Home Crystal structure of the bis((E)-O-ethyl-N-phenylthiocarbamate) – 4,4′-bipyridine co-crystal (2/1), C28H30N4O2S2
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Crystal structure of the bis((E)-O-ethyl-N-phenylthiocarbamate) – 4,4′-bipyridine co-crystal (2/1), C28H30N4O2S2

  • Chien Ing Yeo and Edward R.T. Tiekink EMAIL logo
Published/Copyright: March 15, 2018
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 233 Issue 3

Abstract

C28H30N4O2S2, triclinic, P1̄ (no. 2), a = 10.1450(6) Å, b = 11.6401(11) Å, c = 11.8506(10) Å, α = 102.850(8)°, β = 105.028(6)°, γ = 94.135(6)°, V = 1305.14(19) Å3, Z = 2, Rgt(F) = 0.047, wRref(F2) = 0.139, T = 100(2) K.

CCDC no.: 1825499

The asymmetric unit of the title crystal structure is shown in the figure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Colourless prism
Size:0.32 × 0.08 × 0.06 mm
Wavelength:Cu Kα radiation (1.54184 Å)
μ:21.1 cm−1
Diffractometer, scan mode:SuperNova Dual, ω scans
2θmax, completeness:150°, 98.2%
N(hkl)measured, N(hkl)unique, Rint:9335, 5266, 0.030
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 4417
N(param)refined:335
Programs:Agilent programs [1], SHELX [2, 3] , ORTEP [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
S10.94213(5)0.68914(5)0.53059(5)0.03266(15)
O10.97418(13)0.83644(13)0.39386(13)0.0304(3)
N10.76995(16)0.82306(15)0.43292(15)0.0270(3)
H1N0.713(2)0.786(2)0.466(2)0.036(6)*
C10.89528(18)0.78667(17)0.44937(17)0.0268(4)
C20.71301(18)0.90831(17)0.37352(17)0.0259(4)
C30.58004(19)0.92729(19)0.37951(19)0.0314(4)
H30.53410.88210.41910.038*
C40.5149(2)1.01165(19)0.32808(19)0.0338(4)
H40.42491.02390.33320.041*
C50.5794(2)1.07823(18)0.26933(18)0.0317(4)
H50.53391.13530.23350.038*
C60.7110(2)1.0604(2)0.2636(2)0.0367(5)
H60.75621.10600.22390.044*
C70.7786(2)0.97633(19)0.31555(19)0.0337(4)
H70.86930.96550.31130.040*
C81.10899(19)0.80057(19)0.39825(19)0.0314(4)
H8A1.10040.71560.35600.038*
H8B1.16520.81250.48290.038*
C91.1737(2)0.8785(2)0.3359(2)0.0366(5)
H9A1.26330.85480.33120.055*
H9B1.18650.96170.38170.055*
H9C1.11340.86970.25430.055*
S2−0.21153(4)0.43312(4)0.83774(4)0.02892(14)
O2−0.22983(13)0.26737(12)0.95925(12)0.0287(3)
N2−0.01934(16)0.32103(15)0.94772(15)0.0265(3)
H2N0.036(2)0.355(2)0.918(2)0.034(6)*
C10−0.15194(18)0.33723(17)0.91833(16)0.0256(4)
C110.04098(17)0.23518(17)1.00659(17)0.0260(4)
C120.14105(18)0.17998(18)0.96223(19)0.0302(4)
H120.16560.20010.89620.036*
C130.20473(19)0.09556(19)1.0147(2)0.0330(4)
H130.27260.05760.98410.040*
C140.17009(19)0.06608(18)1.11159(19)0.0315(4)
H140.21320.00761.14670.038*
C150.07211(19)0.12262(18)1.15684(18)0.0307(4)
H150.04820.10271.22320.037*
C160.00844(18)0.20843(17)1.10572(18)0.0288(4)
H16−0.05680.24841.13840.035*
C17−0.37496(18)0.27756(19)0.93651(19)0.0315(4)
H17B−0.42160.25390.84880.038*
H17A−0.38840.36050.96890.038*
C18−0.4315(2)0.1964(2)0.9987(2)0.0440(5)
H18C−0.52970.20190.98800.066*
H18B−0.38220.21941.08500.066*
H18A−0.41980.11440.96410.066*
N30.57846(16)0.70038(15)0.53358(15)0.0285(3)
N40.17372(17)0.43040(15)0.83913(15)0.0300(4)
C190.63612(19)0.68061(17)0.64195(18)0.0281(4)
H190.73260.70310.67650.034*
C200.56286(18)0.62920(17)0.70630(17)0.0271(4)
H200.60870.61820.78310.032*
C210.42135(18)0.59388(16)0.65717(17)0.0253(4)
C220.36089(18)0.61198(18)0.54363(17)0.0284(4)
H220.26500.58840.50600.034*
C230.4424(2)0.66490(18)0.48633(18)0.0308(4)
H230.39940.67670.40920.037*
C240.33747(18)0.53909(17)0.72223(17)0.0256(4)
C250.3886(2)0.46046(19)0.79079(19)0.0321(4)
H250.47990.44220.79920.038*
C260.3035(2)0.4094(2)0.8465(2)0.0345(5)
H260.33970.35600.89290.041*
C270.12698(19)0.50731(18)0.77478(18)0.0296(4)
H270.03570.52470.76890.036*
C280.20374(19)0.56336(18)0.71601(18)0.0294(4)
H280.16540.61780.67200.035*

