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Petrogenesis and tectonic significance of the Mengjiaping beschtauite in the southern Taihang mountains

  • Haofei Tian , Ganyu Li EMAIL logo , Jinyong Choi , Wenlou Luan , Xingtao Cui , Shen Wang , Mengqi Jin , Haotian Chen , Wenjing Chen , Xian Liang , Chengjie Zou , Liang Zhao , Sinan Han , Peijie Zou and Xiaofei Hu
Published/Copyright: December 31, 2021
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Abstract

The evolution process of the North China Craton has been discussed by many scholars; however, the frame for the timing of the Trans-North China Block has not been fully agreed upon. Related research has mostly focused on the northern and southern sections of the Trans-North China Block, and in-depth studies on intrusive rocks in the central region are lacking. In this study, we conduct a systematic study of the petrography, the whole-rock geochemistry, and the zircon U–Pb dating for the beschtauite intrusion, located in the Mengjiaping area of the Southern Taihang Mountains. Our results demonstrate that the dyke intrusion is mainly composed of beschtauite. Laser ablation inductively coupled plasma mass spectrometry zircon U–Pb dating shows that the beschtauite intrusion occurred at ∼1,880 ± 69 Ma. The beschtauite belongs to I-type granite, Arc tholeiite series, and Cale-alkaline series, with low total alkali, low potassium, and high aluminum. They are also enriched in large-ion lithophile elements, relatively depleted in high-field strength elements, and low total rare-earth elements. Based on the abovementioned data, it is suggested that the magmas for the beschtauite intrusion were metasomatized by oceanic slab subduction in the Late Paleoproterozoic. The formation time of the North China Craton basement should be set to after 1,880 Ma.

1 Introduction

The North China Craton is one of the oldest cratons in the world [1]. Compared with other cratons worldwide, the North China Craton has recorded almost all major tectonic events after 3.5 Ga during the early development of the Earth despite possessing a limited exposed area [2]. This craton exhibits a dual paleostructural geographic pattern comprising an early Precambrian metamorphic crystalline basement and a Mesoproterozoic sedimentary cap [3]. Several geologists have explored the structural complexity and multistage tectonic evolution of the North China Craton [4,5,6,7,8,9,10,11,12,13,14,15].

Currently, research on the North China Craton mainly focuses on six aspects as follows: the number of tectonic units, formation mechanism, integration age, tectonic boundary, collision mode, and subduction polarity [16,17,18,19,20,21,22,23,24,25,26,27,28,29,30]. Several geologists have studied the formation and tectonic evolution of the early Precambrian metamorphic crystalline basement of the North China Craton and proposed different basement-division schemes [31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46]. The tripartite scheme of the Eastern Block, Western Block, and Trans-North China Block, proposed by Zhao et al. [4,5,6], is one of the widely accepted schemes (Figure 1). The findings associated with the formation mechanism and formation age of the North China Craton basement are controversial, particularly the final formation age of the Precambrian basement, showing conflicting results of 2,500 and 1,900–1,800 Ma [17,18,19,20,21,30,32,33,34,35,36,37,38,39,40,41,42,43,44,45]. The formation mechanism and formation age of the Trans-North China Block of the North China Craton are critical to comprehensively understand the formation history of the North China Craton basement. Additionally, related studies have mostly focused on the northern and southern sections of the Trans-North China Block [10,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68], and there is a lack of in-depth studies on intrusive rocks in the central region [18,69,70,71,72,73,74,75].

Figure 1 
               Structural model of the North China Craton basement [6].
Figure 1

Structural model of the North China Craton basement [6].

The study area is located in the eastern part of the central Trans-North China Block of the North China Craton. A large number of dykes are intruded in the study area. Previous studies have identified the dykes as quartz augite porphyry. After electron microprobe analysis of the dyke samples, we redesignated the dykes as beschtauite. Previous studies have shown that the petrogenesis types of beschtauite are I-type granite [76,77,78,79,80], A-type granite [81,82,83,84,85], and adakite [79,86,87,88,89]. Beschtauite occurs in both subduction [77,90,91,92,93] and extensional settings [76,81,82,94,95]. The beschtauite in the study area is poorly studied, and its petrogenesis and tectonic setting still need to be studied in depth.

The beschtauite in the Mengjiaping area of the southern section of the Taihang Mountains is selected as the research area in this study. Through detailed geological fieldwork, laboratory petrographic study, geochemical analysis, and zircon U–Pb chronology research, we will discuss the formation period, petrogenesis, and tectonic setting, aiming to provide geological evidence for the tectonic evolution of the North China Craton.

2 Geological setting

The Mengjiaping area is located in the eastern part of the central Trans-North China Block, which is located in the southern section of the Taihang Mountains. It is distributed in western Neiqiu County, Xingtai City, Hebei Province. The Nansizhang and Nansi formations of the Gantaohe Group are the main strata in this area, wherein the relationship between the Nansizhang and Nansi formations is a conformable contact. The lithology of the lower section of the Nansizhang formation mainly comprises metamorphic conglomerates, meta-arkosic sandstones, and slate. By contrast, the upper section mainly comprises chlorite schist with metamorphic feldspar sandstone, metabasalt, tuff lava, and thin-bedded amphibolite schist. The Nansi formation mainly comprises metabasalt, quartzose arkose, metamorphic feldspar sandstone, dolomite, and slate [96]. Magmatic rocks are widely distributed in the Nansi formation (2,090 Ma) and Nansizhang formation (2,087–2,090 Ma) [22,100], and the main types of intrusive rocks include diabase (2,090 Ma) [30,97], beschtauite (1,880 Ma), and a small amount of diorite. The beschtauite is produced in dykes, possessing a length and width of 20–4,500 and 2–35 m, respectively. The dykes are mainly oriented northeast–southwest, followed by the near-south–north direction. The contact boundary between the intrusive and surrounding rocks is prominent and almost straight; the dykes often interpenetrate the surrounding rocks (Figures 2 and 3a). Diabase xenoliths are found at the contacts between the dykes and the surrounding rocks. The number of xenoliths tends to decrease from the outside to the inside of the dyke. The effect of metamorphic deformation on the rock is weak, which is the result of the flow-like arrangement of sheet minerals. The beschtauite is gray, possessing a porphyritic texture and a block structure (Figure 3b and c). The phenocrysts are mainly comprises K-feldspar (10–15%), plagioclase (15–20%), quartz (50–55%), and biotite (3–5%; Figure 3d and e). Among them, most quartz phenocrysts are round and granular. K-feldspar develops according to the Carlsbad twin law, mainly orthoclase. Some K-feldspar phenocrysts occur as giant phenocrysts with a size of 0.5–1.5 cm. The plagioclase exhibits polysynthetic twinning, mainly albite. The matrix comprises fine-granular and occasionally cryptocrystalline orthoclase, albite, quartz, mica, and chlorite. The macrophyllite typically exhibits a flow-like arrangement of sheet minerals, sometimes exhibiting the visible potassium metasomatism phenomenon. The edges of microcline or microstripe feldspar exhibit a visible carbonate metasomatism.

