Startseite The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4
Artikel Open Access

The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4

  • Boris-Marko Kukovec ORCID logo EMAIL logo , Vesna Sokol ORCID logo und Zora Popović ORCID logo
Veröffentlicht/Copyright: 14. Dezember 2022
Artikel downloaden (PDF)
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 238 Heft 1

Abstract

C32H26CdN4O4, tetragonal, P41212 (no. 92), a = 13.7308(6) Å, c = 15.1806(7) Å, V = 2862.1(3) Å3, Z = 4, R gt(F) = 0.0359, wR ref(F 2) = 0.0693, T = 296(2) K.

CCDC no.: 2224185

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colorless prism
Size: 0.42 × 0.39 × 0.25 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.81 mm−1
Diffractometer, scan mode: Oxford Xcalibur2 Sapphire 3, φ and ω
θ max, completeness: 30.0°, 99%
N(hkl)measured, N(hkl)unique, R int: 25832, 4170, 0.035
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 2738
N(param)refined: 192
Programs: C rysAlis CCD, CrysAlis RED [1], Shelx [2, 3], Mercury [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
Cd1 0.26919 (2) 0.26919 (2) 0.500000 0.05077 (13)
N1 0.27305 (19) 0.25344 (18) 0.65508 (15) 0.0404 (6)
N2 0.1454 (2) 0.1454 (2) 0.500000 0.0563 (10)
N3 0.3924 (2) 0.3924 (2) 0.500000 0.0565 (11)
O1 0.38640 (18) 0.16074 (18) 0.53001 (16) 0.0551 (6)
O2 0.47571 (19) 0.0976 (2) 0.63754 (18) 0.0758 (9)
C1 0.3384 (2) 0.1878 (2) 0.6803 (2) 0.0417 (8)
C2 0.3475 (2) 0.1567 (2) 0.7671 (2) 0.0538 (10)
H2 0.393813 0.110202 0.782269 0.065*
C3 0.2881 (3) 0.1952 (3) 0.8292 (2) 0.0564 (10)
H3 0.293419 0.174984 0.887502 0.068*
C4 0.2189 (2) 0.2648 (2) 0.8061 (2) 0.0493 (9)
C5 0.1545 (3) 0.3091 (3) 0.8677 (3) 0.0650 (10)
H5 0.156900 0.290935 0.926692 0.078*
C6 0.0900 (3) 0.3772 (3) 0.8414 (3) 0.0698 (12)
H6 0.048519 0.405414 0.882528 0.084*
C7 0.0847 (3) 0.4059 (3) 0.7529 (3) 0.0628 (10)
H7 0.040118 0.453275 0.735728 0.075*
C8 0.1451 (3) 0.3644 (2) 0.6916 (3) 0.0532 (9)
H8 0.141124 0.383273 0.632912 0.064*
C9 0.2125 (2) 0.2938 (2) 0.7174 (2) 0.0440 (9)
C10 0.4066 (3) 0.1447 (3) 0.6097 (2) 0.0489 (8)
C11 0.1667 (3) 0.0511 (3) 0.4972 (3) 0.0687 (10)
H11 0.232003 0.033366 0.494796 0.082*
C12 0.0985 (3) −0.0218 (3) 0.4977 (4) 0.0729 (11)
H12 0.118145 −0.086585 0.496538 0.087*
C13 0.0011 (4) 0.0011 (4) 0.500000 0.0710 (13)
C14 −0.0763 (4) −0.0763 (4) 0.500000 0.111 (2)
H14Aa −0.127635 −0.057877 0.539550 0.166*
H14Ba −0.048540 −0.136973 0.518863 0.166*
H14Ca −0.102093 −0.083419 0.441587 0.166*
C15 0.3719 (3) 0.4861 (3) 0.5107 (3) 0.0688 (11)
H15 0.307083 0.503615 0.518812 0.083*
C16 0.4405 (4) 0.5588 (4) 0.5104 (4) 0.0820 (12)
H16 0.421399 0.623308 0.517321 0.098*
C17 0.5366 (3) 0.5366 (3) 0.500000 0.0752 (16)
C18 0.6148 (4) 0.6148 (4) 0.500000 0.129 (3)
H18Aa 0.662609 0.599887 0.544108 0.193*
H18Ba 0.585705 0.676791 0.512687 0.193*
H18Ca 0.645430 0.617066 0.443205 0.193*

  1. aOccupancy: 0.5.

