1], [2], [3], [4], [5], [6], [7]. Theoretical predictions and network-based methods to regulate the network topology and geometries have been done to generate serviceable functional frameworks [8]. Of the many advisable means to the design of these frameworks, the route of selecting choreographed organic ligands as building blocks with metal ions as nodes has been certified to be an effective strategy. In this paper, we have chosen the tetracarboxylic acids 5,5′-(hexane-1,6-diyl)-bis(oxy)diisophthalic acid (H4L) as an educt. H4L and the corresponding deprotonated anions are expected to be vigoroso precursors for the construction of outstanding structures as they may admit various coordination modes [9]. The flexibility of the (−CH2−)6 spacers and the existence of two methoxy groups will enable the carboxylic/carboxylate groups to coordinate metal ions in different directions [10], [11], [12]. On the other hand, the “mix-ligand” synthetic strategies also has become a research hotspot. By introducing 2,2′-bipy into the Mn(II)/L4− synthesis system, a new Mn(II) coordination polymer has been obtained.

As shown in the figure, the asymmetric unit contains one crystallographically independent Mn atom, one half of a L4− ligand, one 2,2′-bipy ligand and one coordinated water molecule. Mn1 is six-coordinated (MnO4N2), in which Mn1 is equatorially bonded to carboxylic oxygen atoms (O1, O3A, O4A and N1) from two different L4− ligands (Mn1—O1 = 2.171(3), Mn1—O3A = 2.257(3), Mn1—O4A = 2.385(3), Mn1—N1 = 2.256(3) Å) and one 2,2′-bipy ligand. The two axial sites are occupied by one N atom from one 2,2′-bipy ligand (Mn1—N2 = 2.265(3) Å) and one carboxyl O from one coordinated water molecule (Mn1—O5 = 2.165(3) Å). The bond angles around Mn range from 55.72(11) to 160.43(12)°. In this structure, the L4− anions connects four manganese(II) metal nodes in a κ8O1,O2:O3,O4:O5,O6:O7,O8-mode. The Mn1 ion and symmetry-related Mn1 metal centers show intermetallic distance of about 9.97 and 18.48 Å. The connection constructs a 1D stair-like structure (cf. the figure). Noticeably, the 2,2′-bipy ligand do not play an indispensable role in the construction of final 1D architecture.

Acknowledgement

This work was financially supported by the research start-up fund of Henan Institute of Science and Technology, the key scientific research project funding scheme of colleges and universities of henan province (16A150007).

References

1 Zheng, A. X.; Si, J.; Tang, X. Y.; Miao, L. L.; Yu, M.; Hou, K. P.; Wang, F.; Li, H. X.; Lang, J. P.: Reactions of the cationic zinc thiolate model complex [Zn(Tab)4](PF6)2 with N-donor ligands and cobalt dichloride. Inorg. Chem. 51 (2012) 10262–10273.10.1021/ic301191nSearch in Google Scholar

2 Jiang, H. L.; Feng, D. W.; Liu, T. F.; Li, J. R.; Zhou, H. C.: Pore surface engineering with controlled loadings of functional groups via click chemistry in highly stable metal–organic frameworks. J. Am. Chem. Soc. 134 (2012) 14690–14693.10.1021/ja3063919Search in Google Scholar

3 Wu, H. H.; Gong, Q. H.; Olson, D. H.; Li, J.: Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks. Chem. Rev. 112 (2012) 836–868.10.1021/cr200216xSearch in Google Scholar

4 Long, J. R.; Yaghi, O. M.: The pervasive chemistry of metal–organic frameworks. Chem. Soc. Rev. 38 (2009) 1213–1214.10.1039/b903811fSearch in Google Scholar

5 Della Rocca, J.; Liu, D.; Lin, W.: Nanoscale metal–organic frameworks for biomedical imaging and drug delivery. Acc. Chem. Res. 44 (2011) 957–968.10.1021/ar200028aSearch in Google Scholar