Figure 2 
               Geological map of Mengjiaping in the southern Taihang Mountains (taken from the 1:50,000 Motianling map [99]). (1) Loess, sand, and gravel, (2) upper cambrian, (3) lower cambrian, (4) Changzhougou formation, (5) Zhaojiazhuang formation, (6) Section 1 of Nansi formation, (7) Section 1 of Nansizhang formation, (8) Section 2 of Nansizhang formation, (9) Shijialan formation, (10) beschtauite, (11) gabbro diabase, (12) diabase, (13) diorite dyke, (14) slate, (15) normal fault, and (16) sampling location.
Figure 2

Geological map of Mengjiaping in the southern Taihang Mountains (taken from the 1:50,000 Motianling map [99]). (1) Loess, sand, and gravel, (2) upper cambrian, (3) lower cambrian, (4) Changzhougou formation, (5) Zhaojiazhuang formation, (6) Section 1 of Nansi formation, (7) Section 1 of Nansizhang formation, (8) Section 2 of Nansizhang formation, (9) Shijialan formation, (10) beschtauite, (11) gabbro diabase, (12) diabase, (13) diorite dyke, (14) slate, (15) normal fault, and (16) sampling location.

Figure 3 
               Field photographs and lithologic photographs in Mengjiaping; Qtz – quartz and Pl – plagioclase. (a) Rock mass photos, (b,c) Rock specimen photos, (d), (e) Microscopic photos of rock flakes.
Figure 3

Field photographs and lithologic photographs in Mengjiaping; Qtz – quartz and Pl – plagioclase. (a) Rock mass photos, (b,c) Rock specimen photos, (d), (e) Microscopic photos of rock flakes.

3 Methods

The sampling coordinates of the zircon U–Pb dating sample (35 kg) were 37°22′36″ N and 114°7′8″ E. The zircon samples were crushed in the Laboratory of the Langfang Institute of Regional Geology and Mineral Survey, Hebei Province. The zircon samples were placed in an epoxy resin, and they were abrasively polished until the zircon core was exposed. The internal structure of zircon was observed using cathodoluminescence (CL) microphotography by combining the reflected and transmitted lights. Microfield measurements for the in situ zircon U–Pb dating samples were performed at the Key Laboratory of Xi’an Center of Geological Survey, via LA-ICP-MS (Agilent 7500X). A Geolas Pro laser with a laser spot diameter of 32 µm, a laser energy density of 6.0 J/cm2, and a laser frequency of 9 Hz was used. Helium was used as the carrier gas to remove the denuded materials. Zircon 91500 and NIST610 were used as external and internal standards, respectively, for the U–Th–Pb isotope analysis. For principles and a detailed analysis process of the U–Th–Pb isotope analysis, refer to the Yuan et al. [100]. The experimental data containing the isotopic ratios were calibrated using the method proposed by Andersen [101] to minimize the influence of ordinary Pb on the test results. Using the 206Pb/238U ratio, the error of the weighted mean was calculated as 2σ. The ICP-MS Data Cal 8.3 program was used for data processing, and Isoplot (Version 4.0) was used for calculating the weighted age and obtaining the harmonic plot [102].

The total weight of the 12 beschtauite samples is 4 kg. The samples were collected near the highway in the Mengjiaping village and were used for the geochemical analysis. The beschtauite samples were fresh, and their alteration was weak. The beschtauites were cleaned, dried, and smashed to 200-mesh particles. They were analyzed using the wet chemical method at the Key Laboratory of Hebei GEO University. The major elements were analyzed using a ZSX Primus α X-ray fluorescence spectrometer. The trace and rare-earth (rare-earth elements [REEs]) elements were analyzed using MS and ICP atomic emission MS.

4 Results

4.1 Zircon U–Pb dating

Table 1 presents the 12 data obtained from the LA-ICP-MS zircon U–Pb dating. The zircon CL image (Figure 4) indicates that most zircon samples showed intact crystal structure with clear edges and faces, and their long axes were between 150 and 280 µm. Their aspect ratio was between 1:1 and 3:1. The zircon particles exhibited a complete crystal structure, and both cylindrical and conical surfaces could be observed. All the zircon particles exhibited clear oscillating growth zones in the CL images, and some zircon particles exhibited round central nuclei. The Th/U ranged from 0.21 to 0.58 (>0.1), indicating the magmatic zircon characteristics of the sample [103]. The weighted age was 1,880 ± 69 Ma (MSWD = 1.17, N = 12; Figure 5).

