Home Crystal structure of bis(μ2-diethyldithiocarbamato-κ3S,S′:S′)-bis(tricyclohexylphosphane-κP)dicopper(I), C46H86Cu2N2P2S4
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Crystal structure of bis(μ2-diethyldithiocarbamato-κ3S,S′:S′)-bis(tricyclohexylphosphane-κP)dicopper(I), C46H86Cu2N2P2S4

  • Yi Jiun Tan , Chien Ing Yeo , Nathan R. Halcovitch and Edward R.T. Tiekink EMAIL logo
Published/Copyright: March 10, 2018
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 233 Issue 3

Abstract

C46H86Cu2N2P2S4, triclinic, P1̄ (no. 2), a = 9.9626(3) Å, b = 11.0489(3) Å, c = 12.3604(3) Å, α = 106.205(3)°, β = 99.165(2)°, γ = 100.306(3)°, V = 1253.53(6) Å3, Z = 1, Rgt(F) = 0.0232, wRref(F2) = 0.0555, T = 100(2) K.

CCDC no.: 1825489

The structure of the title complex is shown in the figure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Yellow prism
Size:0.53 × 0.30 × 0.10 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:11.1 cm−1
Diffractometer, scan mode:SuperNova Dual, ω scans
2θmax, completeness:59.4°, 88.4%
N(hkl)measured, N(hkl)unique, Rint:25023, 6283, 0.026
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 5853
N(param)refined:255
Programs:Rigaku programs [1], SHELX [2, 3] , ORTEP [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Cu0.12237(2)0.49233(2)0.56887(2)0.01060(5)
N10.19361(11)0.79619(10)0.41105(9)0.0150(2)
P10.28568(3)0.59326(3)0.73101(3)0.00891(6)
S10.12240(3)0.54656(3)0.39823(2)0.01103(6)
S2−0.03819(3)0.73773(3)0.48691(3)0.01220(7)
C10.10318(12)0.70499(12)0.43227(10)0.0114(2)
C20.30950(14)0.76790(14)0.35599(12)0.0195(3)
H2A0.34130.69580.37680.023*
H2B0.38890.84510.38540.023*
C30.26620(17)0.73107(18)0.22524(13)0.0303(4)
H3A0.19180.65130.19540.045*
H3B0.34700.71700.19160.045*
H3C0.23190.80120.20450.045*
C40.18069(15)0.93151(13)0.44115(12)0.0212(3)
H4A0.08050.93310.43010.025*
H4B0.22160.97320.38880.025*
C50.25463(17)1.00744(14)0.56534(14)0.0300(3)
H5A0.21330.96710.61740.045*
H5B0.24411.09690.58280.045*
H5C0.35421.00740.57600.045*
C110.46488(12)0.62587(12)0.70495(10)0.0116(2)
H110.48150.53940.66560.014*
C120.47318(13)0.70237(14)0.61921(11)0.0185(3)
H12A0.45830.78980.65430.022*
H12B0.39810.65750.54890.022*
C130.61556(14)0.71546(15)0.58591(12)0.0224(3)
H13A0.62620.62860.54360.027*
H13B0.62000.76920.53390.027*
C140.73512(13)0.77773(14)0.69273(11)0.0197(3)
H14A0.82580.78050.66920.024*
H14B0.73020.86790.73070.024*
C150.72666(13)0.70130(13)0.77774(11)0.0162(3)
H15A0.80230.74550.84780.019*
H15B0.74060.61370.74210.019*
C160.58515(12)0.68917(12)0.81185(10)0.0126(2)
H16A0.57470.77630.85360.015*
H16B0.58100.63620.86450.015*
C210.29670(12)0.49601(12)0.83101(10)0.0114(2)
H210.36540.55000.90430.014*
C220.34733(14)0.37356(12)0.77842(11)0.0158(3)
H22A0.28460.32300.70240.019*
H22B0.44270.39910.76600.019*
C230.34917(15)0.28893(13)0.85759(12)0.0202(3)
H23A0.37540.20810.81890.024*
H23B0.42100.33560.92970.024*
C240.20768(16)0.25474(13)0.88752(12)0.0228(3)
H24A0.21510.20530.94290.027*
H24B0.13800.19900.81670.027*
C250.15820(15)0.37659(13)0.94044(11)0.0192(3)
H25A0.06390.35160.95510.023*
H25B0.22280.42831.01530.023*
C260.15317(13)0.45857(12)0.85934(11)0.0145(2)
H26A0.12360.53830.89600.017*
H26B0.08300.40910.78690.017*
C310.26895(12)0.75415(11)0.82070(10)0.0104(2)
H310.32460.82030.79380.012*
C320.32714(13)0.79275(12)0.95165(10)0.0127(2)
H32A0.27470.73060.98310.015*
H32B0.42650.78850.96640.015*
C330.31514(13)0.93010(12)1.01325(11)0.0147(2)
H33A0.37470.99310.98710.018*
H33B0.34950.95101.09760.018*
C340.16414(13)0.94275(12)0.98858(11)0.0153(2)
H34A0.10590.88581.02110.018*
H34B0.16001.03331.02610.018*
C350.10698(13)0.90498(12)0.85875(11)0.0155(2)
H35A0.16050.96690.82770.019*
H35B0.00800.91050.84400.019*
C360.11688(12)0.76766(12)0.79637(11)0.0134(2)
H36A0.08220.74730.71220.016*
H36B0.05700.70490.82250.016*

