Home Crystal structure of 4-phenyl-3-((4-phenyl-1H-1,2,3-triazol-1-yl)methyl)-1H-1,2,4-triazole-5(4H)-thione, C17H14N6S
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Crystal structure of 4-phenyl-3-((4-phenyl-1H-1,2,3-triazol-1-yl)methyl)-1H-1,2,4-triazole-5(4H)-thione, C17H14N6S

  • Mohamed Reda Aouad EMAIL logo , Mouslim Messali , Nadjet Rezki , Naveen Shivalingegowda and Ismail Warad EMAIL logo
Published/Copyright: May 22, 2018
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 233 Issue 4

Abstract

C17H14N6S, orthorhombic, P212121 (no. 19), a = 7.3832(3) Å, b =14.4702(7) Å, c = 15.2806(7) Å, V = 1632.52(13) Å3, Z = 4 and with Rint = 0.0577, Rgt(F) = 0.0358, wRref(F2) = 0.0944, T = 296(2) K.

CCDC no.: 1824847

Table 1:

Data collection and handling.

Crystal:Rectangle, white
Size:0.28 × 0.26 × 0.22 mm
Wavelength:Cu Kα radiation (1.54178 Å)
μ:1.85 mm−1
Diffractometer, scan mode:Bruker X8 Proteum, φ and ω-scans
θmax, completeness:66.57°, >99%
N(hkl)measured, N(hkl)unique, Rint:28809, 2869, 0.058
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 2848
N(param)refined:217
Programs:Bruker programs [1], SHELX [2, 3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
S1−0.02291(6)−0.68235(3)−0.89262(4)0.06769(16)
N1−0.33020(17)−0.78853(8)−0.87530(8)0.0480(3)
N2−0.38008(19)−0.64350(9)−0.88009(9)0.0550(3)
H2−0.3640−0.5847−0.88330.066
N3−0.54711(18)−0.68324(9)−0.87164(9)0.0531(3)
N4−0.68993(17)−0.86710(9)−0.76957(8)0.0498(3)
N5−0.6828(2)−0.95080(9)−0.65555(9)0.0588(3)
N6−0.6413(2)−0.94984(9)−0.73887(9)0.0595(3)
C1−0.2441(2)−0.70438(10)−0.88287(9)0.0513(3)
C2−0.5139(2)−0.77161(10)−0.86984(9)0.0482(3)
C3−0.2396(2)−0.87673(10)−0.87094(10)0.0514(3)
C4−0.1890(3)−0.92074(13)−0.94624(13)0.0674(4)
H4−0.2152−0.8949−1.00050.081
C5−0.0984(4)−1.00414(16)−0.94056(18)0.0884(6)
H5−0.0640−1.0347−0.99140.106
C6−0.0589(3)−1.04186(14)−0.86126(19)0.0870(7)
H60.0029−1.0978−0.85820.104
C7−0.1099(4)−0.99780(17)−0.78625(18)0.0924(7)
H7−0.0830−1.0237−0.73210.111
C8−0.2012(3)−0.91491(14)−0.79070(13)0.0743(5)
H8−0.2367−0.8849−0.73970.089
C9−0.6575(2)−0.84319(11)−0.86167(9)0.0513(3)
H9A−0.7688−0.8203−0.88750.062
H9B−0.6213−0.8982−0.89350.062
C10−0.7623(2)−0.81429(11)−0.70616(10)0.0542(3)
H10−0.8064−0.7543−0.71120.065
C11−0.7570(2)−0.86804(10)−0.63250(10)0.0517(3)
C12−0.8083(2)−0.84733(12)−0.54128(10)0.0549(4)
C13−0.7714(3)−0.76039(14)−0.50696(13)0.0714(5)
H13−0.7218−0.7148−0.54250.086
C14−0.8082(4)−0.74174(19)−0.42030(14)0.0871(6)
H14−0.7838−0.6835−0.39750.104
C15−0.8811(3)−0.80935(19)−0.36726(12)0.0835(6)
H15−0.9018−0.7974−0.30830.100
C16−0.9232(3)−0.89474(16)−0.40187(13)0.0787(6)
H16−0.9772−0.9395−0.36680.094
C17−0.8854(3)−0.91398(13)−0.48846(12)0.0674(4)
H17−0.9119−0.9720−0.51130.081