Source of material

The water-containing complex [Cd(quin)2(H2O)2] was prepared as reported previously [5]. A 4-picoline solution (5 mL) of [Cd(quin)2(H2O)2] (0.05 g, 0.10 mmol) was prepared by a gentle heating and left to stand at room temperature to slowly evaporate. The colorless crystals were formed in a couple of days, filtered off, washed with mother liquor and dried in air. Yield: 0.03 g (43%).

Experimental details

The positions of hydrogen atoms belonging to the Csp 2 and Csp 3 carbon atoms were geometrically optimized applying the riding model (Csp 2—H, 0.93 Å; U iso(H) = 1.2U eq(C) and Csp 3(methyl)—H, 0.96 Å; U iso(H) = 1.5U eq(C), respectively). The methyl H atoms (attached to the C14 and C18 atoms) are disordered about the twofold axis and their site occupancy factors were set to 0.5 during refinement. This disorder was refined by using a PART-1 instruction.

Comment

Quinoline-2-carboxylic acid (2-quinaldic acid, quinH) is an efficient chelating reagent for various metal ions and is, thus, used in the gravimetric analysis of metal(II) ions [6]. Metal complexes with 2-quinaldic acid have been extensively studied, as the crystal structures of 2-quinaldate complexes of transition metals, 12th group metals, platinum group metals, lanthanoids and main group metals have been reported [7]. The 2-quinaldate as a ligand may have attracted such an interest due to the fact that it has a role in a tryptophan metabolism [8] and several of its metabolites participate as signaling agents in neuronal pathways, revealing to be crucial in brain neuropathology [9]. The 2-quinaldic acid also reveals a potential application in the removal and recovery of aluminum(III) ions from environmental waste sites [10]. Previously, we have prepared [Cd(quin)2(H2O)2] by a reaction of cadmium(II) acetate and 2-quinaldic acid in a water/ethanol solution [5]. The respective DMSO-containing complex, [Cd(quin)2(DMSO)2], was obtained by a prolonged recrystallization of [Cd(quin)2(H2O)2] from DMSO solution, revealing to be a trans-isomer (the DMSO molecules bound in the octahedral axial positions) [5]. In the meantime, a water-containing complex [Cd(quin)2(H2O)2] was also obtained by a hydrothermal procedure which allowed formation of its single crystals and a determination of its crystal structure, showing to be a cis-isomer [9]. Therefore, the additional O-donor ligands (DMSO vs. water) in the respective cadmium(II) complexes can be placed either in trans- or cis-positions [5, 9]. We wanted to check the type of isomer (cis vs. trans) that can be obtained if a suitable N-donor ligand is used e.g. 4-methylpyridine (4-picoline). With this goal in mind, we recrystallized the water-containing complex [Cd(quin)2(H2O)2] from a 4-picoline solution to obtain the title compound.

Since the Cd1, N2, N3, C13, C14, C17 and C18 atoms are placed on a twofold axis along [110], the asymmetric unit of the title compound is composed of one half of a cadmium(II) ion, one 2-quinaldate ion and two halves of two independent 4-picoline molecules. The cadmium(II) ion is octahedrally coordinated by two N,O-chelating 2-quinaldate ligands (via respective N1 and N1 i atoms (Cd1—N1, 2.365(2) Å) and carboxylate O1 and O1 i atoms (Cd1—O1, 2.239(2) Å), symmetry code (i): y, x, −z+1) in the equatorial plane and by two 4-picoline molecules (via respective N2 and N3 atoms (Cd1—N2, 2.404(4) Å and Cd1—N3, 2.393(4) Å)) in the axial positions, giving a trans-isomer (N2—Cd1—N3, 180°). The bond angles around cadmium(II) ion corresponding to the trans pairs of donor atoms are in the range of 174.4(1)–180°, whilst those corresponding to the cis pairs are in the range of 73.77(8)–106.45(8)°, revealing a distorted octahedral coordination. Such a distortion from an ideal geometry is also clearly seen in the small value of the bite angle O1—Cd1—N1 (73.77(8)°). The 2-quinaldate pyridine ring (defined by the atoms N1/C1/C2/C3/C4/C9) and the corresponding five-membered chelate ring (defined by the atoms Cd1/O1/C10/C1/N1) are almost co-planar, with a value of a dihedral angle between those rings of 6.4(2)°. There are no classical hydrogen bonds in the crystal packing of the title compound and the molecules are assembled into a 3–D structure by C—H⋯π interactions only. These interactions are formed in between 4-picoline C12 atoms and centroids (cg) of 2-quinaldate pyridine rings N1/C1/C2/C3/C4/C9 (C⋯cg, 3.857(4) Å; C—H⋯Cg, 168°). There are only three structurally related cadmium(II) complexes with N,O-chelating 2-quinaldate known from the literature, containing either water molecules (in cis-position) [9] or DMSO molecules [5] or 4-(1-naphthylvinyl)pyridine [11] molecules in trans-position. Consequently, the Cd—N and Cd—O bond lengths (N and O atoms from 2-quinaldate) are comparable not only to the corresponding bond lengths in those compounds, but also in cadmium(II) complexes with picolinate [12], 6-methylpicolinate [13, 14], 3-hydroxypicolinate [15, 16] and 5-hydroxypicolinate [17] ligands.