Table 1

U–Pb isotopic testing data of the beschtauite in Mengjiaping

Sample no. Content (µg/g) Th/U n(207Pb)/n(206Pb) n(207Pb)/n(235U) n(206Pb)/n(238U) n(208Pb)/n(232Th) 207Pb/235U Age (Ma) 206Pb/238U Age (Ma) 208Pb/232Th Age (Ma) ρr
232Th 238U Test 1σ Test 1σ Test 1σ Test 1σ Test 1σ Test 1σ Test 1σ
LF01 74.58 134.25 0.58 0.1369 0.0007 9.5457 0.1406 0.5050 0.0079 0.1140 0.0038 2,392 14 2,635 34 2,181 69 0.9
LF02 102.23 314.39 0.35 0.1283 0.0005 8.5065 0.1143 0.4794 0.0061 0.1114 0.0028 2,287 12 2,525 27 2,134 52 0.9
LF03 138.47 252.86 0.56 0.1353 0.0007 8.5489 0.1585 0.4582 0.0094 0.0929 0.0030 2,291 17 2,432 41 1,796 56 0.9
LF04 67.27 167.34 0.45 0.1237 0.0005 9.1183 0.1305 0.5327 0.0066 0.1162 0.0027 2,350 13 2,753 28 2,222 49 0.8
LF05 210.14 484.49 0.48 0.1148 0.0008 5.0794 0.1035 0.3197 0.0045 0.0678 0.0011 1,833 17 1,788 22 1,326 21 0.9
LF06 242.79 512.76 0.51 0.1177 0.0004 4.9320 0.1125 0.3029 0.0046 0.0635 0.0014 1,808 19 1,706 23 1,244 27 0.9
LF07 32.36 94.01 0.37 0.1275 0.0006 9.7532 0.1728 0.5529 0.0047 0.1335 0.0042 2,412 16 2,837 20 2,534 75 0.8
LF08 85.04 219.28 0.41 0.1229 0.0007 7.7755 0.0997 0.4582 0.0045 0.1053 0.0023 2,205 12 2,431 20 2,023 42 0.9
LF09 60.10 130.09 0.46 0.1382 0.0017 9.7568 0.1775 0.5102 0.0057 0.1250 0.0037 2,412 17 2,658 24 2,381 67 0.9
LF10 103.28 376.67 0.27 0.1128 0.0017 5.1293 0.1106 0.3285 0.0041 0.0906 0.0077 1,841 18 1,831 20 1,752 144 0.9
LF11 122.71 370.16 0.34 0.1161 0.0006 5.4593 0.1353 0.3404 0.0081 0.0859 0.0027 1,894 21 1,889 39 1,665 50 0.9
LF12 59.41 163.89 0.38 0.1288 0.0008 9.6886 0.1086 0.5448 0.0043 0.1295 0.0031 2,406 10 2,803 18 2,461 56 0.8
LF13 76.15 210.74 0.38 0.1241 0.0007 7.8117 0.1840 0.4561 0.0105 0.1185 0.0037 2,210 21 2,422 47 2,263 68 0.9
LF14 82.79 349.73 0.21 0.1070 0.0006 5.9130 0.2161 0.4000 0.0143 0.0850 0.0049 1,963 32 2,169 66 1,650 91 0.9
LF15 121.99 433.92 0.30 0.1079 0.0004 4.6789 0.0907 0.3145 0.0061 0.0516 0.0015 1,763 16 1,763 30 1,017 29 0.9
Figure 4 
                  Zircon CL images of the beschtauite in Mengjiaping.
Figure 4

Zircon CL images of the beschtauite in Mengjiaping.

Figure 5 
                  Zircon U–Pb age concordance and weighted mean age of the beschtauite in Mengjiaping.
Figure 5

Zircon U–Pb age concordance and weighted mean age of the beschtauite in Mengjiaping.

5 Petrogeochemical characteristics

5.1 Major elements

The major elemental contents and related parameters of the beschtauite samples are shown in Table 2. The SiO2 content ranged from 71.1 to 77.4%, with an average of 75.2%. The Al2O3 content was high, ranging from 11.75 to 15.3%, with an average of 13.65%. The Fe 2 O 3 T content ranged from 1.30 to 3.94%, with an average of 2.52%. The MgO content was 0.48–1.76%. The total alkali content (K2O + Na2O) ranged from 4.73 to 6.04%, with an average of 5.53%. The K2O content was 0.70–2.53%, with an average of 1.53%. The Na2O/K2O ratio ranged from 1.35 to 6.87, with an average of 3.13, which places this sample in the sodium type. In the volcanic rock TAS classification diagram, all the samples fall into the granite region (Figure 6a). The K2O/SiO2 ratio ranged from 0.01 to 0.03, with an average of 0.02. Moreover, the alkalinity ratio (AR) ranged from 1.95 to 2.52. The diagram of the AR–SiO2 and SiO2–K2O shows that the beschtauite belongs to the low-potassium series and the calc-alkaline series (Figure 6b and c). The saturation (A/CNK) ranged from 1.17 to 1.79, with an average of 1.47. In the A/CNK–A/NK diagram, all samples are peraluminous granite (Figure 6d).

Table 2

Major elements (wt%), trace elements (10−6), REEs, and related parameters of the beschtauite in Mengjiaping