6 Dang, D.; Wu, P.; He, C.; Xie, Z.; Duan, C.: Homochiral metal-organic frameworks for heterogeneous asymmetric catalysis. J. Am. Chem. Soc. 132 (2010) 14321–14323.10.1021/ja101208sSearch in Google Scholar

7 Zhang, C. L.; Zhang, M. D.; Qin, L.; Zheng, H. G.: Crystal structures and spectroscopic properties of metal–organic frameworks based on rigid ligands with flexible functional groups. Cryst. Growth Des. 14 (2014) 491–499.10.1021/cg401149hSearch in Google Scholar

8 Dong, Y. B.; Smith, M. D.; Zur Loye, H. C.: [Cu(2-pyrazinecarboxylato)2HgI2]⋅HgI2: An open noninterpenetrating CuII–HgII mixed-metal cuboidal framework encapsulating nearly linear HgI2 guest molecules. Angew. Chem. Int. Ed. 112 (2000) 4441–4443.10.1002/1521-3757(20001201)112:23<4441::AID-ANGE4441>3.0.CO;2-BSearch in Google Scholar

9 Karmakar, A.; Goldberg, I.: Coordination polymers of flexible tetracarboxylic acids with metal ions. I. Synthesis of CH2− and (CH2)2-spaced bis(oxy)isophthalic acid ligands, and structural characterization of their polymeric adducts with lanthanoid ions. CrystEngComm 13 (2011) 339–349.10.1039/C0CE00474JSearch in Google Scholar

10 Kan, W. Q.; Ma, J. F.; Liu, B.; Yang, J.: A series of coordination polymers based on 5,5′-(ethane-1,2-diyl)-bis(oxy)diisophthalic acid and structurally related N-donor ligands: syntheses, structures and properties. CrystEngComm 14 (2012) 286–299.10.1039/C1CE05877KSearch in Google Scholar

11 Wenge, Q.; Jason, A. P.; Qukasz, W.; Mohamed, E.; Michael, J. Z.: Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”. Chem. Commun. 46 (2010) 8734–8736.10.1039/c0cc03270kSearch in Google Scholar

12 Zafar, A.; Yang, J.; Geib, S. J.; Hamilton, A. D.: Linked bis-isophthalic acid derivatives as bulding blocks in the design of self-assembling structures. Tetrahedron Lett. 37 (1996) 2327–2330.10.1016/0040-4039(96)00287-0Search in Google Scholar

13 Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed

14 Rigaku/MSC. CrystalClear. Rigaku/MSC Inc., The Woodlands, Texas, USA, (2006).Search in Google Scholar

Received: 2016-8-4
Accepted: 2017-2-14
Published Online: 2017-3-13
Published in Print: 2017-5-24