Corresponding author: Boris-Marko Kukovec, Department of Physical Chemistry, Faculty of Chemistry and Technology, University of Split, Rudera Boškovića 35, HR-21000 Split, Croatia, E-mail:

Funding source: Ministry of Science, Education and Sports of the Republic of Croatia

Award Identifier / Grant number: 119–1193079–1332

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research was funded by the Ministry of Science, Education and Sports of the Republic of Croatia (grant no. 119–1193079–1332) and the open access paper charge was funded by the Faculty of Chemistry and Technology, University of Split institutional funding.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Oxford Diffraction Ltd. CrysAlis CCD and CrysAlis RED: Abingdon, Oxfordshire, England, 2008.Suche in Google Scholar

2. Sheldrick, G. M. SHELXTL – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Suche in Google Scholar

3. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Suche in Google Scholar

4. Macrae, C. F., Sovago, I., Cottrell, S. J., Galek, P. T. A., McCabe, P., Pidcock, E., Platings, M., Shields, G. P., Stevens, J. S., Towler, M., Wood, P. A. Mercury 4.0: from visualization to analysis, design and prediction. J. Appl. Crystallogr. 2020, 53, 226–235; https://doi.org/10.1107/s1600576719014092.Suche in Google Scholar PubMed PubMed Central

5. Kukovec, B.-M., Kodrin, I., Mihalić, Z., Popović, Z. Preparation, structural, spectroscopic, thermal and DFT characterization of cadmium(II) complexes with quinaldic acid. Inorg. Chim. Acta. 2011, 378, 154–162; https://doi.org/10.1016/j.ica.2011.08.050.Suche in Google Scholar

6. Vogel, A. Textbook of Quantitative Inorganic Analysis, 3rd ed.; Longman: London, 1962.Suche in Google Scholar

7. Groom, C. R., Bruno, I. J., Lightfoot, M. P., Ward, S. C. The Cambridge structural database. Acta Crystallogr. 2016, B72, 171–179; https://doi.org/10.1107/s2052520616003954.Suche in Google Scholar

8. Zhou, P., O’Hagan, D., Mocek, U., Zeng, Z., Yuen, L. D., Frenzel, T., Unkefer, C. J., Beale, J. M., Floss, H. G. Biosynthesis of the antibiotic thiostrepton. Methylation of tryptophan in the formation of the quinaldic acid moiety by transfer of the methionine methyl group with net retention of configuration. J. Am. Chem. Soc. 1989, 111, 7274–7276; https://doi.org/10.1021/ja00200a065.Suche in Google Scholar

9. Pan, G.-H., Tang, J.-N., Jin, X.-H., Xu, W.-J., Huang, Z.-J. Synthesis, structures, electrochemical analysis, and luminescence properties of four supramolecular complexes based on quinoline-2-carboxylic acid. Synth. React. Inorg., Met.-Org., Nano-Met. Chem. 2014, 44, 848–858; https://doi.org/10.1080/15533174.2013.791848.Suche in Google Scholar