Source of materials

The title complex was prepared from the in situ reaction of CuCl, Cy3P and Na[S2CNEt2] in a 1:1:1 ratio. Cy3P (Sigma–Aldrich; 1.0 mmol, 0.283 g) dissolved in hexane (10 mL) was added to a hexane solution (10 mL) of CuCl (Sigma–Aldrich; 1.0 mmol, 0.100 g). The temperature of reaction was maintained at below 4 °C. Then, Na[S2CNEt2] (BDH, 1.0 mmol, 0.250 g) in hexane (10 mL) was added to the reaction mixture, followed by stirring for 4 h. The resulting mixture was filtered and left for evaporation at room temperature to yield bright-yellow crystals. Yield: 0.239 (68.7%). M.p.: 418–420 K. IR (cm−1): 2909 (s), 2843 (s) ν(C—H); 1474 (s) ν(C—N); 1072 (m), 995 (m) ν(C–S).

Experimental details

The C-bound H atoms were geometrically placed (C–H = 0.98–1.00 Å) and refined as riding with Uiso(H) = 1.2–1.5 Ueq(C).

Comment

The initial interest in complexes related to the title compound, i.e. of general formula [R3PCu(S2CNRR′)]2, R, R′ = alkyl or aryl, arose as a result of the desire to generate more efficacious synthetic precursors for copper sulfide nanomaterials [5]. Thus, the addition of base, in this case triorganophosphanes with relatively small R substituents, disrupted the polymeric structure of [Cu(S2CNRR′)]n to provide soluble materials that were more suitable for decomposition studies. However, it was in recognition of the biological potential of metal dithiocarbamates [6] that prompted more recent investigations into these types of ternary compounds. Specifically, a recent report [7] highlighted the species-specific anti-microbial activity of certain (Ph3P)2Cu(S2CNRR′) derivatives and it was this observation that prompted the synthesis of the title compound, [Cy3PCu(S2CNEt2)]2.

As seen from the Figure (70% displacement ellipsoids; the C4 atom is obscured), the title compound is binuclear and indeed, disposed about a centre of inversion; unlabelled atoms are related by the symmetry operation: −x, 1 − y, 1 − z. The diethyldithiocarbamate ligand is μ2-bridging, chelating one copper(I) centre, while simultaneously binding to a second via one of the sulfur atoms only. The bridging Cu—S1 bond length of 2.5169(3) Å is systematically longer than the chelating Cu—S1i, S2i bond lengths of 2.3480(3) and 2.3905(3) Å; the internal Cu⋯Cui separation is 2.8034(3) Å. These variations are reflected in the associated C—S bond lengths with the bond formed by the bridging-S1 atom being systematically longer than the bond involving the chelating-S2 atom, i.e. 1.7356(13) cf. 1.7087(13) Å. The pattern in Cu—S bond lengths implies the central Cu2S2 core is rectangular. The overall Cu2S4 arrangement resembles a partial step-ladder as the edge-shared CuS2 triangles lie above and below the plane through the central core. The four-coordinate geometry of the copper(I) atom is completed by a phosphane-P atom and the resultant PS3 donor set approximates a tetrahedron but, with significant distortions. Thus, the smallest angle subtended at copper(I) of 73.827(11)° corresponds to the chelate angle and the widest angle of 123.178(12)° corresponds to S1—Cu—P1, i.e. involving the bridging-S1 and sterically crowded phosphorous atoms.

There are two direct literature precedents for the structure of the title compound, namely [R3PCu(S2CNEt2)]2 for R = Me and Et [5]. These adopt the same structural motif and they are both located around a inversion centre.