Sample no. w-1 w-2 w-3 w-4 w-5 w-6 w-7-1 w-7-2 w-8 w-9 w-10 w-11
SiO2 76.8 73.2 74.9 77.4 73.2 73.5 77.1 77.3 71.1 76.0 75.2 76.9
TiO2 0.18 0.30 0.26 0.18 0.26 0.37 0.17 0.15 0.33 0.16 0.18 0.17
Al2O3 13.0 13.9 14.1 12.74 12.96 15.9 11.88 11.75 15.3 13.91 15.18 13.20
Fe 2 O 3 T 1.87 3.06 2.37 1.88 3.18 1.30 2.46 2.72 3.94 2.54 2.51 2.44
MnO 0.041 0.053 0.047 0.036 0.043 0.013 0.049 0.049 0.037 0.048 0.042 0.040
MgO 0.67 1.18 1.06 0.70 0.75 0.48 1.11 1.22 1.76 1.07 1.25 1.07
CaO 0.74 0.51 0.69 0.56 1.52 0.79 0.39 0.33 0.68 0.36 0.44 0.41
Na2O 4.78 3.87 3.88 4.27 3.41 3.49 4.06 4.05 4.29 4.09 4.02 3.74
K2O 0.70 2.17 2.05 1.39 2.53 2.46 1.13 1.17 1.68 1.09 1.00 0.99
P2O5 0.079 0.088 0.062 0.042 0.043 0.088 0.069 0.051 0.072 0.048 0.052 0.048
COL 0.59 1.07 0.9 0.72 1.51 1.25 1.90 0.74 1.38 0.73 0.76 0.65
TOTAL 99.45 99.40 100.32 99.92 99.41 99.64 100.32 99.53 100.57 100.05 100.63 99.66
Na2O/K2O 6.87 1.78 1.89 3.07 1.35 1.42 3.58 3.46 2.55 3.74 4.03 3.78
K2O/SiO2 0.01 0.03 0.03 0.02 0.03 0.03 0.01 0.02 0.02 0.01 0.01 0.01
A/CNK 1.30 1.44 1.43 1.33 1.17 1.61 1.38 1.38 1.51 1.62 1.79 1.66
A/NK 1.51 1.59 1.64 1.49 1.55 1.89 1.50 1.48 1.72 1.76 1.97 1.83
AR 2.33 2.44 2.34 2.48 2.39 2.11 2.47 2.52 2.19 2.14 1.95 2.07
Mg# 45.75 47.58 51.28 46.70 35.69 46.49 51.50 51.35 51.25 49.78 53.96 50.79
Rb 20.4 50.2 43.2 33.2 42.0 39.6 26.4 38.7 45.4 25.2 21.7 20.1
Ba 258 481 580 505 682 997 182 273 470 205 187 180
Th 5.62 9.58 8.10 5.33 9.56 12.0 6.62 5.53 6.32 7.21 7.40 7.33
U 0.499 0.747 0.718 0.510 1.24 0.691 0.543 0.465 0.800 0.651 0.623 0.694
Ta 0.38 0.48 0.33 0.27 0.31 0.51 0.19 0.16 0.40 0.18 0.19 0.23
Nb 3.97 5.05 4.10 3.21 3.71 6.82 2.20 1.90 5.66 2.32 2.36 2.28
La 22.20 27.70 19.50 16.50 25.20 13.60 20.40 17.10 29.90 14.50 20.10 16.90
Ce 41.80 54.90 35.40 31.30 46.20 25.40 36.50 28.70 58.40 27.40 36.00 31.00
Pb 13.10 10.80 9.07 10.80 23.80 7.25 6.97 6.89 6.40 6.12 6.93 6.32
Pr 5.11 5.97 4.10 3.46 4.96 3.12 4.20 3.33 6.38 3.29 4.06 3.62
Sr 128 94.7 96.4 151 88.9 103 98.6 108 126 97.2 122 106
Nd 18.6 20.1 14.0 12.2 16.8 12.0 14.1 11.4 22.3 11.9 13.9 12.9
Zr 41.8 64.0 66.0 35.7 52.2 47.8 47.5 41.8 54.3 57.4 51.4 40.8
Hf 1.11 1.71 1.67 0.93 1.47 1.33 1.36 1.21 1.38 1.55 1.36 1.13
Sm 3.29 3.11 2.06 2.02 2.48 2.44 2.18 1.74 3.51 2.08 2.09 2.06
Eu 0.89 0.73 0.56 0.65 0.71 0.84 0.55 0.52 1.07 0.50 0.53 0.50
Y 9.52 9.27 5.74 5.20 5.98 7.19 5.76 3.61 10.4 5.24 5.17 5.10
Gd 2.88 2.80 1.77 1.70 2.15 2.07 1.88 1.48 3.14 1.73 1.78 1.75
Tb 0.34 0.32 0.19 0.18 0.22 0.25 0.20 0.16 0.33 0.19 0.19 0.19
Dy 1.99 1.89 1.07 1.04 1.18 1.53 1.15 0.87 1.90 1.07 1.05 1.04
Ho 0.37 0.36 0.20 0.19 0.21 0.28 0.21 0.16 0.36 0.20 0.19 0.19
Er 1.15 1.16 0.70 0.62 0.68 0.87 0.68 0.50 1.15 0.61 0.62 0.60
Tm 0.15 0.16 0.096 0.084 0.090 0.12 0.088 0.065 0.15 0.080 0.083 0.079
Yb 0.88 0.96 0.61 0.52 0.54 0.72 0.55 0.39 0.93 0.48 0.50 0.47
Lu 0.13 0.14 0.094 0.081 0.082 0.11 0.082 0.057 0.14 0.075 0.075 0.072
ΣREE 99.71 120.35 80.37 70.53 101.49 63.44 82.81 66.44 129.66 64.18 81.18 71.40
LREE 91.82 112.56 75.65 66.12 96.34 57.50 77.97 62.76 121.56 59.75 76.69 67.02
HREE 7.89 7.79 4.72 4.41 5.15 5.93 4.84 3.68 8.09 4.43 4.50 4.38
LREE/HREE 11.64 14.45 16.03 14.98 18.69 9.69 16.11 17.03 15.02 13.48 17.06 15.29
δEu 0.86 0.74 0.88 1.05 0.92 1.11 0.80 0.97 0.96 0.78 0.82 0.79
δCe 0.93 1.00 0.92 0.97 0.95 0.92 0.92 0.87 0.99 0.93 0.92 0.93
(La/Sm)N 4.36 5.75 6.11 5.27 6.56 3.60 6.04 6.34 5.50 4.50 6.21 5.30
(La/Yb)N 18.10 20.70 22.93 22.76 33.47 13.55 26.61 31.45 23.06 21.67 28.84 25.79
(Gd/Yb)N 2.71 2.41 2.40 2.70 3.29 2.38 2.83 3.14 2.79 2.98 2.95 3.08
Rb/Sr 0.16 0.53 0.45 0.22 0.47 0.39 0.27 0.36 0.36 0.26 0.18 0.19
Rb/Nb 5.14 9.95 10.53 10.35 11.32 5.81 11.98 20.38 8.02 10.85 9.19 8.80
La/Nb 5.59 5.49 4.76 5.14 6.79 1.99 9.27 9.00 5.28 6.25 8.52 7.41
La/Yb 25.23 28.85 31.97 31.73 46.67 18.89 37.09 43.85 32.15 30.21 40.20 35.96
K/Rb 0.034 0.043 0.048 0.042 0.060 0.062 0.043 0.030 0.037 0.043 0.046 0.049
Sr/Y 13.40 10.21 16.80 29.07 14.87 14.29 17.11 29.83 12.13 18.53 23.51 20.78
Sr/Nd 6.85 4.70 6.89 12.43 5.28 8.54 6.97 9.47 5.66 8.17 8.74 8.18
Zr/Hf 37.63 37.40 39.58 38.54 35.42 35.85 34.85 34.52 39.32 36.98 37.84 36.10
Nb/Ta 10.58 10.56 12.37 11.89 11.97 13.36 11.54 12.24 14.04 12.91 12.20 10.06