10. Li, W., Olmstead, M. M., Miggins, D., Fish, R. H. Synthesis and structural studies of metal complexes of the biological ligand 2-quinaldic acid: utilization of the polymer pendant analog PS-2–QA for selective aluminum ion removal from aqueous solution. Inorg. Chem. 1996, 35, 51–55; https://doi.org/10.1021/ic950503j.Suche in Google Scholar PubMed

11. Dutta, B., Dey, A., Sinha, C., Ray, P. P., Mir, M. H. Sunlight-induced topochemical photodimerization and switching of the conductivity of a metal-organic compound. Inorg. Chem. 2019, 58, 5419–5422; https://doi.org/10.1021/acs.inorgchem.9b00619.Suche in Google Scholar PubMed

12. Deloume, J.-P., Loiseleur, H. Structure cristalline du pyridine-2 carboxylate de cadmium. Acta Crystallogr. 1974, B30, 607–609; https://doi.org/10.1107/s0567740874003396.Suche in Google Scholar

13. Kukovec, B.-M., Popović, Z., Pavlović, G. A one-dimensional CdII coordination polymer: catena-poly[cadmium(II)-bis(μ-6-methylpicolinato)]. Acta Crystallogr. 2007, C63, m389–m391; https://doi.org/10.1107/s0108270107034646.Suche in Google Scholar PubMed

14. Avcı, D., Altürk, S., Sönmez, F., Tamer, O., Başoğlu, A., Atalay, Y., Kurt, B. Z., Dege, N. A novel series of M(II) complexes of 6-methylpyridine-2-carboxylic acid with 4(5)methylimidazole: synthesis, crystal structures, α-glucosidase activity, density functional theory calculations and molecular docking. Appl. Organomet. Chem. 2019, 36, e6591.10.1002/aoc.4935Suche in Google Scholar

15. Popović, Z., Pavlović, G., Vinković, M., Vikić-Topić, D., Rajić Linarić, M. Coordination modes of 3-hydroxypicolinic acid (OH-picH): synthesis and characterization of cadmium(II) complexes: crystal and molecular structures of [CdX(OH-pic)(OH-picH)(H2O)]2. Polyhedron 2006, 25, 2353–2362.10.1016/j.poly.2006.02.010Suche in Google Scholar

16. Kukovec, B.-M., Popović, Z., Pavlović, G., Vinković, M., Vikić-Topić, D. Synthesis and characterization of some novel cadmium(II) complexes with 3-hydroxypicolinic acid (3–OHpicH): crystal and molecular structures of [CdI(3–OHpic)(3–OHpicH)(H2O)]2, [Cd(3–OHpic)2(H2O)2] and [Cd(3–OHpic)2]n. Polyhedron 2008, 27, 1479–1488; https://doi.org/10.1016/j.poly.2008.01.021.Suche in Google Scholar

17. Gao, P., Bing, Y. Y., Hu, M. From 0D to 3D transition based on pH-dependent assembly of supramolecular architectures: structures and properties. Inorg. Chem. Commun. 2015, 59, 28–31; https://doi.org/10.1016/j.inoche.2015.06.023.Suche in Google Scholar
Received: 2022-11-06
Accepted: 2022-12-03
Published Online: 2022-12-14
Published in Print: 2023-01-27