Source of materials

4,4′-Bipyridine (Merck; bpy; 0.05 g, 0.32 mmol) and 2.1 mol equivalent of EtOC(=S)N(H)Ph [5] (0.11 g, 0.67 mmol), each in acetonitrile (10 mL), were mixed and stirred at 323 K for 3 h. The resulting mixture was left for evaporation at room temperature after which colourless crystals were deposited. Elem. Anal. Calc. for C28H30N4O2S2: C, 64.84; H, 5.83; N, 10.80%. Found: C, 63.28; H, 6.66; N, 10.24%. IR (cm−1): 3164 (br) ν(N—H); 1593 (s) ν(C=C, bpy); 1448 (s) ν(C—N); 1393 (s) ν(C—N, bpy); 1204 (s) ν(C=S); 1087 (vs) ν(C—O).

Experimental details

The C-bound H atoms were geometrically placed (C—H = 0.95–1.00 Å) and refined as riding with Uiso(H) = 1.2–1.5 Ueq(C). The N-bound H-atoms were located in a difference Fourier map but were refined with a distance restraint of N—H = 0.88 ± 0.01 Å, and with Uiso(H) set to 1.2 Ueq(N).

Comment

A common feature of the structurally characterized monofunctional alkoxycarbothioamides so far, i.e. molecules of the general formula ROC(=S)N(H)R′ for R, R′ = alkyl/aryl, is that all but three structures have a syn disposition of the thioamide-H and thione-S atoms [6]. This arrangement allows for the formation of an eight-membered thioamide synthon, i.e. {⋯HNCS}2, in their molecular packing with the exceptions for cases where thioamide-N—H⋯O, N hydrogen bonding prevails. A similar homogeneity is found in the known co-crystals of the alkoxycarbothioamides, whereby thioamide-N—H⋯N(pyridyl) hydrogen bonds always feature in their structures [7, 8] . In this regard, the title co-crystal conforms to the structures of the literature precedents.

The three-molecule aggregate in [EtOC(=S)N(H)Ph]2(4,4′-bipyridine) is shown in the Figure (70% displacement ellipsoids). There are thioamide-N—H⋯N(pyridyl) hydrogen bonds connecting the co-crystal coformers [N1—H⋯N3 = 2.06(2) Å and 178(2)°; N3—H⋯N4 = 2.11(2) Å and 177(2)°]. The structure differs from related co-crystals in that it lacks the crystallographically imposed symmetry, i.e. 1̄ or 2-fold, exhibited by all the other examples [7, 8] . There is a twist in the 4,4′-bipyridine molecule with the dihedral angle between the constituent rings being 36.90(10)°. As is usual for alkoxycarbothioamides [6], the central CNOS residue is strictly planar and the thioamide-H and thione-S atoms are syn. The major difference between the ethoxycarbothioamide molecules is found in the relative orientations of the pendent phenyl rings with respect to the central CNOS residue. Thus, in the S1-molecule, the dihedral angle between these planes is 4.66(13)° cf. 39.18(8)° for the S2-molecule. The O-bound ethyl groups are practically superimposable.

The X-ray structure of the ethoxycarbothioamide molecule found in the new co-crystal has also been reported in the pure form. Here [5], there are three independent molecules in the asymmetric unit. An overlay diagram (not shown) of the five independent molecules in the two structures shows that the conformation of the terminal ethyl group is the same across the series. Also, the dihedral angles between the CNOS and phenyl planes in the structure of the pure molecule range from 14.39(18) to 31.86(22)°, i.e. between the equivalent angles in the co-crystal. Bond lengths and angles are all in the expected ranges [9].

