Startseite Crystal structure of 14-O-acetyldelcosine, C26H41NO8
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Crystal structure of 14-O-acetyldelcosine, C26H41NO8

  • Huan-Ni Liu , Yi-Kun Hao , Neng-Hua Chen und Lai-Ming Li ORCID logo EMAIL logo
Veröffentlicht/Copyright: 21. November 2022
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 238 Heft 1

Abstract

C26H41NO8, orthorhombic, P212121 (no. 19), a = 8.24370(10) Å, b = 13.1867(2) Å, c = 22.8490(4) Å, V = 2483.85(6) Å3, Z = 4, Rgt (F) = 0.0357, wRref (F 2) = 0.0975, T = 169.99(10) K.

CCDC no.: 2217908

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.15 × 0.13 × 0.10 mm
Wavelength: Cu Kα radiation (1.54184 Å)
μ: 0.80 mm−1
Diffractometer, scan mode: SuperNova, ω
θ max, completeness: 73.7°, 99%
N(hkl)measured, N(hkl)unique, R int: 11,294, 4713, 0.026
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 4616
N(param)refined: 325
Programs: CrysAlisPRO [1], Olex2 [2, 3], SHELX [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.7956 (2) 0.50370 (17) 0.39373 (10) 0.0256 (4)
H1A 0.847524 0.458957 0.365058 0.031*
C2 0.8512 (3) 0.4694 (2) 0.45373 (11) 0.0338 (5)
H2A 0.828855 0.397648 0.458469 0.041*
H2B 0.967391 0.479378 0.457309 0.041*
C3 0.7647 (3) 0.5288 (2) 0.50112 (10) 0.0344 (5)
H3A 0.801845 0.598540 0.500115 0.041*
H3B 0.793543 0.500744 0.538956 0.041*
C4 0.5766 (3) 0.52728 (18) 0.49463 (10) 0.0268 (5)
C5 0.5232 (2) 0.45535 (16) 0.44418 (9) 0.0217 (4)
H5 0.548326 0.384413 0.453196 0.026*
C6 0.3401 (2) 0.47056 (15) 0.43253 (9) 0.0208 (4)
H6 0.293106 0.505222 0.466480 0.025*
C7 0.3312 (2) 0.54438 (16) 0.37903 (9) 0.0194 (4)
C8 0.2940 (2) 0.48856 (15) 0.32082 (9) 0.0211 (4)
C9 0.4078 (2) 0.39600 (16) 0.31399 (9) 0.0215 (4)
H9 0.363592 0.337474 0.335077 0.026*
C10 0.5832 (2) 0.41749 (16) 0.33411 (9) 0.0224 (4)
H10 0.631842 0.352317 0.344934 0.027*
C11 0.6071 (2) 0.49028 (16) 0.38642 (9) 0.0206 (4)
C12 0.6715 (3) 0.45519 (18) 0.27704 (9) 0.0272 (5)
H12A 0.715712 0.522637 0.282732 0.033*
H12B 0.759170 0.409579 0.266608 0.033*
C13 0.5408 (3) 0.45607 (18) 0.22913 (9) 0.0266 (5)
H13 0.588187 0.441289 0.190727 0.032*
C14 0.4326 (3) 0.36978 (17) 0.24931 (10) 0.0257 (4)
H14 0.491369 0.305424 0.246022 0.031*
C15 0.2974 (3) 0.56062 (16) 0.26763 (9) 0.0242 (4)
H15A 0.203764 0.545568 0.243457 0.029*
H15B 0.284484 0.629387 0.281961 0.029*
C16 0.4488 (3) 0.55801 (18) 0.22823 (9) 0.0257 (4)
H16 0.523110 0.611627 0.240981 0.031*
C17 0.5075 (2) 0.58758 (16) 0.37614 (9) 0.0196 (4)
H17 0.529234 0.613961 0.336820 0.024*
C18 0.5034 (3) 0.49664 (19) 0.55309 (10) 0.0312 (5)
H18A 0.536570 0.544193 0.583183 0.037*
H18B 0.385926 0.497936 0.550526 0.037*
C19 0.5151 (3) 0.63504 (17) 0.48061 (9) 0.0271 (5)
H19A 0.398644 0.637759 0.486562 0.033*
H19B 0.565066 0.683011 0.507263 0.033*
C20 0.4967 (3) 0.76764 (16) 0.40648 (10) 0.0273 (5)
H20A 0.387847 0.776995 0.421675 0.033*
H20B 0.492477 0.776065 0.364331 0.033*
C21 0.6074 (3) 0.84748 (18) 0.43235 (12) 0.0350 (5)
H21A 0.574192 0.913334 0.419032 0.053*
H21B 0.717002 0.834855 0.420135 0.053*
H21C 0.601303 0.844901 0.474276 0.053*
C22 0.2288 (3) 0.3225 (2) 0.47661 (11) 0.0367 (6)
H22A 0.172823 0.260315 0.468307 0.055*
H22B 0.165421 0.362483 0.503286 0.055*
H22C 0.332150 0.307652 0.493932 0.055*
C23 0.1832 (3) 0.28837 (18) 0.22702 (10) 0.0302 (5)
C24 0.0282 (3) 0.2997 (2) 0.19410 (13) 0.0417 (6)
H24A −0.009197 0.368431 0.197165 0.063*
H24B −0.051791 0.254807 0.210245 0.063*
H24C 0.045827 0.283149 0.153682 0.063*
C25 0.5133 (4) 0.6211 (2) 0.13365 (11) 0.0407 (6)
H25A 0.465460 0.645563 0.098029 0.061*
H25B 0.589279 0.568153 0.124785 0.061*
H25C 0.568554 0.675751 0.152987 0.061*
C26 0.5076 (5) 0.3691 (3) 0.62518 (13) 0.0576 (9)
H26A 0.391674 0.373603 0.628317 0.086*
H26B 0.556884 0.413509 0.653298 0.086*
H26C 0.541259 0.300577 0.632617 0.086*
N1 0.5524 (2) 0.66417 (13) 0.42028 (8) 0.0223 (4)
O1 0.85168 (19) 0.60412 (13) 0.38212 (8) 0.0311 (4)
H1 0.794405 0.645016 0.399559 0.047*
O2 0.25227 (18) 0.37757 (12) 0.42371 (7) 0.0262 (3)
O3 0.21858 (17) 0.62386 (11) 0.38845 (7) 0.0232 (3)
H3 0.126230 0.602606 0.383232 0.035*
O4 0.12791 (17) 0.45398 (12) 0.32342 (7) 0.0255 (3)
H4 0.114672 0.419847 0.353031 0.038*
O5 0.2857 (2) 0.36506 (12) 0.21506 (7) 0.0282 (3)
O6 0.2158 (3) 0.22038 (14) 0.26007 (9) 0.0428 (4)
O7 0.3905 (2) 0.58278 (14) 0.17064 (7) 0.0351 (4)
O8 0.5563 (2) 0.39794 (15) 0.56787 (7) 0.0390 (4)