© 2022 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of undecacalcium decaarsenide, Ca11As10
  4. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4- ylmethylene)amino)-1,2-dihydro-3H -pyrazol-3-one-κ2 N: O)zinc(II)], C17H16I2N4OZn
  5. The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ4 N 4-naphthalocyanido-κ4 N 4-neodymium(IV) - chloroform (1/6) C114H90N12Cl18Nd
  6. The crystal structure of 1-(4-bromophenyl)-3-(2-chlorobenzyl)urea, C14H12BrClN2O
  7. Crystal structure of bis[benzyl(methyl)carbamodithioato-κ 2 S,S′]-di-n-butyltin(IV), C26H38N2S4Sn
  8. Crystal structure of (E)-3-(2-(4-(diethylamino)-2-hydroxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate – methanol (1/2), C25H32N2O4S⋅2CH3OH
  9. Synthesis and crystal structure of {(N′,N″-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))-bis(methaneylylidene))bis(2-hydroxybenzohydrazonato)-κ6 N 2 O 4}copper(II), C30H24CuN4O6
  10. The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4
  11. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3-(p-tolylamino)hexadecahydro-1H-cyclopenta-[a]phenanthren-17-yl)ethan-1-one, C28H41NO
  12. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid—pyrazine-2-carboxamide(1/1), C13H10N4O7
  13. Crystal structure of poly[tetrakis(μ3-2-aminonicotinato-κ3N,O,O′)-(μ2-oxalato-κ4 O,O′:O″,O′″)-(μ4-oxalato-κ6 N:N′:O,O′:O″,O′″)dicopper(I)-disamarium(III)], [SmCu(C6N2H5O2)2(C2O4)] n
  14. The crystal structure of 2,3,4-trihydroxybenzoic- acid—pyrazine-2-carboxamide—water (1/1/1), C12H13N3O7
  15. Crystal structure of N-ethyl-4-[3-(trifluoromethyl)-phenyl]piperazine-1-carbothioamide, C14H18F3N3S
  16. The crystal structure of 3-anilino-1,4-diphenyl-4H-1,2,4-triazol-1-ium iodide, C20H17N4I
  17. The crystal structure of (tris(2-benzimidazolylmethyl)amine)-benzoato-copper(II) perchlorate monohydrate, CuC31H28N7O7Cl
  18. Crystal structure of [2-hydroxy-3-methyl-benzoato-k1 O-triphenyltin(IV)], C26H22O3Sn
  19. Crystal structure of diaqua-bis(4-(hydroxymethyl)-benzoato-k1 O)zinc(II), C16H18O8Zn
  20. The crystal structure of dicarbonyl-(N-nitroso-N-oxido-phenylamine-κ 2 O,O)-rhodium(I), C8H5N2O4Rh
  21. The crystal structure of oxalic acid – 2-ethoxybenzamide (2/1), C20H24N2O8
  22. The crystal structure of ethyl 7-ethyl-5-methyl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylate, C10H15N5O2
  23. Crystal structure of poly[(N,N-dimethylacetamide-κO) (μ4-2-nitroisophthalato-κ 4 O:O′:O″:O′″)manganese(II)], C11H10N2O7Mn
  24. Crystal structure of 14-O-acetyldelcosine, C26H41NO8
  25. The crystal structure of poly[(1,10-phenanthroline-κ2 N,N′)-(μ 4-2-chlorobenzene-1,3-dicarboxylato-κ5 O:O′:O″:O‴) cadmium(II)] monohydrate, C20H13CdClN2O5
