Startseite Hydrothermal synthesis and crystal structure of aqua-tris(4-acetamidobenzoato-κ2 O,O′)-(1,10-phenanthroline-κ2 N,N′)terbium(III) hydrate C39H36N5O11Tb
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Hydrothermal synthesis and crystal structure of aqua-tris(4-acetamidobenzoato-κ2 O,O′)-(1,10-phenanthroline-κ2 N,N′)terbium(III) hydrate C39H36N5O11Tb

  • Yu-Xuan Xia , Zhuo-Wen Xu , Wei Li ORCID logo EMAIL logo und Chang-Hong Li EMAIL logo
Veröffentlicht/Copyright: 28. März 2024
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 239 Heft 3

Abstract

C39H36N5O11Tb, triclinic, P 1 ‾ (no. 2), a = 10.3365(12) Å, b = 13.0194(15) Å, c = 15.2064(18) Å, α = 108.769(2)°, β = 94.694(2)°, γ = 100.882(2)°, V = 1880.2(4) Å3, Dc = 1.607 g/cm3, Z = 2, Rgt (F) = 0.0315, wRref (F 2) = 0.0836, T = 296.15 K.

CCDC no.: 2326332

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colorless block
Size: 0.22 × 0.20 × 0.18 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 1.95 mm−1
Diffractometer, scan mode: Bruker SMART, φ and ω-scans
θ max, completeness: 25°, >99 %
N(hkl)measured, N(hkl)unique, R int: 19,718, 6629, 0.084
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 6210
N(param)refined: 511
Programs: Olex2 [8], Shelx [9, 10]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

