Home Crystal structure of the 2D coordination polymer poly[aqua(μ2-2,2′-(1,2-phenylene)diacetato-κ3O,O′:O′)-(μ2-4,4′-bis((1H-1,2,4-triazol-1-yl)methyl)-1,1′-biphenyl-κ2N:N′)cobalt(II)], C28H26CoN6O5
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Crystal structure of the 2D coordination polymer poly[aqua(μ2-2,2′-(1,2-phenylene)diacetato-κ3O,O′:O′)-(μ2-4,4′-bis((1H-1,2,4-triazol-1-yl)methyl)-1,1′-biphenyl-κ2N:N′)cobalt(II)], C28H26CoN6O5

  • Xin Ling-Yun , Li Yun-Ping and Liu Guang-Zhen EMAIL logo
Published/Copyright: March 8, 2018
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 233 Issue 3

Abstract

C28H26CoN6O5, monoclinic, P21/c (no. 14), a = 13.2393(8) Å, b = 8.6608(5) Å, c = 22.4553(12) Å, β = 91.073(2)°, V = 2574.3(3) Å3, Z = 4, Rgt(F) = 0.0327, wRref(F2) = 0.0804, T = 293(2) K.

CCDC no.:: 1824812

The asymmetric unit of the title crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Block, pink
Size:0.35 × 0.31 × 0.26 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.72 mm−1
Diffractometer, scan mode:Bruker SMART, φ and ω-scans
θmax, completeness:25.4°, >99%
N(hkl)measured, N(hkl)unique, Rint:16323, 4699, 0.038
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3577
N(param)refined:361
Programs:Bruker programs [1], SHELX [2, 3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Co10.42169(2)−0.00080(3)0.31041(2)0.03048(10)
O10.43535(11)−0.05030(16)0.22128(6)0.0364(3)
O20.34097(12)0.14089(17)0.18354(6)0.0446(4)
O30.57726(11)0.25837(16)0.16606(6)0.0427(4)
O40.58036(11)0.43043(18)0.09544(6)0.0408(4)
O5W0.40444(11)0.23913(15)0.29330(6)0.0407(4)
H5WA0.37910.23520.25730.061*
H5WB0.46080.30900.29090.061*
N10.57931(13)0.02332(19)0.32356(7)0.0366(4)
N20.74043(15)0.0834(3)0.30574(8)0.0513(5)
N30.73292(13)0.00854(19)0.35856(8)0.0376(4)
N41.10765(13)0.5696(2)0.77934(8)0.0380(4)
N51.09534(15)0.4409(3)0.81235(9)0.0529(5)
N61.25900(13)0.50492(19)0.80771(7)0.0362(4)
C10.39275(17)0.0238(2)0.17847(9)0.0343(5)
C20.4083(2)−0.0483(3)0.11747(9)0.0538(7)
H2A0.4778−0.08280.11540.065*
H2B0.3655−0.13890.11410.065*
C30.38625(17)0.0550(2)0.06473(9)0.0369(5)
C40.29045(18)0.0508(3)0.03806(10)0.0459(6)
H40.2416−0.01470.05320.055*
C50.26695(19)0.1424(3)−0.01062(10)0.0517(7)
H50.20270.1384−0.02800.062*
C60.3385(2)0.2391(3)−0.03330(10)0.0526(7)
H60.32290.3006−0.06620.063*
C70.43258(19)0.2451(3)−0.00762(9)0.0444(6)
H70.48050.3118−0.02310.053*
C80.45836(16)0.1538(2)0.04108(8)0.0354(5)
C90.56563(17)0.1650(3)0.06586(11)0.0524(7)
H9A0.58460.06720.08390.063*
H9B0.61140.18510.03360.063*
C100.57573(15)0.2921(3)0.11189(9)0.0352(5)
C110.63822(17)−0.0273(2)0.36778(10)0.0415(6)
H110.6155−0.08100.40080.050*
C120.64607(17)0.0883(3)0.28686(10)0.0443(6)
H120.62690.13330.25080.053*
C130.82243(18)−0.0323(3)0.39433(11)0.0493(6)
H13A0.8798−0.03880.36820.059*
H13B0.8122−0.13390.41130.059*
C140.84791(16)0.0790(3)0.44417(10)0.0411(5)
C150.78959(18)0.0859(3)0.49457(11)0.0494(6)
H150.73090.02700.49630.059*
C160.81664(17)0.1779(3)0.54209(10)0.0451(6)
H160.77680.17820.57580.054*
C170.90186(16)0.2702(2)0.54089(9)0.0373(5)
C180.95840(18)0.2670(3)0.48959(10)0.0529(7)
H181.01520.32970.48700.063*
C190.93207(18)0.1725(3)0.44206(10)0.0538(6)
H190.97160.17210.40830.065*
C200.93182(16)0.3656(2)0.59330(9)0.0366(5)
C210.86153(16)0.4265(3)0.63187(10)0.0427(5)
H210.79320.40860.62450.051*
C220.89053(17)0.5130(3)0.68099(10)0.0430(6)
H220.84170.55200.70620.052*
C230.99184(17)0.5421(2)0.69304(10)0.0395(5)
C241.06258(17)0.4819(3)0.65524(11)0.0468(6)
H241.13090.49960.66300.056*
C251.03363(17)0.3959(3)0.60604(10)0.0451(6)
H251.08270.35730.58100.054*
C261.02305(18)0.6391(3)0.74612(10)0.0481(6)
H26A1.04230.74120.73260.058*
H26B0.96600.65060.77230.058*
C271.20434(17)0.6050(3)0.77703(10)0.0415(5)
H271.23030.68900.75650.050*
C281.18794(18)0.4085(3)0.82822(10)0.0486(6)
H281.20400.32410.85220.058*

