Home Crystal structure of catena-poly[(μ3-4,4′-oxydibenzoato- κ5 O,O′: O″,O‴:O‴)-bis(2,4,6-tri(3-pyridine)-1,3,5-triazine-κ1 N)cadmium(II)], C50H32CdN12O5
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Crystal structure of catena-poly[(μ3-4,4′-oxydibenzoato- κ5 O,O′: O″,O‴:O‴)-bis(2,4,6-tri(3-pyridine)-1,3,5-triazine-κ1 N)cadmium(II)], C50H32CdN12O5

  • Hao Jing ORCID logo EMAIL logo , Liu Ke , Hou Xia and Wang Hai
Published/Copyright: February 28, 2025
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 240 Issue 3

Abstract

C50H32CdN12O5, triclinic, P 1 ‾ (no. 2), a = 9.0273(2) Å, b = 15.4626(3) Å, c = 15.8910(2) Å, α = 96.5060(10)°, β = 98.5010(10)°, γ = 97.354(2)°, V = 2155.88(7) Å3, Z = 2, R gt (F) = 0.0320, wR ref (F2) = 0.0849, T = 100 K.

CCDC no.: 2405657

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size 0.14 × 0.12 × 0.10 mm
Wavelength: Cu Kα radiation (1.54184 Å)
μ: 4.60 mm−1
Diffractometer, scan mode: XtaLAB AFC12 (RINC), ω
θmax, completeness: 75.8°, > 99 %
N(hkl)measured, N(hkl)unique, Rint: 22,150, 8,625, 0.034
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 8,134
N(param)refined: 613
Programs: Shelx, 1 Olex2 2
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
Cd1 0.64565 (2) 0.41531 (2) 0.53857 (2) 0.01816 (6)
O1 0.78953 (19) 0.54540 (10) 0.59472 (11) 0.0239 (3)
O2 0.56358 (18) 0.58581 (11) 0.56124 (11) 0.0251 (4)
O3 1.00228 (18) 0.95346 (11) 0.62526 (12) 0.0248 (4)
O4 0.81454 (19) 1.33334 (11) 0.61285 (11) 0.0254 (4)
O5 0.64287 (19) 1.26001 (11) 0.50671 (11) 0.0247 (4)
N1 0.7556 (2) 0.43012 (13) 0.41519 (13) 0.0202 (4)
N2 0.8359 (2) 0.29170 (13) 0.14324 (13) 0.0234 (4)
N3 0.6912 (2) 0.21209 (14) 0.23014 (13) 0.0244 (4)
N4 0.7471 (3) 0.13959 (14) 0.10103 (14) 0.0279 (5)
N5 1.0788 (3) 0.29514 (17) −0.05959 (15) 0.0395 (6)
N6 0.5646 (5) −0.10158 (19) 0.1635 (3) 0.0835 (14)
N7 0.4989 (2) 0.39996 (13) 0.64605 (13) 0.0232 (4)
N8 0.3804 (2) 0.53002 (13) 0.91280 (13) 0.0228 (4)
N9 0.4885 (2) 0.67750 (14) 0.96763 (13) 0.0236 (4)
N10 0.5478 (2) 0.61022 (14) 0.83734 (13) 0.0239 (4)
N11 0.1403 (3) 0.51661 (18) 1.11638 (16) 0.0420 (6)
N12 0.7687 (3) 0.90810 (17) 0.9524 (2) 0.0498 (7)
C1 0.7279 (2) 0.36271 (15) 0.35145 (15) 0.0204 (5)
H1 0.662917 0.311214 0.357603 0.025*
C2 0.7904 (3) 0.36501 (15) 0.27649 (15) 0.0210 (5)
C3 0.8822 (3) 0.44183 (16) 0.26668 (16) 0.0243 (5)
H3 0.926078 0.445797 0.216231 0.029*
C4 0.9079 (3) 0.51192 (16) 0.33169 (17) 0.0259 (5)
H4 0.967815 0.565452 0.326013 0.031*
C5 0.8452 (3) 0.50314 (16) 0.40538 (16) 0.0229 (5)
H5 0.866527 0.550822 0.450749 0.028*
C6 0.7695 (3) 0.28548 (16) 0.21249 (15) 0.0209 (5)
C7 0.8213 (3) 0.21715 (16) 0.08942 (15) 0.0237 (5)
C8 0.8973 (3) 0.21950 (17) 0.01344 (16) 0.0276 (5)
C9 1.0003 (3) 0.29247 (17) 0.00643 (16) 0.0277 (5)
H9 1.015985 0.342070 0.049557 0.033*
C10 1.0496 (4) 0.2238 (2) −0.1202 (2) 0.0503 (9)
H10 1.103292 0.224659 −0.167312 0.060*
C11 0.9481 (4) 0.1504 (2) −0.1188 (2) 0.0516 (9)
H11 0.931802 0.102224 −0.163499 0.062*