Acknowledgements

Sunway University is thanked for support of biological and crystal engineering studies of metal dithiocarbamates.

References

Rigaku/Oxford Diffraction: CrysAlisPRO. Rigaku Corporation, The Woodlands, TX, USA (2015).Search in Google Scholar

Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed

Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central

Farrugia, L. J.: WinGX and ORTEP for Windows: an update. J. Appl. Cryst. 45 (2012) 849–854.10.1107/S0021889812029111Search in Google Scholar

Afzaal, M.; Rosenberg, C. L.; Malik, M. A.; White, A. J. P.; O’Brien, P.: Phosphine stabilized copper(I) complexes of dithiocarbamates and xanthates and their decomposition pathways. New J. Chem. 35 (2011) 2773–2780.10.1039/c1nj20586bSearch in Google Scholar

Hogarth, G.: Metal-dithiocarbamate complexes: chemistry and biological activity. Mini Rev. Med. Chem. 12 (2012) 1202–1215.10.2174/138955712802762095Search in Google Scholar PubMed

Jamaludin, N. S.; Halim, S. N. A.; Khoo, C.-H.; Chen, B.-J.; See, T.-H.; Sim, J.-H.; Cheah, Y.-K.; Seng, H.-L.; Tiekink, E. R. T.: Bis(phosphane)copper(I) and silver(I) dithiocarbamates: crystallography and anti-microbial assay. Z. Kristallogr. − CM 231 (2016) 341–349.10.1515/zkri-2016-0003Search in Google Scholar

Received: 2017-12-12
Accepted: 2018-2-23
Published Online: 2018-3-10
Published in Print: 2018-5-24