A/CNK = (Al2O3)/[(CaO) + (Na2O) + (K2O)]; Mg# = 100 × [(MgO)/40.3044]/[(MgO)/40.3044 + (FeOT)/71.844]; A/NK = (Al2O3)/[(Na2O) + (K2O)]; AR = [(Al2O3) + (CaO) + (Na2O) + (K2O)]/{(Al2O3) + (CaO)–[(Na2O) + (K2O)]}; FeOT = Fe 2 O 3 T × 0.8998 × 0.85; δEu = EuN/(SmN × GdN)1/2; δCe = CeN/(LaN × PrN)1/2; and the subscript N denotes standardization with chondrites [107].

Mg# reflects the ratio of magnesium to iron in the rock.

Figure 6 
                  (a) Diagram of Na2O + K2O–SiO2 (TAS) in granitoids [104], (b) AR-SiO2 diagram [105], (c) K2O–SiO2 diagram [105], and (d) A/NK–A/KNC diagram [106].
Figure 6

(a) Diagram of Na2O + K2O–SiO2 (TAS) in granitoids [104], (b) AR-SiO2 diagram [105], (c) K2O–SiO2 diagram [105], and (d) A/NK–A/KNC diagram [106].

5.2 Trace and REEs

Based on the primitive mantle-normalized multielement spider diagram (Figure 7a), the elemental distribution characteristics of the granite samples were generally consistent. Compared with the Earth’s crust, the high-field strength elements (HFSEs), such as P, Nb, Ce, Ta, Sr, and Ti, were relatively depleted, whereas the large-ion lithophile elements (LILEs), such as Rb, Th, and K, were relatively enriched, which is a characteristic of a volcanic-arc granite. The normalized REE partition pattern diagram of chondrites revealed a right-leaning pattern of enriched LREE and depleted HREE (Figure 7b). The LREE/HREE ratio was 9.69–18.69, and the (La/Yb)N ratio was 13.55–33.47, which were considerably larger than 1; the fractionation of LREEs and HREEs was obvious. The (La/Sm)N ratio was 3.60–6.56, and the (Gd/Yb)N ratio was 2.38–3.29. A weak HREE differentiation was observed, a weak Eu negative anomaly was found (δEu = 0.74–1.11), and Ce showed no obvious positive or negative anomaly (δCe = 0.87–1.00).

Figure 7 
                  (a) Primitive mantle-normalized multielement spider diagram and (b) chondrite-normalized REE patterns [107].
Figure 7

(a) Primitive mantle-normalized multielement spider diagram and (b) chondrite-normalized REE patterns [107].

6 Discussion

6.1 Formation era

From bottom to top, the strata of the Gantaohe Group include the Nansizhang, Nansi, Songting, and Niushan formations. The Mengjiaping beschtauite mainly intrudes the strata of the Nansizhang formation and to a lesser extent in the Nansi formation. Previous studies showed that the age of rhyolite in the upper part of the Nansizhang formation is 2,088 ± 8 Ma [98], the age of metamorphic basalt in the Nansizhang formation is 2,087 ± 16 Ma [20], the age of diabase in the Nansizhang formation is 2,090 ± 14 Ma [97], and the age of dolomite in the Nansi formation is 2,090 ± 3 Ma [97]. The LA-ICP-MS zircon U–Pb age of the beschtauite obtained in the present study is 1,880 ± 69 Ma, which is less than the age of the Nansizhang and Nansi formations and consistent with geological facts. Therefore, it can be deduced that the magma emplacement age is 1,880 ± 69 Ma, and the emplacement era is during the Late Paleoproterozoic.

6.2 Petrogenesis

The major element contents of beschtauite include high Si (71.1–77.4%), low alkali (K2O = 0.70–2.53%, Na2O = 3.41–4.78%), and high aluminum saturation index (A/CNK: 1.17–1.79%). It also has the characteristics of low P (0.04–0.08%), low Mg (0.48–1.76%), and low Ti (0.15–0.37%). Among the trace elements, europium and cerium do not have obvious anomalies (δEu = 0.74–1.11, δCe = 0.87–1.00). The beschtauite is enriched in LILEs such as Rb and relatively deficient in HFSEs such as Nb. These factors provide beschtauite the Si-rich and P-poor characteristics of A-type granite; similarities to high Si, peraluminous S-type granite, and the Na-rich characteristics of I-type granite. Therefore, the petrogenetic type of beschtauite is worth discussing.

Granite is an important component of the continental crust. It can be divided into I-type, S-type, and A-type based on the characteristics of the magma source area [108,109,110,111]. Among these granites, A-type granites, usually contain signature alkaline dark minerals such as riebeckite–arfvedsonite, aegirine–augite, and fayalite [112]. In terms of geochemical composition, they are usually Si rich, K rich, Ga rich, Zr rich, Nb rich, Ta rich, and HFSE rich as well as possessing high diagenetic temperatures, which make them high-temperature granites [111,113,114]. No typical A-type granite minerals were observed in the beschtauite thin sections. Beschtauite trace elements have lower Ga, Zr, Nb, and other HFSEs. Herein, the geochemical characteristics of the beschtauite show that the ranges of 10,000 Ga/Al (2.57–1.48) and Zr + Nb + Ce + Y (75 × 10−6 to 133 × 10−6) are significantly lower than the lower limits of 3.75 and 350 × 10−6 proposed for A-type granite. Simultaneously, in the granite classification diagram (Figure 8a–d), all the rock samples fall into the region of non-A-type granites. Hence, it can be concluded that the beschtauite is more likely to be an I-type or S-type granite with high differentiation, not an A-type granite.