Source of material

All reagents used in these syntheses were of analytical grade and used as purchased without further purification. The mixtures of 1,2-phenylenediacetic acid (phda) (0.1 mmol, 19.4 mg), 4,4′-bis((1H-1,2,4-triazol-1-yl)methyl)-1,1′-biphenyl (btmb) (0.1 mmol, 31.6 mg), Co(H3C2O2)2⋅4H2O (0.1 mmol, 24.9 mg), NaOH (0.1 mmol), and H2O (6.0 mL) were placed in a 23 mL Teflon liner stainless steel reactor. The vessel was heated to 393 K for 4 days, and then slowly cooled to room temperature. Pink crystals were obtained, and further crystals were filtered off, washed with mother liquid, and dried under ambient conditions. Yield 46%.

Experimental details

All hydrogen atoms were placed in calculated positions and refined isotropically with a riding model except for those bound to water molecules, which were initially located in a difference Fourier map and included in the final refinement by use of geometrical restraints with the O—H distances being fixed at 0.85 Å and Uiso(H) equivalent to 1.5 times of Ueq(O). All calculations were performed using the SHELXL-2014/7 program package [2, 3] .

Discussion

As is known, the self-assembly of discrete coordination polymers (CPs) is highly determined by the ligand with certain features such as flexibility, appropriate angles, and versatile binding modes to coordinate to the metal ion with plastic coordination geometry [4], [5], [6]. Recently, a large number of CPs have been reported by using mixed-ligand strategy [7], [8], [9], most of which was based on the combination of metal-polycarboxylate and N-donor molecules, because this strategy can offer chance for new coordination polymers. Among them, benzene multi-carboxylates with long-spanning carboxyl groups has been used by us and others [10, 11] , making structures including helices and interpenetrating networks that may be attributed to the flexibility of carboxyl groups. At same time, the dipyridyl-type molecules are widely used coligands that can pillar polycarboxylate motifs into high dimensional structures [12], [13], [14].