©2017 Lu Liu et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of 2,5-diiodo-4-nitro-1H-imidazole hemihydrate, C6H4I4N6O5
  3. Crystal structure of catena-poly[μ2-2,2′-(1,3-phenylene)diacetato-κ4O,O′:O′′,O′′′)-(μ2-1,6-bis(2-methyl-1H-benzo[d]imidazol-1-yl)hexane-κ2N:N′)cadmium(II)], C32H34CdN4O4
  4. Crystal structure of poly[aqua-(2,2′-bipyridine-κN,N′)-(μ4-5,5′-(hexane-1,6-diyl)-bis(oxy)diisophthalato κ8O1,O2:O3,O4:O5,O6:O7,O8)manganese(II)], C21H21MnN2O7
  5. Crystal structure of poly-[(μ2-((1,3-bis(benzimidazol-1-yl)propane-κ2N:N′)(μ2-4-tert-butyl-phthalato-κ2O:O′)cobalt(II)] monohydrate, C29H30CoN4O5
  6. Crystal structure of 2-amino-4-(3,4,5-trimethoxy-phenyl)-5-(oxo-5,6,7,8-tetrahydro-4H-chromene)-3-carbonitrile – ethanol (1/1), C21H26N2O6
  7. Crystal structure of ethyl 1-benzyl-5-phenyl-1H-pyrazole-3-carboxylate, C19H18N2O2
  8. Crystal structure of 2-(1-benzyl-3-phenyl-1H-pyrazol-5-yl)-5-(4-nitrobenzylthio)-1,3,4-oxadiazole, C25H19N5O3S
  9. Structure and photochromism of 1,2-bis[2-methyl-5-(2-chlorophenyl)-3-thienyl]-3,3,4,4,5,5-hexafluorocyclopent-1-ene, C27H16Cl2F6S2
  10. The crystal structure of the Schiff base (E)-2,6-diisopropyl-N-(pyridin-4-ylmethylene)aniline, C18H22N2
  11. Crystal structure of (E)-2,4-dibromo-6-(((4-methyl-2-nitrophenyl)imino) methyl)phenol, C10H14Br2N2O3
  12. Crystal structure of (bis(2,2′-bipyridine-κ2N,N′))-(3,5-dinitrosalicylato-κ2O,O′)nickel(II), C27H18N6NiO7
  13. Crystal structure of 1-(diethoxy phosphonomethyl) 2-benzoyl-3-chloro-2-cyclohexen-1-ol, C18H24ClO5P
  14. Crystal structure of tetraaqua-bis(1,3-benzimidazol-3-ium-1,3-diacetato-κO)copper(II) hemihydrate, C22H27CuN4O12.50
  15. Crystal structure of 1α,11-dihydroxyeremophil-9-en-8-one, C15H24O3
  16. Crystal structure of 1-ferrocenylsulfonyl-1H-imidazo[4,5-b]pyridine, C16H13FeN3O2S
  17. Crystal structure of bis(μ2-azido-κ2N:N)-dichlorido-bis(μ2-2-(pyridin-2-yl)ethan-1-ol-κ2O,N)dicopper(II), C14H18Cl2Cu2N8O2
  18. Crystal structure of (5,15-cis-bis(2-hydroxy-1-naphthyl)-10-phenyl-20-(4-hydroxyphenyl)-porphyrinato)-(pyridine)-zinc(ii) pyridine solvate, C67H47N7O3Zn
  19. Crystal structure of (μ2-[2,2′-bis(diphenylphosphino)-1,1′-binaphthalene oxide-κ2O,P])-iodido copper(I), C44H32CuIOP2
  20. Crystal structure of 6,8-diphenyl-2-(4-fluorophenyl)-2,3-dihydroquinolin-4(3H)-one, C27H20FNO