C12 0.8709 (4) 0.1484 (2) −0.05098 (19) 0.0426 (8)
H12 0.799397 0.098553 −0.048109 0.051*
C13 0.6847 (3) 0.14096 (17) 0.17229 (17) 0.0266 (5)
C14 0.6071 (3) 0.05652 (18) 0.19117 (18) 0.0336 (6)
C15 0.6255 (5) −0.0229 (2) 0.1470 (3) 0.0612 (12)
H15 0.684725 −0.021516 0.102309 0.073*
C16 0.4802 (5) −0.1016 (2) 0.2260 (3) 0.0674 (13)
H16 0.436141 −0.156658 0.238930 0.081*
C17 0.4537 (4) −0.0260 (2) 0.2725 (2) 0.0550 (10)
H17 0.390572 −0.029035 0.315168 0.066*
C18 0.5206 (4) 0.0539 (2) 0.2559 (2) 0.0450 (8)
H18 0.507373 0.106891 0.288654 0.054*
C19 0.5107 (3) 0.46677 (15) 0.70950 (15) 0.0219 (5)
H19 0.571788 0.520573 0.705827 0.026*
C20 0.4380 (3) 0.46116 (16) 0.78037 (16) 0.0233 (5)
C21 0.3490 (3) 0.38200 (17) 0.78543 (17) 0.0287 (5)
H21 0.297603 0.375588 0.832908 0.034*
C22 0.3366 (3) 0.31293 (18) 0.72026 (18) 0.0310 (6)
H22 0.276435 0.258343 0.722352 0.037*
C23 0.4128 (3) 0.32418 (17) 0.65187 (17) 0.0273 (5)
H23 0.403756 0.276363 0.607355 0.033*
C24 0.4566 (3) 0.53789 (16) 0.84756 (15) 0.0223 (5)
C25 0.3994 (3) 0.60233 (16) 0.97069 (15) 0.0218 (5)
C26 0.5604 (3) 0.67777 (16) 0.89983 (15) 0.0228 (5)
C27 0.3162 (3) 0.59871 (17) 1.04399 (15) 0.0239 (5)
C28 0.2154 (3) 0.52437 (18) 1.05000 (17) 0.0310 (6)
H28 0.198957 0.476659 1.004806 0.037*
C29 0.1665 (4) 0.5856 (2) 1.17843 (19) 0.0439 (7)
H29 0.116443 0.580962 1.226647 0.053*
C30 0.2608 (3) 0.6628 (2) 1.17730 (17) 0.0337 (6)
H30 0.272609 0.710117 1.222557 0.040*
C31 0.3372 (3) 0.66965 (17) 1.10931 (16) 0.0265 (5)
H31 0.403325 0.721898 1.106729 0.032*
C32 0.6612 (3) 0.75922 (17) 0.89291 (16) 0.0256 (5)
C33 0.6748 (4) 0.83360 (19) 0.9533 (2) 0.0379 (7)
H33 0.614475 0.831563 0.997390 0.045*
C34 0.8524 (4) 0.9085 (2) 0.8888 (2) 0.0430 (7)
H34 0.921225 0.960119 0.887631 0.052*
C35 0.8442 (3) 0.83882 (19) 0.82551 (18) 0.0333 (6)
H35 0.904062 0.843039 0.781323 0.040*
C36 0.7478 (3) 0.76291 (18) 0.82737 (17) 0.0292 (5)
H36 0.740385 0.713658 0.784599 0.035*
C37 0.7054 (3) 0.60396 (15) 0.58160 (14) 0.0199 (4)
C38 0.7791 (3) 0.69714 (15) 0.59145 (14) 0.0189 (4)
C39 0.6950 (3) 0.76597 (15) 0.59692 (15) 0.0217 (5)
H39 0.588303 0.753713 0.593551 0.026*
C40 0.7650 (3) 0.85221 (15) 0.60723 (16) 0.0231 (5)
H40 0.706991 0.899117 0.612127 0.028*
C41 0.9204 (3) 0.86991 (15) 0.61039 (15) 0.0201 (4)
C42 1.0067 (3) 0.80199 (16) 0.60462 (15) 0.0218 (5)
H42 1.113240 0.814465 0.607228 0.026*
C43 0.9353 (3) 0.71557 (15) 0.59498 (15) 0.0214 (5)
H43 0.993397 0.668649 0.590763 0.026*
C44 0.9327 (3) 1.02584 (15) 0.60807 (15) 0.0210 (5)
C45 0.8217 (3) 1.02547 (15) 0.53760 (16) 0.0236 (5)
H45 0.787039 0.973268 0.498314 0.028*
C46 0.7622 (3) 1.10171 (15) 0.52520 (15) 0.0222 (5)
H46 0.684164 1.101265 0.477879 0.027*
C47 0.8147 (3) 1.17950 (15) 0.58100 (15) 0.0203 (5)
C48 0.9303 (3) 1.17932 (17) 0.64915 (17) 0.0297 (5)
H48 0.970036 1.232321 0.686400 0.036*
C49 0.9883 (3) 1.10240 (17) 0.66326 (17) 0.0297 (6)
H49 1.065940 1.102406 0.710671 0.036*
C50 0.7534 (3) 1.26276 (15) 0.56576 (15) 0.0203 (4)