  26. Crystal structure of propane-1,3-diylbis(diphenylphosphine sulfide) ethanol solvate, C27H26P2S2
  27. Crystal structure of bis{[(4-diethylamino-2-hydroxy-benzylidene)-hydrazinocarbonylmethyl]-trimethylammonium} tetrabromozincate, C32H54N8O4ZnBr4
  28. Synthesis and crystal structure of dimethyl 2,2′-(2,5-bis(4-hydroxyphenyl)-2,5-dihydrofuran-3,4-diyl)dibenzoate, C34H30O7
  29. Synthesis and crystal structure of 2-(2-oxo-2-phenylethyl)-4H-chromen-4-one, C17H12O3
  30. The crystal structure of tetra(imidazole-κ1 N)zinc(II) μ2-oxido-hexaoxido-divanadium(VI) C12H16N8O6V2Zn
  31. Crystal structure of S-2-(1-(5-methylpyridin-2-ylamino)octyl)-3-hydroxynaphthalene-1,4-dione, C24H28N2O3
  32. Crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxido-2-oxo-2-phenylethylidene)-benzohydrazonato-κ5 N,O,O′:N′,O′′)-oktakis(pyridine-κ1 N)trinickel(II) – methanol – pyridine (1/1/1) C76H65N13Cl2Ni3O9
  33. The crystal structure of methyl 3,5-diaminobenzoate, C8H10N2O2
  34. Crystal structure of 10-(9H-carbazol-9-yl)-5H-dibenzo[a,d][7]annelen-5-one, C27H17NO
  35. Crystal structure of ethyl 1-(2-hydroxyethyl)-4-((4-methoxyphenyl)amino)-5-oxo-2,5-dihydro-1H-pyrrole-3-carboxylate, C16H20N2O5
  36. The crystal structure of 1-(4-bromophenyl)-3-cycloheptylurea, C14H19BrN2O
  37. The crystal structure of 1,4-bis(1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl)-3,6-bis ((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene)-1,4-dialuminacyclohexane – benzene (1/2), C50H72Al2B2O4
  38. Crystal structure of bis(μ 3-diphenylphosphinato)-tetrakis(μ 2-diphenylphosphinato)-bis(diphenylphosphinato)-bis(μ 2-hydroxo)dicopper(II)-ditin(IV), C104H100O18P8Cu2Sn2
  39. Crystal structure of 3-((3,4-dichloroisothiazol-5-yl)methoxy)benzo[d] isothiazole 1,1-dioxide, C11H6Cl2N2O3S2
  40. Synthesis and crystal structure of 2-(2-(2-fluorophenyl)-2-oxoethyl)-4H-chromen-4-one, C17H11FO3
  41. The crystal structure of tris(carbonyl)-bis(carbonyl)-[μ-propane-1,2- dithiolato]-(benzyldiphenylphosphine)diiron (Fe—Fe), C27H23Fe2O5PS2
  42. Crystal structure of 1-(2-(4-chlorophenethyl)-2-hydroxy-3,3-dimethylbutyl)-1H-1,2,4-triazol-4-ium nitrate, C16H23N4O4Cl
  43. The crystal structure of 3,3′-disulfanediyldi(1H-1,2,4-triazol-5-amine) monohydrate, C4H8N8OS2
  44. The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4
  45. The crystal structure of ethyl 2′-hydroxy-4′,6′-dimethoxy-3-(4-methoxynaphthalen-1-yl)-5-oxo-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxylate, C28H28O7
https://doi.org/10.1515/ncrs-2022-0515
Creative Commons
BY 4.0