The asymmetric unit of complex contains one cobalt atom, one phda anion, one btmb molecule and one ligated water molecule. Each Co atom is octahedrally coordinated by three carboxylate O donors of two symmetry-related phda anions and one coordinated water molecule in the equatorial plane with two N donors of two symmetry-related btmb ligands in the axial positions. The Co—O bond lengths are in the range of 2.0586(15)–2.1963(15) Å and the Co—N bond lengths are 2.1113(19) and 2.1508(19) Å, respectively. Both carboxylate groups of the phda ligand bridge adjacent Co(II) centers by a monodentate bridging and a bidentate chelating mode to form zigzag carboxylate chains running along the crystallographic b axis. The adjacent chains are further interconnected to each other through the btmb molecules resulting in stepwise (4,4) grids layer. Each layer is corrugated with two btmb ligands, two phda anion, and four Co atoms forming repeating rhombic grid with a side length of 5.5338(4)–17.7382(8) Å. Furthermore, the presence of coordinated water molecules leads to the formation of extensive H-bonding scheme within the layers (O(5W)–H(2W)⋯O(1)) and (O(5W)–H(1W)⋯O(2)). Interestingly, no H-bonds are observed between the layers, which stack in a slightly off-set parallel fashion and are cohered only by the van der Waals forces to complish its entire structure.

Acknowledgements

This work was supported by the Foundation of Science and Technology of Henan Province (No. 152102310348) and the Foundation of Education Committee of Henan Province (No. 15A150063).

References

Bruker. APEX2, SAINT and SADABS. Brucker AXS Inc., Madison, WI, USA (2012).Search in Google Scholar

Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed

Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central

Dai, F. N.; Dou, J. M.; He, H. Y.; Zhao, X. L.; Sun, D. F.: Self-assembly of metal-organic supramolecules: from a metallamacrocycle and a metal-organic coordinationcage to 1D or 2D coordination polymers based on flexible dicarboxylate ligands. Inorg. Chem. 49 (2010) 4117–4124.10.1021/ic902178cSearch in Google Scholar PubMed

Wang, C.; Liu, D. M.; Lin, W. B.: Metallorganic frameworks as a tunable platform for designing functional molecular materials. J. Am. Chem. Soc. 135 (2013) 13222–13234.10.1021/ja308229pSearch in Google Scholar PubMed PubMed Central

Schoedel, A.; Jaquier, M.; Boyette, W.; Wojtas, L.; Eddaoudi, M.; Zaworotko, M. J.: 4,6-Connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes. Cryst. Growth Des. 14 (2014) 2115–2117.10.1021/cg500205fSearch in Google Scholar

Xin, L. Y.; Liu, G. Z.; Ma, L. F.; Zhang, X.; Wang, L. Y.: Structural diversity and fluorescence regulation of three ZnII coordination polymers assembled from mixed ligands tectons. Aust. J. Chem. 68 (2015) 758–765.10.1071/CH14347Search in Google Scholar

Hou, X. Y.; Wang, X.; Wang, H.; Cao, J.; Fu, F.; Wang, J. J.; Gao, L. J.: Visible-light-driven photocatalysts of two copper(II) coordination polymers with rare sulfonate and imidazole co-ligand system. Z. Anorg. Allg. Chem. 641 (2015) 1316–1321.10.1002/zaac.201500053Search in Google Scholar

Li, G. L.; Liu, G. Z.; Xin, L. Y.; Li, X. L.; Ma, L. F.; Wang, L. Y.: Syntheses, structures and fluorescence properties of four Zn/Cd(II) coordination polymers with 3-nitrobenzene-1,2-dicarboxylate and dipyridyl-typed coligands. J. Inorg. Organomet. Polym. 25 (2015) 694–701.10.1007/s10904-014-0147-4Search in Google Scholar

Li, X. L.; Liu, G. Z.; Xin, L. Y.; Li, G. L.: Synthesis, crystal structure, and properties of two 2D lamella coordination polymers generated from unsymmetrically carboxylate bridging ligand. Synth. React. Inorg. Met. Org. Chem. 45 (2015) 914–920.10.1080/15533174.2013.769595Search in Google Scholar