x y z U iso*/U eq
Tb1 1.07767 (2) 0.30084 (2) 0.36652 (2) 0.02586 (8)
O8 1.1005 (2) 0.3378 (2) 0.21827 (18) 0.0419 (6)
O4 1.1685 (2) 0.21834 (18) 0.47830 (16) 0.0345 (5)
O2 0.8872 (2) 0.3166 (2) 0.45265 (18) 0.0401 (6)
O7 0.8991 (3) 0.2941 (3) 0.25006 (19) 0.0503 (7)
O11 1.1183 (3) 0.4987 (2) 0.40126 (19) 0.0547 (8)
H11A 1.123930 0.542416 0.366189 0.082*
H11B 1.117799 0.546726 0.456899 0.082*
O5 1.1813 (3) 0.39790 (19) 0.53090 (17) 0.0412 (6)
O1 0.9043 (2) 0.15059 (19) 0.3663 (2) 0.0427 (6)
O3 0.2572 (3) −0.1510 (2) 0.3414 (3) 0.0640 (9)
O6 1.3110 (5) 0.1404 (4) 0.9029 (3) 0.1039 (14)
O9 0.6163 (4) 0.4661 (3) −0.0810 (3) 0.0804 (11)
N2 1.3189 (3) 0.3096 (2) 0.34066 (19) 0.0296 (6)
N1 1.1193 (3) 0.1272 (2) 0.2479 (2) 0.0374 (7)
N3 0.2954 (3) 0.0352 (2) 0.4200 (2) 0.0381 (7)
H3 0.255328 0.086276 0.447158 0.046*
N4 1.3214 (4) 0.3214 (3) 0.9214 (2) 0.0509 (8)
H4 1.336464 0.386896 0.963228 0.061*
N5 0.7547 (4) 0.3608 (4) −0.1425 (3) 0.0724 (12)
H5 0.784286 0.329110 −0.193211 0.087*
C22 1.1911 (3) 0.3104 (3) 0.5469 (2) 0.0283 (7)
C12 1.3497 (3) 0.2198 (3) 0.2776 (2) 0.0321 (7)
C31 0.9765 (4) 0.3183 (3) 0.1955 (3) 0.0340 (8)
C3 1.0400 (6) −0.0525 (4) 0.1278 (4) 0.0846 (18)
H3A 0.968186 −0.110445 0.093447 0.102*
C39 0.6233 (5) 0.4222 (5) −0.2447 (3) 0.0719 (14)
H39A 0.700952 0.452884 −0.266478 0.108*
H39B 0.560153 0.468249 −0.241220 0.108*
H39C 0.583700 0.348314 −0.287575 0.108*
C17 0.4337 (3) 0.0716 (3) 0.4229 (3) 0.0343 (7)
C4 1.1674 (6) −0.0562 (4) 0.1103 (4) 0.0807 (17)
H4A 1.182693 −0.118263 0.064716 0.097*
C34 0.7265 (4) 0.3209 (4) 0.0012 (3) 0.0477 (9)
H34 0.634573 0.309481 −0.013304 0.057*
C23 1.2282 (3) 0.3141 (3) 0.6443 (2) 0.0312 (7)
C29 1.3304 (5) 0.2380 (4) 0.9548 (3) 0.0623 (12)
C14 0.7008 (3) 0.1642 (3) 0.4258 (2) 0.0322 (7)
C8 1.4814 (4) 0.2191 (3) 0.2583 (3) 0.0398 (8)
C19 0.6236 (3) 0.2270 (3) 0.4803 (2) 0.0353 (7)
H19 0.660976 0.300454 0.518191 0.042*
C9 1.5809 (4) 0.3163 (4) 0.3056 (3) 0.0471 (10)
H9 1.668663 0.319430 0.295059 0.056*
C13 0.8381 (3) 0.2132 (3) 0.4156 (2) 0.0310 (7)
C25 1.2861 (5) 0.2215 (3) 0.7517 (3) 0.0469 (10)
H25 1.303370 0.157944 0.761090 0.056*
C32 0.9179 (4) 0.3270 (3) 0.1061 (2) 0.0350 (8)
C18 0.4914 (3) 0.1814 (3) 0.4788 (3) 0.0356 (8)
H18 0.440278 0.224494 0.515464 0.043*
C1 1.2447 (3) 0.1239 (3) 0.2287 (2) 0.0354 (7)
C37 0.9992 (4) 0.3500 (3) 0.0432 (3) 0.0456 (9)
H37 1.090907 0.358755 0.056469 0.055*
C11 1.4158 (4) 0.3987 (3) 0.3828 (3) 0.0400 (8)
H11 1.395103 0.460471 0.425567 0.048*
C33 0.7816 (4) 0.3109 (3) 0.0832 (3) 0.0406 (8)
H33 0.725868 0.292932 0.123729 0.049*
C35 0.8085 (5) 0.3480 (4) −0.0588 (3) 0.0537 (11)
C2 1.0210 (5) 0.0401 (3) 0.1985 (3) 0.0579 (12)
H2 0.934988 0.041343 0.211828 0.069*
C24 1.2560 (4) 0.2210 (3) 0.6620 (3) 0.0403 (8)
H24 1.254019 0.156854 0.611511 0.048*
C38 0.6623 (4) 0.4176 (4) −0.1495 (3) 0.0519 (10)
C26 1.2910 (4) 0.3162 (3) 0.8285 (3) 0.0403 (8)
C28 1.2349 (4) 0.4088 (3) 0.7212 (3) 0.0393 (8)
H28 1.219055 0.472728 0.711807 0.047*
C20 0.2168 (4) −0.0684 (3) 0.3806 (3) 0.0462 (10)
C10 1.5474 (4) 0.4054 (4) 0.3668 (3) 0.0472 (9)
H10 1.611893 0.470595 0.397883 0.057*
C15 0.6432 (3) 0.0528 (3) 0.3729 (3) 0.0402 (8)
H15 0.694951 0.009081 0.337474 0.048*
C5 1.2740 (5) 0.0322 (3) 0.1602 (3) 0.0534 (10)
C27 1.2644 (4) 0.4095 (3) 0.8110 (3) 0.0458 (9)
H27 1.266818 0.473745 0.861389 0.055*
C7 1.5083 (5) 0.1224 (4) 0.1929 (3) 0.0533 (11)
H7 1.595703 0.120420 0.183346 0.064*
C16 0.5120 (4) 0.0062 (3) 0.3720 (3) 0.0441 (9)
H16 0.476110 −0.068621 0.337388 0.053*
C30 1.3616 (7) 0.2708 (5) 1.0590 (4) 0.0810 (17)
H30A 1.414128 0.345832 1.084764 0.121*
H30B 1.410634 0.221481 1.074180 0.121*
H30C 1.280076 0.266143 1.085059 0.121*
C36 0.9452 (4) 0.3600 (4) −0.0386 (3) 0.0570 (11)
H36 1.000321 0.374699 −0.080561 0.068*
C21 0.0722 (4) −0.0748 (4) 0.3920 (4) 0.0628 (13)
H21A 0.016688 −0.124007 0.334526 0.094*
H21B 0.054311 −0.001919 0.406769 0.094*
H21C 0.053432 −0.102733 0.441964 0.094*
C6 1.4081 (5) 0.0330 (4) 0.1442 (4) 0.0613 (12)
H6 1.427070 −0.028346 0.099899 0.074*
O10 0.0912 (4) −0.3562 (3) 0.2993 (4) 0.0839 (12)
H10A 0.118998 −0.286100 0.314716 0.126*
H10B 0.008815 −0.365329 0.304157 0.126*

