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Thermal evolution of free volumes and of crystallization in amorphous Si–B–C–N ceramics

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Veröffentlicht/Copyright: 31. Mai 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 97 Heft 5

Abstract

We report on the crystallization behavior of initially amorphous precursor-derived Si3B1C4.3N2 ceramics, making use of macroscopic and atomic scale investigation techniques. As derived from our kinetic studies upon heating, the following temperature sequence of solid state processes is observed with approximately the same kinetic time constants: after an initial densification in the amorphous state (1673K), crystallization occurs (1873K) with subsequent strain relaxation and disappearance of nanovoids (2073K). This behavior indicates an increasing activation enthalpy of the atomic mechanisms giving rise to these processes when the annealing temperature is increased. The nanovoids may be located in the turbostratic BNCx layers as derived from positron annihilation studies. For grain growth at high temperatures an activation energy of HG=3.9eV is derived.

Keywords: Amorphous ceramics; Nanovoids; Crystallization behavior; Positron annihilation
* Correspondence address: Dr. Klaus J. Reichle, Walbertsweiler, Raster Str. 20, D-88639 Wald, Germany, Tel.: +497578933171, Fax: +49121266633557799. E-mail:

Dedicated to Professor Dr. Fritz Aldinger on the occasion of his 65th birthday

References

[1] R.Riedel, A.Kienzle, W.Dreßler, L.M.Ruwisch, J.Bill, F.Aldinger: Nature382 (1996) 796.10.1038/382796a0Suche in Google Scholar

[2] T.W.Kamphowe, M.Weinmann, J.Bill, F.Aldinger: Silic. Ind.63 (1998) 159.Suche in Google Scholar

[3] E.Butchereit, K.G.Nickel, A.Müller: J. Am. Ceram. Soc.84 (2001) 2184; M. Weinmann, J. Schuhmacher, H. Kummer, S. Prinz, J. Peng, H. J. Seifert, M. Christ, K. Müller, J. Bill, F. Aldinger, Chem. Mater. 12 (2000) 623.10.1111/j.1151-2916.2001.tb00985.xSuche in Google Scholar

[4] Z.-C.Wang, F.Aldinger, R.Riedel: J. Am. Ceram. Soc.84 (2001) 2179.10.1111/j.1151-2916.2001.tb00984.xSuche in Google Scholar

[5] A.Müller, A.Zern, P.Gerstel, J.Bill, F.Aldinger: J. Europ. Ceram. Soc.22 (2002) 1631.10.1016/S0955-2219(01)00480-0Suche in Google Scholar

[6] A.Müller, P.Gerstel, M.Weinmann, J.Bill, F.Aldinger: Chem. Mater.14 (2002) 3398.10.1021/cm021178iSuche in Google Scholar

[7] A.Müller, J.Peng, H.J.Seifert, J.Bill, F.Aldinger: Chem. Mater.14 (2002) 3406.10.1021/cm021179aSuche in Google Scholar

[8] B.Baufeld, H.Gu, J.Bill, F.Wakai, F.Aldinger: J. Europ. Ceram. Soc.19 (1999) 2797.10.1016/S0955-2219(99)00079-5Suche in Google Scholar

[9] A.Bauer, M.Christ, A.Zimmermann, F.Aldinger: J. Am. Ceram. Soc.84 (2001) 2203.10.1111/j.1151-2916.2001.tb00988.xSuche in Google Scholar

[10] M.Christ, G.Thurn, M.Weinmann, J.Bill, F.Aldinger: J. Am. Ceram. Soc.83 (2000) 3025.10.1111/j.1151-2916.2000.tb01678.xSuche in Google Scholar

[11] M.Christ, A.Zimmermann, F.Aldinger: J. Mater. Res.16 (2001) 1994.10.1557/JMR.2001.0273Suche in Google Scholar

[12] A.Zimmermann, A.Bauer, M.Christ, Y.Cai, F.Aldinger: Acta Mater.50 (2002) 1187.10.1016/S1359-6454(01)00420-7Suche in Google Scholar

[13] W.Sprengel, F.Baier, K.Sato, X.Y.Zhang, H.-E.Schaefer, in:Quasicrystals: Structure and Properties, (Wiley-VCH, Weinheim, 2003) 414.Suche in Google Scholar