1 Source of material

The reagents were purchased from standard commercial sources and used without further purification. The 2,4,6-tri(3-pyridinyl)-1,3,5-triazine was synthesized according to literature. 3 The preparation of the title crystal is similar to the previously reported literature procedure. 4 A mixture of 2,4,6-tri(3-pyridinyl)-1,3,5-triazine (5.3 mg, 0.017 mmol), 4,4′-oxydibenzoic acid (4.4 mg, 0.017 mmol) and Cd(NO3)2·4H2O (10.8 mg, 0.035 mmol) were dispersed in a mixed solution of N,N-dimethyl formamide (1.5 mL) and ethyl alcohol (1.5 mL) and sealed in a caped glass bottle at 358 K for 72 h. The colourless block crystals were prepared with the yield of 58 % based on 2,4,6-tri(3-pyridinyl)-1,3,5-triazine.

2 Experimental details

The initial crystal structure was solved and refined by Olex2 and SHELXS. 1 , 2 Hydrogen atoms on organic ligands were located at geometrically calculated positions and refined with fixed thermal factors.

3 Comment

The design and production of metal-organic frameworks (MOFs) have attracted widespread attention, due to their potential applications in the fields, such as information storage, gas storage/separation, magnetism, catalyst and so on. 5 , 6 Over the past decade, numerous MOFs constructed by aromatic carboxylic organic ligands have been extensively studied. 7 In addition, the topological structures of MOFs could be improved and controlled by using aromatic carboxylic acids and N-heterocycle rings mixed ligand strategies. 8 , 9

Recently, the title compound was obtained by using 2,4,6-tri(3-pyridinyl)-1,3,5-triazine, 4,4′-oxydibenzoic acid and Cd(NO3)2·4H2O under solvothermal conditions. The asymmetric structural unit consists of one Cd center, one 4,4′-oxydibenzoic acid and two 2,4,6-tri(3-pyridinyl)-1,3,5-triazine ligands. Each Cd(II) ion is a hexagonal octahedral geometry defined by two pyridyl nitrogen atoms of two 2,4,6-tri(3-pyridinyl)-1,3,5-triazine ligands, two carboxylate oxygen atoms of two 4,4′-oxydibenzate ligands and two carboxylate oxygen atoms of one 4,4′-oxydibenzoate ligand. On the other hand, each 4,4′-oxydibenzoate is linked to three independent Cd(II) ions by four carboxyl oxygen atoms, and each 2,4,6-tri(3-pyridinyl)-1,3,5-triazine ligand is coordinated to one Cd(II) ion via one external pyridyl donor. Interestingly, only one pyridine N atoms are involved in the coordination in 2,4,6-tri(3-pyridinyl)-1,3,5-triazine.