1 Introduction

Complexes constructed by aromatic carboxylic acids and metal ions have shown potential application value in many fields [1], [2], [3], [4]. p-Acetamidobenzoic acid is not only an important chemical raw material, widely used in fuel, medicine and other industries and other fields, but also as an important organic synthesis intermediate, which can be esterified to produce a series of compounds [1, 5]. It is also an important material for the synthesis of quinazolin-4-one derivatives of non-barbiturate hypnosedative drugs, fluorescent whitening agents and anti-asthmatic drugs N-cinnamyl anthranilic acid [6]. p-Acetamidobenzoic acid also acts as an aromatic carboxylic acid ligand, which can coordinate with metal ions due to its multiple coordination sites (nitrogen and oxygen atoms), and is also the giver and acceptor of hydrogen bonds to form functional complexes with stable structures [7]. The single crystal structure analysis revealed that the title compound crystallized in the orthorhombic space group P 1 ‾ . The Ortep diagram is presented in the figure. Bond lengths and angles are all in the expected ranges. There is only one molecule in the asymmetric unit. As shown in figure, complex 1 consists of one Tb ion, three p-acetamidobenzoate anions, one 1,10-phenanthroline molecule, one coordinating water molecule and one free water molecule. The central Tb ion is coordinated with two nitrogen atoms from 1,10-phenanthroline molecules, and seven oxygen atoms from three acid anions and one water molecule. The Tb(III) ion adopts a single-capped square antiprism coordination geometry, where the cap position is occupied by O8. Atoms N1, O7, O11 and N2 give the upper plane of the square antiprism, and atoms O1, O2, O5 and O4 determine the plane below. Their plane equations are −3.321x + −5.831y + 14.384z = 1.5663 and −2.969x + −6.064y + 14.479z = −0.6825, where the average distance of all the atoms in the plane is 0.1556 Å and 0.1635 Å respectively, and their dihedral angle is 2.1°. The bond lengths Tb1–O1, Tb1–O2, Tb1–O4, Tb1–O5, Tb1–O7, Tb1–O8 and Tb1–O11 are 2.389(2), 2.457(2), 2.494(2), 2.452(2), 2.419(3), 2.472(2) and 2.402(2) Å, respectively, which are in the normal ranges. The bond lengths of Tb1–N1 and Tb1–N2 are 2.534(3) and 2.543(3) Å, with the average to be 2.5385 Å. Otherwise, the shortest center distance between aromatic cycles of 2-(tert-pentyl)anthracene group is 3.610 Å, shorter than 3.700 Å, indicating π–π stacking interaction between the aromatic cycles [8].

2 Experimental

The H atoms bound to C atoms were placed in idealized positions and treated as riding on their parent atoms, with d (C–H) = 0.96 Å (methylene), with U iso(H) = 1.5U eq(C), and d(C–H) = 0.93 Å (aromtic), with U iso(H) = 1.2U eq(C).

2.1 Refinement

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Corresponding authors: Wei Li, Department of Chemistry and materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China, E-mail: ; and Chang-Hong Li, Department of Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421002, China, E-mail:

Acknowledgments

We gratefully acknowledge support by Natural Science Foundation of Hunan Province for financial support (grant No. 2023JJ50107).

References

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Received: 2024-01-23
Accepted: 2024-03-01
Published Online: 2024-03-28
Published in Print: 2024-06-25