Liu, G. Z.; Li, X. L.; Xin, L. Y.; Wang, L. Y.: Two topologically new trinodal cobalt(II) metalorganic frameworks characterized as a 1D metallic oxide and a 2D-3D penetrated porous solid. CrystEngComm 14 (2012) 5315–5321.10.1039/c2ce25556aSearch in Google Scholar

Sezer, G. G.; Arici, M.; Erucar, L.; Yesilel, O. Z.; Ozel, H. U.; Gemici, B. T.; Erer, H.: Zinc(II) and cadmium(II) coordination polymers containing phenylenediacetate and 4,4′-azobis(pyridine) ligands: syntheses, structures, dye adsorption properties and molecular dynamics simulations. J. Solid State Chem. 255 (2017) 89–96.10.1016/j.jssc.2017.08.002Search in Google Scholar

Xin, L. Y.; Li, Y. P.; Ju, F. Y.; Li, X. L.; Liu, G. Z.: Syntheses, structure and luminescent detection for trace Ag+ of a coordination polymer with lewis basic sites. Chinese J. Inorg. Chem. 33 (2017) 1474–1480.Search in Google Scholar

Ren, C.; Zhang, Y. N.; Shi, W. J.; Liu, B.; Wang, Y. Y.; Shi, Q. Z.: Structural diversity of coordination polymers assembled from adamantane dicarboxylates and conformational bis-triazole ligand. CrystEngComm 13 (2011) 5179–5189.10.1039/c1ce05299cSearch in Google Scholar

Received: 2017-11-6
Accepted: 2018-2-20
Published Online: 2018-3-8
Published in Print: 2018-5-24