Figure 8 
                  (a) 10,000 Ga/Al–Ce diagram [121], (b) 10,000 Ga/Al–Zr diagram [121], (c) SiO2–Ce diagram [121], and (d) (Zr + Nb + Ce + Y)–(Na2O + K2O)/CaO diagram [120].
Figure 8

(a) 10,000 Ga/Al–Ce diagram [121], (b) 10,000 Ga/Al–Zr diagram [121], (c) SiO2–Ce diagram [121], and (d) (Zr + Nb + Ce + Y)–(Na2O + K2O)/CaO diagram [120].

Divergent I- or S-type granites tend to have similar major element characteristics and mineral assemblages. Their petrogenetic types are difficult to identify accurately [115]. However, Pichavant et al. showed that phosphorus has a high solubility in strongly peraluminous melts, and the content increases with increasing fractionation [116]. In contrast, phosphorus has a very low solubility in aluminous or weakly peraluminous melts, and the content decreases with the increase of the degree of differentiation. The relationship between P2O5 and SiO2 can be used as an effective discriminator under the premise that the evolved samples belong to the same rock suite. The P2O5 content in beschtauite was low, and the contents of P2O5, TiO2, and Fe 2 O 3 T decreased with increasing SiO2 contents (Figure 9a, c, and d). This does not conform to the typical characteristic that apatite increases with an increase in the SiO2 content in S-type granites. The beschtauite source area is presumed to be peraluminous or weakly peraluminous. The beschtauite has high Na2O (>3.41%), which differs significantly from typical S-type granite features [110,112]. Mineralogically, the typical S-type granite aluminum-rich minerals such as corundum, tourmaline, cordierite, and garnet are not found [117]. In addition, beschtauite has a well-defined ring zone of nascent zircons compared to the highly differentiated pale granites while clearly differing from the geochemical characteristics and classification of pale granites [118,119]. To summarize, the beschtauite in the Mengjiaping area is a highly differentiated I-type granite.

Figure 9 
                  (a) SiO2–P2O5 diagram [109], (b) SiO2–Zr diagram [120], (c) SiO2–TiO2 diagram [109], and (d) SiO2–
                        
                           
                           
                              
                                 
                                    Fe
                                 
                                 
                                    2
                                 
                              
                              
                                 
                                    O
                                 
                                 
                                    3
                                 
                                 
                                    T
                                 
                              
                           
                           {\text{Fe}}_{2}{\text{O}}_{3}^{\text{T}}
                        
                      diagram [109].
Figure 9

(a) SiO2–P2O5 diagram [109], (b) SiO2–Zr diagram [120], (c) SiO2–TiO2 diagram [109], and (d) SiO2 Fe 2 O 3 T diagram [109].

Three main petrogenesis types of I-types granite are indicated by previous data. The first type is the partial melting and crystallization of the mantle-derived magma [123]. The second type is the mantle-derived differentiated basic magma that penetrates the lower crust and mixes with the crust-derived felsic magma to form a mixed magma chamber in the shallow source, which was formed by separation and crystallization in the later stage of temperature drop [108,124]. The third type is the partial melting of crustal materials owing to the invasion of the magma with mantle differentiation at the bottom to form highly differentiated I-type granite [126,127].

The magma formed via the partial melting or separation crystallization of the mantle is basic or neutral and must exhibit a low SiO2 content and high Mg# [128]. The beschtauite shows a high SiO2 content within a small range (71.1–77.4%), lacking the separation sequence from basalt to granodiorite and then to granite. Moreover, it exhibits a low Mg# (35.69–53.96), indicating that the magma source area of the beschtauite in Mengjiaping cannot be directly derived from the partial melting and separation crystallization of the mantle-derived magma. The Rb/Nb ratio is 5.14–20.38, with an average of 10.19, and the Sr/Y ratio is 10.21–29.83, with an average of 18.38. Furthermore, the Nb/Ta ratio is 10.06–14.04, with an average of 11.98, close to that of the crustal average (12.22) [105,106] and lower than that of the original mantle average (17.4) [102], indicating the presence of continental crustal materials. The Zr/Hf ratio is 34.52–39.58, with an average of 37.00, higher than that of the original mantle average (36.25) [105] and higher than that of the crustal average (35.5) [105,129], reflecting the obvious fractionation during magmatic evolution. The Rb/Sr ratio is 0.16–0.53, with an average of 0.32, which is consistent with that of the global upper crustal average (0.32) [105]. These characteristics are more inclined to the third-type petrogenesis of I-type granites. Owing to the underplating of mantle-derived magma in this petrogenesis, the crustal material was partially melted, and the beschtauite in Mengjiaping was formed.

Melts formed under high pressures will exhibit a higher (Al2O3)/(Fe2O3 + MgO + TiO2) ratio than those formed under low pressures. The crust–mantle interaction occurs in the region between the high-pressure and low-pressure curves. This region occurs in the depth range of the crust–mantle interaction processes [122]. The (Al2O3)/(Fe2O3 + MgO + TiO2) ratio of the beschtauite exceeds 0.4 (0.36–0.54, average 0.48). Moreover, a small number of rock samples were distributed in the middle region, and the majority of them were concentrated below the low-pressure curve (Figure 10). This indicates that the petrogenesis of the rocks was associated with the lower crust under high-temperature settings, where mixing of the mantle-derived materials might have occurred.

Figure 10 
                  (Al2O3 + Fe2O3 + MgO + TiO2)–(Al2O3/Fe2O3 + MgO + TiO2) diagram [122]. The high-pressure and low-pressure reaction curves are formed by the melting of high-Al olivine basalt and metagreywacke. The interval between the high-pressure and low-pressure curves is the depth range where the crust and mantle are contaminated.
Figure 10

(Al2O3 + Fe2O3 + MgO + TiO2)–(Al2O3/Fe2O3 + MgO + TiO2) diagram [122]. The high-pressure and low-pressure reaction curves are formed by the melting of high-Al olivine basalt and metagreywacke. The interval between the high-pressure and low-pressure curves is the depth range where the crust and mantle are contaminated.