Acknowledgements

Sunway University is thanked for support of biological and crystal engineering studies of metal alkoxycarbothioamides.

References

Agilent Technologies. CrysAlisPRO. Agilent Technologies, Santa Clara, CA, USA (2013).Search in Google Scholar

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Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central

Farrugia, L. J.: WinGX and ORTEP for Windows: an update. J. Appl. Cryst. 45 (2012) 849–854.10.1107/S0021889812029111Search in Google Scholar

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Yeo, C. I.; Tiekink, E. R. T.: Crystal structure of the bis((E)-O-ethyl-N-phenylthiocarbamate) – 4,4′-bipyridine co-crystal (2/1), C28H30N4O2S2. Z. Kristallogr. – NCS 233 (2018) 499–501.10.1515/ncrs-2017-0398Search in Google Scholar

Yeo, C. I.; Tiekink E. R. T.: Crystal structure of N-(2-methylphenyl)ethoxycarbothioamide, C10H13NOS. Z. Kristallogr. NCS 233 (2018) 299–301.10.1515/ncrs-2017-0295Search in Google Scholar

Received: 2017-12-9
Accepted: 2018-2-23
Published Online: 2018-3-15
Published in Print: 2018-5-24

©2018 Chien Ing Yeo et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

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  61. A triclinic polymorph of bis(μ-N,N-bis(2-hydroxyethyl)dithiocarbamato-κ3S,S′:S′) bis(N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S:S′)zinc(II), C20H40N4O8S8Zn2
https://doi.org/10.1515/ncrs-2017-0398
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Bis(tetraethylammonium) carbonate – boric acid – water (1/2/5), C17H56B2N2O14
  3. Crystal structure of 4-methoxy-6-phenyl-2H-pyran-2-one, C12H10O3
  4. Crystal structure of tris{(3-((E)-(((E)-2-oxidobenzylidene)hydrazono)methyl)-2-oxo-2H-chromen-4-olato-κ3O,N:N′)}dicobalt(III)tris(dimethylformamide), C60H50Co2N9O15
  5. Crystal structure of poly[bis(1-methyl-[4,4′-bipyridin]-1-ium-κN)-tetrakis(μ3-sulfato-κ3O:O′:O′′)trizinc(II)], C22H22Zn3N4O16S4
  6. Crystal structure of (5Z,10Z)-3,13-dichloro-17,18-dioxo-5,11-diphenyl-8,9,17,18-tetrahydro-7H-dibenzo[e,n][1,4,8,12]tetraazacyclopentadecine-16,19-diido-κ4N,N′,N′′,N′′′)copper(II), C31H22N4O2Cl2Cu
  7. Crystal structure of bis{5-methoxy-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2N,O}zinc(II), C34H24N2O8Zn
  8. Crystal structure of 2,2′-((((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))diphenolato-κ2N;κ4O)nickel(II), C28H22N2O4Ni
  9. Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)cobalt(II), C36H26N2O4Co
  10. Crystal structure of camptothecin, C20H16N2O4
  11. Crystal structure of (2-(chlorophenyl)-5-methyl-1,3-dioxane-5-carboxylato–κ2O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, Ni(C16H36N4)(C12H12O4Cl)ClO4⋅H2O
  12. Crystal structure of 3-(2-chloro-6-methoxyquinolin-3-yl)-5-phenylisoxazole (C19H13ClN2O2)
  13. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)-bis{[(E)-2,6-diisopropyl-N-(pyridin-3-ylmethylene)aniline]copper (II)}, C44H56Cu2N4O8
  14. Crystal structure of diethyl 2-(2-chlorophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19Cl1O6
  15. Crystal structure of (μ2-2,2′-bipyridine-3,3′-dicarboxylato)-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-di-nickel(II) perchlorate N,N′-dimethylformamide solvate, C50H92Cl2N12Ni2O14