Source of material

A solution of N-phenyl-2-(2-(4-phenyl-1H-1,2,3-triazol-1-yl)acetyl)hydrazinecarbothioamide (10 mmol, 3.52 g) in aqueous sodium hydroxide 10% (100 ml) was heated under reflux for 6 h. After cooling, the reaction mixture was acidified with diluted hydrochloric acid. The precipitate formed was filtered and recrystallized from ethanol to give the title compound as colorless needles in 89% yield, m.p. 269–270 °C.

Experimental details

Hydrogen atoms were placed at the calculated positions and refined using a riding model with Uiso(H) = 1.2Ueq or 1.5Ueq of the adjacent non-hydrogen atom. H3 Atom position was localized from the difference map and refined with DFIX 0.87 and Uiso(H) = 1.5Ueq(O3) [2, 3] .

Discussion

Triazole and its derivatives compound have gained a great biological activities like antiproliferative, antibacterial, analgesic, antitubercular, anti-inflammatory, anti-tuberculosis, anti-inflammatory, depressant, anti-HIV and anti-cancer [4], [5], [6], [7], [8], [9], [10]. The design and synthesis of novel triazole-thione bearing different aromatic moieties have become a broad area in bio-organic synthesis research [11], [12]. 1,2,4-Triazoles are used as poly-chelate ligands for the synthesis of metal complexes [13]. There is one molecule in the asymmetric unit as in the figure; the compound has not been detected in dimer form. All the angles and bond lengths are in their expected ranges. The two phenyl groups are almost perpendicular to the plane of the 1,2,4-triazole-5(4H)-thione ring. The molecules packing in the crystal structure is stabilized via several interaction types. N—H⋯N hydrogen bonds with 2.701 Å, 2.674 Å and 2.576 Å, C—H⋯S hydrogen bonds 2.741 Å, aromatic C—H⋯pi stacking interactions with 2.89 Å and 2.85 Å were also detected. These interactions link the molecules to a three-dimensional arrangement.

References

Bruker. SAINT, APEX2, Bruker Inc., Madison, Wisconsin, USA (2016).Search in Google Scholar

Sheldrick, G. M.: SHELXL2014: Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, Germany (2014).Search in Google Scholar

Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed

Balzarini, J.; Orzeszko, B.; Mauri, J. K.; Orzeszko, A.: Synthesis and anti-HIV studies of 2-adamantyl-substituted thiazolidin-4-ones. Eur. J. Med. Chem. 42 (2007) 993–1003.10.1016/j.ejmech.2007.01.003Search in Google Scholar PubMed

El-Emam, A. A.; Al-Tamimi, A.-M. S.; Al-Omar, M. A.; Al-Rashood, K. A.; Habib, E. E.: Synthesis and antimicrobial activity of novel 5-(1-adamantyl)-2-aminomethyl-4-substituted- 1,2,4-triazoline-3-thiones. Eur. J. Med. Chem. 68 (2013) 96–102.10.1016/j.ejmech.2013.07.024Search in Google Scholar PubMed

Wang, X.; Dong, Y.; Wittlin, S.; Charman, S. A.; Chiu, F. C. K.; Chollet, J.; Katneni, K.; Mannila, J.; Morizzi, J.; Ryan, E.; Scheurer, C.; Steuten, J.; Tomas, J. S.; Snyder, C.; Vennerstrom, J. L.: Comparative antimalarial activities and ADME profiles of ozonides (1,2,4-trioxolanes) OZ277, OZ439, and their 1,2-dioxolane, 1,2,4-trioxane, and 1,2,4,5-tetraoxane isosteres. J. Med. Chem. 56 (2013) 2547–2555.10.1021/jm400004uSearch in Google Scholar PubMed