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of tris((Z)-2-hydroxy-N-((E)-pyridin-2-ylmethylene)benzohydrazonato-k2O,N)europium(III), C39H30N9O6Eu
  4. Crystal structure of (E)-3-(benzylideneamino)-2-phenylthiazolidin-4-one, C16H14N2OS
  5. The crystal structure of (E)-4-fluoro-N′-(1-(o-tolyl)ethylidene)benzohydrazide, C16H15FN2O
  6. Crystal structure of (6-chloropyridin-3-yl)methyl 2-(6-methoxynaphthalen-2-yl)propanoate, C20H18ClNO3
  7. Crystal structure of methyl 3-methoxy-4-(2-methoxy-2-oxoethoxy)benzoate, C12H14O6
  8. The crystal structure of bis[(4-methoxyphenyl)(picolinoyl)amido-κ2 N:N′]copper(II), C26H22CuN4O4
  9. The crystal structure of poly[di(μ2-aqua)-diaqua-bis(3-aminopyridine-4-carboxylate-κ2 O: O′)-tetra(μ2-3-aminopyridine-4-carboxylate-κ2 O: O′)-dineodymium(III), [Nd2(C6H5N2O2)6(H2O)4] n
  10. The crystal structure of t-butyl 7-[3-(4-fluorophenyl)-1-(propan-2-yl)-1H-indol-2-yl]-3,5-dihydroxyhept-6-enoate, C28H34FNO4
  11. Crystal structure of catena-poly[(benzylamine-κ1 N)-(sorbato-κ1 O)-(μ2-sorbato-κ2 O,O′)-copper(II), C19H23CuNO4
  12. Crystal structure of (4-(2-chlorophenyl)-1H-pyrrol-3-yl)(ferrocenyl) methanone, C21H16ClFeNO
  13. The crystal structure of N-[4-(4-bromophenyl)-1,3-thiazol-2-yl]-3-(2-methylphenyl)-2-sulfanylprop-2-enamide hydrate, C19H17BrN2O2S2
  14. The crystal structure of N′-{5-[2-(2,6-dimethylphenoxy) acetamido]-4-hydroxy-1,6-diphenylhexan-2-yl}-3-methyl-2-(2-oxo-1,3-diazinan-1-yl)butanamide hydrate
  15. Crystal structure of 2-(naphthalen-1-yl)ethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C26H24O3
  16. Crystal structure of naphthalen-1-ylmethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C25H22O3
  17. Crystal structure of poly[diaqua- (μ4-5-(1H-1,2,4-triazol-1-yl)benzene-1,3-dicarboxylato-κ5N:O,O’:O’’:O’’’)calcium(II), C10H9CaN3O6
  18. Crystal structure of (E)-N′-(4-((E)-3-(dimethylamino)acryloyl)-3-hydroxyphenyl)-N, N-dimethylformimidamide, C14H19N3O2
  19. Crystal structure of (E)-3-(dimethylamino)-1-(2-hydroxy-4,6-dimethoxyphenyl)prop-2-en-1-one, C13H17NO4
  20. Crystal structure of (2-chloropyridin-3-yl)methyl-2-(6-methoxynaphthalen-2-yl)propanoate, C20H18ClNO3
  21. The crystal structure of diethyl 4-(3,4-dimethylphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate, C21H27NO4
  22. Crystal structure of (8R,9S,10R,13S,14S,17S)-17-hydroxy-10,13-dimethyl-17-((4-(2-phenylpropyl)phenyl)ethynyl)-1,2,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-3H-cyclopenta[a]phenanthren-3-one, C36H42O2
  23. Synthesis and crystal structure of 4-(4-cyclopropylnaphthalen-1-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione, C15H13N3S
  24. Crystal structure of catena-poly[aqua-(2,6-di-(2-pyridyl)-pyridine-κ3 N,N′, N″)(μ2-1,4-naphthalene dicarboxylato-κ2 O,O′)nickel(II)], C27H19NiN3O5
  25. Crystal structure of 3-(diphenylphosphoryl)-3-hydroxy-1-phenylpropan-1-one, C21H19O3P
  26. The crystal structure of R,S-{N-[(2-oxidonaphthalen-1-yl)methylidene]phenylglycinato}divinylsilicon, C23H19NO3Si
  27. The crystal structure of 1,2,4-tris(bromomethyl)benzene, C9H9Br3
  28. Crystal structure of chlorido-[4-(pyridin-2-yl)benzaldehyde-κ2 N,C]-(diethylamine-κ1 N)platinum(II), C16H18ClN2OPt
  29. Crystal structure of 3-(methoxycarbonyl)-1-(4-methoxyphenyl)-2,3,4,9- tetrahydro-1H-pyrido[3,4-b]indol-2-ium chloride hydrate, C40H48Cl2N4O9
