Home Crystal structure of catena-poly[diaqua-(μ2-bipyridine-κ2N:N′)-bis(3,5-dichloroisonicotinato-κO)cadmium(II)] dihydrate, C22H20CdCl4N4O8
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Crystal structure of catena-poly[diaqua-(μ2-bipyridine-κ2N:N′)-bis(3,5-dichloroisonicotinato-κO)cadmium(II)] dihydrate, C22H20CdCl4N4O8

  • Sun Xiao-Tian EMAIL logo and Lei Zheng
Published/Copyright: March 5, 2020
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 235 Issue 4

Abstract

C22H20CdCl4N4O8, monoclinic, C2/c (no. 15), a = 14.9908(5) Å, b = 11.6786(3) Å, c = 15.4664(5) Å, β = 95.448(3)°, V = 2695.50(14) Å3, Z = 4, Rgt(F) = 0.0226, wRref(F2) = 0.0516, T = 291.5(2) K.

CCDC no.: 1985058

A part of the title structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Colourless block
Size:0.31 × 0.29 × 0.24 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:1.26 mm−1
Diffractometer, scan mode:SuperNova, ω
θmax, completeness:25.5°, 99%
N(hkl)measured, N(hkl)unique, Rint:7350, 2483, 0.024
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 2353
N(param)refined:180
Programs:CrysAlisPRO [1], Olex2 [2], SHELX [3], [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Cd10.50001.03175(2)0.25000.02445(9)
Cl10.24664(5)0.76936(6)0.35432(5)0.05245(18)
Cl20.21715(5)1.23093(6)0.37513(4)0.05187(18)
O10.37754(10)1.02956(12)0.33085(10)0.0322(4)
O1W0.59373(11)1.02934(14)0.38208(10)0.0436(4)
H1WA0.58370.97700.41800.065*
H1WB0.64431.04390.36390.065*
O20.26863(12)1.00620(17)0.22345(11)0.0498(5)
N10.50000.8348(2)0.25000.0268(5)
N20.50000.22852(19)0.25000.0273(5)
N30.11375(16)0.9752(2)0.49901(15)0.0592(7)
C10.52998(15)0.77471(18)0.18483(14)0.0298(5)
H10.55070.81470.13880.036*
C20.53175(14)0.65701(17)0.18243(13)0.0288(5)
H20.55400.61920.13610.035*
C30.50000.5949(2)0.25000.0226(6)
C40.50000.4681(2)0.25000.0223(6)
C50.44032(14)0.40609(18)0.29486(14)0.0310(5)
H50.39920.44390.32610.037*
C60.44226(14)0.28851(18)0.29295(14)0.0327(5)
H60.40130.24860.32300.039*
C70.29748(15)1.01301(18)0.30013(15)0.0307(5)
C80.23147(14)0.9998(2)0.36874(13)0.0317(5)
C90.19390(15)1.0932(2)0.40781(14)0.0378(5)
C100.13614(17)1.0772(3)0.47149(16)0.0519(7)
H100.11201.14150.49600.062*
C110.14801(17)0.8849(3)0.46173(17)0.0522(7)
H110.13210.81220.47950.063*
C120.20622(15)0.8934(2)0.39770(14)0.0376(5)
O2W0.55444(16)0.87438(18)0.51129(11)0.0693(6)
H2WA0.58630.90170.55490.104*
H2WB0.49870.86540.53580.104*

Source of material

All reagents and solvents for synthesis and analysis were commercially available and used as received. The mixture of 3,5-dichloroisonicotinic acid (dcia) (0.1 mmol, 19.2 mg), 4,4′-bipyridine (bpy) (0.1 mmol, 15.6 mg), Cd(OAC)2 ⋅ 2H2O (0.1 mmol, 26.7 mg) and H2O (6.0 mL) were placed in a 23 mL Teflon liner stainless steel reactor. The vessel was heated to 393 K for 4 days, then cooled slowly to the room temperature. Colorless crystals were obtained, and further crystals were filtered off, washed with mother liquid, and dried under ambient conditions. Yield 46% (based on dcia ligand).

Experimental details

Using Olex2 [2], the structure was solved with the ShelXT [3] structure solution program and refined with the ShelXL [4] refinement package. All hydrogen atoms were placed in calculated positions and refined isotropically with a riding model except for those bound to water molecules, which were initially located in a difference Fourier map and included in the final refinement with Uiso(H) equivalent to 1.5 times of Ueq(O).

