Startseite The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4
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The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4

  • Ting Li , Keying Qiu , Yuxing Tan ORCID logo EMAIL logo und Wujiu Jiang ORCID logo
Veröffentlicht/Copyright: 28. Oktober 2022
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 238 Heft 1

Abstract

C28H21Br2MnN5O4, triclinic, P 1 ‾ (no. 2), a = 8.9193(14) Å, b = 9.2271(15) Å, c = 17.933(3) Å, α = 103.574(2)°, β = 91.518(2)°, γ = 98.762(2)°, V = 1415.0(4) Å3, Z = 2, Rgt (F) = 0.0347, wRref (F 2) = 0.0864, T = 296(2) K.

CCDC no.: 2194277

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Brown block
Size: 0.22 × 0.21 × 0.18 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 3.33 mm−1
Diffractometer, scan mode: Bruker Apex-II, φ and ω
θ max, completeness: 25.1°, >99%
N(hkl)measured, N(hkl)unique, R int: 15,027, 5015, 0.026
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 3905
N(param)refined: 361
Programs: Bruker [1], Shelx [2, 3], WinGX/Ortep [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
Br1 0.18458 (5) 0.46796 (6) 0.35855 (3) 0.08344 (16)
Br2 0.77624 (5) 0.75514 (5) 0.47505 (2) 0.07265 (14)
Mn1 0.90399 (5) 0.87393 (5) 0.22980 (3) 0.04434 (13)
O1 0.8114 (2) 0.7609 (2) 0.30946 (12) 0.0489 (5)
O2 0.9105 (2) 0.9820 (3) 0.13740 (13) 0.0552 (6)
O4 0.3667 (4) 0.6314 (4) −0.08933 (17) 0.1019 (11)
O3 0.4608 (4) 0.7898 (5) −0.15187 (17) 0.1136 (12)
N1 0.4602 (4) 0.7393 (5) −0.09467 (17) 0.0734 (9)
N2 0.6833 (3) 0.7760 (3) 0.16347 (13) 0.0394 (5)
N5 1.0041 (3) 0.6661 (3) 0.16103 (15) 0.0492 (6)
N3 1.1405 (3) 0.9492 (3) 0.28493 (16) 0.0531 (7)
N4 0.8498 (3) 1.0919 (3) 0.31044 (16) 0.0498 (6)
C4 0.3819 (4) 0.5607 (4) 0.3421 (2) 0.0552 (8)
C3 0.4903 (4) 0.6107 (4) 0.40302 (19) 0.0558 (9)
H3 0.468446 0.596070 0.451395 0.067*
C2 0.6302 (4) 0.6823 (4) 0.39079 (17) 0.0472 (7)
C1 0.6748 (3) 0.7048 (3) 0.31819 (16) 0.0410 (7)
C13 0.8015 (3) 0.9307 (3) 0.08481 (18) 0.0445 (7)
C12 0.7961 (4) 0.9844 (4) 0.0171 (2) 0.0556 (8)
H12 0.871043 1.062302 0.011526 0.067*
C11 0.6845 (4) 0.9254 (4) −0.04019 (19) 0.0561 (9)
H11 0.682861 0.964016 −0.083633 0.067*
C10 0.5737 (4) 0.8079 (4) −0.03316 (17) 0.0515 (8)
C9 0.5705 (3) 0.7536 (4) 0.03294 (17) 0.0462 (7)
H9 0.494949 0.674957 0.037038 0.055*
C8 0.6791 (3) 0.8162 (3) 0.09219 (16) 0.0394 (7)
C7 0.5693 (3) 0.6984 (4) 0.18504 (17) 0.0461 (7)
H7 0.485962 0.662393 0.149704 0.055*
C6 0.5558 (3) 0.6605 (3) 0.25846 (16) 0.0426 (7)
C5 0.4134 (4) 0.5870 (4) 0.27136 (19) 0.0535 (8)
H5 0.338477 0.555193 0.231284 0.064*
C14 1.0981 (4) 0.6768 (5) 0.1050 (2) 0.0621 (9)
H14 1.125151 0.770358 0.093742 0.075*
C15 1.1564 (4) 0.5551 (6) 0.0633 (2) 0.0723 (12)
H15 1.221043 0.566425 0.024457 0.087*
C16 1.1183 (4) 0.4182 (5) 0.0796 (2) 0.0729 (11)
H16 1.157246 0.334790 0.052449 0.087*
C17 1.0225 (5) 0.4046 (5) 0.1361 (2) 0.0717 (11)
H17 0.994554 0.312004 0.148196 0.086*
C18 0.9682 (4) 0.5303 (4) 0.1747 (2) 0.0601 (9)
H18 0.901962 0.519804 0.213013 0.072*
C19 1.1891 (4) 0.8904 (4) 0.3400 (2) 0.0700 (11)
H19 1.122857 0.816830 0.355638 0.084*
C20 1.3336 (5) 0.9338 (5) 0.3749 (3) 0.0807 (13)
H20 1.364187 0.891356 0.413793 0.097*
C21 1.4301 (5) 1.0397 (6) 0.3514 (3) 0.0939 (15)
H21 1.529065 1.069086 0.373140 0.113*
C22 1.3820 (5) 1.1026 (7) 0.2960 (3) 0.1124 (19)
H22 1.446324 1.176900 0.279906 0.135*
C23 1.2353 (4) 1.0538 (5) 0.2641 (2) 0.0790 (12)
H23 1.202022 1.096949 0.226001 0.095*
C24 0.8710 (4) 1.1121 (4) 0.3860 (2) 0.0599 (9)
H24 0.905788 1.036435 0.404584 0.072*
C25 0.8445 (4) 1.2384 (4) 0.4377 (2) 0.0658 (10)
H25 0.861636 1.248558 0.490237 0.079*
C26 0.7921 (5) 1.3497 (4) 0.4109 (3) 0.0763 (12)
H26 0.772808 1.436926 0.444761 0.092*
C27 0.7686 (5) 1.3300 (4) 0.3332 (3) 0.0753 (12)
H27 0.732729 1.403805 0.313461 0.090*
C28 0.7985 (4) 1.2010 (4) 0.2851 (2) 0.0574 (9)
H28 0.782454 1.188760 0.232403 0.069*