Corresponding author: Hao Jing, School of Applied Chemical Engineering, Lanzhou Petrochemical University of Vocational Technology, Lanzhou 730000, People’s Republic of China, E-mail:

Funding source: University Teacher Innovation Fund Program

Award Identifier / Grant number: No. 2024A-241

Funding source: Lanzhou Petrochemical University of Vocational Technology Doctoral Fund

Award Identifier / Grant number: No. 2023BJ-04

Funding source: Functional Materials and Catalysis Innovation Team in Lanzhou Petrochemical University of Vocational Technology

  1. Conflict of interest: The authors declare no conflicts of interest regarding this article.

  2. Research funding: This work was supported by the University Teacher Innovation Fund Program (No. 2024A-241), Lanzhou Petrochemical University of Vocational Technology Doctoral Fund (No. 2023BJ-04), and Functional Materials and Catalysis Innovation Team in Lanzhou Petrochemical University of Vocational Technology.

  3. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

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Received: 2024-12-03
Accepted: 2025-01-14
Published Online: 2025-02-28
Published in Print: 2025-06-26

© 2025 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  55. Crystal structure of (Z)-2-(5-((4-(dimethylamino)naphthalen-1-yl)methylene)-4-oxo-2-thioxothiazolidin-3-yl)acetic acid, C18H16N2O3S2
  56. Crystal structure of (4-fluorobenzyl)triphenylphosphonium bromide, C25H21BrFP
  57. The crystal structure of dichlorido-[6-(pyridin-2-yl)phenanthridine-κ2N, N′]zinc(II)-chloroform (1/1), C19H13N2ZnCl5
  58. Crystal structure of (E)-(3-(2,4-dichlorophenyl)acryloyl)ferrocene, C19H14Cl2FeO
  59. The crystal structure of (E)-7-chloro-1-cyclopropyl-6-fluoro-3-((2-hydroxybenzylidene)amino)quinolin-4(1H)-one, C19H14ClFN2O2
  60. Crystal structure of 2-bromo-11-(((fluoromethyl)sulfonyl)methyl)-6-methyl-6,11-dihydrodibenzo[c,f][1,2]thiazepine 5,5-dioxide, C16H13BrFNO4S2
  61. Crystal structure of 2-chloro-11-(((fluoromethyl)sulfonyl)methyl)-6-methyl-6,11-dihydrodibenzo[c,f][1,2]thiazepine 5,5-dioxide, C16H13ClFNO4S2
  62. Crystal structure of 5-(2,2-difluoropropyl)-5-methyl-6-oxo-5,6-dihydrobenzo[4,5]imidazo[2,1-a]isoquinoline-3-carbonitrile, C20H15F2N3O
https://doi.org/10.1515/ncrs-2024-0463
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of 5,5′-bis(2,4,6-trinitrophenyl)-2,2′-bi(1,3,4-oxadiazole), C16H4N10O14
  4. Crystal structure of catena-poly[(μ3-4,4′-oxydibenzoato- κ5 O,O′: O″,O‴:O‴)-bis(2,4,6-tri(3-pyridine)-1,3,5-triazine-κ1 N)cadmium(II)], C50H32CdN12O5
  5. The crystal structure of 1,4-diazepane-1,4-diium potassium trinitrate, C5H14KN5O9
  6. The crystal structure of benzyl 2,2,5,5-tetramethylthiazolidine-4-carboxylate, C15H21NO2S
  7. Crystal structure of 2-hydroxyethyl-triphenylphosphonium tetracyanidoborate, C24H20BN4OP
  8. The crystal structure of 1-methyl-3-(N-methylnitrous amide–N-methylene) imidazolidine-2,4,5-trione