Kouatly, O.; Geronikaki, A.; Kamoutsis, C.; Hadjipavlou-Litina, D.; Eleftheriou, P.: Adamantane derivatives of thiazolyl-N-substituted amide, as possible non-steroidal anti-inflammatory agents. Eur. J. Med. Chem. 44 (2009) 1198–1204.10.1016/j.ejmech.2008.05.029Search in Google Scholar PubMed

Tozkoparan, B.; Küpeli, E.; Ye silada, E.; Ertan, M.: Preparation of 5-aryl-3-alkylthio-l, 2,4-triazoles and corresponding sulfones with anti-inflammatory-analgesic activity. Bioorg. Med. Chem. 15 (2007) 1808–1814.10.1016/j.bmc.2006.11.029Search in Google Scholar PubMed

Almajan, G. L.; Barbuceanu, S. -F.; Almajan, E.; Draghici, C.; Saramet, G.: Synthesis, characterization and antibacterial activity of some triazole Mannich bases carrying diphenylsulfone moieties. Eur. J. Med. Chem. 44 (2009) 3083–3089.10.1016/j.ejmech.2008.07.003Search in Google Scholar PubMed

Al-Deeb, O. A.; Al-Omar, M. A.; El-Brollosy, N. R.; Habib, E. E.; Ibrahim, T. M.; El-Emam, A. A.: Synthesis, antimicrobial, and anti-inflammatory activities of novel 2-[3-(1-adamantyl)-4-substituted-5-thioxo-1,2,4-triazolin-1-yl]acetic acids, 2-[3-(1-adamantyl)-4-substituted-5-thioxo-1,2,4-triazolin-1-yl]propionic acids and related derivatives. Arzneim.-Forsch. 56 (2006) 40–47.10.1055/s-0031-1296699Search in Google Scholar PubMed

Ishibashi, Y.; Umesato, T.; Fujiwara, M.; Une, K.; Yoneda, Y.; Sotome, H.; Katayama, T.; Kobatake, S.; Asahi, T.; Irie, M.; Miyasaka, H.: Solvent polarity dependence of photochromic reactions of a diarylethene derivative as revealed by steadtystate and transient spectroscopies. J. Phys. Chem. 120 (2016) 1170–1177.10.1021/acs.jpcc.5b08504Search in Google Scholar

Wang, J.; Liu, G.; Fan, C.; Pu, Sh.: Structure and photochromism of 1,2-bis[2-methyl-5-(2-chlorophenyl)-3-thienyl]-3,3,4,4,5, 5-hexafluorocyclopent-1-ene, C27H16Cl2F6S2. Z. Kristallogr. NCS 232 (2017) 359–361.Search in Google Scholar

Castineiras, A.; Garcia-Santos, I.: Desulfuration and cyclization of (Z)-2-[amino(pyridine-2-yl)methylene]hydrazonecarbothioamide in the presence of manganese(II). Z. Anorg. Allg. Chem. 634 (2008) 2907–2916.10.1002/zaac.200800326Search in Google Scholar

Received: 2018-01-14
Accepted: 2018-04-30
Published Online: 2018-05-22
Published in Print: 2018-07-26