  16. Crystal structure of catena-poly[triaqua(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)-(1,2-bis(4-pyridyl)ethane-κN)nickel(II)] 2-aminonicotinate nitrate – 1,2-bis(4-pyridyl)ethane – water (2/1/8), C36H44N8NiO12
  17. Hydrothermal synthesis and crystal structure of poly[bis(μ2-3-(3,5-dicarboxyphenoxy)phthalato-κ3O,O′:O′′)-(μ2-1,2-di(pyridin-4-yl)ethane-κ2N:N′)copper(II)], C22H14CuNO9
  18. Crystal structure of catena-poly[aqua-(methanol-κO)-bis(μ2-4-(pyridin-4-yl)benzoato-κ2N:O)-bis(triphenylphospine-κP)disilver(I)], C61H52Ag2N2O6P2
  19. The crystal structure of 6-(4-bromobenzyl)-1,3,5-trimethyl-7-phenyl-1,5-dihydro-2H-pyrrolo[3,2-d]pyrimidine-2,4(3H)-dione, C22H20BrN3O2
  20. Synthesis and crystal structure of catena-poly[bis(2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κO;κ2O′,O′′)-(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)zinc(II)], C44H32N4ZnCl4O4
  21. Crystal structure of diaqua-bis[N-phenyl-2-(quinolin-8-yloxy)acetamide-κ3-N,O,O′]-nitrato(κ2O,O′)-cerium(III) dinitrate - acetone (1/2), C40H44N7O17Ce
  22. Crystal structure of the 2D coordination polymer poly[aqua(μ2-2,2′-(1,2-phenylene)diacetato-κ3O,O′:O′)-(μ2-4,4′-bis((1H-1,2,4-triazol-1-yl)methyl)-1,1′-biphenyl-κ2N:N′)cobalt(II)], C28H26CoN6O5
  23. Crystal structure of (dimethylformamide-κO)(perchlorato-κ2O,O′){μ2-6,6′-((1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(4-bromo-2-methoxyphenolate)-κ8N,N′,O:O,O′:O′,O′′,O′′′}sodium(I)nickel(II), C25H23Br2ClN3NaNiO9
  24. The crystal structure of catena-poly[bis((4-aminophenyl)sulfonyl)(pyrimidin-2-yl)amido-κ2N,N′)-bis(μ2-4,4′-bipyridine-N,N′-κ2N:N′)zinc(II) – methanol (1/2), C32H34N10O6S2Zn
  25. Synthesis and crystal structure poly[aqua(μ3-2-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio)acetate-κ4O,O′:O′′:O′′′) sodium] monohydrate, C18H18NNaO11S
  26. Crystal structure of methyl 4′-amino-3′,5′-diisopropyl-[1,1′-biphenyl]-4-carboxylate, C20H25NO2
  27. Crystal structure of (η6-1-isopropyl-4-methyl benzene)-(N-(2,5-dichlorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) perchlorate, C22H22Cl4N2O4Ru
  28. Crystal structure of 2-(2-(1-Chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl)-1H-1,2,4-triazole-3(2H)-thione, C14H15Cl2N3OS
  29. Crystal structure of methyl 4′-amino-3′,5′-dimethyl-[1,1′-biphenyl]-4-carboxylate, C16H17NO2
  30. The crystal structure of 1-(5-ferrocenyl-3-(trifluoromethyl)-1H-pyrazol-1-yl)pentan-1-on, C19H19F3FeN2O
  31. The crystal structure of (3S,12R,20R,24S)-3,12-diacetyl-20,24-epoxy-dammarane-3,12,25-triol acetone solvate, C34H56O6
  32. Crystal structure of methyl 10-(pyridin-4-yl)-anthracene-9-carboxylate, C21H15NO2
  33. Crystal structure of catena-poly[diaqua-bis(di(N2,N6-dihydroxypyridine-2,6-dicarboxamide))potassium(I)]tetrahydrate, C14H25N6O14K
  34. Crystal structure of poly{[μ2-(E)-1,4-bis(1H-benzo[d]imidazol-1-yl)but-2-ene-κ2N:N′][μ3–cyclohexane-1,4-dicarboxylato-κ4O,O′:O′′:O′′′]cadmium(II)}, C26H26CdN4O4
  35. Crystal structure of poly[aqua(μ3-[2,2′-bipyridine]-3,3′-dicarboxylato-κ4N,N′:O:O′)zinc(II)] – dimethylformamide (1/1), C15H15N3O6Zn
  36. The crystal structure of poly[tetraaqua-tris(μ2-2,6-di(1H-imidazol-1-yl)naphthalene-κ2N:N′)-bis(thiophene-2,5-dicarboxylato-κ1O)]dicobalt(II), C30H24CoN6O6S
  37. Crystal structure of (S)-1-(5-(anthracen-9-yl)-3-phenyl-4,5-dihydro-1H-pyrazol-1-yl)propan-1-one, C26H22N2O