Comment

The self-assembly of coordination polymers (CPs) using a mixed-ligand strategy continues to attract attention due to their fascinating architectures and topologies, as well as their potential application [5], [6], [7], [8], [9], [10]. Among them, isonicotinates own different kinds of coordination donors, that are both pyridyl and carboxylate donor groups which have been used extensively to synthesize CPs [11], [12], [13], [14], [15]. With that in mind, we selected the 3,5-dichloroisonicotinic acid (dcia) as the educt, as the architectures of CPs constructed from the dcia ligand are rather rare.

The asymmetric unit of complex contains half a cadmium atom, one dcia anion, half a bpy molecule, one ligated water molecule and one guest water molecule. Each cadmium atom is six-coordinated by four O donors of two symmetry-related dcia anions and two coordinated water molecule in the equatorial plane with two N donors of two symmetry-related bpy ligands in the axial positions. The Cd—O bond lengths are 2.3173(14) and 2.3671(16) Å, respectively. The Cd—N bond length are 2.300(2) and 2.298(2) Å, respectively. The [CdO4N2] environment are bridged by two N atoms of bpy along the b direction forming a chain, while each dcia carboxylate ligand works as a terminal ligand with uncoordinated pyridine N atoms. The monocoordinated dcia ligands decorate the chain. Besides intramolecular O(1W)-H(1WB)⋯O(2) hydrogen bonds, intermolecular H-bonds between ligated H2O and guest H2O molecule [O(1W)-H(1WA)⋯O(2W); d(O1W⋯O2W) = 2.800(3) Å; degree (O1W-H1WA⋯O2W) = 171.6°; O(2W)-H(2WB)⋯O(1W); d(O2W⋯O1W) = 3.101(3) Å; degree (O2W-H2WB⋯O1W) = 138.6°] and between guest H2O molecule and carboxylate O atom of dcia ligand [O(2W)-H(2WA)⋯O(1); d(O2W⋯O1) = 2.791(2) Å; degree (O2W-H2WA⋯O1) = 161.9°] further extend the adjacent paralleled chains to result in the 2D layer. The adjacent 2D layers are stacked in a parallel fashion and cohered together by the weak effect of van der Waals force into the entire 3D network. Finally it should not kept unmentioned that the title structure is closely related to a recently reported Co(II) CP [16].

Acknowledgements

This work was supported by the National Natural Science Foundation of China (no. 11804140).

References

1. Agilent Technologies: CrysAlisPRO Software system. Agilent Technologies UK Ltd, Oxford, UK (2011).Search in Google Scholar

2. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H.: OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 42 (2009) 339–341.10.1107/S0021889808042726Search in Google Scholar

3. Sheldrick, G. M.: SHELXT – Integrated space-group and crystal-structure determination. Acta Crystallogr. A71 (2015) 3–8.10.1107/S2053273314026370Search in Google Scholar PubMed PubMed Central

4. Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central

5. Li, G. L.; Liu, G. Z.; Ma, L. F.; Xin, L. Y.; Li, X. L.; Wang, L. Y.: Crystallographic determination of solid-state structural transformations in a dynamic metal-organic framework. Chem. Commun. 50 (2014) 2615–2617.10.1039/C3CC49106DSearch in Google Scholar

6. Zhao, Y.; Wang, L.; Fan, N. N.; Han, M. L.; Yang, G. P.; Ma, L. F.: Porous Zn(II)-based metal-organic frameworks decorated with carboxylate groups exhibiting high gas adsorption and separation of organic Dyes. Cryst. Growth Des. 50 (2018) 7114–7121.10.1021/acs.cgd.8b01290Search in Google Scholar

7. Yao, S. L.; Liu, S. J.; Tian, X. M.; Zheng, T. F.; Cao, C.; Niu, C. Y.; Chen, Y. Q.; Chen, J. L.; Huang, H.; Wen, H. R.: A Zn(II)-based metal-organic framework with a rare tcj topology as a turn-on fluorescent sensor for acetylacetone. Inorg. Chem. 58 (2019) 3578–3581.10.1021/acs.inorgchem.8b03316Search in Google Scholar PubMed

8. Xue, L. P.; Li, Z. H.; Zhang, T.; Cui, J. J.; Gao, Y.; Yao, J. X.: Construction of two Zn(II)/Cd(II) multifunctional coordination polymers with mixed ligands for catalytic and sensing properties. New J. Chem. 42 (2018) 14203–14209.10.1039/C8NJ02055HSearch in Google Scholar