[14] M.J.Puska, C.Corbel: Phys. Rev. B63 (1988) 9875.Suche in Google Scholar

[15] G.Amarendra, R.Rajaraman, G.Venugopal, K.G.M.Nair, B.Viswanathan, R.Suzuki, T.Ohdaira, T.Mikado: Phys. Rev.B63 (2001) 224112.Suche in Google Scholar

[16] A.A.Rempel, W.Sprengel, K.Blaurock, K.J.Reichle, J.Major, H.-E.Schaefer: Phys. Rev. Lett.89 (2002) 185501.10.1103/PhysRevLett.89.185501Suche in Google Scholar

[17] X.Y.Zhang, W.Sprengel, T.E.M.Staab, H.Inui, H.-E.Schaefer: Phys. Rev. Lett.92 (2004) 155502.10.1103/PhysRevLett.92.155502Suche in Google Scholar

[18] P.Kirkegaard, M.Eldrup: Comput. Phys. Commun.7 (1974) 401.10.1016/0010-4655(74)90070-8Suche in Google Scholar

[19] P.Kirkegaard, M.Eldrup, O.E.Mogensen, D.J.Pedersen: Comput. Phys. Commun.23 (1981) 307.10.1016/0010-4655(81)90006-0Suche in Google Scholar

[20] P.Kirkegaard, N.J.Pedersen, M.Eldrup, Patfit-88: A Data-Processing System for Positron Annihilation Spectra on Mainframe and Personal Computers (1989).Suche in Google Scholar

[21] A.Jalowiecki, J.Bill, F.Aldinger, J.Mayer: CompositesA27 (1996) 717.Suche in Google Scholar

[22] J.Bill, J.Schuhmacher, K.Müller, S.Schempp, J.Seitz, J.Dürr, H.-P.Lamparter, J.Golczewski, J.Peng, H.J.Seifert, F.Aldinger: Z. Metallkd.91 (2000) 335.Suche in Google Scholar

[23] Y.Cai, S.Prinz, A.Zimmermann, A.Zern, W.Sigle, M.Rühle, F.Aldinger: Scr. Mater.47 (2002) 7.10.1016/S1359-6462(02)00087-8Suche in Google Scholar

[24] H.-J.Seifert, H.-L.Lukas, F.Aldinger: Ber. Bunsen-Ges. Phys. Chem. Chem. Phys.102 (1998) 1309.Suche in Google Scholar

[25] G.K.Williamson, W.H.Hall: Acta Metall.1 (1953) 22.10.1016/0001-6160(53)90006-6Suche in Google Scholar

[26] J.Schuhmacher, F.Berger, M.Weinmann, J.Bill, F.Aldinger, K.Müller: Appl. Organometal. Chem15 (2001) 809.10.1002/aoc.235Suche in Google Scholar

[27] K.J.Reichle: Ph.D. thesis, University of Stuttgart, Germany (2003).Suche in Google Scholar

[28] P.Feltham: Acta Metall.5 (1957) 97.10.1016/0001-6160(57)90136-0Suche in Google Scholar

[29] L.E.Murr: Interfacial phenomena in metals and alloys (Reading, Mass., Addison-Wesley, 1975).Suche in Google Scholar

[30] L.-T.Voss: Ph.D. thesis, University of Stuttgart, Germany (2002).Suche in Google Scholar

[31] H.Schmidt, G.Borchardt, S.Weber, S.Scherrer, H.Baumann, A.Müller, J.Bill: J. Appl. Phys.88 (2000) 1827.10.1063/1.1305903Suche in Google Scholar

[32] T.W.Kamphowe: Ph.D. thesis, University of Stuttgart, Germany (1999).Suche in Google Scholar

Received: 2005-10-31
Accepted: 2006-2-5
Published Online: 2013-05-31
Published in Print: 2006-05-01