  9. Crystal structure of N-((3-cyano-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(2,2,2-trifluoroacetyl)-1H-pyrazol-5-yl)carbamoyl)-2,6-difluorobenzamide, C20H7Cl2F8N5O3S
  10. Crystal structure of 5-(2,2-difluoropropyl)-5-methylbenzo[4,5]imidazo[2,1-a] isoquinolin-6(5H)-one, C20H18F2N2O
  11. The crystal structure of N′,N″-[1,2-bis(4-chlorophenyl)ethane-1,2-diylidene]bis(furan-2- carbohydrazide), C24H16Cl2N4O4
  12. Crystal structure of [(4-bromobenzyl)triphenylphosphonium] tetrabromoantimony(III), [C25H21BrP]+[SbBr4]−
  13. Crystal structure of [(4-bromobenzyl)triphenylphosphonium] tetrabromidoindium(III), [C25H21BrP]+[InBr4]−
  14. The crystal structure of 4-carboxy-2-oxobutan-1-aminium chloride, C5H10ClNO3
  15. Crystal structure of (4-(4-chlorophenyl)-1H-pyrrole-3-carbonyl)ferrocene, C21H16ClFeNO
  16. The crystal structure of dichlorido(η6-p-cymene)(triphenylarsine)ruthenium(II), C28H29AsCl2Ru
  17. Crystal structure of (Z)-2-hydroxy-N′-(1-(o-tolyl)ethylidene)benzohydrazide, C16H16N2O2
  18. The crystal structure of 10-(1-bromoethyl)-14-(bromomethyl)dibenzo[a, c]acridine, C24H17NBr2
  19. Synthesis and crystal structure of 6-methoxy-7-[(4-methoxyphenyl)methoxy]-2H-1-benzopyran-2-one, C18H16O5
  20. Synthesis and crystal structure of ethyl 4-((4-trifluoromethylbenzyl)amino)benzo, C17H16F3NO2
  21. The crystal structure of (Z)-2-(tert-butyl)-6-(7-(tert-butyl)-5-methylbenzo[d][1,3]oxathiol-2-ylidene)-4-methylcyclohexa-2,4-dien-1-one, C23H28O2S
  22. The crystal structure of (R)-2-aminobutanamide hydrochloride, C4H11ClN2O
  23. Crystal structure of bromido[hydridotris(3-tert-butyl-5-isopropylpyrazolyl)borato-κ3 N,N′,N″]copper(II), C30H52BBrCuN6
  24. Crystal structure of chlorido{hydridotris[3-mesityl-5-methyl-1H-pyrazol-1-yl-κN3]borato}-copper(II) dichloromethane monosolvate
  25. Crystal structure of 4-[3,5-bis(propan-2-yl)-1H-pyrazol-4-yl]pyridine, C14H19N3
  26. Crystal structure of ((4-(4-bromophenyl)-1H-pyrrol-3-yl)methyl)ferrocene, C21H16BrFeNO
  27. Crystal structure of [(4-chlorobenzyl)triphenylphosphonium] dichloridocopper(I), {[C25H21ClP]+[CuCl2]−}n
  28. The crystal structure of {Cu(2,9-diisopropyl-4,7-diphenyl-1,10-phenanthroline)[4,5-bis(diphenylphosphino)-9,9-dimethylxanthene]}+ PF6−·1.5(EtOAC)
  29. Crystal structure of 3,5-bis(t-butyl)-1H-pyrazol-4-amine, C11H21N3
  30. Crystal structure of [(2,4-dichlorobenzyl)triphenylphosphonium] trichloridocopper(II), [C25H20Cl2P]+[CuCl3]−
  31. The crystal structure of dipotassium sulfide, K2S
  32. Crystal structure of (4-(4-methoxyphenyl)-1H-pyrrole-3-carbonyl)ferrocene, C22H19FeNO2
  33. Crystal structure of (E)-6-(4-methylpiperazin-1-yl)-2-(4-(trifluoromethyl)benzylidene)-3, 4-dihydronaphthalen-1(2H)-one, C23H23F3N2O
  34. Crystal structure of (E)-6-morpholino-2-(4-(trifluoromethyl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one, C22H20F3NO2