9. Xin, L. Y.; Liu, G. Z.; Ma, L. F.; Wang, L. Y.: Coligand-regulated assembly, fluorescence, and magnetic properties of Co(II) and Cd(II) complexes with a non-coplanar dicarboxylate. J. Solid State Chem. 206 (2013) 233–241.10.1016/j.jssc.2013.08.010Search in Google Scholar

10. Li, X. L.; Liu, G. Z.; Xin, L. Y.; Wang, L. Y.: Three Zn(II) metal-organic frameworks assembled from a versatile tecton 5-ethyl-pyridine-2,3-dicarboxylate and dipyridyl-type coligand. CrystEngComm 14 (2012) 1729–1736.10.1039/C1CE06050CSearch in Google Scholar

11. Schoedel, A.; Jaquier, M.; Boyette, W.; Wojtas, L.; Eddaoudi, O.; Zaworotko, M. J.: 4,6-Connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes. Cryst. Growth Des. 14 (2014) 2115–2117.10.1021/cg500205fSearch in Google Scholar

12. Mei, L.; Hu, K. Q.; Zhang, Z. H.; An, S. W.; Chai, Z. F.; Shi, W. Q.: Stepwise ortho chlorination of carboxyl groups for promoting structure variance of heterometallic uranyl-silver coordination polymers of isonicotinate. Inorg. Chem. 57 (2018) 4673–4685.10.1021/acs.inorgchem.8b00402Search in Google Scholar PubMed

13. An, Z.; Zhou, T.: A heterometallic Cu(I)-Sr(II) coordination polymer based on isonicotinic acid ligand: synthesis, crystal structure, luminescence and photocatalytic performance for methylene blue degradation. Chin. J. Struct. Chem. 38 (2019) 644–650.Search in Google Scholar

14. Xin, L. Y.; Ju, F. Y.; Li, X. L.; Liu, G. Z.: Thermal stabilities and crystal structures of two supramolecular microporous frameworks based on carboxylate-dipyridyl mix-ligands. Russ. J. Coord. Chem. 43 (2017) 55–62.10.1134/S1070328417010080Search in Google Scholar

15. Ju, F. Y.; Li, Y. P.; Li, G. L.; Liu, G. Z.; Xin, L. Y.; Li, X. L.: Zinc(II) and cadmium(II) coordination polymers with various polynuclears spaced by semirigid 4-carboxybenzeneacetate and nitrogen-rich co-ligands: syntheses, structures and properties. Chin. J. Inorg. Chem. 32 (2016) 1876–1884.Search in Google Scholar

16. Li, X.-L.; Feng, K.-X.; Xin, L.-Y.: Crystal structure of catena-poly[diaqua-bis(3,5-dichloropyridine-4-carboxylato-κ1O)-bis(μ2-4,4′-bipyridine-κ2N:N′)cobalt(II)], C22H16Cl4CoN4O6. Z. Kristallogr. NCS 234 (2019) 639–640.10.1515/ncrs-2018-0592Search in Google Scholar

Received: 2020-01-05
Accepted: 2020-02-19
Published Online: 2020-03-05
Published in Print: 2020-06-25