  21. Crystal structure of 5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetrahexoxycalix[4]arene, C68H104O4
  22. Crystal structure of N,N′–bis(pyridin-4-ylmethyl)pyrazine-2,3-dicarboxamide dihydrate, C18H20N6O4
  23. Crystal structure of a diaqua-bis(3,5-di(1H-imidazol-1-yl)pyridine-κN)-bis(2-(4-carboxy-phenyl)acetato-κO]manganese(II), C40H36MnN10O10
  24. Crystal structure of 4-(4-hydroxy-3-methoxy-phenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylic acid methyl ester, C21H25NO5
  25. Crystal structure of (E)-4,4′-(ethene-1,2-diyl)bis(3-nitrobenzoic acid) 1.5 hydrate, C16H13N2O9.5
  26. Crystal structure of (E)-2-(5-(4-fluorophenyl)-3-(furan-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-5-((4-fluorophenyl)diazenyl)-4-methylthiazole, C23H17F2N5OS
  27. Crystal structure of the co-crystalline adduct 4-((4,4-dimethyl-2,6-dioxocyclohexylidene)methylamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide - acetic acid (1/1), C21H24N4O4S ⋅ C2H4O2
  28. Synthesis and crystal structure of 2-((5-chlorobenzo[c][1,2,5]thiadiazol-4-yl)amino)-4,5-dihydro-1H-imidazol-3-ium tetraphenylborate, C33H29BClN5S
  29. Crystal structure of (4-chlorophenyl)(3-ferrocenyl-5-(trifluoromethyl)-1H-pyrazol-1-yl)methanone, C21H14ClF3FeN2O
  30. Crystal structure of (S)-benzyl 3-(benzylcarba-moyl)-3,4-dihydroisoquinoline-2(1H)-carboxylate, C25H24N2O3
  31. Crystal structure of 5-acetyl-3-(3-fluoro-4-morpholinophenyl)oxazolidin-2-one, C15H17FN2O4
  32. Crystal structure of 2-(4-fluorophenyl)-1,3-dimethyl-1H-perimidin-3-ium iodide, C19H16FIN2
  33. Crystal structure of methyl 1H-indole-2-carboxylate, C10H9NO2
  34. Crystal structure of 2,3-diphenyl-1-[(dipropylamino)acetyl]-1,3-diazaspiro[4.5]decan-4-one, C28H37N3O2
  35. Crystal structure of 1-(2H-1,3-benzodioxol-5-yl)-3-(1H-imidazol-1-yl)propan-1-one, C13H12N2O3
  36. Crystal structure of 2,9-dibromo-1,10-phenanthroline, C12H6Br2N2
  37. Crystal structure of 3-(adamantan-1-yl)-4-(4-fluorophenyl)-1H-1,2,4-triazole-5(4H)-thione, C18H20FN3S
  38. Crystal structure of trans-bis((E)-7-oxo-4-(phenyldiazenyl)cyclohepta-1,3,5-trien-1-olato)-κ2O,O′)-bis(pyridine-κN)cobalt(II), C36H28CoN6O4
  39. Crystal structure of 2-(4-methyl-3-phenylthiazol-2(3H)-ylidene)malononitrile, C13H9N3S
  40. Crystal structure of (Z)-3-(adamantan-1-yl)-1-(3-chlorophenyl)-S-benzylisothiourea, C24H27ClN2S