Source of material

All chemicals were purchased from commercial sources and used as received. A mixture of 2-amino-4-nitrophenol (10 mmol), 3,5-dibromo-2-hydroxybenzaldehyde (10 mmol) and CH3OH (50 mL) was added in a round-bottomed flask (100 mL), and refluxed with agitating for 4.0 h. The solution was cooled, and then the insoluble matter is removed by filtration. The ligand 2,4-dibromo-6-(((2-hydroxy-5-nitrophenyl)imino)methyl)phenol was obtained. 1 mmol 2,4-dibromo-6-(((2-hydroxy-5-nitrophenyl)imino)methyl)-phenol and 1 mmol manganese(II) acetate were added in CH3OH (50 mL) and refluxed with agitating for 4 h. Then, most of the methanol was evaporated, followed by adding pyridine dropwise until it just dissolved. The reaction solution continued to reflux for 2.5 h and filtered afterwards. Finally, the title crystal was precipitated by controlling solvent volatilization.

Experimental details

All H-atoms were placed geometrically and refined using a riding model with common isotropic displacement factors U iso(H) = 1.2 or 1.5 U eq(parent C-atom).

Comment

Schiff bases are versatile compounds, which have been synthesized from the condensation of carbonyl compounds with amino compounds and exhibit a broad range of applications [5]. The metal complexes with Schiff bases have been widely investigated for their versatile structures and potential applications in many fields [6, 7]. At present, the Schiff base derivatives of salicylaldine are mostly studied. Such Schiff bases have multiple coordination sites and can form stable metal complexes with most metal ions [8]. Furthermore, manganese is one of the most important transition metal ions in biological systems and plays an important role in activation of enzymes and sugar metabolism [9, 10].