©2018 Yi Jiun Tan et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

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  2. Bis(tetraethylammonium) carbonate – boric acid – water (1/2/5), C17H56B2N2O14
  3. Crystal structure of 4-methoxy-6-phenyl-2H-pyran-2-one, C12H10O3
  4. Crystal structure of tris{(3-((E)-(((E)-2-oxidobenzylidene)hydrazono)methyl)-2-oxo-2H-chromen-4-olato-κ3O,N:N′)}dicobalt(III)tris(dimethylformamide), C60H50Co2N9O15
  5. Crystal structure of poly[bis(1-methyl-[4,4′-bipyridin]-1-ium-κN)-tetrakis(μ3-sulfato-κ3O:O′:O′′)trizinc(II)], C22H22Zn3N4O16S4
  6. Crystal structure of (5Z,10Z)-3,13-dichloro-17,18-dioxo-5,11-diphenyl-8,9,17,18-tetrahydro-7H-dibenzo[e,n][1,4,8,12]tetraazacyclopentadecine-16,19-diido-κ4N,N′,N′′,N′′′)copper(II), C31H22N4O2Cl2Cu
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  8. Crystal structure of 2,2′-((((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))diphenolato-κ2N;κ4O)nickel(II), C28H22N2O4Ni
  9. Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)cobalt(II), C36H26N2O4Co
  10. Crystal structure of camptothecin, C20H16N2O4
  11. Crystal structure of (2-(chlorophenyl)-5-methyl-1,3-dioxane-5-carboxylato–κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, Ni(C16H36N4)(C12H12O4Cl)ClO4⋅H2O
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  16. Crystal structure of catena-poly[triaqua(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)-(1,2-bis(4-pyridyl)ethane-κN)nickel(II)] 2-aminonicotinate nitrate – 1,2-bis(4-pyridyl)ethane – water (2/1/8), C36H44N8NiO12
  17. Hydrothermal synthesis and crystal structure of poly[bis(μ2-3-(3,5-dicarboxyphenoxy)phthalato-κ3O,O′:O′′)-(μ2-1,2-di(pyridin-4-yl)ethane-κ2N:N′)copper(II)], C22H14CuNO9
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  19. The crystal structure of 6-(4-bromobenzyl)-1,3,5-trimethyl-7-phenyl-1,5-dihydro-2H-pyrrolo[3,2-d]pyrimidine-2,4(3H)-dione, C22H20BrN3O2
  20. Synthesis and crystal structure of catena-poly[bis(2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κO;κ2O′,O′′)-(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)zinc(II)], C44H32N4ZnCl4O4
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  51. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-di(ethanol)-bis{μ2-5-(N,N′-diethylamine)-5′-methoxyl-2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato-κ6O:O,N,N,O′:O′}trinickel(II) – ethanol – acetonitrile (1/2/2), C58H86Ni3N8O18
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  54. Crystal structure of bis(μ2-diethyldithiocarbamato-κ3S,S′:S′)-bis(tricyclohexylphosphane-κP)dicopper(I), C46H86Cu2N2P2S4
  55. Crystal structure of N-(3-chlorophenyl)ethoxycarbothioamide, C9H10ClNOS
  56. Crystal structure of bis(μ2-pyrrolidine-1-carbodithioato-κ3S,S′:S;κ3S:S:S′)-bis(tricyclohexylphosphane-P)-di-copper(I), C46H82Cu2N2P2S4
  57. Crystal structure of N-(2-chlorophenyl)methoxycarbothioamide, C8H8ClNOS
  58. Crystal structure of chlorido-methanol-(N-(2-(oxy)-3-methoxybenzylidene)pyridine-4-carbohydrazonato-κ3O,N,O′)-(4-methylphenyl)methyl-tin(IV), C23H24ClN3O4Sn
  59. Crystal structure of N-(3-chlorophenyl)(propan-2-yloxy)carbothioamide, C10H12ClNOS
  60. Crystal structure of 1-[(Z)-[4-(4-methoxyphenyl)butan-2-ylidene]amino]-3-phenylurea, C18H21N3O2
  61. A triclinic polymorph of bis(μ-N,N-bis(2-hydroxyethyl)dithiocarbamato-κ3S,S′:S′) bis(N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S:S′)zinc(II), C20H40N4O8S8Zn2
https://doi.org/10.1515/ncrs-2017-0402
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Bis(tetraethylammonium) carbonate – boric acid – water (1/2/5), C17H56B2N2O14
  3. Crystal structure of 4-methoxy-6-phenyl-2H-pyran-2-one, C12H10O3
  4. Crystal structure of tris{(3-((E)-(((E)-2-oxidobenzylidene)hydrazono)methyl)-2-oxo-2H-chromen-4-olato-κ3O,N:N′)}dicobalt(III)tris(dimethylformamide), C60H50Co2N9O15
  5. Crystal structure of poly[bis(1-methyl-[4,4′-bipyridin]-1-ium-κN)-tetrakis(μ3-sulfato-κ3O:O′:O′′)trizinc(II)], C22H22Zn3N4O16S4