  30. The crystal structure of 1-(2-chlorobenzyl)-3-(3-chlorophenyl)urea, C14H12Cl2N2O
  31. Hydrothermal synthesis and crystal structure of aqua-tris(4-acetamidobenzoato-κ2 O,O′)-(1,10-phenanthroline-κ2 N,N′)terbium(III) hydrate C39H36N5O11Tb
  32. The crystal structure of zwitterionic 3-aminoisonicotinic acid, C6H6N2O2
  33. The crystal structure of bis{[monoaqua-μ2-4-[(pyridine-4-carbonyl)-amino]-phthalato-κ3 N:O,O′-(2,2′-bipyridine κ2 N,N′)copper(II)]}decahydrate, C48H56N8O22Cu2
  34. Crystal structure of poly[μ10-4,4′-methylene-bis(oxy)benzoatodipotassium], C15H10K2O6
  35. The crystal structure of catena-poly[[tetraaqua[(μ2-1,4-di(4-methyl-1-imidazolyl)benzene] cobalt(II)]bis(formate)], C16H24CoN4O8
  36. The crystal structure of (E)-2-chloro-5-((2-(nitromethylene)imidazolidin-1-yl)methyl)pyridine, C10H11ClN4O2
  37. The crystal structure of (E)-1-(((2-amino-4,5-dimethylphenyl)iminio)methyl)naphthalen-2-olate, C19H18N2O
  38. Crystal structure of N-(acridin-9-yl)-2-(4-methylpiperidin-1-yl) acetamide monohydrate, C21H25N3O2
  39. The crystal structure of dichlorido-bis(3-methyl-3-imidazolium-1-ylpropionato-κ2 O,O′)-zinc(II), C14H20Cl2N4O4Zn
  40. The crystal structure of 2,8-diethyl-1,3,7,9-tetramethyl-4λ4,5λ4-spiro[dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine-5,2′-naphtho[1,8-de][1,3,2]dioxaborinine], C25H29BN2O2
  41. The crystal structure of 5-tert-butyl-2-(5-tert-butyl-3-iodo-benzofuran-2-yl)-3-iodobenzofuran, C24H24I2O2
  42. Synthesis and crystal structure of methyl 2-{[4-(4-cyclopropyl-1-naphthyl)-4H-1,2,4-triazole-3-yl]thio} acetate, C18H17N3O2S
  43. The crystal structure of n-propylammonium bis(2,3-dimethylbutane-2,3-diolato)borate-boric acid (1/1), [C3H10N][C12H24BO4]·B(OH)3
  44. Crystal structure of methyl 1-(2-bromophenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C19H17BrN2O2
  45. Crystal structure of (4-bromobenzyl)triphenylphosphonium bromide ethanol solvate, C52H48Br4OP2
  46. The crystal structure of unsymmetrical BOPHY C26H27BN4
  47. The crystal structure of Tb3B5O11(OH)2
  48. The crystal structure of (Z)-4-ethyl-2-((4-ethyl-3,5-dimethyl-1H-pyrrol-2-yl)methylene)-3,5-dimethyl-2H-pyrrol-1-ium 2,2'-spirobi[naphtho[1,8-de][1,3,2]dioxaborinin]-2-uide, C37H37BN2O4
  49. Crystal structure of bis(methylammonium) hexadecaselenidopalladate(II), (CH3NH3)2PdSe16
  50. The crystal structure of (2-diphenylphosphanylphenyl) 2-[7-(dimethylamino)-2-oxochromen-4-yl]acetate, C31H26NO4P
  51. Crystal structure of (E)-6-(4-ethylpiperazin-1-yl)-2-(3-fluorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C23H25FN2O
  52. The structure of RUB-56, (C6H16N)8 [Si32O64(OH)8]·32 H2O, a hydrous layer silicate (2D-zeolite) that contains microporous levyne-type silicate layers
  53. Crystal structure of 4-amino-3,5-dibromobenzonitrile, C7H4Br2N2
  54. Crystal structure of 2-(naphthalen-1-yl)ethyl 2-acetoxybenzoate, C21H18O4
  55. Single-crystal structure determination of Tm3B12O19(OH)7
  56. Crystal structure determination of NdB3.6O7
  57. The crystal structure of NdB6O8(OH)5·H3BO3
  58. Crystal structure of 2-(5-ethylpyridin-2-yl)ethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H25NO3
  59. Crystal structure of N-(1-(3,4-dimethoxyphenyl)-2-methylpropyl)aniline, C18H23NO2