The ORTEP diagram is presented in the Figure. Bond lengths and angles are all in the expected ranges. The ligand of the title molecule exhibits an E configuration. The bond length of C7=N2 is 1.275(4) Å, which is similar to those reported in the literature [11]. Mn1 forms a distorted octahedral coordination geometry and it is surrounded by two oxygen atoms (O1 and O2) and one nitrogen atom (N2) from the ligand, three nitrogen atoms (N3, N4 and N5) from three different pyridine ligands. The axial positions were occupied by two nitrogen atoms (N4 and N5) from two pyridine ligands, respectively. The angle of N4–Mn1–N5 is 169.09(9)° which obviously deviates from linear angle 180°. The four atoms (O1, O2, N2 and N3) were placed in equatorial sites, the sum of the angles [O2–Mn1–N2 = 76.44(8)°, O1–Mn1–N2 = 83.74(8)°, O1–Mn1–N3 = 98.41(10)°, O2–Mn1–N3 = 102.38(10)°] is 360.97°, which shows that the four atoms are basically planar, but the bond lengths [Mn1–O1 = 2.076(2) Å, Mn1–O2 = 2.123(2) Å, Mn1–N2 = 2.222(2) Å, Mn1–N3 = 2.243(3) Å] are unequal. It indicated that the central Mn atom is six-coordinate in a distorted pentagonal pyramid geometry, and the coordination mode is similar to that of previously reported complexes [12, 13].

Intermolecular hydrogen bonding exists in the crystal structure of the title compound. The carbon atom C15 provides one intermolecular hydrogen bond to O4′ of another molecule (C15⋯O4 = 3.504(5) Å; ′ = x + 1, y, z). The carbon atom C22 provides one intermolecular hydrogen bond to O3′′ of another molecule (C22⋯O3′′ = 3.257(6) Å; ′′ = −x + 2, −y + 2, −z). The carbon atom C28 provides one intermolecular hydrogen bond to O3′′′ of another molecule (C28⋯O3′′′ = 3.306(5) Å; ′′′ = −x + 1, −y + 2, −z).

Corresponding author: Yuxing Tan, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China, E-mail:

Funding source: Hunan Provincial Natural Science Foundation of China

Award Identifier / Grant number: 2022JJ30096

Funding source: College Students Innovation and Entrepreneurship Training Program

Award Identifier / Grant number: NYD202212

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the Hunan Provincial Natural Science Foundation of China (No. 2022JJ30096), and College Students Innovation and Entrepreneurship Training Program (No. NYD202212).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

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Received: 2022-08-23
Accepted: 2022-10-14
Published Online: 2022-10-28
Published in Print: 2023-01-27