©2020 Sun Xiao-Tian et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

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  67. Crystal structure of 1-(4-chloro-phenyl)-7-ethoxyl-6,8-difluoro-4-oxo-1,4-dihydro-quinoline-3-carboxylic acid, C18H12ClF2NO4
  68. Crystal structure of 7-ethoxy-6,8-difluoro-4-oxo-1-pyridin-2-ylmethyl-1,4-dihydro-quinoline-3-carboxylic acid, C18H14F2N2O4
  69. Crystal structure of octahydro-7aR,8′R-dimethylspiro[isobenzofuran-4(1H), 4′ (3′H)-[1H-7,9a]methanocyclohepta[c]pyran]-1′,3, 9′ (3aH,4′aH)-trione, C20H26O5
  70. Crystal structure of bis(5-ethoxy-2-(((1-hydroxy-2-methyl-3-oxidopropan-2-yl)imino)methyl)phenolato-κ3N,O,O’)manganese(IV) – methanol (1/1), C27H38MnN2O9
  71. Crystal structure of 8a,8a′′-oxybis(8aH-8,9-dioxa-3a1λ4-aza-8aλ4-borabenzo[fg]tetracene), C34H22B2N2O5
  72. Crystal structure of bromido-triphenyl-(triphenylarsine oxide-κO)tin(IV), C36H30AsBrOSn
  73. Crystal structure of catena-poly[chlorido-(μ2-formato-κ2O:O′)-(1,10-phenathroline-κ2N,N′)copper(II)], C26H18Cl2Cu2N4O4
  74. The crystal structure of poly[(μ10-5-carboxyisophthalato-κ10O)disodium], C9H4Na2O6
  75. The crystal structure of 3,5-difluoroisonicotinic acid, C6H3F2NO2
  76. The crystal structure of ethyl-1-(N-(adamantan-1-yl)-carbamothioyl)piperidine-4-carboxylate, C19H30N2O2S
  77. Crystal structure of 5-methyl-3-phenyl-1-tosyl-1,2,3,4-tetrahydropyridine, C19H21NO2S
  78. Crystal structure of bis((3-chlorosalicylidene)-ethylenediaminato-κ4N,N′,O,O′)nickel (II), C16H12Cl2NiN2O2
  79. Crystal structure of (E)-N′-(2-chloro-6-hydroxybenzylidene)-4-hydroxybenzohydrazide — dihydrofuran-2(3H)-one (1/1), C18H17ClN2O5
  80. Crystal structure of bis((3-bromosalicylidene)-ethylenediaminato-κ4N,N′,O,O′) nickel (II), C16H12Br2NiN2O2
  81. Crystal structure of trimethylsulfoxonium tetrachloridocobaltate(II) [(CH3)3SO]2CoCl4
https://doi.org/10.1515/ncrs-2020-0011
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Articles in the same Issue