Source of material

The dry seeds of Delphinium grandiflorum were purchased from Kaiyuan, Liaoning Province, China. Dried powder (50.0 kg) was extracted three times with 95% ethanol at room temperature. The solution was evaporated under reduced pressure to get a residue (6.5 kg). The crude extract was suspended in water and we adjusted pH to 2–3 with HCl, and then partitioned with dichloromethane. The aqueous layer was adjusted to pH 9–10 with ammonium hydroxide and extracted by dichloromethane. After evaporation the dichloromethane soluble fraction (400 g) was obtained. This fraction was chromatographed by macroporous resins, eluted with EtOH/H2O solvent system, which afforded four fractions (fr. 1–4). The title compound was obtained from fr.4 and crystallized in methanol.

Experimental details

A suitable crystal was selected and mounted on a SuperNova, Dual, Cu at zero, AtlasS2 diffractometer. Using Olex2 [2], the structure was solved with the ShelXT [3] and refined with ShelXL [4]. Refinement package using least squares.

Comment

The plant D. grandiflorum belongs to Ranunculaceae Juss. It is originated in southern Europe and is now widely distributed throughout China [5]. Previous chemical investigations of D. grandiflorum have revealed that diterpene alkaloids are the main chemical constituents of this plant [6]. The single crystals were obtained by slow evaporation from a methanol solution.

The title compound was determined structurally as 14-O-acetyldelcosine [7], which is belonging to a class of diterpene alkaloids. The C=O bond length is 1.203 Å, the C–O bond lengths have values of 1.346(2)–1.444(8) Å, and the C–N and C–C bond lengths are within normal ranges [8, 9].

Corresponding author: Lai-Ming Li, College of Pharmacy, Southwest Minzu University, Chengdu, 610041, P. R. China, E-mail:
Huan-Ni Liu and Yi-Kun Hao contributed equally to this work.