© 2022 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of undecacalcium decaarsenide, Ca11As10
  4. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4- ylmethylene)amino)-1,2-dihydro-3H -pyrazol-3-one-κ2 N: O)zinc(II)], C17H16I2N4OZn
  5. The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ4 N 4-naphthalocyanido-κ4 N 4-neodymium(IV) - chloroform (1/6) C114H90N12Cl18Nd
  6. The crystal structure of 1-(4-bromophenyl)-3-(2-chlorobenzyl)urea, C14H12BrClN2O
  7. Crystal structure of bis[benzyl(methyl)carbamodithioato-κ 2 S,S′]-di-n-butyltin(IV), C26H38N2S4Sn
  8. Crystal structure of (E)-3-(2-(4-(diethylamino)-2-hydroxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate – methanol (1/2), C25H32N2O4S⋅2CH3OH
  9. Synthesis and crystal structure of {(N′,N″-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))-bis(methaneylylidene))bis(2-hydroxybenzohydrazonato)-κ6 N 2 O 4}copper(II), C30H24CuN4O6
  10. The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4
  11. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3-(p-tolylamino)hexadecahydro-1H-cyclopenta-[a]phenanthren-17-yl)ethan-1-one, C28H41NO
  12. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid—pyrazine-2-carboxamide(1/1), C13H10N4O7
  13. Crystal structure of poly[tetrakis(μ3-2-aminonicotinato-κ3N,O,O′)-(μ2-oxalato-κ4 O,O′:O″,O′″)-(μ4-oxalato-κ6 N:N′:O,O′:O″,O′″)dicopper(I)-disamarium(III)], [SmCu(C6N2H5O2)2(C2O4)] n
  14. The crystal structure of 2,3,4-trihydroxybenzoic- acid—pyrazine-2-carboxamide—water (1/1/1), C12H13N3O7
  15. Crystal structure of N-ethyl-4-[3-(trifluoromethyl)-phenyl]piperazine-1-carbothioamide, C14H18F3N3S
  16. The crystal structure of 3-anilino-1,4-diphenyl-4H-1,2,4-triazol-1-ium iodide, C20H17N4I
  17. The crystal structure of (tris(2-benzimidazolylmethyl)amine)-benzoato-copper(II) perchlorate monohydrate, CuC31H28N7O7Cl
  18. Crystal structure of [2-hydroxy-3-methyl-benzoato-k1 O-triphenyltin(IV)], C26H22O3Sn
  19. Crystal structure of diaqua-bis(4-(hydroxymethyl)-benzoato-k1 O)zinc(II), C16H18O8Zn
  20. The crystal structure of dicarbonyl-(N-nitroso-N-oxido-phenylamine-κ 2 O,O)-rhodium(I), C8H5N2O4Rh
  21. The crystal structure of oxalic acid – 2-ethoxybenzamide (2/1), C20H24N2O8
  22. The crystal structure of ethyl 7-ethyl-5-methyl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylate, C10H15N5O2
  23. Crystal structure of poly[(N,N-dimethylacetamide-κO) (μ4-2-nitroisophthalato-κ 4 O:O′:O″:O′″)manganese(II)], C11H10N2O7Mn
  24. Crystal structure of 14-O-acetyldelcosine, C26H41NO8
  25. The crystal structure of poly[(1,10-phenanthroline-κ2 N,N′)-(μ 4-2-chlorobenzene-1,3-dicarboxylato-κ5 O:O′:O″:O‴) cadmium(II)] monohydrate, C20H13CdClN2O5
  26. Crystal structure of propane-1,3-diylbis(diphenylphosphine sulfide) ethanol solvate, C27H26P2S2
  27. Crystal structure of bis{[(4-diethylamino-2-hydroxy-benzylidene)-hydrazinocarbonylmethyl]-trimethylammonium} tetrabromozincate, C32H54N8O4ZnBr4
  28. Synthesis and crystal structure of dimethyl 2,2′-(2,5-bis(4-hydroxyphenyl)-2,5-dihydrofuran-3,4-diyl)dibenzoate, C34H30O7
  29. Synthesis and crystal structure of 2-(2-oxo-2-phenylethyl)-4H-chromen-4-one, C17H12O3
  30. The crystal structure of tetra(imidazole-κ1 N)zinc(II) μ2-oxido-hexaoxido-divanadium(VI) C12H16N8O6V2Zn
  31. Crystal structure of S-2-(1-(5-methylpyridin-2-ylamino)octyl)-3-hydroxynaphthalene-1,4-dione, C24H28N2O3
  32. Crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxido-2-oxo-2-phenylethylidene)-benzohydrazonato-κ5 N,O,O′:N′,O′′)-oktakis(pyridine-κ1 N)trinickel(II) – methanol – pyridine (1/1/1) C76H65N13Cl2Ni3O9