  41. Crystal structure of chlorido{[3-(η5-cyclopenta-dienyl)-2,2,3-trimethyl-1-phenylbutylidene] azanido-κN}[η2(N,O)-N,N-dimethylhydroxylaminato]titanium(IV), C20H27ClN2OTi
  42. Crystal Structure of 1,1′-dimethyl-[4,4′-bipyridine]-1,1′-diium tetrachloridozincate(II), C12H14Cl4N2Zn
  43. Crystal structure of 5-nitro-2-(pyrrolidin-1-yl)benzaldehyde, C11H12N2O3
  44. Crystal structure of 2,3-diphenyl-1-(morpholin-4-ylacetyl)-1,3-diazaspiro[4.5]decan-4-one, C26H31N3O3
  45. Crystal structure of 3,3-dimethyl-3,4-dihydro-1H-benzo[c]chromene-1,6(2H)-dione, C15H14O3
  46. Crystal structure of bis(2-(2-hydroxymethyl)pyridine-κ2N,O)-bis(pivalato-κO)nickel(II), C22H32N2NiO6
  47. Crystal structure of (1,10-phenanthroline-κ2N,N′)-bis(1H-pyrazole-3-carboxylato-κ2N,O)manganese(II) trihydrate, C20H20N6O7Mn
  48. The crystal structure of 3-aminopropan-1-aminium iodide, C3H11N2I
  49. Crystal structure of ethyl 1-(4-chlorophenyl)-5-methyl-1H-1,2,3-triazole-4 carboxylate, C12H12ClN3O2
  50. Crystal structure of 4,4′-((1Z,1′Z)-2,2′-(2,5-diethoxy-1,4-phenylene)bis(ethene-2,1-diyl))dipyridine, C24H24N2O2
  51. Crystal structure of (16S)-12,16-epoxy-11,14-dihydroxy-17(15/16)-abeo-3a,18-cyclo-8,11,13-abietatrien-7-one, C20H24O4
  52. Crystal structure of aquadichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3N,N′,N′′)nickel(II) monohydrate, C18H16Cl2N6NiO2
  53. Crystal structure of catena-poly[dichlorido-(μ-ethane-1,2-diyl-bis-(pyridyl-4-carboxylate-κN:N′)mercury(II)], C15H14Cl2HgN2O4
  54. Crystal structure of methyl 2-acetamido-5-chlorbenzoate, C10H10ClNO3
  55. Crystal structure of tetrakis(μ2-3,3-dimethylacrylato-κ2O,O′)-bis(2-aminopyrimidine-κN) dicopper(II), C28H38Cu2N6O8
  56. Crystal structure of 3-amino-8-methoxy-1-phenyl-1H-benzo[f]chromene-2-carbonitrile, C21H16N2O2
  57. Crystal structure of 4-(2-ammonioethyl)morpholin-4-ium dichloride monohydrate, C6H18Cl2N2O2
  58. Crystal structure of 1-(3-((5-bromo-2-hydroxybenzylidene)amino)phenyl)ethanone O-benzyl oxime, C22H19BrN2O2
  59. Crystal structure of 2-(4-(dimethylamino)-2-fluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-ol monohydrate, C15H20FN7O2
  60. Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O
  61. Crystal structure of 1,2,3,4,5-pentamethyl-1,3-cyclopentadiene, C10H16
https://doi.org/10.1515/ncrs-2016-0239
Creative Commons
BY-NC-ND 3.0