  38. Crystal structure of 5-methyl-3,3-diphenyl-1-tosyl-1,2,3,4-tetrahydropyridine, C25H25NO2S
  39. Synthesis and crystal structure of μ-[1,1′-di(mesitylphosphanido)ferrocene]bis[η5-cyclopentadienylnickel(II)] tetrahydrofurane solvate, C42H48FeNi2OP2
  40. Synthesis and crystal structure of (E)-1-(4-(((E)-5-chloro-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H15ClN2O2
  41. Crystal structure of bis(1-(phenylsulfonyl)-2-(1-(pyrazin-2-yl)ethylidene)hydrazin-1-ido-κ3N,N′,O)nickel(II), C24H22N8O4S2Ni
  42. Crystal Structure of bis(1-(phenylsulfonyl)-2-(1-(pyrazin-2-yl)ethylidene)hydrazin-1-ido-κ3N,N′,O)copper(II), C24H22N8O4S2Cu
  43. Synthesis and crystal structure of poly[aqua{μ3-(1S,2S)-1-((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)pyrrolidin-1-ium-2-carboxylato-κ4O,O′:O′′:O′′′}sodium(I)] monohydrate, C21H22NNaO11S
  44. Halogen bonds in the crystal structure of 1,4-diiodotetrafluorobenzene–1,2-bis(4-pyridyl)propane (1/1), C19H14F4I2N2
  45. Crystal structure of bis(μ-N-i-propyl-N-n-propyldithiocarbamato-κ2S:S′) bis(N-i-propyl-N-n-propyldithiocarbamato-κ2S,S′)dizinc(II), C28H56N4S8Zn2
  46. Crystal structure of bis(μ-N-i-propyl-N-n-propyldithiocarbamato-κ3S,S′:S)bis(N-i-propyl-N-n-propyldithiocarbamato-κ2S,S′)dicadmium(II), C28H56Cd2N4S8
  47. Crystal structure of bis(μ2-di-n-butyldithiocarbamato-κ3S,S′:S;κ3S:S:S′)-hexacarbonyl-di-rhenium(I), C24H36N2O6Re2
  48. Crystal structure of 7-(4-methylphenyl)imidazo[1,2-a][1,3,5]triazin-4-amine, C12H11N5
  49. Crystal structure of the co-crystal O-isopropyl phenylcarbamothioate – 4,4′-bipyridine (2/1), C15H17N2OS
  50. Crystal structure of the coordination polymer catena-poly[chlorido-{μ2-2-(((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amino)-3-hydroxybutanoato-κ4N,N,O:O′}copper(II)], C11H16ClCuN2O3
  51. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-di(ethanol)-bis{μ2-5-(N,N′-diethylamine)-5′-methoxyl-2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato-κ6O:O,N,N,O′:O′}trinickel(II) – ethanol – acetonitrile (1/2/2), C58H86Ni3N8O18
  52. Crystal structure of the bis((E)-O-ethyl-N-phenylthiocarbamate) – 4,4′-bipyridine co-crystal (2/1), C28H30N4O2S2
  53. Crystal structure of the (E)-O-methyl-N-phenyl-thiocarbamate – 4,4′-bipyridine (1/1), C18H17N3OS
  54. Crystal structure of bis(μ2-diethyldithiocarbamato-κ3S,S′:S′)-bis(tricyclohexylphosphane-κP)dicopper(I), C46H86Cu2N2P2S4
  55. Crystal structure of N-(3-chlorophenyl)ethoxycarbothioamide, C9H10ClNOS
  56. Crystal structure of bis(μ2-pyrrolidine-1-carbodithioato-κ3S,S′:S;κ3S:S:S′)-bis(tricyclohexylphosphane-P)-di-copper(I), C46H82Cu2N2P2S4
  57. Crystal structure of N-(2-chlorophenyl)methoxycarbothioamide, C8H8ClNOS
  58. Crystal structure of chlorido-methanol-(N-(2-(oxy)-3-methoxybenzylidene)pyridine-4-carbohydrazonato-κ3O,N,O′)-(4-methylphenyl)methyl-tin(IV), C23H24ClN3O4Sn
  59. Crystal structure of N-(3-chlorophenyl)(propan-2-yloxy)carbothioamide, C10H12ClNOS
  60. Crystal structure of 1-[(Z)-[4-(4-methoxyphenyl)butan-2-ylidene]amino]-3-phenylurea, C18H21N3O2
  61. A triclinic polymorph of bis(μ-N,N-bis(2-hydroxyethyl)dithiocarbamato-κ3S,S′:S′) bis(N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S:S′)zinc(II), C20H40N4O8S8Zn2
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