  60. Crystal structure of Ba6Cd12Mn4SiF48
  61. Synthesis and crystal structure of 5-fluoro-1-methyl-2-oxo-3-(2-oxochroman-4-yl)indolin-3-yl acetate, C20H16FNO5
  62. The crystal structure of 6-methacryloylbenzo[d][1,3]dioxol-5-yl 4-nitrobenzenesulfonate, C17H13NO8S
  63. Crystal structure of ethyl 2-(3-benzyl-4-oxo-3,4-dihydrophthalazin-1-yl)- 2,2-difluoroacetate, C19H16F2N2O3
  64. The crystal structure of tetrakis(μ 2-(1H-benzimidazole-2-methoxo-κ2 N,O:O:O)-(n-butanol-κO)-chlorido)-tetranickel(II), C48H68Cl4N8O8Ni4
  65. Synthesis and crystal structure of trans-tetraaqua-bis((1-((7-hydroxy-3-(4-methoxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carbonyl)oxy-κO)zinc(II)hexahydrate, C46H64N2O28S2Zn
  66. The crystal structure of 1-(4-carboxybutyl)-3-methyl-1H-imidazol-3-ium hexafluoridophosphate, C9H15F6N2O2P
  67. Crystal structure of 1-(4-chlorophenyl)-4-(2-furoyl)-3-phenyl-1H-pyrazol-5-ol, C20H13ClN2O3
  68. Crystal structure of dimethyl (R)-2-(3-(1-phenylethyl)thioureido)-[1,1′-biphenyl]-4,4′-dicarboxylate, C25H24N2O4S
  69. The crystal structure of 1-(3-carboxypropyl)-1H-imidazole-3-oxide, C7H10N2O3
  70. Synthesis and crystal structure of dimethyl 4,4′-(propane-1,3-diylbis(oxy))dibenzoate, C19H20O6
  71. Crystal structure of methyl-1-(p-tolyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C20H20N2O2
  72. The crystal structure of 1-(1-adamantan-1-yl)ethyl-3-(3-methoxyphenyl)thiourea, C20H28N2OS
  73. The crystal structure of N,N′-carbonylbis(2,6-difluorobenzamide), C15H8F4N2O3
https://doi.org/10.1515/ncrs-2024-0039
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of tris((Z)-2-hydroxy-N-((E)-pyridin-2-ylmethylene)benzohydrazonato-k2O,N)europium(III), C39H30N9O6Eu
  4. Crystal structure of (E)-3-(benzylideneamino)-2-phenylthiazolidin-4-one, C16H14N2OS
  5. The crystal structure of (E)-4-fluoro-N′-(1-(o-tolyl)ethylidene)benzohydrazide, C16H15FN2O
  6. Crystal structure of (6-chloropyridin-3-yl)methyl 2-(6-methoxynaphthalen-2-yl)propanoate, C20H18ClNO3
  7. Crystal structure of methyl 3-methoxy-4-(2-methoxy-2-oxoethoxy)benzoate, C12H14O6
  8. The crystal structure of bis[(4-methoxyphenyl)(picolinoyl)amido-κ2 N:N′]copper(II), C26H22CuN4O4
  9. The crystal structure of poly[di(μ2-aqua)-diaqua-bis(3-aminopyridine-4-carboxylate-κ2 O: O′)-tetra(μ2-3-aminopyridine-4-carboxylate-κ2 O: O′)-dineodymium(III), [Nd2(C6H5N2O2)6(H2O)4] n
  10. The crystal structure of t-butyl 7-[3-(4-fluorophenyl)-1-(propan-2-yl)-1H-indol-2-yl]-3,5-dihydroxyhept-6-enoate, C28H34FNO4
  11. Crystal structure of catena-poly[(benzylamine-κ1 N)-(sorbato-κ1 O)-(μ2-sorbato-κ2 O,O′)-copper(II), C19H23CuNO4
  12. Crystal structure of (4-(2-chlorophenyl)-1H-pyrrol-3-yl)(ferrocenyl) methanone, C21H16ClFeNO
  13. The crystal structure of N-[4-(4-bromophenyl)-1,3-thiazol-2-yl]-3-(2-methylphenyl)-2-sulfanylprop-2-enamide hydrate, C19H17BrN2O2S2
  14. The crystal structure of N′-{5-[2-(2,6-dimethylphenoxy) acetamido]-4-hydroxy-1,6-diphenylhexan-2-yl}-3-methyl-2-(2-oxo-1,3-diazinan-1-yl)butanamide hydrate
  15. Crystal structure of 2-(naphthalen-1-yl)ethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C26H24O3
  16. Crystal structure of naphthalen-1-ylmethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C25H22O3
