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Creep of binary Ni-rich NiTi shape memory alloys and the influence of pre-creep on martensitic transformations

  • G. Eggeler EMAIL logo , J. Khalil-Allafi , K. Neuking and A. Dlouhý
Published/Copyright: January 3, 2022
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Abstract

The present work represents an exploratory study of creep in a Ni-rich NiTi shape memory alloy (50.7 at.% Ni) in the temperature range 470 – 530 °C at stresses between 90 and 150 MPa. Creep of Ni-rich NiTi alloys is characterized by stress exponents of 2 (for the minimum creep rate data) and of 4.7 (for creep rates measured after 10% of accumulated strain). During creep, Ni4Ti3 precipitates (which nucleate and grow during heating under a small pre-load) coarsen. The interparticle spacing increases and this is why the resistance of the material to creep decreases. It was not possible to rationalize this creep softening on the basis of a traditional Orowan process. Instead a wrapping process, where particles were wrapped in by migrating sub-grain boundaries, was observed. The sharp minima in the creep curves and the strain dependence of the stress exponent as observed in the present study can be rationalized on the basis of an initial climb controlled bypassing of particles followed by this wrapping process, which becomes more intense as interparticle spacings increase. When comparing crept materials with materials which were aged at the same temperature for the same time there only is a small difference between the corresponding differential scanning calorimetry (DSC) charts. Therefore we conclude that the precipitation and coarsening of Ni4Ti3 particles during creep is more important in affecting DSC chart features than the evolution of a creep dislocation structure.


Dedicated to Professor Dr. Haël Mughrabi on the occasion of his 65th birthday

The authors would like to acknowledge funding by the Deutsche Forschungsgemeinschaft (DFG) in the framework of the shape memory center SFB 459 (“Formgedächtnistechnik”). A. D. acknowledges travelling support from the Grant Agency of the Czech Republic (contract no. 106/99/1172).

G. Eggeler Institut für Werkstoffe Ruhr-Universität Bochum, D-44780 Bochum, Germany Tel.: +49 234 32 23 022 Fax: +49 234 32 14 235

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Received: 2002-03-03
Published Online: 2022-01-03

© 2002 Carl Hanser Verlag, München

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