The beschtauite exhibits strong peraluminous geochemical characteristics (Figure 6d) and a tectonic low-pressure setting (Figure 10). Earlier studies have suggested that strong peraluminous granite demonstrates two tectonic settings as follows: one is high pressure and the other is high temperature [125,126,127,128,129,130,131]. The beschtauite in Mengjiaping is concluded to be in a high-temperature tectonic setting, further verifying the petrogenesis via partial crustal melting. Therefore, this beschtauite may have been formed by mantle-derived magma in a high-temperature setting, causing the partial melting of the crustal materials.

7 Structural significance

Geochemical characteristics indicate that Mengjiaping beschtauite is a calc-alkaline–arc tholeiite series, peraluminous granite. The LREEs and HREEs are clearly fractionated, enriching the LREEs and depleting the HREEs. It is enriched in LILEs such as Rb, Th, and K, deficient in HFSEs such as Nb, Ta, and Ti and has the basic characteristics of a typical volcanic-arc granite. Earlier studies have shown that the petrogenesis types of beschtauite are I-type granite [76,77,78,79,80], A-type granite [81,82,83,84,85], and adakite [79,86,87,88,89]. Although in this study, the beschtauite La/Yb ratio meets the criteria of adakite (La/Yb > 20) [132,133,134,135,136], the Sr content is considerably lower than the standard for identifying typical adakite (Sr > 400 × 10−6) [137,138,139]. So, it is judged that beschtauite may have some similar geochemical characteristics to adakite, but it is not an adakite. In addition, beschtauite is clearly distinguished from A-type granites (Figure 8a–d), and all fall into the I-type granite region in the SiO2–Zr diagram (Figure 9b). Therefore, Mengjiaping beschtauite is an I-type granite.

Mengjiaping beschtauite demonstrates an arc-related tectonic setting in the isotope study (Figure 11a–d) [140,141]. The results indicate that beschtauite may originate from mantle-derived magma or mixed crust- and mantle-derived magma. In the tectonic-setting identification diagram (Figure 12a–d) [142], the rock samples are all cast in the volcanic-arc granite region, indicating that the beschtauite is the product of arc magmatic rocks associated with the subduction of the oceanic crust. The Nb/Ta ratio is 10.06–14.04, which is low (<17). Furthermore, the characteristics of Nb and Ta are deficient relative to LILE. This indicates that the original rock has experienced partial melting under water-bearing conditions, indicating a subduction environment [143]. This conclusion is consistent with the findings of several researchers. Ye et al. suggested that the beschtauite in the Jidong Dalizi iron ore district is a I-type granite, formed in a subduction environment [77]. Lai et al. considered the beschtauite of Songnuo in the Gezan Island arc of Yunnan as an I-type granite, formed in a volcanic-arc tectonic setting and associated with oceanic crustal subduction tectonics [90]. Zhang et al. suggested that the beschtauite in the Duolong mineralized area is a high potassium–calcium–alkaline quasi–aluminous I-type granite with more typical geochemical characteristics of island-arc magmatism and formed in a subduction environment [91]. Sha et al. considered the beschtauite in the Xuejiping copper mining area to be an I-type granite, formed in a subduction environment [92]. Liu et al. suggested that the beschtauite of Yunnan Zhuoma is an I-type granite with features of island-arc granite, formed in a subduction environment [93]. In summary, the tectonic setting of beschtauite in this study is a volcanic arc, which is closely related to the subduction of oceanic crust.

Figure 11 
               (a) Y–Zr diagram [140], (b) Zr/Al2O3–TiO2/Al2O3 diagram [140], (c) TiO2–Al2O diagram [140], and (d) Th/Yb–Ta/Yb diagram [141].
Figure 11

(a) Y–Zr diagram [140], (b) Zr/Al2O3–TiO2/Al2O3 diagram [140], (c) TiO2–Al2O diagram [140], and (d) Th/Yb–Ta/Yb diagram [141].

Figure 12 
               Identification diagram of the tectonic setting [142]: (a) Y–Nb diagram, (b) Yb–Ta diagram, (c) Y + Nb–Rb diagram, and (d) Y + Ta–Rb diagram. ORG – oceanic ridge granite, WPG – intraplate granite, VAG – volcanic-arc granite, and syn-COLG – syncollisional granite.
Figure 12

Identification diagram of the tectonic setting [142]: (a) Y–Nb diagram, (b) Yb–Ta diagram, (c) Y + Nb–Rb diagram, and (d) Y + Ta–Rb diagram. ORG – oceanic ridge granite, WPG – intraplate granite, VAG – volcanic-arc granite, and syn-COLG – syncollisional granite.

Recently, several scholars have determined that the Trans-North China Block is associated with a subduction magmatism event during the Paleoproterozoic [21,53,54,55]. They proposed that the limited properties of the North China Craton are crucial in the construction of the Trans-North China Block, occurrence of magma activity chronological events, and indication of geochemical characteristics that enable the study of the Trans-North China Block intrusive rocks. Zhao et al. believed that the magmatic activity of 2,200–2,000 Ma in the Trans-North China Block was associated with subduction [53,54,55]. Wang et al. believed that the main sedimentary setting of the Paleoproterozoic Gantaohe Group in the middle and southern sections of the Taihang Mountains was a set of terrigenous clastic–flysch–carbonate rock-basic volcanic rocks with terrigenous clastic formation, produced in the nearshore setting [144]. The Mengjiaping beschtauite (1,880 ± 69 Ma) studied in this article is associated with a subduction setting. Based on this finding, the Trans-China North Block may be in a subducting tectonic setting. This conclusion is consistent with the earlier results [51,145,146,147].

The Xuting granite intrusion is nearest to the study area of this article, located ∼50 km northeast of the Mengjiaping beschtauite. Not only do they share the same tectonic position but also share similar geochemical characteristics. Both the Xuting granite and beschtauite exhibit high Si (75.95–77.21, 71.1–77.4%, respectively), high Na (2.85–3.54, 3.41–4.78%, respectively), LREE/HREE ratios that are enriched in LREEs and deficient in HREEs (7.29–11.90, 9.66–18.70, respectively). Xuting granite and Mengjiaping beschtauite. Many similar geochemical characteristics indicate that the two may have originated from the same magmatic source area.