  17. Crystal structure of poly[diaqua- (μ4-5-(1H-1,2,4-triazol-1-yl)benzene-1,3-dicarboxylato-κ5N:O,O’:O’’:O’’’)calcium(II), C10H9CaN3O6
  18. Crystal structure of (E)-N′-(4-((E)-3-(dimethylamino)acryloyl)-3-hydroxyphenyl)-N, N-dimethylformimidamide, C14H19N3O2
  19. Crystal structure of (E)-3-(dimethylamino)-1-(2-hydroxy-4,6-dimethoxyphenyl)prop-2-en-1-one, C13H17NO4
  20. Crystal structure of (2-chloropyridin-3-yl)methyl-2-(6-methoxynaphthalen-2-yl)propanoate, C20H18ClNO3
  21. The crystal structure of diethyl 4-(3,4-dimethylphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate, C21H27NO4
  22. Crystal structure of (8R,9S,10R,13S,14S,17S)-17-hydroxy-10,13-dimethyl-17-((4-(2-phenylpropyl)phenyl)ethynyl)-1,2,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-3H-cyclopenta[a]phenanthren-3-one, C36H42O2
  23. Synthesis and crystal structure of 4-(4-cyclopropylnaphthalen-1-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione, C15H13N3S
  24. Crystal structure of catena-poly[aqua-(2,6-di-(2-pyridyl)-pyridine-κ3 N,N′, N″)(μ2-1,4-naphthalene dicarboxylato-κ2 O,O′)nickel(II)], C27H19NiN3O5
  25. Crystal structure of 3-(diphenylphosphoryl)-3-hydroxy-1-phenylpropan-1-one, C21H19O3P
  26. The crystal structure of R,S-{N-[(2-oxidonaphthalen-1-yl)methylidene]phenylglycinato}divinylsilicon, C23H19NO3Si
  27. The crystal structure of 1,2,4-tris(bromomethyl)benzene, C9H9Br3
  28. Crystal structure of chlorido-[4-(pyridin-2-yl)benzaldehyde-κ2 N,C]-(diethylamine-κ1 N)platinum(II), C16H18ClN2OPt
  29. Crystal structure of 3-(methoxycarbonyl)-1-(4-methoxyphenyl)-2,3,4,9- tetrahydro-1H-pyrido[3,4-b]indol-2-ium chloride hydrate, C40H48Cl2N4O9
  30. The crystal structure of 1-(2-chlorobenzyl)-3-(3-chlorophenyl)urea, C14H12Cl2N2O
  31. Hydrothermal synthesis and crystal structure of aqua-tris(4-acetamidobenzoato-κ2 O,O′)-(1,10-phenanthroline-κ2 N,N′)terbium(III) hydrate C39H36N5O11Tb
  32. The crystal structure of zwitterionic 3-aminoisonicotinic acid, C6H6N2O2
  33. The crystal structure of bis{[monoaqua-μ2-4-[(pyridine-4-carbonyl)-amino]-phthalato-κ3 N:O,O′-(2,2′-bipyridine κ2 N,N′)copper(II)]}decahydrate, C48H56N8O22Cu2
  34. Crystal structure of poly[μ10-4,4′-methylene-bis(oxy)benzoatodipotassium], C15H10K2O6
  35. The crystal structure of catena-poly[[tetraaqua[(μ2-1,4-di(4-methyl-1-imidazolyl)benzene] cobalt(II)]bis(formate)], C16H24CoN4O8
  36. The crystal structure of (E)-2-chloro-5-((2-(nitromethylene)imidazolidin-1-yl)methyl)pyridine, C10H11ClN4O2
  37. The crystal structure of (E)-1-(((2-amino-4,5-dimethylphenyl)iminio)methyl)naphthalen-2-olate, C19H18N2O
  38. Crystal structure of N-(acridin-9-yl)-2-(4-methylpiperidin-1-yl) acetamide monohydrate, C21H25N3O2
  39. The crystal structure of dichlorido-bis(3-methyl-3-imidazolium-1-ylpropionato-κ2 O,O′)-zinc(II), C14H20Cl2N4O4Zn
  40. The crystal structure of 2,8-diethyl-1,3,7,9-tetramethyl-4λ4,5λ4-spiro[dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine-5,2′-naphtho[1,8-de][1,3,2]dioxaborinine], C25H29BN2O2
  41. The crystal structure of 5-tert-butyl-2-(5-tert-butyl-3-iodo-benzofuran-2-yl)-3-iodobenzofuran, C24H24I2O2
  42. Synthesis and crystal structure of methyl 2-{[4-(4-cyclopropyl-1-naphthyl)-4H-1,2,4-triazole-3-yl]thio} acetate, C18H17N3O2S
  43. The crystal structure of n-propylammonium bis(2,3-dimethylbutane-2,3-diolato)borate-boric acid (1/1), [C3H10N][C12H24BO4]·B(OH)3