  6. Crystal structure of (5Z,10Z)-3,13-dichloro-17,18-dioxo-5,11-diphenyl-8,9,17,18-tetrahydro-7H-dibenzo[e,n][1,4,8,12]tetraazacyclopentadecine-16,19-diido-κ4N,N′,N′′,N′′′)copper(II), C31H22N4O2Cl2Cu
  7. Crystal structure of bis{5-methoxy-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2N,O}zinc(II), C34H24N2O8Zn
  8. Crystal structure of 2,2′-((((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))diphenolato-κ2N;κ4O)nickel(II), C28H22N2O4Ni
  9. Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)cobalt(II), C36H26N2O4Co
  10. Crystal structure of camptothecin, C20H16N2O4
  11. Crystal structure of (2-(chlorophenyl)-5-methyl-1,3-dioxane-5-carboxylato–κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, Ni(C16H36N4)(C12H12O4Cl)ClO4⋅H2O
  12. Crystal structure of 3-(2-chloro-6-methoxyquinolin-3-yl)-5-phenylisoxazole (C19H13ClN2O2)
  13. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)-bis{[(E)-2,6-diisopropyl-N-(pyridin-3-ylmethylene)aniline]copper (II)}, C44H56Cu2N4O8
  14. Crystal structure of diethyl 2-(2-chlorophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19Cl1O6
  15. Crystal structure of (μ2-2,2′-bipyridine-3,3′-dicarboxylato)-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-di-nickel(II) perchlorate N,N′-dimethylformamide solvate, C50H92Cl2N12Ni2O14
  16. Crystal structure of catena-poly[triaqua(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)-(1,2-bis(4-pyridyl)ethane-κN)nickel(II)] 2-aminonicotinate nitrate – 1,2-bis(4-pyridyl)ethane – water (2/1/8), C36H44N8NiO12
  17. Hydrothermal synthesis and crystal structure of poly[bis(μ2-3-(3,5-dicarboxyphenoxy)phthalato-κ3O,O′:O′′)-(μ2-1,2-di(pyridin-4-yl)ethane-κ2N:N′)copper(II)], C22H14CuNO9
  18. Crystal structure of catena-poly[aqua-(methanol-κO)-bis(μ2-4-(pyridin-4-yl)benzoato-κ2N:O)-bis(triphenylphospine-κP)disilver(I)], C61H52Ag2N2O6P2
  19. The crystal structure of 6-(4-bromobenzyl)-1,3,5-trimethyl-7-phenyl-1,5-dihydro-2H-pyrrolo[3,2-d]pyrimidine-2,4(3H)-dione, C22H20BrN3O2
  20. Synthesis and crystal structure of catena-poly[bis(2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κO;κ2O′,O′′)-(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)zinc(II)], C44H32N4ZnCl4O4
  21. Crystal structure of diaqua-bis[N-phenyl-2-(quinolin-8-yloxy)acetamide-κ3-N,O,O′]-nitrato(κ2O,O′)-cerium(III) dinitrate - acetone (1/2), C40H44N7O17Ce
  22. Crystal structure of the 2D coordination polymer poly[aqua(μ2-2,2′-(1,2-phenylene)diacetato-κ3O,O′:O′)-(μ2-4,4′-bis((1H-1,2,4-triazol-1-yl)methyl)-1,1′-biphenyl-κ2N:N′)cobalt(II)], C28H26CoN6O5
  23. Crystal structure of (dimethylformamide-κO)(perchlorato-κ2O,O′){μ2-6,6′-((1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(4-bromo-2-methoxyphenolate)-κ8N,N′,O:O,O′:O′,O′′,O′′′}sodium(I)nickel(II), C25H23Br2ClN3NaNiO9
  24. The crystal structure of catena-poly[bis((4-aminophenyl)sulfonyl)(pyrimidin-2-yl)amido-κ2N,N′)-bis(μ2-4,4′-bipyridine-N,N′-κ2N:N′)zinc(II) – methanol (1/2), C32H34N10O6S2Zn
  25. Synthesis and crystal structure poly[aqua(μ3-2-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio)acetate-κ4O,O′:O′′:O′′′) sodium] monohydrate, C18H18NNaO11S
  26. Crystal structure of methyl 4′-amino-3′,5′-diisopropyl-[1,1′-biphenyl]-4-carboxylate, C20H25NO2
  27. Crystal structure of (η6-1-isopropyl-4-methyl benzene)-(N-(2,5-dichlorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) perchlorate, C22H22Cl4N2O4Ru
  28. Crystal structure of 2-(2-(1-Chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl)-1H-1,2,4-triazole-3(2H)-thione, C14H15Cl2N3OS
  29. Crystal structure of methyl 4′-amino-3′,5′-dimethyl-[1,1′-biphenyl]-4-carboxylate, C16H17NO2
  30. The crystal structure of 1-(5-ferrocenyl-3-(trifluoromethyl)-1H-pyrazol-1-yl)pentan-1-on, C19H19F3FeN2O
  31. The crystal structure of (3S,12R,20R,24S)-3,12-diacetyl-20,24-epoxy-dammarane-3,12,25-triol acetone solvate, C34H56O6
  32. Crystal structure of methyl 10-(pyridin-4-yl)-anthracene-9-carboxylate, C21H15NO2