©2018 Xin Ling-Yun et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

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  50. Crystal structure of the coordination polymer catena-poly[chlorido-{μ2-2-(((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amino)-3-hydroxybutanoato-κ4N,N,O:O′}copper(II)], C11H16ClCuN2O3
  51. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-di(ethanol)-bis{μ2-5-(N,N′-diethylamine)-5′-methoxyl-2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato-κ6O:O,N,N,O′:O′}trinickel(II) – ethanol – acetonitrile (1/2/2), C58H86Ni3N8O18
  52. Crystal structure of the bis((E)-O-ethyl-N-phenylthiocarbamate) – 4,4′-bipyridine co-crystal (2/1), C28H30N4O2S2
  53. Crystal structure of the (E)-O-methyl-N-phenyl-thiocarbamate – 4,4′-bipyridine (1/1), C18H17N3OS
  54. Crystal structure of bis(μ2-diethyldithiocarbamato-κ3S,S′:S′)-bis(tricyclohexylphosphane-κP)dicopper(I), C46H86Cu2N2P2S4
  55. Crystal structure of N-(3-chlorophenyl)ethoxycarbothioamide, C9H10ClNOS
  56. Crystal structure of bis(μ2-pyrrolidine-1-carbodithioato-κ3S,S′:S;κ3S:S:S′)-bis(tricyclohexylphosphane-P)-di-copper(I), C46H82Cu2N2P2S4
  57. Crystal structure of N-(2-chlorophenyl)methoxycarbothioamide, C8H8ClNOS
  58. Crystal structure of chlorido-methanol-(N-(2-(oxy)-3-methoxybenzylidene)pyridine-4-carbohydrazonato-κ3O,N,O′)-(4-methylphenyl)methyl-tin(IV), C23H24ClN3O4Sn
  59. Crystal structure of N-(3-chlorophenyl)(propan-2-yloxy)carbothioamide, C10H12ClNOS
  60. Crystal structure of 1-[(Z)-[4-(4-methoxyphenyl)butan-2-ylidene]amino]-3-phenylurea, C18H21N3O2
  61. A triclinic polymorph of bis(μ-N,N-bis(2-hydroxyethyl)dithiocarbamato-κ3S,S′:S′) bis(N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S:S′)zinc(II), C20H40N4O8S8Zn2
https://doi.org/10.1515/ncrs-2017-0308
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Bis(tetraethylammonium) carbonate – boric acid – water (1/2/5), C17H56B2N2O14
  3. Crystal structure of 4-methoxy-6-phenyl-2H-pyran-2-one, C12H10O3
  4. Crystal structure of tris{(3-((E)-(((E)-2-oxidobenzylidene)hydrazono)methyl)-2-oxo-2H-chromen-4-olato-κ3O,N:N′)}dicobalt(III)tris(dimethylformamide), C60H50Co2N9O15
  5. Crystal structure of poly[bis(1-methyl-[4,4′-bipyridin]-1-ium-κN)-tetrakis(μ3-sulfato-κ3O:O′:O′′)trizinc(II)], C22H22Zn3N4O16S4
  6. Crystal structure of (5Z,10Z)-3,13-dichloro-17,18-dioxo-5,11-diphenyl-8,9,17,18-tetrahydro-7H-dibenzo[e,n][1,4,8,12]tetraazacyclopentadecine-16,19-diido-κ4N,N′,N′′,N′′′)copper(II), C31H22N4O2Cl2Cu
  7. Crystal structure of bis{5-methoxy-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2N,O}zinc(II), C34H24N2O8Zn
  8. Crystal structure of 2,2′-((((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))diphenolato-κ2N;κ4O)nickel(II), C28H22N2O4Ni
  9. Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)cobalt(II), C36H26N2O4Co
  10. Crystal structure of camptothecin, C20H16N2O4
  11. Crystal structure of (2-(chlorophenyl)-5-methyl-1,3-dioxane-5-carboxylato–κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, Ni(C16H36N4)(C12H12O4Cl)ClO4⋅H2O
  12. Crystal structure of 3-(2-chloro-6-methoxyquinolin-3-yl)-5-phenylisoxazole (C19H13ClN2O2)
  13. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)-bis{[(E)-2,6-diisopropyl-N-(pyridin-3-ylmethylene)aniline]copper (II)}, C44H56Cu2N4O8
  14. Crystal structure of diethyl 2-(2-chlorophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19Cl1O6