Funding source: Southwest Minzu University

Award Identifier / Grant number: ZYN2022059

Award Identifier / Grant number: X202210656418

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 82173695

Award Identifier / Grant number: 82003609

Funding source: Guangdong Basic and Applied Basic Research Foundation

Award Identifier / Grant number: 2020B1515020033

Award Identifier / Grant number: 2020A1515110415

Award Identifier / Grant number: 2020A1515110453

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: “The Fundamental Research Funds for the Central Universities”, Southwest Minzu University (No. ZYN2022059), the College Student Innovation and Entrepreneurship Training Program Project of Southwest Minzu University (No: X202210656418); the National Natural Science Foundation of China (Nos. 82173695, 82003609), Guangdong Basic and Applied Basic Research Foundation (Nos. 2020B1515020033, 2020A1515110415, 2020A1515110453).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Agilent Technologies. CrysAlisPRO. Agilent Technologies: Santa Clara, CA, USA, 2017.Suche in Google Scholar

2. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Suche in Google Scholar

3. Bourhis, L. J., Dolomanov, O. V., Gildea, R. J., Howard, J. A. K., Puschmann, H. The anatomy of a comprehensive constrained, restrained refinement program for the modern computing environment – Olex2 dissected. Acta Crystallogr. 2015, A71, 59–75; https://doi.org/10.1107/s2053273314022207.Suche in Google Scholar

4. Sheldrick, G. M. SHELXTL – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Suche in Google Scholar PubMed PubMed Central

5. Chen, N. H., Zhang, Y. B., Li, W., Li, P., Chen, L. F., Li, Y. L., Li, G. Q., Wang, G. C. Grandiflodines A and B, two novel diterpenoid alkaloids from Delphinium grandiflorum. RSC Adv. 2017, 7, 24129–24132; https://doi.org/10.1039/c7ra02869e.Suche in Google Scholar

6. Zhou, X. L., Chen, D. L., Chen, Q. H., Wang, F. P. C20-diterpenoid alkaloids from Delphinium trifoliolatum. J. Nat. Prod. 2005, 68, 1076–1079; https://doi.org/10.1021/np0401922.Suche in Google Scholar PubMed

7. Bai, Y. L., Benn, M. Norditerpenoid alkaloids of Delphinium leroyi. Phytochemistry 1992, 31, 3243–3245; https://doi.org/10.1016/0031-9422(92)83484-g.Suche in Google Scholar

8. Eiichi, F., Itsuo, U., Tetsuro, F. Teucvin, a novel furanoid norditerpene from Teucrium viscidum var. Miquelianum. J. Chem. Soc. Chem. Commun. 1973, 20, 793–794; https://doi.org/10.1039/c39730000793.Suche in Google Scholar

9. Zeng, Z., Qasem, A. M. A., Kociok-Köhn, G., Rowan, M. G., Blagbrough, I. S. The 1α-hydroxy-A-rings of norditerpenoid alkaloids are twisted-boat conformers. RSC Adv. 2020, 10, 18797–18805; https://doi.org/10.1039/d0ra03811c.Suche in Google Scholar PubMed PubMed Central

Received: 2022-10-19
Accepted: 2022-11-07
Published Online: 2022-11-21
Published in Print: 2023-01-27