  33. The crystal structure of methyl 3,5-diaminobenzoate, C8H10N2O2
  34. Crystal structure of 10-(9H-carbazol-9-yl)-5H-dibenzo[a,d][7]annelen-5-one, C27H17NO
  35. Crystal structure of ethyl 1-(2-hydroxyethyl)-4-((4-methoxyphenyl)amino)-5-oxo-2,5-dihydro-1H-pyrrole-3-carboxylate, C16H20N2O5
  36. The crystal structure of 1-(4-bromophenyl)-3-cycloheptylurea, C14H19BrN2O
  37. The crystal structure of 1,4-bis(1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl)-3,6-bis ((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene)-1,4-dialuminacyclohexane – benzene (1/2), C50H72Al2B2O4
  38. Crystal structure of bis(μ 3-diphenylphosphinato)-tetrakis(μ 2-diphenylphosphinato)-bis(diphenylphosphinato)-bis(μ 2-hydroxo)dicopper(II)-ditin(IV), C104H100O18P8Cu2Sn2
  39. Crystal structure of 3-((3,4-dichloroisothiazol-5-yl)methoxy)benzo[d] isothiazole 1,1-dioxide, C11H6Cl2N2O3S2
  40. Synthesis and crystal structure of 2-(2-(2-fluorophenyl)-2-oxoethyl)-4H-chromen-4-one, C17H11FO3
  41. The crystal structure of tris(carbonyl)-bis(carbonyl)-[μ-propane-1,2- dithiolato]-(benzyldiphenylphosphine)diiron (Fe—Fe), C27H23Fe2O5PS2
  42. Crystal structure of 1-(2-(4-chlorophenethyl)-2-hydroxy-3,3-dimethylbutyl)-1H-1,2,4-triazol-4-ium nitrate, C16H23N4O4Cl
  43. The crystal structure of 3,3′-disulfanediyldi(1H-1,2,4-triazol-5-amine) monohydrate, C4H8N8OS2
  44. The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4
  45. The crystal structure of ethyl 2′-hydroxy-4′,6′-dimethoxy-3-(4-methoxynaphthalen-1-yl)-5-oxo-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxylate, C28H28O7
https://doi.org/10.1515/ncrs-2022-0425
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of undecacalcium decaarsenide, Ca11As10
  4. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4- ylmethylene)amino)-1,2-dihydro-3H -pyrazol-3-one-κ2 N: O)zinc(II)], C17H16I2N4OZn
  5. The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ4 N 4-naphthalocyanido-κ4 N 4-neodymium(IV) - chloroform (1/6) C114H90N12Cl18Nd
  6. The crystal structure of 1-(4-bromophenyl)-3-(2-chlorobenzyl)urea, C14H12BrClN2O
  7. Crystal structure of bis[benzyl(methyl)carbamodithioato-κ 2 S,S′]-di-n-butyltin(IV), C26H38N2S4Sn
  8. Crystal structure of (E)-3-(2-(4-(diethylamino)-2-hydroxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate – methanol (1/2), C25H32N2O4S⋅2CH3OH
  9. Synthesis and crystal structure of {(N′,N″-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))-bis(methaneylylidene))bis(2-hydroxybenzohydrazonato)-κ6 N 2 O 4}copper(II), C30H24CuN4O6
  10. The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4
  11. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3-(p-tolylamino)hexadecahydro-1H-cyclopenta-[a]phenanthren-17-yl)ethan-1-one, C28H41NO
  12. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid—pyrazine-2-carboxamide(1/1), C13H10N4O7
  13. Crystal structure of poly[tetrakis(μ3-2-aminonicotinato-κ3N,O,O′)-(μ2-oxalato-κ4 O,O′:O″,O′″)-(μ4-oxalato-κ6 N:N′:O,O′:O″,O′″)dicopper(I)-disamarium(III)], [SmCu(C6N2H5O2)2(C2O4)] n
  14. The crystal structure of 2,3,4-trihydroxybenzoic- acid—pyrazine-2-carboxamide—water (1/1/1), C12H13N3O7
  15. Crystal structure of N-ethyl-4-[3-(trifluoromethyl)-phenyl]piperazine-1-carbothioamide, C14H18F3N3S
  16. The crystal structure of 3-anilino-1,4-diphenyl-4H-1,2,4-triazol-1-ium iodide, C20H17N4I
  17. The crystal structure of (tris(2-benzimidazolylmethyl)amine)-benzoato-copper(II) perchlorate monohydrate, CuC31H28N7O7Cl