  15. Crystal structure of (μ2-2,2′-bipyridine-3,3′-dicarboxylato)-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-di-nickel(II) perchlorate N,N′-dimethylformamide solvate, C50H92Cl2N12Ni2O14
  16. Crystal structure of catena-poly[triaqua(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)-(1,2-bis(4-pyridyl)ethane-κN)nickel(II)] 2-aminonicotinate nitrate – 1,2-bis(4-pyridyl)ethane – water (2/1/8), C36H44N8NiO12
  17. Hydrothermal synthesis and crystal structure of poly[bis(μ2-3-(3,5-dicarboxyphenoxy)phthalato-κ3O,O′:O′′)-(μ2-1,2-di(pyridin-4-yl)ethane-κ2N:N′)copper(II)], C22H14CuNO9
  18. Crystal structure of catena-poly[aqua-(methanol-κO)-bis(μ2-4-(pyridin-4-yl)benzoato-κ2N:O)-bis(triphenylphospine-κP)disilver(I)], C61H52Ag2N2O6P2
  19. The crystal structure of 6-(4-bromobenzyl)-1,3,5-trimethyl-7-phenyl-1,5-dihydro-2H-pyrrolo[3,2-d]pyrimidine-2,4(3H)-dione, C22H20BrN3O2
  20. Synthesis and crystal structure of catena-poly[bis(2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κO;κ2O′,O′′)-(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)zinc(II)], C44H32N4ZnCl4O4
  21. Crystal structure of diaqua-bis[N-phenyl-2-(quinolin-8-yloxy)acetamide-κ3-N,O,O′]-nitrato(κ2O,O′)-cerium(III) dinitrate - acetone (1/2), C40H44N7O17Ce
  22. Crystal structure of the 2D coordination polymer poly[aqua(μ2-2,2′-(1,2-phenylene)diacetato-κ3O,O′:O′)-(μ2-4,4′-bis((1H-1,2,4-triazol-1-yl)methyl)-1,1′-biphenyl-κ2N:N′)cobalt(II)], C28H26CoN6O5
  23. Crystal structure of (dimethylformamide-κO)(perchlorato-κ2O,O′){μ2-6,6′-((1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(4-bromo-2-methoxyphenolate)-κ8N,N′,O:O,O′:O′,O′′,O′′′}sodium(I)nickel(II), C25H23Br2ClN3NaNiO9
  24. The crystal structure of catena-poly[bis((4-aminophenyl)sulfonyl)(pyrimidin-2-yl)amido-κ2N,N′)-bis(μ2-4,4′-bipyridine-N,N′-κ2N:N′)zinc(II) – methanol (1/2), C32H34N10O6S2Zn
  25. Synthesis and crystal structure poly[aqua(μ3-2-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio)acetate-κ4O,O′:O′′:O′′′) sodium] monohydrate, C18H18NNaO11S
  26. Crystal structure of methyl 4′-amino-3′,5′-diisopropyl-[1,1′-biphenyl]-4-carboxylate, C20H25NO2
  27. Crystal structure of (η6-1-isopropyl-4-methyl benzene)-(N-(2,5-dichlorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) perchlorate, C22H22Cl4N2O4Ru
  28. Crystal structure of 2-(2-(1-Chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl)-1H-1,2,4-triazole-3(2H)-thione, C14H15Cl2N3OS
  29. Crystal structure of methyl 4′-amino-3′,5′-dimethyl-[1,1′-biphenyl]-4-carboxylate, C16H17NO2
  30. The crystal structure of 1-(5-ferrocenyl-3-(trifluoromethyl)-1H-pyrazol-1-yl)pentan-1-on, C19H19F3FeN2O
  31. The crystal structure of (3S,12R,20R,24S)-3,12-diacetyl-20,24-epoxy-dammarane-3,12,25-triol acetone solvate, C34H56O6
  32. Crystal structure of methyl 10-(pyridin-4-yl)-anthracene-9-carboxylate, C21H15NO2
  33. Crystal structure of catena-poly[diaqua-bis(di(N2,N6-dihydroxypyridine-2,6-dicarboxamide))potassium(I)]tetrahydrate, C14H25N6O14K
  34. Crystal structure of poly{[μ2-(E)-1,4-bis(1H-benzo[d]imidazol-1-yl)but-2-ene-κ2N:N′][μ3–cyclohexane-1,4-dicarboxylato-κ4O,O′:O′′:O′′′]cadmium(II)}, C26H26CdN4O4
  35. Crystal structure of poly[aqua(μ3-[2,2′-bipyridine]-3,3′-dicarboxylato-κ4N,N′:O:O′)zinc(II)] – dimethylformamide (1/1), C15H15N3O6Zn
  36. The crystal structure of poly[tetraaqua-tris(μ2-2,6-di(1H-imidazol-1-yl)naphthalene-κ2N:N′)-bis(thiophene-2,5-dicarboxylato-κ1O)]dicobalt(II), C30H24CoN6O6S