©2018 Mohamed Reda Aouad et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

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  7. Crystal structure of catena-poly[aqua-(μ2-(3,5-di(1H-imidazol-1-yl)-pyridine-κ2N:N′)-(μ2-2-(carboxylatomethyl)benzoato-κ2O:O′)] cadmium(II), C20H17CdN5O5
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  78. Crystal structure of 1-heptylpyridazin-1-ium iodide, C11H19N2I
  79. The crystal structure of N-butylpyridinium bis(μ2-dichlorido)-tetrachloridodicopper(II), C18H28N2Cu2Cl6
  80. Crystal structure of 6-hydroxy-5-((2-hydroxy-6-oxocyclohex-1-en-1-yl)(4-methoxyphenyl)methyl)-1,3-dimethylpyrimidine-2,4(1H,3H)-dione, C20H22N2O6
  81. Crystal structure of bis(acetonitrile)-diaqua-dichloridoiron(II), C4H10Cl2N2O2Fe
https://doi.org/10.1515/ncrs-2018-0025
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of (E)-1-(4-(((E)-2-hydroxy-5-methylbenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C17H18N2O2
  3. Crystal structure of 1,3,5,7-tetraazaadamantane-1,3-diium 2,5-dicarboxyterephthalate, C16H18N4O8
  4. Crystal structure of guanidinium tetrabutyl-ammonium 5-hydroxyisophthalate dihydrate, C25H50N4O7
  5. Crystal structure of poly[aqua-(μ2-5-methoxyisophthalate-κ3O,O′:O′′)-(μ2-1,4-bis((1H-1,2,4-triazol-1-yl)methyl)benzene-κ2N:N′)nickel(II), NiC21H20N6O6
  6. Crystal structure of aqua-bis(3,4-dimethoxybenzoato-κ1O)-(2,2′-bipyridine-κ2N,N′)copper(II), C28H26CuN2O9
  7. Crystal structure of catena-poly[aqua-(μ2-(3,5-di(1H-imidazol-1-yl)-pyridine-κ2N:N′)-(μ2-2-(carboxylatomethyl)benzoato-κ2O:O′)] cadmium(II), C20H17CdN5O5
  8. The crystal structure of catena-poly[chlorido-(μ2-5-methyl-1,3,4-thiadiazole-2-thiolato-κ2S:N)mercury(II)], C3H3ClHgN2S2
  9. Crystal structure of (E)-2,4-dichloro-6-(((4-methyl-2-nitrophenyl)imino)methyl)phenol, C14H10Cl2N2O3
  10. Crystal structure of a new polymorph of bis[μ-1,3-bis(diphenylphosphino)propane-κ2P:P′-disilver(I)] bis(tetrafluoroborate), [Ag(dppp)]2(BF4)2, C54H52Ag2B2F8P4
  11. The crystal structure of 2-phenyl-4,6-bis(R-tert-butylsulfonamido)-1,3,5-triazine – ethyl acetate (2/1), C38H58N10O6S4
  12. Crystal structure of 6-amino-8-(2-methoxy-phenyl)-2-methyl-2,3,8,8a-tetrahydro-1H-iso-quinoline-5,7,7-tricarbonitrile monohydrate, C20H21N5O2
  13. Crystal structure of methyl (1-phenylethyl)carbamate, C10H13NO2
  14. Crystal structure of dimethanol-(μ2-squarato-κ2O:O′)-tetrakis(tri-p-tolylphosphane-κP)disilver(I) – methanol (1/2), C92H98Ag2O8P4
  15. Crystal structure of catena-poly[bis(μ2-1,4-bis(triazol-1-ylmethyl)benzene-κ2N:N′)-bis(5-tert-butyl-isophthalate-κO)copper(II)]tetrahydrate, C36H46CuN6O12