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of 2,5-diiodo-4-nitro-1H-imidazole hemihydrate, C6H4I4N6O5
  3. Crystal structure of catena-poly[μ2-2,2′-(1,3-phenylene)diacetato-κ4O,O′:O′′,O′′′)-(μ2-1,6-bis(2-methyl-1H-benzo[d]imidazol-1-yl)hexane-κ2N:N′)cadmium(II)], C32H34CdN4O4
  4. Crystal structure of poly[aqua-(2,2′-bipyridine-κN,N′)-(μ4-5,5′-(hexane-1,6-diyl)-bis(oxy)diisophthalato κ8O1,O2:O3,O4:O5,O6:O7,O8)manganese(II)], C21H21MnN2O7
  5. Crystal structure of poly-[(μ2-((1,3-bis(benzimidazol-1-yl)propane-κ2N:N′)(μ2-4-tert-butyl-phthalato-κ2O:O′)cobalt(II)] monohydrate, C29H30CoN4O5
  6. Crystal structure of 2-amino-4-(3,4,5-trimethoxy-phenyl)-5-(oxo-5,6,7,8-tetrahydro-4H-chromene)-3-carbonitrile – ethanol (1/1), C21H26N2O6
  7. Crystal structure of ethyl 1-benzyl-5-phenyl-1H-pyrazole-3-carboxylate, C19H18N2O2
  8. Crystal structure of 2-(1-benzyl-3-phenyl-1H-pyrazol-5-yl)-5-(4-nitrobenzylthio)-1,3,4-oxadiazole, C25H19N5O3S
  9. Structure and photochromism of 1,2-bis[2-methyl-5-(2-chlorophenyl)-3-thienyl]-3,3,4,4,5,5-hexafluorocyclopent-1-ene, C27H16Cl2F6S2
  10. The crystal structure of the Schiff base (E)-2,6-diisopropyl-N-(pyridin-4-ylmethylene)aniline, C18H22N2
  11. Crystal structure of (E)-2,4-dibromo-6-(((4-methyl-2-nitrophenyl)imino) methyl)phenol, C10H14Br2N2O3
  12. Crystal structure of (bis(2,2′-bipyridine-κ2N,N′))-(3,5-dinitrosalicylato-κ2O,O′)nickel(II), C27H18N6NiO7
  13. Crystal structure of 1-(diethoxy phosphonomethyl) 2-benzoyl-3-chloro-2-cyclohexen-1-ol, C18H24ClO5P
  14. Crystal structure of tetraaqua-bis(1,3-benzimidazol-3-ium-1,3-diacetato-κO)copper(II) hemihydrate, C22H27CuN4O12.50
  15. Crystal structure of 1α,11-dihydroxyeremophil-9-en-8-one, C15H24O3
  16. Crystal structure of 1-ferrocenylsulfonyl-1H-imidazo[4,5-b]pyridine, C16H13FeN3O2S
  17. Crystal structure of bis(μ2-azido-κ2N:N)-dichlorido-bis(μ2-2-(pyridin-2-yl)ethan-1-ol-κ2O,N)dicopper(II), C14H18Cl2Cu2N8O2
  18. Crystal structure of (5,15-cis-bis(2-hydroxy-1-naphthyl)-10-phenyl-20-(4-hydroxyphenyl)-porphyrinato)-(pyridine)-zinc(ii) pyridine solvate, C67H47N7O3Zn
  19. Crystal structure of (μ2-[2,2′-bis(diphenylphosphino)-1,1′-binaphthalene oxide-κ2O,P])-iodido copper(I), C44H32CuIOP2
  20. Crystal structure of 6,8-diphenyl-2-(4-fluorophenyl)-2,3-dihydroquinolin-4(3H)-one, C27H20FNO
  21. Crystal structure of 5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetrahexoxycalix[4]arene, C68H104O4
  22. Crystal structure of N,N′–bis(pyridin-4-ylmethyl)pyrazine-2,3-dicarboxamide dihydrate, C18H20N6O4
  23. Crystal structure of a diaqua-bis(3,5-di(1H-imidazol-1-yl)pyridine-κN)-bis(2-(4-carboxy-phenyl)acetato-κO]manganese(II), C40H36MnN10O10
  24. Crystal structure of 4-(4-hydroxy-3-methoxy-phenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylic acid methyl ester, C21H25NO5
  25. Crystal structure of (E)-4,4′-(ethene-1,2-diyl)bis(3-nitrobenzoic acid) 1.5 hydrate, C16H13N2O9.5
  26. Crystal structure of (E)-2-(5-(4-fluorophenyl)-3-(furan-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-5-((4-fluorophenyl)diazenyl)-4-methylthiazole, C23H17F2N5OS
  27. Crystal structure of the co-crystalline adduct 4-((4,4-dimethyl-2,6-dioxocyclohexylidene)methylamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide - acetic acid (1/1), C21H24N4O4S ⋅ C2H4O2
  28. Synthesis and crystal structure of 2-((5-chlorobenzo[c][1,2,5]thiadiazol-4-yl)amino)-4,5-dihydro-1H-imidazol-3-ium tetraphenylborate, C33H29BClN5S
  29. Crystal structure of (4-chlorophenyl)(3-ferrocenyl-5-(trifluoromethyl)-1H-pyrazol-1-yl)methanone, C21H14ClF3FeN2O