  37. Crystal structure of (S)-1-(5-(anthracen-9-yl)-3-phenyl-4,5-dihydro-1H-pyrazol-1-yl)propan-1-one, C26H22N2O
  38. Crystal structure of 5-methyl-3,3-diphenyl-1-tosyl-1,2,3,4-tetrahydropyridine, C25H25NO2S
  39. Synthesis and crystal structure of μ-[1,1′-di(mesitylphosphanido)ferrocene]bis[η5-cyclopentadienylnickel(II)] tetrahydrofurane solvate, C42H48FeNi2OP2
  40. Synthesis and crystal structure of (E)-1-(4-(((E)-5-chloro-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H15ClN2O2
  41. Crystal structure of bis(1-(phenylsulfonyl)-2-(1-(pyrazin-2-yl)ethylidene)hydrazin-1-ido-κ3N,N′,O)nickel(II), C24H22N8O4S2Ni
  42. Crystal Structure of bis(1-(phenylsulfonyl)-2-(1-(pyrazin-2-yl)ethylidene)hydrazin-1-ido-κ3N,N′,O)copper(II), C24H22N8O4S2Cu
  43. Synthesis and crystal structure of poly[aqua{μ3-(1S,2S)-1-((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)pyrrolidin-1-ium-2-carboxylato-κ4O,O′:O′′:O′′′}sodium(I)] monohydrate, C21H22NNaO11S
  44. Halogen bonds in the crystal structure of 1,4-diiodotetrafluorobenzene–1,2-bis(4-pyridyl)propane (1/1), C19H14F4I2N2
  45. Crystal structure of bis(μ-N-i-propyl-N-n-propyldithiocarbamato-κ2S:S′) bis(N-i-propyl-N-n-propyldithiocarbamato-κ2S,S′)dizinc(II), C28H56N4S8Zn2
  46. Crystal structure of bis(μ-N-i-propyl-N-n-propyldithiocarbamato-κ3S,S′:S)bis(N-i-propyl-N-n-propyldithiocarbamato-κ2S,S′)dicadmium(II), C28H56Cd2N4S8
  47. Crystal structure of bis(μ2-di-n-butyldithiocarbamato-κ3S,S′:S;κ3S:S:S′)-hexacarbonyl-di-rhenium(I), C24H36N2O6Re2
  48. Crystal structure of 7-(4-methylphenyl)imidazo[1,2-a][1,3,5]triazin-4-amine, C12H11N5
  49. Crystal structure of the co-crystal O-isopropyl phenylcarbamothioate – 4,4′-bipyridine (2/1), C15H17N2OS
  50. Crystal structure of the coordination polymer catena-poly[chlorido-{μ2-2-(((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amino)-3-hydroxybutanoato-κ4N,N,O:O′}copper(II)], C11H16ClCuN2O3
  51. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-di(ethanol)-bis{μ2-5-(N,N′-diethylamine)-5′-methoxyl-2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato-κ6O:O,N,N,O′:O′}trinickel(II) – ethanol – acetonitrile (1/2/2), C58H86Ni3N8O18
  52. Crystal structure of the bis((E)-O-ethyl-N-phenylthiocarbamate) – 4,4′-bipyridine co-crystal (2/1), C28H30N4O2S2
  53. Crystal structure of the (E)-O-methyl-N-phenyl-thiocarbamate – 4,4′-bipyridine (1/1), C18H17N3OS
  54. Crystal structure of bis(μ2-diethyldithiocarbamato-κ3S,S′:S′)-bis(tricyclohexylphosphane-κP)dicopper(I), C46H86Cu2N2P2S4
  55. Crystal structure of N-(3-chlorophenyl)ethoxycarbothioamide, C9H10ClNOS
  56. Crystal structure of bis(μ2-pyrrolidine-1-carbodithioato-κ3S,S′:S;κ3S:S:S′)-bis(tricyclohexylphosphane-P)-di-copper(I), C46H82Cu2N2P2S4
  57. Crystal structure of N-(2-chlorophenyl)methoxycarbothioamide, C8H8ClNOS
  58. Crystal structure of chlorido-methanol-(N-(2-(oxy)-3-methoxybenzylidene)pyridine-4-carbohydrazonato-κ3O,N,O′)-(4-methylphenyl)methyl-tin(IV), C23H24ClN3O4Sn
  59. Crystal structure of N-(3-chlorophenyl)(propan-2-yloxy)carbothioamide, C10H12ClNOS
  60. Crystal structure of 1-[(Z)-[4-(4-methoxyphenyl)butan-2-ylidene]amino]-3-phenylurea, C18H21N3O2
  61. A triclinic polymorph of bis(μ-N,N-bis(2-hydroxyethyl)dithiocarbamato-κ3S,S′:S′) bis(N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S:S′)zinc(II), C20H40N4O8S8Zn2
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