  1. Frontmatter
  2. Crystal structure of bis [1-(phenylsulfonyl)-2-(1-(pyrazin-2-yl)ethylidene)hydrazin-1-ido-κ3N,N′,O]cobalt(II), C24H22N8O4S2Co
  3. The crystal structure of 1,3-bis(4-(methoxycarbonyl)benzyl)-2-methyl-1H-benzo[d]imidazol-3-ium bromide, C26H25BrN2O4
  4. Crystal structure of {tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ4N,N′,N′′,N′′′}-(nitrito-κ2O,O′)nickel(II) perchlorate – ethanol (1/1), C26H27ClN8NiO7
  5. Crystal structure of catena-poly[aqua[(μ2-4,5-dicarboxylato-2-(2-carboxylatophenyl)imidazol-1-ido-κ4N,O,O′:N′)](μ2-4,4′-bipyridine-κ2N:N′)dicopper(II)], C22H14Cu2N4O7
  6. Crystal structure of chlorido-tris(4-methylbenzyl-κC)-(triphenylarsine oxide-κO)tin(IV), C42H42AsClOSn
  7. The crystal structure of 4,4′-bipyridinium bis(3-carboxy-2-nitrobenzoate) tetrahydrate, C13H13N2O8
  8. Crystal structure of 1-(3-chlorophenyl)-4-(4-(((2,3-dihydro-1H-inden-5-yl)oxy)methyl)phenethyl)piperazine, C28H31ClN2O
  9. Crystal structure of catena-poly[diaqua-bis(μ2-5,5′-(1H-imidazole-4,5-diyl)bis(tetrazol-2-ido)-κ4N,N′:N′′,N′′′)magnesium], C10H8N20O2Mg
  10. The crystal structure of (E)-2-((2-hydroxy-4-ethoxybenzylidene)amino)-2-methylpropane-1,3-diol monohydrate, C13H21NO5
  11. Crystal structure of catena-poly[diaqua-(μ2-bipyridine-κ2N:N′)-bis(3,5-dichloroisonicotinato-κO)cadmium(II)] dihydrate, C22H20CdCl4N4O8
  12. The crystal structure of 4-(4-chlorophenyl)cyclohexane-1-carboxylic acid, C13H15ClO2
  13. Redetermination of the crystal structure of yttrium(III) trinitrate(V) pentahydrate, Y(NO3)3 ⋅ 5 H2O, H10N3O14Y
  14. Crystal structure of catena-poly[di-μ2-chlorido-1,10-phenanthroline-κ2N,N′-cadmium(II)], C12H8Cl2CdN2
  15. Crystal structure of 4-((2-methyl-6-(trifluoromethyl)pyrimidin-4-yl)oxy)benzoic acid, C13H9F3N2O3
  16. Crystal structure of 3-acetyl-4-hydroxybenzoic acid, C18H16O8
  17. Crystal structure of bis(N,2-bis(4-ethoxybenzylidene)hydrazine-1-carbohydrazonothioato-κ2N,S)nickel(II) — N,N-dimethylformamide (1/2), C44H56N10S2O6Ni
  18. The crystal structure of 5-chloro-4,6-dimethoxypyrimidin-2-amine, C6H8ClN3O2
  19. Crystal structure of poly[aqua-(μ4-benzene-1,2,4,5-tetracarboxylato-κ4O,O′,O′′,O′′′)bis(μ2-1-(4-(1H-imidazol-1-yl)benzyl)-1H-1,2,4-triazole-κ2N:N)dinickel(II)], NiC17H14N5O5
  20. Crystal structure of poly[aqua(5-dimethylamino)naphthalene-1-sulfonato-κ2N:O)(μ2-4,4′-bipyridyl -κ2N:N′)silver(I)], C44H44Ag2N6O8S2
  21. Crystal structure of 1-[3-(trifluoromethyl)cinnamoyl]-3-(pyridin-2-yl-κN)pyrazole-κ2N-bis(2-phenylpyridinato-k2C,N)iridium(III) hexafluorophosphate complex, [C40H28F3IrN5O]PF6
  22. Crystal structure of catena-poly[aqua(μ6-piperazine-1,4-bisethanesulfonato-κ6N:N′:O:O′:O′′:O′′′)(μ2-pyrazinyl-κ2N:N′)disilver(I)sesquihydrate], C12H30Ag2N4O11S2
  23. Crystal structure of (E)-1-(2-nitrophenyl)-N-(o-tolyl)methanimine, C14H12N2O2
  24. Crystal structure of 4′-amino-3′,5′-diisopropyl-(1,1′-biphenyl)-4-carbonitrile, C19H22N2
  25. The crystal structure of poly[bis(N,N-dimethylformamide-κ1O)-tetrakis(μ2-cyanido-κ2C:N)dinickel(II)], C10H14N6O2Ni2
  26. Crystal structure of rac-trans-N,N′-bis(3-bromo-5-chlorosalicylidene)-1,2-cyclohexanediamine, C20H18Br2Cl2N2O2
  27. Crystal structure of rac-trans-N,N′-bis(3,5-dibromosalicylidene)-1,2-cyclohexanediamine, C20H18Br4N2O2
  28. The crystal structure of (dichromato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)nickel(II), C12H16N4O7Cr2Ni
  29. The crystal structure of 3-((1R,2S)-1-methylpyrrolidin-1-ium-2-yl)pyridin-1-ium tetrachloridozincate(II) monohydrate, C10H18Cl4ZnN2O