Some scholars believe that the central part of the Trans-North China Block was in a tensional rift setting from 2,100 to 1,900 Ma [17,30]. Yang et al. suggested that the bimodal volcanic assemblage of the Xuting granite and the metamorphic basalt of the Gantaohe Group formed in a tensional rift setting. The proportions of basic and acidic rocks vary considerably in bimodal volcanic rocks that were formed in oceanic island-arc settings. The characteristics of basic rocks in this setting are as follows: highly depleted or slightly enriched LREEs, low K, low Ti, low Th, low Nb, enriched LILE, depleted HFSE, and high εNd(t). The characteristics of acidic rocks in this setting are as follows: low K and abundant Nb, depleted LILE, depleted or enriched LREE, obvious negative Eu anomaly, and high εNd(t) [148].

The metamorphic basalt of the Gantaohe Group is a basic rock with the following geochemical characteristics: SiO2 (48.80 × 10−6 to 53.57 × 10−6), LREE/HREE (2.2–4.5), Zr/Nb ratio (18.4–22.2), La (6.1 × 10−6 to 8.6 × 10−6), εNd(t) (4.0, 2.7, −0.8), enriched LILEs (Th and K), and negligibly deficient HSFEs (Nb and Ta) [20]. These characteristics are considerably different from those of the basic rocks in bimodal volcanic rocks formed in a continental rift setting (high LREE/HREE, low Zr/Nb (3–10), low La (50 × 10−6 to 100 × 10−6), middle εNd(t) (2–5), enriched LILE, and enriched HFSE). The metamorphic basalt is low in K (0.35 × 10−6 to 0.83 × 10−6), Ti (0.66 × 10−6 to 1.46 × 10−6), Th (0.4 × 10−6 to 0.7 × 10−6), and Nb (2.7 × 10−6 to 5.0 × 10−6). Further, it exhibits flat-type REE distribution patterns, LREE/HREE (3.2–6.4), and enriched LILE (Rb, Sr, and Ba). These geochemical characteristics indicate that this rock developed in an oceanic island-arc setting.

The Xuting granite is an acid rock with the following geochemical characteristics: SiO2 (75.50 × 10−6 to 77.21 × 10−6), LREE/HREE (7.3–11.9), εNd(t) (from −14.29 to −0.29), depleted LILE (Sr, Ba, and Ta), and depleted HFSE [17]. These geochemical characteristics are considerably different from those of acidic rocks in bimodal volcanic rocks formed in a continental rift setting (high LREE/HREE, middle εNd(t) (2–5), enriched LILEs, and enriched HFSEs). The Xuting granite is low in K (3.36 × 10−6 to 5.33 × 10−6), Ti (0.26 × 10−6 to 0.36 × 10−6), Nb (20.3 × 10−6 to 28.6 × 10−6), and Th (7.65 × 10−6 to 17.5 × 10−6). Moreover, it is LILE deficient (Sr, Ba, and Ta), and the Eu-negative anomaly is prominent (Eu/Eu* = 0.1–0.35). These geochemical characteristics indicate that this rock is developed in the oceanic island-arc setting. It is assumed that the bimodal volcanic assemblage composed of metamorphic basalt of the Gantaohe Group and the Xuting granite may also have formed in a subduction tectonic setting.

In summary, we conclude that the Mengjiaping beschtauite was formed in a volcanic-arc tectonic setting. The ocean basin between the Eastern and Western Blocks was not completely closed during 2,090–1,880 Ma and was still in a subduction setting. The formation time of the crystalline basement in the Trans-North China Block should be delayed to 1,880 Ma.

8 Conclusion

The following are the conclusions drawn from the geological fieldwork, petrographic studies, geochemical analysis, and zircon U–Pb chronology research:

The LA-ICP-MS zircon U–Pb age of the beschtauite is 1,880 ± 69 Ma, indicating that the emplacement era is during the Late Paleoproterozoic.

The beschtauite is an I-type granite characterized by high SiO2, high Na2O2, low K2O, low P2O5, and high differentiation as well as peraluminosity, which may have originated from the partial melting of the crust, along with some mantle-derived materials.

The beschtauite formed in a volcanic-arc tectonic setting and is a product of oceanic crustal subduction. The formation age of the crystalline basement of the North China Craton should be after 1,880 Ma.

Abbreviations

HFSE

high-field strength elements

HREE

heavy rare-earth elements

LILE

large ionic lithophile elements

LREE

light rare-earth elements

REE

rare-earth elements

CL

cathodoluminescence

LA-ICP-MS

laser ablation inductively coupled plasma mass spectrometry

MSWD

mean square weighted deviation

N

number of calculated measure points

2σ

confidence degree error

Acknowledgements

We sincerely appreciate the editors and reviewers for their constructive comments. We also thank Cai Kui, Zhang Minjie, and Yu Yanqiu who critically read the early draft and helped with geochemical analyses.

  1. Funding information: Doctoral Research Startup Fund of Hebei GEO University (BQ2018031).

  2. Author contributions: Conceptualization – Tian, H.F., Chen, W.J., Zou, P.J., and Jin, M.Q.; methodology – Tian, H.F., Cui, X.T., Chen, H.T., and Wang, S.; visualization – Tian, H.F., Hu, X.F., Han, S.N., and Liang, X.; writing – original draft preparation, Tian, H.F., Zou, C.J., and Zhao, L.; and writing – review and editing, Tian, H.F., Li, G.Y., Choi, J.Y., and Luan, W.L. All authors have read and agreed to the published version of the manuscript.

  3. Conflict of interest: Authors state no conflict of interest.

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Received: 2021-05-27
Revised: 2021-11-04
Accepted: 2021-11-22
Published Online: 2021-12-31

© 2021 Haofei Tian et al., published by De Gruyter

This work is licensed under the Creative Commons Attribution 4.0 International License.

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