© 2022 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of undecacalcium decaarsenide, Ca11As10
  4. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4- ylmethylene)amino)-1,2-dihydro-3H -pyrazol-3-one-κ2 N: O)zinc(II)], C17H16I2N4OZn
  5. The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ4 N 4-naphthalocyanido-κ4 N 4-neodymium(IV) - chloroform (1/6) C114H90N12Cl18Nd
  6. The crystal structure of 1-(4-bromophenyl)-3-(2-chlorobenzyl)urea, C14H12BrClN2O
  7. Crystal structure of bis[benzyl(methyl)carbamodithioato-κ 2 S,S′]-di-n-butyltin(IV), C26H38N2S4Sn
  8. Crystal structure of (E)-3-(2-(4-(diethylamino)-2-hydroxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate – methanol (1/2), C25H32N2O4S⋅2CH3OH
  9. Synthesis and crystal structure of {(N′,N″-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))-bis(methaneylylidene))bis(2-hydroxybenzohydrazonato)-κ6 N 2 O 4}copper(II), C30H24CuN4O6
  10. The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4
  11. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3-(p-tolylamino)hexadecahydro-1H-cyclopenta-[a]phenanthren-17-yl)ethan-1-one, C28H41NO
  12. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid—pyrazine-2-carboxamide(1/1), C13H10N4O7
  13. Crystal structure of poly[tetrakis(μ3-2-aminonicotinato-κ3N,O,O′)-(μ2-oxalato-κ4 O,O′:O″,O′″)-(μ4-oxalato-κ6 N:N′:O,O′:O″,O′″)dicopper(I)-disamarium(III)], [SmCu(C6N2H5O2)2(C2O4)] n
  14. The crystal structure of 2,3,4-trihydroxybenzoic- acid—pyrazine-2-carboxamide—water (1/1/1), C12H13N3O7
  15. Crystal structure of N-ethyl-4-[3-(trifluoromethyl)-phenyl]piperazine-1-carbothioamide, C14H18F3N3S
  16. The crystal structure of 3-anilino-1,4-diphenyl-4H-1,2,4-triazol-1-ium iodide, C20H17N4I
  17. The crystal structure of (tris(2-benzimidazolylmethyl)amine)-benzoato-copper(II) perchlorate monohydrate, CuC31H28N7O7Cl
  18. Crystal structure of [2-hydroxy-3-methyl-benzoato-k1 O-triphenyltin(IV)], C26H22O3Sn
  19. Crystal structure of diaqua-bis(4-(hydroxymethyl)-benzoato-k1 O)zinc(II), C16H18O8Zn
  20. The crystal structure of dicarbonyl-(N-nitroso-N-oxido-phenylamine-κ 2 O,O)-rhodium(I), C8H5N2O4Rh
  21. The crystal structure of oxalic acid – 2-ethoxybenzamide (2/1), C20H24N2O8
  22. The crystal structure of ethyl 7-ethyl-5-methyl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylate, C10H15N5O2
  23. Crystal structure of poly[(N,N-dimethylacetamide-κO) (μ4-2-nitroisophthalato-κ 4 O:O′:O″:O′″)manganese(II)], C11H10N2O7Mn
  24. Crystal structure of 14-O-acetyldelcosine, C26H41NO8
  25. The crystal structure of poly[(1,10-phenanthroline-κ2 N,N′)-(μ 4-2-chlorobenzene-1,3-dicarboxylato-κ5 O:O′:O″:O‴) cadmium(II)] monohydrate, C20H13CdClN2O5
  26. Crystal structure of propane-1,3-diylbis(diphenylphosphine sulfide) ethanol solvate, C27H26P2S2
  27. Crystal structure of bis{[(4-diethylamino-2-hydroxy-benzylidene)-hydrazinocarbonylmethyl]-trimethylammonium} tetrabromozincate, C32H54N8O4ZnBr4
  28. Synthesis and crystal structure of dimethyl 2,2′-(2,5-bis(4-hydroxyphenyl)-2,5-dihydrofuran-3,4-diyl)dibenzoate, C34H30O7
  29. Synthesis and crystal structure of 2-(2-oxo-2-phenylethyl)-4H-chromen-4-one, C17H12O3
  30. The crystal structure of tetra(imidazole-κ1 N)zinc(II) μ2-oxido-hexaoxido-divanadium(VI) C12H16N8O6V2Zn
  31. Crystal structure of S-2-(1-(5-methylpyridin-2-ylamino)octyl)-3-hydroxynaphthalene-1,4-dione, C24H28N2O3
  32. Crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxido-2-oxo-2-phenylethylidene)-benzohydrazonato-κ5 N,O,O′:N′,O′′)-oktakis(pyridine-κ1 N)trinickel(II) – methanol – pyridine (1/1/1) C76H65N13Cl2Ni3O9