  44. Crystal structure of methyl 1-(2-bromophenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C19H17BrN2O2
  45. Crystal structure of (4-bromobenzyl)triphenylphosphonium bromide ethanol solvate, C52H48Br4OP2
  46. The crystal structure of unsymmetrical BOPHY C26H27BN4
  47. The crystal structure of Tb3B5O11(OH)2
  48. The crystal structure of (Z)-4-ethyl-2-((4-ethyl-3,5-dimethyl-1H-pyrrol-2-yl)methylene)-3,5-dimethyl-2H-pyrrol-1-ium 2,2'-spirobi[naphtho[1,8-de][1,3,2]dioxaborinin]-2-uide, C37H37BN2O4
  49. Crystal structure of bis(methylammonium) hexadecaselenidopalladate(II), (CH3NH3)2PdSe16
  50. The crystal structure of (2-diphenylphosphanylphenyl) 2-[7-(dimethylamino)-2-oxochromen-4-yl]acetate, C31H26NO4P
  51. Crystal structure of (E)-6-(4-ethylpiperazin-1-yl)-2-(3-fluorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C23H25FN2O
  52. The structure of RUB-56, (C6H16N)8 [Si32O64(OH)8]·32 H2O, a hydrous layer silicate (2D-zeolite) that contains microporous levyne-type silicate layers
  53. Crystal structure of 4-amino-3,5-dibromobenzonitrile, C7H4Br2N2
  54. Crystal structure of 2-(naphthalen-1-yl)ethyl 2-acetoxybenzoate, C21H18O4
  55. Single-crystal structure determination of Tm3B12O19(OH)7
  56. Crystal structure determination of NdB3.6O7
  57. The crystal structure of NdB6O8(OH)5·H3BO3
  58. Crystal structure of 2-(5-ethylpyridin-2-yl)ethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H25NO3
  59. Crystal structure of N-(1-(3,4-dimethoxyphenyl)-2-methylpropyl)aniline, C18H23NO2
  60. Crystal structure of Ba6Cd12Mn4SiF48
  61. Synthesis and crystal structure of 5-fluoro-1-methyl-2-oxo-3-(2-oxochroman-4-yl)indolin-3-yl acetate, C20H16FNO5
  62. The crystal structure of 6-methacryloylbenzo[d][1,3]dioxol-5-yl 4-nitrobenzenesulfonate, C17H13NO8S
  63. Crystal structure of ethyl 2-(3-benzyl-4-oxo-3,4-dihydrophthalazin-1-yl)- 2,2-difluoroacetate, C19H16F2N2O3
  64. The crystal structure of tetrakis(μ 2-(1H-benzimidazole-2-methoxo-κ2 N,O:O:O)-(n-butanol-κO)-chlorido)-tetranickel(II), C48H68Cl4N8O8Ni4
  65. Synthesis and crystal structure of trans-tetraaqua-bis((1-((7-hydroxy-3-(4-methoxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carbonyl)oxy-κO)zinc(II)hexahydrate, C46H64N2O28S2Zn
  66. The crystal structure of 1-(4-carboxybutyl)-3-methyl-1H-imidazol-3-ium hexafluoridophosphate, C9H15F6N2O2P
  67. Crystal structure of 1-(4-chlorophenyl)-4-(2-furoyl)-3-phenyl-1H-pyrazol-5-ol, C20H13ClN2O3
  68. Crystal structure of dimethyl (R)-2-(3-(1-phenylethyl)thioureido)-[1,1′-biphenyl]-4,4′-dicarboxylate, C25H24N2O4S
  69. The crystal structure of 1-(3-carboxypropyl)-1H-imidazole-3-oxide, C7H10N2O3
  70. Synthesis and crystal structure of dimethyl 4,4′-(propane-1,3-diylbis(oxy))dibenzoate, C19H20O6
  71. Crystal structure of methyl-1-(p-tolyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C20H20N2O2
  72. The crystal structure of 1-(1-adamantan-1-yl)ethyl-3-(3-methoxyphenyl)thiourea, C20H28N2OS
  73. The crystal structure of N,N′-carbonylbis(2,6-difluorobenzamide), C15H8F4N2O3
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Heruntergeladen am 22.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2024-0039/html
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