  30. Crystal structure of bis(μ2-azido-k2N,N)-bis(2-amino-1-(N-(3-bromosalicylaldiminato))ethane)-dicopper(II), C20H18Br4N2O2
  31. Crystal structure of (η6-1-methyl-4-isopropylbenzene)-[5-bromo-2-(2-pyridyl)phenyl-κ2C,N]-chloro-ruthenium(II), C21H21BrClNRu
  32. Crystal structure of N-(methyl(oxo)(1-(6-(trifluoromethyl)pyridin-3-yl)ethyl)-λ6-sulfanylidene)cyanamide, C10H10F3N3OS
  33. Crystal structure of 6,6′-((cyclohexane-1,2-diylbis(azanylylidene))bis(methanylylidene))bis(2-bromo-4-chlorophenolato-κ4N,N′,O,O′)nickel(II), C20H16Br2Cl2NiN2O2
  34. Redetermination of the crystal structure of catena-poly[aqua-(1,10-phenanthroline-κ2N,N′)-(μ2-tetraoxidomolybdato(VI)-κ2O:O′)manganese(II) monohydrate, C12H12N2O6MoMn
  35. The crystal structure tetrakis(μ2-o-chlorobenzoato-κ2O:O′)-bis(methanol-κ1O)dirhodium(II), C30H24Cl4O10Rh2
  36. Crystal structure of bis(2,3-diphenyltetrazolidine-5-thione-κ1S)-(nitrato-κ1O)-(nitrato-κ2O,O′)lead(II), C26H20N10O6S2Pb
  37. Crystal structure of bis(3-bromo-N-(1-(3-methylpyrazin-2-yl)ethylidene)benzohydrazonato-κ3O,N,N′)cadmium(II) hemihydrate, C28H25N8O2.5Br2Cd
  38. Crystal structure of catena-poly[tetrakis(μ2-trifluoroacetato-κ2O:O′)(μ2-2,5-dimethylpyrazine-κ2N,N′)dicopper(II)], C7H4CuF6NO4
  39. The crystal structure of catena-poly[bis[3-azoniapentane-1,5-diammonium][bis(μ4-oxo)-tetrakis(μ3-oxo)-heptakis(μ2-oxo)-tetradecaoxo-octa-molybdenum] dihydrate], (C8H36N6O29Mo8)n
  40. Crystal structure of tetraaqua-bis(2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-κO)-nickel(II)—diaqua-bis(2-((3,5,6-trichloropyridin-2-yl)oxy)acetato-nickel(II), C28H24Cl12N4Ni2O18
  41. The crystal structure of bis(2-hydroxypyrimidinium) pentachloridobismuthate(III), (C4N2H5O)2BiCl5
  42. The crystal structure of catena-poly[(μ2-4,4′-dipyridine-κ2N,N′)-bis(3,5,6-trichloropyridine-2-oxyacetato-κO)-bis(ethanol-κO)nickel(II)], C28H26Cl6N4NiO8
  43. Crystal structure and anti-inflammatory activity of (3E,5E)-1-((4-chlorophenyl)sulfonyl)-3,5-bis(4-fluorobenzylidene)piperidin-4-one-dichloromethane (1/1), C26H20Cl3F2NO3S
  44. The crystal structure of 5-bromopicolinic acid monohydrate, C6H6BrNO3
  45. The crystal structure of 2-(3-(4-bromophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl)-8H-indeno[1,2-d]thiazole, C25H17BrFN3S
  46. The crystal structure of catena-poly[(μ2-2-((3-bromo-2-oxidobenzylidene)amino)acetato-κ4O,N,O′:O′′)-(dimethylformamide-κ1O)]zinc(II), C12H13N2O4BrZn
  47. Crystal structure of aqua-azido-κ1N-(6,6′-((propane-1,3-diylbis(azanylylidene))bis(methanylylidene))bis(3-bromophenolato)-κ4N,N′,O,O′iron(III), C17H16Br2FeN5O3
  48. The crystal structure of tris(1-ethylimidazole-κ1N)-(sulfato-κ2O,O′)vanadium(IV), C15H24N6O5SV
  49. Crystal structure of (E)-3-methoxy-N′-(1-(pyridin-2-yl)ethylidene)benzohydrazide, C15H15N3O2
  50. Crystal structure of dichloro-bis-(1-butyl-1H-benzo[d]imidazole)-nickel(II), C22H28Cl2N4Ni
  51. The crystal structure of 2-(2,3-dimethoxyphenyl)-3-hydroxy-4H-chromen-4-one, C17H14O5
  52. The crystal structure of 5-(2-(4-fluorophenyl)hydrazono)-4-methyl-2-((3-(5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)methylene) hydrazono)-2,5-dihydrothiazole dimethylformamide monosolvate, C30H25FN10S⋅C3H7NO
  53. The crystal structure of 1,8-bis(pyridin-4-ylethynyl)anthracene-1,2,4,5-tetrafluoro-3,6-diiodobenzene (2/1), C62H32F4I2N4
  54. The crystal structure of 3,6-di-tert-butyl-1,8-diiodo-9-methyl-9H-carbazole, C21H25I2N