  16. Crystal structure of 4-aminopyridinium 4-acetyl-(pyridin-4-yl)-1H-1,2,3-triazol-5-olate monohydrate, C14H16N6O3
  17. Crystal structure of 2-(8-bromo-2-phenylimidazo[1,2-α]pyridin-3-yl)-6,7-dimethyl-3-phenylquinoxaline, C29H21BrN4
  18. Crystal structure of aqua(1-(2-pyridyl)ethanone oxime-κ2N,N′)(1-(2-pyridyl)ethanone oximato-κ2N,N′) nitrate monohydrate, C14H19N5O7Cu
  19. Crystal structure of poly[tetraaqua-(μ4-oxalato-κ4O,O′:O′′,O′′′)-(μ8-benzene-1,2,4,5-tetracarboxylato-κ8O1:O2:O3:O4:O5:O6:O7:O8)yttrium(III)], C6H5O8Y
  20. Crystal structure of bis{catena-poly[(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)silver(I)]} diaqua-bis(5-(4-carboxyphenyl)pyridine-2-carboxylato-κ2N,O)-(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)disilver(I) octahydrate, C31H35Ag2N4O9
  21. Crystal structure of (E)-N-(2-(benzylamino)-2-oxo-1-(4-oxo-4H-chromen-3-yl)ethyl)-N-(4-bromophenyl)-3-chloroacrylamide hydrate, C27H22BrClN2O5
  22. Crystal structure of catena-poly[octaaqua-bis(μ2-4,6-dicarboxyisophthalate-κ2O:O′)cadmium(II)disodium(I)] dihydrate, C20H28CdNa2O26
  23. Crystal structure of acetonitrile{bis(2-benzimidazolylmethyl)amine-κ3N,N′,N′′}-{maleato-κO}zinc(II) perchlorate - acetonitrile (1/1), C24H24ClN7O8Zn
  24. Crystal structure of 2-amino-4-(3,5-dibromo-4-hydroxyphenyl)-7-methyl-5-oxo-2H,5H-pyrano[4,3-b]pyran-3-carbonitrile, C16H10Br2N2O4
  25. Crystal structure of catena-poly[diaqua-(μ2-3,5-bis(pyridin-4-ylmethoxy)benzoate-κ2N:O) manganese(II)] tetrahydrate [(3,5-bis-(pyridin-4-ylmethoxy)-benzoic-κ1Oκ1N) manganese(II)] trihydrate, C38H42MnN4O14
  26. The crystal structure of 2-carboxybenzaldehyde-2-phenylacetohydrazone, C16H14N2O3
  27. The crystal structure of poly[μ2-aqua-(μ2-2-naphthylamine-1-sulfonato-κ3O,O′:O′′)sodium(I)], C10H10N1O4S1Na
  28. The crystal structure of phthalazin-1(2H)-one, C8H6N2O1
  29. Crystal structure of 3,5-bis(trifluoromethyl)benzyl(Z)-N-(adamantan-1-yl)morpholine-4-carbothioimidate, C24H28F6N2OS
  30. Crystal structure of diazido-bis(μ2-pyridin-2-ylmethanolato-κ2N:O)-bis(pyridin-2-ylmethanolato-κ2N,O)dicobalt(III) – methanol (1/3), C27H35Co2N10O7
  31. Crystal structure of N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide, C14H14F3N5O6S
  32. Crystal structure of 1-phenyl-N′-(1-phenyl-5-(thiophen-2-yl)-1H-pyrazole-3-carbonyl)-5-(thiophen-2-yl)-1H-pyrazole-3-carbohydrazide, C28H20N6O2S2
  33. The crystal structure of poly[bis(4-hydroxybenzoato-κO)-(μ2-4,4′-bipyridine-κ2N:N′)copper(II)] hydrate, C24H20N2O7Cu
  34. Crystal structure of poly[μ3-5-(4-(2,6-di(pyridine-2-yl)pyridine-4-yl)phenoxy)isophthalato-κ5O:O′,O′′:N,N′,N′′cobalt(II)], C29H17CoN3O5
  35. Crystal structure of poly[μ3-5-(4-(2,6-di(pyridine-2-yl)pyridine-4-yl)phenoxy)isophthalato-κ6O:O′,O′′:N,N′,N′′)cobalt(II)] C29H17CoN3O5