  30. Crystal structure of (S)-benzyl 3-(benzylcarba-moyl)-3,4-dihydroisoquinoline-2(1H)-carboxylate, C25H24N2O3
  31. Crystal structure of 5-acetyl-3-(3-fluoro-4-morpholinophenyl)oxazolidin-2-one, C15H17FN2O4
  32. Crystal structure of 2-(4-fluorophenyl)-1,3-dimethyl-1H-perimidin-3-ium iodide, C19H16FIN2
  33. Crystal structure of methyl 1H-indole-2-carboxylate, C10H9NO2
  34. Crystal structure of 2,3-diphenyl-1-[(dipropylamino)acetyl]-1,3-diazaspiro[4.5]decan-4-one, C28H37N3O2
  35. Crystal structure of 1-(2H-1,3-benzodioxol-5-yl)-3-(1H-imidazol-1-yl)propan-1-one, C13H12N2O3
  36. Crystal structure of 2,9-dibromo-1,10-phenanthroline, C12H6Br2N2
  37. Crystal structure of 3-(adamantan-1-yl)-4-(4-fluorophenyl)-1H-1,2,4-triazole-5(4H)-thione, C18H20FN3S
  38. Crystal structure of trans-bis((E)-7-oxo-4-(phenyldiazenyl)cyclohepta-1,3,5-trien-1-olato)-κ2O,O′)-bis(pyridine-κN)cobalt(II), C36H28CoN6O4
  39. Crystal structure of 2-(4-methyl-3-phenylthiazol-2(3H)-ylidene)malononitrile, C13H9N3S
  40. Crystal structure of (Z)-3-(adamantan-1-yl)-1-(3-chlorophenyl)-S-benzylisothiourea, C24H27ClN2S
  41. Crystal structure of chlorido{[3-(η5-cyclopenta-dienyl)-2,2,3-trimethyl-1-phenylbutylidene] azanido-κN}[η2(N,O)-N,N-dimethylhydroxylaminato]titanium(IV), C20H27ClN2OTi
  42. Crystal Structure of 1,1′-dimethyl-[4,4′-bipyridine]-1,1′-diium tetrachloridozincate(II), C12H14Cl4N2Zn
  43. Crystal structure of 5-nitro-2-(pyrrolidin-1-yl)benzaldehyde, C11H12N2O3
  44. Crystal structure of 2,3-diphenyl-1-(morpholin-4-ylacetyl)-1,3-diazaspiro[4.5]decan-4-one, C26H31N3O3
  45. Crystal structure of 3,3-dimethyl-3,4-dihydro-1H-benzo[c]chromene-1,6(2H)-dione, C15H14O3
  46. Crystal structure of bis(2-(2-hydroxymethyl)pyridine-κ2N,O)-bis(pivalato-κO)nickel(II), C22H32N2NiO6
  47. Crystal structure of (1,10-phenanthroline-κ2N,N′)-bis(1H-pyrazole-3-carboxylato-κ2N,O)manganese(II) trihydrate, C20H20N6O7Mn
  48. The crystal structure of 3-aminopropan-1-aminium iodide, C3H11N2I
  49. Crystal structure of ethyl 1-(4-chlorophenyl)-5-methyl-1H-1,2,3-triazole-4 carboxylate, C12H12ClN3O2
  50. Crystal structure of 4,4′-((1Z,1′Z)-2,2′-(2,5-diethoxy-1,4-phenylene)bis(ethene-2,1-diyl))dipyridine, C24H24N2O2
  51. Crystal structure of (16S)-12,16-epoxy-11,14-dihydroxy-17(15/16)-abeo-3a,18-cyclo-8,11,13-abietatrien-7-one, C20H24O4
  52. Crystal structure of aquadichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3N,N′,N′′)nickel(II) monohydrate, C18H16Cl2N6NiO2
  53. Crystal structure of catena-poly[dichlorido-(μ-ethane-1,2-diyl-bis-(pyridyl-4-carboxylate-κN:N′)mercury(II)], C15H14Cl2HgN2O4
  54. Crystal structure of methyl 2-acetamido-5-chlorbenzoate, C10H10ClNO3
  55. Crystal structure of tetrakis(μ2-3,3-dimethylacrylato-κ2O,O′)-bis(2-aminopyrimidine-κN) dicopper(II), C28H38Cu2N6O8
  56. Crystal structure of 3-amino-8-methoxy-1-phenyl-1H-benzo[f]chromene-2-carbonitrile, C21H16N2O2
  57. Crystal structure of 4-(2-ammonioethyl)morpholin-4-ium dichloride monohydrate, C6H18Cl2N2O2
  58. Crystal structure of 1-(3-((5-bromo-2-hydroxybenzylidene)amino)phenyl)ethanone O-benzyl oxime, C22H19BrN2O2
  59. Crystal structure of 2-(4-(dimethylamino)-2-fluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-ol monohydrate, C15H20FN7O2
  60. Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O
  61. Crystal structure of 1,2,3,4,5-pentamethyl-1,3-cyclopentadiene, C10H16
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 22.11.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2016-0239/html
Scroll to top button