© 2006, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Editorial
  5. Basic
  6. Three-dimensional printing of TiAl3/Al2O3 composites
  7. Microemulsion mediated synthesis of nanocrystalline BaTiO3: possibilities, potential and perspectives
  8. Solid-State 17O NMR studies on Yttria-stabilized zirconia
  9. Twinning in ultrathin silicon nanowires
  10. Re-optimization of the Mg–Sb system under topological constraints
  11. Mg-rich phase equilibria of Mg–Mn–Zn alloys analyzed by computational thermochemistry
  12. The In–Pt–Sb phase diagram
  13. Thermodynamic evaluation of the Al–Cr–C system
  14. Thermodynamic description of the Ni–Si–Ti ternary system
  15. Enthalpies of formation measurements and thermodynamic description of the Ag–Cu–Zn system
  16. Thermodynamic assessment of the Mn–Cr–O system for solid oxide fuel cell (SOFC) materials
  17. Subsolidus phase equilibria in the CeO2−x–SiO2–ZrO2 system: An experimental study
  18. Generalized Maugis–Dugdale model of an elastic cylinder in non-slipping adhesive contact with a stretched substrate
  19. Implications of linear relationships between local and macroscopic flow stresses in the composite model
  20. Applied
  21. Gas-phase surface alloying under “kinetic control”: A novel approach to improving the surface properties of titanium alloys
  22. Thin film formation by oriented attachment of polymer-capped nanocrystalline ZnO
  23. The sintering mechanism and microstructure evolution in SiC–AlN ceramics studiedby EFTEM
  24. Thermal evolution of free volumes and of crystallization in amorphous Si–B–C–N ceramics
  25. High-temperature deformation behavior of nanocrystalline precursor-derived Si–B–C–N ceramics in controlled atmosphere
  26. Nanopowder dispersion and spray-drying process: the case of Cr2O3
  27. Electroless deposition of brushite (CaHPO4 · 2H2O) crystals on Ti–6Al–4V at room temperature
  28. The role of chemisorbed anions in the aqueous processing of AlN powder
  29. The influence of porosity on the electrical properties of liquid-phase sintered silicon carbide
  30. Development of high-temperature thermoelectric materials based on SrTiO3-layered perovskites
  31. The influence of the preparation method on the microstructure and properties of Al2O3/TiN nanocomposites
  32. Infrared properties of sintered α-MnSe
  33. Quasi-equilibrium sintering of particle clusters containing Bernal holes
  34. Design of metal ceramic composites
  35. Notifications
  36. DGM News
https://doi.org/10.3139/146.101280
Schlagwörter für diesen Artikel
Amorphous ceramics; Nanovoids; Crystallization behavior; Positron annihilation

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Editorial
  5. Basic
  6. Three-dimensional printing of TiAl3/Al2O3 composites
  7. Microemulsion mediated synthesis of nanocrystalline BaTiO3: possibilities, potential and perspectives
  8. Solid-State 17O NMR studies on Yttria-stabilized zirconia
  9. Twinning in ultrathin silicon nanowires
  10. Re-optimization of the Mg–Sb system under topological constraints
  11. Mg-rich phase equilibria of Mg–Mn–Zn alloys analyzed by computational thermochemistry
  12. The In–Pt–Sb phase diagram
  13. Thermodynamic evaluation of the Al–Cr–C system
  14. Thermodynamic description of the Ni–Si–Ti ternary system
  15. Enthalpies of formation measurements and thermodynamic description of the Ag–Cu–Zn system
  16. Thermodynamic assessment of the Mn–Cr–O system for solid oxide fuel cell (SOFC) materials
  17. Subsolidus phase equilibria in the CeO2−x–SiO2–ZrO2 system: An experimental study
  18. Generalized Maugis–Dugdale model of an elastic cylinder in non-slipping adhesive contact with a stretched substrate
  19. Implications of linear relationships between local and macroscopic flow stresses in the composite model
  20. Applied
  21. Gas-phase surface alloying under “kinetic control”: A novel approach to improving the surface properties of titanium alloys
  22. Thin film formation by oriented attachment of polymer-capped nanocrystalline ZnO
  23. The sintering mechanism and microstructure evolution in SiC–AlN ceramics studiedby EFTEM
  24. Thermal evolution of free volumes and of crystallization in amorphous Si–B–C–N ceramics
  25. High-temperature deformation behavior of nanocrystalline precursor-derived Si–B–C–N ceramics in controlled atmosphere
  26. Nanopowder dispersion and spray-drying process: the case of Cr2O3
  27. Electroless deposition of brushite (CaHPO4 · 2H2O) crystals on Ti–6Al–4V at room temperature
  28. The role of chemisorbed anions in the aqueous processing of AlN powder
  29. The influence of porosity on the electrical properties of liquid-phase sintered silicon carbide
  30. Development of high-temperature thermoelectric materials based on SrTiO3-layered perovskites
  31. The influence of the preparation method on the microstructure and properties of Al2O3/TiN nanocomposites
  32. Infrared properties of sintered α-MnSe
  33. Quasi-equilibrium sintering of particle clusters containing Bernal holes
  34. Design of metal ceramic composites
  35. Notifications
  36. DGM News
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