  36. Crystal structure of diaqua-(acetato-κ3O,O′:O′′)-(μ3-4,6-di(1H-imidazol-1-yl)isophthalato-κ4O:O′:O′′,O′′′)lanthanum(III), C16H15LaN4O8
  37. Synthesis and crystal structure of 6-carboxy-1-(3,5-dicarboxyphenyl)-1H-benzo[d]imidazol-3-ium-5-carboxylate dihydrate, C18H12N2O8
  38. Crystal structure of (E)-2-hydroxybenzaldehyde O-(2-(((E)-(4-(dimethylamino)benzylidene)amino)oxy)ethyl)oxime, C18H21N3O3
  39. Crystal structure of bis{2-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O}zinc(II), C32H30N4O4Zn
  40. Crystal structure of bis(9-aminoacridin-10-ium) tetrachloridocuprate(II) monohydrate, C26H24Cl4CuN4O
  41. The crystal structure of 4-tert-butyl-N′-[(E)-(4-fluoro-3-methoxyphenyl)methylidene]benzohydrazide, C19H21F1N2O2
  42. Crystal structure of (E)-3-(3-(5-methyl-1-4-tolyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)-1-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)prop-2-en-1-one, C31H26N8O
  43. Crystal structure of (E)-N′-(4-methoxybenzylidene)-5-methyl-1-(4-tolyl)-1H-1,2,3-triazole-4-carbohydrazide, C19H19N5O2
  44. Crystal structure and molecular packing of O-ethyl (2-chlorophenyl)carbamothioate, C9H10ClNOS
  45. Crystal structure of pyrene-2-carbaldehyde, C17H10O
  46. Crystal structure of (E)-2,4-diiodo-6-(4-methyl-2-nitrostyryl)phenol, C14H10I2N2O3
  47. Crystal structure of (E)-2,4-dichloro-6-(((4-methoxy-2-nitrophenyl)imino)methyl)phenol, C14H10Cl2N2O4
  48. Crystal structure of (E)-2-bromo-4-chloro-6-(4-methoxy-2-nitrostyryl)phenol, C14H10BrClN2O4
  49. Crystal structure of (E)-4,6-diiodo-2-(((4-methoxy-2-nitrophenyl)imino)methyl)-3-methylphenol, C14H10I2N2O4
  50. The crystal structure of 7-bromo-1-cyclopropyl-8-methyl-4-oxo-1,4-dihydroquinoline-3-carboxylic acid an intermediate of the ozenoxacin synthesis, C14H12BrNO3
  51. Crystal structure of bis(N-(1-(pyrazin-2-yl)ethylidene)nicotinohydrazonato-κ3N,N′,O)copper(II) C24H20N10O2Cu
  52. Crystal structure of diaqua-dinitrato-k2O,O′((Z)-N-((E)-1-(pyrazin-2-yl)ethylidene)nicotinohydrazonato-k3N,N′,O)europium(II), C12H14N7O9Eu
  53. Crystal structure of ethyl 4-amino-5-(5-methyl-1-(4-tolyl)-1H-1,2,3-triazole-4-carbonyl)-2-(phenylamino)thiophene-3-carboxylate, C24H23N5O3S
  54. The crystal structure of acridin-10-ium2-carboxybenzoate, C21H15NO4
  55. The crystal structure of 3-((phenylamino)methylene)-1,5-dioxaspiro[5.5]undecane-2,4-dione, C16H17N1O4
  56. Crystal structure of 12-chloro-5,6,7,12-tetrahydrodibenzo[c,f][1,5]oxastibocine, C14H12ClOSb
  57. Crystal structure of 4-((1,3-dioxoisoindolin-2-yl)methyl)phenethyl 4-methylbenzenesulfonate, C24H21NO5S