  55. The crystal structure of 8-((4-chlorophenylamino)methylene)-6,10-dioxaspiro[4.5]decane-7,9-dione, C15H14ClNO4
  56. The crystal structure of catena-poly[oktaaqua-bis(μ2-4,4′-ethene-1,2-diyldipyridine-κ2N:N′)-(μ2-3,3′-(1-oxidodiazene-1,2-diyl)diphthalato-κ2O:O′)dicobalt(II)] dihydrate, C28H36N4O19Co2
  57. Crystal structure of (E)-1-(2-cyano-3-oxo-1-phenylprop-1-en-1-yl)-3,7-diphenylindolizine-6-carbonitrile, C31H19N3O
  58. Crystal structure of 1,1′-bis(diphenylphosphino)ferrocene-(1,1′-bis(diphenylphosphino)ferrocene-κ2P,P′)-(O-isobutyl sulfurodithioito-κ2S,S′)copper(I), C39H37CuFeOP2S2
  59. Crystal structure of poly[(5-bimethylamino-1-naphthalenesulfonato-κO)-(μ3-hexamethylenetetramino-κ3N:N′:N′′)silver(I)] dihydrate, C36H52Ag2N10O8S2
  60. Crystal structure of poly[μ2-diaqua-(μ2-2-amino-4,5-dicyano-κ2N:N′-imidazol-1-ide)sodium(I)], C5H6N5O2Na
  61. Crystal structure of (1,3-propanediamine-κ2N,N′)(N-(3-aminopropyl)-α-methyl aspartato-κ4N,N′,O,O′)cobalt(III) chloride, C11H24ClCoN4O4
  62. Crystal structure and anti-inflammatory activity of (3E,5E)-3,5-bis(4-fluorobenzylidene)-1-((4-fluorophenyl)sulfonyl)piperidin-4-one-dichloromethane (1/1), C26H20Cl2F3NO3S
  63. Crystal structure of (S)-(+)-1-cyclohexylethylaminium chloride, C8H18NCl
  64. The crystal structure of tris(nitrato-κ2O,O′)-bis(4,4,5,5-tetramethyl-2-(o-pyridyl)imidazoline-1-oxyl 3-oxide-κ2N,O)yttrium(III), C24H32N9O13Y
  65. Hydrogen bonding versus packing effects in the crystal structure of 3-((1R,2S)-1-methylpyrrolidin-1-ium-2-yl)pyridin-1-ium tetraiodidozincate(II), C10H16I4ZnN2
  66. Dimerization of 2-[(2-((2-aminophenyl)thio)phenyl)amino]-cyclohepta-2,4,6-trien-1-one through hydrogen bonding, C19H16N2OS
  67. Crystal structure of 1-(4-chloro-phenyl)-7-ethoxyl-6,8-difluoro-4-oxo-1,4-dihydro-quinoline-3-carboxylic acid, C18H12ClF2NO4
  68. Crystal structure of 7-ethoxy-6,8-difluoro-4-oxo-1-pyridin-2-ylmethyl-1,4-dihydro-quinoline-3-carboxylic acid, C18H14F2N2O4
  69. Crystal structure of octahydro-7aR,8′R-dimethylspiro[isobenzofuran-4(1H), 4′ (3′H)-[1H-7,9a]methanocyclohepta[c]pyran]-1′,3, 9′ (3aH,4′aH)-trione, C20H26O5
  70. Crystal structure of bis(5-ethoxy-2-(((1-hydroxy-2-methyl-3-oxidopropan-2-yl)imino)methyl)phenolato-κ3N,O,O’)manganese(IV) – methanol (1/1), C27H38MnN2O9
  71. Crystal structure of 8a,8a′′-oxybis(8aH-8,9-dioxa-3a1λ4-aza-8aλ4-borabenzo[fg]tetracene), C34H22B2N2O5
  72. Crystal structure of bromido-triphenyl-(triphenylarsine oxide-κO)tin(IV), C36H30AsBrOSn
  73. Crystal structure of catena-poly[chlorido-(μ2-formato-κ2O:O′)-(1,10-phenathroline-κ2N,N′)copper(II)], C26H18Cl2Cu2N4O4
  74. The crystal structure of poly[(μ10-5-carboxyisophthalato-κ10O)disodium], C9H4Na2O6
  75. The crystal structure of 3,5-difluoroisonicotinic acid, C6H3F2NO2
  76. The crystal structure of ethyl-1-(N-(adamantan-1-yl)-carbamothioyl)piperidine-4-carboxylate, C19H30N2O2S
  77. Crystal structure of 5-methyl-3-phenyl-1-tosyl-1,2,3,4-tetrahydropyridine, C19H21NO2S
  78. Crystal structure of bis((3-chlorosalicylidene)-ethylenediaminato-κ4N,N′,O,O′)nickel (II), C16H12Cl2NiN2O2
  79. Crystal structure of (E)-N′-(2-chloro-6-hydroxybenzylidene)-4-hydroxybenzohydrazide — dihydrofuran-2(3H)-one (1/1), C18H17ClN2O5
  80. Crystal structure of bis((3-bromosalicylidene)-ethylenediaminato-κ4N,N′,O,O′) nickel (II), C16H12Br2NiN2O2
  81. Crystal structure of trimethylsulfoxonium tetrachloridocobaltate(II) [(CH3)3SO]2CoCl4
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