  18. Crystal structure of [2-hydroxy-3-methyl-benzoato-k1 O-triphenyltin(IV)], C26H22O3Sn
  19. Crystal structure of diaqua-bis(4-(hydroxymethyl)-benzoato-k1 O)zinc(II), C16H18O8Zn
  20. The crystal structure of dicarbonyl-(N-nitroso-N-oxido-phenylamine-κ 2 O,O)-rhodium(I), C8H5N2O4Rh
  21. The crystal structure of oxalic acid – 2-ethoxybenzamide (2/1), C20H24N2O8
  22. The crystal structure of ethyl 7-ethyl-5-methyl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylate, C10H15N5O2
  23. Crystal structure of poly[(N,N-dimethylacetamide-κO) (μ4-2-nitroisophthalato-κ 4 O:O′:O″:O′″)manganese(II)], C11H10N2O7Mn
  24. Crystal structure of 14-O-acetyldelcosine, C26H41NO8
  25. The crystal structure of poly[(1,10-phenanthroline-κ2 N,N′)-(μ 4-2-chlorobenzene-1,3-dicarboxylato-κ5 O:O′:O″:O‴) cadmium(II)] monohydrate, C20H13CdClN2O5
  26. Crystal structure of propane-1,3-diylbis(diphenylphosphine sulfide) ethanol solvate, C27H26P2S2
  27. Crystal structure of bis{[(4-diethylamino-2-hydroxy-benzylidene)-hydrazinocarbonylmethyl]-trimethylammonium} tetrabromozincate, C32H54N8O4ZnBr4
  28. Synthesis and crystal structure of dimethyl 2,2′-(2,5-bis(4-hydroxyphenyl)-2,5-dihydrofuran-3,4-diyl)dibenzoate, C34H30O7
  29. Synthesis and crystal structure of 2-(2-oxo-2-phenylethyl)-4H-chromen-4-one, C17H12O3
  30. The crystal structure of tetra(imidazole-κ1 N)zinc(II) μ2-oxido-hexaoxido-divanadium(VI) C12H16N8O6V2Zn
  31. Crystal structure of S-2-(1-(5-methylpyridin-2-ylamino)octyl)-3-hydroxynaphthalene-1,4-dione, C24H28N2O3
  32. Crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxido-2-oxo-2-phenylethylidene)-benzohydrazonato-κ5 N,O,O′:N′,O′′)-oktakis(pyridine-κ1 N)trinickel(II) – methanol – pyridine (1/1/1) C76H65N13Cl2Ni3O9
  33. The crystal structure of methyl 3,5-diaminobenzoate, C8H10N2O2
  34. Crystal structure of 10-(9H-carbazol-9-yl)-5H-dibenzo[a,d][7]annelen-5-one, C27H17NO
  35. Crystal structure of ethyl 1-(2-hydroxyethyl)-4-((4-methoxyphenyl)amino)-5-oxo-2,5-dihydro-1H-pyrrole-3-carboxylate, C16H20N2O5
  36. The crystal structure of 1-(4-bromophenyl)-3-cycloheptylurea, C14H19BrN2O
  37. The crystal structure of 1,4-bis(1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl)-3,6-bis ((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene)-1,4-dialuminacyclohexane – benzene (1/2), C50H72Al2B2O4
  38. Crystal structure of bis(μ 3-diphenylphosphinato)-tetrakis(μ 2-diphenylphosphinato)-bis(diphenylphosphinato)-bis(μ 2-hydroxo)dicopper(II)-ditin(IV), C104H100O18P8Cu2Sn2
  39. Crystal structure of 3-((3,4-dichloroisothiazol-5-yl)methoxy)benzo[d] isothiazole 1,1-dioxide, C11H6Cl2N2O3S2
  40. Synthesis and crystal structure of 2-(2-(2-fluorophenyl)-2-oxoethyl)-4H-chromen-4-one, C17H11FO3
  41. The crystal structure of tris(carbonyl)-bis(carbonyl)-[μ-propane-1,2- dithiolato]-(benzyldiphenylphosphine)diiron (Fe—Fe), C27H23Fe2O5PS2
  42. Crystal structure of 1-(2-(4-chlorophenethyl)-2-hydroxy-3,3-dimethylbutyl)-1H-1,2,4-triazol-4-ium nitrate, C16H23N4O4Cl
  43. The crystal structure of 3,3′-disulfanediyldi(1H-1,2,4-triazol-5-amine) monohydrate, C4H8N8OS2
  44. The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4
  45. The crystal structure of ethyl 2′-hydroxy-4′,6′-dimethoxy-3-(4-methoxynaphthalen-1-yl)-5-oxo-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxylate, C28H28O7
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Heruntergeladen am 2.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2022-0425/html
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