  58. Crystal structure of 3-methyl-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C9H8N2OS
  59. Crystal structure of tert-butyl (2-(4-oxo-2-thioxo-1,4-dihydroquinazolin-3(2H)-yl)ethyl)carbamate, C15H19N3O3S
  60. Crystal structure of ethyl 5-formyl-3,4-dimethylpyrrole-2-carboxylate–1-(propan-2-ylidene)thiosemicarbazide (1/1), C14H22N4O3S
  61. Crystal structure of bis-(N′-(5-ethoxycarbonyl-3,4-dimethyl-pyrrol-2-yl-methylidene)-3-hydroxybenzohydrazide-κ2O,N)copper(II) – dimethylformamide (1/2), C40H50N8O10Cu
  62. Crystal structure of bis(acetato-κO)bis{2-((1H-tetrazol-1-yl)methyl)-1H-benzo[d]imidazole-κN}zinc(II), C22H22N12O4Zn
  63. Crystal structure of 4-phenyl-3-((4-phenyl-1H-1,2,3-triazol-1-yl)methyl)-1H-1,2,4-triazole-5(4H)-thione, C17H14N6S
  64. Crystal structure of (Z)-N-(4-nitrophenyl)-3-phenyl-3-(phenylamino)acrylamide, C21H17N3O3
  65. Crystal structure of 1,1′-(pentane-1,5-diyl)bis(3-methyl-1H-imidazol-3-ium)bis(hexafluorophosphate), C13H22F12N4P2
  66. Synthesis and crystal structure of bis(furan-2-ylmethanaminium)-catena-[bis(μ2-phthalato-κ2O:O′)cobalt(II)], C26H24CoN2O10
  67. Crystal structure of methyl (R)-4-(o-chlorobenzoyl)-1-thia-4-azaspiro[4.5]decane-3-carboxylate, C17H20ClNO3S
  68. Crystal structure of 2-[[4-[2-[4-(4-methoxyphenyl)-1-piperazinyl]ethyl]phenyl] methyl]-1H-isoindole-1,3(2H)-dione, C28H29N3O3
  69. The crystal structure of benzenaminium 5,7-dihydroxy-4-oxo-2-phenyl-4H-chromene-8-sulfonate hydrate, C21H19NO8S
  70. Crystal structure of semiconducting potassium poly[(μ2-tetraselenido-κ2Se1:Se4)(μ2-pentaselenido-κ1Se1:Se1)argentate(I)], K3AgSe9
  71. Crystal structure of 2-isopropyl-8-methyl-phenanthrene-3,4-dione, C18H16O2
  72. Crystal structure of 2-isopropyl-8,8-dimethyl-5,6,7,8-tetrahydrophenanthrene-3,4-dione, C19H22O2
  73. Crystal structure of (E)-2-(1-((2-aminophenyl)imino)ethyl)-4-bromophenol, C14H13BrN2O
  74. Crystal structure of 1,1-di(4-cyanophenyl)-2,2-diphenylethene, C28H18N2
  75. Crystal structure of bis(hydroxylamido-κ2O,N)-oxido(1H-pyrazole-3-carboxylato-κ2O,N)vanadium(V), C4H7N4O5V
  76. The crystal structure of In1.2B3O5.6(OH)1.4
  77. The crystal structure of chlorido(2-(1H-pyrazol-3-yl)phenolato-κ2N,O)(2-(1H-pyrazol-3-yl)phenol-κN)copper(II), C18H15ClCuN4O2
  78. Crystal structure of 1-heptylpyridazin-1-ium iodide, C11H19N2I
  79. The crystal structure of N-butylpyridinium bis(μ2-dichlorido)-tetrachloridodicopper(II), C18H28N2Cu2Cl6
  80. Crystal structure of 6-hydroxy-5-((2-hydroxy-6-oxocyclohex-1-en-1-yl)(4-methoxyphenyl)methyl)-1,3-dimethylpyrimidine-2,4(1H,3H)-dione, C20H22N2O6
  81. Crystal structure of bis(acetonitrile)-diaqua-dichloridoiron(II), C4H10Cl2N2O2Fe
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