  33. The crystal structure of methyl 3,5-diaminobenzoate, C8H10N2O2
  34. Crystal structure of 10-(9H-carbazol-9-yl)-5H-dibenzo[a,d][7]annelen-5-one, C27H17NO
  35. Crystal structure of ethyl 1-(2-hydroxyethyl)-4-((4-methoxyphenyl)amino)-5-oxo-2,5-dihydro-1H-pyrrole-3-carboxylate, C16H20N2O5
  36. The crystal structure of 1-(4-bromophenyl)-3-cycloheptylurea, C14H19BrN2O
  37. The crystal structure of 1,4-bis(1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl)-3,6-bis ((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene)-1,4-dialuminacyclohexane – benzene (1/2), C50H72Al2B2O4
  38. Crystal structure of bis(μ 3-diphenylphosphinato)-tetrakis(μ 2-diphenylphosphinato)-bis(diphenylphosphinato)-bis(μ 2-hydroxo)dicopper(II)-ditin(IV), C104H100O18P8Cu2Sn2
  39. Crystal structure of 3-((3,4-dichloroisothiazol-5-yl)methoxy)benzo[d] isothiazole 1,1-dioxide, C11H6Cl2N2O3S2
  40. Synthesis and crystal structure of 2-(2-(2-fluorophenyl)-2-oxoethyl)-4H-chromen-4-one, C17H11FO3
  41. The crystal structure of tris(carbonyl)-bis(carbonyl)-[μ-propane-1,2- dithiolato]-(benzyldiphenylphosphine)diiron (Fe—Fe), C27H23Fe2O5PS2
  42. Crystal structure of 1-(2-(4-chlorophenethyl)-2-hydroxy-3,3-dimethylbutyl)-1H-1,2,4-triazol-4-ium nitrate, C16H23N4O4Cl
  43. The crystal structure of 3,3′-disulfanediyldi(1H-1,2,4-triazol-5-amine) monohydrate, C4H8N8OS2
  44. The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4
  45. The crystal structure of ethyl 2′-hydroxy-4′,6′-dimethoxy-3-(4-methoxynaphthalen-1-yl)-5-oxo-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxylate, C28H28O7
https://doi.org/10.1515/ncrs-2022-0501
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of undecacalcium decaarsenide, Ca11As10
  4. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4- ylmethylene)amino)-1,2-dihydro-3H -pyrazol-3-one-κ2 N: O)zinc(II)], C17H16I2N4OZn
  5. The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ4 N 4-naphthalocyanido-κ4 N 4-neodymium(IV) - chloroform (1/6) C114H90N12Cl18Nd
  6. The crystal structure of 1-(4-bromophenyl)-3-(2-chlorobenzyl)urea, C14H12BrClN2O
  7. Crystal structure of bis[benzyl(methyl)carbamodithioato-κ 2 S,S′]-di-n-butyltin(IV), C26H38N2S4Sn
  8. Crystal structure of (E)-3-(2-(4-(diethylamino)-2-hydroxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate – methanol (1/2), C25H32N2O4S⋅2CH3OH
  9. Synthesis and crystal structure of {(N′,N″-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))-bis(methaneylylidene))bis(2-hydroxybenzohydrazonato)-κ6 N 2 O 4}copper(II), C30H24CuN4O6
  10. The crystal structure of ((E)-2,4-dibromo-6-(((5-(nitro)-2-oxidophenyl)imino)methyl)phenolato-κ 3 N,O,O′)tris(pyridine-κN)manganese(II), C28H21Br2MnN5O4
  11. Synthesis and crystal structure of 1-((3R,10S,13R,17S)-10,13-dimethyl-3-(p-tolylamino)hexadecahydro-1H-cyclopenta-[a]phenanthren-17-yl)ethan-1-one, C28H41NO
  12. The crystal structure of 3-nitrobenzene-1,2-dicarboxylic acid—pyrazine-2-carboxamide(1/1), C13H10N4O7
  13. Crystal structure of poly[tetrakis(μ3-2-aminonicotinato-κ3N,O,O′)-(μ2-oxalato-κ4 O,O′:O″,O′″)-(μ4-oxalato-κ6 N:N′:O,O′:O″,O′″)dicopper(I)-disamarium(III)], [SmCu(C6N2H5O2)2(C2O4)] n
  14. The crystal structure of 2,3,4-trihydroxybenzoic- acid—pyrazine-2-carboxamide—water (1/1/1), C12H13N3O7
  15. Crystal structure of N-ethyl-4-[3-(trifluoromethyl)-phenyl]piperazine-1-carbothioamide, C14H18F3N3S
  16. The crystal structure of 3-anilino-1,4-diphenyl-4H-1,2,4-triazol-1-ium iodide, C20H17N4I
  17. The crystal structure of (tris(2-benzimidazolylmethyl)amine)-benzoato-copper(II) perchlorate monohydrate, CuC31H28N7O7Cl