  33. Crystal structure of catena-poly[diaqua-bis(di(N2,N6-dihydroxypyridine-2,6-dicarboxamide))potassium(I)]tetrahydrate, C14H25N6O14K
  34. Crystal structure of poly{[μ2-(E)-1,4-bis(1H-benzo[d]imidazol-1-yl)but-2-ene-κ2N:N′][μ3–cyclohexane-1,4-dicarboxylato-κ4O,O′:O′′:O′′′]cadmium(II)}, C26H26CdN4O4
  35. Crystal structure of poly[aqua(μ3-[2,2′-bipyridine]-3,3′-dicarboxylato-κ4N,N′:O:O′)zinc(II)] – dimethylformamide (1/1), C15H15N3O6Zn
  36. The crystal structure of poly[tetraaqua-tris(μ2-2,6-di(1H-imidazol-1-yl)naphthalene-κ2N:N′)-bis(thiophene-2,5-dicarboxylato-κ1O)]dicobalt(II), C30H24CoN6O6S
  37. Crystal structure of (S)-1-(5-(anthracen-9-yl)-3-phenyl-4,5-dihydro-1H-pyrazol-1-yl)propan-1-one, C26H22N2O
  38. Crystal structure of 5-methyl-3,3-diphenyl-1-tosyl-1,2,3,4-tetrahydropyridine, C25H25NO2S
  39. Synthesis and crystal structure of μ-[1,1′-di(mesitylphosphanido)ferrocene]bis[η5-cyclopentadienylnickel(II)] tetrahydrofurane solvate, C42H48FeNi2OP2
  40. Synthesis and crystal structure of (E)-1-(4-(((E)-5-chloro-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H15ClN2O2
  41. Crystal structure of bis(1-(phenylsulfonyl)-2-(1-(pyrazin-2-yl)ethylidene)hydrazin-1-ido-κ3N,N′,O)nickel(II), C24H22N8O4S2Ni
  42. Crystal Structure of bis(1-(phenylsulfonyl)-2-(1-(pyrazin-2-yl)ethylidene)hydrazin-1-ido-κ3N,N′,O)copper(II), C24H22N8O4S2Cu
  43. Synthesis and crystal structure of poly[aqua{μ3-(1S,2S)-1-((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)pyrrolidin-1-ium-2-carboxylato-κ4O,O′:O′′:O′′′}sodium(I)] monohydrate, C21H22NNaO11S
  44. Halogen bonds in the crystal structure of 1,4-diiodotetrafluorobenzene–1,2-bis(4-pyridyl)propane (1/1), C19H14F4I2N2
  45. Crystal structure of bis(μ-N-i-propyl-N-n-propyldithiocarbamato-κ2S:S′) bis(N-i-propyl-N-n-propyldithiocarbamato-κ2S,S′)dizinc(II), C28H56N4S8Zn2
  46. Crystal structure of bis(μ-N-i-propyl-N-n-propyldithiocarbamato-κ3S,S′:S)bis(N-i-propyl-N-n-propyldithiocarbamato-κ2S,S′)dicadmium(II), C28H56Cd2N4S8
  47. Crystal structure of bis(μ2-di-n-butyldithiocarbamato-κ3S,S′:S;κ3S:S:S′)-hexacarbonyl-di-rhenium(I), C24H36N2O6Re2
  48. Crystal structure of 7-(4-methylphenyl)imidazo[1,2-a][1,3,5]triazin-4-amine, C12H11N5
  49. Crystal structure of the co-crystal O-isopropyl phenylcarbamothioate – 4,4′-bipyridine (2/1), C15H17N2OS
  50. Crystal structure of the coordination polymer catena-poly[chlorido-{μ2-2-(((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amino)-3-hydroxybutanoato-κ4N,N,O:O′}copper(II)], C11H16ClCuN2O3
  51. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-di(ethanol)-bis{μ2-5-(N,N′-diethylamine)-5′-methoxyl-2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato-κ6O:O,N,N,O′:O′}trinickel(II) – ethanol – acetonitrile (1/2/2), C58H86Ni3N8O18
  52. Crystal structure of the bis((E)-O-ethyl-N-phenylthiocarbamate) – 4,4′-bipyridine co-crystal (2/1), C28H30N4O2S2
  53. Crystal structure of the (E)-O-methyl-N-phenyl-thiocarbamate – 4,4′-bipyridine (1/1), C18H17N3OS
  54. Crystal structure of bis(μ2-diethyldithiocarbamato-κ3S,S′:S′)-bis(tricyclohexylphosphane-κP)dicopper(I), C46H86Cu2N2P2S4
  55. Crystal structure of N-(3-chlorophenyl)ethoxycarbothioamide, C9H10ClNOS
  56. Crystal structure of bis(μ2-pyrrolidine-1-carbodithioato-κ3S,S′:S;κ3S:S:S′)-bis(tricyclohexylphosphane-P)-di-copper(I), C46H82Cu2N2P2S4
  57. Crystal structure of N-(2-chlorophenyl)methoxycarbothioamide, C8H8ClNOS
  58. Crystal structure of chlorido-methanol-(N-(2-(oxy)-3-methoxybenzylidene)pyridine-4-carbohydrazonato-κ3O,N,O′)-(4-methylphenyl)methyl-tin(IV), C23H24ClN3O4Sn
  59. Crystal structure of N-(3-chlorophenyl)(propan-2-yloxy)carbothioamide, C10H12ClNOS
  60. Crystal structure of 1-[(Z)-[4-(4-methoxyphenyl)butan-2-ylidene]amino]-3-phenylurea, C18H21N3O2
  61. A triclinic polymorph of bis(μ-N,N-bis(2-hydroxyethyl)dithiocarbamato-κ3S,S′:S′) bis(N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S:S′)zinc(II), C20H40N4O8S8Zn2
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