  35. Crystal structure of Ce9Ir37Ge25
  36. The crystal structure of ethyl 6-(2-nitrophenyl)imidazo[2,1-b]thiazole-3-carboxylate, C14H11N3O4S
  37. Crystal structure of (4-(4-isopropylphenyl)-1H-pyrrol-3-yl)(ferrocenyl)methanone, C24H23FeNO
  38. Crystal structure of bis(methylammonium) tetrathiotungstate(VI), (CH3NH3)2[WS4]
  39. Crystal structure of 6,11-dihydro-12H-benzo[e]indeno[1,2-b]oxepin-12-one, C17H12O2
  40. Crystal structure of 3-[(4-phenylpiperidin-1-yl)methyl]-5-(thiophen-2-yl)-2,3-dihydro-1,3,4- oxadiazole-2-thione, C18H19N3OS2
  41. Crystal structure of N-isopropyl-1,8-naphthalimide C15H13NO2
  42. TiNiSi-type EuPdBi
  43. Crystal structure of 1-(p-tolylphenyl)-4-(2-thienoyl)-3-methyl-1H-pyrazol-5-ol, C16H14N2O2S
  44. The crystal structure of 3-(3-carboxypropyl)-2-nitro-1H-pyrrole 1-oxide, C7H9N3O5
  45. The crystal structure of tetraaqua-bis(2-(2-methyl-5-nitro-1H-imidazol-1-yl)acetato-k2O:N)-tetrakis(2-(2-methyl-5-nitro-1H-imidazol-1-yl)acetato-k1N)trizinc(II) hexahydrate C36H52N18O32Zn3
  46. The crystal structure of 4-(3-carboxy-1-ethyl-6-fluoro-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium 4-hydroxy-3,5-dimethoxybenzoate monohydrate, C25H30FN3O9
  47. Crystal structure of bis(DL-1-carboxy-2-(1H-indol-3-yl)ethan-1-aminium) oxalate — acetic acid (1/2)
  48. Crystal structure of methyl (E)-4-((4-methylphenyl)sulfonamido)but-2-enoate, C12H15NO4S
  49. The crystal structure of actarit, C10H11NO3
  50. The crystal structure of bicyclol, C19H18O9
  51. The crystal structure of topiroxostat, C13H8N6
  52. Crystal structure of 2,2-dichloro-N-methyl-N-(4-p-tolylthiazol-2-yl)acetamide, C13H12Cl2N2OS
  53. Crystal structure of 4-(trifluoromethyl)-7-coumarinyl trifluoromethanesulfonate C11H4F6O5S
  54. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6)-((Z)-N,N′-bis(2-(dimethylamino)phenyl)carbamimidato-κ1N)potassium(I)
  55. Crystal structure of (Z)-2-(5-((4-(dimethylamino)naphthalen-1-yl)methylene)-4-oxo-2-thioxothiazolidin-3-yl)acetic acid, C18H16N2O3S2
  56. Crystal structure of (4-fluorobenzyl)triphenylphosphonium bromide, C25H21BrFP
  57. The crystal structure of dichlorido-[6-(pyridin-2-yl)phenanthridine-κ2N, N′]zinc(II)-chloroform (1/1), C19H13N2ZnCl5
  58. Crystal structure of (E)-(3-(2,4-dichlorophenyl)acryloyl)ferrocene, C19H14Cl2FeO
  59. The crystal structure of (E)-7-chloro-1-cyclopropyl-6-fluoro-3-((2-hydroxybenzylidene)amino)quinolin-4(1H)-one, C19H14ClFN2O2
  60. Crystal structure of 2-bromo-11-(((fluoromethyl)sulfonyl)methyl)-6-methyl-6,11-dihydrodibenzo[c,f][1,2]thiazepine 5,5-dioxide, C16H13BrFNO4S2
  61. Crystal structure of 2-chloro-11-(((fluoromethyl)sulfonyl)methyl)-6-methyl-6,11-dihydrodibenzo[c,f][1,2]thiazepine 5,5-dioxide, C16H13ClFNO4S2
  62. Crystal structure of 5-(2,2-difluoropropyl)-5-methyl-6-oxo-5,6-dihydrobenzo[4,5]imidazo[2,1-a]isoquinoline-3-carbonitrile, C20H15F2N3O
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