  18. Crystal structure of [2-hydroxy-3-methyl-benzoato-k1 O-triphenyltin(IV)], C26H22O3Sn
  19. Crystal structure of diaqua-bis(4-(hydroxymethyl)-benzoato-k1 O)zinc(II), C16H18O8Zn
  20. The crystal structure of dicarbonyl-(N-nitroso-N-oxido-phenylamine-κ 2 O,O)-rhodium(I), C8H5N2O4Rh
  21. The crystal structure of oxalic acid – 2-ethoxybenzamide (2/1), C20H24N2O8
  22. The crystal structure of ethyl 7-ethyl-5-methyl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylate, C10H15N5O2
  23. Crystal structure of poly[(N,N-dimethylacetamide-κO) (μ4-2-nitroisophthalato-κ 4 O:O′:O″:O′″)manganese(II)], C11H10N2O7Mn
  24. Crystal structure of 14-O-acetyldelcosine, C26H41NO8
  25. The crystal structure of poly[(1,10-phenanthroline-κ2 N,N′)-(μ 4-2-chlorobenzene-1,3-dicarboxylato-κ5 O:O′:O″:O‴) cadmium(II)] monohydrate, C20H13CdClN2O5
  26. Crystal structure of propane-1,3-diylbis(diphenylphosphine sulfide) ethanol solvate, C27H26P2S2
  27. Crystal structure of bis{[(4-diethylamino-2-hydroxy-benzylidene)-hydrazinocarbonylmethyl]-trimethylammonium} tetrabromozincate, C32H54N8O4ZnBr4
  28. Synthesis and crystal structure of dimethyl 2,2′-(2,5-bis(4-hydroxyphenyl)-2,5-dihydrofuran-3,4-diyl)dibenzoate, C34H30O7
  29. Synthesis and crystal structure of 2-(2-oxo-2-phenylethyl)-4H-chromen-4-one, C17H12O3
  30. The crystal structure of tetra(imidazole-κ1 N)zinc(II) μ2-oxido-hexaoxido-divanadium(VI) C12H16N8O6V2Zn
  31. Crystal structure of S-2-(1-(5-methylpyridin-2-ylamino)octyl)-3-hydroxynaphthalene-1,4-dione, C24H28N2O3
  32. Crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxido-2-oxo-2-phenylethylidene)-benzohydrazonato-κ5 N,O,O′:N′,O′′)-oktakis(pyridine-κ1 N)trinickel(II) – methanol – pyridine (1/1/1) C76H65N13Cl2Ni3O9
  33. The crystal structure of methyl 3,5-diaminobenzoate, C8H10N2O2
  34. Crystal structure of 10-(9H-carbazol-9-yl)-5H-dibenzo[a,d][7]annelen-5-one, C27H17NO
  35. Crystal structure of ethyl 1-(2-hydroxyethyl)-4-((4-methoxyphenyl)amino)-5-oxo-2,5-dihydro-1H-pyrrole-3-carboxylate, C16H20N2O5
  36. The crystal structure of 1-(4-bromophenyl)-3-cycloheptylurea, C14H19BrN2O
  37. The crystal structure of 1,4-bis(1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl)-3,6-bis ((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene)-1,4-dialuminacyclohexane – benzene (1/2), C50H72Al2B2O4
  38. Crystal structure of bis(μ 3-diphenylphosphinato)-tetrakis(μ 2-diphenylphosphinato)-bis(diphenylphosphinato)-bis(μ 2-hydroxo)dicopper(II)-ditin(IV), C104H100O18P8Cu2Sn2
  39. Crystal structure of 3-((3,4-dichloroisothiazol-5-yl)methoxy)benzo[d] isothiazole 1,1-dioxide, C11H6Cl2N2O3S2
  40. Synthesis and crystal structure of 2-(2-(2-fluorophenyl)-2-oxoethyl)-4H-chromen-4-one, C17H11FO3
  41. The crystal structure of tris(carbonyl)-bis(carbonyl)-[μ-propane-1,2- dithiolato]-(benzyldiphenylphosphine)diiron (Fe—Fe), C27H23Fe2O5PS2
  42. Crystal structure of 1-(2-(4-chlorophenethyl)-2-hydroxy-3,3-dimethylbutyl)-1H-1,2,4-triazol-4-ium nitrate, C16H23N4O4Cl
  43. The crystal structure of 3,3′-disulfanediyldi(1H-1,2,4-triazol-5-amine) monohydrate, C4H8N8OS2
  44. The crystal structure of trans-[bis(4-methylpyridine-κN)bis(quinoline-2-carboxylato- κ 2 N,O)cadmium(II)], C32H26CdN4O4
  45. The crystal structure of ethyl 2′-hydroxy-4′,6′-dimethoxy-3-(4-methoxynaphthalen-1-yl)-5-oxo-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxylate, C28H28O7
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© 2025 De Gruyter Brill
Heruntergeladen am 22.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2022-0501/html
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