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of undecacalcium decaarsenide, Ca11As10
  4. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4- ylmethylene)amino)-1,2-dihydro-3H -pyrazol-3-one-κ2 N: O)zinc(II)], C17H16I2N4OZn
  5. The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ4 N 4-naphthalocyanido-κ4 N 4-neodymium(IV) - chloroform (1/6) C114H90N12Cl18Nd
  6. The crystal structure of 1-(4-bromophenyl)-3-(2-chlorobenzyl)urea, C14H12BrClN2O
  7. Crystal structure of bis[benzyl(methyl)carbamodithioato-κ 2 S,S′]-di-n-butyltin(IV), C26H38N2S4Sn
  8. Crystal structure of (E)-3-(2-(4-(diethylamino)-2-hydroxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate – methanol (1/2), C25H32N2O4S⋅2CH3OH
  9. Synthesis and crystal structure of {(N′,N″-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))-bis(methaneylylidene))bis(2-hydroxybenzohydrazonato)-κ6 N 2 O 4}copper(II), C30H24CuN4O6
  10. The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4
  11. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3-(p-tolylamino)hexadecahydro-1H-cyclopenta-[a]phenanthren-17-yl)ethan-1-one, C28H41NO
  12. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid—pyrazine-2-carboxamide(1/1), C13H10N4O7
  13. Crystal structure of poly[tetrakis(μ3-2-aminonicotinato-κ3N,O,O′)-(μ2-oxalato-κ4 O,O′:O″,O′″)-(μ4-oxalato-κ6 N:N′:O,O′:O″,O′″)dicopper(I)-disamarium(III)], [SmCu(C6N2H5O2)2(C2O4)] n
  14. The crystal structure of 2,3,4-trihydroxybenzoic- acid—pyrazine-2-carboxamide—water (1/1/1), C12H13N3O7
  15. Crystal structure of N-ethyl-4-[3-(trifluoromethyl)-phenyl]piperazine-1-carbothioamide, C14H18F3N3S
  16. The crystal structure of 3-anilino-1,4-diphenyl-4H-1,2,4-triazol-1-ium iodide, C20H17N4I
  17. The crystal structure of (tris(2-benzimidazolylmethyl)amine)-benzoato-copper(II) perchlorate monohydrate, CuC31H28N7O7Cl
  18. Crystal structure of [2-hydroxy-3-methyl-benzoato-k1 O-triphenyltin(IV)], C26H22O3Sn
  19. Crystal structure of diaqua-bis(4-(hydroxymethyl)-benzoato-k1 O)zinc(II), C16H18O8Zn
  20. The crystal structure of dicarbonyl-(N-nitroso-N-oxido-phenylamine-κ 2 O,O)-rhodium(I), C8H5N2O4Rh
  21. The crystal structure of oxalic acid – 2-ethoxybenzamide (2/1), C20H24N2O8
  22. The crystal structure of ethyl 7-ethyl-5-methyl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylate, C10H15N5O2
  23. Crystal structure of poly[(N,N-dimethylacetamide-κO) (μ4-2-nitroisophthalato-κ 4 O:O′:O″:O′″)manganese(II)], C11H10N2O7Mn
  24. Crystal structure of 14-O-acetyldelcosine, C26H41NO8
  25. The crystal structure of poly[(1,10-phenanthroline-κ2 N,N′)-(μ 4-2-chlorobenzene-1,3-dicarboxylato-κ5 O:O′:O″:O‴) cadmium(II)] monohydrate, C20H13CdClN2O5
  26. Crystal structure of propane-1,3-diylbis(diphenylphosphine sulfide) ethanol solvate, C27H26P2S2
  27. Crystal structure of bis{[(4-diethylamino-2-hydroxy-benzylidene)-hydrazinocarbonylmethyl]-trimethylammonium} tetrabromozincate, C32H54N8O4ZnBr4
  28. Synthesis and crystal structure of dimethyl 2,2′-(2,5-bis(4-hydroxyphenyl)-2,5-dihydrofuran-3,4-diyl)dibenzoate, C34H30O7
  29. Synthesis and crystal structure of 2-(2-oxo-2-phenylethyl)-4H-chromen-4-one, C17H12O3
  30. The crystal structure of tetra(imidazole-κ1 N)zinc(II) μ2-oxido-hexaoxido-divanadium(VI) C12H16N8O6V2Zn
  31. Crystal structure of S-2-(1-(5-methylpyridin-2-ylamino)octyl)-3-hydroxynaphthalene-1,4-dione, C24H28N2O3
  32. Crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxido-2-oxo-2-phenylethylidene)-benzohydrazonato-κ5 N,O,O′:N′,O′′)-oktakis(pyridine-κ1 N)trinickel(II) – methanol – pyridine (1/1/1) C76H65N13Cl2Ni3O9
  33. The crystal structure of methyl 3,5-diaminobenzoate, C8H10N2O2
  34. Crystal structure of 10-(9H-carbazol-9-yl)-5H-dibenzo[a,d][7]annelen-5-one, C27H17NO
  35. Crystal structure of ethyl 1-(2-hydroxyethyl)-4-((4-methoxyphenyl)amino)-5-oxo-2,5-dihydro-1H-pyrrole-3-carboxylate, C16H20N2O5
  36. The crystal structure of 1-(4-bromophenyl)-3-cycloheptylurea, C14H19BrN2O
  37. The crystal structure of 1,4-bis(1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl)-3,6-bis ((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene)-1,4-dialuminacyclohexane – benzene (1/2), C50H72Al2B2O4
  38. Crystal structure of bis(μ 3-diphenylphosphinato)-tetrakis(μ 2-diphenylphosphinato)-bis(diphenylphosphinato)-bis(μ 2-hydroxo)dicopper(II)-ditin(IV), C104H100O18P8Cu2Sn2
  39. Crystal structure of 3-((3,4-dichloroisothiazol-5-yl)methoxy)benzo[d] isothiazole 1,1-dioxide, C11H6Cl2N2O3S2
  40. Synthesis and crystal structure of 2-(2-(2-fluorophenyl)-2-oxoethyl)-4H-chromen-4-one, C17H11FO3
  41. The crystal structure of tris(carbonyl)-bis(carbonyl)-[μ-propane-1,2- dithiolato]-(benzyldiphenylphosphine)diiron (Fe—Fe), C27H23Fe2O5PS2
  42. Crystal structure of 1-(2-(4-chlorophenethyl)-2-hydroxy-3,3-dimethylbutyl)-1H-1,2,4-triazol-4-ium nitrate, C16H23N4O4Cl
  43. The crystal structure of 3,3′-disulfanediyldi(1H-1,2,4-triazol-5-amine) monohydrate, C4H8N8OS2
  44. The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4
  45. The crystal structure of ethyl 2′-hydroxy-4′,6′-dimethoxy-3-(4-methoxynaphthalen-1-yl)-5-oxo-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxylate, C28H28O7
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 26.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2022-0515/html
Button zum nach oben scrollen